DE59904762D1 - ACCELERATOR FOR HARDENABLE SYSTEMS - Google Patents

ACCELERATOR FOR HARDENABLE SYSTEMS

Info

Publication number
DE59904762D1
DE59904762D1 DE59904762T DE59904762T DE59904762D1 DE 59904762 D1 DE59904762 D1 DE 59904762D1 DE 59904762 T DE59904762 T DE 59904762T DE 59904762 T DE59904762 T DE 59904762T DE 59904762 D1 DE59904762 D1 DE 59904762D1
Authority
DE
Germany
Prior art keywords
systems
compound
compounds
formulawherein
accelerators
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE59904762T
Other languages
German (de)
Inventor
Rolf Wiesendanger
Walter Fischer
Bryan Dobinson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Advanced Materials Switzerland GmbH
Original Assignee
Vantico GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vantico GmbH filed Critical Vantico GmbH
Application granted granted Critical
Publication of DE59904762D1 publication Critical patent/DE59904762D1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62Alcohols or phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/686Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/18Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1816Catalysts containing secondary or tertiary amines or salts thereof having carbocyclic groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225Polyamines
    • C08G18/3237Polyamines aromatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62Alcohols or phenols
    • C08G59/621Phenols
    • C08G59/623Aminophenols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Pyrrole Compounds (AREA)
  • Radiation-Therapy Devices (AREA)
  • Auxiliary Drives, Propulsion Controls, And Safety Devices (AREA)

Abstract

Compounds active as accelerators for curable epoxy and polyurethane systems, those compounds having been prepared by means of a transamination reaction by reacting (a) a substituted phenolic compound (Mannich base) having at least one substituent of formulawherein R1 and R2 are each independently of the other linear or branched C1-4alkyl and R3 is hydrogen, methyl, ethyl or phenyl, with (b) a compound of formulawherein R4 and R5 are each independently of the other C1-C6alkyl or together form a radical of formula -(CH2)5- or -(CH2)2-O-(CH2)2-, n is an integer from 2 to 5 and q is zero, 1, 2 or 3, and the compound obtained or the compounds present in the mixture obtained has/have on average, per molecule, at least one substituent of formulaand the use of those compounds as accelerators in curable systems, preferably in curable epoxy and polyurethane systems.
DE59904762T 1998-09-14 1999-09-04 ACCELERATOR FOR HARDENABLE SYSTEMS Expired - Lifetime DE59904762D1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH186698 1998-09-14
CH213698 1998-10-22
PCT/EP1999/006520 WO2000015687A1 (en) 1998-09-14 1999-09-04 Accelerators for hardenable systems

Publications (1)

Publication Number Publication Date
DE59904762D1 true DE59904762D1 (en) 2003-04-30

Family

ID=25688877

Family Applications (1)

Application Number Title Priority Date Filing Date
DE59904762T Expired - Lifetime DE59904762D1 (en) 1998-09-14 1999-09-04 ACCELERATOR FOR HARDENABLE SYSTEMS

Country Status (13)

