DE60235487D1 - Suspensionsverfahren für die kohlenwasserstoffsynthese mit einer isomerierungszone in einem externen aufwärtsstrom schleifenreaktor - Google Patents

Suspensionsverfahren für die kohlenwasserstoffsynthese mit einer isomerierungszone in einem externen aufwärtsstrom schleifenreaktor

Info

Publication number
DE60235487D1
DE60235487D1 DE60235487T DE60235487T DE60235487D1 DE 60235487 D1 DE60235487 D1 DE 60235487D1 DE 60235487 T DE60235487 T DE 60235487T DE 60235487 T DE60235487 T DE 60235487T DE 60235487 D1 DE60235487 D1 DE 60235487D1
Authority
DE
Germany
Prior art keywords
isomeration
zone
loop reactor
hydrocarbon synthesis
suspension method
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60235487T
Other languages
English (en)
Inventor
Charles Mart
Robert Jay Wittenbrink
Janet Renee Clark
Jennifer Schaefer Feeley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Application granted granted Critical
Publication of DE60235487D1 publication Critical patent/DE60235487D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/2485—Monolithic reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/006—Separating solid material from the gas/liquid stream by filtration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/226—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00823—Mixing elements
    • B01J2208/00831—Stationary elements
    • B01J2208/0084—Stationary elements inside the bed, e.g. baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023—Details
    • B01J2208/024—Particulate material
    • B01J2208/025—Two or more types of catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S208/00—Mineral oils: processes and products
    • Y10S208/95—Processing of "fischer-tropsch" crude

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
DE60235487T 2001-11-06 2002-09-27 Suspensionsverfahren für die kohlenwasserstoffsynthese mit einer isomerierungszone in einem externen aufwärtsstrom schleifenreaktor Expired - Lifetime DE60235487D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/992,390 US6649803B2 (en) 2001-11-06 2001-11-06 Slurry hydrocarbon synthesis with isomerization zone in external lift reactor loop
PCT/US2002/030741 WO2003040069A2 (en) 2001-11-06 2002-09-27 Slurry hydrocarbon synthesis with isomerization zone in external lift reactor loop

Publications (1)

Publication Number Publication Date
DE60235487D1 true DE60235487D1 (de) 2010-04-08

Family

ID=25538287

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60235487T Expired - Lifetime DE60235487D1 (de) 2001-11-06 2002-09-27 Suspensionsverfahren für die kohlenwasserstoffsynthese mit einer isomerierungszone in einem externen aufwärtsstrom schleifenreaktor

Country Status (15)

