DE2264702B2 - LIQUID CRYSTAL ELEMENT - Google Patents
LIQUID CRYSTAL ELEMENTInfo
- Publication number
- DE2264702B2 DE2264702B2 DE19722264702 DE2264702A DE2264702B2 DE 2264702 B2 DE2264702 B2 DE 2264702B2 DE 19722264702 DE19722264702 DE 19722264702 DE 2264702 A DE2264702 A DE 2264702A DE 2264702 B2 DE2264702 B2 DE 2264702B2
- Authority
- DE
- Germany
- Prior art keywords
- liquid crystal
- crystal element
- negative electrode
- voltage
- plates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1345—Conductors connecting electrodes to cell terminals
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133553—Reflecting elements
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/1336—Illuminating devices
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2203/00—Function characteristic
- G02F2203/09—Function characteristic transflective
Landscapes
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Mathematical Physics (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Liquid Crystal (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
- Secondary Cells (AREA)
Description
Die Erfindung betrifft ein Flüssigkriscallelement mit zwei im wesentlichen parallelen Platten, mit an deren einander zugewandten Flächen angeordneten Elektroden, von denen mindestens eine transparent ist und die an eine Gleichspannung anschließbar sind, sowie mit einem zwischen den beiden Platten befindlichen nematischen Flüssigkristall.The invention relates to a liquid crystal element two essentially parallel plates, with electrodes arranged on their mutually facing surfaces, at least one of which is transparent and which can be connected to a DC voltage, as well as with a nematic liquid crystal located between the two plates.
Ein derartiges Flüssigkristallelement ist aus »Siemens-Bauteile-Informationen«, 9 (1971), S. 71 bis 73, bekannt. Das dort beschriebene Flüssigkristallelement arbeitet im Gleichspannungsbetrieb, wobei der Stromfluß durch die Flüssigkristallschicht immer die gleiche Richtung hat. Das Lebensdauerverhalten bei dieser Betriebsart ist problematisch, weil wegen des immer gleichen Stromflusses Polarisierungseffekte auftreten, die bei den für die negative Elektrode herkömmlicherweise verwendeten Metallen zu verschiedenen unerwünschten Effekten führt, insbesondere zu einer Schaumbildung und Vergilbung des Flüssigkristalls.Such a liquid crystal element is from "Siemens component information", 9 (1971), pp. 71 to 73, are known. The liquid crystal element described there works in direct voltage mode, the current flow through the liquid crystal layer always being the same Has direction. The service life behavior in this operating mode is problematic because of the always The same current flow polarization effects occur which are conventional for the negative electrode metals used leads to various undesirable effects, in particular one Foaming and yellowing of the liquid crystal.
Vom Standpunkt der Lebensdauer aus wäre grundsätzlich ein Weehselspannungsbetrieb des Flüssigkristallelements günstiger, weil dann Polarisierungseffekte vermieden wurden. Dies bedingt aber eine aufwendigere Steuerschaltung, die nicht nur wegen ihrer höheren Herstellungskosten, sondern insbesondere wegen ihres größeren Platzbedarfs nachteilig ist.From the standpoint of life, the principle would be an alternating voltage operation of the liquid crystal element cheaper because polarization effects were then avoided. But this requires a more complex one Control circuit, not only because of their higher manufacturing costs, but especially because of their larger space requirement is disadvantageous.
Der Erfindung liegt die Aufgabe zugrunde, ein Flüssigkristallelement zu schaffen, das bei Gleichspannungsbetrieb eine höhere Lebensdauer aufweist als das herkömmliche Element.The invention is based on the object of creating a liquid crystal element that operates in DC voltage has a longer service life than the conventional element.
Die Lösung dieser Aufgabe besteht erfindungsgemäß darin, daß ein wesentlicher Bestandteil der negativen Elektrode Titan, Zirkon und/oder Palladium ist.The solution to this problem is that an essential part of the negative Electrode is titanium, zirconium and / or palladium.
Es hat sich herausgestellt, daß bei Verwendung einer derartigen negativen Elektrode die Lebensdauer des Flüssigkristallelements auch im Gleichspannungsbetrieb merklich verlängert wird.It has been found that when using such a negative electrode, the life of the Liquid crystal elements is noticeably lengthened even in DC voltage operation.
