DE19922401A1 - Use of thiacloprid for protecting articles, e.g. ships, nets or buildings, against fouling - Google Patents
Use of thiacloprid for protecting articles, e.g. ships, nets or buildings, against foulingInfo
- Publication number
- DE19922401A1 DE19922401A1 DE1999122401 DE19922401A DE19922401A1 DE 19922401 A1 DE19922401 A1 DE 19922401A1 DE 1999122401 DE1999122401 DE 1999122401 DE 19922401 A DE19922401 A DE 19922401A DE 19922401 A1 DE19922401 A1 DE 19922401A1
- Authority
- DE
- Germany
- Prior art keywords
- thiacloprid
- nets
- ships
- buildings
- against fouling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Die vorliegende Erfindung betrifft ein Verfahren und Mittel zum Schutz von Be wuchs von Gegenständen, insbesondere von Schiffskörpern, Sieben, Netzen, Bau werken, Kaianlagen und Signalanlagen, welche mit See- oder Brackwasser in Ver bindung kommen.The present invention relates to a method and means for protecting Be grew from objects, especially from hulls, screens, nets, construction plants, quay systems and signaling systems, which with sea or brackish water in Ver bond come.
Bewuchs durch sessile Oligochaeten, wie Kalkröhrenwürmer sowie durch Muscheln und Arten der Gruppe Ledamorpha (Entenmuscheln), wie verschiedene lepas- und Scalpellum-Arten, oder durch Arten der Gruppe Blanomorpha (Seepocken), wie Balanus- oder Pollicipes-Species, erhöht den Reibungswiderstand von Schiffen und führt in der folge durch erhöhten Energieverbrauch und darüber hinaus durch häufige Trockendockaufenthalte zu einer deutlichen Steigerung der Betriebskosten.Overgrowth by sessile oligochaetes, such as lime tube worms and by mussels and species of the Ledamorpha (barnacles) group, such as various lepas and Scalpellum species, or by species of the group Blanomorpha (barnacles), such as Balanus or pollicipes species, increases the frictional resistance of ships and subsequently leads through increased energy consumption and moreover through frequent Dry dock stays for a significant increase in operating costs.
Neben dem Bewuchs durch Algen, beispielsweise Ectocarpus sp. und Ceramium sp., kommt insbesondere dem Bewuchs durch sessile Entomostraken-Gruppen, welche unter dem Namen Cirripedia (Rankenflußkrebse) zusammengefaßt werden, be sondere Bedeutung zu.In addition to the growth by algae, for example Ectocarpus sp. and Ceramium sp., comes in particular the vegetation by sessile Entomostraken groups, which can be summarized under the name Cirripedia (barnacles) special importance.
Es ist bereits bekannt, daß N-[3-(6-Chlorpyridin-3-ylmethyl)thiazolidin-2-yliden]cy anamid (Thiacloprid) insektizide Eigenschaften besitzt (EP 235 725).It is already known that N- [3- (6-chloropyridin-3-ylmethyl) thiazolidin-2-ylidene] cy anamide (thiacloprid) has insecticidal properties (EP 235 725).
Es wurde nun überraschenderweise gefunden, daß Thiacloprid allein oder in Kombination mit anderen Wirkstoffen, eine hervorragende Antiflouling (Antibe wuchs)-Wirkung aufweist.It has now surprisingly been found that thiacloprid alone or in Combination with other active ingredients, an excellent antiflouling (antibe growth) effect.