Country Link
US (1) US6649803B2 (de)
EP (1) EP1444178B1 (de)
JP (1) JP4423035B2 (de)
CN (1) CN1302091C (de)
AR (1) AR037028A1 (de)
AT (1) ATE458710T1 (de)
AU (1) AU2002327073B2 (de)
CA (1) CA2466374A1 (de)
DE (1) DE60235487D1 (de)
DK (1) DK1444178T3 (de)
ES (1) ES2340665T3 (de)
SA (1) SA02230390B1 (de)
TW (1) TW574359B (de)
WO (1) WO2003040069A2 (de)
ZA (1) ZA200403384B (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20031361A1 (it) * 2003-07-03 2005-01-04 Enitecnologie Spa Processo per la preparazione di distillati medi e basi lube a partire da cariche idrocarburiche sintetiche.
GB2410449B (en) * 2004-01-28 2008-05-21 Statoil Asa Fischer-Tropsch catalysts
US9168501B2 (en) * 2007-09-10 2015-10-27 Res Usa, Llc Commercial Fischer-Tropsch reactor
GB2473071B (en) 2009-09-01 2013-09-11 Gtl F1 Ag Fischer-tropsch catalysts
GB2475492B (en) 2009-11-18 2014-12-31 Gtl F1 Ag Fischer-Tropsch synthesis
EP2603316B1 (de) 2010-08-09 2017-04-19 Gtl. F1 Ag Fischer-tropsch-katalysatoren
US8519011B2 (en) * 2010-10-28 2013-08-27 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid hydrocarbon mixtures using alternating layers of synthesis gas conversion catalyst, hydrocracking and hydroisomerization catalyst
US8424164B2 (en) * 2010-12-02 2013-04-23 Eaton Corporation Flexible grip with partially textured surface and method of making same
US9006297B2 (en) * 2012-06-16 2015-04-14 Robert P. Herrmann Fischer tropsch method for offshore production risers for oil and gas wells
EP3043898A1 (de) * 2013-09-09 2016-07-20 Zoneflow Reactor Technologies, LLC Nicht-adiabatischer katalytischer reaktor
CN112770834B (zh) * 2018-09-05 2023-07-21 巴斯夫欧洲公司 进行气/液两相高压反应的方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4471145A (en) * 1982-12-01 1984-09-11 Mobil Oil Corporation Process for syngas conversions to liquid hydrocarbon products utilizing zeolite Beta
US4523047A (en) * 1982-12-01 1985-06-11 Mobil Oil Corporation Process for syngas conversions to liquid hydrocarbon products utilizing ZSM-45 zeolite
US4423265A (en) * 1982-12-01 1983-12-27 Mobil Oil Corporation Process for snygas conversions to liquid hydrocarbon products
US4832819A (en) 1987-12-18 1989-05-23 Exxon Research And Engineering Company Process for the hydroisomerization and hydrocracking of Fisher-Tropsch waxes to produce a syncrude and upgraded hydrocarbon products
FR2676749B1 (fr) * 1991-05-21 1993-08-20 Inst Francais Du Petrole Procede d'hydroisomerisation de paraffines issues du procede fischer-tropsch a l'aide de catalyseurs a base de zeolithe h-y.
US5382748A (en) * 1992-12-18 1995-01-17 Exxon Research & Engineering Co. Hydrocarbon synthesis reactor employing vertical downcomer with gas disengaging means
US5659108A (en) * 1995-07-07 1997-08-19 The Dow Chemical Company Process for the complete saturation of halogenated hydrocarbon streams containing unsaturated compounds
GB2322633A (en) 1997-02-28 1998-09-02 Norske Stats Oljeselskap Fischer-Tropsch reactor
US5821270A (en) 1997-05-02 1998-10-13 Exxon Research And Engineering Company Slurry hydrocarbon synthesis process with multistage catalyst rejuvenation
US5958986A (en) * 1997-05-02 1999-09-28 Exxon Research And Engineering Co. Slurry hydrocarbon synthesis process with catalyst rejuvenation in external lift pipe (law544)
US5811469A (en) * 1997-05-06 1998-09-22 Exxon Research And Engineering Company Slurry hydrocarbon synthesis with downcomer fed product filtration (LAW552)
US5866621A (en) 1997-05-06 1999-02-02 Exxon Research And Engineering Company Gas and solids reducing slurry downcomer
US5811468A (en) 1997-05-06 1998-09-22 Exxon Research And Engineering Company Combination gas disengaging downcomer-rejuvenation tube for in-situ slurry catalyst rejuvenation (LAW541)
IT1301801B1 (it) * 1998-06-25 2000-07-07 Agip Petroli Procedimento per la preparazione di idrocarburi da gas di sintesi
JP3648430B2 (ja) * 2000-04-04 2005-05-18 トヨタ自動車株式会社 合成ガスからの低級イソパラフィンの合成方法

Also Published As

Publication number Publication date
DK1444178T3 (da) 2010-06-07
US20030088138A1 (en) 2003-05-08
ES2340665T3 (es) 2010-06-08
ATE458710T1 (de) 2010-03-15
JP4423035B2 (ja) 2010-03-03
SA02230390B1 (ar) 2007-07-31
AR037028A1 (es) 2004-10-20
US6649803B2 (en) 2003-11-18
TW574359B (en) 2004-02-01
ZA200403384B (en) 2005-02-22
AU2002327073B2 (en) 2007-07-26
JP2005508408A (ja) 2005-03-31
EP1444178A2 (de) 2004-08-11
WO2003040069A3 (en) 2003-12-04
WO2003040069A2 (en) 2003-05-15
CN1302091C (zh) 2007-02-28
EP1444178B1 (de) 2010-02-24
CN1578822A (zh) 2005-02-09
CA2466374A1 (en) 2003-05-15

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