Zum Nachweis der erzielten Verlängerung der Lebensdauer wurde ein Element mit einem Flüssigkristall, nämlich MBBA, in einer Schichtdicke von 12 μ gefüllt, wobei als positive Elektrode ein leitender Überzug aus Zinnoxid und als negative Elektrode jeweils einer der in der nachstehenden Tabelle angegebenen Metallüberzüge verwendet wurde. Die ebenfalls in dieser Tabelle angegebene Lebensdauer des jeweiligen Flüssigkristallelements wurde unter Anlegen einer Gleichspannung von 24 V gemessen.An element with a liquid crystal, namely MBBA, filled in a layer thickness of 12 μ, with a conductive electrode as the positive electrode Coating made of tin oxide and, as negative electrode, one of the following table specified metal coatings was used. The service life of the each liquid crystal element was measured with a DC voltage of 24 V applied.
Negative Elektrode AlNegative electrode Al
CuCu
PbPb
ZnZn
AuAu
SnO2SnO2
TiTi
ZrZr
PdPd
Lebensdauer
(in Stunden)lifespan
(in hours)
2222nd
4848
5050
>1000 >1000 >1000> 1000> 1000> 1000
Als Lebensdauer wurde diejenige Zeit gemessen, die verging, bis der flüssige Kristall Schaumbildung und Anzeichen von Vergilbung zeigte. Die Tabelle zeigt, daß die Lebensdauer bei Verwendung von Titan, Zirkon oder Palladium als Komponente der negativen Elektrode außerordentlich stark verlängert wurde.The lifetime was measured as the time it took for the liquid crystal to foam and Showed signs of yellowing. The table shows that the service life when using titanium, zirconium or palladium as a component of the negative electrode has been extremely elongated.
Claims (1)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6234371A JPS5137018B2 (en) | 1971-08-18 | 1971-08-18 | |
JP7832471A JPS4843896A (en) | 1971-10-07 | 1971-10-07 | |
JP1972009524U JPS524940Y2 (en) | 1972-01-24 | 1972-01-24 | |
JP2306872U JPS5153183Y2 (en) | 1972-02-26 | 1972-02-26 |
Publications (3)
Publication Number | Publication Date |
---|---|
DE2264702A1 DE2264702A1 (en) | 1974-08-01 |
DE2264702B2 true DE2264702B2 (en) | 1977-12-22 |
DE2264702C3 DE2264702C3 (en) | 1978-08-31 |
Family
ID=27455198
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE2264702A Expired DE2264702C3 (en) | 1971-08-18 | 1972-08-18 | Liquid crystal element |
DE2240781A Ceased DE2240781B2 (en) | 1971-08-18 | 1972-08-18 | Liquid crystal cells |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE2240781A Ceased DE2240781B2 (en) | 1971-08-18 | 1972-08-18 | Liquid crystal cells |
Country Status (2)
Country | Link |
---|---|
US (2) | US3932024A (en) |
DE (2) | DE2264702C3 (en) |
Families Citing this family (63)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT323249B (en) * | 1972-07-03 | 1975-06-25 | Electrovac | LIQUID CRYSTAL CELL |
CH557071A (en) * | 1973-09-07 | 1974-12-13 | Bbc Brown Boveri & Cie | METHOD FOR MANUFACTURING LIQUID CRYSTAL CELLS, AFTER-MANUFACTURING LIQUID CRYSTAL CELLS AND APPLICATION OF LIQUID CRYSTAL CELLS AS DISPLAY ELEMENTS. |
US4106860A (en) * | 1973-09-07 | 1978-08-15 | Bbc Brown Boveri & Company Limited | Liquid-crystal cell |
US4086003A (en) * | 1974-07-15 | 1978-04-25 | Kabushiki Kaisha Suwa Seikosha | Electrochromic display cell |
DE2534783C2 (en) * | 1974-08-14 | 1983-05-05 | Kabushiki Kaisha Seikosha, Tokyo | Electro-optical display device |
JPS5935195B2 (en) * | 1975-03-12 | 1984-08-27 | セイコーエプソン株式会社 | digital watch |
US4140378A (en) * | 1975-08-09 | 1979-02-20 | Canon Kabushiki Kaisha | View finder device having liquid crystal cell |
US4037930A (en) * | 1976-04-05 | 1977-07-26 | Hitachi, Ltd. | Liquid crystal display cells |
US4183629A (en) * | 1976-07-21 | 1980-01-15 | Citizen Watch Co. Ltd. | Electronic optical display device and method of manufacturing the same |
CH618282A5 (en) * | 1976-07-23 | 1980-07-15 | Sharp Kk | |
CH610668A5 (en) * | 1977-02-11 | 1979-04-30 | Bbc Brown Boveri & Cie | Partially transparent reflector on liquid-crystal displays and method for producing it |
JPS5412761A (en) * | 1977-06-29 | 1979-01-30 | Sharp Corp | Display device |
