DE3728348A1 - Multilayer wiring for VLSI semiconductor components - Google Patents
Multilayer wiring for VLSI semiconductor componentsInfo
- Publication number
- DE3728348A1 DE3728348A1 DE19873728348 DE3728348A DE3728348A1 DE 3728348 A1 DE3728348 A1 DE 3728348A1 DE 19873728348 DE19873728348 DE 19873728348 DE 3728348 A DE3728348 A DE 3728348A DE 3728348 A1 DE3728348 A1 DE 3728348A1
- Authority
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- Prior art keywords
- silicon nitride
- layer
- polyimide
- etching
- flanks
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 32
- 239000004642 Polyimide Substances 0.000 claims abstract description 30
- 229920001721 polyimide Polymers 0.000 claims abstract description 30
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 27
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000005530 etching Methods 0.000 claims abstract description 21
- 238000001465 metallisation Methods 0.000 claims abstract description 14
- 229920002120 photoresistant polymer Polymers 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 230000003647 oxidation Effects 0.000 claims abstract description 6
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 6
- 238000010884 ion-beam technique Methods 0.000 claims abstract description 4
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 238000000137 annealing Methods 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 238000001039 wet etching Methods 0.000 claims description 2
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 239000008151 electrolyte solution Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 238000009413 insulation Methods 0.000 abstract description 3
- 238000007669 thermal treatment Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 33
- 239000004020 conductor Substances 0.000 description 7
- 150000004767 nitrides Chemical class 0.000 description 2
- 238000001020 plasma etching Methods 0.000 description 2
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 235000019892 Stellar Nutrition 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/0217—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon nitride not containing oxygen, e.g. SixNy or SixByNz
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
- H01L21/02271—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
- H01L21/02274—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition in the presence of a plasma [PECVD]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31105—Etching inorganic layers
- H01L21/31111—Etching inorganic layers by chemical means
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76802—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
- H01L21/76804—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics by forming tapered via holes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/528—Geometry or layout of the interconnection structure
- H01L23/5283—Cross-sectional geometry
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/5329—Insulating materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02118—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer carbon based polymeric organic or inorganic material, e.g. polyimides, poly cyclobutene or PVC
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- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/022—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates the layer being a laminate, i.e. composed of sublayers, e.g. stacks of alternating high-k metal oxides
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/02227—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process
- H01L21/02258—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by anodic treatment, e.g. anodic oxidation
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- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
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- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/10—Details of semiconductor or other solid state devices to be connected
- H01L2924/11—Device type
- H01L2924/12—Passive devices, e.g. 2 terminal devices
- H01L2924/1204—Optical Diode
- H01L2924/12044—OLED
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Abstract
Description
Die Erfindung betrifft eine Mehrlagenverdrahtung für höchst integrierte Halbleiterbauelemente mit einem aus Polyimid- und Siliziumnitridschichten bestehenden Mehrschichtdielektrikum zwischen den Metallisierungsebenen und mit schrägen Flanken auf weisenden Durchkontaktierungen, sowie ein Verfahren zu ihrer Herstellung.The invention relates to multi-layer wiring for the highest Integrated semiconductor devices with a polyimide and Silicon nitride layers existing multilayer dielectric between the metallization levels and with sloping flanks pointing vias, and a method for their Manufacturing.
Bei der ständig steigenden Packungsdichte von VLSI-Halbleiter bauelementen ist die Mehrschichtmetallisierung einer der be grenzenden Faktoren für eine weitere Erhöhung der Integration. Zum Anschluß und zur Verdrahtung der Transistoren und anderer Bauelemente auf VLSI-Chips sind meist mehr als zwei Metalli sierungsebenen erforderlich. Verläßliche Strukturen können nur noch dann erhalten werden, wenn die Zwischenschichten vor dem Aufbringen jeder weiteren Metallisierungsebene planarisiert wer den.With the ever increasing packing density of VLSI semiconductors multi-layer metallization is one of the components limiting factors for a further increase in integration. For connecting and wiring transistors and others Components on VLSI chips are usually more than two metals levels required. Reliable structures can only still be obtained if the intermediate layers before the Application of every further level of metallization the.
Zum Planarisieren gut geeignet sind Schichten aus Polyimid. Diese ermöglichen einen hohen Einebnungsgrad, sind thermisch stabil und haben die zur Isolation der einzelnen Leiterbahnen erforderlichen exzellenten dielektrischen Eigenschaften. Auch weisen Polyimidschichten eine niedrige Porendichte auf und sind in einem einfachen und billigen Prozeß herzustellen.Layers of polyimide are well suited for planarization. These enable a high degree of leveling and are thermal stable and have the insulation for the individual conductor tracks required excellent dielectric properties. Also have polyimide layers and have a low pore density to manufacture in a simple and inexpensive process.
Allerdings begrenzt der hygroskopische Effekt des Polyimids die Verwendung dieser organischen Schichten auf Halbleiterbauele menten. Um eine zu starke Wasseraufnahme zu vermeiden, sind nach dem Aufbringen von Polyimid nur noch "trockene" Techniken erlaubt; Naßätzung etwa muß vermieden werden. Außerdem weisen bevorzugt aus Aluminium/Silizium/Titan-Legierungen gefertigte Leiterbahnen eine schlechte Haftung auf Polyimid auf. However, the hygroscopic effect of the polyimide limits the Use of these organic layers on semiconductor devices ment. To avoid excessive water absorption after the application of polyimide only "dry" techniques allowed; Wet etching, for example, must be avoided. Also point out preferably made of aluminum / silicon / titanium alloys Conductors have poor adhesion to polyimide.
Einen weitgehenden Feuchtigkeitsausschluß erreicht man bei Ver wendung eines sandwichartig aus Polyimid- und Siliziumnitrid schichten bestehenden Mehrschichtdielektrikums, wie es zum Bei spiel von H. Fritsche et. al. in einem Beitrag zur IEEE VLSI Multilevel Interconnection Conference 1985, Katalog Nr. 85, Sei te 253, beschrieben wird. Die Siliziumnitridschicht dient beim Ätzen der Durchkontaktierungen als Ätzmaske für die Polyimid schicht und ist einem Beitrag von H. Eggers et. al. zur IEEE VLSI Multilevel Interconnection Conference 1985, Katalog Nr. 85, Seite 163, zu entnehmen.Extensive moisture exclusion can be achieved with Ver application of a sandwich made of polyimide and silicon nitride layers of existing multilayer dielectric, such as for the case game by H. Fritsche et. al. in a contribution to the IEEE VLSI Multilevel Interconnection Conference 1985, Catalog No. 85, Sc te 253. The silicon nitride layer serves for Etching of the vias as an etching mask for the polyimide layer and is a contribution by H. Eggers et. al. to the IEEE VLSI Multilevel Interconnection Conference 1985, catalog no. 85, page 163.
Doch ergeben sich bei dieser Technik verschiedene Nachteile. Bei anisotroper reaktiver Ionenätzung (RIE) geraten die Flanken der Durchkontaktierungen zu steil. Dies führt beim Aufbringen der nächsten Metallisierungsebene zu einer schlechten Kantenbe deckung. Mit reaktiver Ionenstrahltechnik (RIBE) werden zwar flachere Flanken erzielt, doch ergeben sich dabei fertigungs technische Probleme. Außerdem liegen nach diesem Schritt die Polyimidätzflanken frei und können im nachfolgenden Prozeß schritt Feuchtigkeit aufnehmen.However, there are several disadvantages with this technique. In the case of anisotropic reactive ion etching (RIE), the flanks come out the vias too steep. This leads to the application the next level of metallization to a bad edge cover. With reactive ion beam technology (RIBE) flatter flanks achieved, but there are manufacturing technical problems. In addition, after this step the Polyimide etching edges free and can be used in the subsequent process step absorb moisture.
Aufgabe der vorliegenden Erfindung ist es daher, eine Mehrla genverdrahtung anzugeben, die diese Nachteile vermeidet, und die in einem einfachen Prozeß herzustellen ist.The object of the present invention is therefore a Mehrla Specify gene wiring that avoids these disadvantages, and which can be produced in a simple process.
Diese Aufgabe wird durch eine Mehrlagenverdrahtung der eingangs erwähnten Art erfindungsgemäß dadurch gelöst, daß die Flanken der Durchkontaktierungen vollständig mit Siliziumnitrid bedeckt sind.This task is accomplished by multi-layer wiring the input mentioned type according to the invention solved in that the flanks of the vias completely covered with silicon nitride are.
