DE202017106674U1 - Device for removing pollutants from the exhaust gas of a production plant - Google Patents

Abstract

Device (1) for removing pollutants (S), in particular particulate matter (F) and noxious gases, such as NO and NO _x, from an exhaust air mixture (U) of combustion chambers of a production plant, in particular a power plant and / or a factory, said at least one spraying device (7) sprays a liquid solvent (5), in particular water, into a space (R) associated with the production plant and contains the exhaust air mixture (U) and generates a spray and in particular an aerosol which contains the air in the exhaust air mixture (U) pollutants (S) present in this space (R), in particular suspended material particles PM, in particular PM ₁₀ , and harmful gases, for example NO and NO _x , are removed (S2), the space (R) being located in a channel (2) for discharging the exhaust gas of the combustion chamber (s) from the production plant is included.

Description

Technical field and definitions

The present invention relates to a device and a method for removing, in particular by means of binding due to adsorption and / or absorption, of pollutants, in particular dust, particulate matter and / or noxious gases, such as nitrogen oxides NO and NO _x , from a flue-emitting channel of a production plant, in particular a power plant and / or a factory.

In particular, particulate matter is a collective term for all solid material particles, which may also be referred to as material particles, in the air. These particles of material can float in or around the air.

Suspended dust can also be called total dust. Total dust can be called "totally suspended particulates" in English and shortened to TSP. In addition to dust, particulate matter can also be smoke and / or soot. The dust particles include dust and dust.

Nitrogen monoxide NO and nitrogen oxides NO _x are chemical compounds which are formed in particular during combustion processes and are discharged here in particular into combustion chambers of production plants, in particular power stations and / or factories, and of these in their exhaust gases to the ambient air. These are explicitly mentioned here as representative of all sorts of noxious gases that emit combustion chambers and are hazardous to health.

Ambient air here is in particular the air surrounding the power plant or the factory or enclosed by this or on this or above it.

A power plant or a factory has in particular a combustion chamber. There is a combustion of an organic fuel, such as gasoline, diesel, natural gas, biofuel, oil, coal, peat.

Exhaust gas of a production plant, for example a power plant or a factory, is the substance present after the combustion process in the combustion chamber of the power plant. This has conversion products from the combustion process. The combustion process is carried out on an organic, in particular fossil, energy source, for example gasoline, diesel, natural gas, biofuel. This present substance has pollutants, in particular dust, particulate matter and noxious gases, for example ozone, hydrocarbons, chlorofluorocarbons, benzene, carbon dioxide, nitrogen oxides, carbon monoxide, O and SO ₂ NO.

Production plants with conventional combustion chambers can emit soot as material particles, in particular as a result of incomplete combustion processes, smoke as a result of chemical and / or thermal processes, and dust as a result of mechanical processes and / or fluidization.

Dust is here in particular a collective term for all solid material particles, which can also be referred to as material particles, in the air within a production plant, in particular in the exhaust gas of a power plant or a factory.

Production plants can emit smoke as material particles, in particular due to chemical and / or thermal processes, and dust as a result of mechanical processes and / or fluidization.

In particular, in the case of production plants or factories as a result of friction, particles of material may be emitted which consist, for example, of metal and / or plastic material or have this material.

Depending on their diameters, the material particles emitted in particular by production plants or factories can have diameters larger than approximately 10 μm, at diameters smaller than approximately 10 μm inhalable and respirable particulate matter, at diameters smaller than approximately 2.5 μm, inhalable and respirable particulate matter and at diameters smaller than approximately 0, 1μm ultrafine particles also be inhalable and respirable particulate matter.

Fine dusts are therefore here in particular the collective term for the finest solid material particles, which can be swirled up in the air float for a long time, so that fine dusts are components of suspended matter. Fine dust is a part of the suspended dust.

The definition of particulate matter dates back to the "National Air Quality" standard for "Particualte Matter" introduced in 1987, which can be translated as "material particles", the standard being abbreviated to PM standard, the US Environmental Protection Agency EPA (Environmental Protection Agency) can be assigned. For example, PM ₁₀ is a category for particles whose diameter, in particular aerodynamic, is less than 10 μm.

PM ₁₀ material particles with, in particular aerodynamic, diameters smaller than 10 μm can be inhaled in particular by humans and Relatively easy to reach the lungs, especially of humans. In particular, these material particles are referred to as fine dust.

PM _2.5 material particles with, in particular aerodynamic, diameters smaller than 2.5 μm are also inhalable and can also enter the lungs, in particular of humans. Likewise, these material particles belong to the fine dust.

PM _0.1 material particles with, in particular aerodynamic, diameters smaller than 0.1 μm can likewise be referred to as UP particles, that is to say as "ultrafine material particles" and likewise belong to the fine dust. The relevant diameter here is less than 100nm.

PM _0.1 material particles and PM _2.5 material particles are constituents of and belong to the PM ₁₀ material particles. Soot is also assigned to the material particles.

From a health point of view, in addition to a biochemically negative pollutant content of a dust, the size of the material particles is a decisive parameter. Material particles PM with a diameter of greater than 10 μm, referred to as a scientific limit, which are defined as belonging to the coarse dust and counted for this, can in particular stochastically "hang on" or become attached to a larger proportion of nose hairs or mucous membranes of the nasopharynx be filtered from them and thus from breathing air. Smaller and smallest particles of PM ₁₀ can penetrate deep into the lungs via the trachea and bronchi. Therefore, particulate matter is also referred to as inhalable or respirable particulate matter. Due to its size, fine dust can not be directly detected or perceived by the human eye.

The possible harmful effects of individual air pollutants, such as ozone O ₃ , hydrocarbons CnHm, chlorofluorocarbons FC, benzene, CO ₂ nitric oxide NO, NO _x , CO, O, SO ₂ are shown in many scientific studies and studies. For example, reference may be made to the Federal Ministry for the Environment, Nature Conservation, Building and Nuclear Safety, 1987.

In particular, in agglomerations with a large number of production plants, in particular factories and / or power plants, the presence of suspended particles in the ambient air can be measured. For this purpose, a space associated with the metropolitan area can be defined as a measuring volume. For example, a measurement volume along the length of a free area, for example, a meadow of 10m, a height of 10m above a road surface or the meadow and with a width of 10m are used.

A noxious gas volume can be measured, for example, in a fixed reference measurement volume per unit of time. Reference measurement volume here means, in particular, that reference is made to a measurement volume relevant to an environmental load.

In particular, the particulate matter, ie the PM ₁₀ particles, and noxious gases, in particular NO and NO _x , which can reach the lungs, especially of humans, are currently recognized as problematical. It is known that these particles of material in the lungs may cause lung cancer if they progress unfavorably. There are statistics that allocate numbers of deaths per year to air pollution for spatial areas and regions. Furthermore, in the German media regarding a health burden, due to particulate matter and nitrogen oxide, called metropolitan areas, such as Munich, Berlin, Hamburg and Stuttgart are. Globally, a large number of metropolitan areas are affected.

Experts in the field of environmental protection are aware that in theory already a first atom or molecule of a carcinogenic substance can cause cancer.

The pollutants emitted by production plants, in particular power stations or factories, in particular material particles and noxious gases, first enter the ambient air in the space of the production infrastructure. Due to a large production volume, particulate matter may form in a pollutant gas stack as power plants and factories swirl the ambient air and continuously produce and dump material particles and noxious gases into the air. So fine dust with diameters smaller than 2500nm, especially smaller 150nm, are also in the environment. By means of the direct ambient air in the space of the production infrastructure, fine dust and noxious gas can be released by movement of the ambient air and movement in the ambient air in adjacent to the production infrastructure spatial areas and other beyond extending spatial areas and regions. This may result in all the combustion chambers and the entire production infrastructure of a metropolitan area contributing to exposing the whole metropolitan area to particulate matter and noxious gas emissions that exceed legal limits. It may be, for example, a coherent cloud of pollutants or pollutant over an entire metropolitan area, such as a city, educate in the air.

Likewise, due to a large production volume, large amounts of noxious gas may be formed in the ambient air of a production infrastructure.

In order to evaluate whether a production volume is large, measurements of concentration of material particles in a reference measurement volume can also be carried out. Reference measurement volume here means, in particular, that reference is made to a measurement volume relevant to an environmental load.

• 1. Jahresmittel PM₁₀ 20μg/m³
• 2. Jahresmittel PM_2,5 10μg/m³
• 1. Tagesmittel PM₁₀ 50μg/m³ ohne Tage, an denen eine Überschreitung zugelassen wird
• 2. Tagesmittel PM_2,5 25μg/m³ ohne Tage, an denen eine Überschreitung zugelassen wird.

The World Health Organization (WHO), for example, recommends the following limit values in the context of the WHO's air quality guidelines for particulate matter:

• 1st Annual mean PM ₁₀ 20μg / m ³
• 2. Annual mean PM _2.5 10μg / m ³
• 1. Daily mean PM ₁₀ 50μg / m ³ without days, where exceeding is allowed
• 2. Daily mean PM _2.5 25μg / m ³ days not allowed.

These guideline values of the WHO are thus well below the legal limits of the European Union (EU).

Affected by emissions of material particles from production plants, in particular power plants or factories, are in particular all people in a respective agglomeration, for example cities or urban agglomerations. In 2001, according to the German Federal Environment Ministry, 42,000 tons / year of particulate matter were emitted in Germany, for example as a result of road traffic.

For harmful gases, such as NO and NO _x , equally binding limits must be observed.

Basically, first the employees of the emitting power plants and factories are exposed to the pollutant exposure, in particular particulate matter and harmful gas exposure, then the residents to the production infrastructure or the factory and ultimately all residents of the associated agglomeration.

State of the art

Conventionally, it can be tried to equip the occupants or the affected residents with particulate matter masks. Conventional masks are available on the market, which can, for example, filter out material particle sizes down to, in particular, 150 nm from the air. In particular, it is difficult to keep such masks between mouth and ambient air tight for unfiltered air.

Measures are also known which seek to reduce emissions of particulate matter and air pollutants by power plants directly through improvements to the power plant.

Other traditional measures include introducing production limits or lowering production limits for power plants and factories.

