DE461389C - Method of preserving wood - Google Patents

Method of preserving wood

Info

Publication number
DE461389C
DE461389C DEM97397D DEM0097397D DE461389C DE 461389 C DE461389 C DE 461389C DE M97397 D DEM97397 D DE M97397D DE M0097397 D DEM0097397 D DE M0097397D DE 461389 C DE461389 C DE 461389C
Authority
DE
Germany
Prior art keywords
wood
compounds
preserving
preserving wood
aromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEM97397D
Other languages
German (de)
Inventor
Basilius Malenkovic
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Application granted granted Critical
Publication of DE461389C publication Critical patent/DE461389C/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • B27K3/38Aromatic compounds
    • B27K3/42Aromatic compounds nitrated, or nitrated and halogenated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/0278Processes; Apparatus involving an additional treatment during or after impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • B27K3/36Aliphatic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • B27K3/50Mixtures of different organic impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/04Combined bleaching or impregnating and drying of wood

Description

Patentiert im Deutschen Reiche vom 12. Dezember 1926 ab. Es hat sich gezeigt, daß die Molekülverbindungen, die man aus zahlreichen Nitroderivaten der aromatischen Reihe mit aromatischen Aminen erhalten kann, eine außerordentlich starke Giftwirkung gegenüber holzzerstörenden Pilzen aufweisen, welche die Summenwirkung ihrer Einzelbestandteile bei weitem übertrifft. Besonders zeichnen sich in dieser Beziehung die in der Literatur noch nicht beschriebenen Molekülverbindungen aus i-2-4-Dinitroclilorbenzol mit aromatischen Aminen aus. Wenn man die: genannten Verbindungen hölzernen Gegenständen einverleibt, werden diese gegen Fäulniserreger geschützt; infolge der hohen Toxität der Verbindungen genügen schon geringe Zufuhren, um diese Wirkung zu erreichen, und andererseits ist im Zusammenhang mit der geringen Wasserlöslichkeit und der Schwerflüchtigkeit der neuen konservierenden Stoffe der Schutz des Holzes ein sehr lang anhaltender.Patented in the German Empire on December 12, 1926. It has showed that the molecular compounds obtained from numerous nitro derivatives of the aromatic series can be obtained with aromatic amines, an extraordinarily strong one Have poisonous effects on wood-destroying fungi, which have the cumulative effect of its individual components by far. Particularly stand out in this Relationship from the molecular compounds not yet described in the literature i-2-4-Dinitroclilorbenzol with aromatic amines from. If you have the: mentioned connections incorporated into wooden objects, these are protected against putrefactive agents; As a result of the high toxicity of the compounds, even small intakes are sufficient for them To achieve effect, and on the other hand is in connection with the low water solubility and the low volatility of the new preservatives, the protection of the wood a very long lasting one.

In den meisten Fällen ist es notwendig, die Konservierungsmittel in einem geeigneten Lösungsmittels in das Holz einzuführen; als solches verwendet man mit Vorteil ein schwerflüchtiges 01, das entweder an sich keine fungiziden Eigenschaften hat, wie paraffinhaltiges Erdöl, oder selbst ebenfalls hoch konservierend wirkt, wie Steinkohlenteeröl und andere phenolhaltige Öle. Im letzteren Fall wird die Wirkung des Öles durch den Zusatz der neuen Konservierungsmittel gesteigert, und man ist in der Lage, mit einer geringeren Menge (11 als bisher üblich einen gleich guten Schutz des Holzes zu bewirken.In most cases it is necessary to introduce the preservatives into the wood in a suitable solvent; as such is advantageously used a low volatility 01 that either no fungicidal properties per se, like paraffinic oil, or even also high acts as a preservative, such as coal tar and other phenol-containing oils. In the latter case, the effect of the oil is increased by the addition of the new preservative, and it is possible to protect the wood with a smaller amount (11 than has been the case up to now).

Als Beispiele seien folgende Doppelverbindungen angeführt, zugleich mit den Konzentrationen, in denen diese auf einem künstlichen -Nährboden das Wachstum des Hausschwammes Merulius lacrvtnans verhindern: i-2-d.-Ditiitrochlor benzol-a-N aphthvlamin o,oo75 Prozent, i-2-d.-Ditiitrochlor benzol-ß-Naphthvlamin o,ood Prozent, i-2-4-Dinitrochlorbenzol-Benzidin o,oo8 Prozent.The following double compounds are given as examples, at the same time with the concentrations in which these grow on an artificial nutrient medium of the dry rot Merulius lacrvtnans: i-2-d.-ditiitrochlor benzene-a-N aphthvlamin o, oo75 percent, i-2-d.-ditiitrochlor benzene-ß-naphthvlamin o, ood percent, i-2-4-Dinitrochlorobenzene-Benzidine 0.08 percent.

Claims (1)

PATENTANSPRÜCHE: i. Verfahren zum Konservieren von Holz, darin bestehend, daß man Doppelverbindungen aus aromatischen Nitrochlorverbindungen, insbesondere aus i-2- 4-Dinitrochlorbenzol und aromatischen Aminen, gegebenenfalls in Gegenwart anderer holzkonservierender Stoffe, in das Holz einführt. a. Ausführungsform' des Verfahrens nach Anspruch i, darin bestehend, daß man Doppelverbindungen der in Anspruch i genannten Art in hochsiedenden Ölen auflöst und das zu konservierende Holz mit dieser Lösung trocknet.PATENT CLAIMS: i. Process for preserving wood, consisting in that one double compounds from aromatic nitrochloride compounds, in particular from i-2- 4-dinitrochlorobenzene and aromatic amines, optionally in the presence of other wood-preserving substances into the wood. a. Embodiment ' of the method according to claim i, consisting in that double compounds of the in claim i mentioned type dissolves in high-boiling oils and the to be preserved Wood with this solution dries.
DEM97397D 1926-12-12 Method of preserving wood Expired DE461389C (en)

Publications (1)

Publication Number Publication Date
DE461389C true DE461389C (en) 1928-06-18

Family

ID=586106

Family Applications (1)

Application Number Title Priority Date Filing Date
DEM97397D Expired DE461389C (en) 1926-12-12 Method of preserving wood

Country Status (1)

Country Link
DE (1) DE461389C (en)

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