DE2742452A1 - Prodn. of gas mixts. for Fischer-Tropsch petrol synthesis - by coal gasification using oxygen and hydrogen from electrolysis of water - Google Patents

Prodn. of gas mixts. for Fischer-Tropsch petrol synthesis - by coal gasification using oxygen and hydrogen from electrolysis of water

Info

Publication number
DE2742452A1
DE2742452A1 DE19772742452 DE2742452A DE2742452A1 DE 2742452 A1 DE2742452 A1 DE 2742452A1 DE 19772742452 DE19772742452 DE 19772742452 DE 2742452 A DE2742452 A DE 2742452A DE 2742452 A1 DE2742452 A1 DE 2742452A1
Authority
DE
Germany
Prior art keywords
oxygen
synthesis
water
gas
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19772742452
Other languages
German (de)
Inventor
Wolfgang Dipl Ing D Junkermann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DE19772742452 priority Critical patent/DE2742452A1/en
Publication of DE2742452A1 publication Critical patent/DE2742452A1/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0943—Coke
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1618—Modification of synthesis gas composition, e.g. to meet some criteria
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1684—Integration of gasification processes with another plant or parts within the plant with electrolysis of water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Synthesis gas mixts. contg. CO and H2 in volume ratio 1:2 are made by gasification of coal or coke, using oxygen from electrolysis of water, the hydrogen obtd. to the same time being added to the produce gas after purification Excess current from power stations at off-peak periods can be used to produce the O2 and H2 at low cost, with storage in the pipe-line system. Special plant for conversion of part of the CO to CO2 in order to obtain the correct CO/H2 ratio is avoided, and consumption of coal reduced.

Description

Betr.: TreibstoffsynthesegaserzeugeranlageRe: fuel synthesis gas generating plant

eit langem bekannt sind die Benzinsynthese nach Fischer-Tropsch, die Drucksauerstoffvergasung von Kohle oder Koks in verschiedenen Verfahren, sowie die Zerlegung von Wasser in Sauerstoff und Wasserstoff mittels elektrischen Stromes. Nachstehende Beschreibung zeigt, wie man mit einer geeigneten Kombination dieser Verfahren, bezw. von Teilen derselben einige Nachteile der vorhandenen Verfahren vermeiden und eir besonderes umweltfreundliches und preisgünstiges Treibstoffherstellungsverfahren schaffen kann. er besondere Vorteil der Kombination erhellt aus Folgendem.The gasoline synthesis according to Fischer-Tropsch, the Pressurized oxygen gasification of coal or coke in various processes, as well as the Decomposition of water into oxygen and hydrogen by means of an electric current. The description below shows how to come up with a suitable combination of these Procedure, respectively. some of the disadvantages of the existing methods avoid and use a particularly environmentally friendly and inexpensive fuel production process can create. The particular advantage of the combination is evident from the following.

Um Benzin erzeugen zu können, braucht man ein solches Synthesegas, das etwa ein Volumenverhältnis CO : H wie 1 : 2 aufweist. Vorgeschlagen wird wie bisher üblich 2zunächst die Herstellunvon Generatorgas, welches je nach Herstellungsart ein CO : H2 -verhältnis von etwa 1 : 1 aufweist und zwar aus Kohle oder Koks mit Hilfe von sauerstoff gewissen Überdruckes, dem in erster Linie zur Beherrschung der Temperaturen Wasserdampf beigemengt ist.In order to be able to produce gasoline, one needs such a synthesis gas, which has a volume ratio of CO: H such as 1: 2. It is suggested how Up to now, the production of generator gas has been customary, which depends on the type of production has a CO: H2 ratio of about 1: 1 from coal or coke with Help of oxygen of a certain overpressure, primarily for control water vapor is added to the temperatures.

Erfindungsgemass soll der Sauerstoff nicht wie bisher üblich aus einer Luftzerlegungsanlage bezogen werden, sondern durch Zerlegung von Wasser durch elektrischen Strom. Dabei soll beispielsweise Überschussstrom aus Zeiten der Niedrigbelastung von Elektrizitatskraftwerken verwendet werden.According to the invention, the oxygen should not, as was previously the case, from a Air separation plant can be obtained, but by separating water by electrical Current. For example, excess electricity from times of low load should be used used by electric power plants.

