DE2801787A1 - PEST CONTROL - Google Patents
PEST CONTROLInfo
- Publication number
- DE2801787A1 DE2801787A1 DE19782801787 DE2801787A DE2801787A1 DE 2801787 A1 DE2801787 A1 DE 2801787A1 DE 19782801787 DE19782801787 DE 19782801787 DE 2801787 A DE2801787 A DE 2801787A DE 2801787 A1 DE2801787 A1 DE 2801787A1
- Authority
- DE
- Germany
- Prior art keywords
- triazophos
- binapacryl
- weight ratio
- active ingredient
- pest control
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
_ 2αϋ ι_ 2αϋ ι
SCHÄDLINGSBEKÄMPFUNGSMITTELPEST CONTROL PRODUCTS
Gegenstand der Erfindung sind Schädlingsbekämpfungsmittel -insbesondere zur Bekämpfung von Akariden in allen Entwicklungsstadien -die gekennzeichnet sind durch einen Gehalt an 0,0-Diäthyl-(1-phenyl-1,2,4-triazol-3-yl)-thionophosphat (common name: Triazophos) in Kombination mit (2-sec.-Butyl-4,6-dinitrophenyl) -3 ,3-dimethylacrylat (commcn name: Binapacryl).The invention relates to pesticides, in particular for combating acarids in all stages of development -which are characterized by a content of 0,0-diethyl- (1-phenyl-1,2,4-triazol-3-yl) -thionophosphate (common name: Triazophos) in combination with (2-sec-butyl-4,6-dinitrophenyl) -3, 3-dimethyl acrylate (common name: Binapacryl).
Es ist bereits bekannt, daß sowohl Triazophos (I)It is already known that both Triazophos (I)
P - OC9H,- (DT-PS 1 670 876)P - OC 9 H, - (DT-PS 1 670 876)
als auch Binapacryl (II)as well as binapacryl (II)
0-C0-0-C0-
NONO
0-CO-CH=C(CH3)0-CO-CH = C (CH 3 )
(DT-PS 1 099 787)(DT-PS 1 099 787)
akarizide Wirksamkeit besitzen.Have acaricidal activity.
Es wurde nun gefunden, daß Kombinationen aus Triazophos und Binapacryl sich durch eine synergistische Wirksamkeit gegen Akariden und deren Eier - darunter auch Phosphorsäureesterresistente Stämme - auszeichnen. Das Mischungsverhältnis Triazophos : Binapacryl kann dabei im Bereich von 1 : 10 bis 10 : 1 liegen und beträgt vorzugsweise 1 : 1 bis 10 : 1.It has now been found that combinations of Triazophos and Binapacryl are synergistic against Acarids and their eggs - including those resistant to phosphoric acid esters Tribes - distinguish. The mixing ratio Triazophos: Binapacryl can be in the range from 1:10 to 10: 1 and is preferably 1: 1 to 10: 1.
Die erfindungsgemäßen Wirkstoffmischungen können in Form üblicher Zubereitungen wie Emulsionskonzentraten, ÜLV-Lösungen, Dispersionen, Spritzpulvern, Stäuben oder Granulaten formuliertThe active ingredient mixtures according to the invention can be in the form of more conventional ones Preparations such as emulsion concentrates, ÜLV solutions, dispersions, wettable powders, dusts or granules are formulated
909829/0385909829/0385
werden. Der Gesamtwirkstoffgehalt der marktfähigen Formulierungen beträgt dann ca. 10 bis 90 Gew.-?;. Daneben enthalten sie die üblichen Haft-, Netz-, Dispergier-, Füll- und Trägerstoffe. Für den praktischen Einsatz kommen aber auch Tankmischungen aus den einzelnen Wirkstoffkomponenten in entsprechenden Mischungsverhältnissen in Frage.will. The total active ingredient content of the marketable formulations is then approx. 10 to 90 wt .-?;. They also contain the usual adhesives, wetting agents, dispersants, fillers and carriers. However, tank mixes are also sufficient for practical use the individual active ingredient components in appropriate mixing ratios in question.