Accordingly, large populations are exposed to air pollutant exposures.

task

It is an object of the present invention, an environmental pollution by emissions of pollutants, in particular of material particles, in particular particulate matter and / or material particles PM ₁₀ , PM _2.5 , PM _0.1 , and noxious gases, such as nitric oxide NO and NO _x , by to downsize technical machines, in particular power plants and / or factories with combustion chambers, simply and effectively. Abrasable materials, in particular metal and / or plastic materials, are also emitted into and out of production plants, in particular power plants or factories. It should be an entry of these pollutants, in particular material PM and harmful gases into biological systems - plants, animals - for example, be lessened in the lungs of living things, such as humans effectively. It should, especially at temperatures of the production infrastructure and its environment, in particular the ambient air, less than or equal to 0 ° C, a freezing of a liquid solvent and detergent used, especially in the production, be avoided.

solution

The object is achieved by a device according to the main claim and a method according to the independent claim.

According to a first aspect, a device ( 1 ) for removing pollutants (S), in particular particulate matter (F) and noxious gases, such as NO and NO _x, from an exhaust air mixture (U) of combustion chambers of a production plant, in particular a power plant or a factory, proposed, wherein at least one spraying device ( 7 ) a liquid solvent ( 5 ), in particular water, in a space assigned to the production plant and the exhaust gas mixture (U) spray (S1) and generates a spray and in particular an aerosol, which in the exhaust air mixture (U) in this space (R) existing pollutants (S), in particular suspended material particles PM, in particular PM ₁₀ , and the noxious gases, such as NO and NO _x , removed (S2), wherein the space is contained in a channel for discharging the exhaust gas of the combustion chamber (s) of the production plant.

According to a second aspect, a method ( 1 ) for removing pollutants, in particular particulate matter (S), in particular fine dust (F) and noxious gases, for example NO and NO _x, proposed from an exhaust air mixture (U) of combustion chambers of a production plant, in particular a power plant and / or a factory, wherein at least one Spraying device ( 7 ) a liquid solvent ( 5 ), in particular water, in one of the production plant associated and the exhaust gas mixture (U) contained space (R) sprays (S1) and a spray and in particular an aerosol generated that in the exhaust gas mixture (U) in this space (R) pollutants , In particular, suspended material particles PM, in particular PM ₁₀ , and the noxious gases, such as NO and NO _x , removed (S2), wherein the space is contained in a channel for discharging the exhaust gas of the combustion chamber (s) of the production plant.

Other harmful gases which can be removed according to the invention are, for example, SO ₂ , CO, NO, NO ₂ , O ₃ , CnHm, FC, benzene, CO ₂ .

It has been recognized that pollutants emitted by power stations or factories, in particular material particles and noxious gases, can be removed particularly advantageously directly at the point of origin, in particular within the production plant, in particular within the power plant or the factory, simply, effectively and inexpensively. The emissions should not spread beyond a specified space along the respective production plant and be effectively removed from such a space. An environmental load outside of such a room is concentrated effectively already concentrated within this space.

By supplying air, in particular from the environment of the power plant, an exhaust air mixture from the exhaust gas of the combustion chamber can be generated within the power plant or the factory. This mixture of exhaust gases is created in such a way that effective removal of the pollutants can be carried out physically by means of sorption and / or by chemical means.

Examples of chemical bonding and water removal are described by the following chemical formulas: NO ₂ + H ₂ O → HNO ₃ NO + H ₂ O → HNO ₂ 2O ₃ + H ₂ O → H ₂ O ₂ + 2O ₂ CO + H ₂ O → CO ₂ + H ₂ CO ₂ + H ₂ O → H ₂ CO ₃

Since ambient air surrounding a production infrastructure can change dynamically, a production infrastructure is also assigned a space defining a limited volume in which a certain amount of ambient air is present. It makes sense for such a space to contain the contaminated ambient air from which pollutants, in particular material particles and noxious gases, are to be removed.

With an extraction agent, an extraction can be carried out, which is a separation, in particular pollutants emitted by power plants or factories, in particular material particles and noxious gases, as substances to be extracted from ambient air as a mixture or mixtures of substances are dissolved out. The emitted pollutants, in particular material particles and noxious gases, can remain unchanged as extracted components during physical extraction. According to the present invention, the substances to be extracted are the pollutants, in particular material particles and noxious gases, emitted in particular by power plants or factories in a space assigned to a power plant. The mixture of substances or substance mixture here is the air in this space, in particular the ambient air in this space contained in the production plant, for example the power plant.

Further advantageous embodiments are claimed in conjunction with the subclaims.

According to an advantageous embodiment, the extractant may be a solvent and detergent. Here, solvent is generally a matter of solids, here can solve the pollutants emitted by power plants or factories, especially material particles and noxious gases, without causing chemical reactions between the solutes of pollutants emitted by power plants or factories, especially material particles and Harmful gases, and the solvent comes as a solvent. In this way, an occurrence of uncontrollable chemical reactions can advantageously be avoided and a resulting potential additional environmental impact avoided. For example, a magnet can remove magnetic material particles emitted by power plants or factories. Water vapor is suitable because of its respiratory activity and / or inhalability here in combination with the pollutants emitted by power plants or factories, in particular material particles and noxious gases, not as a solvent.

According to a further advantageous embodiment, the dispensing device may have a spraying device which sprays a liquid solvent into the ambient air of the room for droplet formation and in particular generates an aerosol. Aerosol is a word combination of air and solution, and here is the mixture or mixture produced by spraying the liquid solvent into the ambient air of the space of the production infrastructure. Spraying, conventionally referred to as sputtering, is the splitting of a liquid into drops. Spraying in ambient air produces the aerosol, which may also be referred to as spray or spray. In a monodisperse aerosol, the drops have the same diameter. In a polydisperse aerosol, the drops have different diameters. An ensemble of drops may be referred to as a drop collective, which in reality may in particular have a drop size distribution, for example a narrow drop size distribution.

According to a further advantageous embodiment, the liquid solvent may be partially or completely water. Water is advantageously readily available and accessible, easy to transport, easy to feed to the sprayer and manageable and it is not toxic. In principle, it is alternatively possible to use further liquid inorganic solvents, such as, for example, acids or bases. In principle, solvents may also be liquefied carbon dioxide or organic solvents, such as alcohols, terpenes, diethyl ethers, vegetable oils, chlorinated hydrocarbons or n-hexane. In particular, their availability, practicability and environmental compatibility should be examined. For the sake of completeness, it is pointed out that, in principle, a liquid solvent which can be sprayed here can theoretically also be provided as a suspension or a dispersion, if this would be advantageous for purifying the ambient air, in any case resulting in free active respirable or inhalable particles that you can inhale must be prevented. Suspension is a heterogeneous mixture of a liquid and finely dispersed solids, which are slurried in the liquid and kept in suspension. In this case, dispersion is in particular a heterogeneous substance mixture, wherein at least one substance is finely distributed in another continuous substance, wherein the substances do not dissolve into one another or do not chemically bond with one another. It is also to be considered that additional finely divided solids or substances in the ambient air act optically and can impair a respective view of employees of production facilities in the ambient air.

According to a further advantageous embodiment, the spraying device for spraying can have at least one pressure nozzle, in particular at least one single-substance pressure nozzle and / or at least one dual-substance pressure nozzle, or at least one rotary sprayer or vibration sprayer. These embodiments are advantageously well understood in theory and well manageable in practice. According to an advantageous embodiment, in particular the principle of Rayleigh or laminar jet decay can be used, wherein the at least one pressure nozzle a perforated plate or a perforated plate, for example consisting of a plastic, with a defined diameter d of, in particular drilled hole as a nozzle exit or Can be nozzle orifice. Thus, an almost monodisperse drop size spectrum can be generated, which corresponds advantageously in about natural rain events.

According to a further advantageous embodiment, the droplet diameter x of the liquid solvent for leaching or removal by sorption, in particular by adsorption on material particles, greater than the diameter of the material particles PM to be removed, in particular the PM ₁₀ and the PM _2.5 and the PM _0.1 , and more than 10 microns, be set. The larger the droplets are relative to the material particles PM to be picked up, the more material particles PM can be bound to the droplet surfaces and / or absorbed into the droplet volume. This also means that by means of a set drop diameter x, for this purpose larger material particles PM can not be absorbed and adsorb is only possible if a plurality of droplets attaches to each other to a respective material particle. Drop diameter x can be selected and adjusted for targeted sorption.

As a simple and effective means of dissolving the pollutants emitted by power plants or factories, in particular material particles and noxious gases, in particular NO and NO _x , sorption is particularly advantageous as a generic term for adsorption and absorption. Adsorption generally refers to an enrichment of a first phase at an interface to a second phase, here in particular of solid, in particular divided, material particles on a surface of a divided, sprayed, liquid solvent. Here, in particular, the material particles emitted by the power plants or factories on the surfaces become deposited by water droplets and thus adsorbed. Absorption generally refers to an enrichment of a first phase in an interior of a second phase, and here in particular of noxious gases, such as, in particular, nitrogen oxides NO and NO _x , in the interior of a divided, sprayed, liquid solvent. Here, the noxious gases emitted by the power plants or factories are absorbed, and thus absorbed, in particular by water droplets. Phase of matter or material here is in particular a spatial area of matter with similar physical and chemical properties, in particular a homogeneous state of matter of matter or material. In principle, several phases of different order can also occur within a material in the same state of aggregation. The sorption is physical and does not work chemically. Advantageously, no new toxic chemical compounds are generated. There is a solution laundry. At the same time, material particles and noxious gases can be removed together from the ambient air.

According to a further advantageous embodiment, by means of the spraying device, respective droplet diameters x are to be generated in order to avoid respiratory activity and / or inhalability, greater than 10 μm, in particular greater than 900 μm. Correspondingly, water as a solvent is also advantageous for this, since non-respirable and / or non-inhalable drops, with diameters greater than 10 μm, in particular greater than 900 μm, can be produced by means of conventional spraying devices.

According to a further advantageous embodiment, by means of the spraying device, respective generated droplet diameter x, for example, to increase a visual transparency or transparency, smaller than a Sichtschwelldurchmesser, for example less than about 500μm, are generated. The larger the drops, the more light, especially sunlight, they reflect, scatter or break. The larger the drops, the more material particles can bind them, so that they can be visible. A suitable visual threshold diameter can be determined experimentally or by means of a simulation. However, the respiratory tract and / or inhalability of water vapor is also problematic here.

According to a further advantageous embodiment, respective generated droplet diameter x can be adjusted by selecting a diameter d of an orifice or opening of a respective nozzle. This is particularly easy executable.

According to a further advantageous embodiment, droplet diameter x can be adjusted by selecting diameters d≈x / 1.89 of an orifice of a respective nozzle. This is especially true for water as a liquid solvent and detergent.

According to a further advantageous embodiment, effective nozzle diameters d can be formed in the range from approximately 10 μm / 1.89 to approximately 100 μm / 1.89. This means in particular 5.29 μm ≤ d ≤ 52.91 μm. For example, a nozzle opening diameter used may be 50μm to 600μm.

According to a further advantageous embodiment, the droplets with a respective same droplet diameter x and thus a monodisperse aerosol can be generated with the same droplet size and targeted from the ambient air material particles are removed with the smaller droplet size particle sizes with associated diameters. Advantageously acting droplet diameter x can additionally be determined under laboratory conditions. The molecules of the noxious gases, in particular of nitrogen oxide extend maximally in the nanometer range, and can basically be simply absorbed by droplets with sizes in the micrometer range, which are consequently larger by at least a factor of 1000.

According to a further advantageous embodiment, the spraying device can have a pressure-generating device, in particular a pump, which can be electrically driven, for providing a pressure difference Δp.

According to a further advantageous embodiment, the spraying device can be supplied with the liquid solvent from an intermediate container and / or a supply line. This can be determined depending on the required amount of the liquid solvent. Supply lines can be easily connected to power plant or factory internal connections.

According to a further advantageous embodiment, the spraying device can press the liquid solvent into an elongate spraying line which has nozzles arranged along its length. This is an easy to manufacture and cost-effective design.

According to a further advantageous embodiment, a plurality of flexible elongate spray lines, for example along an arc, may extend from an edge of an exhaust passage toward an opposite edge of the exhaust-derived passage or exhaust passage along the passage. This allows across a width of a channel and along this channel be sprayed easily and effectively the room R. Spraying devices can be easily expanded in this way as modules to a spray system and are thus suitable for cleaning any channel structures with any channel lengths. There are no brackets required for bows. Spraying means may alternatively or cumulatively be arranged along the inner surface of the channel.

According to a further advantageous embodiment, the power plant or the factory can have an exhaust gas duct and the exhaust gas containing the pollutants S can be moved in particular by means of a flow-generating device in at least one separate extraction space in which the extractant is introduced, wherein ambient air supplied and generated Exhaust air mixture U is cleaned. In this case, moisture, temperature, pressure and / or density in the separate extraction space to increase the solubility of the material particles to be extracted from power plants or factories can be additionally adjusted.

According to a further advantageous embodiment, the channel can be adapted such that the contaminants dissolved out, in particular material particles PM and noxious gases, binding liquid solvent drops due to gravity and currents in the exhaust gas mixture moves to surfaces and / or volumes of the channel structure and of this, in particular be absorbed by sorption.

According to a further advantageous embodiment, the channel structure V can be adapted so that the recorded solvent drops are summarized again as a liquid solvent collection to a discharge or to a channel edge. It is particularly advantageous if the dissolved-out pollutants, in particular material particles and noxious gas, are discharged into the discharge with the liquid solvent. The latter has the advantage that when the spraying devices are switched off and the ambient air and the channel structure, for example a surface coating, dry again, the pollutants, in particular the PM material particles, are not emitted again from the channel structure into the ambient air.

According to a further advantageous embodiment, the liquid solvent may comprise an antifreeze. An antifreeze is a substance that lowers the freezing point of another substance. The effect depends on the antifreeze used and its concentration in the other substance. The antifreeze agent may be provided as a concentrate that is mixed with the other substance at a fixed mixing ratio. The greater the amount of cryoprotectant added, the lower the temperature at which the other material freezes. A solution of antifreeze and the other material then remains liquid under even lower temperature conditions. Examples of antifreezing agents are glycerol, ethylene glycol and / or ethanol, which are particularly suitable for water as the liquid solvent according to the present invention.

In principle, further additives can be added to the solvent according to the invention, for example rust inhibitors, for the protection of metallic constituents of the production infrastructure or of components of power plants or factories.

According to a further advantageous embodiment, a regulating device can control or regulate the spraying device (s) for spraying the liquid solvent on the basis of measured values of the ambient air (U) detected by means of at least one measuring device.

According to a further advantageous embodiment, the control device may have at least one pollutant measured values, moisture measured values, temperature values, pressure values and / or density values of the ambient air (U) detecting measuring device.

According to a further advantageous embodiment, the control device can control or regulate the spraying device (s) for spraying the liquid solvent by means of a time circuit, in particular by means of time profile profiles.

According to a further advantageous embodiment, the regulating device can control or regulate the spraying device (s) for spraying the liquid solvent by means of a position-determining device which records global coordinates of the place.

According to a further advantageous embodiment, the control device can control or regulate the spraying device (s) for spraying the liquid solvent by means of at least one measuring device which detects the pollutant load of the spray or sorbate which has been removed.

According to a further advantageous embodiment, the regulating device can switch off the spraying device (s) for spraying the liquid solvent when a limit value of the pollutant load of the sprayed or sorbate that has been exhaled is exceeded.

According to a further advantageous embodiment, the sprinkled spray of the / the spray device (s) can be recycled by means of a return line, which in particular has a filter.

The invention will be described in more detail by means of exemplary embodiments in conjunction with the figures. Show it:

1 a first embodiment of a device according to the invention;

2 a second embodiment of a device according to the invention;

3 a third embodiment of a device according to the invention;

4 A fourth embodiment of a device according to the invention;

5 a first embodiment of a method according to the invention;

6 A second embodiment of a method according to the invention.

7 An embodiment of an exhaust gas duct according to the invention in cross section.

1 shows a first embodiment of a device according to the invention 1 on the application of pollution reduction in road transport, which has developed the solution proposed by this application out of the context of motor vehicle traffic and has been generally adapted for production facilities, in particular factories and / or power plants. 1 shows the device 1 for removing pollutants S, in particular particulate matter or particulate matter F and noxious gases, from ambient air U of a production infrastructure V, in particular a road, used by a power plant or a factory, wherein at least one dispensing device in the form of a spraying device 7 an extractant in the form of a liquid solvent 5 in one of the production infrastructure V assigned and here above this space R and introduces in the ambient air U in this space R existing pollutants S, in particular suspended material particles PM, in particular PM ₁₀ , PM _2.5 and PM _0.1 , and noxious gases, in particular NO and NO _x , by interaction with the liquid solvent 5 be removed from the ambient air U of the room R.

The dispensing device in an embodiment of a respective spraying device 7 sprays a divided liquid solvent 5 in the form of drops in the ambient air U of the space R, wherein a spray and in particular an aerosol are generated.

As a liquid solvent 5 Particularly advantageously, water can be used partially or completely. Water can be provided, for example, in a simple manner and in large volume flows.

reference numeral 7 denotes a spraying device used 7 , For spraying a liquid solvent, in particular a mechanical spraying technique can be used, which is conventionally also referred to as sputtering technique, wherein liquids, suspensions or dispersions can be divided into droplets. By means of spraying and thus by means of drop formation, free and, in particular, surfaces which can be used for adsorption and, in particular, volumes usable for absorption can be provided, so that heat exchange processes and, in particular, the pollutants S emitted for the purification of ambient air and removal of in particular power plants or factories, in particular material particles PM and noxious gases, from the ambient air U necessary mass transfer processes can be effectively implemented.

To spray and thus to form new free surfaces energy or work must be supplied to the liquid solvent. This serves to overcome the effective surface tension. For the work to be done, the first approximation applies W _σ ≈ σ A _S (1) where W _σ is the work to be applied, σ is the surface tension of the liquid solvent, A _S is the generated spray surface.

Tropfendurchmesser x von mit x ist der theoretische Tropfendurchmesser, D ist der Innendurchmesser der Kapillare, σ ist die Oberflächenspannung des flüssigen Lösungsmittels, ρ ist die Dichte des flüssigen Lösungsmittels als strömendes Medium, g ist die Erdfallbeschleunigung. An easy way - especially monodisperse - to produce drops, is to drain the liquid solvent in the earth's gravity field with the acceleration g and a very low flow velocity v from a capillary with an inner diameter D. A capillary is a very fine, elongated cavity. In the case of non-wetting between the liquid solvent and the material of which the capillary is made, this results in a theoretical one

Drop diameter x of where x is the theoretical drop diameter, D is the inner diameter of the capillary, σ is the surface tension of the liquid solvent, ρ is the density of the liquid solvent as the flowing medium, g is the gravitational acceleration.

In practice, the drops have slightly smaller diameters than those calculated here. This is because the detachment of a single drop from the capillary and the shaping is not in an ideal spherical shape, but the individual drop is somewhat constricted. Some of the liquid solvent flows back into the capillary. Producing small drops with a relatively large volume flow, however, is hardly practicable with this theoretically possible method.

A technically practicable spraying device 7 can be selected according to the type of energy supply for generating a spray and thus by the way in which the work W _{σ is} applied, in particular from the following three groups, here as possible embodiments of sprayers 7 can be used.

A first group uses the kinetic energy for droplet formation, which, in particular by means of a pressure difference Δp, has been transferred to the accelerated liquid solvent, in particular to an exit velocity v, which has been reached at the exit from a nozzle opening. The liquid solvent is at a spray 7 according to the first group directly or indirectly acted upon by a pressure difference Δp. This results in a certain flow rate of the liquid solvent. Here is for this practicable technical embodiment of a usable spray 7 instead of a general capillary, a nozzle which is especially adapted in the production material and method and / or in the shaping, in particular in the inner diameter D and / or in the length of the cavity, relative thereto, is used.

A second group uses the kinetic energy for droplet formation, which was transferred to a rotating object by means of an accelerated liquid solvent, in particular to an escape velocity v, which was reached when it was detached from an edge of the rotating object.

