DE306220C - - Google Patents
Info
- Publication number
- DE306220C DE306220C DENDAT306220D DE306220DA DE306220C DE 306220 C DE306220 C DE 306220C DE NDAT306220 D DENDAT306220 D DE NDAT306220D DE 306220D A DE306220D A DE 306220DA DE 306220 C DE306220 C DE 306220C
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen sulfide
- carbon disulfide
- carbon
- retort
- muffle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- QGJOPFRUJISHPQ-UHFFFAOYSA-N carbon bisulphide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims description 12
- RWSOTUBLDIXVET-UHFFFAOYSA-N dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 7
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 7
- 239000007789 gas Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/70—Compounds containing carbon and sulfur, e.g. thiophosgene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMTPATENT OFFICE
Bei der Herstellung von Schwefelkohlenstoff aus Schwefel und Kohle bilden sich neben Schwefelkohlenstoff auch erhebliche Mengen von Schwefelwasserstoff, welche, ins Freie gelassen, sich unangenehm und schädlich bemerkbar machen. In the manufacture of carbon disulfide from sulfur and coal form alongside Carbon disulfide also contains considerable amounts of hydrogen sulfide, which, if released into the open, make themselves uncomfortable and harmful.
Um dieses Gas unschädlich zu machen, hat man es in einem besonderen Ofen verbrannt und die gebildete schweflige Säure durch Wasser ausgewaschen.To make this gas harmless, it was burned in a special furnace and the sulphurous acid formed is washed out by water.
Das die schweflige Säure enthaltende Wasser kann jedoch wiederum zu Schwierigkeiten Anlaß geben. Gemäß vorliegender Erfindung werden diese Übelstände beseitigt und der Schwefelwasserstoff nutzbar gemacht, indem er ebenfalls in Schwefelkohlenstoff verwandelt wird. Zu diesem Zwecke wird das Gas, welches den Apparat nach der Kondensation des Schwefelkohlenstoffes verläßt und welches den Schwefelwasserstoff enthält, in einer Retorte, Muffel o. dgl. mit glühendem Kohlenstoff bzw. Holzkohle behandelt, wodurch der Schwefelwasserstoff nach folgender Formel umgewandelt wird-:However, the water containing the sulphurous acid can in turn cause difficulties To give reason. According to the present invention, these inconveniences are eliminated and the Made hydrogen sulfide usable by also converting it into carbon disulfide will. For this purpose, the gas, which the apparatus after the condensation of the Carbon disulfide and which contains the hydrogen sulfide, in a retort, Muffle o. The like. Treated with red-hot carbon or charcoal, whereby the hydrogen sulfide is converted according to the following formula:
2 H2S + C =2 H 2 S + C =
2 H2.2 H 2 .
Das nach der Kondensation des Schwefelkohlenstoffes verbleibende, von Schwefelwasserstoff befreite Wasserstoffgas kann nachher zur Beheizung der Retorte bzw. Muffel verwendet werden, oder man kann es auch zu anderen Zwecken verwenden bzw. gewinnen.The remaining after the condensation of the carbon disulfide, of hydrogen sulfide The liberated hydrogen gas can then be used to heat the retort or muffle or you can use it for other purposes or win it.
Das Verfahren läßt sich auch mit anderen Prozessen verbinden, bei denen Schwefelwasserstoff entwickelt wird. ,The process can also be combined with other processes that use hydrogen sulfide is being developed. ,
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE306220C true DE306220C (en) |
Family
ID=559668
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT306220D Active DE306220C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE306220C (en) |
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0
- DE DENDAT306220D patent/DE306220C/de active Active
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