DE289065C - - Google Patents
Info
- Publication number
- DE289065C DE289065C DENDAT289065D DE289065DA DE289065C DE 289065 C DE289065 C DE 289065C DE NDAT289065 D DENDAT289065 D DE NDAT289065D DE 289065D A DE289065D A DE 289065DA DE 289065 C DE289065 C DE 289065C
- Authority
- DE
- Germany
- Prior art keywords
- gas
- hydrocarbons
- hydrogen
- molecular weight
- gaseous hydrocarbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 150000002430 hydrocarbons Chemical class 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000004071 soot Substances 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- 238000000605 extraction Methods 0.000 claims 1
- 125000004435 hydrogen atoms Chemical class [H]* 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 210000003800 Pharynx Anatomy 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 230000003197 catalytic Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001105 regulatory Effects 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002641 tar oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- ΛΙ 289065 KLASSE 12«. GRUPPE- ΛΙ 289065 CLASS 12 «. GROUP
Zusatz zum Patent 257715.Addition to patent 257715.
. Patentiert im Deutschen Reiche vom 7. Dezember 1912 ab. Längste Dauer: 4. Juni 1925.. Patented in the German Empire on December 7, 1912. Longest duration: June 4, 1925.
Gegenstand des Patents 257715 ist ein Verfahren zur Herstellung von Wasserstoff, das darin besteht, daß man· Dämpfen von Rohpetroleum, Handelspetroleum, Teerölen o. dgl. bei einer Temperatur von 1200 bis 1350° 18,1 g Kalorien für je 16 g Gas zuführt.The subject of the patent 257715 is a process for the production of hydrogen, the consists of steaming crude kerosene, commercial kerosene, tar oils or the like. at a temperature of 1200 to 1350 ° 18.1 g Calories for every 16 g of gas.
Das Verfahren wird derart ausgeführt, daß man die Kohlenwasserstoffdämpfe in einer verhältnismäßig engen und langen Röhre auf eine Temperatur von 1200 bis 13500 erhitzt und durch Regulierung der zugeführten Dämpfe oder durch Abmessen der entsprechenden Rohrlänge dafür Sorge trägt, daß die zur vollständigen Zersetzung in reinen Wasserstoff und Kohlenstoff, der im Einklang mit dem Wortlaut des Hauptpatents in Form von Ruß erhalten wird, verlangte Wärmemenge auch dem gesamten Rohrinhalt zugeführt wird.The process is carried out in such a way that the hydrocarbon vapors are heated to a temperature of 1200 to 1350 0 in a relatively narrow and long tube and by regulating the supplied vapors or by measuring the appropriate length of the tube, care is taken to ensure that they are completely decomposed into pure hydrogen and carbon, which is obtained in accordance with the wording of the main patent in the form of soot, the required amount of heat is also supplied to the entire contents of the pipe.
Es wurde nun gefunden, daß man nicht auf die Verwendung flüssiger Kohlenwasserstoffe beschränkt ist, sondern daß man mit besonderem Vorteil auch gasförmige Kohlenwasserstoffe, wie sie z. B. die Natur in den reichlich vorhandenen Gasquellen liefert, oder wie solche z. B. künstlich in der Leuchtgas-, Generatorgas- usw. Industrie dargestellt werden, verwenden kann.It has now been found that there is no need to use liquid hydrocarbons is limited, but that one with particular advantage also gaseous hydrocarbons, as z. B. nature in the supplies abundant gas sources, or such as such. B. artificially in the coal gas, Generator gas etc. industry can be represented.
Die bei gewöhnlicher Temperatur an sichThe ones at ordinary temperature per se
gasförmigen Kohlenwasserstoffe bestehen, gleich welcher Herkunft, aus Kohlenwasserstoffen von niederem Molekulargewicht, während die aus Petroleum usw. gewonnenen Kohlenwasserstoffdämpfe aus Kohlenwasserstoffen von hohem, sogar beträchtlich höherem Molekulargewicht zusammengesetzt sind.gaseous hydrocarbons exist, the same which origin, from hydrocarbons of low molecular weight, while those from Petroleum, etc. obtained hydrocarbon vapors from hydrocarbons of high, are composed of even considerably higher molecular weights.
Es war aber nun keineswegs ohne weiteres vorauszusehen oder naheliegend, an Stelle der zu zerlegenden Kohlenwasserstoffdämpfe von hohem Molekulargewicht und komplizierterem, chemischem Aufbau einfach gebaute gasförmige Kohlenwasserstoffe niedrigen Molekulargewichts in dem Verfahren des Hauptpatents zu verwenden. Es sind im allgemeinen chemische Verbindungen mit zunehmendem Molekulargewicht leichter zu zersetzen7; es mußte daher a priori angenommen werden, daß die Petrol-usw. Dämpfe nach Patent 257715 sich rascher und leichter zerlegen lassen als etwa Methan, Äthan usw., indem die einmal begonnene Reaktion aus irgendwelchen Gründen, z. B. aus katalytischen Einflüssen, leichter vorwärts schreitet und die Zerlegung erleichtert. Das vorliegende Verfahren geht unter den nämlichen Bedingungen wie das des Hauptpatents vor sich; sollte das erhaltene Gas infolge Verunreinigung des Ausgangsmaterials mit Kohlenoxyd oder Kohlensäure in geringerem Maße verunreinigt sein, so kann eine Reinigung mit den zur Absorption geeigneten Mitteln eintreten.However, it was by no means foreseeable or obvious to use simply constructed gaseous hydrocarbons of low molecular weight in the process of the main patent in place of the hydrocarbon vapors of high molecular weight and complex, chemical structure to be broken down. In general, chemical compounds are easier to decompose with increasing molecular weight 7 ; it had therefore to be assumed a priori that the petrol etc. Vapors according to patent 257715 can be broken down more quickly and easily than methane, ethane, etc. B. from catalytic influences, progresses more easily and facilitates the decomposition. The present process takes place under the same conditions as those of the main patent; Should the gas obtained be contaminated to a lesser extent as a result of contamination of the starting material with carbon dioxide or carbonic acid, purification by means suitable for absorption can take place.
Man kann die Reaktion auch dadurch erleichtern, daß man dem zu zerlegenden Gase oder Gasgemisch noch Wasserdampf oder Sauer-The reaction can also be facilitated by adding the gases to be decomposed or gas mixture, steam or acid
stoff oder beide zugleich zuführt. Dies empfiehlt sich jedoch nur dann, wenn die Nebenbildung von Kohlenoxyd, also die Erzeugung eines kehlenoxydhaltigen Wasserstoffgases nicht unerwünscht ist.material or both at the same time. However, this is only recommended if the secondary education of carbon oxide, i.e. the production of a hydrogen gas containing throat oxide is undesirable.
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE289065C true DE289065C (en) |
Family
ID=544128
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT289065D Active DE289065C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE289065C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6797147B2 (en) | 2001-10-02 | 2004-09-28 | Henkel Kommanditgesellschaft Auf Aktien | Light metal anodization |
-
0
- DE DENDAT289065D patent/DE289065C/de active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6797147B2 (en) | 2001-10-02 | 2004-09-28 | Henkel Kommanditgesellschaft Auf Aktien | Light metal anodization |
| US6916414B2 (en) | 2001-10-02 | 2005-07-12 | Henkel Kommanditgesellschaft Auf Aktien | Light metal anodization |
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