A third group, which is still to be tested for its practicability, uses the liquid solvent for the formation of droplets by means of a mechanical vibration device 5 transmitted kinetic vibration energy. sprayers 7 from the second and third groups conventionally also called mechanical sprayers.

Basically, as sprayers 7 according to 1 all physically possible means for spraying and for producing drops of liquid solvents 5 be used.

The sprayer 7 For droplet formation, the liquid solvent may first be generated in the form of a jet or in the form of a lamella or in the form of waves prior to the generation of a spray.

A leaking jet of the liquid solvent or a lamella of the liquid solvent or waves of the liquid solvent break up into individual drops, in particular due to a turbulent or laminar flow, and form the spray. Furthermore, aerodynamic effects due to interactions with the ambient air U of the space R in the drop formation are to be considered.

In a nozzle according to the first group using spray 7 An exit velocity v of the liquid solvent from a nozzle orifice, its contour and the generated drop size spectrum depend on a large number of influencing variables. In particular, the pressure difference .DELTA.p, so-called rheological properties of the liquid solvent and the geometric configuration of the nozzle itself play an important role. A certain maximum exit velocity v _{max, which} can be calculated in particular by means of the pressure difference Δp and the density ρ of the liquid solvent, can not be exceeded. Vmax = √ 2Δp / ρ (3) with: v _max is the maximum exit velocity, Δp is that of a pressure generator 9 provided pressure difference, ρ is the density of the liquid solvent.

Particularly advantageously, medium and large volume flows of viscous or lower-viscosity liquid solvents, for example of water having a density ρ _W = 0.999941 to 0.995,649 kg / dm ³ at temperatures from 0 to 30 ° C., can be sprayed into fine drops. For this purpose, only relatively low pressure differences .DELTA.p are required and it can be a small flow area within a relatively large nozzle. A smallest flow cross-section within a nozzle is usually at the exit of the nozzle.

A flow, in particular nozzle flow, of the liquid solvent can be described by means of the turbulence-describing and computable Reynolds number Re. Re = Lρv / η, (4) where L is a characteristic length that can be defined for a given problem and describes a respective body in a flow and here can be an inner diameter of a nozzle with respect to a nozzle flow, ρ the density of the nozzle liquid solvent, v is the relative flow velocity between the liquid solvent and the body or the nozzle, and η is the dynamic viscosity of the liquid solvent.

The dynamic viscosity of, for example, water η _W is 1.002 mPa s at 20 ° C and 1.792 mPa s at 0 ° C.

At a Reynolds number Re of less than 2300, there is practically a laminar nozzle flow of the liquid solvent, in which case the drops produced are relatively large, and then it becomes more difficult to produce a spray with relatively small drops. The more laminar the nozzle flow, the larger the droplets produced can be.

The so-called unconsciousness number Oh additionally describes the breaking up of liquid jets or lamellae of the liquid solvent into drops and describes the influence of the viscosity or viscosity of the liquid solvent on the deformation of the drops. Oh = n / √ Lρσ , (5) where η is the dynamic viscosity of the liquid solvent, L is a characteristic length that can be defined for a particular problem and describes a respective body in a flow and here can be an inner diameter of a nozzle with respect to a nozzle flow, ρ is the density of the liquid solvent and σ is the surface tension of the liquid solvent.

For water, the surface tension σ _W = 0.0756 N / m at 0 ° C; 0.0727 N / m at 20 ° C; 0.0678 N / m at 50 ° C; 0.0588 N / m at 100 ° C.

A laminar liquid jet of the liquid solvent emerging from an exit of a nozzle or a nozzle orifice decomposes under certain conditions into approximately monodisperse drops. This decay mechanism is known as Rayleigh or laminar jet decay. The higher the viscosity of the liquid solvent, the finer the droplets produced can be. The reason for this is that due to the effective gravitational acceleration, the liquid jet of the liquid solvent flows faster and faster with increasing distance from the nozzle orifice. According to the rules of the so-called continuity equation, this goes hand in hand with a decrease in the beam diameter. Decomposes such a thin liquid jet, resulting in accordance with small droplet diameter x of the liquid solvent. A droplet diameter x for a low-viscosity liquid solvent, such as water, for example, can be calculated to a good approximation as follows: x ≈ 1.89d, (6) where d here describes the diameter of the nozzle exit, which can also be called nozzle orifice or nozzle opening. At a disintegration of highly viscous liquid solvents 5 In addition, relevant rheological properties must be considered.

Turbulent jets forming liquid jets, in contrast to laminar jets, can produce, in particular, more compact jets of liquid, in particular producing more powerful jets of liquid.

Lamella-forming nozzles are, for example, flat jet and hollow cone pressure nozzles as well as tongue and cone nozzles. At the nozzle orifice of such a nozzle, a lamella of the liquid solvent can be formed with a lamella thickness δ. The lamella decays due to various disintegration mechanisms to the spray.

The so-called Weber number We detects the surface force and the inertial force of the liquid solvent in the deformation of droplets and serves as a measure of a droplet deformation and in particular for characterizing a quality of a spray and is here: We = v ² Lρ / σ = (Oh · Re) ² , (7) where v is the relative flow velocity between ambient air and the droplets, L is a characteristic length that can be defined for a particular problem and a beam thickness when beam formation and lamella thickness δ here with respect to the lamination, ρ is the density of the liquid solvent and σ is the surface tension of the liquid solvent.

The various disintegration mechanisms of a lamella to the spray can roughly be divided into four areas as the Weber number We:
A Weber number We smaller 2 means that forming a lamella is not yet possible. A Weber number We smaller 1640 means that due to decay of the lamella due to a Randwulstkontraktion and a possible Lochbildung relatively coarse drops arise. A Weber number We greater than 1640 describes an aerodynamic disintegration of the lamella, with a strong interaction with the ambient air, whereby relatively fine drops of the liquid solvent are formed. A Weber Number We much larger than 1640 describes one increasingly due to turbulent effects specific decay of the lamella, resulting in fine droplets.

In a hollow cone pressure nozzle can be achieved either by means of special swirl body within the nozzle or by tangential entries into a so-called swirl chamber, that the liquid solvent does not completely fill a nozzle outlet diameter. It can thus be formed a relatively thin liquid plate, which breaks down into fine drops. In tangential hollow cone pressure nozzles thus relatively large flow cross sections can be used. This minimizes the clogging tendency of the nozzle with a contaminated liquid solvent 5 , In the hollow cone pressure nozzles, calculating the volume flow as a function of the pressure difference Δp and the density ρ and the viscosity of the liquid solvent is complex. Note also a so-called hollow cone pressure gland paradox, which states that, in contrast to nozzles with fully filled nozzle outlet, the volume flow initially increases with increasing viscosity of the liquid solvent. With decreasing viscosity, however, the volume flow of the liquid solvent decreases. This leads, for example, to a decrease in the volume flow of this liquid solvent when preheating a higher-viscosity liquid solvent at a defined pressure difference Δp. Viscosity here is a measure of the viscosity of the liquid solvent. Water is a low-viscosity liquid.

Most lamella-forming nozzles produce significantly finer droplets than jet-forming jet and turbulence nozzles under identical operating conditions and liquid solvent rheology.

A spraying device 7 For example, the first group may be embodied as a so-called single-substance pressure nozzle. Here, the kinetic energy for droplet formation is transferred directly to the liquid solvent as the only substance. That is, the pressure difference Δp acts directly on the liquid solvent.

A spraying device 7 The first group can be designed as a so-called dual-fluid nozzle as an alternative to the single-fluid nozzle. In this case, the kinetic energy for the droplet formation is transferred indirectly via a second medium to the liquid solvent. That is, for example, a pressure difference Δp or a proportion thereof acts indirectly on the liquid solvent. It is the principle of a so-called jet pump applied, the pumping action by means of the second medium, which is also referred to as a driving medium is generated, which sucks by means of pulse exchange, the liquid solvent, which can also be referred to as a suction medium here, accelerates and compresses or promotes , The liquid solvent should be under a sufficient pressure.

In the case of sprayers using two-component nozzles, therefore, an additional gas mass flow flowing at high speed, which can be particularly advantageously an air mass flow which is easy to produce, serves as an energy supplier for spraying the liquid solvent. This offers the advantage that, in contrast to single-component pressure nozzles, smaller volume flows of, in particular higher-viscosity, liquid solvents can be atomized to a drop size range with small droplet diameters. An important role in this case plays the mass flow ratio μ between the gas g and the liquid solvent. μ = ṁ _g / ṁ (8)

This mass flow ratio μ is also referred to as loading. With increasing load, the generated drops tend to become smaller (finer). The larger the load number, the more margin one has with respect to the mass flows for a constant characteristic drop diameter.

Dual fluid nozzles with an external mixture can be used. The liquid solvent and the propellant only interact with each other outside the nozzle. Often encountered here is the so-called prefilming nozzle. The liquid solvent occurs here almost without pressure in the center of the nozzle. The driving medium flows at high speed from a surrounding annular channel. This results in the vicinity of the nozzle orifice, which can also be called nozzle outlet or nozzle outlet, a negative pressure, which propagates the liquid solvent on a so-called prefilming surface as a film. This thin film strikes the high-velocity propellant or gas and is broken up into small (fine) droplets. Under certain conditions, this nozzle type works self-priming.

Dual fluid nozzles with an internal mixture can be used. In this type of nozzle, a two-phase mixture of the liquid solvent with the additional blowing medium is already produced inside the nozzle. This has a low speed of sound. In a so-called nozzle exit level, this results in a so-called pressure jump. Drops having a critical diameter thereby undergo further fragmentation and contribute to a high level of fines in the spray. In contrast to the two-component nozzles outer mixture pressure of the Propellant or propellant gas and pressure of the liquid solvent are matched. In this respect, a higher control engineering effort is required.

According to the second group, the sprayer 7 use a rotating object. The sprayer 7 As a rotation sprayer, it uses the kinetic energy of the liquid solvent thrown out of the rotating object in the form of a jet or in the form of a lamella to produce a spray. This embodiment of the so-called rotary sprayers is also one of the mechanical sprayers.

For example, a rotating disk or a cup can be pressurized with almost no pressure with the liquid solvent. The liquid solvent is accelerated toward the edge due to adhesion conditions. Depending on the operating conditions, it forms individual liquid jets in the form of liquid threads or a lamella. These decompose at a certain distance from the edge of the sprayer to drops.

