DE4318902C2 - Water-soluble, water-softening agent - Google Patents

Water-soluble, water-softening agent

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Publication number
DE4318902C2
DE4318902C2 DE4318902A DE4318902A DE4318902C2 DE 4318902 C2 DE4318902 C2 DE 4318902C2 DE 4318902 A DE4318902 A DE 4318902A DE 4318902 A DE4318902 A DE 4318902A DE 4318902 C2 DE4318902 C2 DE 4318902C2
Authority
DE
Germany
Prior art keywords
water
weight
softening agent
agent according
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE4318902A
Other languages
German (de)
Other versions
DE4318902A1 (en
Inventor
Guido Dr Waeschenbach
Manfred Mueller
Harald Ahnsorge
Wolfgang Dr Ussat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reckitt Benckiser NV
Original Assignee
Joh A Benckiser 67059 Ludwigshafen De GmbH
Joh A Benckiser GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6489821&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE4318902(C2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Joh A Benckiser 67059 Ludwigshafen De GmbH, Joh A Benckiser GmbH filed Critical Joh A Benckiser 67059 Ludwigshafen De GmbH
Priority to DE4318902A priority Critical patent/DE4318902C2/en
Priority to EP94108688A priority patent/EP0628627B1/en
Priority to ES94108688T priority patent/ES2098820T3/en
Priority to AT94108688T priority patent/ATE150081T1/en
Priority to DK94108688.6T priority patent/DK0628627T3/en
Priority to DE59402005T priority patent/DE59402005D1/en
Priority to SI9430037T priority patent/SI0628627T1/en
Publication of DE4318902A1 publication Critical patent/DE4318902A1/en
Publication of DE4318902C2 publication Critical patent/DE4318902C2/en
Application granted granted Critical
Priority to GR970400868T priority patent/GR3023207T3/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3719—Polyamides or polyimides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Developing Agents For Electrophotography (AREA)

Abstract

The invention relates to a water-soluble, water-softening builder in the form of a tablet consisting of A) 60-98% by weight of a combination of a) citrate and/or citric acid and b) a polymer which acts as softening agent in an a:b ratio of 70:30 to 50:50, preferably 65:35 to 55:45, by weight B) 0.5-6% by weight of polyethylene glycol and C) 0-38% by weight of other auxiliaries.

Description

Gegenstand der Erfindung ist ein wasserlösliches, vorwiegend organisches, wasserenthärtendes Mittel mit Buildereigenschaften.The invention relates to a water-soluble, predominantly organic, water-softening agent with builder properties.

Die DE 36 14 779 A1 offenbart ein granulares, phosphatfreies Wasserenthärtungsmittel zum Enthärten von Waschlaugen als auch als Zusatz zu Waschmitteln, welches aus 50-60 Gew.-% feinkristallinem Zeolith, 3-5 Gew.-% Natriumsalz eines Polyacrylsäure-, Polymethacrylsäure- oder Acrylsäure- Maleinsäure-Copolymeren, 4-15 Gew.-% Natriumcitrat, 4-12 Gew.-% Natriumcarbonat und gegebenenfalls bis zu 2 Gew.-% Natrium- Carboxymethylcellulose besteht.DE 36 14 779 A1 discloses a granular, phosphate-free Water softening agent for softening wash liquors as also as an additive to detergents, which consists of 50-60% by weight fine crystalline zeolite, 3-5 wt .-% sodium salt of a Polyacrylic acid, polymethacrylic acid or acrylic acid Maleic acid copolymers, 4-15% by weight of sodium citrate, 4-12% by weight Sodium carbonate and optionally up to 2% by weight of sodium Carboxymethylcellulose exists.

In der DE 40 22 605 A1 wird ein Feinwaschmittel offenbart, welches als einzigen Builder eine Kombination aus einem wasserlöslichen Citrat mit einem Polyacrylat oder einem Polymer aus Acrylsäure und Maleinsäure enthält.DE 40 22 605 A1 discloses a mild detergent, which as a single builder a combination of a water-soluble citrate with a polyacrylate or a Polymer of acrylic acid and maleic acid contains.

Die DE 36 03 471 A1 offenbart ein phosphorarmes, bzw. phosphorfreies Wasch- und/oder Reinigungsmittel, welches ein Tensid, einen anorganischen und/oder organischen Builder und mindestens ein kolloidales Schichtsilikat enthält, sowie zusätzlich mindestens ein wasserlösliches Kalzium- und/oder Magnesiumsalz und Polyacrylsäure.DE 36 03 471 A1 discloses a low-phosphorus, or phosphorus-free washing and / or cleaning agent, which a  Surfactant, an inorganic and / or organic builder and contains at least one colloidal sheet silicate, and additionally at least one water-soluble calcium and / or Magnesium salt and polyacrylic acid.

Die DE 39 31 871 A1 beschreibt ein granulares, phosphatfreies Wasserenthärtungsmittel enthaltend 50-70 Gew.-% feinkristallinen Zeolith, 2-10 Gew.-% eines Schichtsilikates, 5-15 Gew.-% des Natriumsalzes einer (Co-)polymeren Carbonsäure und 1-10 Gew.-% Natriumsulfat.DE 39 31 871 A1 describes a granular, phosphate-free Water softening agent containing 50-70% by weight fine crystalline zeolite, 2-10% by weight of a layered silicate, 5-15% by weight of the sodium salt of a (co) polymeric carboxylic acid and 1-10% by weight of sodium sulfate.

Die DE 39 43 019 A1 offenbart ein granulares Waschmitteladditiv enthaltend 20-45 Gew.-% eines Schichtsilikates, 15-50 Gew.-% eines feinkristallinen, synthetischen Zeoliths, 0-15 Gew.-% eines Sulfats, Carbonats oder Phosphats, 0-8 Gew.-% des Natriumsalzes einer homopolymeren, bzw. copolymeren (Meth-)acrylsäure, 0-2 Gew.-% an Celluloseether, 0-20 Gew.-% an nichtionischen Tensiden aus der Klasse der Polyglykolether. Eine ähnliche sprühgetrocknete Zusammensetzung wird in der DE 40 09 618 A1 offenbart.DE 39 43 019 A1 discloses a granular detergent additive containing 20-45% by weight of a layered silicate, 15-50% by weight a fine crystalline synthetic zeolite, 0-15% by weight of a sulfate, carbonate or phosphate, 0-8% by weight of Sodium salt of a homopolymeric or copolymeric (Meth) acrylic acid, 0-2 wt .-% of cellulose ether, 0-20 wt .-% of nonionic surfactants from the class of polyglycol ethers. A similar spray-dried composition is described in DE 40 09 618 A1 discloses.

Die FR-PS 1 599 547 offenbart eine Zusammensetzung zur Inhibierung der Kesselsteinbildung durch Erdalkalisalze in wäßrigen Systemen, enthaltend eine Carbonsäure wie beispielsweise Zitronensäure und ein wasserlösliches organisches Polymer wie beispielsweise ein Acrylsäurepolymer oder -copolymer.FR-PS 1 599 547 discloses a composition for inhibition scale formation by alkaline earth salts in aqueous systems, containing a carboxylic acid such as citric acid and a water-soluble organic polymer such as a Acrylic acid polymer or copolymer.

Die CH-A5 577 937 offenbart ein Mittel in Tablettenform zur Verhinderung von Kalkansatz, enthaltend entweder Zitronensäure und Zusätze von Acetylsalizylsäure und/oder Borsäure und/oder Nikotinsäure oder Nikotinsäure.CH-A5 577 937 discloses an agent in tablet form for Prevention of Kalkansatz, containing either citric acid and Additions of acetylsalicylic acid and / or boric acid and / or Nicotinic acid or nicotinic acid.

Die WO 91/17238 offenbart ein Mittel mit retardierter Auflösung zur Verhinderung des Wasserstein-Aufbaus in Wasser- und Abwassersystemen, welches sauer ist und in einem sauren System eingesetzt werden muß.WO 91/17238 discloses a sustained release agent for the prevention of waterstone buildup in water and Sewage systems, which are acidic and in an acidic system must be used.

Es ist den Fachmann bekannt und durch den zitierten Stand der Technik dokumentiert, daß wasserenthärtende waschmitteladditive bislang in möglichst kleinteiliger, vorzugsweise Pulverform, allenfalls in Granulatform angeboten werden, da die Meinung bestand, daß nur dadurch die erforderliche schnelle Löslichkeit eines Wasserenthärters gewährleistet werden kann.It is known in the art and by the cited state of Technique documents that water-softening detergent additives so far in the smallest possible particle size, preferably powdered form,  possibly offered in granular form, as the opinion was that only by the required rapid solubility a water softener can be guaranteed.

Die Anmelderin hat sich zur Aufgabe gesetzt, einen Wasserenthärter mit Buildereigenschaften in leicht handhabbarer, gut dosierbarer Form zur Verfügung zu stellen.The Applicant has set itself the task of a water softener with builder properties in easy to handle, well dosed To provide form.

Erfindungsgemäß wird dies durch ein wasserlösliches, wasserenthärtendes Mittel mit Buildereigenschaften zur Verwendung in einer Waschlauge in Form einer schnell sich auf lösenden Tablette erreicht, wobei die Tablette eine bestimmte Zusammensetzung aufweist, die einerseits eine gute Handhabbarkeit der Tablette, andererseits eine schnelle Auflösung der Tablette in der Waschlauge gewährleistet. According to the invention, this is achieved by a water-soluble, water softening agent with builder properties for use in a wash liquor in the form of a rapidly dissolving one Tablet is reached, the tablet being a specific Composition, on the one hand good handling the tablet, on the other hand, a rapid dissolution of the tablet in the wash liquor ensured.  

Das erfindungsgemäße wasserlösliche, wasserenthärtende Mittel in Form einer Tablette besteht ausThe water-soluble, water-softening agent according to the invention in the form of a tablet consists of

  • A) 60-98 Gew.-% einer Kombination ausA) 60-98 wt .-% of a combination of
  • a) Citrat und/oder Citronensäure unda) citrate and / or citric acid and
  • b) einem als Enthärter wirksamen Polymerb) a polymer which acts as a softener

in einem Gewichtsverhältnis von a:b von 70 : 30 bis 50 : 50, vorzugsweise 65 : 35 bis 55 : 45,in a weight ratio of a: b of 70:30 to 50:50, preferably 65:35 to 55:45,

  • B) 0,5-6 Gew.-% PolyethylenglykolB) 0.5-6 wt .-% polyethylene glycol
  • C) 0-38 Gew.-% weiterer Hilfsstoffe.C) 0-38 wt .-% of other auxiliaries.

Die erfindungsgemäß in Kombination mit Citrat und/oder Citronensäure einzusetzenden, als Enthärter wirksamen Polymeren sind bekannte Substanzen. Hierfür eignen sich Maleinsäure/Acrylsäure-Copolymerisate und vorzugsweise biologisch abbaubare Polymere, insbesondere solche auf Peptid-Basis. Solche Polymere auf Peptid-Basis sind beispielsweise die Cygnus-Produkte der Cygnus Corporation. Als Builder geeignete Serin-N-N-Diessigsäurederivate werden in der EP 287 885 beschrieben.The invention in combination with citrate and / or Citric acid to be used, effective as a softener Polymers are known substances. Suitable for this purpose Maleic acid / acrylic acid copolymers and preferably biodegradable polymers, especially those on Peptide-based. Such peptide-based polymers are For example, the Cygnus products of Cygnus Corporation. Suitable builders are serine N-N-diacetic acid derivatives in EP 287 885.

Als Builder geeignete Maleinsäure/Acrylsäure-Copolymerisate sind unter verschiedenen Marken im Handel, beispielsweise ein Maleinsäure/Acrylsäure-Copolymerisat, Natriumsalz.As builder suitable maleic acid / acrylic acid copolymers are under different brands in the trade, for example, a maleic acid / acrylic acid copolymer, Sodium salt.

