DE3832342C1 - Platinum-jacketed wire, method for production of a platinum-jacketed wire and use of a platinum-jacketed wire - Google Patents

Platinum-jacketed wire, method for production of a platinum-jacketed wire and use of a platinum-jacketed wire

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Publication number
DE3832342C1
DE3832342C1 DE19883832342 DE3832342A DE3832342C1 DE 3832342 C1 DE3832342 C1 DE 3832342C1 DE 19883832342 DE19883832342 DE 19883832342 DE 3832342 A DE3832342 A DE 3832342A DE 3832342 C1 DE3832342 C1 DE 3832342C1
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Germany
Prior art keywords
platinum
wire
weight
sheathed wire
palladium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE19883832342
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German (de)
Inventor
Albrecht Dr. 6454 Bruchkoebel De Bischoff
Helmut 6450 Hanau De Koch
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WC Heraus GmbH and Co KG
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WC Heraus GmbH and Co KG
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Application filed by WC Heraus GmbH and Co KG filed Critical WC Heraus GmbH and Co KG
Priority to DE19883832342 priority Critical patent/DE3832342C1/en
Application granted granted Critical
Publication of DE3832342C1 publication Critical patent/DE3832342C1/en
Expired legal-status Critical Current

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Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K7/00Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements
    • G01K7/16Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements using resistive elements
    • G01K7/18Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements using resistive elements the element being a linear resistance, e.g. platinum resistance thermometer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/04Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of bars or wire
    • B21C37/042Manufacture of coated wire or bars
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/01Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/018Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of a noble metal or a noble metal alloy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Resistance Heating (AREA)

Abstract

The invention discloses a jacketed wire having a platinum jacket which encases a core composed of an alloy of 1 to 5% by weight of tungsten, the remainder being palladium. The jacket volume per length unit is 10 to 50% of the total volume of the jacketed wire. These jacketed wires are produced by drawing a rod-tube arrangement. The jacketed wires are preferably used as supply-lead wires for resistance thermometers having a platinum measurement resistor.

Description

Die Erfindung bezieht sich auf einen Manteldraht mit einem Mantel aus Platin, der einen Kern aus einem edelmetallhaltigen Werkstoff umhüllt, auf ein Verfahren zur Herstellung solcher Manteldrähte sowie auf deren Verwendung.The invention relates to a sheathed wire with a sheath made of platinum, which encases a core made of a precious metal-containing material Process for the production of such sheathed wires and their use.

Es sind seit vielen Jahren Widerstandsthermometer im Handel erhältlich, bei denen mit dem im wesentlichen aus Platin bestehenden Meßwiderstand ein Manteldraht als Zuleitungsdraht für die Stromzuleitung unverrückbar verbunden, insbesondere verschweißt, ist. Der Zuleitungsdraht besteht aus einem Mantel aus Platin, der einen Kern aus einer Gold-Legierung, die 5 Gewichts-% Platin enthält, umhüllt. Diese bekannten Manteldrähte weisen gute mechanische Eigenschaften, wie Zugfestigkeit, Bruchdehnung und Streckfähigkeit auf. Allerdings ist ihr Preis sehr erheblich, insbesondere weil das Volumen des aus Platin bestehenden Mantels pro Längeneinheit etwa 64% des Gesamtvolumens des Manteldrahts beträgt. Man hat daher schon versucht, den Volumen-Anteil des Mantels am Gesamtvolumen des Manteldrahts zu vermindern, um dadurch den Preis des Manteldrahts zu reduzieren. Derartige Versuche schlugen jedoch fehl, weil mit der Verminderung des Mantelvolumens Verschlechterungen der mechanischen Eigenschaften des Manteldrahts einhergingen.Resistance thermometers have been commercially available for many years, at those with the measuring resistor consisting essentially of platinum Sheathed wire firmly connected as a lead wire for the power lead, especially welded. The lead wire consists of a sheath Made of platinum, which has a core made of a gold alloy, which is 5% platinum by weight contains, envelops. These known sheathed wires have good mechanical Properties such as tensile strength, elongation at break and stretchability. However, their price is very substantial, especially because of the volume of the Platinum existing jacket per unit length about 64% of the total volume of the Sheathed wire is. One has therefore already tried to determine the volume proportion of the To reduce the sheath to the total volume of the sheathed wire, thereby reducing the price to reduce the sheathed wire. However, such attempts failed because with the reduction of the jacket volume deterioration of the mechanical Properties of the sheathed wire went hand in hand.