Rotary sprayers are advantageously almost free of blockage, since no critical cross-sections are required. In addition, they clean themselves due to the centrifugal acceleration, when the supply of the liquid solvent is interrupted. For this reason, such a rotary sprayer used for spraying suspensions. It is particularly interesting that such a spray device 7 under certain circumstances, is advantageously capable of producing a near monodisperse spray. Depending on the operating condition, the following droplet-forming mechanisms occur on a rotary sprayer, namely drip-off processes which enable a bimodal droplet size distribution; a thread decay, producing almost monodisperse drops; a lamellar formation, which gives droplet size distributions similar to lamellae forming single-fluid pressure nozzles.

The sprayer 7 can as a rotary sprayer 7 be used in the operating range of the thread decay for a uniform surface spraying, for example, if in addition to the spraying in the room, a surface, for example, a respective power plant to be sprayed, is concentrated on the fine dust. An additional, in particular electrostatic, guiding the drops can minimize an undesired so-called overspray effect.

According to the third group, the spray can 7 a vibratory sprayer, but which uses capillary effects to be. Drop formation takes place here by means of mechanical vibrations, in particular with frequencies of up to 3 MHz, which are transmitted to a liquid film. These vibrations can be generated for example by means of piezoceramic elements that convert electrical vibrations into mechanical vibrations. These can lead to the formation of waves on the surface of the liquid film, in particular capillary waves, which rise exponentially with increasing excitation frequency. Depending on the excitation frequency, drops with a specific diameter x can be generated. This decreases with increasing excitation frequency or with increasing density ρ and decreasing surface tension σ of the liquid solvent. According to the present invention, such a spraying device 7 also provide here in particular drop sizes with diameters of greater than 10 microns to less than 100 microns.

Vibration sprayers should not produce sound waves in the infrasound range and in the human hearing range. In this way, a further environmental impact should be avoided. Likewise, no sound waves are to be generated in certain ultrasonic ranges, as a Höhrbarkeit for certain animals, especially for dogs, may be given. Advantageous excitation frequencies can be determined experimentally. It should also be determined whether it is feasible to produce small drops with a high volume flow by means of this theoretically possible method.

Basically, as the sprayer 7 also so-called special atomizers can be used, as are atomizers, which operate on the principle of electrostatic atomization.

The respective spraying device 7 according to 1 sprays drops or droplets of the liquid solvent 5 in the space R, which is filled with ambient air U, this being in 1 represented by thin arrows.

According to 1 For example, the material particles PM emitted by power stations or factories can be deposited on the surface of the drops and adsorbed therewith and / or harmful gases, in particular NO and NO _x , are taken up by the drops in their interior and thus absorbed, the drops remaining intact. As a result of the adsorption, the material particles PM emitted by power plants or factories are condensed in the space and compressed in such a way that mass agglomerations are formed whose cooperating overall masses become larger. Due to gravity, the weight of such mass agglomerations also increases, so that they sink to the ground in the room 1 is shown by thick arrows, and here in particular on the street or on a road surface. Furthermore, in particular due to the movements of the power plants, currents in the ambient air U cause a transport of the droplets, laden with the pollutants S, in particular material particles PM and noxious gases, in particular NO and / or NO _x , to surfaces and / or volumes of the production infrastructure V, This is a four-lane road with two lanes in one direction.

A spraying device 7 according to 1 has a pressure generating device 9 for providing a pressure difference Δp. The sprayer 7 Presses or sucks the liquid solvent from an intermediate container 11 , in addition of a supply line, not shown here 13 can be supplied. The sprayer 7 may additionally have weights in the basic bodies shown here as squares for safe positioning, so that wind the respective two sprayers here 7 can not just move away. Additional mechanical brackets can also be a respective spray device 7 protect against unwanted movement. The two sprayers 7 according to 1 each press the liquid solvent 5 from the ground, at its height in about a respective intermediate container 11 can be arranged in an elongated spray line 15 having nozzles arranged along the length thereof. These nozzles become the liquid solvent 5 sprayed in the form of droplets in the ambient air U, this being illustrated by the thin arrows. 1 shows left and right at the roadside the two sprayers 7 with two flexible elongated spray lines 15 here having the shape of a respective arc extending from an edge of a road toward an opposite edge of the road along the road. In this way, the emission sources can be effectively limited and / or included.

The respective spraying device 7 has here for spraying a plurality of pressure nozzles, which are in particular each produced by means of a perforated plate. This comes here according to this embodiment 1 the one-substance pressure nozzle principle for use.

According to the present invention, the device is integrated into a respective power plant and adapted accordingly.

2 shows a second embodiment of a device according to the invention 1 , To 1 like reference numerals denote like elements with respect to a production infrastructure V.

The production infrastructure V is according to 2 a road tunnel, wherein the pollutants S contained ambient air U of the room R here by means of two respective flow generating facilities 17 in a separate extraction room 19 is moved, in which the liquid solvent 5 is introduced, this air is cleaned and returned to the tunnel.

Respective spraying devices 7 Press the liquid solvent into an elongated spray line 15 having nozzles arranged along the length thereof. It can be a variety of elongated spray lines 15 in the tunnel above on a ceiling and / or laterally on side walls are arranged so that the entire space R is sufficiently sprayed for cleaning and solution.

The production infrastructures V are adapted or in most cases already configured such that the dissolved pollutants S, in particular material particles PM and noxious gases, binding liquid solvent drops due to gravity and currents in the ambient air U to surfaces and / or volumes of production infrastructure V moves and from this , in particular by sorption, are recorded. In principle, the material particles PM are then bound, as long as the surfaces and / or volumes are wet in the case of water as the solvent or as long as the sprayers 7 spraying and wetting the surfaces and / or volumes with the liquid solvent 5 provide. Noxious gases, especially NO and NO _x , may react chemically or biologically upon contact with the soil or material of the production infrastructure.

The production infrastructures V are adapted or usually already designed such that the recorded solvent drops again summarized as a liquid solvent, in particular together with the dissolved pollutants S, in particular material particles PM and noxious gases, to a sewer 21 be dissipated. This is 2 illustrated by thick horizontal arrows.

In principle, separation processes can also be used subsequently, as may be filtration or precipitation, for example, for separating the extracted component dissolved in the extractant from the extraction agent, that is, for example, for re-separation of the liquid solvent which is no longer drop-shaped 5 dissolved PM material particles from the no longer drop-shaped and withdrawn from the sewer liquid solvent 5 ,

According to the present invention, the device is integrated into a respective power plant and adapted accordingly.

3 shows a third embodiment of a device according to the invention 1 , To 1 like reference numerals denote like elements with respect to a production infrastructure V. Here, the production infrastructure V is a road bridged by means of a transverse element, which may be, for example, a bridge or a signage. The sprayers 7 can be attached to this cross member and clean the top of the pollutants S contained ambient air U of the room R or clean.

3 shows two sprayers 7 , which at least one pressure generating device 9 associated with providing a pressure difference Δp. The two sprayers 7 becomes the liquid solvent 5 by means of a common supply line integrated in the transverse element 13 fed. The respective spraying device 7 pushes the liquid solvent 5 here in two horizontally arranged elongated spray lines 15 presses, which has along the length arranged nozzles, from the outputs of which a respective spray is generated, which complement each other in the ambient air U of the space R to form a total spray. Some of the spray directions are illustrated by short thin arrows. Drops loaded with pollutants S, in particular material particles PM and noxious gases, can be absorbed by surfaces of power plants or factories and combine to form liquid accumulations. As a result of gravity, liquid accumulations on the power plants or factories are moved further towards the ground. Likewise, the loaded with the material particles PM drops of liquid solvent 5 , which reach the ground directly, can, in particular due to the respective surface tension σ of the liquid solvent acting towards a minimum volume of a liquid 5 , to respective larger pools of fluid that can be colloquially called laughter or puddles. Moving power plants can act on it mechanically, with sufficient amount of liquid solvent 5 in space R, the pollutants S, in particular PM and noxious gases, remain bound in the larger fluid collections. A respective road surface may be slightly inclined downhill for the discharge of rainwater to the respective roadside. In this way, the larger liquid accumulations of the liquid solvent 15 as well in a sewer 21 or be removed to a roadside and disposed of. Therefore, another important criterion is the selection of a suitable liquid solvent 5 as well its harmlessness for the environment. Accordingly, water is also here as a particularly advantageous liquid solvent 5 proposed, which may also be called detergent. The drop of the drops is illustrated by thick vertical arrows. The disposal of streams of liquid solvent 5 in the sewer 21 is illustrated with thick horizontal arrows.

According to the present invention, the device is integrated into a respective power plant and adapted accordingly.

4 shows a fourth embodiment of a device according to the invention 1 , To 1 like reference numerals denote like elements with respect to a production infrastructure V. The production infrastructure is schematically illustrated here a four lane road. It is a plan view of a section showing in both directions each two-lane road running. This can be, for example, a ring road in a metropolitan area, for example with more than 1 million inhabitants, with a high production volume.

4 shows on the right side across the road a relatively thick line, here is a reference measurement line RML for detecting a production load. For example, up to approximately 50,000 power plants can overrun this reference measurement line RML in both directions in one day. A more accurate determination of the production volume can be carried out, for example, by means of light barriers detecting a respective overrun.

From above, a cube-shaped space R is shown in cross section by means of a square as a pattern space R _m . Such a pattern space R _m can, for example, 10 _m along the course of the road, 10m across to in 4 schematically illustrated road course and 10m in height to the road surface. In this way, such a pattern space R _m can be easily determined and defined in reality, for example by means of markings, on a real road. This pattern space R _m defines here thus a limited volume of 1000m ³ . In this sample space R _m , a certain mass of ambient air U is present at a time t _p . Due to air currents, for example due to wind, the ambient air U located in the sample space Rm is variable over time.