Ein wesentlicher Bestandteil der erfindungsgemäßen Tabletten stellt das Polyethylenglykol dar, welches in einer Menge von 0,5-6 Gew.-%, vorzugsweise 1-3 Gew.-%, anwesend sein sollte. Als geeignete Polyethylenglykole sind die Polyethylenglykole (1000-6000) zu nennen, insbesondere Polyethylenglykol (4000-6000). Diese Polyethylenglykole wirken als Tablettierungshilfsmittel. Daß Polyethylenglykol als Tablettierungshilfsmittel brauchbar ist, war bekannt. Jedoch ergab sich überraschenderweise, daß, während bei anderen Tablettierungshilfsmitteln Auflösungsschwierigkeiten sich ergaben, die genannten Polyethylenglykole für den erfindungsgemäßen Zweck vorzüglich geeignet sind.An essential part of the invention Tablets represents the polyethylene glycol, which in in an amount of 0.5-6% by weight, preferably 1-3% by weight should be. Suitable polyethylene glycols are the Polyethylene glycols (1000-6000), in particular Polyethylene glycol (4000-6000). These polyethylene glycols act as tableting aids. That polyethylene glycol  was useful as a tabletting aid was known. However, it has surprisingly been found that while other tabletting aids dissolution difficulties showed, the said polyethylene glycols for the Purpose of the invention are excellent.

Ein Polyethylenglykol mit niederem Ethoxylierungsgrad, beispielsweise Polyethylenglykol 200, eignet sich nicht als Tablettierungsmittel, wohl aber als Staubbindemittel und kann als solches in der erfindungsgemäßen Tablette ebenfalls in geringer Menge, beispielsweise in einer Menge von 0,5-5 Gew.-%, anwesend sein.A polyethylene glycol with a low degree of ethoxylation, for example, polyethylene glycol 200, is not suitable as Tabletting agent, but probably as a dust binder and can as such in the tablet according to the invention also in small amount, for example in an amount of 0.5-5 Wt .-%, to be present.

Die erfindungsgemäße Tablette sollte ein Sprengmittel enthalten. Als solches eignet sich ein unlösliches Polyvinylpyrrolidon, welches in einer Menge von 1-20 Gew.-%, vorzugsweise 7-12 Gew.-%, vorliegen kann.The tablet of the invention should be a disintegrant contain. As such, an insoluble is suitable Polyvinylpyrrolidone which is present in an amount of 1-20% by weight, preferably 7-12 wt .-%, may be present.

Es wird jedoch besonders bevorzugt in der Builderkombination (A) Citronensäure und/oder teilneutralisiertes, sauer wirkendes Polymer einzusetzen und als weiteren Hilfsstoff Carbonat und/oder Bicarbonat, beispielsweise Natriumcarbonat, Natriumhydrogencarbonat und/oder Kaliumcarbonat, welches in Kombination mit der vorerwähnten sauren Komponente als Sprengmittel dient. Das Carbonat/Bicarbonat kann in Mengen von 5-30 Gew.-% eingesetzt werden.However, it is particularly preferred in the builder combination (A) citric acid and / or partially neutralized, acidic to use acting polymer and as another excipient Carbonate and / or bicarbonate, for example sodium carbonate, Sodium bicarbonate and / or potassium carbonate, which in Combination with the aforementioned acidic component as Blasting agent is used. The carbonate / bicarbonate can be used in quantities from 5 to 30% by weight.

Vorzugsweise stellen die in der erfindungsgemäßen Kombination (A) genannten Builder die einzigen Builder in der Tablette dar. Zeolithe werden vorzugsweise nicht mitverwendet, obwohl gegebenenfalls die Tablette 5-20 Gew.-% eines Schichtsilikates enthalten kann, was den Builder besonders geeignet macht für hartes Wasser mit hohen Anteilen Magnesiumhärte.Preferably, those in the inventive combination (A) Builder the only builder in the tablet Zeolites are preferably not included, although optionally the tablet 5-20 wt .-% of a phyllosilicate which makes the builder particularly suitable for Hard water with high levels of magnesium hardness.

Als weitere Hilfsmittel zusätzlich zu den bereits genannten können beispielsweise Cellulosederivate, wie Methylhydroxy­ ethylcellulose, oder Paraffinöl in geringen Mengen mit­ verwendet werden.As a further aid in addition to those already mentioned For example, cellulose derivatives such as methylhydroxy  ethylcellulose, or paraffin oil in small amounts with be used.

Eine bevorzugte Builder-Tablette gemäß vorliegender Erfindung enthält:
16-40 Gew.-%, vorzugsweise 18-35 Gew.-% Trinatriumcitrat,
14-21 Gew.-%, vorzugsweise 17-19 Gew.-% Citronensäure,
20-40 Gew.-%, vorzugsweise 30-36 Gew.-% Maleinsäure/Acrylsäure- Copolymerisat, Na-Salz und/oder Polymer auf Peptidbasis,
2-5 Gew.-% Polyethylenglykol (4000-6000),
15-30 Gew.-% Carbonat/Bicarbonat,
1-2 Gew.-% Polyvinylpyrrolidon.A preferred builder tablet according to the present invention contains:
16-40% by weight, preferably 18-35% by weight of trisodium citrate,
14-21% by weight, preferably 17-19% by weight of citric acid,
20-40% by weight, preferably 30-36% by weight, of maleic acid / acrylic acid copolymer, Na salt and / or peptide-based polymer,
2-5% by weight of polyethylene glycol (4000-6000),
15-30% by weight of carbonate / bicarbonate,
1-2% by weight of polyvinylpyrrolidone.

Beispiel 10Example 10

Aus folgenden Bestandteilen wurde eine Builder-Tablette gepreßt:The following ingredients became a builder tablet pressed:

Maleinsäure/Acrylsäure-Copolymerisat, Granulat , pH 4|30%Maleic acid / acrylic acid copolymer, granules, pH 4 | 30% Trinatriumcitrattrisodium citrate 19%19% Citronensäurecitric acid 18%18% Natriumcarbonatsodium 30%30% Paraffinölparaffin oil 0,2%0.2% Polyethylenglykol (1500)Polyethylene glycol (1500) 2,8% 2.8% 100,0%100.0%

Claims (11)

