DE3889233T2 - Verfahren zur Herstellung von Essigsäure und heterogener Katalysator dafür. - Google Patents

Verfahren zur Herstellung von Essigsäure und heterogener Katalysator dafür.

Info

Publication number
DE3889233T2
DE3889233T2 DE3889233T DE3889233T DE3889233T2 DE 3889233 T2 DE3889233 T2 DE 3889233T2 DE 3889233 T DE3889233 T DE 3889233T DE 3889233 T DE3889233 T DE 3889233T DE 3889233 T2 DE3889233 T2 DE 3889233T2
Authority
DE
Germany
Prior art keywords
production
acetic acid
heterogeneous catalyst
catalyst therefor
therefor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE3889233T
Other languages
English (en)
Other versions
DE3889233D1 (de
Inventor
Charles R Marston
Gerald L Goe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CNA Holdings LLC
Original Assignee
Reilly Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reilly Industries Inc filed Critical Reilly Industries Inc
Publication of DE3889233D1 publication Critical patent/DE3889233D1/de
Application granted granted Critical
Publication of DE3889233T2 publication Critical patent/DE3889233T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
DE3889233T 1987-02-05 1988-02-03 Verfahren zur Herstellung von Essigsäure und heterogener Katalysator dafür. Expired - Lifetime DE3889233T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US1128687A 1987-02-05 1987-02-05

Publications (2)

Publication Number Publication Date
DE3889233D1 DE3889233D1 (de) 1994-06-01
DE3889233T2 true DE3889233T2 (de) 1994-08-11

Family

ID=21749702

Family Applications (1)

Application Number Title Priority Date Filing Date
DE3889233T Expired - Lifetime DE3889233T2 (de) 1987-02-05 1988-02-03 Verfahren zur Herstellung von Essigsäure und heterogener Katalysator dafür.

Country Status (7)

Country Link
EP (1) EP0277824B1 (de)
JP (1) JPH072671B2 (de)
KR (1) KR950013076B1 (de)
BR (1) BR8800468A (de)
CA (1) CA1322193C (de)
DE (1) DE3889233T2 (de)
IL (1) IL85320A (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010040921A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure
WO2014070735A1 (en) 2012-10-31 2014-05-08 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates
WO2014209633A2 (en) 2013-06-27 2014-12-31 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5334755A (en) * 1992-04-24 1994-08-02 Chiyoda Corporation Process for the production of acetic acid from methanol and carbon monoxide using supported rhodium catalyst
US5284974A (en) * 1992-08-11 1994-02-08 Monsanto Company Process for the preparation of thioacetamide
US5281359A (en) * 1992-08-31 1994-01-25 Hoechst Celanese Corporation Polymeric carbonylation catalyst system
GB9303770D0 (en) * 1993-02-25 1993-04-14 Bp Chem Int Ltd Process
US6235673B1 (en) * 2000-04-05 2001-05-22 Eastman Chemical Company Carbonylation catalyst supported on a carbonized polysulfonated divinylbenzene-styrene copolymer
US6420304B1 (en) * 2000-04-20 2002-07-16 China Petrochemical Development Corporation Polymer-supported carbonylation catalyst and its use
JP4891482B2 (ja) * 2001-02-06 2012-03-07 千代田化工建設株式会社 カルボン酸の製造方法
CN100376325C (zh) * 2004-03-25 2008-03-26 香港理工大学 羰基合成催化剂、其制备方法和制备乙酸和乙酐的方法
WO2011099264A1 (ja) 2010-02-09 2011-08-18 千代田化工建設株式会社 メタノールのカルボニル化反応速度の向上方法
US9926397B2 (en) 2012-02-10 2018-03-27 Chiyoda Corporation Vinylpyridine resin for catalyst carriers and method of manufacturing the same
EP2631010B1 (de) * 2012-02-27 2020-08-05 Chiyoda Corporation Vinylpyridinharz für katalysatorträger und verfahren zur herstellung davon
JP2014234383A (ja) 2013-06-05 2014-12-15 千代田化工建設株式会社 カルボニル化合物の製造方法
CN108778496B (zh) 2016-03-18 2021-05-28 千代田化工建设株式会社 催化剂载体用乙烯基吡啶树脂、其制造方法及甲醇的羰基化反应用催化剂
KR101874523B1 (ko) 2017-08-23 2018-07-04 (주)부흥산업사 메탄올 카보닐레이션에 의한 초산제조용 불균일 촉매
JP7440229B2 (ja) 2019-09-05 2024-02-28 ケロッグ ブラウン アンド ルート エルエルシー 酢酸製造方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3769329A (en) * 1970-03-12 1973-10-30 Monsanto Co Production of carboxylic acids and esters
US4328125A (en) * 1979-05-14 1982-05-04 University Of Illinois Foundation Heterogeneous anionic transition metal catalysts

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010040921A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure
WO2012034929A2 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur herstellung von acrylsäure aus methanol und essigsäure
US8877966B2 (en) 2010-09-16 2014-11-04 Basf Se Process for preparing acrylic acid from methanol and acetic acid
WO2014070735A1 (en) 2012-10-31 2014-05-08 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates
WO2014209633A2 (en) 2013-06-27 2014-12-31 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates

Also Published As

Publication number Publication date
KR950013076B1 (ko) 1995-10-24
IL85320A (en) 1992-08-18
EP0277824B1 (de) 1994-04-27
CA1322193C (en) 1993-09-14
JPH072671B2 (ja) 1995-01-18
DE3889233D1 (de) 1994-06-01
KR890012932A (ko) 1989-09-20
EP0277824A3 (en) 1989-12-20
JPS63253047A (ja) 1988-10-20
IL85320A0 (en) 1988-07-31
BR8800468A (pt) 1988-09-20
EP0277824A2 (de) 1988-08-10

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Legal Events

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8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: HOECHST CELANESE CORP., SOMERVILLE, N.J., US