Ein Verfahren zum Herstellen der erfindungsgemäßen Mehrlagenver drahung besteht aus den folgenden Verfahrensschritten:A method for producing the multi-layer ver drahung consists of the following process steps:
- a) Aufbringen und Tempern einer Polyimidschicht,a) applying and annealing a polyimide layer,
- b) Durchführung einer Photolacktechnik zur Definition der Durch kontaktierungen,b) Implementation of a photoresist technique to define the through contacts,
- c) anisotrope Ätzung der Kontaktlöcher bzw. Vias in der Polyi midschicht mit der Photolackstruktur als Ätzmaske,c) anisotropic etching of the contact holes or vias in the polyi mid layer with the photoresist structure as an etching mask,
- d) Entfernen der restlichen Ätzmaske,d) removing the remaining etching mask,
- e) ganzflächige Abscheidung einer Siliziumnitridschicht,e) full-surface deposition of a silicon nitride layer,
- f) anodische Oxidation der Siliziumnitridschicht in den Be reichen, wo die Schicht die Böden der Kontaktlöcher bedeckt,f) anodic oxidation of the silicon nitride layer in the Be range where the layer covers the bottoms of the vias,
- g) Entfernen der oxidierten Siliziumnitridbereiche undg) removing the oxidized silicon nitride regions and
- h) Aufbringen der nächsten Metallisierungsebene.h) applying the next metallization level.
Weitere Ausgestaltungen der Erfindung sind den Ünteransprüchen zu entnehmen.Further embodiments of the invention are the subclaims refer to.
Durch die erfindungsgemäße vollständige Bedeckung der Polyimid ätzflanken mit dem nicht hygroskopischen Siliziumnitrid wird eine nachträgliche Feuchtigkeitsaufnahme des Polyimid vermieden und die Fehlerdichte der Polyimidschicht reduziert. Durch die Verwendung einer organischen Ätzmaske für die Ätzung der Durch kontaktierungen in die Polyimidschicht können flache Ätzwinkel erzeugt werden. Die Flanken der Ätzmaske werden dabei auf das Polyimid übertragen. Auf diese Weise läßt sich bei der ab schließenden Metallisierung eine gute Kantenbedeckung erzielen. Die Mehrlagenverdrahtung kann somit lunkerfrei fertiggestellt werden.Through the complete covering of the polyimide according to the invention etching edges with the non-hygroscopic silicon nitride subsequent moisture absorption of the polyimide avoided and reduces the defect density of the polyimide layer. Through the Use an organic etch mask for through etching Contacts in the polyimide layer can have flat etching angles be generated. The edges of the etching mask are on the Transfer polyimide. In this way, the can closing metallization achieve good edge coverage. The multi-layer wiring can thus be completed without voids will.
Im folgenden wird die Erfindung anhand eines Ausführungsbei spiels und der Fig. 1 bis 5 näher beschrieben.In the following the invention with reference to a game Ausführungsbei and FIGS . 1 to 5 will be described in more detail.
Dabei zeigenShow
die Fig. 1 bis 4 im Querschnitt die wichtigsten Stationen bei der Herstellung der erfindungsgemäßen Mehr lagenverdrahtung, Figs. 1 to 4 in cross section the most important stages in the manufacture of multilayer wiring according to the invention,
Fig. 5 zeigt die fertige Struktur nach einer leicht variierten Ausführungsform des Verfahrens. Fig. 5 shows the completed structure after a slightly varied embodiment of the method.
In Fig. 1 sind Leiterbahnen 2 der ersten Metallisierungsebene eines mikroelektronischen Bauelementes (zum Beispiel eines bipo laren gate-arrays) auf einer die Transistoren des Bauelements isolierenden SiO2-Schicht 1 angeordnet. In einem spin-on-Prozeß wird darauf eine Polyimidschicht 3 in einer Stärke von zum Bei spiel 1,3 µm aufgebracht. Durch kurzzeitige Temperaturerhöhung wird das Polyimid 3 "gebacken" (zyklisiert).In Fig. 1, tracks 2 are arranged in the first metallization of a microelectronic device (for example, a Bipo stellar gate arrays) on one of the component transistors insulating SiO 2 layer 1. In a spin-on process, a polyimide layer 3 is applied in a thickness of, for example, 1.3 µm. The polyimide 3 is “baked” (cyclized) by briefly increasing the temperature.
Fig. 2: Auf der eingeebneten Oberfläche wird nun ganzflächig eine Photolackschicht 4 aufgebracht (siehe Fig. 2) und struk turiert. An den für die späteren Durchkontaktierungen vorge sehenen Stellen ist der Photolack 4 bis auf die Polyimidschicht 3 abgetragen. Die Durchbrechungen weisen schräge Flanken 5 auf. Fig. 2: A photoresist layer 4 is now applied over the entire surface (see FIG. 2) and structured. At the locations provided for the later plated-through holes, the photoresist 4 is removed down to the polyimide layer 3 . The openings have inclined flanks 5 .