1. Wasserlösliches, wasserenthärtendes Mittel mit Buildereigen­ schaften zur Verwendung in einer Waschlauge, in Form einer schnell sich auflösenden Tablette, bestehend aus
  • A) 60-98 Gew.-% einer Kombination aus
  • a) Citrat und/oder Citronensäure und
  • b) einem als Enthärter wirksamen Polymer
A water-soluble, water-softening agent with builder properties for use in a wash liquor, in the form of a rapidly dissolving tablet consisting of
  • A) 60-98 wt .-% of a combination of
  • a) citrate and / or citric acid and
  • b) a polymer which acts as a softener
in einem Gewichtsverhältnis von a : b von 70 : 30 bis 50 : 50,
  • B) 0,5-6 Gew.-% Polyethylenglykol
  • C) 0-38 Gew.-% weiterer Hilfsstoffe.
in a weight ratio of a: b of 70:30 to 50:50,
  • B) 0.5-6 wt .-% polyethylene glycol
  • C) 0-38 wt .-% of other auxiliaries.
2. Wasserenthärtendes Mittel nach Anspruch 1, dadurch gekennzeichnet, daß das Polymer ein biologisch abbaubares Polymer auf Peptid-Basis ist.2. water-softening agent according to claim 1, characterized characterized in that the polymer is a biodegradable polymer is based on peptide. 3. Wasserenthärtendes Mittel nach Anspruch 1, dadurch gekennzeichnet, daß das Polymer ein Maleinsäure/Acrylsäure Copolymerisat ist. 3. water-softening agent according to claim 1, characterized characterized in that the polymer is a maleic acid / acrylic acid Copolymer is.   4. Wasserenthärtendes Mittel nach einem der vorgehenden Ansprüche, dadurch gekennzeichnet, daß es in der Kombination A Citronensäure und/oder teilneutralisiertes, sauer wirkendes Polymer enthält und als weiteren Hilfsstoff Carbonat und/oder Bicarbonat als Sprengmittel.4. water-softening agent according to one of the preceding Claims, characterized in that it is in the combination A Citric acid and / or partially neutralized, acidic Contains polymer and as a further adjuvant carbonate and / or Bicarbonate as a disintegrant. 5. Wasserenthärtendes Mittel nach einem der vorgehenden Ansprüche, dadurch gekennzeichnet, daß es 1-3 Gew.-% Polyethylenglykol (1000-6000) enthält.5. water-softening agent according to one of the preceding Claims, characterized in that it contains 1-3% by weight Polyethylene glycol (1000-6000) contains. 6. Wasserenthärtendes Mittel nach einem der vorgehenden Ansprüche, dadurch gekennzeichnet, daß es als weiteren Hilfsstoff 0,5-5 Gew.-% Polyethylenglykol (200) als Staubbindemittel enthält.6. water-softening agent according to one of the preceding Claims, characterized in that it as a further Excipient 0.5-5 wt .-% polyethylene glycol (200) as Contains dust binder. 7. Wasserenthärtendes Mittel nach einem der vorgehenden Ansprüche, dadurch gekennzeichnet, daß es als weiteren Hilfsstoff 1-20 Gew.-% eines unlöslichen Polyvinylpyrrolidons als Sprengmittel enthält.7. Water-softening agent according to one of the preceding Claims, characterized in that it as a further Excipient 1-20 wt .-% of an insoluble polyvinylpyrrolidone contains as disintegrant. 8. Wasserenthärtendes Mittel nach einem der vorgehenden Ansprüche, dadurch gekennzeichnet, daß es als weiteren Hilfsstoff 5-20 Gew.-% eines Schichtsilikats enthält.8. water-softening agent according to one of the preceding Claims, characterized in that it as a further Excipient contains 5-20 wt .-% of a layered silicate. 9. Wasserenthärtendes Mittel nach einem der vorgehenden Ansprüche, dadurch gekennzeichnet, daß es
  • a1) 16-40 Gew.-% Trinatriumcitrat,
  • a2) 14-21 Gew.-% Citronensäure,
  • b) 20-40 Gew.-%, Maleinsäure/Acrylsäure-Copolymerisat, Na-Salz und/oder Polymer auf Peptidbasis,
    2-5 Gew.-% Polyethylenglykol (4000-6000),
    15-30 Gew.-% Carbonat/Bicarbonat,
    1-2 Gew.-% Polyvinylpyrrolidon
9. water-softening agent according to one of the preceding claims, characterized in that it
  • a1) 16-40% by weight of trisodium citrate,
  • a2) 14-21% by weight of citric acid,
  • b) 20-40% by weight, maleic acid / acrylic acid copolymer, Na salt and / or peptide-based polymer,
    2-5% by weight of polyethylene glycol (4000-6000),
    15-30% by weight of carbonate / bicarbonate,
    1-2% by weight of polyvinylpyrrolidone
enthält.contains.
DE4318902A 1993-06-07 1993-06-07 Water-soluble, water-softening agent Expired - Fee Related DE4318902C2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DE4318902A DE4318902C2 (en) 1993-06-07 1993-06-07 Water-soluble, water-softening agent
DK94108688.6T DK0628627T3 (en) 1993-06-07 1994-06-07 Water soluble, water softening builder
ES94108688T ES2098820T3 (en) 1993-06-07 1994-06-07 IMPROVER OF THE SOLUBLE DETERGENCE IN WATER AND WATER DESINCURER.
AT94108688T ATE150081T1 (en) 1993-06-07 1994-06-07 WATER SOLUBLE, WATER SOFTENING BUILDER
EP94108688A EP0628627B1 (en) 1993-06-07 1994-06-07 Water-soluble, water softening builder
DE59402005T DE59402005D1 (en) 1993-06-07 1994-06-07 Water soluble, water softening builder
SI9430037T SI0628627T1 (en) 1993-06-07 1994-06-07 Water-soluble, water softening builder
GR970400868T GR3023207T3 (en) 1993-06-07 1997-04-21 Water-soluble, water softening builder.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4318902A DE4318902C2 (en) 1993-06-07 1993-06-07 Water-soluble, water-softening agent

Publications (2)

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DE4318902A1 DE4318902A1 (en) 1994-12-08
DE4318902C2 true DE4318902C2 (en) 1996-10-24

