DE60210089D1 - METALLOCENE, USE IN CATALYSTS FOR OLEFIN POLYMERIZATION - Google Patents
METALLOCENE, USE IN CATALYSTS FOR OLEFIN POLYMERIZATIONInfo
- Publication number
- DE60210089D1 DE60210089D1 DE60210089T DE60210089T DE60210089D1 DE 60210089 D1 DE60210089 D1 DE 60210089D1 DE 60210089 T DE60210089 T DE 60210089T DE 60210089 T DE60210089 T DE 60210089T DE 60210089 D1 DE60210089 D1 DE 60210089D1
- Authority
- DE
- Germany
- Prior art keywords
- sup
- atom
- sub
- hydrogen atoms
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000001336 alkenes Chemical class 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 6
- 239000004215 Carbon black (E152) Substances 0.000 abstract 5
- 229930195733 hydrocarbon Natural products 0.000 abstract 5
- 125000004429 atom Chemical group 0.000 abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052735 hafnium Chemical group 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Chemical group 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
- C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
- C07F7/0814—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring said ring is substituted at a C ring atom by Si
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Abstract
A metallocene compound of formula (I): wherein M is zirconium, titanium and hafnium; X is a hydrogen atom, a halogen atom or a hydrocarbon radical; R<SUP>1 </SUP>is a linear C<SUB>1</SUB>-C<SUB>20</SUB>-alkyl radical; R<SUP>2 </SUP>is a hydrogen atom or hydrocarbon R<SUP>3</SUP>, R<SUP>4</SUP>, R<SUP>5</SUP>, R<SUP>6</SUP>, R<SUP>7</SUP>, and R<SUP>8</SUP>, are hydrogen atoms or hydrocarbon radicals, A is a sulphur (S) atom or an oxygen (O) atom; Q is a radical of formula (II), (III) or (IV) being bonded to the indenyl at the position indicated by the symbol *; (II), (III), (IV) wherein T<SUP>1 </SUP>is a sulphur atom, an oxygen (O) atom or a NR; R<SUP>9</SUP>, R<SUP>10 </SUP>and R<SUP>11 </SUP>are hydrogen atoms or hydrocarbon radicals; T<SUP>2</SUP>, T<SUP>3</SUP>, T<SUP>4</SUP>, T<SUP>5</SUP>, and T<SUP>6 </SUP>are carbon atoms (C) or nitrogen atoms (N); m<SUP>1</SUP>, m<SUP>2</SUP>, m<SUP>3</SUP>, m<SUP>4 </SUP>and m<SUP>5 </SUP>are 0 or 1; R<SUP>12</SUP>, R<SUP>13</SUP>, R<SUP>14</SUP>, R<SUP>15 </SUP>and R<SUP>16 </SUP>are hydrogen atoms or hydrocarbon radicals with the provisos that at least one of R<SUP>12</SUP>, R<SUP>13</SUP>, R<SUP>14</SUP>, R<SUP>15 </SUP>and R<SUP>16 </SUP>is different from hydrogen atoms, and that no more than two of T<SUP>2</SUP>, T<SUP>3</SUP>, T<SUP>4</SUP>, T<SUP>5 </SUP>and T<SUP>6 </SUP>are nitrogen atoms.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01202413 | 2001-06-22 | ||
| EP01202413 | 2001-06-22 | ||
| PCT/EP2002/007093 WO2003000706A1 (en) | 2001-06-22 | 2002-06-20 | Metallocenes, use in catalyst systems for producing olefin polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60210089D1 true DE60210089D1 (en) | 2006-05-11 |
| DE60210089T2 DE60210089T2 (en) | 2006-10-19 |
Family
ID=8180524
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60210089T Expired - Fee Related DE60210089T2 (en) | 2001-06-22 | 2002-06-20 | METALLOCENE, USE IN CATALYSTS FOR OLEFIN POLYMERIZATION |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7241903B2 (en) |
| EP (1) | EP1397371B1 (en) |
| JP (1) | JP4418228B2 (en) |
| AT (1) | ATE321061T1 (en) |
| DE (1) | DE60210089T2 (en) |
| WO (1) | WO2003000706A1 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002100908A1 (en) * | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| DE60233961D1 (en) * | 2001-06-12 | 2009-11-19 | Basell Polyolefine Gmbh | Process for the polymerization of butene-1 |
| EP1406969A1 (en) * | 2001-07-17 | 2004-04-14 | Basell Polyolefine GmbH | Multistep process for the (co)polymerization of olefins |
| US7534848B2 (en) * | 2002-12-04 | 2009-05-19 | Basell Polyolefine Gmbh | 1-butene copolymers and process for preparing them |
| US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| EP1622948B1 (en) | 2003-05-12 | 2019-11-20 | Basell Polyolefine GmbH | Process for polymerizing 1-butene |
| EP1765886A1 (en) * | 2004-07-13 | 2007-03-28 | Basell Polyolefine GmbH | Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom |
| WO2006102106A1 (en) * | 2005-03-17 | 2006-09-28 | University Of Maryland, College Park | Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby |
| KR101653356B1 (en) | 2014-10-17 | 2016-09-01 | 주식회사 엘지화학 | Metallocene catalyst for preparing polyolefin with high molecular weight |
| KR101653357B1 (en) | 2014-11-06 | 2016-09-01 | 주식회사 엘지화학 | Metallocene catalyst for preparing polyolefin with high molecular weight |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU6158390A (en) | 1989-08-03 | 1991-03-11 | Exxon Chemical Patents Inc. | Very high molecular weight polyethylene |
| BR9106589A (en) | 1990-06-22 | 1993-06-01 | Exxon Chemical Patents Inc | ALUMINUM-FREE MONOCYCLOPENTADYLENE METAL CATALYSTS FOR THE POLYMERIZATION OF OLEFINS |
| IT1264680B1 (en) | 1993-07-07 | 1996-10-04 | Spherilene Srl | SUPPORTED CATALYSTS FOR THE POLYMERIZATION OF OLEFINS |
| US5594080A (en) | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
| IT1269837B (en) | 1994-05-26 | 1997-04-15 | Spherilene Srl | COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINS |
| KR100536794B1 (en) * | 1996-11-15 | 2005-12-14 | 바셀 테크놀로지 캄파니 비이브이 | Heterocyclic matallocenes and polymerization catalysys |
| DE19757563A1 (en) | 1997-03-07 | 1999-07-08 | Targor Gmbh | Free-flowing catalyst system for olefin polymerisation |
| BR9808827B1 (en) | 1997-03-07 | 2009-12-01 | process for the preparation of indanones, and use of an indanone. | |
| EP0931099A1 (en) | 1997-03-07 | 1999-07-28 | Basell Polyolefine GmbH | Method for producing olefin polymers with a higher melting point |
| US6559252B1 (en) | 1997-10-29 | 2003-05-06 | Basell Technology Company Bv | Catalysts and processes for the polymerization of olefins |
| DE69903388T2 (en) | 1998-01-14 | 2003-06-18 | Basell Polyolefine Gmbh | METHOD FOR PRODUCING METALLOCENES |
| EP1214364B1 (en) | 1999-09-22 | 2003-07-16 | Basell Polyolefine GmbH | Catalyst system and process for the polymerization of olefins |
| DE19962910A1 (en) | 1999-12-23 | 2001-07-05 | Targor Gmbh | Chemical compound, process for its preparation and its use in catalyst systems for the production of polyolefins |
| DE19962814A1 (en) | 1999-12-23 | 2001-06-28 | Targor Gmbh | Catalyst system, useful for the production of polyolefins, comprises a metallocene, a Lewis base, a support and a compound containing at least one Group 3 element |
| EP1157027B1 (en) * | 1999-12-28 | 2007-09-19 | Basell Polyolefine GmbH | Heterocyclic metallocene compounds and use thereof in catalyst systems for producing olefin polymers |
| AU3538601A (en) | 1999-12-28 | 2001-07-09 | Basell Technology Company B.V. | Process for the preparation of ethylene polymers |
| WO2001062764A1 (en) | 2000-02-24 | 2001-08-30 | Basell Technology Company B.V. | Organometallic compound useful as cocatalyst for polymerizing olefins |
| JP2003528195A (en) | 2000-03-22 | 2003-09-24 | バセル テクノロジー カンパニー ビー．ブイ． | Thermoplastic composition of isotactic propylene polymer and soft propylene polymer having reduced isotacticity and method for producing the same |
| JP3986441B2 (en) | 2001-04-10 | 2007-10-03 | バセル ポリオレフィン ジーエムビーエイチ | Method for producing monohalide or dihalide metallocene compound |
| WO2002092564A2 (en) | 2001-05-15 | 2002-11-21 | Basell Polyolefine Gmbh | Synthesis of cyclopentadiene derivatives |
| WO2003042258A1 (en) * | 2001-11-12 | 2003-05-22 | Basell Polyolefine Gmbh | Process for polymerizing 1-butene and 1-butene polymers |
| JP2005517773A (en) * | 2002-02-25 | 2005-06-16 | バセル ポリオレフィン ジーエムビーエイチ | Copolymerization method of ethylene |
| AU2003273400A1 (en) * | 2002-10-10 | 2004-05-04 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
| EP1622948B1 (en) * | 2003-05-12 | 2019-11-20 | Basell Polyolefine GmbH | Process for polymerizing 1-butene |
-
2002
- 2002-06-20 DE DE60210089T patent/DE60210089T2/en not_active Expired - Fee Related
- 2002-06-20 EP EP02748826A patent/EP1397371B1/en not_active Expired - Lifetime
- 2002-06-20 WO PCT/EP2002/007093 patent/WO2003000706A1/en active IP Right Grant
- 2002-06-20 AT AT02748826T patent/ATE321061T1/en not_active IP Right Cessation
- 2002-06-20 JP JP2003507109A patent/JP4418228B2/en not_active Expired - Fee Related
- 2002-06-20 US US10/481,372 patent/US7241903B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP4418228B2 (en) | 2010-02-17 |
| WO2003000706A1 (en) | 2003-01-03 |
| DE60210089T2 (en) | 2006-10-19 |
| JP2004534829A (en) | 2004-11-18 |
| US20040171855A1 (en) | 2004-09-02 |
| EP1397371A1 (en) | 2004-03-17 |
| ATE321061T1 (en) | 2006-04-15 |
| US7241903B2 (en) | 2007-07-10 |
| EP1397371B1 (en) | 2006-03-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |