DE20202609U1 - Colorants containing (1,1'-biphenyl) -3,5-diamine derivatives and new (1,1'-biphenyl) -3,5-diamine derivatives - Google Patents

Colorants containing (1,1'-biphenyl) -3,5-diamine derivatives and new (1,1'-biphenyl) -3,5-diamine derivatives

Info

Publication number
DE20202609U1
DE20202609U1 DE20202609U DE20202609U DE20202609U1 DE 20202609 U1 DE20202609 U1 DE 20202609U1 DE 20202609 U DE20202609 U DE 20202609U DE 20202609 U DE20202609 U DE 20202609U DE 20202609 U1 DE20202609 U1 DE 20202609U1
Authority
DE
Germany
Prior art keywords
group
amino
diamino
hydrogen
benzene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE20202609U
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Deutschland GmbH
Original Assignee
Wella GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wella GmbH filed Critical Wella GmbH
Priority to DE20202609U priority Critical patent/DE20202609U1/en
Publication of DE20202609U1 publication Critical patent/DE20202609U1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/52—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/347—Phenols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35—Ketones, e.g. benzophenone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/415—Aminophenols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/49—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton
    • C07C211/50—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton with at least two amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/51—Phenylenediamines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C215/00—Compounds containing amino and hydroxy groups bound to the same carbon skeleton
    • C07C215/74—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/78—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C07C217/80—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C225/00—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones
    • C07C225/22—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/58—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/31—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
    • C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
    • C07D317/50—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to atoms of the carbocyclic ring
    • C07D317/58—Radicals substituted by nitrogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/32—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using oxidation dyes

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Cosmetics (AREA)

Description

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßt The description text was not recorded electronically  

Der Beschreibungstext wurde nicht elektronisch erfaßtThe description text was not recorded electronically

Claims (13)

