DE2614975B1 - Simultaneous washing and preservation of vehicles - using aq. emulsion of abrasive, solvent, wax, silicone oil and anionic surfactant - Google Patents
Simultaneous washing and preservation of vehicles - using aq. emulsion of abrasive, solvent, wax, silicone oil and anionic surfactantInfo
- Publication number
- DE2614975B1 DE2614975B1 DE19762614975 DE2614975A DE2614975B1 DE 2614975 B1 DE2614975 B1 DE 2614975B1 DE 19762614975 DE19762614975 DE 19762614975 DE 2614975 A DE2614975 A DE 2614975A DE 2614975 B1 DE2614975 B1 DE 2614975B1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- wax
- composition
- silicone oil
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229920002545 silicone oil Polymers 0.000 title claims abstract description 17
- 238000005406 washing Methods 0.000 title claims abstract description 14
- 239000000839 emulsion Substances 0.000 title claims abstract description 6
- 239000003945 anionic surfactant Substances 0.000 title claims abstract 5
- 238000004321 preservation Methods 0.000 title claims abstract 4
- 239000002904 solvent Substances 0.000 title description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000001993 wax Substances 0.000 claims abstract description 14
- 239000003960 organic solvent Substances 0.000 claims abstract description 10
- 238000004140 cleaning Methods 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000009835 boiling Methods 0.000 claims abstract description 6
- 239000012170 montan wax Substances 0.000 claims abstract description 6
- 239000005909 Kieselgur Substances 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims abstract description 5
- 238000007127 saponification reaction Methods 0.000 claims abstract description 5
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 claims abstract 3
- 229960005068 monoethanolamine oleate Drugs 0.000 claims abstract 3
- 238000004078 waterproofing Methods 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims description 20
- 239000003973 paint Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 9
- -1 polysiloxanes Polymers 0.000 claims description 9
- 239000002453 shampoo Substances 0.000 claims description 8
- 125000000129 anionic group Chemical group 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- 239000003082 abrasive agent Substances 0.000 claims description 6
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- 230000002209 hydrophobic effect Effects 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 238000005498 polishing Methods 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 2
- 239000004203 carnauba wax Substances 0.000 claims description 2
- 235000013869 carnauba wax Nutrition 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 239000005871 repellent Substances 0.000 claims description 2
- 230000002940 repellent Effects 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 9
- 238000002360 preparation method Methods 0.000 claims 3
- 238000010936 aqueous wash Methods 0.000 claims 2
- 125000002091 cationic group Chemical group 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- OBMBYGXRLQQDHH-KVVVOXFISA-N morpholin-4-ium;(z)-octadec-9-enoate Chemical compound C1COCCN1.CCCCCCCC\C=C/CCCCCCCC(O)=O OBMBYGXRLQQDHH-KVVVOXFISA-N 0.000 claims 1
- 230000002335 preservative effect Effects 0.000 claims 1
- 230000001681 protective effect Effects 0.000 claims 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract description 2
- 239000002184 metal Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000010985 leather Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- WNEODWDFDXWOLU-QHCPKHFHSA-N 3-[3-(hydroxymethyl)-4-[1-methyl-5-[[5-[(2s)-2-methyl-4-(oxetan-3-yl)piperazin-1-yl]pyridin-2-yl]amino]-6-oxopyridin-3-yl]pyridin-2-yl]-7,7-dimethyl-1,2,6,8-tetrahydrocyclopenta[3,4]pyrrolo[3,5-b]pyrazin-4-one Chemical compound C([C@@H](N(CC1)C=2C=NC(NC=3C(N(C)C=C(C=3)C=3C(=C(N4C(C5=CC=6CC(C)(C)CC=6N5CC4)=O)N=CC=3)CO)=O)=CC=2)C)N1C1COC1 WNEODWDFDXWOLU-QHCPKHFHSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60S—SERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
- B60S3/00—Vehicle cleaning apparatus not integral with vehicles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Als nbrasivmittel kommen die für Autopolituren üblichen, mild wirkenden Schleifmittel, wie Diatomeencrde, Neuburger Kieselkreide, Poliertonerden usw., in Betracht. Die Abrasivstolfe müssen äußerst feinteilig sein, damit sie den Autolack nicht schädigen. Sie sind in der Komposition in einer Menge von 1-40 Gew.-'MO enthalten. The milder agents customary for car polishes are used as nbrasive agents Abrasives such as diatomaceous earth, Neuburg chalk, polishing earth, etc., in Consideration. The abrasive tools must be extremely be finely divided so they do not damage the car paint. You are in the composition in a crowd of 1-40 wt .- 'MO included.