4 shows in the square of the room R two sprayers 7 that the two sprayers 7 according to 1 which can now be viewed from above. The two sprayers 7 Here are the flexible elongated spray lines 15 each extending along an arc from one edge of the road toward the opposite edge of the road. The spray lines 15 for example be made of plastic channels or pipes that can easily resonate in the wind. The respective nozzles may advantageously be perforated plates which can be easily integrated and fixed in the tubes. Such perforated plates can when using water as a liquid solvent 5 simulate natural rain in a simple way. Thus, inmates of power plants or factories are not overly irritated by unexpected spraying. The nozzles may be advantageously positioned for uniformly spraying the space R at regular intervals along the respective arc. Since gravity is added to the spraying pressure in the upper sections, the upper horizontally oriented perforated plates are particularly advantageous for completely distributing the liquid solvent 5 in space R. Accordingly, the number of nozzles per length of a spray line 15 may be provided enlarged to an upper portion of a respective arc. A respective arc extends in the space R up to a certain height h, that for the one of the liquid solvent 7 fully filled spray line 15 built-up pressure p is essential. The liquid solvent 5 forms here in a pipe a so-called column. p = F / A = mg / A = ρV _s g / A = ρhg, (9) where p is the pressure built up by the column of liquid solvent, F is the force built up by the column, A is the cross-sectional area of the spray line, m is the mass of the column, g is the gravitational acceleration, ρ is the density of the liquid solvent, V Here _s is the volume of the column, h is the maximum height up to which the column extends here from the surface of the road, assuming here a pressure generator 9 for a balance in which the liquid solvent 5 remains, the back pressure to pressure p builds up.

The liquid solvent 5 will be from the two sprayers 7 introduced in the form of drops in the sample space R _m . This is in 4 by the distribution of the reference mark 5 illustrated in the room R _m .

Given an assumed load of the ambient air U present at a time t _p in the sample space R _m with the volume of 1000m ³ with material particles PM ₁₀ of 100μg / m ³ , a total mass of 100000μg = 100mg of finely divided results in the sample space R _m defined here Material particles PM ₁₀ .

For an exemplary design of the two sprayers 7 the total mass of the finely divided material particles PM ₁₀ in the sample space R _{m should be} reduced to the World Health Organization (WHO) recommended daily mean value of 50 μg / m ³ PM ₁₀ to 50 000 μg = 50 mg of finely divided PM ₁₀ material particles.

It is questionable how large the volumetric flow V provided by the two sprayers. on liquid solvent 5 must be to extract 50000μg = 50mg of finely divided material particles PM ₁₀ from 1000m ^{3 of} the sample space R _m ? The binding effect caused by sorption depends in particular on the diameters of the drops in the spray. In particular, an optimization can be carried out experimentally under laboratory conditions.

It is obvious for effective adsorption to produce the diameters of the receiving drops larger than the diameters of the PM to be absorbed. The larger the diameter of the droplets relative to the diameters of the material particles PM, the greater the number of PM particles accumulating on the surface of the droplets. Accordingly, it is advantageous if the sprayers 7 respective droplet diameter x for dissolving in particular by adsorption greater than the diameter of the material particles to be removed PM, in particular the PM ₁₀ and the PM _2.5 and the PM _0.1 , and always generates greater than 10 .mu.m. In addition, those of the sprayers 7 produced respective droplet diameter x also for health reasons to avoid respiratory activity and / or inhalability of the drops of the liquid solvent 5 definitely be larger than 10μm. Accordingly, it can first be said that the larger the droplet diameter x produced than 10 μm, the more advantageous. However, as the droplet diameter x increases, the surface A _S required for adsorption, which is produced by means of the entirety of the droplets in the pattern space R _m , which is the spray surface produced from the formula (1), also decreases.

Furthermore, drops can cause optical effects, such as refraction or reflection, especially at the surfaces of the drops, which also have to be considered with regard to their effect on occupants of vehicles. Likewise, these effects in their entirety for a spray can be detected experimentally and under laboratory conditions. It is believed that drops of increasing drop diameters can be more easily detected by the human eye. As the droplet size decreases, the spray surface, which is also optically active, becomes larger.

Due to the decreasing due to a growing drop diameter x for adsorption acting spray surface A _s , is here for the of the spray 7 generated respective droplet diameter x proposed to narrow this to less than about 100μm. In principle, larger droplet diameters x are possible, for example up to about 300 μm or about 500 μm or larger. For this purpose, the clogging and susceptibility to wear of a nozzle must also be taken into account.

At the sprayers 7 For example, a respective generated droplet diameter x can be set by selecting a diameter of the respective nozzle opening. By means of formula (6), a respective nozzle orifice diameter in the range of about 5.29 μm for x = 10 μm to about 52.91 μm for x = 100 μm is thus proposed. Larger nozzle opening diameters are basically possible as well.

The drops can be produced with a uniformity of all nozzle opening diameters with a respective same droplet diameter x and thus in its entirety as a monodisperse spray or monodisperse aerosol with a uniform droplet size.

Generated drops can be ideal as spheres, especially as completely from the liquid solvent 5 existing massive ball, to be accepted, wherein given a droplet diameter x the following surface O: O = πx ² , (10) with the circle number π and the drop diameter x.

For a drop diameter x = 10 μm = 10 × 10^-6m results in a drop surface of about 3.14 × 10^-10m², With a droplet diameter of x = 100 μm = 100 × 10^-6m results in a drop surface of about 3.14 × 10^-8thm² = 31.4nm², The latter is used for further calculation.

For example, a material particle PM ₁₀ may have a diameter d _p of approximately 10 μm = 10 × 10 ^-6 m. Simplified, such a material particle PM _{10 can} also be assumed to be spherical. It is assumed here that, when adsorbed on a surface of a drop, such a material particle PM ₁₀ occupies a surface area on the surface which corresponds to the maximum cross-sectional area A _{p of} the material particle according to the following formula: A _p = d _p ² π / 4, (11) where A _{p is} the maximum cross-sectional area of a material particle, d _p is the diameter of the material particle, π is the circle number.

A material particle PM ₁₀ with the diameter d _p = 10 μm = 10 × 10 ^-6 m thus has a theoretically assumed surface for adsorption A _p = 100 × 10 ^-12 m ² π / 4 = 78.5 × 10 ^-12 m ² . Accordingly, with respect to a drop having a surface area of 3.14 x 10 ^-8 m ² = 31.4 nm ^2, a theoretical number of 400 material particles PM ₁₀ determined by division could be bound to the surface of this drop. In practice, for real adsorption conditions, a small number of actually bound material particles PM ₁₀ per drop is expected, with a weighting factor of 0.01 and thus with a number of 4 bound material particles PM ₁₀ per droplet being further calculated. The material of material particles may include metals and / or plastics. For example, iron can have a density ρ _Fe of 7.4 kg / dm ³ . Rubber has a density ρ _Gu of 0.92 kg / dm ³ = 920 g / (10 ^-1 m) ³ = 920 × 10 ³ g / m ³ .

The material particles PM selected here for a calculation have, with the diameter d _p = 10 μm = 10 × 10 ^-6 m, an idealized volume V _{p in} accordance with the following formula: V _p = d _p ³ π / 6, (12) with: V _p is here a theoretical, approximated particle volume, d _p is the selected particle diameter, π is the circle number.

The result is a respective particle volume of V _p = 1000 × 10 ^-18 m ³ × π / 6 = 523.60 × 10 ^-18 m ³ and a number of 4 bonded material particles results in a volume bound per drop of 2094.40 × 10 ^-18 m ³ , this being, for example, at an abovementioned rubber density of 920 × 10 ³ g / m ^3, a mass bound per drop of 2094.40 × 10 ^-18 m ³ × 920 × 10 ³ g / m ³ = 1926848 × 10 ^-15 g of rubber results.

50 × 10 ^-3 g / 1926848 × 10 ^-15 g ≈ 25949115 drops are needed to remove 50000 μg = 50 mg of finely divided material particles PM from 1000 _m ^{3 of} the sample space R _m , with the same from formula (12) from the drop diameter x = 100 μm of computable drop volume of V _T = (100 x 10 ^-6 m) ³ π / 6 = 1000000am ³ π / 6 = 523598.78 am ³ = 523598.78 x 10 ^-18 m ³ , a total volume of liquid solvent required 5 of 25949115 · 523598.78 · 10 ^-18 m ³ = 13,587 · 10 ^-9 m ³ = 13,587 · 10 ^-9 · (10dm) ³ = 13,587 · 10 ^-6 dm ³ = 13,587 · 10 ^-3 dm ³ ≈ 14ml results.

This amount of liquid solvent 5 here is therefore theoretically by calculation in the form of a spray with 100 microns drops into the pattern space needed R _m of the volume of 1000m ³ dispersed for extracting and removing.

If, for example, a cleaning performance of 50 mg in one minute is required, since the power plant passing through the sample space R _m For example, also emit this mass of material particles / minute, is a volume flow V. on liquid solvent 5 in the sample space R _m of 14ml / min, for example, for a period of 12 hours from the two sprayers 7 contribute. This would be about 840ml / h and about 10liter / 12h and about 20liter / 24h. At two spraying devices spraying the sample space Rm 7 would need a single spraying device 7 then for a downsizing of a particulate matter as a result of a constant production so Spray here about 10 liters / 24 hours in a half volume of the sample space R _m.

By means of a sequence of means of spraying 7 sprayed pattern spaces R _m along a road may be targeted, reduced a respective pollutant, to particulate matter, and in particular a respective particulate matter and noxious gas load.

With regard to the absorption capacity as a function of the droplet diameter x, additional experiments can be made for a respective harmful gas. But since the total volume of the drops remains largely unchanged, it is assumed that the influence of x is low. The larger the volume flow of the solvent 5 is, the greater the absorption effect. Harmful gas measurements may aid in optimizing the apparatus and method of the invention.

It is questionable now, on what to be provided power P _mech one of a spray 7 associated pressure generating device 9 is to be interpreted.

According to the formula (1) mentioned with reference to capillaries, that of a pressure generating device 9 for a respective spray device formed with at least one nozzle 7 Expected work W from the surface tension σ of the liquid solvent 5 and to be generated spray surface A _{S are} derived.

