DE502006004629D1 - Organophosphorus-containing prepolymers and uses therefor - Google Patents

Organophosphorus-containing prepolymers and uses therefor

Info

Publication number
DE502006004629D1
DE502006004629D1 DE502006004629T DE502006004629T DE502006004629D1 DE 502006004629 D1 DE502006004629 D1 DE 502006004629D1 DE 502006004629 T DE502006004629 T DE 502006004629T DE 502006004629 T DE502006004629 T DE 502006004629T DE 502006004629 D1 DE502006004629 D1 DE 502006004629D1
Authority
DE
Germany
Prior art keywords
molecular weight
resin
prepolymer
average molecular
organophosphorus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
DE502006004629T
Other languages
German (de)
Inventor
Monika Bauer
Berthold Just
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Schill and Seilacher Struktol AG
Original Assignee
Schill and Seilacher Struktol AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Schill and Seilacher Struktol AG filed Critical Schill and Seilacher Struktol AG
Publication of DE502006004629D1 publication Critical patent/DE502006004629D1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1488—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014—Nitrogen containing compounds
    • C08G59/4021—Ureas; Thioureas; Guanidines; Dicyandiamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/692—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
    • C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
    • C08G8/10—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Epoxy Resins (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

A prepolymer having an average molecular weight Mn 200 - 10,000 and an average molecular weight Mw 400 - 30,000 obtained by reacting at least one phosphinic acid derivative with at least one resin selected from epoxy resin, cyanate resin, an unsaturated polyester, vinyl ester, phenol resin, or a bismaleimide. The molecular weight is determined by GPC. A prepolymer having an average molecular weight Mn 200 - 10,000 and an average molecular weight Mw 400 - 30,000 obtained by reacting at least one phosphinic acid derivative of formula (R 1O)(R 2)P(O)-R 3 with at least one resin selected from epoxy resin, cyanate resin, an unsaturated polyester, vinyl ester, phenol resin, or a bismaleimide. The molecular weight is determined by GPC. R 1 and R 21-20C (aryl)alkyl, 1-20C (alkyl)aryl or 1-20C alkylarylalkyl (all optionally substituted);and R 3H or R 1. Independent claims are included for the following: (1) use of the prepolymer for producing a flame resistance polymer; and a flame resistance polymer comprising the prepolymer.
DE502006004629T 2005-04-05 2006-04-05 Organophosphorus-containing prepolymers and uses therefor Active DE502006004629D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102005015605A DE102005015605B4 (en) 2005-04-05 2005-04-05 Organophosphorus-containing prepolymers and uses therefor

Publications (1)

Publication Number Publication Date
DE502006004629D1 true DE502006004629D1 (en) 2009-10-08

Family

ID=36648768

Family Applications (2)

Application Number Title Priority Date Filing Date
DE102005015605A Expired - Fee Related DE102005015605B4 (en) 2005-04-05 2005-04-05 Organophosphorus-containing prepolymers and uses therefor
DE502006004629T Active DE502006004629D1 (en) 2005-04-05 2006-04-05 Organophosphorus-containing prepolymers and uses therefor

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE102005015605A Expired - Fee Related DE102005015605B4 (en) 2005-04-05 2005-04-05 Organophosphorus-containing prepolymers and uses therefor

Country Status (4)

Country Link
US (1) US20060223921A1 (en)
EP (1) EP1710264B1 (en)
AT (1) ATE440880T1 (en)
DE (2) DE102005015605B4 (en)