Emulgierbare Konzentrate werden durch Auflösen der Wirkstoffe in geeigneten organischen Lösungsmitteln erhalten. Als Lösungsmittel hierfür kommen beispielsweise in Frage: Toluol, Xylole, Chlorbenzole und andere höher siedende Aromaten, ferner Benzine oder Paraffinöle, Cyclohexanon, Dime thy lfoi'mamid, Dimethylsulfoxid, Tetrahydrofuran, Dioxan, Diacetonalkohol, Äthylacetat, Isophoron.Emulsifiable concentrates are obtained by dissolving the active ingredients in suitable organic solvents. As a solvent for example: toluene, xylenes, Chlorobenzenes and other higher-boiling aromatics, also gasoline or paraffin oils, cyclohexanone, dimethy lfoi'mamide, dimethyl sulfoxide, Tetrahydrofuran, dioxane, diacetone alcohol, ethyl acetate, isophorone.
Im Falle von "Ultra-Low-Volume" (ULV)-Formulierungen wendet man zweckmäßigerweise hochsiedende Lösungsmittel an, um die Verdunstungsrate beim Versprühen gering zu halten, z. B. höher siedende Paraffine, Ketone oder Estei" sowie evtl. pflanzliche öle.In the case of "Ultra-Low-Volume" (ULV) formulations, use is made expediently high-boiling solvents to reduce the evaporation rate to keep low when spraying, z. B. higher-boiling paraffins, ketones or Estei "as well as possibly vegetable oils.
Als Trägermaterialien für feste Formulierungen kommen vor allem mineralische Stoffe in Frage, z. B. Kieselsäuren und Silikate wie Kieselgur, Kaoline, Tonerden oder Talkum, Kreide oder Kieselkreiden, aber auch Zubereitungen dieser mineralischen Stoffe mit Hilfszusätzen wie Stearaten, Alkyl-, Aryl- oder Alkylarylsulfonaten, Ligninsulfonaten und ähnlichem. Darüber hinaus können weitere Netz-, Dispergier- und Haftstoffe sowie Mahlhilfsmittel der verschiedensten Art zum Zwecke der anwendungsspezifischen Formulierung verwendet werden.As carrier materials for solid formulations, especially mineral substances come into question, eg. B. Silicas and Silicates such as kieselguhr, kaolins, clays or talc, chalk or silica chalks, but also preparations of these mineral ones Substances with auxiliary additives such as stearates, alkyl, aryl or Alkyl aryl sulfonates, lignosulfonates and the like. In addition, other wetting agents, dispersants and adhesives can be used and grinding aids of the most varied types for the purpose of application-specific formulation can be used.
Vor der eigentlichen Anwendung werden die genannten Emulsionskonzentrate, Spritzpulver oder Dispersionen mit einem geeigneten Verdünnungsmittel - gewöhnlich Wasser - weiter verdünnt und so auf eine für praktische Anwendung geeignete Konzentration gebracht. Diese variiert wie üblich mit der Anwendungsart undBefore the actual application, the emulsion concentrates, wettable powders or dispersions mentioned are mixed with a suitable Diluent - usually water - further diluted to a concentration suitable for practical use brought. As usual, this varies with the type of application and
909829/0385909829/0385
-A--A-
den Klimabedingungen, insbesondere Temperatur und Feuchtigkeit, liegt jedoch allgemein, z. B. bei Spritzpulvern, im Bereich von 0,005 bis 1,0 Gew.-% Gesamtwirkstoffanteil.However, the climatic conditions, especially temperature and humidity, is generally, e.g. B. in wettable powders, in the area from 0.005 to 1.0% by weight of total active ingredient.
Die erfindungsgemäßen Schädlingsbekämpfungsmittel besitzen eine ausgezeichnete Wirkung gegen Schadinsekten, gegen Akariden und deren Eier und können in weit geringeren Mengen bzw. Konzentrationen mit Erfolg eingesetzt werden als Schädlingsbekämpfungsmittel, die nur eine der beiden Wirkstoffkomponenten allein enthalten.The pesticides according to the invention have a excellent action against insect pests, acarids and their eggs and can be used in far lower amounts or concentrations Can be used successfully as a pesticide containing only one of the two active ingredient components alone contain.
Darüber hinaus sind die erfindungsgemäßen Mittel auch gegen Phosphorsäureester-resistente Akaridenstämme wirksam.In addition, the agents according to the invention are also against Acarid strains resistant to phosphoric acid ester are effective.
909829/0385909829/0385
FormulierungsbeispieleFormulation examples
1. Emulsionskonzentrat (Gew.-Verhältnis Triazophos : Binapacryl1. Emulsion concentrate (weight ratio Triazophos: Binapacryl
= 10 : 1)= 10: 1)
Binapacryl
Triazophos
Phenylsulfonat Ca Emuisogen EL 400^ Sapogenat T 500®
XylolBinapacryl
Triazophos
Phenylsulfonat Ca Emuisogen EL 400 ^ Sapogenat T 500® Xylene
4,0 40,04.0 40.0
5,05.0
7,47.4
1,6 42,01.6 42.0
100,0 Gew.-#100.0 wt .- #
2. Emulsionskonzentrat (Gew.-Verhältnis Triazophos : Binapacryl2. Emulsion concentrate (weight ratio Triazophos: Binapacryl
= 1 : 10)= 1: 10)
Binapacryl
Triazophos
Phenylsulfonat Ca Emuisogen EL 360 " XylolBinapacryl
Triazophos
Phenylsulfonate Ca Emuisogen EL 360 "Xylene
40,040.0
4,04.0
3,03.0
2,0 51,02.0 51.0
100,0 Gew.-#100.0 wt .- #
y09829/0385y09829 / 0385
Emulsionskonzentrate der Wirkstoffe Triazophos und Binapacryl wurden mit Wasser so verdünnt, daß die in folgenden Beispielen angegebenen Wirkstoffkonzentrationen vorlagen. Diese Wirkstoffpräparationen wurden auf mit Vollpopulationen der jeweiligen Schädlinge stark besetzte Bohnenpflanzen (Phaseolus vulgaris) durch Spritzen bis zum beginnenden Abtropfen gleichmäßig verteilt. Nach Antrocknung der Spritzbeläge wurden die Pflanzen im Gewächshaus aufgestellt. Die Auswertung erfolgte jeweils 8 Tage nach der Behandlung durch mikroskopische Kontrolle.Emulsion concentrates of the active ingredients Triazophos and Binapacryl were diluted with water so that the following examples indicated drug concentrations were available. These active ingredient preparations were on bean plants (Phaseolus vulgaris) heavily populated with full populations of the respective pests evenly distributed by spraying until it begins to drain. After the spray coatings had dried on, the plants became placed in the greenhouse. The evaluation was carried out 8 days after the treatment by microscopic control.