DE2735493C2 (en) * | 1977-08-05 | 1981-10-15 | Siemens AG, 1000 Berlin und 8000 München | A method for manufacturing a liquid crystal cell and a liquid crystal cell manufactured thereafter |
US4128312A (en) * | 1977-10-04 | 1978-12-05 | Hughes Aircraft Company | Long life reflective liquid crystal display for dc operation |
DE2910779C3 (en) * | 1979-03-19 | 1981-11-19 | Siemens AG, 1000 Berlin und 8000 München | Display module with an electro-optical display device |
IL58213A (en) * | 1979-09-10 | 1984-05-31 | Stolov Michael | Electronically controlled multicolor display |
JPS56122011A (en) * | 1980-02-29 | 1981-09-25 | Sharp Corp | Sealing structure of liquid crystal panel |
US4362903A (en) * | 1980-12-29 | 1982-12-07 | General Electric Company | Electrical conductor interconnect providing solderable connections to hard-to-contact substrates, such as liquid crystal cells |
JP2721497B2 (en) * | 1984-03-19 | 1998-03-04 | ケント・ステート・ユニバーシティ | Method for producing light modulating substance |
US4671618A (en) * | 1986-05-22 | 1987-06-09 | Wu Bao Gang | Liquid crystalline-plastic material having submillisecond switch times and extended memory |
US4685771A (en) * | 1985-09-17 | 1987-08-11 | West John L | Liquid crystal display material comprising a liquid crystal dispersion in a thermoplastic resin |
US4673255A (en) * | 1986-05-22 | 1987-06-16 | John West | Method of controlling microdroplet growth in polymeric dispersed liquid crystal |
JPS6444336A (en) * | 1987-08-10 | 1989-02-16 | Nissan Motor | Vehicle display device |
EP0402170B1 (en) * | 1989-06-09 | 1994-11-09 | Sharp Kabushiki Kaisha | Liquid crystal display device |
US5910854A (en) | 1993-02-26 | 1999-06-08 | Donnelly Corporation | Electrochromic polymeric solid films, manufacturing electrochromic devices using such solid films, and processes for making such solid films and devices |
FR2704074B1 (en) * | 1993-04-15 | 1995-06-02 | France Telecom | Method for producing a display cell with counter-electrode recovery. |
US5668663A (en) | 1994-05-05 | 1997-09-16 | Donnelly Corporation | Electrochromic mirrors and devices |
JP3881092B2 (en) * | 1997-07-10 | 2007-02-14 | シチズン時計株式会社 | LCD panel |
US6891563B2 (en) | 1996-05-22 | 2005-05-10 | Donnelly Corporation | Vehicular vision system |
US5867236A (en) * | 1996-05-21 | 1999-02-02 | Rainbow Displays, Inc. | Construction and sealing of tiled, flat-panel displays |
US5953094A (en) * | 1997-04-04 | 1999-09-14 | Sanyo Electric Co., Ltd. | Liquid crystal display device |
US6326613B1 (en) | 1998-01-07 | 2001-12-04 | Donnelly Corporation | Vehicle interior mirror assembly adapted for containing a rain sensor |
US8294975B2 (en) | 1997-08-25 | 2012-10-23 | Donnelly Corporation | Automotive rearview mirror assembly |
US6172613B1 (en) * | 1998-02-18 | 2001-01-09 | Donnelly Corporation | Rearview mirror assembly incorporating vehicle information display |
US6124886A (en) | 1997-08-25 | 2000-09-26 | Donnelly Corporation | Modular rearview mirror assembly |
WO1999028782A1 (en) * | 1997-12-04 | 1999-06-10 | Flat Panel Display Co. (Fpd) B.V. | Display device |
US6445287B1 (en) | 2000-02-28 | 2002-09-03 | Donnelly Corporation | Tire inflation assistance monitoring system |
US8288711B2 (en) | 1998-01-07 | 2012-10-16 | Donnelly Corporation | Interior rearview mirror system with forwardly-viewing camera and a control |
EP1550902A3 (en) * | 1998-02-04 | 2006-03-01 | Seiko Epson Corporation | Liquid crystal device and electronic apparatus |
US6477464B2 (en) | 2000-03-09 | 2002-11-05 | Donnelly Corporation | Complete mirror-based global-positioning system (GPS) navigation solution |
US6693517B2 (en) * | 2000-04-21 | 2004-02-17 | Donnelly Corporation | Vehicle mirror assembly communicating wirelessly with vehicle accessories and occupants |
US6329925B1 (en) | 1999-11-24 | 2001-12-11 | Donnelly Corporation | Rearview mirror assembly with added feature modular display |
EP1263626A2 (en) | 2000-03-02 | 2002-12-11 | Donnelly Corporation | Video mirror systems incorporating an accessory module |