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BRPI0720577B1 (en) * 2006-12-22 2018-09-04 Mankiewicz Gebr & Co Gmbh & Co Kg polymeric film for surface coating of fiber / plastic composite materials
JP5024205B2 (en) * 2007-07-12 2012-09-12 三菱瓦斯化学株式会社 Prepreg and laminate
DE602007008593D1 (en) * 2007-12-12 2010-09-30 Atotech Deutschland Gmbh Solid powder formulations for the preparation of resin-coated films and their use in the manufacture of printed circuit boards
US20110003946A1 (en) * 2008-01-18 2011-01-06 Klaus-Volker Schuett Curable reaction resin system
DE102008009298B4 (en) * 2008-02-15 2011-04-14 Schill + Seilacher "Struktol" Aktiengesellschaft Curable epoxy resin formulations with polyester flame retardant
DE102008012806A1 (en) * 2008-03-06 2009-09-10 Schill + Seilacher Ag Halogen-free flame retardants
WO2010069835A1 (en) 2008-12-17 2010-06-24 Basf Se Layered silicate flame retardant compositions
CN102272216A (en) * 2008-12-29 2011-12-07 巴斯夫欧洲公司 Dopo-flame retardant in epoxy resins
DE102009037631A1 (en) * 2009-08-14 2011-02-17 Schill + Seilacher "Struktol" Gmbh Phosphorus-containing flame retardant
JP5544184B2 (en) * 2010-02-08 2014-07-09 新日鉄住金化学株式会社 Method for producing phosphorus-containing epoxy resin, epoxy resin composition and cured product thereof
CN102757547B (en) * 2011-04-27 2016-07-06 新日铁住金化学株式会社 The phosphorous epoxy resin with nitrogen
CN102875842A (en) * 2012-09-28 2013-01-16 沈阳化工大学 Phosphorus-nitrogen intumescent flame retardant and preparation method thereof
DE102013101487A1 (en) 2013-02-14 2014-08-14 Chemische Fabrik Budenheim Kg Duromer, method of manufacture, use and compositions
DE102014004454A1 (en) 2013-03-28 2014-10-02 Deutsche Institute Für Textil- Und Faserforschung Denkendorf Flameproof polyamide, a process for its preparation and its use
TR201910821T4 (en) 2013-07-16 2019-08-21 Deutsche Inst Fuer Textil Und Faserforschung Denkendorf Method for the production of flame retardant copolyamides, polyamide yarns obtained accordingly and their use.
WO2015109135A2 (en) * 2014-01-17 2015-07-23 Qed Labs Llc Articles with improved flame retardancy and/or melt dripping properties
CN103833958B (en) * 2014-03-11 2016-08-17 固德电材系统（苏州）股份有限公司 The preparation method of environment-friendly type one-component solvent-free epoxy impregnation resin
EP3078723B1 (en) 2015-04-09 2018-10-31 Evonik Degussa GmbH Adducts from isocyanate oalkyltri methoxysilanes and flame retardants that react with them
EP3540000A1 (en) 2018-03-16 2019-09-18 Stutz, Felix Benjamin Flame retardant polyamide 6 master batch and fibers made thereof
CN110204797A (en) * 2019-05-07 2019-09-06 南漳富元鼎航空器材配件有限公司 A kind of rubber spring sizing material and preparation method thereof that high temperature resistant is ageing-resistant
US11718580B2 (en) 2019-05-08 2023-08-08 Meta Platforms Technologies, Llc Fluorene derivatized monomers and polymers for volume Bragg gratings
US11780819B2 (en) 2019-11-27 2023-10-10 Meta Platforms Technologies, Llc Aromatic substituted alkane-core monomers and polymers thereof for volume Bragg gratings
CN111848963B (en) * 2020-07-14 2022-05-27 北京化工大学 Preparation method of flame-retardant resin capable of being repeatedly processed and thermally cured at high temperature
US11879024B1 (en) 2020-07-14 2024-01-23 Meta Platforms Technologies, Llc Soft mold formulations for surface relief grating fabrication with imprinting lithography
CN112480478B (en) * 2020-10-28 2021-12-31 厦门大学 Preparation method and application of silver-loaded polymer microspheres
CN112961314B (en) * 2021-03-15 2021-12-31 四川大学 Preparation method of flame-retardant water-based polyurethane for impregnation of microfiber base cloth
CN115894860B (en) * 2022-12-16 2023-08-18 江南大学 Hyperbranched flame-retardant epoxy resin and epoxy resin composition prepared from same
CN116218195B (en) * 2023-03-20 2023-07-25 固达电线电缆(集团)有限公司 High-flame-retardance modified polyurethane cable material and preparation method thereof

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Also Published As

Publication number Publication date
US20060223921A1 (en) 2006-10-05
EP1710264B1 (en) 2009-08-26
DE102005015605A1 (en) 2006-10-12
DE102005015605B4 (en) 2008-04-17
EP1710264A2 (en) 2006-10-11
EP1710264A3 (en) 2007-12-05
ATE440880T1 (en) 2009-09-15

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