Schädlingsstamm: Gemeine Spinnmilbe (Tetranychus urticae),Pest strain: Common spider mite (Tetranychus urticae),
normal sensibel
Gewichtsverhältnis Triazophos : Binapacryl = 1 : 10normally sensitive
Triazophos: Binapacryl weight ratio = 1:10
der SpritzbrüheWt .- $ AS in
the spray mixture
in io AbtötungAcaricidal effect
in io mortification
+ Binapacrvl
Triazophos
BinapacrylTriazophos
+ Binapacrvl
Triazophos
Binapacryl
+ 0,00075
0,000075
0,000750.000075
+ 0.00075
0.000075
0.00075
50
1092
50
10
909829/0385909829/0385
Schädlingsstamm: Gemeine Spinnmilbe (Tetranychus urticae),Pest strain: Common spider mite (Tetranychus urticae),
"Baardse", PE-resistent Gewichtsverhältnis Triazophos : Binapacryl =2:1"Baardse", PE-resistant Triazophos: Binapacryl weight ratio = 2: 1
der SpritzbrüheWt .- ^ AS in
the spray mixture
in $ AbtötungOvicidal effect
in $ mortification
+ Binapacryl
Triazophos
Binapacryl
Triazophos
+ Binapacryl
Triazophos
BinapacrylTriazophos
+ Binapacryl
Triazophos
Binapacryl
Triazophos
+ Binapacryl
Triazophos
Binapacryl
+ 0,0031
0,0063
0,0031
0,0031
+ 0,0016
0,0031
0,00160.0063
+ 0.0031
0.0063
0.0031
0.0031
+ 0.0016
0.0031
0.0016
0
75
50
0
25100
0
75
50
0
25th
Schädlingsstamm: Gemeine Spinnmilbe (Tetranychus urticae),Pest strain: Common spider mite (Tetranychus urticae),
"Baardse", PE-resistent und selektiert Gewichtsverhältnis Triazophos : Binapacryl = 10 : 1"Baardse", PE-resistant and selected weight ratio Triazophos: Binapacryl = 10: 1
der SpritzbrüheWt .- # AS in
the spray mixture
in i° AbtötungOvicidal effect
in i ° death
+ Binapacryl
Triazophos
Binapacryl
Triazophos
+ Binapacryl
Triazophos
BinapacrylTriazophos
+ Binapacryl
Triazophos
Binapacryl
Triazophos
+ Binapacryl
Triazophos
Binapacryl
+ 0,00125
0,0125
0,00125
0,0063
+ 0,00063
0,0063
0,000630.0125
+ 0.00125
0.0125
0.00125
0.0063
+ 0.00063
0.0063
0.00063
oo to to ι in ηoo to to ι in η
909829/0385909829/0385
Claims (3)
Priority Applications (27)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782801787 DE2801787A1 (en) | 1978-01-17 | 1978-01-17 | PEST CONTROL |
| BG7942052A BG28696A3 (en) | 1978-01-17 | 1979-01-12 | Composition and method for pest fighting |
| EG25/79A EG13763A (en) | 1978-01-17 | 1979-01-15 | Pesticidal compositions |
| DD79210478A DD141407A5 (en) | 1978-01-17 | 1979-01-15 | SCHAEDLINGSBEKAEMPFUNGSMITTEL |
| ZM4/79A ZM479A1 (en) | 1978-01-17 | 1979-01-15 | Pesticidal compositions |
| PH22064A PH14337A (en) | 1978-01-17 | 1979-01-15 | Synergistic combination of triazophor and binapacryl as pesticides |
| NZ189371A NZ189371A (en) | 1978-01-17 | 1979-01-15 | Synergistic insecticidal composition |
| AR275160A AR219961Q (en) | 1978-01-17 | 1979-01-15 | ANTIPARASITIC PRODUCTS |
| IT19306/79A IT1110014B (en) | 1978-01-17 | 1979-01-15 | Anti-parasitic |
| AT26479A ATA26479A (en) | 1978-01-17 | 1979-01-15 | INSECTICIDES AND ACARICIDES |
