DE19850373A1 - Exhaust system with adsorber for internal combustion engine, in which fresh air flow can be mixed with exhaust gas downstream of adsorber and upstream of catalytic converter - Google Patents

Exhaust system with adsorber for internal combustion engine, in which fresh air flow can be mixed with exhaust gas downstream of adsorber and upstream of catalytic converter

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Publication number
DE19850373A1
DE19850373A1 DE19850373A DE19850373A DE19850373A1 DE 19850373 A1 DE19850373 A1 DE 19850373A1 DE 19850373 A DE19850373 A DE 19850373A DE 19850373 A DE19850373 A DE 19850373A DE 19850373 A1 DE19850373 A1 DE 19850373A1
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Prior art keywords
adsorber
exhaust gas
combustion engine
internal combustion
fresh air
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DE19850373A
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German (de)
Inventor
Heinz Oeller
Bernd Plodek
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Bayerische Motoren Werke AG
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Bayerische Motoren Werke AG
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Priority to DE19850373A priority Critical patent/DE19850373A1/en
Publication of DE19850373A1 publication Critical patent/DE19850373A1/en
Withdrawn legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/0205Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust using heat exchangers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/05Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of air, e.g. by mixing exhaust with air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0835Hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0871Regulation of absorbents or adsorbents, e.g. purging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2006Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating
    • F01N3/2013Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means
    • F01N3/2026Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means directly electrifying the catalyst substrate, i.e. heating the electrically conductive catalyst substrate by joule effect
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/30Arrangements for supply of additional air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/30Arrangements for supply of additional air
    • F01N3/303Filtering additional air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/30Arrangements for supply of additional air
    • F01N3/32Arrangements for supply of additional air using air pump
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/02Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a heat exchanger
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2370/00Selection of materials for exhaust purification
    • F01N2370/22Selection of materials for exhaust purification used in non-catalytic purification apparatus
    • F01N2370/24Zeolitic material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

The exhaust system includes a catalytic converter (8) with an adsorber (6) in front of it for the short-term storage of at least one component of the exhaust gas after a cold start. A fresh air flow can be mixed with the exhaust gas downstream of the adsorber and upstream of the catalytic converter. This fresh air stream as previously been brought into heat-exchange connection with the exhaust gas flow upstream of the adsorber.

Description

Die Erfindung betrifft eine Abgasanlage einer Brennkraftmaschine mit einem Kataly­ sator zur Konvertierung schädlicher Abgasbestandteile sowie mit einem diesem vor­ geschalteten Adsorber, in welchem insbesondere nach einem Kaltstart der Brenn­ kraftmaschine zumindest eine Komponente des Brennkraftmaschinen-Abgases kurzfristig speicherbar ist. Zum technischen Umfeld wird beispielshalber auf die US 5,538,698 verwiesen.The invention relates to an exhaust system of an internal combustion engine with a catalyzer sator for converting harmful exhaust gas components as well as with one switched adsorber, in which in particular after a cold start of the combustion Engine at least one component of the internal combustion engine exhaust gas can be saved at short notice. For technical reasons, reference is made to the US 5,538,698.

Zur Erfüllung zunehmend strengerer Abgasgrenzwerte an von Brennkraftmaschinen angetriebenen Kraftfahrzeugen ist es grundsätzlich von Vorteil, einen üblichen Ab­ gas-Katalysator im Anschluß an einen Kaltstart der Brennkraftmaschine möglichst schnell auf seine Betriebstemperatur zu bringen. Ein bekanntes Mittel hierfür ist es, diesen Katalysator insbesondere mit elektrischer Energie aufzuheizen. Auch ist ein System bekannt, das die nach dem Brennkraftmaschinen-Start ausgestoßenen Kohlenwasserstoffe zu einem großen Teil in einem sog. Adsorber zumindest bei niedrigen Temperaturen festhält und erst bei höheren Temperaturen (des Adsor­ bers) wieder abgibt. Diese werden dann in dem bis dahin bereits im wesentlichen aufgeheizten und stromab des Adsorbers vorgesehenen Katalysator konvertiert. Ein derartiges System ist in der o. g. Schrift gezeigt. To meet increasingly stringent exhaust gas limits on internal combustion engines driven motor vehicles, it is generally advantageous to start a normal gas catalyst after a cold start of the internal combustion engine if possible to quickly bring it up to its operating temperature. A well-known means of doing this is to heat this catalyst in particular with electrical energy. Is also a System known that the ejected after the engine start A large part of hydrocarbons in a so-called adsorber, at least holds low temperatures and only at higher temperatures (the adsor bers) again. These are then essentially already in the meantime heated catalyst and provided downstream of the adsorber. On such system is in the above. Scripture shown.  