Die Kraftwerke müssen sowieso den ganzen Tag laufen. Ihre Abschreibungs- und Beaienungskosten sind bereits aus der normalen Elektrizitatserzeugung gedeckt, so dass neben gewissem apparativem Aufwand wesentliche Herstellungskosten fur Sauerstoff und Wasserstoff nur noch aus dem Mehrverbrauch des Kraftwerkes an Brennstoff resultieren, der aber insbesondere bei Atomkraftwerken ziemlich billig ist.The power plants have to run all day anyway. Your depreciation and maintenance costs are already covered by normal electricity generation, so that, in addition to a certain outlay in terms of equipment, there are significant manufacturing costs for oxygen and hydrogen only result from the additional fuel consumption of the power plant, but it is quite cheap, especially in the case of nuclear power plants.

Die durch die Wasserzerlegung gewonnenen Gase O und H können in langen Rohrsystemen gespeichert werde, evtl. auf dem Wege vom Kraftwerk zur Syntheseanlage. Dort wird man auch die Generatorgasanlage mit ihren Nebenanlagen aufstellen, z.B. CO -wäsche. Auf jeden Fall ist ferner vor der Synthese eini Gasentschwefelung erforderlich.The gases O and H obtained through the decomposition of water can be used for a long time Pipe systems are stored, possibly on the way from the power plant to the synthesis plant. The generator gas system with its ancillary systems will also be set up there, e.g. CO washing. In any case, gas desulphurization is also required before the synthesis.

Üblich ist es bisher für Synthesen das Generatorgas in einer Konversionsanlage so umzuwandeln, dass es die für die Synthese nötige Zusammensetzung erhalt, also CO : H wie 1 : 2. Dabei wird eine besondere Anlage benötigt, de unter anderem eine gewisse Menge Co in Co2umwandelt, was jedoch hier aus Gründen der Kohleersparnis vermieden werden soll.The generator gas in a conversion plant has been customary for syntheses up to now to convert in such a way that it receives the composition necessary for the synthesis, i.e. CO: H as 1: 2. A special system is required, including one converts a certain amount of Co into Co2, but here for reasons of coal saving should be avoided.

In einfachster Weise soll stattdessen erfindungsgemäss das Generatorgas in Synthesegas umgewandelt werden, indem man den Wasserstoff aus der elektrischen Wasserzerlegung im Wesentlichen unter Umgehung der Generatoranlage direkt dem erzeugten Generatorgas nach seiner Reinigung zufügt.Instead, according to the invention, the generator gas is to be used in the simplest manner can be converted into synthesis gas by taking the hydrogen from the electrical Water decomposition essentially bypassing the generator system directly to the generated one Adding generator gas after it has been cleaned.

Gegenüber den bisherigen Verfanren stellt diese Arbeitsweise eine sehr grosse Vereinfachung dar, insbesondere auch, weil die einzelnen Anlageteile der Gaserzeugung una Reinigung geringere Abmessurgen erfordern. @berschüsse von Wasserstoff wie auch das Restgas aus der spateren Syntnesc Konnen zu Heizzwecken verwendet, bezw. als Zusatz zum Dampf fur den Generatorbetrieb verwendet werden.Compared to the previous procedures, this way of working represents a very great simplification, especially because the individual parts of the system gas generation and cleaning require smaller dimensions. @ surpluses of Hydrogen as well as the residual gas from the later Syntnesc can be used for heating purposes used, respectively. can be used as an additive to steam for generator operation.

Bei dem Sauerstoffgeneratorverfahren kommt das die Umwelt verschmutzende Aufheizen der ublicherweise verwendeten Wassergaserzeuger mit Luftdurchblasen in die Atmosphare vollkommen in Fortfall, wobei zugleich hochwertiger Generatorkoks gespart wird.With the oxygen generator process comes what is polluting the environment Heating of the commonly used water gas generator with air blowing in the atmosphere completely in decline, while at the same time high quality generator coke is saved.