| IL56432A IL56432A0 (en) | 1978-01-17 | 1979-01-15 | Pesticidal compositions comprising triazophos together with another active compound |
| MW2/79A MW279A1 (en) | 1978-01-17 | 1979-01-15 | Pesticidal compositions |
| PT7969082A PT69082A (en) | 1978-01-17 | 1979-01-16 | Process for preparing plagicid compositions |
| NL7900349A NL7900349A (en) | 1978-01-17 | 1979-01-16 | PESTICIDES AGAINST HARMFUL ORGANISMS. |
| CS79346A CS203030B2 (en) | 1978-01-17 | 1979-01-16 | Insecticide and acaricide |
| ZA79171A ZA79171B (en) | 1978-01-17 | 1979-01-16 | Pesticidal compositions |
| BR7900268A BR7900268A (en) | 1978-01-17 | 1979-01-16 | PRAGUICIDAL COMPOSITIONS AND THEIR APPLICATION |
| PL21282179A PL212821A1 (en) | 1978-01-17 | 1979-01-16 | PESTICIAL KILLER |
| AU43397/79A AU516996B2 (en) | 1978-01-17 | 1979-01-16 | Pesticidal compositions |
| JP229579A JPS54101429A (en) | 1978-01-17 | 1979-01-16 | Agricultural chemicals |
| GB791567A GB2012587B (en) | 1978-01-17 | 1979-01-16 | Pesticidal compositions |
| DK18279A DK18279A (en) | 1978-01-17 | 1979-01-16 | MEASURES TO COMBAT HARMFUL BODIES AND THE USE OF THE PRODUCT |
| SU792712808A SU717989A3 (en) | 1978-01-17 | 1979-01-16 | Mite control agent |
| MX797664U MX6664E (en) | 1978-01-17 | 1979-01-17 | IMPROVED PROCEDURE FOR PREPARING A PESTICIDE COMPOSITION |
| FR7901077A FR2414300A1 (en) | 1978-01-17 | 1979-01-17 | PESTICIDE PRODUCTS CONTAINING A PHOSPHORIC ESTER AND A DINITRO-PHENOL DERIVATIVE |
| OA56712A OA06152A (en) | 1978-01-17 | 1979-01-17 | Pesticide products containing a phosphoric ester and a dinitro-phenol derivative. |
| BE0/192941A BE873536A (en) | 1978-01-17 | 1979-01-17 | PESTICIDE PRODUCTS CONTAINING A PHOSPHORIC ESTER AND A DINITRO-PHENOL DERIVATIVE |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782801787 DE2801787A1 (en) | 1978-01-17 | 1978-01-17 | PEST CONTROL |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2801787A1 true DE2801787A1 (en) | 1979-07-19 |
Family
ID=6029650
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19782801787 Withdrawn DE2801787A1 (en) | 1978-01-17 | 1978-01-17 | PEST CONTROL |
Country Status (27)
| Country | Link |
|---|---|
| JP (1) | JPS54101429A (en) |
| AR (1) | AR219961Q (en) |
| AT (1) | ATA26479A (en) |
| AU (1) | AU516996B2 (en) |
| BE (1) | BE873536A (en) |
| BG (1) | BG28696A3 (en) |
| BR (1) | BR7900268A (en) |
| CS (1) | CS203030B2 (en) |
| DD (1) | DD141407A5 (en) |
| DE (1) | DE2801787A1 (en) |
| DK (1) | DK18279A (en) |
| EG (1) | EG13763A (en) |
| FR (1) | FR2414300A1 (en) |
| GB (1) | GB2012587B (en) |
| IL (1) | IL56432A0 (en) |
| IT (1) | IT1110014B (en) |
| MW (1) | MW279A1 (en) |
| MX (1) | MX6664E (en) |
| NL (1) | NL7900349A (en) |
| NZ (1) | NZ189371A (en) |
| OA (1) | OA06152A (en) |
| PH (1) | PH14337A (en) |
| PL (1) | PL212821A1 (en) |
| PT (1) | PT69082A (en) |
| SU (1) | SU717989A3 (en) |
| ZA (1) | ZA79171B (en) |