Eine weitere bekannte Maßnahme, mit Hilfe derer ein Abgas-Katalysator schnell auf seine Betriebstemperatur gebracht werden kann, ist es, die Brennkraftmaschine unmittelbar nach einem Start mit einem fetten Luft-Kraftstoffgemisch zu betreiben, so daß die dabei emittierten Kohlenwasserstoffe und Kohlenmonoxide zusammen mit einem dem Abgas zugeführten Frischluftstrom im Katalysator durch exotherme Reaktionen die erwünschte Aufheizung bewirken. Zusätzlich kann durch einen Be­ trieb einer fremdgezündeten Brennkraftmaschine mit späten Zündwinkeln das hier­ durch heißere Abgas die Aufheizung des Katalysators beschleunigen.Another known measure by means of which an exhaust gas catalytic converter quickly turns on its operating temperature can be brought down to the internal combustion engine operate with a rich air-fuel mixture immediately after starting, so that the hydrocarbons and carbon monoxides emitted together with a fresh air stream supplied to the exhaust gas in the catalytic converter by exothermic Reactions bring about the desired heating. In addition, a Be drove this to a spark ignition internal combustion engine with late firing angles accelerate the heating up of the catalytic converter by hotter exhaust gas.

Nachteilig an diesen bekannten Verfahrensweisen ist es, daß die relativ heißen und schadstoffreichen Abgase der Brennkraftmaschine auch den insbesondere die Kohlenwasserstoffe adsorbierenden und vor dem Katalysator angeordneten Adsor­ ber in unerwünschter Weise aufheizen, so daß dieser die adsorbierte(n) Abgaskom­ ponente(n), insbesondere Kohlenwasserstoffe, bereits zu einem Zeitpunkt wieder abgibt, zu dem der nachfolgende Katalysator seine Betriebstemperatur noch nicht vollständig erreicht hat.A disadvantage of these known procedures is that the relatively hot and pollutant-rich exhaust gases from the internal combustion engine, particularly the Adsorbing hydrocarbons and arranged in front of the catalyst About heating in an undesirable manner, so that this the adsorbed exhaust gas (s) component (s), especially hydrocarbons, at one point in time emits at which the subsequent catalyst does not yet reach its operating temperature has reached completely.

Eine Abhilfemaßnahme für diese geschilderte Problematik aufzuzeigen, ist Aufgabe der vorliegenden Erfindung.It is the task of pointing out a remedial measure for this problem of the present invention.

Die Lösung dieser Aufgabe ist dadurch gekennzeichnet, daß dem Brennkraftma­ schinen-Abgas stromab des Adsorbers sowie stromauf des Katalysators ein Frisch­ luftstrom beimengbar ist, der zuvor mit dem Abgasstrom stromauf des Adsorbers in eine wärmetauschende Verbindung gebracht wird. Bevorzugt vorgesehen ist hierzu eine vom Ansaugtrakt der Brennkraftmaschine abzweigende und in der das Brenn­ kraftmaschinen-Abgas führenden Abgasleitung stromab des Adsorbers sowie stromauf des Katalysators mündende Frischluftleitung, die durch einen an der das Abgas dem Adsorber zuführenden Abgasleitung vorgesehenen Wärmetauscher geführt ist, und in der sich ein Mengensteuerorgan und/oder eine Fördervorrichtung für den Frischluftstrom befindet.The solution to this problem is characterized in that the internal combustion engine Engine exhaust gas fresh downstream of the adsorber and upstream of the catalytic converter Airflow is admixed, which previously upstream with the exhaust gas flow in the adsorber a heat-exchanging connection is brought. It is preferably provided for this one branching off from the intake tract of the internal combustion engine and in which the combustion engine exhaust leading exhaust pipe downstream of the adsorber as well upstream of the catalyst opening fresh air line, through which the Exhaust gas supplying the adsorber exhaust pipe provided heat exchanger is guided, and in which there is a quantity control member and / or a conveyor for the fresh air flow.

