DE3667281D1 - CATALYST FOR THE PRODUCTION OF CARBONIC ACID ANHYDRIDES. - Google Patents

CATALYST FOR THE PRODUCTION OF CARBONIC ACID ANHYDRIDES.

Info

Publication number
DE3667281D1
DE3667281D1 DE8686307562T DE3667281T DE3667281D1 DE 3667281 D1 DE3667281 D1 DE 3667281D1 DE 8686307562 T DE8686307562 T DE 8686307562T DE 3667281 T DE3667281 T DE 3667281T DE 3667281 D1 DE3667281 D1 DE 3667281D1
Authority
DE
Germany
Prior art keywords
catalyst
vanadium
oxide
production
carbonic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE8686307562T
Other languages
German (de)
Inventor
Ramzi Yanni Saleh
Israel Ephraim Wachs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of DE3667281D1 publication Critical patent/DE3667281D1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)

Abstract

An improved catalyst for molecular oxidation of a hydrocarbon to form the corresponding carboxylic anhydrides is prepared by depositing on titanium dioxide solids in the anatase form a continuous monolayer of a source of zirconium dioxide, calcining to convert the zirconium oxide source into the oxide then depositing at least one vanadium compound which is convertable into vanadium oxide upon heating and calcining the vanadium-deposited solids to convert the vanadium compound into vanadium oxide, the catalyst is particularly useful in preparing phthalic anhydride.
DE8686307562T 1985-10-02 1986-10-01 CATALYST FOR THE PRODUCTION OF CARBONIC ACID ANHYDRIDES. Expired - Lifetime DE3667281D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/782,966 US4728744A (en) 1985-10-02 1985-10-02 Catalysts for preparation of aromatic carboxylic anhydrides

Publications (1)

Publication Number Publication Date
DE3667281D1 true DE3667281D1 (en) 1990-01-11

Family

ID=25127753

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8686307562T Expired - Lifetime DE3667281D1 (en) 1985-10-02 1986-10-01 CATALYST FOR THE PRODUCTION OF CARBONIC ACID ANHYDRIDES.

Country Status (7)

Country Link
US (1) US4728744A (en)
EP (1) EP0222487B1 (en)
JP (1) JPS6291243A (en)
AT (1) ATE48422T1 (en)
BR (1) BR8604772A (en)
CA (1) CA1267654A (en)
DE (1) DE3667281D1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4864036A (en) * 1984-06-29 1989-09-05 Exxon Research & Engineering Company Process for preparing aromatic carboxylic anhydride
US4831164A (en) * 1985-10-02 1989-05-16 Exxon Chemical Patents Inc. Process of preparing carboxylic anhydride
US4931572A (en) * 1989-05-17 1990-06-05 Exxon Chemical Patents Inc. Aromatic carboxylic anhydride catalyst
US5169821A (en) * 1991-11-14 1992-12-08 Exxon Research And Engineering Company Method for stabilizing titania supported cobalt catalyst and the catalyst for use in Fischer-Tropsch process
GB9213140D0 (en) * 1992-06-20 1992-08-05 Tioxide Specialties Ltd Preparation of anatase titanium dioxide
EP1145762A1 (en) * 2000-04-11 2001-10-17 dmc2 Degussa Metals Catalysts Cerdec AG Process for the preparation of a vanadia SCR-catalyst supported on titania
US8137646B2 (en) * 2007-03-27 2012-03-20 The Shepherd Color Company Non-chromate corrosion inhibitor formulas based on zirconium vanadium oxide compositions
KR100917734B1 (en) * 2007-07-19 2009-09-21 삼성에스디아이 주식회사 Pouch Type Lithium Secondary Battery

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3306915A (en) * 1963-04-03 1967-02-28 Sinclair Research Inc Oxidation of aromatic compounds
US3507813A (en) * 1963-04-03 1970-04-21 Sinclair Research Inc Oxidation catalyst comprising fused mixture of oxides of vanadium,zirconium and lanthanide series metal
DE1261117B (en) * 1963-10-30 1968-02-15 Basf Ag Process for the production of carrier catalysts
NL134884C (en) * 1965-05-18
FR1501769A (en) * 1966-07-04 1967-11-18 Commissariat Energie Atomique Free radicals of the nitroxide type
BE723887A (en) * 1967-11-17 1969-05-14
US3721683A (en) * 1969-06-13 1973-03-20 Teijin Chemicals Ltd Process for the preparation of aromatic carboxylic anhydrides
DE2159441A1 (en) * 1971-12-01 1973-06-07 Basf Ag Vanadium pentoxide/zirconium dioxide catalyst - for effective use in oxidn reactions
DE2200913A1 (en) * 1972-01-10 1973-07-19 Basf Ag Phthalic anhydride prepn - using oxidation catalyst containing vanadium pentoxide, zirconium dioxide and optionally titan
DE2212964C3 (en) * 1972-03-17 1980-01-31 Basf Ag, 6700 Ludwigshafen Supported catalyst containing vanadium pentoxide, titanium dioxide and optionally zirconium dioxide, phosphorus and other metal oxides
US3926846A (en) * 1972-08-25 1975-12-16 Nippon Catalytic Chem Ind Catalysts for the preparation of phthalic anhydride
DE2260615A1 (en) * 1972-12-12 1974-06-20 Basf Ag SUPPORT CATALYST FOR THE OXIDATION OF O-XYLOL OR NAPHTHALINE TO PHTHALIC ANHYDRIDE
DE2909670A1 (en) * 1979-03-12 1980-10-02 Basf Ag METHOD FOR PRODUCING SHELL CATALYSTS
DE2914683A1 (en) * 1979-04-11 1980-10-16 Basf Ag VANADIUM AND TITANIUM AND / OR ZIRCONIZED CARRIER CATALYST
DE2925682A1 (en) * 1979-06-26 1981-01-29 Basf Ag VANADINE PENTOXIDE, TITANIUM DIOXIDE, PHOSPHORUS, RUBIDIUM AND / OR CAESIUM AND Possibly. ZIRCONDIOXIDE CONTAINING CARRIER CATALYST
US4582911A (en) * 1984-06-29 1986-04-15 Exxon Research & Engineering Co. Molecular oxidation of aromatic hydrocarbons to the corresponding anhydrides using an improved catalyst
US4582912A (en) * 1984-10-01 1986-04-15 Exxon Research & Engineering Co. Process for preparing carboxylic anhydride using improved catalysts

Also Published As

Publication number Publication date
BR8604772A (en) 1987-06-30
ATE48422T1 (en) 1989-12-15
EP0222487A1 (en) 1987-05-20
EP0222487B1 (en) 1989-12-06
US4728744A (en) 1988-03-01
CA1267654A (en) 1990-04-10
JPS6291243A (en) 1987-04-25

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee