DE60305203D1 - BORON CONTAINING LITHIUM INTERCALATION COMPOUNDS FOR USE AS ACTIVE MATERIALS FOR ELECTRODES, STORAGE MEDIA AND ELECTROCHROMICAL DEVICES - Google Patents
BORON CONTAINING LITHIUM INTERCALATION COMPOUNDS FOR USE AS ACTIVE MATERIALS FOR ELECTRODES, STORAGE MEDIA AND ELECTROCHROMICAL DEVICESInfo
- Publication number
- DE60305203D1 DE60305203D1 DE60305203T DE60305203T DE60305203D1 DE 60305203 D1 DE60305203 D1 DE 60305203D1 DE 60305203 T DE60305203 T DE 60305203T DE 60305203 T DE60305203 T DE 60305203T DE 60305203 D1 DE60305203 D1 DE 60305203D1
- Authority
- DE
- Germany
- Prior art keywords
- compounds
- lithium
- electrochromical
- electrodes
- devices
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001875 compounds Chemical class 0.000 title abstract 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title abstract 5
- 229910052744 lithium Inorganic materials 0.000 title abstract 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title 1
- 239000011149 active material Substances 0.000 title 1
- 229910052796 boron Inorganic materials 0.000 title 1
- 230000002687 intercalation Effects 0.000 title 1
- 238000009830 intercalation Methods 0.000 title 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 4
- 238000003780 insertion Methods 0.000 abstract 3
- 230000037431 insertion Effects 0.000 abstract 3
- 229910052719 titanium Inorganic materials 0.000 abstract 3
- 239000007772 electrode material Substances 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 2
- 239000011572 manganese Substances 0.000 abstract 2
- KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 229910052732 germanium Inorganic materials 0.000 abstract 1
- -1 lithium cobaltate Chemical class 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 229910052609 olivine Inorganic materials 0.000 abstract 1
- 239000010450 olivine Substances 0.000 abstract 1
- 229910052596 spinel Inorganic materials 0.000 abstract 1
- 239000011029 spinel Substances 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- YTZVWGRNMGHDJE-UHFFFAOYSA-N tetralithium;silicate Chemical compound [Li+].[Li+].[Li+].[Li+].[O-][Si]([O-])([O-])[O-] YTZVWGRNMGHDJE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
- H01M4/1315—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
- H01M4/13915—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/582—Halogenides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
Abstract
Boron-doped lithium insertion compounds (I) are new. Boron-doped lithium insertion compounds of formula (I) are new: LiaMbM1vM2wM3xM4yM5zBc(XO4-eZe) (I) M = divalent V, Mn, Fe, Co or Ni; M1 = Na or K; M2 = divalent Mg, Zn, Cu, Ti or Ca; M3 = trivalent Al, Ti, Cr, Fe, Mn, Ga or V; M4 = tetravalent Ti, Ge, Sn, V or Zr; M5 = pentavalent V, Nb or Ta; X = B3+, Al3+, V5+, Si4+, P5+, S6+ and/or Ge4+; Z = F, Cl, Br or I; a = 0-2; b = 1-2; c = a number greater than zero; e = 0-2; a + 2b + 3c + v + 2w + 3x + 4y + 5z + m = 8-e; c/(b+v+w+x+y+z) = 0-0.1 but not zero. Independent claims are also included for: (1) a process for preparing (I); (2) active electrode material comprising one or more compounds (I) and optionally one or more other active compounds, e.g. lithium cobaltate, lithium nickelate, lithium manganese spinel, olivine isotype compounds, Nasicon compounds and lithium orthosilicate insertion compounds; (3) positive electrode comprising the active electrode material; (4) accumulator comprising the positive electrode; and (5) electrochromic device comprising (I).