Aus der EP-PS 00 29 888 ist die Herstellung eines Manteldrahtes bekannt, der einen Kern aus einer Zirkon-Kupferlegierung und einen Mantel aus Gold besitzt. Er wird in der Weise hergestellt, daß ein Vorratsdraht aus der Zirkon-Kupfer­ legierung gereckt, dann Gold plattiert und nach der Goldplattierung der Draht in zwei Stufen auf Enddurchmesser gereckt wird. Hierbei handelt es sich offen­ sichtlich um ein galvanisches Plattierverfahren.From EP-PS 00 29 888 the manufacture of a sheathed wire is known has a core made of a zircon-copper alloy and a jacket made of gold. It is made in such a way that a supply wire made of zircon copper alloy stretched, then gold plated and after gold plating the wire is stretched to final diameter in two stages. This is open obviously a galvanic plating process.

Der Erfindung liegt daher die Aufgabe zugrunde, einen preiswerteren Manteldraht mit Platin-Mantel zu schaffen, der zumindest gleich gute mechanische Eigenschaften wie die bekannten Manteldrähte mit Platin-Mantel und einem Kern aus einer 95 Gewichts-% Gold und 5 Gewichts-% Platin bestehenden Legierung aufweist.The invention is therefore based on the object, a cheaper To create sheathed wire with a platinum sheath that is at least equally good mechanical properties like the well-known sheathed wires with platinum sheath and a core consisting of a 95% by weight gold and 5% by weight platinum Alloy.

Gelöst wird diese Aufgabe für einen Manteldraht mit einem Mantel aus Platin, der einen Kern aus einem edelmetallhaltigen Werkstoff umhüllt, erfindungsgemäß dadurch, daß der Kern aus einer Palladium-Legierung besteht, die 1 bis 5 Gewichts-% Wolfram, Rest Palladium enthält, und daß das Mantelvolumen pro Längeneinheit 10 bis 50% des Gesamtvolumens des Manteldrahts beträgt.This task is solved for a sheathed wire with a sheath made of platinum, which encases a core made of a noble metal-containing material, according to the invention in that the core consists of a palladium alloy, the 1 to 5 % By weight tungsten, the rest contains palladium, and that the jacket volume per Unit of length is 10 to 50% of the total volume of the sheathed wire.

Bewährt hat sich besonders ein Manteldraht, der sich dadurch auszeichnet, daß der Kern aus einer Legierung aus 3 Gewichts-% Wolfram und 97 Gewichts-% Palladium besteht und daß das Mantelvolumen 30% des Gesamtvolumens des Manteldrahtes beträgt.A sheathed wire, which is characterized in that the core of an alloy of 3% by weight tungsten and 97% by weight Palladium exists and that the jacket volume 30% of the total volume of the Sheathed wire is.

Überraschenderweise haben Vergleichsuntersuchungen ergeben, daß für einen Manteldraht gemäß Anspruch 2 Zugfestigkeitswerte von 322 N/mm2, eine Streckgrenze von 125 N/mm2 und eine Bruchdehnung von 24% erreicht werden, während unter gleichen Bedingungen für einen Manteldraht mit Platin-Mantel und einem Kern aus einer Legierung, die aus 95 Gewichts-% Gold und 5 Gewichts-% Platin besteht, und dessen Mantelvolumen pro Längeneinheit 64%, bezogen auf das Gesamtvolumen des Manteldrahts, beträgt, Zugfestigkeitswerte von 229 N/mm2, eine Streckgrenze von 144 N/mm2 und eine Bruchdehnung von 17% gemessen wurden. Die Zugversuche zur Ermittlung der Zugfestigkeit-, Streckgrenzen- und Bruchdehnungswerte wurden gemäß DIN 51210 durchgeführt. Die Kosteneinsparungen für erfindungsgemäße Manteldrähte betragen etwa 1/3 der Kosten für die zu den Vergleichsversuchen herangezogenen Manteldrähte des Standes der Technik.Surprisingly, comparative tests have shown that tensile strength values of 322 N / mm 2 , a yield strength of 125 N / mm 2 and an elongation at break of 24% are achieved for a sheathed wire according to claim 2, while under the same conditions for a sheathed wire with a platinum sheath and a Core made of an alloy consisting of 95% by weight gold and 5% by weight platinum, and whose sheath volume per unit length is 64%, based on the total volume of the sheathed wire, tensile strength values of 229 N / mm 2 , a yield strength of 144 N / mm 2 and an elongation at break of 17% were measured. The tensile tests to determine the tensile strength, yield strength and elongation at break values were carried out in accordance with DIN 51210. The cost savings for inventive sheath wires are about 1/3 of the cost of the zoom drawn to the comparative experiments sheath wires of the prior art.

Außer der Kosteneinsparung hat sich überraschenderweise ergeben, daß die mechanischen Eigenschaften erfindungsgemäßer Manteldrähte gegenüber den bekannten und bewährten Vergleichs-Manteldrähten sogar verbessert sind; bei etwa gleichen Werten für die Streckgrenze liegen die Werte für die Zugfestigkeit und die Bruchdehnung um etwa 40% höher.In addition to the cost savings, it has surprisingly been found that the mechanical properties of sheathed wires according to the invention compared to  known and proven comparison sheathed wires are even improved; at The values for the are about the same values for the yield strength Tensile strength and elongation at break about 40% higher.

Die Herstellung des erfindungsgemäßen Manteldrahts mit Mantel aus Platin und einem Kern aus einer Palladium-Wolfram-Legierung erfolgt vorteilhafterweise so, daß ein stabförmiger Kern-Werkstoff aus einer Palladium-Legierung, die aus 1 bis 5 Gewichts-% Wolfram, Rest Palladium besteht, in ein Rohr aus Platin eingebracht und diese Stab-Rohr-Anordnung auf Enddraht-Durchmesser gezogen wird.The production of the sheathed wire according to the invention with a sheath made of platinum and a core made of a palladium-tungsten alloy is advantageously made so that a rod-shaped core material made of a palladium alloy 1 to 5% by weight of tungsten, rest of palladium, in a tube made of platinum introduced and drawn this rod-tube arrangement to end wire diameter becomes.

Vorteilhafterweise erfolgt der Ziehvorgang in mehreren Stufen mit jeweils einer Zwischenglühung.The drawing process advantageously takes place in several stages, each with an intermediate annealing.

Erfindungsgemäße Manteldrähte werden vorzugsweise als Zuleitungsdraht für Widerstandsthermometer mit einem aus im wesentlichen aus Platin bestehenden Meßwiderstand verwendet.Sheathed wires according to the invention are preferably used as lead wires for Resistance thermometer with one consisting essentially of platinum Measuring resistor used.

In der Figur ist schematisch ein Ausführungsbeispiel eines Manteldrahts gemäß der Erfindung dargestellt.In the figure, an exemplary embodiment of a sheathed wire is shown schematically presented the invention.

Mit der Bezugsziffer 1 ist der aus Platin bestehende Mantel bezeichnet, dessen Volumen pro Längeneinheit 30%, bezogen auf das Gesamtvolumen des Manteldrahts, beträgt. Der Mantel 1 umhüllt den Kern 2, der aus einer Legierung aus 97 Gewichts-% Palladium und 3 Gewichts-% Wolfram besteht und dessen Volumen pro Längeneinheit 70%, bezogen auf das Gesamtvolumen des Manteldrahts, beträgt.The reference number 1 denotes the sheath consisting of platinum, the volume of which per unit length is 30%, based on the total volume of the sheathed wire. The jacket 1 envelops the core 2 , which consists of an alloy of 97% by weight palladium and 3% by weight tungsten and whose volume per unit length is 70%, based on the total volume of the jacket wire.

Ein Beispiel für die Herstellung eines erfindungsgemäßen Manteldrahts wird nachfolgend beschrieben: Ausgangsmaterialien sind einerseits ein Rohr aus chemisch reinem Platin mit einem Außendurchmesser von 10 mm und einem Innendurchmesser von 7 mm, andererseits ein Stab aus einer Legierung aus 97 Gewichts-% Palladium und 3 Gewichts-% Wolfram mit einem Durchmesser von 6,5 mm. Der Stab wird in das Rohr geschoben und diese Anordnung durch eine Kombination von Zieh-, Warmwalz- und Kaltwalzschritten zu einem Manteldraht mit einem Durchmesser von 3 mm verformt. Dieser so hergestellte Manteldraht wird dann einem Ziehprozeß mit 20 Ziehschritten unterworfen, wodurch ein Manteldraht mit einem Enddurchmesser von 0,35 mm entsteht. Die Dicke des Platin-Mantels beträgt 15 µm.An example of the production of a sheathed wire according to the invention is Described below: Starting materials are made of a tube chemically pure platinum with an outer diameter of 10 mm and a Inside diameter of 7 mm, on the other hand an alloy rod 97% by weight of palladium and 3% by weight of tungsten with a diameter of 6.5 mm. The rod is pushed into the tube and this arrangement by a  Combination of drawing, hot rolling and cold rolling steps to form a sheathed wire deformed with a diameter of 3 mm. This sheathed wire made in this way is then subjected to a drawing process with 20 drawing steps, whereby a Sheathed wire with a final diameter of 0.35 mm is created. The thickness of the Platinum coat is 15 µm.