Country Link
US (1) US6465601B1 (en)
EP (1) EP1114076B1 (en)
JP (1) JP4411571B2 (en)
KR (1) KR100584173B1 (en)
CN (1) CN1127531C (en)
AT (1) ATE235526T1 (en)
BR (1) BR9913665A (en)
DE (1) DE59904762D1 (en)
DK (1) DK1114076T3 (en)
ES (1) ES2193746T3 (en)
PT (1) PT1114076E (en)
TW (1) TW577900B (en)
WO (1) WO2000015687A1 (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1314716A1 (en) * 2001-11-23 2003-05-28 Sigma Coatings B.V. Amine phenolic compounds and their use as hardener and/or accelerators in epoxy coatings
EP1475412A1 (en) * 2003-05-05 2004-11-10 Sika Technology AG Epoxy compositions containing a Mannich base suitable for high temperature applications
EP1475411A1 (en) 2003-05-05 2004-11-10 Sika Technology AG Mannich bases and Preparation of Mannich bases
EP1674495A1 (en) 2004-12-22 2006-06-28 Huntsman Advanced Materials (Switzerland) GmbH Coating system
JP6130298B2 (en) 2010-11-10 2017-05-17 ダウ グローバル テクノロジーズ エルエルシー Amino group transfer of nitrogen-containing compounds to high molecular weight polyalkyleneamines.
CN103261174B (en) 2010-11-10 2016-04-20 陶氏环球技术有限责任公司 Nitrogenous compound turns amino and manufactures ring-type and ring-type/acyclic polyamine mixture
EP2452963A1 (en) 2010-11-11 2012-05-16 Sika Technology AG Condensation products of aminofunctional polymers
BR112014016218A8 (en) 2011-12-29 2017-07-04 Dow Global Technologies Llc reaction product, reaction composition and method of manufacturing a polyfunctional amine
BR112014015972B1 (en) 2011-12-29 2020-12-29 Dow Global Technologies Llc composition, polyether polyol amine, polyurethane foam, method for preparing a polyether polyol amine and method for preparing a polyurethane foam
US9644066B2 (en) 2011-12-29 2017-05-09 Dow Global Technologies Llc Cyclic amine compounds, compositions, and polyurethane foams made therefrom
EP2639252A1 (en) 2012-03-14 2013-09-18 Sika Technology AG Polymeric accelerator for two component epoxy resin
EP2900727B1 (en) * 2012-09-28 2018-09-26 Director General, Defence Research & Development Organisation An epoxy resin formulation for large and thick composite structures
CN103409037A (en) * 2013-08-06 2013-11-27 信和新材料股份有限公司 Solvent type double-composition epoxy coating material quick to solidify at low temperature and preparation method thereof
MY195495A (en) 2013-10-17 2023-01-26 Valspar Sourcing Inc Di(Amido(Alkyl)Phenol) Compounds and Polymers Formed Therefrom
EP3077444B1 (en) 2013-12-02 2018-04-25 Dow Global Technologies LLC Preparation of high molecular weight, branched, acyclic polyalkyleneamines and mixtures thereof
BR112016026342B1 (en) 2014-05-19 2022-03-03 Swimc Llc ARTICLE
CN104087057B (en) * 2014-07-04 2015-12-30 中国海洋石油总公司 A kind of low temperature curing agent composition for epoxy anticorrosion coating
EP3274329B1 (en) * 2015-03-23 2020-09-16 Sika Technology AG Cold curing epoxy resin primer or adhesive
US10556985B2 (en) 2015-11-17 2020-02-11 Evonik Operations Gmbh Nitrogen-containing heterocyclic epoxy curing agents, compositions and methods
US10465039B2 (en) 2015-11-17 2019-11-05 Evonik Degussa Gmbh Epoxy curing agents, compositions and uses thereof
EP3205682A1 (en) * 2016-02-15 2017-08-16 Sika Technology AG Hardener for low-emission epoxy resin compositions
US10669370B2 (en) * 2016-02-22 2020-06-02 Evonik Operations Gmbh Benzylated mannich base curing agents, compositions, and methods

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE146754C (en) *
EP0003479B1 (en) * 1978-02-11 1981-09-16 Schering Aktiengesellschaft Hardening agents and process for preparing epoxy resin polyadducts
RU2071494C1 (en) * 1994-02-01 1997-01-10 Татарский технологический научный центр Казанского государственного технологического университета при Кабинете Министров Республики Татарстан Composition for coating
EP0684268A1 (en) 1994-05-18 1995-11-29 Air Products And Chemicals, Inc. Low temperature curing agents for epoxy resins
RU2072380C1 (en) * 1994-11-09 1997-01-27 Татарский технологический научный центр КГТУ при кабинете Министров Республики Татарстан Adhesive composition (variants thereof)
RU2114145C1 (en) * 1996-08-02 1998-06-27 Татарский технологический научный центр КГТУ при кабинете Министров Республики Татарстан Adhesive composition (variants)
ATE192462T1 (en) 1996-10-04 2000-05-15 Shell Int Research STABLE, ONE-COMPONENT COATING COMPOSITIONS AND METHODS FOR COATING STABLE ONE-COMPONENT COATING COMPOSITIONS AND METHODS FOR COATING
RU2134282C1 (en) * 1998-02-12 1999-08-10 Казанский государственный технологический университет Sealing composition

Also Published As

Publication number Publication date
BR9913665A (en) 2001-06-05
CN1317027A (en) 2001-10-10
EP1114076A1 (en) 2001-07-11
JP4411571B2 (en) 2010-02-10
US6465601B1 (en) 2002-10-15
WO2000015687A1 (en) 2000-03-23
PT1114076E (en) 2003-07-31
DK1114076T3 (en) 2003-07-07
KR20010079678A (en) 2001-08-22
KR100584173B1 (en) 2006-05-26
TW577900B (en) 2004-03-01
EP1114076B1 (en) 2003-03-26
ES2193746T3 (en) 2003-11-01
CN1127531C (en) 2003-11-12
JP2002524629A (en) 2002-08-06
ATE235526T1 (en) 2003-04-15

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8328 Change in the person/name/address of the agent

Representative=s name: PFENNING MEINIG & PARTNER GBR, 80339 MUENCHEN

8328 Change in the person/name/address of the agent

Representative=s name: MAIWALD PATENTANWALTSGESELLSCHAFT MBH, 80335 MUENC