DE30746C - Process for industrial use! extraction of sulfur from hydrogen sulfide - Google Patents
Process for industrial use! extraction of sulfur from hydrogen sulfideInfo
- Publication number
- DE30746C DE30746C DENDAT30746D DE30746DA DE30746C DE 30746 C DE30746 C DE 30746C DE NDAT30746 D DENDAT30746 D DE NDAT30746D DE 30746D A DE30746D A DE 30746DA DE 30746 C DE30746 C DE 30746C
- Authority
- DE
- Germany
- Prior art keywords
- sulfur
- hydrogen sulfide
- metal
- sulphate
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 10
- 229910052717 sulfur Inorganic materials 0.000 title claims description 10
- 239000011593 sulfur Substances 0.000 title claims description 10
- RWSOTUBLDIXVET-UHFFFAOYSA-N dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims description 9
- 238000000034 method Methods 0.000 title claims description 7
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title claims description 6
- 238000000605 extraction Methods 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 2
- 238000007664 blowing Methods 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- YALHCTUQSQRCSX-UHFFFAOYSA-N S.OS(O)(=O)=O Chemical group S.OS(O)(=O)=O YALHCTUQSQRCSX-UHFFFAOYSA-N 0.000 claims 1
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 230000008929 regeneration Effects 0.000 claims 1
- 238000011069 regeneration method Methods 0.000 claims 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L Calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 229910052602 gypsum Inorganic materials 0.000 description 3
- 239000010440 gypsum Substances 0.000 description 3
- 235000011132 calcium sulphate Nutrition 0.000 description 2
- 239000001175 calcium sulphate Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- JGIATAMCQXIDNZ-UHFFFAOYSA-N Calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 125000004430 oxygen atoms Chemical group O* 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/06—Preparation of sulfur; Purification from non-gaseous sulfides or materials containing such sulfides, e.g. ores
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
(Oesterr.-Schlesien).(Eastern Silesia).
Das Verfahren besteht wesentlich darin, dafs man den. Schwefelwasserstoff bei gleichzeitiger Einwirkung von Hitze durch Sulfate von Alkalien oder alkalischen Erden streichen läfst, wobei der Sauerstoff dieser Salze sich mit dem Wasserstoff des Schwefelwasserstoffes zu Wasser verbindet, während das betreffende Schwefelmetall zurückbleibt und freier Schwefel abfliefst. Durch darauf folgendes Einblasen von atmosphärischer Luft bei fortdauernder Einwirkung von Hitze kann das Schwefelmetall wieder zu Sulfat oxydirt werden, welches neuerlich Verwendung findet. The main thing is that the Hydrogen sulfide at the same time Can be exposed to heat from sulphates of alkalis or alkaline earths, the oxygen of these salts and the hydrogen of the hydrogen sulphide to form water connects, while the sulfur metal in question remains and free sulfur flows off. By subsequently blowing in atmospheric air with continued exposure The sulfur-metal can be oxidized again by heat to sulfate, which is used again.
Bei der praktischen Durchführung dieses Processes, welcher zur Verwerthung der bei
der Sodafabrikation nach dem Leblanc'schen Verfahren sich ergebenden Rückstände besondere
Vortheile bietet, wird der zu verarbeitende Schwefelwasserstoff durch ein zur Rothglut erhitztes,
vorzugsweise1 mit Gypsstücken gefülltes Röhrensystem geleitet, dessen anderes Ende mit
einem Condensator für den flüssigen Schwefel in Verbindung steht. Die hierbei stattfindende
Reaction wird durch folgende Gleichung ausgedrückt :
Ca S O4 + 4 H2 S — Ca S ■+- 4 H2 O + 4 S. In the practical implementation of this process, which offers particular advantages for the recovery of the residues resulting from the production of soda according to the Leblanc method, the hydrogen sulfide to be processed is passed through a system of pipes, preferably one filled with pieces of gypsum, which is heated to a red ember and preferably filled with pieces of gypsum a condenser for the liquid sulfur is in connection. The reaction that takes place is expressed by the following equation:
Ca S O 4 + 4 H 2 S - Ca S ■ + - 4 H 2 O + 4 S.
Um bei dem Processe'jede Möglichkeit einer Verbindung des freiwerdenden Sauerstoffes mit dem Schwefel hinten anzuhalten, leitet man beständig einen Ueberschufs an Schwefelwasserstoff zu, so dafs jedes Sauerstoffatom in statu nascendi immer eine genügende Menge der gröfsere Affinität besitzenden Wasserstoffatome vorfindet. Der auf diese Weise in die Condensationskammern gelangte Schwefelwasserstoff wird wieder in die zur Production dieses Gases dienende Lauge geleitet und so weiter verarbeitet. In order to prevent any possibility of a connection between the released oxygen and the sulfur in the process, an excess of hydrogen sulfide is constantly supplied, so that every oxygen atom in statu nascendi always finds a sufficient quantity of the hydrogen atoms with greater affinity. The hydrogen sulphide that got into the condensation chambers in this way is fed back into the liquor used for the production of this gas and processed further.
Ist sämmtlicher Gyps zu Schwefelcalcium reducirt, so leitet man das zu zersetzende Schwefelwasserstoffgas durch einen nebenstehenden Apparat gleicher Einrichtung, in welchem sich der Procefs in gleicher Weise vollzieht, während man in den ersten Apparat atmosphärische Luft einbläst, um ■ das Schwefelcalcium wieder zu Calciumsulfat zu oxydiren.When all the gypsum is reduced to calcium sulphide, that which is to be decomposed is passed on Hydrogen sulfide gas through an adjacent apparatus of the same facility in which the process takes place in the same way, while the first apparatus is atmospheric Air is blown in to re-oxidize the calcium sulphate to calcium sulphate.
Behufs Verwerthung der bedeutenden Menge von Wärme, welche bei diesem Oxydationsprocesse frei wird, sind die beiden im Vorstehenden erwähnten zusammengehörigen Röhrensysteme so mit einander verbunden, dafs die in einem Röhrensystem freiwerdende Wärme das Alkali- oder Erdalkalisulfat im anderen Röhrensystem erhitzt.For the purpose of utilizing the considerable amount of heat produced in this process of oxidation becomes free, are the two pipe systems mentioned above that belong together so connected with one another that the heat released in one system of pipes dissolves the alkali or alkaline earth sulphate in the other Tubular system heated.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE30746C true DE30746C (en) |
Family
ID=306855
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT30746D Expired - Lifetime DE30746C (en) | Process for industrial use! extraction of sulfur from hydrogen sulfide |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE30746C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2813744A1 (en) * | 1977-03-31 | 1978-10-12 | Electricity Council | METHOD AND DEVICE FOR DRYING MATERIAL |
-
0
- DE DENDAT30746D patent/DE30746C/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2813744A1 (en) * | 1977-03-31 | 1978-10-12 | Electricity Council | METHOD AND DEVICE FOR DRYING MATERIAL |
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