Claims (4)

1. Manteldraht aus einem Mantel aus Platin, der einen Kern aus einem edelmetallhaltigen Werkstoff umhüllt, dadurch gekennzeichnet, daß der Kern aus einer Palladium-Legierung besteht, die 1 bis 5 Gewichts-% Wolfram, Rest Palladium enthält und daß das Mantelvolumen pro Längeneinheit 10 bis 50% des Gesamtvolumens des Manteldrahts beträgt.1. Sheathed wire from a sheath made of platinum, which surrounds a core made of a noble metal-containing material, characterized in that the core consists of a palladium alloy containing 1 to 5% by weight of tungsten, the rest being palladium, and in that the sheath volume per unit length is 10 is up to 50% of the total volume of the sheathed wire. 2. Manteldraht nach Anspruch 1, dadurch gekennzeichnet, daß der Kern aus einer Legierung aus 3 Gewichts-% Wolfram und 97 Gewichts-% Palladium besteht und daß das Mantelvolumen pro Längeneinheit 30% des Gesamtvolumens des Manteldrahts beträgt.2. Sheathed wire according to claim 1, characterized in that the core an alloy of 3% by weight tungsten and 97% by weight palladium exists and that the jacket volume per unit length 30% of Total volume of the sheathed wire is. 3. Verfahren zur Herstellung eines Manteldrahts mit einem Mantel aus Platin und einem Kern aus edelmetallhaltigem Werkstoff, dadurch gekennzeichnet, daß ein stabförmiger Kern-Werkstoff aus einer Palladium-Legierung, die aus 1 bis 5 Gewichts-% Wolfram, Rest Palladium besteht, in ein Rohr aus Platin eingebracht und diese Stab-Rohr-Anordnung auf Enddraht-Durchmesser gezogen wird.3. Process for producing a sheathed wire with a sheath made of platinum and a core made of precious metal-containing material, characterized in that that a rod-shaped core material made from a palladium alloy 1 to 5% by weight of tungsten, rest of palladium, in a tube made of platinum introduced and drawn this rod-tube arrangement to end wire diameter becomes. 4. Verwendung eines Manteldrahts nach den Ansprüchen 1 oder 2 als Zuleitungsdraht für Widerstandsthermometer mit einem aus im wesentlichen aus Platin bestehenden Meßwiderstand.4. Use of a sheathed wire according to claims 1 or 2 as Essentially, lead wire for resistance thermometers with one off measuring resistor made of platinum.
DE19883832342 1988-09-23 1988-09-23 Platinum-jacketed wire, method for production of a platinum-jacketed wire and use of a platinum-jacketed wire Expired DE3832342C1 (en)