1. Mittel zur oxidativen Färbung von Keratinfasern auf der Basis einer Entwicklersubstanz-Kupplersubstanz-Kombination, dadurch gekenn­ zeichnet, dass es als Kupplersubstanz mindestens ein [1,1'-Biphenyl]-3,5- diamin-Derivat der Formel (I) oder dessen Salz mit einer anorganischen oder organischen Säure enthält,
worin
R1 gleich Wasserstoff, einem Halogenatom, einer C1-C4-Alkoxygruppe, einer C1-C4 Hydroxyalkoxygruppe, einer C1-C6-Alkylgruppe, einer C1-C4- Alkylthioethergruppe, einer Trifluormethangruppe, einer -Si(CH3)3-Gruppe, einer C1-C4-Hydroxyalkylgruppe oder einer C2-C4 Dihydroxyalkylgruppe ist;
R2, R3, R4, R5, R6 gleich oder verschieden sein können und unabhängig voneinander Wasserstoff, ein Halogenatom, eine Cyanogruppe, eine Hydroxygruppe, eine C1-C4-Alkoxygruppe, eine C1-C4-Hydroxyalkoxy­ gruppe, eine C1-C6-Alkylgruppe, eine C1-C4-Alkyl-thioethergruppe, eine Mercaptogruppe, eine Nitrogruppe, eine Amino-gruppe (NH2), eine C1-C4- Monoalkylaminogruppe, eine Di(C1-C4)-alkyl-aminogruppe, eine Trifluor­ methangruppe eine -C(O)H-Gruppe, eine -C(O)CH3-Gruppe, eine -C(O)CF3-Gruppe, eine -Si(CH3)3-Gruppe, eine C1-C4-Hydroxyalkyl­ gruppe, eine C2-C4 Dihydroxyalkylgruppe, eine -CH=CHR7-Gruppe, eine -(CH2)p-CO2R8-Gruppe oder eine -(CH2)p-R9-Gruppe mit p = 1, 2, 3 oder 4, eine -C(R10)=NR11-Gruppe oder eine C(R13)H-NR14R15-Gruppe bedeuten, oder zwei nebeneinanderliegende Reste R2 bis R6 eine -O-CH2-O-Brücke bilden;
R7 gleich Wasserstoff, einer Nitrogruppe, einer CO2R8-Gruppe oder einer -C(O)CH3-Gruppe ist;
R8, R10 und R13 gleich oder verschieden sein können und unabhängig voneinander gleich Wasserstoff oder einer C1-C4-Alkylgruppe sind;
R9 gleich einer Aminogruppe oder einer Nitrilgruppe ist;
R11, R14 und R15 gleich oder verschieden sein können und unabhängig voneinander gleich Wasserstoff, einer Hydroxygruppe, einer C1-C4-Alkyl­ gruppe, einer C1-C4-Hydroxyalkylgruppe, einer C2-C4-Dihydroxyalkyl- gruppe oder einem Rest der Formel
sind;
R12 gleich Wasserstoff, einer Aminogruppe oder einer Hydroxygruppe ist; unter der Bedingung, dass die Verbindung der Formel (I) kein Inversions­ zentrum aufweist.1. Agent for the oxidative dyeing of keratin fibers on the basis of a developer substance -coupler substance combination, characterized in that it contains at least one [1,1'-biphenyl] -3,5-diamine derivative of the formula (I) or as a coupler substance whose salt contains an inorganic or organic acid,
wherein
R1 is hydrogen, a halogen atom, a C 1 -C 4 alkoxy group, a C 1 -C 4 hydroxyalkoxy group, a C 1 -C 6 alkyl group, a C 1 -C 4 alkylthioether group, a trifluoromethane group, a -Si (CH 3 ) 3 group, a C 1 -C 4 hydroxyalkyl group or a C 2 -C 4 dihydroxyalkyl group;
R2, R3, R4, R5, R6 can be the same or different and, independently of one another, hydrogen, a halogen atom, a cyano group, a hydroxy group, a C 1 -C 4 alkoxy group, a C 1 -C 4 hydroxyalkoxy group, a C 1 -C 6 alkyl group, a C 1 -C 4 alkyl thioether group, a mercapto group, a nitro group, an amino group (NH2), a C 1 -C 4 monoalkylamino group, a di (C 1 -C 4 ) - alkyl-amino group, a trifluoromethane group, a -C (O) H group, a -C (O) CH 3 group, a -C (O) CF 3 group, an -Si (CH 3 ) 3 group, a C 1 -C 4 hydroxyalkyl group, a C 2 -C 4 dihydroxyalkyl group, a -CH = CHR7 group, a - (CH 2 ) p -CO 2 R8 group or a - (CH 2 ) p -R9- Group with p = 1, 2, 3 or 4, a -C (R10) = NR11 group or a C (R13) H-NR14R15 group, or two adjacent radicals R2 to R6 are an -O-CH 2 -O -Building a bridge;