It is assumed here that with a technical nozzle the required work is greater than with a capillary, for example by a factor k> 1 could be greater. For water as a solvent 5 is a surface tension σ _W = 0.0727 N / m at 20 ° C basis. A _s required spray surface can be calculated with the droplet diameter x = 100μm according to the above calculation example, as follows, namely A _s = drop surface · number of drops = 3.14 · 10 ^-8 m ² · 25949115 = 0.81521549m ² . Accordingly, a work required to divide water into the drops would be W = 0.0727 N / m x 0.81521549m ² = 0.059266166Nm. This value can be multiplied by a factor k = 100 for adaptation to a nozzle, so that then also relatively large volume flows are taken into account. If this work is to be done within one minute, a pressure chamber should be assigned to a sample space R _m , here two 7 together provide a mechanical power P _mech ≈ 0.098777W ≈ 99mW.

Another possibility of approaching one of a pressure generating device 9 to be provided pumping power P _mech is the following: pressure generating devices 9 For example, they can be designed as hydrostatic positive displacement pumps, which are simply speed-controllable and self-priming by means of mechanical displacement, for example by means of pistons, and can generate a pressure of up to 10000 bar per stage. Alternatively, hydrodynamic centrifugal pumps can be used, which convert rotational energy into pressure, are just as easy to control the speed and can provide efficiencies of up to 70%. Centrifugal pumps can provide their hydrodynamic performance in particular by means of high speeds and can therefore be made compact and therefore more mobile than displacement pumps due to a small footprint. Correspondingly, spraying devices designed by means of centrifugal pumps are used 7 Acquisition costs and capital service less than for positive displacement pumps. In the case of a pump, a volumetric flow V. be provided directly proportional to their speed. A mechanical pump power P _mech can be described as follows: P _mech = Δp · V., (13) where Δp that of a pressure generator 9 provided pressure difference, and with V. the volume flow to be provided is specified.

A generated pressure difference Δp may, for example, be 2bar. A volume flow V. For example, for a sprayer 7  be the calculated above 14ml / 60s. Thus, the pumps for a sample space R_m together a mechanical power P_mech = 2 · 10⁵ N / m²· 14 · 10^-3dm³/ 60s = 28x10²· 10^-3 N m / 60s = 2.8Nm / 60s = 0.046W = 46mW. If a larger pressure difference Δp = 4bar is required, the result is 92mW. In pumps operated by electric motors, for determining an electrical power P to be provided_el the following formula are used: P _el = U · I, (14)  where P_el at a pump of a sprayer 7  electric power required for operation with the electric motor, U the applied electric voltage, I the electric current flowing to the operation.

At an efficiency of the pump w = P _mech / P _el (15) for example of w = 50%, must for two sprayers 7 with together P _mech = 100mW an electric power P _el of 200mW be provided. This can be provided for example by a solar module. For example, given a relatively weak ("30%") solar irradiation of 300 W / m ² module area and a solar module efficiency of 10%, ¹ m ² solar module area 30 W electric power P _el available.

In this way theoretically 300 sprayers could 7 be supplied with electrical power. It is advantageous that spraying in the case of rain is not necessary and that a reduction of the provided power of a solar module due to the clouding is thus no problem. In principle, alternatively or cumulatively, batteries, accumulators and / or electrical supply cables can also be used for an electric power supply of electric pumps.

For larger volume flows V to be provided, for example of 100 ml / 60 s, all the required power values can be assumed to be increased by a factor of 7.14 or 10 in such a way that with respect to the sample space R _m for both spray devices 7 P _mech ≈ 1W and P _el ≈ 2W and from a solar module then 30 sprayers 7 can be supplied with electrical power.

In principle, a sample space R _{m can} alternatively only be provided by a suitably dimensioned spraying device 7 be sprayed. Such - compared to two separate sprayers 7 - Doubled sprayer 7 can thus, for example, within 12h operating time volumes of 10 liters to 72 liters or up to 100 liters or more of liquid solvent 5 consume. These volumes can be from a respective intermediate container 11 or by means of supply lines 13 be promoted. This results in a volume flow V at 10 liters. = 10 x 1000ml / (12 x 60 x 60s) = 14ml / 60s. At 100 liters, V results. = 140ml / 60s.

Finally, it is pointed out again that analogous to Gartenbesprühungsanlagen the use of conventional perforated plates or perforated plates, for example, iron, steel, aluminum as metals or PVC as an example of a plastic, as respective nozzles simulate natural rain in a particularly simple manner. Correspondingly, such a configuration is the practice-related adaptation of differential pressure Δp to be built up and of a respective intermediate container 11 or by means of supply lines 13 Particularly easy to train volume flows to be promoted and therefore advantageous. Rule replication is advantageous because occupants of power plants or factories are not overly irritated when driving in a spray and because a purifying action of natural rain for particulate matter is known. Correspondingly, the diameters of produced drops can be adapted to those of rain, in particular stochastically.

To simulate rain, the spraying devices can be located in the sample space R _m 7 be set so that natural precipitation amounts in dm ³ / m ² h (precipitation / floor area and hour), in particular in the range of 5mm / h to 30mm / h, respectively. In a sample space R _m , the floor area is 100 _m ² , which would then be covered by, for example, 100 liters in 12 h. This corresponds to 100 x (0.1m) ³ / (100m ² x 12h) = 0.001m / 12h = 1mm / 12h. For a rainfall of 5mm / h then a sprayed volume of 60 x 100 liters = 6000 liters in 12 hours is required. A required volume flow V. then would be 8.33 liters / minute = 8333ml / 60s. In particular for simulating rain, respective nozzle orifice diameters may also be in the range of greater than 52.91 μm (for respective drop diameter x = 100 μm), for example up to about 530 μm (for respective drop diameter to about x = 1 mm) or to about 5.3 mm (for respective drop diameter to about x = 1cm) or even above.

Accordingly, then the required electrical power P _el for the then required mechanical power P _{mech must be} increased. Alternatively, instead of the differential pressure Ap can be reduced for a constant power, if appropriate, if the maximum discharge speed v _max then generated is still sufficient according to formula (3).

It is questionable for this purpose how large the differential pressure Δp should be in order to ensure a sufficient spray distribution in the sample space R _m and a sufficient covering of the soil in the sample space R _m . If all nozzles can spray vertically from the top down to the ground and the spray line (s) 15 extending across the full width of the road, the differential pressure Δp must first be as follows with respect to formula (9) for constructing the column up to the height h = 10m for water at 20C °: Δp = 0.9982 Kg / (0.1m ) ³ · 10m · 9.81N / Kg = 90836N / m ² ≈ 0.91bar. If a pump 2bar still provides 1.09 bar for spray generation, then according to formula (3) a maximum exit velocity of v _max ≈ √ (2 · 1.09 · 10 ⁵ N / m ² ) / (0.9982 Kg / (0,1m) ³ ) ≈ 14,78 m / s, with which the drops of the spray emerge from a nozzle. With a width of the sample space of 10m and a pump with a generated differential pressure Δp = 2bar can already be applied to a horizontal spraying from the roadside by means of a spraying device 7 the entire width of the road is covered by the spray. It is possible to choose the differential pressure Δp depending on a specific task, in particular depending on a necessary spray width, ie a width up to which drops are to be sprayed.

Likewise, the manufacturers' emission values of / Km can be used to calculate how large a sorption force of a spray produced should be, in particular so that at least a balance of emission and sorption is achieved. For example, emission levels of 159 g / km for CO ₂ emissions from manufacturers are mentioned. Accordingly, an entry of pollutants S or even material particles PM can then be extrapolated into a sample space R _m .

The above performed and illustrated calculations for a possible flow rate V. and a possible differential pressure Δp are to be considered as examples only, as for a real road device 1 and based on a modular system with sprayers 7 with pressure generating devices 9 can be set up and dimensioned to extract dust from the ambient air U a street. Due to these explicit calculations, a simple derivation for an actual required volumetric flow V is. and an actually required differential pressure Δp executable. Overdimensioning can be avoided due to the given calculation possibilities in order to unnecessarily waste resources on material, energy and money. Corresponding adjustments can be made simply and comprehensibly with the knowledge of a person skilled in the art of sputtering with reference to the above formulas and calculations in the context of the disclosure of this document.

Conventional measurements for each actual pollutant load, particulate matter, in particular particulate matter, can be carried out for each real sample space R _m . Such measured values can also be used for a design of a device according to the invention 1 and their operating parameters, such as the number and type of sprayers 7 and / or their respective differential pressures Ap and volumetric flows V. are to be used. By means of continuous or regular discrete measurements spraying devices can additionally be regulated. sprayers 7 may be from respective separate control devices 23 or be controlled or regulated by a central control device, for example by radio. Timers are also executable.

Modules that clean a respective pattern space R _m may be arranged along a road. In this case, a particulate matter and fine dust from road sections with a length of some 100m up to one or more km can be removed effectively and inexpensively.

According to 4 are two each according to, for example 1 illustrated sprayers 7 assigned a space R of the road, these pairs along the road for further spaces R can be repeatedly arranged and fixed in a modular manner. The distances of the modules along the road can be selected according to the size of the spaces R to be cleaned.

According to 4 the three are in the picture below along a horizontal line and also outside the pattern space R _m separate sprayers 7 containing the liquid solvent 5 each from their intermediate containers 11 use. Accordingly, an operating period is limited in time, since without refilling the intermediate container 11 the liquid solvent 5 is used up. The three in the picture above along a horizontal line and also outside of the sample space R _m arranged sprayers 7 are all on a common supply line 13 connected to the sprayers 7 continuous and unlimited in time with the liquid solvent 5 can provide. Accordingly, this can be a continuous operation of the device according to the invention 1 be created. In addition, several sprayers 7 from a single pressure generator 9 over the supply line 13 be subjected to a respective pressure difference Δp. When using electric pumps, these can also be supplied with electrical power by means of rechargeable batteries. 21 denotes a respective sewer system.

When it rains, the sprayers can 7 and the associated pressure generating device 9 switched off and then turned on again. The reconnection can be carried out delayed in time, for example after two or five hours, or only after a certain general solar radiation power. Likewise, a moisture measurement of a respective ambient air U of a room R an operation of a respective spraying device 7 Taxes. This is how a spraying device can be 7 generally be switched off on reaching a certain humidity of the ambient air U in the respective sample space R _m . The sprayers 7 can be powered by photovoltaic systems simply electrical power, since in the rain and then in the absence of power supply through the solar cells, the spray 7 do not need to be turned on.

