DE548983C - Process for the preparation of catalysts suitable for the reduction or hydrogenation of organic compounds - Google Patents

Process for the preparation of catalysts suitable for the reduction or hydrogenation of organic compounds

Info

Publication number
DE548983C
DE548983C DEI31017D DEI0031017D DE548983C DE 548983 C DE548983 C DE 548983C DE I31017 D DEI31017 D DE I31017D DE I0031017 D DEI0031017 D DE I0031017D DE 548983 C DE548983 C DE 548983C
Authority
DE
Germany
Prior art keywords
hydrogenation
reduction
organic compounds
catalysts suitable
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEI31017D
Other languages
German (de)
Inventor
Dr Hermann Behncke
Dr Karl Brodersen
Dr Karl Marx
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEI31017D priority Critical patent/DE548983C/en
Application granted granted Critical
Publication of DE548983C publication Critical patent/DE548983C/en
Expired legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Description

Verfahren zur Herstellung von für die Reduktion oder Hydrierung organischer Verbindungen " geeigneten Katalysatoren In dem Hauptpatent 546828 wird ein Verfahren zur Herstellung von für die Reduktion oder Hydrierung organischer Verbindungen geeigneten, aus unedlen Metallen, wie Nickel, Kobalt, Kupfer oder ihren Gemischen, bestehenden Katalysatoren beschrieben, welches dadurch gekennzeichnet ist, daß man diese Metalle aus den wäßrigen Lösungen ihrer Salze in Gegen-,vart von Ammoniak durch Wasserstoff oder wasserstoffhaltige Gase bei Gegenwart oder Abwesenheit eines Trägers zur Abscheidung bringt.Process for the production of catalysts suitable for the reduction or hydrogenation of organic compounds The main patent 546828 describes a process for the production of catalysts suitable for the reduction or hydrogenation of organic compounds and consisting of base metals such as nickel, cobalt, copper or their mixtures , which is characterized in that these metals are brought to the deposition from the aqueous solutions of their salts in the presence of ammonia by means of hydrogen or hydrogen-containing gases in the presence or absence of a carrier.

Wie nun in weiterer Bearbeitung des Verfahrens gefunden wurde, kann man bei der Abscheidung durch Wasserstoff mit dem gleichen Erfolge an Stelle von Ammoniak organische Basen oder auch Säureamide anwenden. Die so erhaltenen Katalysatoren zeichnen sich durch die gleiche hohe Wirksamkeit bei der katalytischen Hydrierung und Reduktion organischer Verbindungen aus wie die Produkte des Hauptpatents.As has now been found in further processing of the procedure, can one with the deposition by hydrogen with the same success in place of Use ammonia, organic bases or acid amides. The catalysts thus obtained are characterized by the same high efficiency in catalytic hydrogenation and reduction of organic compounds like the products of the main patent.

Von den bekannten Verfahren zur Herstellung kolloider unedler Metalle durch Reduktion neutraler Lösungen organischer Metallverbindungen, besonders des Nickels, wie Nickelcarbonyl, Nickelformiat und Nickelacetat, vorzugsweise in Glycerinlösung, unterscheidet sich das vorliegende Verfahren dadurch, daß anorganische Metallsalze in Gegenwart von organischen Basen oder Säureamiden zu nicht kolloidalen Metallen reduziert werden. ' Beispiel toi Teile Nickelsulfat werden in 40o Teilen Wasser gelöst und mit izo Teilen Pyridin versetzt. Zu dieser Mischung gibt man, i i o Teile Kieselgur und a Teile feinverteiltes Nickel. Hierauf wird im Rührautoklaven bei etwa ioo° C und 30 bis 4o Atm. durch Wasserstoff das Metall auf dem Träger abgeschieden. Der Katalysator wird von der Flüssigkeit befreit und kann in feuchtem Zustande oder nach dem Trocknen für katalytische Reduktionen oder Hydrierungen verwendet werden.The present process does not differ from the known processes for the production of colloidal base metals by reducing neutral solutions of organic metal compounds, especially nickel, such as nickel carbonyl, nickel formate and nickel acetate, preferably in glycerol solution, in that inorganic metal salts are not present in the presence of organic bases or acid amides colloidal metals are reduced. For example, one part of nickel sulfate is dissolved in 40o parts of water and izo parts of pyridine are added. To this mixture are added iio parts of kieselguhr and a part of finely divided nickel. This is done in a stirred autoclave at about 100 ° C and 30 to 40 atm. the metal is deposited on the carrier by hydrogen. The catalyst is freed from the liquid and can be used in the moist state or after drying for catalytic reductions or hydrogenations.

Claims (1)

PATENTANSPRÜCHE: i. Verfahren zur Herstellung - von für die Reduktion oder Hydrierung organischer Verbindungen geeigneten, aus unedlen Metallen, wie Nickel, Kobalt, Kupfer oder ihren Gemischen, bestehenden Katalysatoren, dadurch gekennzeichnet, da;ß man in Abänderung des Verfahrens des Patents 5468--8 die Metalle aus , den Lösungen ihrer Salze in Gegenwart von wasserlöslichen organischen Basen oder Säureamiden durch Behandlung mit Wasserstoff oder wasserstoffhaltigen Gasen unter Druck bei Gegenwart oder Abwesenheit eines Trägers zur Abscheidung bringt. a. Ausführungsform des Verfahrens nach Anspruch i, dadurch gekennzeichnet, daB man in Gegenwart katalytisch wirkender Metalle arbeitet.PATENT CLAIMS: i. Process for the production of catalysts suitable for the reduction or hydrogenation of organic compounds and consisting of base metals such as nickel, cobalt, copper or their mixtures, characterized in that the metals are modified in the process of patent 5468-8 from, the solutions of their salts in the presence of water-soluble organic bases or acid amides by treatment with hydrogen or hydrogen-containing gases under pressure in the presence or absence of a carrier to deposit. a. Embodiment of the process according to claim i, characterized in that one works in the presence of catalytically active metals.
DEI31017D 1927-04-29 1927-04-29 Process for the preparation of catalysts suitable for the reduction or hydrogenation of organic compounds Expired DE548983C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEI31017D DE548983C (en) 1927-04-29 1927-04-29 Process for the preparation of catalysts suitable for the reduction or hydrogenation of organic compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEI31017D DE548983C (en) 1927-04-29 1927-04-29 Process for the preparation of catalysts suitable for the reduction or hydrogenation of organic compounds

Publications (1)

Publication Number Publication Date
DE548983C true DE548983C (en) 1932-04-21

Family

ID=7187771

Family Applications (1)

Application Number Title Priority Date Filing Date
DEI31017D Expired DE548983C (en) 1927-04-29 1927-04-29 Process for the preparation of catalysts suitable for the reduction or hydrogenation of organic compounds

Country Status (1)

Country Link
DE (1) DE548983C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE740634C (en) * 1940-01-21 1943-10-25 Ig Farbenindustrie Ag Process for the production of masses which contain insoluble metal compounds, in particular oxides, or metals in or on carrier materials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE740634C (en) * 1940-01-21 1943-10-25 Ig Farbenindustrie Ag Process for the production of masses which contain insoluble metal compounds, in particular oxides, or metals in or on carrier materials

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