Die organischen Lösungsmittel sollen eine lösende Wirkung gegenüber öligen Verschmutzungen sowie eine ausreichende Flüchtigkeit aufweisen und dürfen den Lack nicht angreifen. The organic solvents are said to have a dissolving effect oily soiling as well as sufficient volatility and may do not attack the paint.
Geeigent sind beispielsweise aliphatische und/oder aromatische Kohlenwasserstofle, Ketone, Alkohole, Glykoläther usw., die Siedepunkte von etwa 120-240 C besitzen. Bevorzugt werden Benzinkohlenwasserstoffe des Siedebereiches 160-220 C. Der Mengenanteil der Lösungsmittel in der Komposition beträgt 5-50 Gew»Y». Suitable are, for example, aliphatic and / or aromatic hydrocarbons, Ketones, alcohols, glycol ethers, etc., which have boiling points of around 120-240 C. Gasoline hydrocarbons in the boiling range 160-220 C. are preferred the solvent in the composition is 5-50% by weight.
Weiterhin enthalten die Kompositionen 0,1-10 Gew.-% eines glanzgebenden Wachses, wie z. B. Montanwachsderivate, Carnaubawachs, oder einer anderen, in Autopolituren üblichen Wachskomponente. Vorzugsweise werden Montanwachsderivate mit Säurezahlen von 10-170, beispielsweise 90, und Verseifungszahlen von 15-180, beispielsweise 130, verwendet. The compositions also contain 0.1-10% by weight of a gloss-imparting agent Wax, such as B. montan wax derivatives, carnauba wax, or another, in car polishes usual wax component. Montan wax derivatives with acid numbers are preferred from 10-170, for example 90, and saponification numbers from 15-180, for example 130 is used.
Die Kompositionen enthalten ferner 0,1-10 Gew.JY0 eines Silikonöls, z. B. ein Dimethylpolysiloxan der Viskosität 50-100000 Centistokes. Es kommen auch Mischungen aus Silikonölen verschiedener Viskositätsstufen, z. B. 50-500 und 5000-15000 Centistokes, in Betracht. Ferner können auch Polysiloxane, die funktionelle Gruppen, z. B. Aminogruppen, enthalten, eingesetzt werden. Derartige Polysiloxane ergeben besonders shampoofeste Pflegemittelfil me. The compositions also contain 0.1-10% by weight of a silicone oil, z. B. a dimethylpolysiloxane having a viscosity of 50-100,000 centistokes. There are also coming Mixtures of silicone oils of different viscosity grades, e.g. B. 50-500 and 5000-15000 Centistokes, into consideration. Furthermore, polysiloxanes, the functional groups, z. B. amino groups contain, are used. Such polysiloxanes result especially shampoo-resistant care product films.