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0215343 | 2002-12-05 | ||
FR0215343A FR2848205B1 (en) | 2002-12-05 | 2002-12-05 | BORON SUBSTITUTED LITHIUM INSERTION COMPOUNDS, ELECTRODE ACTIVE MATERIALS, ACCUMULATORS AND ELECTROCHROME DEVICES |
PCT/FR2003/050148 WO2004052787A1 (en) | 2002-12-05 | 2003-12-02 | Boron-substituted lithium compounds, active electrode materials, batteries and electrochrome devices |
Publications (2)
Publication Number | Publication Date |
---|---|
DE60305203D1 true DE60305203D1 (en) | 2006-06-14 |
DE60305203T2 DE60305203T2 (en) | 2007-03-01 |
Family
ID=32320006
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60305203T Expired - Lifetime DE60305203T2 (en) | 2002-12-05 | 2003-12-02 | BORON CONTAINING LITHIUM INTERCALATION COMPOUNDS FOR USE AS ACTIVE MATERIALS FOR ELECTRODES, STORAGE MEDIA AND ELECTROCHROMICAL DEVICES |
Country Status (9)
Country | Link |
---|---|
US (1) | US7529014B2 (en) |
EP (1) | EP1567452B1 (en) |
JP (1) | JP4773964B2 (en) |
CN (1) | CN100371254C (en) |
AT (1) | ATE325778T1 (en) |
DE (1) | DE60305203T2 (en) |
ES (1) | ES2264036T3 (en) |
FR (1) | FR2848205B1 (en) |
WO (1) | WO2004052787A1 (en) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100418255C (en) * | 2005-12-23 | 2008-09-10 | 清华大学 | Method for preparing lithium enriched lithium ion phosphate powder |
CN101855754B (en) * | 2007-11-12 | 2013-07-03 | 户田工业株式会社 | Lithium manganate particle powder for nonaqueous electrolyte secondary battery, method for producing the same, and nonaqueous electrolyte secondary battery |
TWI466370B (en) * | 2008-01-17 | 2014-12-21 | A123 Systems Inc | Mixed metal olivine electrode materials for lithium ion batteries |
TW200951066A (en) * | 2008-04-17 | 2009-12-16 | Basf Se | Process for the preparation of crystalline lithium-, iron-and phosphate-comprising materials |
TW201010944A (en) * | 2008-04-17 | 2010-03-16 | Basf Se | Process for the preparation of crystalline lithium-, iron-and phosphate-comprising materials |
DE102008029804A1 (en) | 2008-06-24 | 2010-07-08 | Süd-Chemie AG | Mixed oxide containing a lithium manganese spinel and process for its preparation |
CA2772255A1 (en) * | 2009-09-24 | 2011-03-31 | Valence Technology, Inc. | Manganese phosphates and related electrode active materials |
EP2355214B1 (en) | 2010-01-28 | 2013-12-25 | Prayon | Lithium accumulators based on lithiated iron phosphate and carbon |
US9160001B2 (en) | 2010-12-23 | 2015-10-13 | Wildcat Discovery Technologies, Inc. | Lithium-ion battery materials with improved properties |
KR101233410B1 (en) | 2011-01-31 | 2013-02-15 | 한국과학기술원 | Cathode active material for lithium secondary battery, method for preparing same, and lithium battery comprising same |
DE102011012552A1 (en) | 2011-02-24 | 2012-08-30 | Schott Ag | Lithium-ion battery |
CN102569803A (en) * | 2012-02-29 | 2012-07-11 | 华南理工大学 | Lithium iron phosphate/PpyPy composite cathode material for boron-doped modification lithium ion battery and preparation method therefor |
JP2016039027A (en) * | 2014-08-07 | 2016-03-22 | トヨタ自動車株式会社 | Positive electrode active material for lithium secondary battery, lithium secondary battery, and method for producing positive electrode active material for lithium secondary battery |
US10266410B2 (en) | 2015-01-08 | 2019-04-23 | Advanced Lithium Electrochemistry Co., Ltd. | Preparation method of battery composite material and precursor thereof |
KR102368975B1 (en) * | 2015-08-24 | 2022-03-03 | 삼성전자주식회사 | Cathode active material, cathode and lithium secondary battery including the same, and method of preparing the cathode active material |
CN108254989B (en) * | 2016-12-29 | 2020-09-29 | 宁波祢若电子科技有限公司 | All-solid-state electrochromic window, solid-state electrochromic mirror and preparation method of all-solid-state electrochromic window and solid-state electrochromic mirror |
