DE60210867D1 - Reduction of organic chlorine formed during chlorine dioxide bleaching - Google Patents
Reduction of organic chlorine formed during chlorine dioxide bleachingInfo
- Publication number
- DE60210867D1 DE60210867D1 DE60210867T DE60210867T DE60210867D1 DE 60210867 D1 DE60210867 D1 DE 60210867D1 DE 60210867 T DE60210867 T DE 60210867T DE 60210867 T DE60210867 T DE 60210867T DE 60210867 D1 DE60210867 D1 DE 60210867D1
- Authority
- DE
- Germany
- Prior art keywords
- chlorine
- aox
- chlorine dioxide
- bleaching
- pulp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/12—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds
- D21C9/14—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites
- D21C9/142—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites with ClO2/Cl2 in a multistage process involving ClO2/Cl2 exclusively
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/12—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds
- D21C9/14—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites
- D21C9/144—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites with ClO2/Cl2 and other bleaching agents in a multistage process
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to an improvement in bleaching of kraft pulp. In ECF bleaching chlorine dioxide is most often a prefered bleaching chemical in certain process positions. The disadvantage is that residual amounts of organically bound chlorine in form of AOX, i.e organically bound chlorine in effluents, and/or OCl, i.e. chlorine organically bound in the produced pulp, is obtained. A normal approach has been to reduce charges of chlorine dioxide. According to the invention could substantial reductions in AOX levels be obtained if the process conditions in the chlorine dioxide stage elevated to above 91 DEG C and extended to more than 90 minutes. A major reduction of AOX up to 50% have been shown without a corresponding increase in OCI. The chlorinated substances is degraded by the process conditions to harmless chloride ions, instead of being liberated into the effluent as AOX or bound to pulp as OCl. <IMAGE>
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/SE2001/001262 WO2002099186A1 (en) | 2001-06-06 | 2001-06-06 | Reduction of organically bound chlorine formed in chlorine dioxide bleaching |
WOPCT/SE01/01262 | 2001-06-06 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE60210867D1 true DE60210867D1 (en) | 2006-06-01 |
DE60210867T2 DE60210867T2 (en) | 2007-05-10 |
Family
ID=20283731
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60210867T Revoked DE60210867T2 (en) | 2001-06-06 | 2002-04-03 | Reduction of organic chlorine formed during chlorine dioxide bleaching |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1270805B1 (en) |
JP (1) | JP2004522008A (en) |
AT (1) | ATE324485T1 (en) |
BR (1) | BR0202504A (en) |
DE (1) | DE60210867T2 (en) |
WO (1) | WO2002099186A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050051288A1 (en) * | 2003-09-09 | 2005-03-10 | Caifang Yin | Extended retention and medium consistency pulp treatment |
US8920603B2 (en) | 2006-10-11 | 2014-12-30 | Akzo Nobel N.V. | Bleaching of pulp |
BRPI0719893A2 (en) * | 2006-10-11 | 2014-05-06 | Akzo Nobel Nv | PULP BLEACHING |
CN112908423B (en) * | 2021-01-07 | 2022-10-11 | 广西大学 | Method for reducing AOX discharge amount in ECF bleaching process |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE334286B (en) * | 1968-12-05 | 1971-04-19 | Mo Och Domsjoe Ab | |
CA864409A (en) * | 1969-04-14 | 1971-02-23 | H. Andrews Douglas | Pulp bleaching process |
SE9000340L (en) * | 1990-01-31 | 1991-08-01 | Eka Nobel Ab | PROCEDURES FOR BLACKING OF LIGNOCELLULOSALLY MATERIAL |
SE506938C3 (en) * | 1996-06-28 | 1998-04-20 | Sunds Defibrator Ind Ab | Pressurized chlorine dioxide bleaching with chlorine dioxide recovery |
JPH1181173A (en) * | 1997-09-01 | 1999-03-26 | Oji Paper Co Ltd | Production of bleached pulp |
AU2822099A (en) * | 1998-03-16 | 1999-10-11 | Pulp And Paper Research Institute Of Canada | Chlorine dioxide bleaching with additives |
BR9901291B1 (en) * | 1999-04-27 | 2011-11-01 | process for bleaching low consistency chemical pulps. |
-
2001
- 2001-06-06 JP JP2003502286A patent/JP2004522008A/en active Pending
- 2001-06-06 WO PCT/SE2001/001262 patent/WO2002099186A1/en active Application Filing
-
2002
- 2002-04-03 DE DE60210867T patent/DE60210867T2/en not_active Revoked
- 2002-04-03 AT AT02076282T patent/ATE324485T1/en not_active IP Right Cessation
- 2002-04-03 EP EP02076282A patent/EP1270805B1/en not_active Revoked
- 2002-06-06 BR BR0202504-3A patent/BR0202504A/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ATE324485T1 (en) | 2006-05-15 |
BR0202504A (en) | 2003-04-01 |
DE60210867T2 (en) | 2007-05-10 |
EP1270805B1 (en) | 2006-04-26 |
EP1270805A2 (en) | 2003-01-02 |
JP2004522008A (en) | 2004-07-22 |
EP1270805A3 (en) | 2003-02-26 |
WO2002099186A1 (en) | 2002-12-12 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8339 | Ceased/non-payment of the annual fee | ||
8331 | Complete revocation | ||
8380 | Miscellaneous part iii |
Free format text: DIE ZURUECKNAHME VOM 19.02.2009 WURDE GELOESCHT. |