DE615744C - Diazotization process - Google Patents

Diazotization process

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Publication number
DE615744C
DE615744C DEG85050D DEG0085050D DE615744C DE 615744 C DE615744 C DE 615744C DE G85050 D DEG85050 D DE G85050D DE G0085050 D DEG0085050 D DE G0085050D DE 615744 C DE615744 C DE 615744C
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DE
Germany
Prior art keywords
water
diazotization
soluble
salts
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEG85050D
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German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Gesellschaft fuer Chemische Industrie in Basel CIBA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gesellschaft fuer Chemische Industrie in Basel CIBA filed Critical Gesellschaft fuer Chemische Industrie in Basel CIBA
Application granted granted Critical
Publication of DE615744C publication Critical patent/DE615744C/en
Expired legal-status Critical Current

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Description

Es wurde gefunden, daß sich primäre aromatische Basen, welche in Wasser schwer löslich, sind oder deren Salze in Wasser leicht der Hydrolyse unterliegen, leicht und glatt diazotieren lassen, wenn man in Gegenwart solcher säure- und salzbeständiger wasserlöslicher kapillaraktiver Stoffe arbeitet,, die keine oder leicht lösliche Diazosalze bilden. Das Verfahren eignet sich also für die Diazotierung solcher Basen, die nach den allgemein gebräuchlichen und geeigneten Diazotierungsverfahren nur schwer diazotierbar sind. Ferner verhindert die Mitverwendung der genanntein Hilfsstoffe die Bildung unerwünschter Nebenprodukte, die infolge Oxydation, Selbstkupplung usw. entstehen können.It has been found that primary aromatic bases, which are heavy in water soluble, or their salts are easily hydrolyzed in water, easily and smoothly Let diazotize if you are water-soluble in the presence of such acid and salt-resistant capillary-active substances, which form no or easily soluble diazo salts. The process is therefore suitable for the diazotization of such bases, which are generally used and suitable Diazotization processes are difficult to diazotize. It also prevents co-use the called one auxiliary substances the formation of undesired by-products, which as a result Oxidation, self-coupling, etc. can occur.

Als Hilfsstoffe eignen sich besonders die wasserlöslichen Kondensationsprodukte, die aus höheren Fettalkoholen und Äthylenoxyd erhalten werden; die mit Hilfe von höheren Fettsäuren acylierten asymmetrischen Dialkyläthylendiamine und deren Ammoniumverbindungen, Polyvinylalkohole, Methylcellulose, Alkalisalze des Oleyltaurins und des Ölsäureisäthionssäureesters usw.Particularly suitable auxiliaries are the water-soluble condensation products made from higher fatty alcohols and ethylene oxide obtained; the asymmetric dialkylethylenediamines acylated with the aid of higher fatty acids and their ammonium compounds, polyvinyl alcohols, methyl cellulose, alkali salts of oleyl taurine and oleic acid ester etc.

Beispiel. S Teile 4-(1'-Methyl)-phenoxyacetylamino -2, 5 - dimethoxy-1 -aminobenzol werden mit 0,3 Teilen Trimethylammoniummethylsulfat * des Monooleyläthylendiamins und 40 Teilen heißem Wasser gut angeteigt. Hierauf setzt man 6 Raumteile 32,10/0ige Salzsäure zu und stellt mit kaltem Wasser auf 200 Raumteile ein. Unter Rühren werden 5,5 Raumteile einer 250/oigen Natriumnitritlösung unter die Oberfläche der Flüssigkeit eingeführt. Nach kurzer Zeit ist die Diazotierung beendet.Example. S parts 4- (1'-methyl) -phenoxyacetylamino -2, 5 - dimethoxy-1-aminobenzene are mixed with 0.3 parts of trimethylammonium methyl sulfate * the Monooleyläthylendiamins and 40 parts of hot water well pasted. On this you place 6 room parts 32,10 / 0ige Add hydrochloric acid and adjust to 200 parts by volume with cold water. Be stirring 5.5 parts by volume of a 250% sodium nitrite solution inserted under the surface of the liquid. The diazotization takes place after a short time completed.

Ähnlich verfährt man mit anderen Basen, wie z. B. !mit dem i-Amino-2, 5-dichlor-4-benzoylaminobenzol, oder tnit dem Anilid des 2-Amino-5, 4'-dichlor-4-carbonsäure-1, i'-diphenyläthers. The procedure is similar with other bases, such as B.! With the i-amino-2, 5-dichloro-4-benzoylaminobenzene, or with the anilide of 2-amino-5, 4'-dichloro-4-carboxylic acid-1, i'-diphenyl ether.

Claims (1)

Patentanspruch:Claim: Diazotierungsverfahren für primäre aromatische Basen, welche in Wasser schwer löslich sind oder deren Salze in Wasser leicht der Hydrolyse unterliegen, gekennzeichnet durch den vor Beginn der Diazotierung erfolgenden Zusatz von solchen säure- und salzbeständigen wasserlöslichen kapillaraktiven Stoffen, die keine oder leicht lösliche Diazosalze bilden.Diazotization process for primary aromatic bases, which are in water are sparingly soluble or the salts of which are easily subject to hydrolysis in water, characterized by the addition of such acid- and salt-resistant water-soluble ones before the start of the diazotization capillary-active substances that do not form any or easily soluble diazo salts.
DEG85050D 1933-03-09 1933-03-12 Diazotization process Expired DE615744C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH769591X 1933-03-09

Publications (1)

Publication Number Publication Date
DE615744C true DE615744C (en) 1935-07-11

Family

ID=4535291

Family Applications (1)

Application Number Title Priority Date Filing Date
DEG85050D Expired DE615744C (en) 1933-03-09 1933-03-12 Diazotization process

Country Status (3)

Country Link
CH (1) CH165829A (en)
DE (1) DE615744C (en)
FR (1) FR769591A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1023771B (en) * 1956-03-09 1958-02-06 Bayer Ag Process for the diazotization of aromatic amines which are sparingly soluble in water, the salts of which are easily hydrolyzed in water

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1023771B (en) * 1956-03-09 1958-02-06 Bayer Ag Process for the diazotization of aromatic amines which are sparingly soluble in water, the salts of which are easily hydrolyzed in water

Also Published As

Publication number Publication date
FR769591A (en) 1934-08-28
CH165829A (en) 1933-12-15

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