EP3415470A1 (en) | 2017-06-14 | 2018-12-19 | Karlsruher Institut für Technologie | Boron-doped sodium-ion cathode material, method of producing same and its use |
JP7164178B2 (en) * | 2018-12-27 | 2022-11-01 | 株式会社オキサイド | lithium metal phosphate, positive electrode material for lithium ion secondary battery, lithium ion secondary battery |
CN114335433B (en) * | 2021-12-31 | 2023-09-05 | 松山湖材料实验室 | Positive electrode lithium supplementing material, preparation method and application thereof |
EP4379838A1 (en) * | 2022-04-29 | 2024-06-05 | Contemporary Amperex Technology Co., Limited | Secondary battery, and battery module, battery pack and electric device comprising same |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6085015A (en) * | 1997-03-25 | 2000-07-04 | Hydro-Quebec | Lithium insertion electrode materials based on orthosilicate derivatives |
JP3639468B2 (en) * | 1999-08-04 | 2005-04-20 | 三洋電機株式会社 | Lithium secondary battery |
JP2002056849A (en) * | 2000-08-09 | 2002-02-22 | Toshiba Battery Co Ltd | Lithium ion secondary battery |
JP4724911B2 (en) * | 2000-10-05 | 2011-07-13 | ソニー株式会社 | Nonaqueous electrolyte secondary battery |
JP3982165B2 (en) * | 2000-10-05 | 2007-09-26 | ソニー株式会社 | Solid electrolyte battery |
JP2002117903A (en) * | 2000-10-05 | 2002-04-19 | Sony Corp | Nonaqueous electrolyte battery |
JP4126862B2 (en) * | 2000-10-05 | 2008-07-30 | ソニー株式会社 | Non-aqueous electrolyte battery and solid electrolyte battery |
TW513822B (en) * | 2000-10-06 | 2002-12-11 | Sony Corp | Method for producing cathode active material and method for producing non-aqueous electrolyte cell |
JP4491949B2 (en) * | 2000-10-06 | 2010-06-30 | ソニー株式会社 | Method for producing positive electrode active material and method for producing non-aqueous electrolyte battery |
JP2002117908A (en) * | 2000-10-06 | 2002-04-19 | Sony Corp | Nonaqueous electrolyte battery |
JP3997702B2 (en) * | 2000-10-06 | 2007-10-24 | ソニー株式会社 | Nonaqueous electrolyte secondary battery |
JP3988374B2 (en) * | 2000-10-06 | 2007-10-10 | ソニー株式会社 | Non-aqueous electrolyte secondary battery |
JP4491950B2 (en) * | 2000-10-06 | 2010-06-30 | ソニー株式会社 | Method for producing positive electrode active material and method for producing non-aqueous electrolyte battery |
CN100414746C (en) * | 2001-12-21 | 2008-08-27 | 麻省理工学院 | Conductive lithium storage electrode |
-
2002
- 2002-12-05 FR FR0215343A patent/FR2848205B1/en not_active Expired - Lifetime
-
2003
- 2003-12-02 DE DE60305203T patent/DE60305203T2/en not_active Expired - Lifetime
- 2003-12-02 US US10/536,178 patent/US7529014B2/en not_active Expired - Fee Related
- 2003-12-02 EP EP03799704A patent/EP1567452B1/en not_active Expired - Lifetime
- 2003-12-02 WO PCT/FR2003/050148 patent/WO2004052787A1/en active IP Right Grant
- 2003-12-02 ES ES03799704T patent/ES2264036T3/en not_active Expired - Lifetime
- 2003-12-02 CN CNB2003801047378A patent/CN100371254C/en not_active Expired - Fee Related
- 2003-12-02 JP JP2006527177A patent/JP4773964B2/en not_active Expired - Fee Related
- 2003-12-02 AT AT03799704T patent/ATE325778T1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE60305203T2 (en) | 2007-03-01 |
EP1567452B1 (en) | 2006-05-10 |
FR2848205A1 (en) | 2004-06-11 |
ES2264036T3 (en) | 2006-12-16 |
WO2004052787A8 (en) | 2004-08-19 |
JP4773964B2 (en) | 2011-09-14 |
FR2848205B1 (en) | 2006-03-24 |
WO2004052787A1 (en) | 2004-06-24 |
ATE325778T1 (en) | 2006-06-15 |
CN1720197A (en) | 2006-01-11 |
US20060127295A1 (en) | 2006-06-15 |
JP2007502249A (en) | 2007-02-08 |
US7529014B2 (en) | 2009-05-05 |
CN100371254C (en) | 2008-02-27 |
EP1567452A1 (en) | 2005-08-31 |
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