Der Rest der Anlage mit Kontaktofen, Aktivkohleabscheidung des Benzins usw. braucht nier nicht naher beschrieben zu werden, da er von den Fischer-Tropsch Anlagen seit 50 Jahren bekannt istThe rest of the plant with contact furnace, activated carbon separation of the gasoline etc. need not be described in more detail, since it is from the Fischer-Tropsch Plants has been known for 50 years

Claims (1)

Patentanspruch Verfahren zur Treibstoffsynthesegaserzeugung, bei welchem die Vergasung von Kohle oder KOKS in einem Sauerstoffgasgenerator erfoigt und der Sauerstoff beispielsweise mittels @berschussstromes von Elektrizitatskraftwerken erfindungsgemass durch Wasserzerlegung erzeugt wird, wobei aer gleichzeitig entstehende Wasserstoff dem Generatorgas im Xesentlichen nach dessen Reinigung, also unter Umgehung der gesatten Gasgeneratorenanlage beigefugt wira, um so das fur die Synthese erforderliche CO : H@ -vernaltnis zu erzielen. Claim method for fuel synthesis gas generation, at which requires the gasification of coal or COKS in an oxygen gas generator and oxygen, for example, by means of excess electricity from electric power plants is produced according to the invention by decomposition of water, aer being produced at the same time Hydrogen to the generator gas essentially after it has been cleaned, i.e. bypassing it the full gas generator system was added, so as to provide that which is necessary for the synthesis CO: H @ -vernaltnis to achieve.
DE19772742452 1977-09-21 1977-09-21 Prodn. of gas mixts. for Fischer-Tropsch petrol synthesis - by coal gasification using oxygen and hydrogen from electrolysis of water Pending DE2742452A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19772742452 DE2742452A1 (en) 1977-09-21 1977-09-21 Prodn. of gas mixts. for Fischer-Tropsch petrol synthesis - by coal gasification using oxygen and hydrogen from electrolysis of water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19772742452 DE2742452A1 (en) 1977-09-21 1977-09-21 Prodn. of gas mixts. for Fischer-Tropsch petrol synthesis - by coal gasification using oxygen and hydrogen from electrolysis of water

Publications (1)

Publication Number Publication Date
DE2742452A1 true DE2742452A1 (en) 1979-03-29

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2552443A1 (en) * 1983-09-24 1985-03-29 Kloeckner Humboldt Deutz Ag Synthesis gas suitable for methanol mfr. made by gasifying coal
WO1990001529A1 (en) * 1988-08-05 1990-02-22 Weber Anneler Hans Process for obtaining components, elements or compounds from mixtures of materials
US7863340B2 (en) 2005-03-16 2011-01-04 Fuelcor Llc Systems, methods, and compositions for production of synthetic hydrocarbon compounds
DE102010027474A1 (en) * 2010-07-16 2012-01-19 Rwe Power Ag Method for manufacturing synthesis gas from carbonaceous solids in e.g. gas turbine power plant, involves setting molar ratio, where treatment of raw gas comprises allowance of hydrogen debited to shift reaction

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2552443A1 (en) * 1983-09-24 1985-03-29 Kloeckner Humboldt Deutz Ag Synthesis gas suitable for methanol mfr. made by gasifying coal
WO1990001529A1 (en) * 1988-08-05 1990-02-22 Weber Anneler Hans Process for obtaining components, elements or compounds from mixtures of materials
GR890100490A (en) * 1988-08-05 1990-08-22 Anneler Hans Dr Weber Method for recuparating components or compounds from mixtures
US7863340B2 (en) 2005-03-16 2011-01-04 Fuelcor Llc Systems, methods, and compositions for production of synthetic hydrocarbon compounds
US8093305B2 (en) 2005-03-16 2012-01-10 Fuelcor, Llc Systems, methods, and compositions for production of synthetic hydrocarbon compounds
US8114916B2 (en) 2005-03-16 2012-02-14 Fuelcor, Llc Systems, methods, and compositions for production of synthetic hydrocarbon compounds
US8168143B2 (en) 2005-03-16 2012-05-01 Fuelcor, Llc Systems, methods, and compositions for production of synthetic hydrocarbon compounds
DE102010027474A1 (en) * 2010-07-16 2012-01-19 Rwe Power Ag Method for manufacturing synthesis gas from carbonaceous solids in e.g. gas turbine power plant, involves setting molar ratio, where treatment of raw gas comprises allowance of hydrogen debited to shift reaction

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