Den vorgenannten Bestandteilen werden noch 1-15 Gew.-% eines anionischen Tensids zugefügt, das einerseits emulgierende und reinigende Eigenschaften besitzen muß, andererseits die Glanzbildung nicht beeinträchtigen darf. Geeignete Tenside sind höhere Fettalkoholsulfate, Alkylsulfonate oder Alkylarylsulfonate mit 8-18 C-Atomen. Es hat sich gezeigt, daß Alkali- oder Aminsalze höherer Fettsäuren mit 8-18 C-Atomen besonders günstige Eigenschaften aufweisen, wie z. B. die Monoäthanolamin- oder Morpholinseifen der Ölsäure. The aforementioned constituents are still 1-15% by weight of an anionic Added surfactants, which on the one hand have emulsifying and cleaning properties must, on the other hand must not affect the gloss formation. Suitable surfactants are higher fatty alcohol sulfates, alkyl sulfonates or alkyl aryl sulfonates with 8-18 Carbon atoms. It has been shown that alkali or amine salts of higher fatty acids with 8-18 carbon atoms have particularly favorable properties, such as B. the monoethanolamine or morpholine soaps of oleic acid.
Durch Zusatz von bis zu 60 Gew.-O/u Wasser kann die Komposition in Emulsionsform übergeführt werden. Sie läßt sich in dieser Form leicht durch bloßes Eingießen und Umrühren mit dem Waschwasser verdünnen. By adding up to 60% by weight of water, the composition can be used in Emulsion form are converted. In this form it can easily be passed through Pour in and stir to dilute with the wash water.
Die Wagenwäsche wird in üblicher Weise mit einer 0,2- bis 2%igen Verdünnung der Komposition durchgeführt, wobei die Wäsche vorzugsweise von hand mit Hilfe von Schwämmen, Bürsten oder dgl., gegebenenfalls auch in mit rotierenden Bürsten arbeitenden automatischen Waschanlagen, erfolgt. Nach dem Trocknenlassen oder Abledern ist ein weiteres Auspolieren nicht erforderlich. Die Lackoberflächen sind hydrophob und weisen einen ausgezeichneten Glanz auf. Selbstverständlich können besonders stark verschmutzte oder geschädigte Lackflächen auch mit der unverdünnten Komposition vor- oder nachbehandelt werden. The car wash is carried out in the usual way with a 0.2 to 2% strength Dilution of the composition carried out, washing preferably by hand with the help of sponges, brushes or the like, possibly also in rotating Brushing automatic washing systems. After letting it dry No further polishing is required or leather is removed. The painted surfaces are hydrophobic and have an excellent gloss. Of course you can especially heavily soiled or damaged paintwork surfaces, even with the undiluted one Composition can be pre- or post-treated.
Beispiel Zu den folgenden Versuchen wurde ein Produkt der nachstehenden Zusammensetzung verwendet: Silikatische Schleifmittel 15 Gew.-% (Diatomeenerde) Benzinkohlenwasserstofle 30 Gew.-'MO Siedebereich 160-220 C Siliconöl (Viskosität 350 cSt) 3 Gew.-% Wachs (Montanwachsderivat) 1 Gew.-% Sliurezahl 90, Verseifungszahl 130) Monoiithanolamin-oleat 2,5 Gew.-% Wasser 48,5 Gew.-% Alle lackierten Bleche, die für die folgenden Versuche benutzt wurden, waren wor der Behandlung mit einer 20%gen Aufschlämmung von Neuburger Kieselkreide in zeiger Seifenlösung gereinigt, anschließend mit Wasser gespült und mit Isopropanol nachgewischt worden. Example A product of the following was used in the following experiments Composition used: Silicate abrasives 15% by weight (diatomaceous earth) Petrol hydrocarbons 30 wt .- 'MO boiling range 160-220 C Silicone oil (viscosity 350 cSt) 3% by weight wax (montan wax derivative) 1% by weight acid number 90, saponification number 130) Monoithanolamine oleate 2.5% by weight water 48.5% by weight All painted metal sheets, which were used for the following experiments were treated with a 20% of the slurry of Neuburg Siliceous Chalk cleaned in Zeiger soap solution, then rinsed with water and wiped with isopropanol.