| ZM (1) | ZM479A1 (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2200436A1 (en) * | 1971-01-19 | 1972-08-10 | Agripat Sa | New esters |
-
1978
- 1978-01-17 DE DE19782801787 patent/DE2801787A1/en not_active Withdrawn
-
1979
- 1979-01-12 BG BG7942052A patent/BG28696A3/en unknown
- 1979-01-15 PH PH22064A patent/PH14337A/en unknown
- 1979-01-15 IT IT19306/79A patent/IT1110014B/en active
- 1979-01-15 MW MW2/79A patent/MW279A1/en unknown
- 1979-01-15 AR AR275160A patent/AR219961Q/en unknown
- 1979-01-15 EG EG25/79A patent/EG13763A/en active
- 1979-01-15 NZ NZ189371A patent/NZ189371A/en unknown
- 1979-01-15 AT AT26479A patent/ATA26479A/en not_active IP Right Cessation
- 1979-01-15 IL IL56432A patent/IL56432A0/en unknown
- 1979-01-15 ZM ZM4/79A patent/ZM479A1/en unknown
- 1979-01-15 DD DD79210478A patent/DD141407A5/en unknown
- 1979-01-16 PL PL21282179A patent/PL212821A1/en unknown
- 1979-01-16 BR BR7900268A patent/BR7900268A/en unknown
- 1979-01-16 GB GB791567A patent/GB2012587B/en not_active Expired
- 1979-01-16 CS CS79346A patent/CS203030B2/en unknown
- 1979-01-16 PT PT7969082A patent/PT69082A/en unknown
- 1979-01-16 ZA ZA79171A patent/ZA79171B/en unknown
- 1979-01-16 DK DK18279A patent/DK18279A/en not_active Application Discontinuation
- 1979-01-16 JP JP229579A patent/JPS54101429A/en active Pending
- 1979-01-16 NL NL7900349A patent/NL7900349A/en not_active Application Discontinuation
- 1979-01-16 SU SU792712808A patent/SU717989A3/en active
- 1979-01-16 AU AU43397/79A patent/AU516996B2/en not_active Ceased
- 1979-01-17 BE BE0/192941A patent/BE873536A/en unknown
- 1979-01-17 MX MX797664U patent/MX6664E/en unknown
- 1979-01-17 OA OA56712A patent/OA06152A/en unknown
- 1979-01-17 FR FR7901077A patent/FR2414300A1/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2200436A1 (en) * | 1971-01-19 | 1972-08-10 | Agripat Sa | New esters |
Also Published As
| Publication number | Publication date |
|---|---|
| ZM479A1 (en) | 1980-08-22 |
| BR7900268A (en) | 1979-08-14 |
| MX6664E (en) | 1985-10-07 |
| PT69082A (en) | 1979-02-01 |
| BE873536A (en) | 1979-07-17 |
| GB2012587A (en) | 1979-08-01 |
| NL7900349A (en) | 1979-07-19 |
| AR219961Q (en) | 1980-09-30 |
| NZ189371A (en) | 1980-10-24 |
| AU516996B2 (en) | 1981-07-02 |
| FR2414300A1 (en) | 1979-08-10 |
| ZA79171B (en) | 1980-01-30 |
| SU717989A3 (en) | 1980-02-25 |
| GB2012587B (en) | 1982-06-16 |
| IT1110014B (en) | 1985-12-23 |
| OA06152A (en) | 1981-06-30 |
| BG28696A3 (en) | 1980-06-16 |
| EG13763A (en) | 1982-03-31 |
| PH14337A (en) | 1981-05-29 |
| IT7919306A0 (en) | 1979-01-15 |
| DK18279A (en) | 1979-07-18 |
| JPS54101429A (en) | 1979-08-10 |
| IL56432A0 (en) | 1979-03-12 |
| DD141407A5 (en) | 1980-04-30 |
| CS203030B2 (en) | 1981-02-27 |
| MW279A1 (en) | 1980-03-12 |
| PL212821A1 (en) | 1979-09-10 |
| ATA26479A (en) | 1981-01-15 |
| AU4339779A (en) | 1979-07-26 |
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