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DE4318902A Expired - Fee Related DE4318902C2 (en) 1993-06-07 1993-06-07 Water-soluble, water-softening agent
DE59402005T Expired - Lifetime DE59402005D1 (en) 1993-06-07 1994-06-07 Water soluble, water softening builder

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DE59402005T Expired - Lifetime DE59402005D1 (en) 1993-06-07 1994-06-07 Water soluble, water softening builder

Country Status (7)

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EP (1) EP0628627B1 (en)
AT (1) ATE150081T1 (en)
DE (2) DE4318902C2 (en)
DK (1) DK0628627T3 (en)
ES (1) ES2098820T3 (en)
GR (1) GR3023207T3 (en)
SI (1) SI0628627T1 (en)

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DE19606765A1 (en) * 1996-02-23 1997-08-28 Henkel Kgaa Process for the production of dishwasher tablets
DE19714657C1 (en) * 1997-04-09 1999-01-07 Benckiser Nv Water soluble, water softening builder
EP1004661A1 (en) 1998-11-11 2000-05-31 DALLI-WERKE WÄSCHE- und KÖRPERPFLEGE GmbH & Co. KG High density granule, method for production thereof, and its use as disintegrant in tablets
DE19858888A1 (en) * 1998-12-19 2000-06-21 Henkel Kgaa Use of low molecular weight homopolymeric polyacrylates in water softeners and in preventing deposits on heating rods during machine washing of textiles
DE19937428A1 (en) * 1999-08-07 2001-02-08 Henkel Kgaa Detergent tablets
US20030104969A1 (en) 2000-05-11 2003-06-05 Caswell Debra Sue Laundry system having unitized dosing
DE10123621B4 (en) * 2001-05-15 2006-12-07 Henkel Kgaa Process for the preparation of a water softener tablet
GB2410496A (en) * 2004-01-31 2005-08-03 Reckitt Benckiser Nv Water softening tablets
GB0415316D0 (en) * 2004-07-08 2004-08-11 Reckitt Benckiser Nv Method of removing laundry ash
GB0415291D0 (en) * 2004-07-08 2004-08-11 Reckitt Benckiser Nv Method of removing laundry ash
DE102007059677A1 (en) * 2007-12-10 2009-06-25 Henkel Ag & Co. Kgaa cleaning supplies
CN102575197B (en) * 2009-09-02 2013-10-30 荷兰联合利华有限公司 Composition and method for treatment of fabric
CA2682636C (en) 2009-11-05 2010-06-15 The Procter & Gamble Company Laundry scent additive
US8476219B2 (en) 2009-11-05 2013-07-02 The Procter & Gamble Company Laundry scent additive
DE102010051226A1 (en) 2010-11-12 2012-05-31 Dental Care Innovation Gmbh Rinse-off tray with abrasive components
WO2014003845A1 (en) * 2012-06-27 2014-01-03 Amcol International Corporation Low density builder and detergent particles via high shear agglomeration
CN104854229B (en) 2012-12-20 2018-08-07 宝洁公司 laundry scent additive
JP2020505431A (en) 2017-02-02 2020-02-20 ウォーター ピック インコーポレイテッド Tablets containing tooth cleaning abrasives

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US5328633A (en) * 1990-05-04 1994-07-12 The United States Of America As Represented By The Secretary Of The Navy Extended-release plaque preventing and dissolving compositions
DK166548B1 (en) * 1991-03-15 1993-06-07 Cleantabs As PHOSPHATE-FREE MACHINE DISHWASH

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CN103981713A (en) * 2014-05-21 2014-08-13 吴江市英力达塑料包装有限公司 Fabric care softener and preparation method thereof

Also Published As

Publication number Publication date
EP0628627B1 (en) 1997-03-12
EP0628627A1 (en) 1994-12-14
DK0628627T3 (en) 1997-08-25
GR3023207T3 (en) 1997-07-30
DE59402005D1 (en) 1997-04-17
SI0628627T1 (en) 1997-10-31
ATE150081T1 (en) 1997-03-15
DE4318902A1 (en) 1994-12-08
ES2098820T3 (en) 1997-05-01

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