Durch Einsatz von Thiacloprid oder von Thiacloprid in Kombination mit anderen Wirkstoffen, kann auf den Einsatz von Schwermetallen wie z. B. in Bis(trialkylzinn)- sulfiden, Tri-n-butylzinnlaurat, Tri-n-butylzinnchlorid, Kupfer(I)-oxid, Triethylzinn chlorid, Tri-n-butyl-(2-phenyl-4-chlorphenoxy)-zinn, Tributylzinnoxid, Molybdän disulfid, Antimonoxid, polymerem Butyltitanat, Phenyl-(bispyridin)-wismutchlorid, Tri-n-butylzinnfluorid, Manganethylenbisthiocarbamat, Zinkdimethyldithiocarbamat, Zinkethylenbisthiocarbamat, Zinksalz von 2-Pyridinthiol-1-oxid, Bisdimethyldithio carbamoylzinkethylenbisthiocarbamat, Zinkoxid, Kupfer(I)-ethylen-bisdithio carbamat, Kupferthiocyanat, Kupfernaphthenat und Tributylzinnhalogeniden ver zichtet werden oder die Konzentraktion dieser Verbindungen entscheidend reduziert werden.By using thiacloprid or thiacloprid in combination with others Active ingredients, can on the use of heavy metals such. B. in bis (trialkyltin) - sulfides, tri-n-butyltin laurate, tri-n-butyltin chloride, copper (I) oxide, triethyltin chloride, tri-n-butyl- (2-phenyl-4-chlorophenoxy) tin, tributyltin oxide, molybdenum disulfide, antimony oxide, polymeric butyl titanate, phenyl (bispyridine) bismuth chloride, Tri-n-butyltin fluoride, manganese ethylene bisthiocarbamate, zinc dimethyldithiocarbamate, Zinc ethylene bisthiocarbamate, zinc salt of 2-pyridinthiol-1-oxide, bisdimethyldithio carbamoylzinc ethylene bisthiocarbamate, zinc oxide, copper (I) ethylene bisdithio carbamate, copper thiocyanate, copper naphthenate and tributyltin halides ver be eliminated or the concentration of these compounds significantly reduced become.
Gegenstand der Anmeldung sind daher Antifouling-Mittel, die entweder Thiacloprid oder Thiacloprid in Kombination mit anderen Wirkstoffen, vorzugsweise Algiziden, Fungiziden, Herbiziden, Molluskiziden bzw. anderen Antifouling-Wirkstoffen ent halten.The application therefore relates to antifouling agents, either thiacloprid or thiacloprid in combination with other active ingredients, preferably algicides, Fungicides, herbicides, molluscicides or other antifouling agents ent hold.
Gegenstand der Erfindung ist auch ein Verfahren zum Schutz von Gegenständen vor Bewuchs, das darin besteht, daß man die erfindungsgemäßen Antifouling-Mittel auf die Gegenstände aufträgt bzw. die Gegenstände mit dem Antifouling-Mittel versetzt.The invention also relates to a method for protecting objects from Growth, which consists in that the antifouling agents according to the invention apply the objects or add the antifouling agent to the objects.
Gegenstand der Erfindung ist weiterhin die Verwendung der erfindungsgemäßen Antifuoling-Mittel zum Schutz von Gegenständen vor Bewuchs, insbesondere vor Bewuchs durch sessile Entomortraken und sessile Oligochaeten.The invention further relates to the use of the invention Antifuoling agent for protecting objects against fouling, especially against Overgrowth by sessile Entomorra and sessile oligochaetes.
Als Kombinationspartner für die erfindungsgemäßen Antifouling-Mittel eignen sich
vorzugsweise:
Algizide wie 2-tert.-Butylamino-4-cyclopropylamino-6-methylthio-1,3,5-triazin, Di
chlorophen, Diuron, Endothal, Fentinacetat, Isoproturon, Methabenzthiazuron, Oxy
fluorfen, Quinoclamine und Terbutryn;
Fungizide wie Benzo[b]thiophencarbonsäurecyclohexylamid-S,S-dioxid, Dichlo
fluanid, Fluorfolpet, 3-Iod-2-propinyl-butylcarbamat, Tolylfluanid und Azole wie
Azaconazol, Cyproconazol, Epoxyconazol, Hexaconazol, Metconazol, Propiconazol
und Tebuconazol;
Molluskizide wie Fentinacetat, Metaldehyd, Methiocarb, Niclosamid, Thiodicarb und
Trimethacarb;
oder herkömmliche Antifouling-Wirkstoffe wie 4,5-Dichlor-2-octyl-4-isothiazolin-3-
on, Diiodmethylparatrylsulfon, 2-(N,N-Dimethylthiocarbamoylthio)-5-nitrothiazyl,
Kalium-, Kupfer, Natrium- und Zinksalze von 2-Pyridinthiol-1-oxid, Pyridin-tri
phenylboran, Tetrabutyldistannoxan, 2,3,5,6-Tetrachlor-4-(methylsulfonyl)-pyridin,
2,4,5,6-Tetrachloroisophthalonitril, Tetramethylthiuramdisulfid und 2,4,6-Trichlor
phenylmaleinimid.Suitable combination partners for the antifouling agents according to the invention are preferably:
Algicides such as 2-tert-butylamino-4-cyclopropylamino-6-methylthio-1,3,5-triazine, di chlorophene, diuron, endothal, fentin acetate, isoproturon, methabenzthiazuron, oxy fluorfen, quinoclamine and terbutryn;
Fungicides such as benzo [b] thiophenecarboxylic acid cyclohexylamide-S, S-dioxide, dichlo fluanide, fluorfolpet, 3-iodo-2-propynyl butyl carbamate, tolylfluanid and azoles such as azaconazole, cyproconazole, epoxyconazole, hexaconazole, metconazolebuconazole, propicon;
Molluscicides such as fentin acetate, metaldehyde, methiocarb, niclosamide, thiodicarb and trimethacarb;
or conventional antifouling agents such as 4,5-dichloro-2-octyl-4-isothiazolin-3-one, diiodomethylparatrylsulfone, 2- (N, N-dimethylthiocarbamoylthio) -5-nitrothiazyl, potassium, copper, sodium and zinc salts of 2-pyridinthiol-1-oxide, pyridine-tri phenylborane, tetrabutyldistannoxane, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, 2,4,5,6-tetrachloroisophthalonitrile, tetramethylthiuram disulfide and 2,4,6 -Trichlor phenylmaleimide.
Die verwendeten Antifouling-Mittel enthalten den erfindungsgemäßen Wirkstoff in einer Konzentration von 0,001 bis 50 Gew.-%, insbesondere von 0,01 bis 20 Gew.-%.The antifouling agents used contain the active ingredient according to the invention in a concentration of 0.001 to 50 wt .-%, in particular from 0.01 to 20% by weight.
Die erfindungsgemäßen Antifouling-Mittel enthalten desweiteren die üblichen Be standteile wie z. B. in Ungerer, Chem. Ind. 1985, 37, 730-732 und Williams, Anti fouling Marine Coatings, Noyes, Park Ridge, 1973 beschrieben.The antifouling agents according to the invention also contain the usual Be components such as B. in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams, Anti fouling Marine Coatings, Noyes, Park Ridge, 1973.
Antifouling-Anstrichmittel enthalten neben den algiziden, fungiziden, molluskiziden und erfindungsgemäßen insektiziden Wirkstoffen insbesondere Bindemittel.Antifouling paints contain algicidal, fungicidal, molluscicides and insecticidal active substances according to the invention, in particular binders.
