DE50211894D1 - DETERMINATION OF THE REACTION PROGRESS OF PROCESS POLYMERIZATION REACTIONS - Google Patents
DETERMINATION OF THE REACTION PROGRESS OF PROCESS POLYMERIZATION REACTIONSInfo
- Publication number
- DE50211894D1 DE50211894D1 DE50211894T DE50211894T DE50211894D1 DE 50211894 D1 DE50211894 D1 DE 50211894D1 DE 50211894 T DE50211894 T DE 50211894T DE 50211894 T DE50211894 T DE 50211894T DE 50211894 D1 DE50211894 D1 DE 50211894D1
- Authority
- DE
- Germany
- Prior art keywords
- reaction
- monomers
- polymers
- spectra
- determination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/65—Raman scattering
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/65—Raman scattering
- G01N2021/653—Coherent methods [CARS]
- G01N2021/656—Raman microprobe
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/24—Nuclear magnetic resonance, electron spin resonance or other spin effects or mass spectrometry
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
- Polymerization Catalysts (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Abstract
A method of using Raman Spectra for determining the progress of a graft polymerization reaction is disclosed. The method entails (a) measuring at the beginning of the reaction and at a plurality of time intervals in the course of the reaction, continuously and on-site, the Raman spectrum in the wave number range of 100 to 4000 cm<SUP>-1 </SUP>of one or more of the monomers and/or polymers entailed in the reaction and of at least one internal standard and (b) recording the spectra and (c) adding reaction partners necessary to the reaction continuously and/or discontinuously and (d) calculating the change in concentration of the monomers and polymers by comparing the spectra of the monomers or polymers with the internal standard.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10153536 | 2001-10-30 | ||
DE10204392A DE10204392A1 (en) | 2001-10-30 | 2002-02-04 | Determination of the progress of graft polymerization reactions |
PCT/EP2002/012060 WO2003038415A1 (en) | 2001-10-30 | 2002-10-24 | Determination of the reaction advancement of graft polymerization reactions |
Publications (1)
Publication Number | Publication Date |
---|---|
DE50211894D1 true DE50211894D1 (en) | 2008-04-24 |
Family
ID=26010486
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE50211894T Expired - Fee Related DE50211894D1 (en) | 2001-10-30 | 2002-10-24 | DETERMINATION OF THE REACTION PROGRESS OF PROCESS POLYMERIZATION REACTIONS |
Country Status (7)
Country | Link |
---|---|
US (1) | US7122379B2 (en) |
EP (1) | EP1442284B1 (en) |
JP (1) | JP2005507456A (en) |
CN (1) | CN1578906A (en) |
AT (1) | ATE389174T1 (en) |
DE (1) | DE50211894D1 (en) |
WO (1) | WO2003038415A1 (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1442283A1 (en) * | 2001-10-30 | 2004-08-04 | Bayer Aktiengesellschaft | Method for producing grafted polymerization products |
DE10304817A1 (en) * | 2003-02-06 | 2004-09-02 | Bayer Ag | Process for the improved production of graft polymers |
WO2006106934A1 (en) * | 2005-03-31 | 2006-10-12 | Hitachi Chemical Co., Ltd. | Method of estimating dissolution rate of polyimide, process for producing polyimide and polyimide obtained using the methods |
JP2010513669A (en) * | 2006-12-19 | 2010-04-30 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Semi-batch copolymerization process for homogeneous composition copolymers |
US8189189B1 (en) * | 2008-10-08 | 2012-05-29 | Herendeen Robert O | LED sensor for process control |
EP2545107A1 (en) | 2010-03-12 | 2013-01-16 | Basf Se | Method for producing expandable styrene polymers |
US8455559B2 (en) | 2010-03-12 | 2013-06-04 | Basf Se | Preparing expandable styrene polymers |
EP2567219B1 (en) * | 2010-05-07 | 2019-09-18 | MannKind Corporation | Method and apparatus for determining weight percent of microparticles of diketopiperazine in suspension using raman spectroscopy |
ES2699639T3 (en) * | 2010-12-21 | 2019-02-12 | Dow Global Technologies Llc | Polymerization procedure and Raman analysis for olefin-based polymers |
US10197500B2 (en) | 2015-01-22 | 2019-02-05 | Advanced Polymer Monitoring Technologies, Inc. | Systems and methods for predicting and controlling the properties of a chemical species during a time-dependent process |
US10436758B2 (en) * | 2017-06-16 | 2019-10-08 | Xerox Corporation | Method and apparatus for determining an ultraviolet (UV) cure level |
WO2020109601A1 (en) * | 2018-11-29 | 2020-06-04 | Basf Se | Prediction of physical properties of superabsorbent polymers |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4125534A (en) * | 1977-02-25 | 1978-11-14 | Allied Chemical Corporation | Carbazolyl diacetylenic compounds |
US4661383A (en) * | 1986-05-04 | 1987-04-28 | Allied Corporation | Method for grafting polymers to polytetrafluoroethylene, and grafted composites thereof |
US5072576A (en) * | 1990-09-26 | 1991-12-17 | Tucker Housewares | Newspaper bundler |
CA2263850C (en) * | 1996-08-22 | 2003-04-29 | Eastman Chemical Company | On-line quantitative analysis of chemical compositions by raman spectrometry |
US6072576A (en) * | 1996-12-31 | 2000-06-06 | Exxon Chemical Patents Inc. | On-line control of a chemical process plant |
EP1214362A1 (en) * | 1999-07-30 | 2002-06-19 | ExxonMobil Chemical Patents Inc. | Raman analysis system for olefin polymerization control |
-
2002
- 2002-10-24 EP EP02802305A patent/EP1442284B1/en not_active Expired - Lifetime
- 2002-10-24 DE DE50211894T patent/DE50211894D1/en not_active Expired - Fee Related
- 2002-10-24 AT AT02802305T patent/ATE389174T1/en not_active IP Right Cessation
- 2002-10-24 WO PCT/EP2002/012060 patent/WO2003038415A1/en active IP Right Grant
- 2002-10-24 JP JP2003540634A patent/JP2005507456A/en not_active Withdrawn
- 2002-10-24 CN CN02821753.5A patent/CN1578906A/en active Pending
- 2002-10-28 US US10/281,597 patent/US7122379B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1578906A (en) | 2005-02-09 |
US20030119199A1 (en) | 2003-06-26 |
ATE389174T1 (en) | 2008-03-15 |
EP1442284A1 (en) | 2004-08-04 |
JP2005507456A (en) | 2005-03-17 |
EP1442284B1 (en) | 2008-03-12 |
WO2003038415A1 (en) | 2003-05-08 |
US7122379B2 (en) | 2006-10-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8327 | Change in the person/name/address of the patent owner |
Owner name: INEOS ABS (JERSEY) LTD., ST. HELIER, JERSEY, GB |
|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |