DE258293C - - Google Patents
Info
- Publication number
- DE258293C DE258293C DENDAT258293D DE258293DA DE258293C DE 258293 C DE258293 C DE 258293C DE NDAT258293 D DENDAT258293 D DE NDAT258293D DE 258293D A DE258293D A DE 258293DA DE 258293 C DE258293 C DE 258293C
- Authority
- DE
- Germany
- Prior art keywords
- quinizarine
- sulfonic acids
- parts
- quinizarin
- chromium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- -1 quinizarine sulfonic acids Chemical class 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 5
- 150000001844 chromium Chemical class 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 235000013311 vegetables Nutrition 0.000 claims description 3
- GUEIZVNYDFNHJU-UHFFFAOYSA-N 1,4-Dihydroxyanthraquinone Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC=C2O GUEIZVNYDFNHJU-UHFFFAOYSA-N 0.000 description 3
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 230000001180 sulfating Effects 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- 229920001615 Tragacanth Polymers 0.000 description 1
- 210000002268 Wool Anatomy 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- BFMYDTVEBKDAKJ-UHFFFAOYSA-L disodium;(2',7'-dibromo-3',6'-dioxido-3-oxospiro[2-benzofuran-1,9'-xanthene]-4'-yl)mercury;hydrate Chemical compound O.[Na+].[Na+].O1C(=O)C2=CC=CC=C2C21C1=CC(Br)=C([O-])C([Hg])=C1OC1=C2C=C(Br)C([O-])=C1 BFMYDTVEBKDAKJ-UHFFFAOYSA-L 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/36—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using mordant dyes ; using metallisable dyes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- M 258293 KLASSE Sn. GRUPPE- M 258293 CLASS Sn. GROUP
auf pflanzlicher Faser.on vegetable fiber.
Patentiert im Deutschen Reiche vom 26. April 1912 ab.Patented in the German Empire on April 26, 1912.
Die Chinizarinsulfosäuren haben bisher in der Färberei keine praktische Verwendung gefunden. Nach v. Georgievics (Zeitschr. f. Farben- und Textil-Industrie, 4, 190) besitzt zwar die durch Sulfieren von Chinizarin mit rauchender Schwefelsäure bei 140 ° erhältliche Sulfosäure die Eigenschaften eines Beizenfarbstoffes, aber die Färbungen auf gebeizter Wolle sind weder walk- noch karbonisierecht. Auf Garantiestreifen erhält man einen praktisch wertlosen bordeauxfarbenen Chromlack. The quinizarine sulfonic acids have so far not found any practical use in dyeing. According to v. Georgievics (Zeitschr. F. Farben- und Textil-Industrie, 4, 190) owns although the one obtainable by sulfating quinizarin with fuming sulfuric acid at 140 ° Sulphonic acid has the properties of a stain dye, but the colorations on stain Wool is neither milled nor carbonized. You get one on the guarantee strip practically worthless burgundy chrome paint.
Es wurde nun die überraschende Beobachtung gemacht, daß beim Drucken der Chinizarinsulfosäuren zusammen mit Chromsalzen auf die pflanzliche Faser und Dämpfen der Drucke graue bis tiefschwarze Färbungen entstehen. Bei Anwendung von anorganischen Chromsalzen, deren Säuren die Faser an-The surprising observation has now been made that when printing the quinizarine sulfonic acids together with chromium salts on the vegetable fibers and steaming of the prints, gray to deep black colorations are created. When using inorganic chromium salts, the acids of which affect the fiber
ao greifen, müssen hierbei entweder mineralsäurebindende Mittel, wie z. B. Natriumacetat, zugesetzt werden, oder die Menge des Chromsalzes, z. B. Fluorchrom, muß so gewählt werden, daß die Faser praktisch nicht angegriffen wird. Die Färbungen zeichnen sich durch hervorragende Waschechtheit und Lichtechtheit aus.ao grab, either mineral acid binding agents such. B. sodium acetate added or the amount of chromium salt, e.g. B. Fluorochrome, must be chosen so that the fiber is practically not attacked. The dyeings are characterized by excellent washfastness and lightfastness the end.
Es eignen sich für dieses Verfahren die verschiedenen Chinizarinsulfosäuren.The various methods are suitable for this procedure Quinizarin sulfonic acids.
Mit einer Druckfarbe, hergestellt aus 3,5 Teilen des Natronsalzes der Chinizarinsulfosäure (aus Chinizarin durch Sulfieren erhalten), 13,5 Teilen Wasser, 7 Teilen essigsaurem Chrom 20° Be., ι Teil Ameisensäure, 25 Teilen essigsaurer Stärke-Tragant-Verdickung, wird gedruckt und der Druck 1 Stunde bei 1J2 Atmosphäre gedämpft. Man erhält eine tief schwarze Färbung.With a printing ink made from 3.5 parts of the sodium salt of quinizarine sulfonic acid (obtained from quinizarin by sulfating), 13.5 parts of water, 7 parts of acetic chromium 20 ° Be., Ι part of formic acid, 25 parts of acetic starch-tragacanth thickening, is printed and the print is steamed for 1 hour at 1 1/2 atmosphere. A deep black color is obtained.
Analog verfährt man bei Verwendung anderer Chinizarinsulfosäuren, z. B. derjenigen der Patentschrift 84505.The same procedure is followed when using other quinizarine sulfonic acids, e.g. B. that of Patent 84505.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE258293C true DE258293C (en) |
Family
ID=516135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT258293D Active DE258293C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE258293C (en) |
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0
- DE DENDAT258293D patent/DE258293C/de active Active
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