Beispiele für anerkannte Bindemittel sind Polyvinylchlorid in einem Lösungs mittelsystem, chlorierter Kautschuk in einem Lösungsmittelsystem, Acrylharze in einem Lösungsmittelsystem insbesondere in einem wäßrigen System, Vinyl chlorid/Vinylacetat-Copolymersysteme in Form wäßriger Dispersionen oder in Form von organischen Lösungsmittelsystemen, Butadien/Styrol/Acrylnitril-Kautschuke, trocknende Öle, wie Leinsamenöl, Harzester oder modifizierte Hartharze in Kombination mit Teer oder Bitumina, Asphalt sowie Epoxyverbindungen, geringe Mengen Chlorkautschuk, chloriertes Polypropylen und Vinylharze.Examples of recognized binders are polyvinyl chloride in a solution medium system, chlorinated rubber in a solvent system, acrylic resins in a solvent system especially in an aqueous system, vinyl chloride / vinyl acetate copolymer systems in the form of aqueous dispersions or in the form of organic solvent systems, butadiene / styrene / acrylonitrile rubbers, drying oils, such as linseed oil, resin esters or modified hard resins in Combination with tar or bitumen, asphalt and epoxy compounds, low Amounts of chlorinated rubber, chlorinated polypropylene and vinyl resins.
Gegebenenfalls enthalten Anstrichmittel auch anorganische Pigmente, organische Pigmente oder Farbstoffe, welche vorzugsweise in Seewasser unlöslich sind. Ferner können Anstrichmittel Materialien, wie Kolophonium enthalten, um eine gesteuerte Freisetzung der Wirkstoffe zu ermöglichen. Die Anstriche können ferner Weich macher, die rheologischen Eigenschaften beeinflussende Modifizierungsmittel sowie andere herkömmliche Bestandteile enthalten. Auch in Self-Polishing-Antifouling- Systemen können Thiacloprid oder die erfindungsgemäßen Kombinationen mit Thiacloprid eingearbeitet werden.Paints may also contain inorganic pigments, organic Pigments or dyes, which are preferably insoluble in sea water. Further Paints can contain materials, such as rosin, to be controlled To enable release of the active ingredients. The paints can also be soft makers, modifiers influencing the rheological properties, and contain other conventional ingredients. Also in self-polishing antifouling Systems can include thiacloprid or the combinations according to the invention Thiacloprid are incorporated.
Claims (4)
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1999122401 DE19922401A1 (en) | 1999-05-14 | 1999-05-14 | Use of thiacloprid for protecting articles, e.g. ships, nets or buildings, against fouling |
| KR1020000013014A KR20000071444A (en) | 1999-04-07 | 2000-03-15 | Antifouling compositions comprising thiacloprid |
| JP2000085861A JP2000313855A (en) | 1999-04-07 | 2000-03-27 | Antifouling composition containing thiacloprid |
| EP00106005A EP1042955A1 (en) | 1999-04-07 | 2000-03-27 | Antifouling agents containing thiacloprid |
| ARP000101388A AR023194A1 (en) | 1999-04-07 | 2000-03-28 | ANTIINCRUSTING AGENT CONTAINING THIACLOPRID |
| US09/538,393 US6245784B1 (en) | 1999-04-07 | 2000-03-29 | Antifouling compositions containing thiacloprid |
| AU26398/00A AU2639800A (en) | 1999-04-07 | 2000-04-05 | Antifouling compositions comprising thiacloprid |
| NZ503798A NZ503798A (en) | 1999-04-07 | 2000-04-05 | Antifouling compositions comprising thiacloprid for treating infestation by sessile Entomostraca and/or sessile Oligochaetes |
| NO20001783A NO20001783L (en) | 1999-04-07 | 2000-04-06 | Antifouling agents containing thiacloprid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1999122401 DE19922401A1 (en) | 1999-05-14 | 1999-05-14 | Use of thiacloprid for protecting articles, e.g. ships, nets or buildings, against fouling |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19922401A1 true DE19922401A1 (en) | 2000-11-16 |
Family
ID=7908166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1999122401 Withdrawn DE19922401A1 (en) | 1999-04-07 | 1999-05-14 | Use of thiacloprid for protecting articles, e.g. ships, nets or buildings, against fouling |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE19922401A1 (en) |
-
1999
- 1999-05-14 DE DE1999122401 patent/DE19922401A1/en not_active Withdrawn
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8130 | Withdrawal |