Versuch I Zur Bestimmung der Reinigungswirkung wurde eine weiß lackierte Blechtafel (Karosserieblech, Lackaufbau wie im Automobilbau üblich) mit Testschmutz, bestehend aus 13,0 'wo Kaolin 33,0 % Quarzmehl 13,0 % Bimsmehl 2,6 % Lanolin 1,4 % Vaseline 1,2 % Ruß 0,2 % Eisenoxidschwarz ad 100 Wasser künstlich verschmutzt. Experiment I To determine the cleaning effect, a white lacquer was used Sheet metal (body sheet, paint structure as usual in automotive engineering) with test dirt, consisting of 13.0 'wo kaolin 33.0% quartz flour 13.0% pumice flour 2.6% lanolin 1.4 % Vaseline 1.2% soot 0.2% black iron oxide ad 100 water artificially contaminated.
Das so vorbehandelte Blech wurde mit einer 0,6%igen Lösung des erfindungsgemäßen Mittels in Wasser gereinigt. Dabei wurde ein weicher Kunststoff-Schwamm Größe 20 x 15 cm, getränkt mit der Prüflösung 5mal über das Blech unter einer Belastung von 5kg gezogen. Anschließend wurde mit Wasser gespült und mit einem Autoleder abgetrocknet. The sheet metal pretreated in this way was coated with a 0.6% solution of the Purified by means of water. A size 20 soft plastic sponge was used x 15 cm, soaked with the test solution 5 times over the sheet under a load of 5kg pulled. It was then rinsed with water and dried with a car leather.
Zur Messung der Reinigungswirkung wurde der Weißgrad herangezogen, der mit dem Weißgradmesser der Firma Leitz bestimmt wurde (Bezugswert MgO 100). The degree of whiteness was used to measure the cleaning effect, which was determined with the Leitz whiteness meter (reference value MgO 100).
Ergebnisse Blech sauber (Ausgangswert) 64 Verschmutztes Blech mit erfindungs- 63 gemäßen Produkt gewaschen Die Messungen beweisen, daß die Reinigungswirkung des erfindungsgemäßen Mittels ausgezeichnet ist. Results Sheet metal clean (initial value) 64 Soiled sheet metal with Washed product according to the invention. The measurements show that the cleaning effect of the agent according to the invention is excellent.
Versuch 2 Ein lackiertes Blech wurde mit einer 0,6%gen Lösung des erfindungsgemäßen Mittels gereinigt, mit Wasser gespült und mit einem Leder getrocknet Anschließend wurden die Randwinkel und die Glanzwerte bestimmt. Experiment 2 A painted metal sheet was treated with a 0.6% solution of the Agent according to the invention cleaned, rinsed with water and dried with a leather The contact angles and the gloss values were then determined.
Randwinkel Glanz Autoblech, unbehandelt 680 76 Autoblech, mit erfindungs- 760 82 gemäßen Produkt, 0,6'l/oiger Lösung behandelt Die hohe Hydrophobierwirkung der erfindungsgemäßen Mittel bei der Anwendung in starker Verdünnung im Waschwasser erreicht damit Werte, die sonst nur bei Anwendung von Autolackreinigungspolituren erreicht werden. Sie liegen wesentlich über dem Wert, der von handelsüblichen Waschkonservierern erzielt wird. I Handelsübliche Autoshampoos auch wachshaltige - geben kleinere Randwinkel als das unbehandelte Blech. Edge angle gloss car sheet, untreated 680 76 car sheet, with inventive 760 82 according to the product, 0.6 l / o solution treated The high water repellent effect of the agents according to the invention when used in strong dilution in the wash water thus achieves values that are otherwise only available when using car paint cleaning polishes can be achieved. They are significantly above the value of commercially available laundry preservatives is achieved. I Commercially available car shampoos also contain waxy ones - give smaller contact angles than the untreated sheet.
Werden in dem erfindungsgemäßen Mittel statt der anionischen Emulgatoren nichtionische Tenside oder Gemische von nichtionischen Tensiden mit anionischen Tensiden verwendet, so erhält man Randwinkel die kleiner als die des unbehandelten Bleches sind. Are in the agent according to the invention instead of anionic emulsifiers nonionic surfactants or mixtures of nonionic surfactants with anionic ones If surfactants are used, contact angles are obtained which are smaller than those of the untreated Are sheet metal.