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Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4108514A1 (en) * 1990-03-16 1991-09-19 Ngk Insulators Ltd RESISTANCE ELEMENT WITH INLETS
EP0447612A2 (en) * 1990-03-23 1991-09-25 W.C. Heraeus GmbH Method of making a composite metal wire
DE4117928C1 (en) * 1991-05-31 1992-09-17 Heraeus Sensor Gmbh, 6450 Hanau, De Electrical resistance wire for use above 800 deg. C. - has core of dispersion-hardened material comprising mainly platinum gp. metal contg. e.g. dispersed zirconium@, and platinum gp. metal of alloy sheath
DE4125980A1 (en) * 1991-08-06 1993-02-11 Heraeus Sensor Gmbh Temp.-resistant connector wire - consists of a highly conductive core and a platinum@-rich mantle into which gold@ has been diffused to allow easier connection
EP1256963A2 (en) * 2001-05-09 2002-11-13 Isabellenhütte Heusler GmbH KG Electrical resistor and method of manufacture
DE10153217A1 (en) * 2001-10-31 2003-06-05 Heraeus Sensor Nite Gmbh Sheathed wire, in particular connecting wire for electrical temperature sensors
DE10206336A1 (en) * 2002-02-14 2003-09-04 Bauerhin I G Electric heating element for seat heaters and steering wheel heaters
DE102004011514A1 (en) * 2004-03-08 2005-10-06 W.E.T. Automotive Systems Ag Heater element comprises an electric conductor with a plastic, string-like core and an outer cover consisting at least partially of gold and/or silver
WO2007019990A1 (en) * 2005-08-15 2007-02-22 W.C. Heraeus Gmbh Pt-ir-based wire hardened by oxide dispersion and other alloys provided with an improved surface for spark plug electrodes
DE102006026047A1 (en) * 2006-06-01 2007-12-06 W.E.T. Automotive Systems Ag Flat heating element
DE202007003046U1 (en) 2007-02-28 2008-07-03 W.E.T. Automotive Systems Ag Electrical conductor
DE102007010145A1 (en) 2007-02-28 2008-09-11 W.E.T Automotive Systems Aktiengesellschaft Electrical conductor
US7838804B2 (en) 2006-05-08 2010-11-23 W.E.T. Automotive Systems Ag Flat heating element
DE202011106363U1 (en) 2010-10-19 2012-03-13 W.E.T. Automotive Systems Ag Electrical conductor
DE102011114949A1 (en) 2010-10-19 2012-04-19 W.E.T. Automotive Systems Ag Electrical conductor
US8226855B2 (en) 2007-02-14 2012-07-24 Heraeus Materials Technology Gmbh & Co. Kg Pt or Pt alloy materials hardened by oxide dispersion, produced by inner oxidation and having proportions of oxide and good ductility
US8253071B2 (en) 2005-12-11 2012-08-28 W.E.T. Automotive Systems, Ltd. Flat heating element
US8288693B2 (en) 2004-03-08 2012-10-16 W.E.T. Automotive Systems Ag Flat heating element
CN103111487A (en) * 2013-03-01 2013-05-22 重庆材料研究院 Preparation method of platinum-coated palladium wire for hot resistance lead
US10721965B2 (en) 2015-07-29 2020-07-28 Altria Client Services Llc E-vapor device including heater structure with recessed shell layer
WO2021043634A1 (en) * 2019-09-06 2021-03-11 Deutsches Zentrum für Luft- und Raumfahrt e.V. Heating mat
EP3932575A1 (en) 2020-07-03 2022-01-05 Heraeus Deutschland GmbH & Co. KG Method for producing sheathed wires with ni core and pt sheath
US11589427B2 (en) 2015-06-01 2023-02-21 Altria Client Services Llc E-vapor device including a compound heater structure

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Cited By (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4108514A1 (en) * 1990-03-16 1991-09-19 Ngk Insulators Ltd RESISTANCE ELEMENT WITH INLETS
EP0447612A2 (en) * 1990-03-23 1991-09-25 W.C. Heraeus GmbH Method of making a composite metal wire
EP0447820A2 (en) * 1990-03-23 1991-09-25 W.C. Heraeus GmbH Method of making a composite metal wire
DE4009366A1 (en) * 1990-03-23 1991-09-26 Heraeus Gmbh W C METHOD FOR PRODUCING A METAL COMPOSITE WIRE
EP0447820A3 (en) * 1990-03-23 1992-02-05 W.C. Heraeus Gmbh Method of making a composite metal wire
EP0447612A3 (en) * 1990-03-23 1992-02-12 W.C. Heraeus Gmbh Method of making a composite metal wire
DE4117928C1 (en) * 1991-05-31 1992-09-17 Heraeus Sensor Gmbh, 6450 Hanau, De Electrical resistance wire for use above 800 deg. C. - has core of dispersion-hardened material comprising mainly platinum gp. metal contg. e.g. dispersed zirconium@, and platinum gp. metal of alloy sheath
DE4125980A1 (en) * 1991-08-06 1993-02-11 Heraeus Sensor Gmbh Temp.-resistant connector wire - consists of a highly conductive core and a platinum@-rich mantle into which gold@ has been diffused to allow easier connection
EP1256963A3 (en) * 2001-05-09 2004-12-22 Isabellenhütte Heusler GmbH & Co.KG Electrical resistor and method of manufacture
EP1256963A2 (en) * 2001-05-09 2002-11-13 Isabellenhütte Heusler GmbH KG Electrical resistor and method of manufacture
DE10122468C1 (en) * 2001-05-09 2003-03-20 Heusler Isabellenhuette Electrical resistance and process for its manufacture
DE10153217A1 (en) * 2001-10-31 2003-06-05 Heraeus Sensor Nite Gmbh Sheathed wire, in particular connecting wire for electrical temperature sensors
DE10153217B4 (en) * 2001-10-31 2007-01-18 Heraeus Sensor Technology Gmbh Sheathed wire, in particular connecting wire for electrical temperature sensors
DE10206336B4 (en) * 2002-02-14 2004-10-07 Bauerhin, I.G. Electric heating element for seat heaters and steering wheel heaters
DE10206336A1 (en) * 2002-02-14 2003-09-04 Bauerhin I G Electric heating element for seat heaters and steering wheel heaters
DE102004011514A1 (en) * 2004-03-08 2005-10-06 W.E.T. Automotive Systems Ag Heater element comprises an electric conductor with a plastic, string-like core and an outer cover consisting at least partially of gold and/or silver
US8288693B2 (en) 2004-03-08 2012-10-16 W.E.T. Automotive Systems Ag Flat heating element
DE102004011514B4 (en) * 2004-03-08 2010-09-30 W.E.T. Automotive Systems Ag Electric heating element
WO2007019990A1 (en) * 2005-08-15 2007-02-22 W.C. Heraeus Gmbh Pt-ir-based wire hardened by oxide dispersion and other alloys provided with an improved surface for spark plug electrodes
US7736752B2 (en) 2005-08-15 2010-06-15 W.C. Heraeus Gmbh Pt/Pd alloy wires, strips or reshaped parts hardened by oxide dispersion, and process of producing the same
US8525079B2 (en) 2005-12-11 2013-09-03 W.E.T. Automotive Systems Ag Flat heating element
US8253071B2 (en) 2005-12-11 2012-08-28 W.E.T. Automotive Systems, Ltd. Flat heating element
US7838804B2 (en) 2006-05-08 2010-11-23 W.E.T. Automotive Systems Ag Flat heating element
US7714256B2 (en) 2006-06-01 2010-05-11 W.E.T. Automotive Systems Ag Flat heating element
DE102006026047A1 (en) * 2006-06-01 2007-12-06 W.E.T. Automotive Systems Ag Flat heating element
DE102006026047B4 (en) * 2006-06-01 2015-06-11 Gentherm Gmbh Heating element, seat and vehicle with such
US8106338B2 (en) 2006-06-01 2012-01-31 W.E.T. Automotive Systems Ag Flat heating element
US8226855B2 (en) 2007-02-14 2012-07-24 Heraeus Materials Technology Gmbh & Co. Kg Pt or Pt alloy materials hardened by oxide dispersion, produced by inner oxidation and having proportions of oxide and good ductility
US8723043B2 (en) 2007-02-28 2014-05-13 W.E.T. Automotive Systems Ag Electric conductor
DE202007003046U1 (en) 2007-02-28 2008-07-03 W.E.T. Automotive Systems Ag Electrical conductor
DE102007010145A1 (en) 2007-02-28 2008-09-11 W.E.T Automotive Systems Aktiengesellschaft Electrical conductor
DE102011114949A1 (en) 2010-10-19 2012-04-19 W.E.T. Automotive Systems Ag Electrical conductor
DE202011106363U1 (en) 2010-10-19 2012-03-13 W.E.T. Automotive Systems Ag Electrical conductor
CN103111487A (en) * 2013-03-01 2013-05-22 重庆材料研究院 Preparation method of platinum-coated palladium wire for hot resistance lead
CN103111487B (en) * 2013-03-01 2015-06-17 重庆材料研究院 Preparation method of platinum-coated palladium wire for hot resistance lead
US11589427B2 (en) 2015-06-01 2023-02-21 Altria Client Services Llc E-vapor device including a compound heater structure
US10721965B2 (en) 2015-07-29 2020-07-28 Altria Client Services Llc E-vapor device including heater structure with recessed shell layer
US11684085B2 (en) 2015-07-29 2023-06-27 Altria Client Services Llc E-vapor device including heater structure with recessed shell layer
WO2021043634A1 (en) * 2019-09-06 2021-03-11 Deutsches Zentrum für Luft- und Raumfahrt e.V. Heating mat
EP3932575A1 (en) 2020-07-03 2022-01-05 Heraeus Deutschland GmbH & Co. KG Method for producing sheathed wires with ni core and pt sheath

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