Fig. 3 zeigt die Struktur nach einem anisotropen RIBE (reakti ver Ionenstrahl) Ätzprozeß. Hierbei dient die Photolackstruktur 4 als Ätzmaske. Die schrägen Flanken 5 der Maske werden beim Ätzen der Polyimidschicht 3 beibehalten, bis in den geätzten Löchern die Oberfläche der Leiterbahnen 2 freigelegt ist. Fig. 3 shows the structure after an anisotropic RIBE (reactive ion beam) etching process. Here, the photoresist structure 4 serves as an etching mask. The oblique flanks 5 of the mask are retained during the etching of the polyimide layer 3 until the surface of the conductor tracks 2 is exposed in the etched holes.
Fig. 4: Nun entfernt man den übrigen Photolack 4 mit einem Lö sungsmittel. Dann wird ganzflächig in einem Plasma unterstütz ten CVD-Verfahren (PECVD) eine Siliziumnitridschicht 6 in einer Stärke von zum Beispiel 0,25 µm abgeschieden. Fig. 4: Now remove the remaining photoresist 4 with a solvent. A silicon nitride layer 6 is then deposited over the entire surface in a plasma-assisted CVD process (PECVD) in a thickness of, for example, 0.25 μm.
Anschließend wird das Bauelement bzw. die Leiterbahnen 2 mit einer Stromquelle verbunden, als Anode geschaltet und in einem zum Beispiel wäßrigen Elektrolytbad gegen eine Gegenelektrode elektrolysiert.Subsequently, the component or the conductor tracks 2 are connected to a current source, switched as an anode and electrolyzed in a, for example, aqueous electrolyte bath against a counter electrode.
Fig. 5 zeigt das Ergebnis dieser anodischen Oxidation. In den über den Leiterbahnen 2 liegenden Bereichen 7 ist die Silizium nitridschicht oxidiert. Die dadurch veränderten chemischen Ei genschaften bzw. das geänderte Ätzverhalten der oxidierten Be reiche 7 gegenüber der unveränderten Siliziumnitridschicht 6 er möglicht das Entfernen der Bereiche 7, wodurch in den Kontakt löchern die Leiterbahnen 2 freigelegt werden. Fig. 5 shows the result of anodic oxidation. The silicon nitride layer is oxidized in the regions 7 lying above the conductor tracks 2 . The resultant change in chemical characteristics or the modified egg etching the oxidized Be rich 7 relative to the unaltered silicon nitride layer 6 it enables the removal of the portions 7, whereby in the contact holes, the conductor tracks 2 are exposed.
Anschließend wird eine zweite Metallisierungsebene erzeugt. Wahl weise können gemäß der Lehre der Erfindung durch Wiederholung der Prozeßschritte weitere Metallisierungsebenen geschaffen wer den.A second metallization level is then generated. Choice can, according to the teaching of the invention, by repetition the process steps created additional levels of metallization the.
Fig. 6 zeigt in leichter Abänderung des Verfahrens eine ähnli che Struktur nach dem Entfernen der oxidierten Bereiche. Dabei wird jedoch noch vor dem Aufbringen der Polyimidschicht 3 zu nächst eine 20 µm starke PECVD-Siliziumnitridschicht 8 abge schieden. Die weiteren Schritte sind identisch. Nur werden bei der anisotropen Kontaktlochätzung nicht, wie in Fig. 3 ge zeigt, die Leiterbahnen 2 freigelegt, sondern nur bis zur Ni tridschicht 8 geätzt. Bei der anodischen Oxidation werden daher in den Bereichen 9 beide hier übereinander liegenden Nitrid schichten 8 und 6 oxidiert. Mit dieser Technik gelingt ein noch besseres Isolieren der Polyimidschicht 3, die nun vollständig von zwei Siliziumnitridschichten 6 und 8 umschlossen wird. Fig. 6 shows in a slight modification of the method a similar structure after the removal of the oxidized areas. In this case, however, before the application of the polyimide layer to the next, a 20 .mu.m thick PECVD silicon nitride layer 8 abge eliminated. 3 The next steps are identical. Only in the anisotropic contact hole etching, as is shown in FIG. 3, the conductor tracks 2 are not exposed, but only etched up to the nitride layer 8 . In the anodic oxidation, therefore, both nitride layers 8 and 6 lying here one above the other are oxidized in the regions 9 . This technique enables an even better insulation of the polyimide layer 3 , which is now completely enclosed by two silicon nitride layers 6 and 8 .