R7 is hydrogen, a nitro group, a CO 2 R8 group or a -C (O) CH 3 group;
R8, R10 and R13 may be the same or different and, independently of one another, are hydrogen or a C 1 -C 4 -alkyl group;
R9 is an amino group or a nitrile group;
R11, R14 and R15 may be the same or different and, independently of one another, are the same as hydrogen, a hydroxyl group, a C 1 -C 4 -alkyl group, a C 1 -C 4 -hydroxyalkyl group, a C 2 -C 4 -dihydroxyalkyl group or one Rest of the formula
are;
R12 is hydrogen, an amino group or a hydroxy group; provided that the compound of formula (I) has no center of inversion. 2. Mittel nach Anspruch 1, dadurch gekennzeichnet, dass R1 gleich Wasserstoff ist.2. Composition according to claim 1, characterized in that R1 is the same Is hydrogen. 3. Mittel nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass R1 gleich Wasserstoff ist und mindestens 3 der Reste R2 bis R6 Wasserstoff bedeuten.3. Means according to claim 1 or 2, characterized in that R1 is hydrogen and at least 3 of the radicals R2 to R6 are hydrogen mean. 4. Mittel nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass R1 gleich Wasserstoff ist, 3 der Reste R2 bis R6 gleich Wasserstoff sind und die beiden verbleibenden Reste R2 bis R6 unabhängig voneinander Wasserstoff, Fluor, eine Methoxygruppe, eine Hydroxy­ gruppe, eine Methylgruppe oder eine Aminogruppe darstellen.4. Agent according to one of claims 1 to 3, characterized in that R1 is hydrogen, 3 of the radicals R2 to R6 are hydrogen and the two remaining residues R2 to R6 are independent  from each other hydrogen, fluorine, a methoxy group, a hydroxy represent a group, a methyl group or an amino group. 5. Mittel nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass das [1,1'-Biphenyl]-3,5-diamin-Derivat der Formel (I) ausgewählt ist aus Biphenyl-3,5-diamin; 4-Benzo[1,3]dioxol-5-yl-benzol-1,3-diamin; 3',5'-Diamino-biphenyl-4-ol; 4'-Fluor-biphenyl-3,5-diamin; 4'-Amino­ biphenyl-3,5-diamin; 3'-Hydroxy-biphenyl-3,5-diamin; 4'-Methoxy­ biphenyl-3,5-diamin sowie deren physiologisch verträglichen Salzen.5. Agent according to one of claims 1 to 4, characterized in that the [1,1'-biphenyl] -3,5-diamine derivative of formula (I) is selected from biphenyl-3,5-diamine; 4-Benzo [1,3] dioxol-5-yl-benzene-1,3-diamine; 3 ', 5'-diamino-biphenyl-4-ol; 4'-fluoro-biphenyl-3,5-diamine; 4'-Amino biphenyl-3,5-diamine; 3'-hydroxy-biphenyl-3,5-diamine; 4'-methoxy biphenyl-3,5-diamine and their physiologically tolerable salts. 6. Mittel nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass das [1,1'-Biphenyl]-3,5-diamin der Formel (I) in einer Menge von 0,005 bis 20 Gewichtsprozent enthalten ist.6. Agent according to one of claims 1 to 5, characterized in that the [1,1'-biphenyl] -3,5-diamine of the formula (I) in an amount of 0.005 to 20 weight percent is included. 