The sprayers 7 and / or the pressure generating devices 9 can by means of electronic control devices 23 automatically or manually controlled and / or regulated. The control devices, for example, electric motors, valves and / or sensors on and / or off and / or power supply. Every device 1 may be a controller 23 be assigned, which can additionally be controlled centrally by means of a main control device, for example by radio. This is in 4 by means of arrows on a control device 23 shown.

control devices 23 can control electric motors based on time values and / or humidity values.

A controller is particularly simple and saves money, material and energy when spraying 7 only within a humidity range, in particular a range of relative humidity of the ambient air U in the relevant room R are turned on. The control devices 23 turn on the sprayers 7 by means of humidity measurements only when the relative humidity is, for example, below 80%, in particular below approximately 70% or below approximately 50% of the ambient air U for a room R, and correspondingly out again. The greater the absolute or relative humidity, in the extreme case of rain, the greater the number of drops of water naturally created in the ambient air U of the space R can be. In this way, a device according to the invention 1 to help reduce particulate pollution, promote natural droplet formation.

Likewise, a control on the basis of pollutant measurements, such as PM measurements or NO _x measurements can be executed. Further measured values for the control devices 23 For example, brightness readings, temperature readings, sound pressure readings and / or camera readings can be taken which can be detected by means of appropriate measuring devices, for example sensors and / or cameras. Any number of control types are applicable that take into account the emission behavior of power plants or factories or trains or general environmental parameters. Power supply installations 25 for providing electrical energy and power for operating the control devices 23 , Electric motors, sensors and other electrical components of the devices 1 For example, batteries, accumulators, solar cells, wind turbines, and / or transformer and distribution stations of a low or medium voltage electrical network can be.

According to the present invention, the device is integrated into a respective power plant and adapted accordingly.

In particular, flow characteristics of the exhaust gas and the exhaust air mixture should be taken into account.

5 shows a first embodiment of a method according to the invention. By means of devices according to the invention 1 , for example, according to the preceding 1 to 4 , is carried out in a first step S1 removal of pollutants S, in particular fine dust F and NO _x , from the ambient air U used by power plants or factories production infrastructure V, in particular a road, wherein at least one dispensing means an extraction means, in particular in the embodiment of a liquid sprayed solvent 5 , in a room R assigned to the production infrastructure V. By means of a second step S2 are present in the ambient air U in this space R floating pollutants S, in particular material particles PM and noxious gases, especially PM ₁₀ and PM _2.5 and PM _0.1 , by interaction with the extractant from the ambient air U of the room R removed. In a third step S3, the production infrastructure V is adapted such that the dissolved pollutants S, in particular material particles PM and noxious gases binding liquid solvent drops due to gravity and currents in the ambient air U to surfaces and / or volumes of the production infrastructure V moves and from this , in particular by sorption, can be recorded. This is usually the case with most production infrastructures V already. Basically, with the step S3, there is a possibility of disposal when using water as a liquid solvent 5 , the production infrastructure V is always sprayed with water, so that in particular the PM material particles always remain bound to surfaces and / or volumes.

According to the present invention, the apparatus and method are integrated into a respective power plant.

6 shows a second embodiment of a method according to the invention, which in the first three steps S1, S2 and S3 those according to the 5 like. In a fourth step S4, the production infrastructure V has been adapted so that the absorbed solvent drops again as combined liquid accumulations of the solvent 5 , in particular together with the dissolved pollutants S, in particular material particles PM and noxious gases, to a sewage system 21 discharged and disposed of.

According to the present invention, the apparatus and method are integrated into a respective power plant.

7 shows an embodiment of an exhaust passage or channel 2 in cross section. 7 corresponds to the first embodiment of a device according to the invention 1 who now use a channel instead of a production infrastructure V 2 for discharging an exhaust gas from a combustion chamber for heating a working medium - for example, a turbine for driving an electric generator - cleans. 7 shows the device 1 for removing pollutants S, in particular particulate matter or fine dust F and noxious gases, from a mixture of exhaust air U of a channel 2 , wherein at least one dispensing device in the form of a spray device 7 an extractant in the form of a liquid solvent 5 into a canal 2 assigned and here lying in this room R and in the exhaust air mixture U in this space R existing pollutants S, in particular suspended material particles PM, in particular PM ₁₀ , PM _2.5 and PM _0.1 , and noxious gases, such as NO and NO _x , by interaction with the liquid solvent 5 be removed from the exhaust air mixture U of the room R.

The dispensing device in an embodiment of a respective spraying device 7 sprays a divided liquid solvent 5 in the form of drops in the exhaust air mixture U of the space R, wherein a spray and in particular an aerosol are generated.

As a liquid solvent 5 Particularly advantageously, water can be used partially or completely. Water can be provided, for example, in a simple manner and in large volume flows.

reference numeral 7 denotes a spraying device used 7 , For spraying a liquid solvent, in particular a mechanical spraying technique can be used, which is conventionally also referred to as sputtering technique, wherein liquids, suspensions or dispersions can be divided into droplets. By means of spraying and thus by means of drop formation, free and, in particular, surfaces which can be used for adsorption and, in particular, volumes usable for absorption can be provided, so that heat exchange processes and in particular those for the purification of ambient air and removal of production plants, in particular of power plants or factories, emitted pollutants S, in particular material particles PM and noxious gases, from the ambient air U necessary mass transfer processes can be effectively implemented.

The subject of the application may also be implemented as a method:
Procedure ( 1 ) for removing pollutants, in particular particulate matter (S), in particular fine dust (F) and noxious gases, such as NO and NO _x, from an exhaust air mixture (U) of combustion chambers of a production plant, in particular a power plant and / or a factory, wherein at least one spraying device ( 7 ) a liquid solvent ( 5 ), in particular water, in one of the production plant associated and the exhaust gas mixture (U) contained space (R) sprays (S1) and a spray and in particular an aerosol generated that in the exhaust gas mixture (U) in this space (R) pollutants , in particular suspended material particles PM, in particular PM ₁₀ , and harmful gases, for example NO and NO _x , removed (S2), the space (R) in a channel ( 2 ) is contained for discharging the exhaust gas of the combustion chamber (s) from the production plant.

Method, wherein a control device ( 23 ) the spraying device (s) ( 7 ) for spraying the liquid solvent ( 5 ) controls or regulates on the basis of measured values of the ambient air (U) detected by means of at least one measuring device.

Method, the control device ( 23 ) has at least one pollutant measured values, moisture measurement values, temperature values, pressure values and / or density values of the ambient air (U) detecting measuring device.

Method, the control device ( 23 ) the spraying device (s) ( 7 ) for spraying the liquid solvent ( 5 ) by means of a timing circuit, in particular by means of timing profiles, controls or regulates.

Method, the control device ( 23 ) the spraying device (s) ( 7 ) for spraying the liquid solvent ( 5 ) controls or regulates by means of a global position coordinates detecting position determining device.

Method, the control device ( 23 ) the spraying device (s) ( 7 ) for spraying the liquid solvent ( 5 ) controls or regulates by means of at least one measuring device which detects the pollutant load of the spray or sorbate which has been removed.

Method, the control device ( 23 ) the spraying device (s) ( 7 ) for spraying the liquid solvent ( 5 ) switches off when a limit value of the pollutant load of the sprinkled spray or sorbate is exceeded.

Method, wherein the sprung spray of the / the spray device (s) is returned by means of a return line, which in particular has a filter.

Claims (9)

Contraption ( 1 ) for removing pollutants (S), in particular particulate matter (F) and noxious gases, such as NO and NO _x, from an exhaust air mixture (U) of combustion chambers of a production plant, in particular a power plant and / or a factory, wherein at least one spraying device ( 7 ) a liquid solvent ( 5 ), in particular water, in one of the production plant associated and the exhaust gas mixture (U) contained space (R) sprays (S1) and a spray and in particular an aerosol generated which in the exhaust gas mixture (U) in this space (R) pollutants (S), in particular suspended material particles PM, in particular PM ₁₀ , and harmful gases, for example NO and NO _x , removed (S2), wherein the space (R) in a channel ( 2 ) is contained for discharging the exhaust gas of the combustion chamber (s) from the production plant. Device according to claim 1, characterized in that the spraying device ( 7 ) for spraying at least one, in particular by means of a perforated plate or perforated plate generated, pressure nozzle, in particular at least one single-fluid pressure nozzle, or at least one rotary sprayer. Device according to claim 1 or 2, characterized in that the spraying device ( 7 ) respective droplet diameter (x) for dissolution (S2) by sorption, in particular by adsorption, and / or chemically greater than the diameter of the material particles to be removed PM, in particular PM ₁₀ and the PM _2.5 and PM _0.1 , namely greater than 10 .mu.m, and in particular less than 1100 .mu.m, in particular less than about 300 .mu.m generated. Apparatus according to claim 2 or 3, characterized in that a nozzle opening diameter d of an outlet opening of a respective pressure nozzle in the range of about 1000μm / 1.89 = 529.1μm to about 100μm / 1.89 = 52.91μm is selected. Device according to claim 3 or 4, characterized in that the spraying device ( 7 ) the liquid solvent ( 5 ) from an intermediate container ( 11 ) and / or a supply line ( 13 ) is supplied. Device according to one of the preceding claims, characterized in that the spraying device ( 7 ) the liquid solvent into an elongated spray line ( 15 ) having nozzles arranged along the length thereof, wherein a plurality of, in particular flexible, elongated spray lines (FIGS. 15 ), in particular along an arc, extending from an edge of the channel towards an opposite edge of the channel and along the channel. Device according to one of the preceding claims, characterized in that the production plant has the channel and the pollutants (S) contained exhaust gas of the combustion chamber (s), in particular by means of a flow-generating device ( 17 ), in at least one separate extraction room ( 19 ), in which the solvent ( 5 ) is introduced, wherein the exhaust gas is cleaned together with ambient air. Device according to one of the preceding claims, characterized in that a regulating device ( 23 ) is set up such that the spray device (s) ( 7 ) for spraying the liquid solvent ( 5 ) is controlled or regulated on the basis of measured values of the exhaust gas and / or the ambient air (U) detected by means of measuring devices and / or by means of time profile profiles. Device according to one of the preceding claims, characterized in that the liquid solvent ( 5 ) has an antifreeze.

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