Die überraschend hohe Pflegewirkung des erfindungsgemäßen Mittels zeigt sich auch in der starken Glanzsteigerung des behandelten Bleches, die nahezu die Glanzwerte erreichen, die bei konzentrierten Aufträgen von Lackreinigungspolituren erzielt werden. The surprisingly high care effect of the agent according to the invention is also shown in the strong increase in gloss of the treated sheet, which is almost Reach the gloss values that are achieved with concentrated applications of paint cleaning polishes be achieved.
Beim Waschen mit üblichen Shampoos werden dagegen keine Glanzsteigerungen erzielt, mit Waschkonservierern nur sehr schwache Glanzerhöhungen.When washing with conventional shampoos, on the other hand, there are no increases in gloss achieved, with washing preservatives only very slight increases in gloss.
Werden in dem erlindungsgemäßen Produkt statt der anionischen Emulgatoren nichtionische Tenside oder Gemische von nichtionischen Tensiden mit anionischen Tensiden verwandt, so erreicht man keinen gleichmäßigen Glanz. Die Lackoberfläche erscheint eckig. Are in the product according to the invention instead of the anionic emulsifiers nonionic surfactants or mixtures of nonionic surfactants with anionic ones If surfactants are used, a uniform gloss is not achieved. The paint surface appears angular.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19762614975 DE2614975B1 (en) | 1976-04-07 | 1976-04-07 | Simultaneous washing and preservation of vehicles - using aq. emulsion of abrasive, solvent, wax, silicone oil and anionic surfactant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19762614975 DE2614975B1 (en) | 1976-04-07 | 1976-04-07 | Simultaneous washing and preservation of vehicles - using aq. emulsion of abrasive, solvent, wax, silicone oil and anionic surfactant |
Publications (1)
Publication Number | Publication Date |
---|---|
DE2614975B1 true DE2614975B1 (en) | 1977-10-13 |
Family
ID=5974655
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19762614975 Ceased DE2614975B1 (en) | 1976-04-07 | 1976-04-07 | Simultaneous washing and preservation of vehicles - using aq. emulsion of abrasive, solvent, wax, silicone oil and anionic surfactant |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE2614975B1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2815905A1 (en) * | 1978-04-10 | 1979-10-11 | Dieter Groth | Cleaning and polishing compsn. for wood, metal and glass - contg. wax, methylcellulose, silicone, siliceous chalk, emulsifier, sodium carbonate and specified hydrocarbon |
DE102010032205A1 (en) * | 2010-07-26 | 2012-01-26 | Farrokh Djalali Bazzaz | Car cleaning agent comprises e.g. carnauba wax, silicon, ethanol, deionized water, sodium lauryl ether sulfate, lauryl alcohol, lauryl-halogen compound, glyceride, glycerin, glycerin derivative, saturated and unsaturated fatty acids |
-
1976
- 1976-04-07 DE DE19762614975 patent/DE2614975B1/en not_active Ceased
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2815905A1 (en) * | 1978-04-10 | 1979-10-11 | Dieter Groth | Cleaning and polishing compsn. for wood, metal and glass - contg. wax, methylcellulose, silicone, siliceous chalk, emulsifier, sodium carbonate and specified hydrocarbon |
DE102010032205A1 (en) * | 2010-07-26 | 2012-01-26 | Farrokh Djalali Bazzaz | Car cleaning agent comprises e.g. carnauba wax, silicon, ethanol, deionized water, sodium lauryl ether sulfate, lauryl alcohol, lauryl-halogen compound, glyceride, glycerin, glycerin derivative, saturated and unsaturated fatty acids |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8239 | Disposal/non-payment of the annual fee | ||
8235 | Patent refused |