7. Mittel nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass die Entwicklersubstanz ausgewählt ist aus der Gruppe bestehend aus 1,4-Diaminobenzol, 1,4-Diamino-2-methyl-benzol, 1,4-Diamino-2,6- dimethyl-benzol, 1,4-Diamino-3,5-diethyl-benzol, 1,4-Diamino-2,5- dimethyl-benzol, 1,4-Diamino-2,3-dimethyl-benzol, 2-Chlor-1,4-diamino­ benzol, 1,4-Diamino-2-(thiophen-2-yl)benzol, 1,4-Diamino-2-(thiophen-3- yl)benzol, 1,4-Diamino-2-(pyridin-3-yl)benzol, 2,5-Diamino-biphenyl, 1,4-Diamino-2-methoxymethyl-benzol, 1,4-Diamino-2-aminomethyl- benzol, 1,4-Diamino-2-hydroxymethyl-benzol, 1,4-Diamino-2-(2- hydroxyethoxy)-benzol, 1-(2,5-Diamino-phenyl)-ethanol, 2-(2-(Acetyl­ amino)ethoxy)-1,4-diamino-benzol, 4-Phenylamino-anilin, 4-Dimethylamino-anilin, 4-Diethylamino-anilin, 4-Dipropylamino-anilin, 4-[Ethyl(2-hydroxyethyl)amino]-anilin, 4-[Di(2-hydroxyethyl)amino]-anilin, 4-[Di(2-hydroxyethyl)amino]-2-methyl-anilin, 4-[(2-Methoxyethyl)amino]- anilin, 4-[(3-Hydroxypropyl)amino]-anilin, 4-[(2,3-Dihydroxypropyl)amino]- anilin, 1,4-Diamino-2-(2-hydroxyethyl)-benzol, 1,4-Diamino-2-(1-methyl- ethyl)-benzol, 1,3-Bis[(4-aminophenyl)(2-hydroxyethyl)amino]-2-propanol, 1,4-Bis[(4-Aminophenyl)amino]-butan, 1,8-Bis(2,5-diaminophenoxy)-3,6- dioxaoctan, 4-Amino-phenol, 4-Amino-3-methyl-phenol, 4-Amino-3- (hydroxymethyl)-phenol, 4-Amino-3-fluor-phenol, 4-Methylamino-phenol, 4-Amino-2-(aminomethyl)-phenol, 4-Amino-2-(hydroxymethyl)-phenol, 4-Amino-2-fluor-phenol, 4-Amino-2-[(2-hydroxyethyl)-amino]methyl- phenol, 4-Amino-2-methyl-phenol, 4-Amino-2-(methoxymethyl)-phenol, 4-Amino-2-(2-hydroxyethyl)-phenol, 5-Amino-salicylsäure, 2,5-Diamino­ pyridin, 2,4,5,6-Tetraamino-pyrimidin, 2,5,6-Triamino-4-(1H)-pyrimidon, 4,5-Diamino-1-(2-hydroxyethyl)-1H-pyrazol, 4,5-Diamino-1-(1-methyl- ethyl)-1H-pyrazol, 4,5-Diamino-1-[(4-methylphenyl)methyl]-1H-pyrazol, 1-[(4-Chlorphenyl)methyl]-4,5-diamino-1H-pyrazol, 4,5-Diamino-1-methyl- 1H-pyrazol, 4,5-Diamino-3-methyl-1-methyl-1H-pyrazol, 4,5-Diamino-3- methyl-1-methyl-1H-pyrazol, 2-Amino-phenol, 2-Amino-6-methyl-phenol und 2-Amino-5-methyl-phenol.7. Agent according to one of claims 1 to 6, characterized in that the developer substance is selected from the group consisting of from 1,4-diaminobenzene, 1,4-diamino-2-methyl-benzene, 1,4-diamino-2,6- dimethyl-benzene, 1,4-diamino-3,5-diethyl-benzene, 1,4-diamino-2,5- dimethyl benzene, 1,4-diamino-2,3-dimethyl benzene, 2-chloro-1,4-diamino benzene, 1,4-diamino-2- (thiophene-2-yl) benzene, 1,4-diamino-2- (thiophene-3- yl) benzene, 1,4-diamino-2- (pyridin-3-yl) benzene, 2,5-diamino-biphenyl, 1,4-diamino-2-methoxymethyl-benzene, 1,4-diamino-2-aminomethyl- benzene, 1,4-diamino-2-hydroxymethyl-benzene, 1,4-diamino-2- (2- hydroxyethoxy) benzene, 1- (2,5-diaminophenyl) ethanol, 2- (2- (acetyl amino) ethoxy) -1,4-diamino-benzene, 4-phenylamino-aniline, 4-dimethylamino-aniline, 4-diethylamino-aniline, 4-dipropylamino-aniline, 4- [ethyl (2-hydroxyethyl) amino] aniline, 4- [di (2-hydroxyethyl) amino] aniline, 4- [di (2-hydroxyethyl) amino] -2-methyl-aniline, 4 - [(2-methoxyethyl) amino] -  aniline, 4 - [(3-hydroxypropyl) amino] aniline, 4 - [(2,3-dihydroxypropyl) amino] - aniline, 1,4-diamino-2- (2-hydroxyethyl) benzene, 1,4-diamino-2- (1-methyl- ethyl) benzene, 1,3-bis [(4-aminophenyl) (2-hydroxyethyl) amino] -2-propanol, 1,4-bis [(4-aminophenyl) amino] butane, 1,8-bis (2,5-diaminophenoxy) -3,6- dioxaoctane, 4-amino-phenol, 4-amino-3-methyl-phenol, 4-amino-3- (hydroxymethyl) phenol, 4-amino-3-fluoro-phenol, 4-methylamino-phenol, 4-amino-2- (aminomethyl) phenol, 4-amino-2- (hydroxymethyl) phenol, 