US7167796B2 (en) | 2000-03-09 | 2007-01-23 | Donnelly Corporation | Vehicle navigation system for use with a telematics system |
WO2004058540A2 (en) * | 2002-12-20 | 2004-07-15 | Donnelly Corporation | Accessory system for vehicle |
US7370983B2 (en) | 2000-03-02 | 2008-05-13 | Donnelly Corporation | Interior mirror assembly with display |
US7255451B2 (en) | 2002-09-20 | 2007-08-14 | Donnelly Corporation | Electro-optic mirror cell |
US7581859B2 (en) | 2005-09-14 | 2009-09-01 | Donnelly Corp. | Display device for exterior rearview mirror |
ATE363413T1 (en) | 2001-01-23 | 2007-06-15 | Donnelly Corp | IMPROVED VEHICLE LIGHTING SYSTEM |
US6950220B2 (en) * | 2002-03-18 | 2005-09-27 | E Ink Corporation | Electro-optic displays, and methods for driving same |
US6918674B2 (en) * | 2002-05-03 | 2005-07-19 | Donnelly Corporation | Vehicle rearview mirror system |
WO2003105099A1 (en) * | 2002-06-06 | 2003-12-18 | Donnelly Corporation | Interior rearview mirror system with compass |
US7329013B2 (en) | 2002-06-06 | 2008-02-12 | Donnelly Corporation | Interior rearview mirror system with compass |
US7310177B2 (en) | 2002-09-20 | 2007-12-18 | Donnelly Corporation | Electro-optic reflective element assembly |
WO2004103772A2 (en) | 2003-05-19 | 2004-12-02 | Donnelly Corporation | Mirror assembly for vehicle |
AU2003278863A1 (en) | 2002-09-20 | 2004-04-08 | Donnelly Corporation | Mirror reflective element assembly |
US7446924B2 (en) | 2003-10-02 | 2008-11-04 | Donnelly Corporation | Mirror reflective element assembly including electronic component |
US7308341B2 (en) | 2003-10-14 | 2007-12-11 | Donnelly Corporation | Vehicle communication system |
ATE517368T1 (en) | 2005-05-16 | 2011-08-15 | Donnelly Corp | VEHICLE MIRROR ARRANGEMENT WITH CHARACTER ON THE REFLECTIVE PART |
CN101535087B (en) | 2005-11-01 | 2013-05-15 | 唐纳利公司 | Interior rearview mirror with display |
US8154418B2 (en) | 2008-03-31 | 2012-04-10 | Magna Mirrors Of America, Inc. | Interior rearview mirror system |
US8848158B2 (en) | 2008-07-01 | 2014-09-30 | Gentex Corporation | Liquid crystal display device and associated liquid crystal media for use in the same |
US7803285B2 (en) * | 2008-07-01 | 2010-09-28 | Gentex Corporation | Liquid crystal display device and associated liquid crystal media for use in the same |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2387745A (en) * | 1943-02-16 | 1945-10-30 | Libbey Owens Ford Glass Co | Mirror and reflector |
US3600060A (en) * | 1968-02-23 | 1971-08-17 | Ncr Co | Display device containing minute droplets of cholesteric liquid crystals in a substantially continuous polymeric matrix |
US3614210A (en) * | 1969-11-06 | 1971-10-19 | Rca Corp | Liquid crystal day/night mirror |
US3748017A (en) * | 1970-06-05 | 1973-07-24 | K Yamamura | Electrodes for liquid crystal display device |
US3751137A (en) * | 1971-10-18 | 1973-08-07 | Rockwell International Corp | Liquid crystal display device |
US3748018A (en) * | 1972-02-09 | 1973-07-24 | American Micro Syst | Universal transmission reflectance mode liquid crystal display |
-
1972
- 1972-08-18 DE DE2264702A patent/DE2264702C3/en not_active Expired
- 1972-08-18 DE DE2240781A patent/DE2240781B2/en not_active Ceased
-
1973
- 1973-08-16 US US05/389,072 patent/US3932024A/en not_active Expired - Lifetime
-
1974
- 1974-08-19 US US05/498,339 patent/US3947090A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE2264702A1 (en) | 1974-08-01 |
DE2264702C3 (en) | 1978-08-31 |
US3932024A (en) | 1976-01-13 |
US3947090A (en) | 1976-03-30 |
DE2240781A1 (en) | 1973-02-22 |
DE2240781B2 (en) | 1979-05-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C3 | Grant after two publication steps (3rd publication) | ||
8328 | Change in the person/name/address of the agent |
Free format text: STREHL, P., DIPL.-ING. DIPL.-WIRTSCH.-ING. SCHUEBEL-HOPF, U., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 8000 MUENCHEN |
|
8339 | Ceased/non-payment of the annual fee |