Claims (10)
- a) Aufbringen und Tempern einer Polyimidschicht (3),
- b) Durchführung einer Photolacktechnik (4) zur Definition der Durchkontaktierungen,
- c) Anisotrope Ätzung der Kontaktlöcher bzw. Vias in der Polyimidschicht (3) mit der Photolackstruktur (4) als Ätzmaske,
- d) Entfernen der restlichen Ätzmaske (4),
- e) ganzflächige Abscheidung einer Siliziumnitridschicht (6),
- f) anodische Oxidation der Siliziumnitridschicht (6) in den Be reichen (7), wo die Schicht die Böden der Kontaktlöcher be deckt,
- g) Entfernen der oxidierten Siliziumnitridbereiche (7) und
- h) Aufbringen der nächsten Metallisierungsebene.
- a) applying and annealing a polyimide layer ( 3 ),
- b) carrying out a photoresist technique ( 4 ) to define the plated-through holes,
- c) anisotropic etching of the contact holes or vias in the polyimide layer ( 3 ) with the photoresist structure ( 4 ) as an etching mask,
- d) removing the remaining etching mask ( 4 ),
- e) full-surface deposition of a silicon nitride layer ( 6 ),
- f) anodic oxidation of the silicon nitride layer ( 6 ) in the areas ( 7 ) where the layer covers the bottoms of the contact holes,
- g) removing the oxidized silicon nitride regions ( 7 ) and
- h) applying the next metallization level.
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DE19873728348 DE3728348A1 (en) | 1987-08-25 | 1987-08-25 | Multilayer wiring for VLSI semiconductor components |
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DE19873728348 DE3728348A1 (en) | 1987-08-25 | 1987-08-25 | Multilayer wiring for VLSI semiconductor components |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0632497A2 (en) * | 1993-07-02 | 1995-01-04 | Plessey Semiconductors Limited | Multichip module substrate structure |
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DE2541624C2 (en) * | 1975-09-18 | 1982-09-16 | Ibm Deutschland Gmbh, 7000 Stuttgart | Aqueous etching solution and method for etching polymer films or foils based on polyimide |
DE3237026A1 (en) * | 1981-10-13 | 1983-04-21 | Monolithic Memories, Inc., 94086 Sunnyvale, Calif. | SEMICONDUCTOR STRUCTURE AND METHOD FOR THE PRODUCTION THEREOF - PRODUCTION OF PLANAR TRANSISTORS USING POLYIMIDE FOR DIELECTRIC INSULATION - |
DE2441170C2 (en) * | 1973-09-07 | 1984-07-12 | N.V. Philips' Gloeilampenfabrieken, Eindhoven | Method for manufacturing a semiconductor device |
EP0177845A1 (en) * | 1984-09-28 | 1986-04-16 | Siemens Aktiengesellschaft | Integrated circuit with multilayer wiring and method for manufacturing it |
-
1987
- 1987-08-25 DE DE19873728348 patent/DE3728348A1/en not_active Withdrawn
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DE2441170C2 (en) * | 1973-09-07 | 1984-07-12 | N.V. Philips' Gloeilampenfabrieken, Eindhoven | Method for manufacturing a semiconductor device |
DE2541624C2 (en) * | 1975-09-18 | 1982-09-16 | Ibm Deutschland Gmbh, 7000 Stuttgart | Aqueous etching solution and method for etching polymer films or foils based on polyimide |
DE3237026A1 (en) * | 1981-10-13 | 1983-04-21 | Monolithic Memories, Inc., 94086 Sunnyvale, Calif. | SEMICONDUCTOR STRUCTURE AND METHOD FOR THE PRODUCTION THEREOF - PRODUCTION OF PLANAR TRANSISTORS USING POLYIMIDE FOR DIELECTRIC INSULATION - |
EP0177845A1 (en) * | 1984-09-28 | 1986-04-16 | Siemens Aktiengesellschaft | Integrated circuit with multilayer wiring and method for manufacturing it |
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Title |
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US-Z:IBM Technical Disclosure Bulletin, Bd.25, Nr.1, Juni 1987, S.303 * |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0632497A2 (en) * | 1993-07-02 | 1995-01-04 | Plessey Semiconductors Limited | Multichip module substrate structure |
EP0632497A3 (en) * | 1993-07-02 | 1995-12-06 | Plessey Semiconductors Ltd | Multichip module substrate structure. |
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