4-amino-2-fluoro-phenol, 4-amino-2 - [(2-hydroxyethyl) amino] methyl- phenol, 4-amino-2-methylphenol, 4-amino-2- (methoxymethyl) phenol, 4-amino-2- (2-hydroxyethyl) phenol, 5-amino salicylic acid, 2,5-diamino pyridine, 2,4,5,6-tetraaminopyrimidine, 2,5,6-triamino-4- (1H) pyrimidone, 4,5-diamino-1- (2-hydroxyethyl) -1H-pyrazole, 4,5-diamino-1- (1-methyl- ethyl) -1H-pyrazole, 4,5-diamino-1 - [(4-methylphenyl) methyl] -1H-pyrazole, 1 - [(4-chlorophenyl) methyl] -4,5-diamino-1H-pyrazole, 4,5-diamino-1-methyl- 1H-pyrazole, 4,5-diamino-3-methyl-1-methyl-1H-pyrazole, 4,5-diamino-3- methyl-1-methyl-1H-pyrazole, 2-amino-phenol, 2-amino-6-methyl-phenol and 2-amino-5-methylphenol. 8. Mittel einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass es zusätzlich mindestens eine weitere Kupplersubstanz und/oder mindestens einen direktziehenden Farbstoff enthält.8. Means one of claims 1 to 7, characterized in that it additionally at least one further coupler substance and / or contains at least one substantive dye. 9. Mittel nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass die Entwicklersubstanzen und zusätzlichen Kupplersubstanzen, bezogen auf die Gesamtmenge des Färbemittels, jeweils in einer Gesamtmenge von 0,005 bis 20 Gewichtsprozent enthalten sind. 9. Composition according to one of claims 1 to 8, characterized in that the developer substances and additional coupler substances, based on the total amount of the colorant, each in one Total amount from 0.005 to 20 percent by weight are included.   10. Mittel nach einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, dass es vor der Anwendung mit dem Oxidationsmittel in einem Gewichts­ verhältnis von 5 : 1 bis 1 : 3 vermischt wird.10. Agent according to one of claims 1 to 9, characterized in that it is in one weight with the oxidizer before use ratio of 5: 1 to 1: 3 is mixed. 11. Mittel nach Anspruch 10, dadurch gekennzeichnet, dass das gebrauchsfertige Oxidationsfärbemittel einen pH-Wert von 3 bis 11,5 aufweist.11. Means according to claim 10, characterized in that the ready-to-use oxidation colorants have a pH of 3 to 11.5 having. 12. Mittel nach einem der Ansprüche 1 bis 11, dadurch gekenn­ zeichnet, dass es ein Haarfärbemittel ist.12. Composition according to one of claims 1 to 11, characterized records that it is a hair dye. 13. [1,1'-Biphenyl]-3,5-diamin-Derivate der allgemeinen Formel (II),
worin
R1 gleich Wasserstoff, einem Halogenatom, einer C1-C4-Alkoxygruppe, einer C1-C4-Hydroxyalkoxygruppe, einer C1-C6-Alkylgruppe, einer C1-C4- Alkylthioethergruppe, einer Trifluormethangruppe, einer -Si(CH3)3-Gruppe, einer C1-C4-Hydroxyalkylgruppe oder einer C2-C4 Dihydroxyalkylgruppe ist;
R2, R3, R4, R5, R6 gleich oder verschieden sein können und unabhängig voneinander Wasserstoff, ein Halogenatom, eine Cyanogruppe, eine Hydroxygruppe, eine C1-C4-Alkoxygruppe, eine C1-C4-Hydroxyalkoxy­ gruppe, eine C1-C6-Alkylgruppe, eine C1-C4-Alkylthioethergruppe, eine Mercaptogruppe, eine Nitrogruppe, eine Amino-gruppe (NH2), eine C1-C4- Monoalkylaminogruppe, eine Di(C1-C4)-alkyl-aminogruppe, eine Trifluor­ methangruppe eine -C(O)H-Gruppe, eine -C(O)CH3-Gruppe, eine -C(O)CF3-Gruppe, eine -Si(CH3)3-Gruppe, eine C1-C4-Hydroxyalkyl­ gruppe, eine C2-C4 Dihydroxyalkylgruppe, eine -CH=CHR7-Gruppe, eine -(CH2)p-CO2R8-Gruppe oder eine -(CH2)p-R9-Gruppe mit p = 1, 2, 3 oder 4, eine -C(R10)=NR11-Gruppe oder eine C(R13)H-NR14R15-Gruppe bedeuten, oder zwei nebeneinanderliegende Reste R2 bis R6 eine -O-CH2-O-Brücke bilden;
R7 gleich Wasserstoff, einer Nitrogruppe, einer CO2R8-Gruppe oder einer -C(O)CH3-Gruppe ist;
R8, R10 und R13 gleich oder verschieden sein können und unabhängig voneinander gleich Wasserstoff oder einer C1-C4-Alkylgruppe sind;
R9 gleich einer Aminogruppe oder einer Nitrilgruppe ist;
R11, R14 und R15 gleich oder verschieden sein können und unabhängig voneinander gleich Wasserstoff, einer Hydroxygruppe, einer C1-C4-Alkyl­ gruppe, einer C1-C4-Hydroxyalkylgruppe, einer C2-C4-Dihydroxyalkyl­ gruppe oder einem Rest der Formel
sind;
R12 gleich Wasserstoff, einer Aminogruppe oder einer Hydroxygruppe ist;
unter den Bedingungen, dass dies Verbindung der Formel (II) kein Inversionszentrum aufweist, und mindestens einer der Rest R2 bis R6 nicht gleich Wasserstoff ist und R4 nicht gleich einer Hydroxygruppe ist, wenn gilt R2=R3=R5=R6=Wasserstoff.13. [1,1'-biphenyl] -3,5-diamine derivatives of the general formula (II),
wherein
R1 is hydrogen, a halogen atom, a C 1 -C 4 alkoxy group, a C 1 -C 4 hydroxyalkoxy group, a C 1 -C 6 alkyl group, a C 1 -C 4 alkylthioether group, a trifluoromethane group, a -Si ( CH 3 ) 3 group, a C 1 -C 4 hydroxyalkyl group or a C 2 -C 4 dihydroxyalkyl group;
R2, R3, R4, R5, R6 can be the same or different and independently of one another hydrogen, a halogen atom, a cyano group, a hydroxy group, a C 1 -C 4 alkoxy group, a C 1 -C 4 hydroxyalkoxy group, a C 1 -C 6 alkyl group, a C 1 -C 4 alkyl thioether group, a mercapto group, a nitro group, an amino group (NH 2 ), a C 1 -C 4 monoalkylamino group, a di (C 1 -C 4 ) alkyl -amino group, a trifluoromethane group, a -C (O) H group, a -C (O) CH 3 group, a -C (O) CF 3 group, a -Si (CH 3 ) 3 group, a C 1 -C 4 hydroxyalkyl group, a C 2 -C 4 dihydroxyalkyl group, a -CH = CHR7 group, a - (CH 2 ) p -CO 2 R8 group or a - (CH 2 ) p -R9 group with p = 1, 2, 3 or 4, is a -C (R10) = NR11 group or a C (R13) H-NR14R15 group, or two adjacent radicals R2 to R6 are an -O-CH 2 -O- Build a bridge;
R7 is hydrogen, a nitro group, a CO 2 R8 group or a -C (O) CH 3 group;
R8, R10 and R13 may be the same or different and, independently of one another, are hydrogen or a C 1 -C 4 -alkyl group;
R9 is an amino group or a nitrile group;
R11, R14 and R15 may be the same or different and, independently of one another, are the same as hydrogen, a hydroxyl group, a C 1 -C 4 -alkyl group, a C 1 -C 4 -hydroxyalkyl group, a C 2 -C 4 -dihydroxyalkyl group or a radical of the formula
are;
R12 is hydrogen, an amino group or a hydroxy group;
under the conditions that this compound of formula (II) has no inversion center and at least one of the radicals R2 to R6 is not hydrogen and R4 is not a hydroxyl group if R2 = R3 = R5 = R6 = hydrogen.
DE20202609U 2001-03-13 2002-02-20 Colorants containing (1,1'-biphenyl) -3,5-diamine derivatives and new (1,1'-biphenyl) -3,5-diamine derivatives Expired - Lifetime DE20202609U1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE20202609U DE20202609U1 (en) 2001-03-13 2002-02-20 Colorants containing (1,1'-biphenyl) -3,5-diamine derivatives and new (1,1'-biphenyl) -3,5-diamine derivatives

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10111937 2001-03-13
DE20202609U DE20202609U1 (en) 2001-03-13 2002-02-20 Colorants containing (1,1'-biphenyl) -3,5-diamine derivatives and new (1,1'-biphenyl) -3,5-diamine derivatives

Publications (1)

Publication Number Publication Date
DE20202609U1 true DE20202609U1 (en) 2002-06-20

Family

ID=7677221

Family Applications (1)

Application Number Title Priority Date Filing Date
DE20202609U Expired - Lifetime DE20202609U1 (en) 2001-03-13 2002-02-20 Colorants containing (1,1'-biphenyl) -3,5-diamine derivatives and new (1,1'-biphenyl) -3,5-diamine derivatives

Country Status (1)

Country Link
DE (1) DE20202609U1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004002604A1 (en) * 2004-01-15 2005-08-04 Beiersdorf Ag Visualization of sunscreen on the skin
CN112538031A (en) * 2020-12-02 2021-03-23 吉林奥来德光电材料股份有限公司 Antioxidant for thin film packaging, composition and application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004002604A1 (en) * 2004-01-15 2005-08-04 Beiersdorf Ag Visualization of sunscreen on the skin
CN112538031A (en) * 2020-12-02 2021-03-23 吉林奥来德光电材料股份有限公司 Antioxidant for thin film packaging, composition and application thereof
CN112538031B (en) * 2020-12-02 2022-05-06 吉林奥来德光电材料股份有限公司 Antioxidant for thin film packaging, composition and application thereof

Similar Documents

Publication Publication Date Title
DE2760164C2 (en) 2,4-diaminophenol derivatives
DE2331009C2 (en) Colorants for human hair and pyridine-N-oxide-azo compounds
DE20206274U1 (en) 2,3-diaminophenol derivatives and oxidation hair colorants containing these compounds
DE20202609U1 (en) Colorants containing (1,1'-biphenyl) -3,5-diamine derivatives and new (1,1'-biphenyl) -3,5-diamine derivatives
DE10111936C1 (en) Hair dyes containing N-heteroarylmethyl-m-phenylenediamine derivatives and new N-heteroarylmethyl-m-phenylenediamine derivatives
US6685751B2 (en) Substituted 1,4-diaminobenzene compounds and oxidation dye precursor compositions containing same
DE10114084A1 (en) New 1,3-diamino-4-aminomethyl-benzene derivatives, useful as coupler substances in oxidative hair dye formulations based on a developer-coupler combination
EP1558204B1 (en) Means for colouring keratin fibres comprising 2-amino-5-ethylphenol
WO1995021603A1 (en) 2-fluoro-6-nitroanilines
DE102005005875A1 (en) 3-amino-2-aminomethyl-phenol derivatives and colorants containing these compounds
EP1392673A2 (en) 1,3-dihydroxybenzene derivatives and colorants containing said compounds
DE19813937C1 (en) Oxidation hair dye giving intense orange to red-brown shades
DE19922392C1 (en) Diaminobenzene derivatives and colorants containing these compounds
DE20217957U1 (en) Oxidative dyeing agent for keratin fibers uses 2-aminomethylene-substituted resorcinols as couplers, some of which are novel compounds
EP1355619B1 (en) Colouring agents for keratin fibres containing (1.1'-biphenyl)-2.4-diamine derivatives in addition to novel (1.1'-biphenyl)-2.4-diamine-derivatives
WO2002062783A1 (en) Dyes for keratin fibres containing 1,3-diamino-4-heteroarylbenzene derivatives and novel 1,3-diamino-4-heteroarylbenzene derivatives
EP1226107B1 (en) N-benzyl-p-phenylenediamine-derivatives containing colouring agents for keratin fibres and novel n-benzyl-p-phenylenediamine-derivatives
DE10125451A1 (en) New N-benzyl-m-phenylenediamine derivatives and physiologically-compatible, water-soluble salts are used in oxidative colorant for keratin fibers, especially human hair
DE10217270A1 (en) 3-Aminophenol derivatives substituted in the 2-position and colorants containing these compounds
DE29912881U1 (en) Medium for coloring keratin colors
WO2003017955A1 (en) Oxidation hair dyes containing 3-aminophenol derivatives, and novel 3-aminophenol derivatives
DE10102084A1 (en) New 1,4-diamino-2- (thiazol-2-yl) benzene derivatives and colorants containing these compounds
DE10251106A1 (en) Composition for oxidative dyeing of keratin fibre, especially human hair, based on a developer-coupler combination which also contains a 4-amino-biphenyl- 3-ol derivative or soluble salt thereof
DE102004004733A1 (en) Agent for dyeing keratin fibers containing 4- (2-hydroxyethyl) amino-3-nitro-1-trifluoromethylbenzene
DE29912882U1 (en) Medium for coloring keratin colors

Legal Events

Date Code Title Description
R207 Utility model specification

Effective date: 20020725

R150 Term of protection extended to 6 years

Effective date: 20050307

R151 Term of protection extended to 8 years

Effective date: 20080220

R152 Term of protection extended to 10 years

Effective date: 20100301

R081 Change of applicant/patentee

Owner name: WELLA GMBH, DE

Free format text: FORMER OWNER: WELLA AG, 64295 DARMSTADT, DE

Effective date: 20110720

R071 Expiry of right
R071 Expiry of right