Inhalt der Erfindung ist es somit, das Verhalten des Adsorbers dadurch positiv zu beeinflussen, daß dem Abgas vor dem Adsorber ein Teil der an dieser Stelle uner­ wünschten Wärme entzogen und stromauf des Katalysators wieder zugeführt wird.The content of the invention is thus to improve the behavior of the adsorber influence that the exhaust gas in front of the adsorber part of the un at this point  Desired heat is withdrawn and fed upstream of the catalyst.

Erfindungsgemäß geschieht dies dadurch, daß die zum frühzeitigen Anspringen des Katalysators zusätzlich zugeführte Frischluft, d. h. die sog. Sekundärluft, über einen stromauf des Adsorbers gelegenen Wärmetauscher geleitet wird, wobei diese Frischluft/Sekundärluft einen möglichst großen Teil der Abgaswärme aufnimmt und diese danach stromauf des Katalysators bei einer Vermischung derselben mit dem Abgasstrom wieder einbringt. Auf diese Weise bleibt das wunschgemäß frühe An­ springverhalten des Katalysators unverändert, während der Adsorber weniger schnell aufgeheizt wird und dadurch längere Zeit seine erwünschte Funktion als Speicherorgan für zumindest eine Abgaskomponente, insbesondere Kohlenwasser­ stoffe, wahrnehmen kann.According to the invention this is done in that the early start of the Fresh air supplied to the catalyst, i. H. the so-called secondary air, via a upstream of the adsorber heat exchanger is passed, this Fresh air / secondary air absorbs as much of the exhaust gas heat as possible and this then upstream of the catalyst when mixed with the Introduces exhaust gas flow again. In this way, the early on as desired remains jumping behavior of the catalyst unchanged, while the adsorber less is heated up quickly and thus its desired function as a long time Storage device for at least one exhaust gas component, in particular hydro fabrics, can perceive.

Näher erläutert wird die Erfindung anhand eines in der beigefügten einzigen Figur dargestellten bevorzugten Ausführungsbeispieles.The invention is explained in more detail with reference to one in the attached single figure illustrated preferred embodiment.

Mit der Bezugsziffer 1 ist eine hier vierzylindrige, gemischverdichtende, fremdge­ zündete Brennkraftmaschine bezeichnet, deren Zylindern über einen Ansaugtrakt 2 Frischgas zugeführt wird. Nicht dargestellt ist eine Kraftstoffeinspritzvorrichtung, mit Hilfe derer dem Frischgas Kraftstoff beigemengt wird. Diese Mischung wird dann wie üblich in den Brennkraftmaschinen-Zylindern verbrannt und als Abgas über die in ihrer Gesamtheit mit der Bezugsziffer 3 bezeichnete Abgasanlage in die Umgebung abgeführt.Reference number 1 denotes a four-cylinder, mixture-compressing, externally ignited internal combustion engine, the cylinders of which are supplied with fresh gas via an intake tract 2 . A fuel injection device, by means of which fuel is added to the fresh gas, is not shown. This mixture is then burned as usual in the internal combustion engine cylinders and discharged into the environment as exhaust gas via the exhaust gas system, designated in its entirety by reference number 3 .

Die Abgasanlage 3 besteht aus einem die Abgase der einzelnen Zylinder sammeln­ den Abgaskrümmer 4, an welchen sich eine Abgasleitung 5 anschließt, die in einem Adsorber 6 mündet. Von diesem Adsorber 6 aus werden die Brennkraftmaschinen- Abgase über eine weitere Abgasleitung 7 einem in seiner Gesamtheit mit der Be­ zugsziffer 8 bezeichneten Katalysator zugeführt. Dieser Katalysator 8 besteht aus einem elektrisch beheizbaren sog. E-Katalysator 8a sowie einem sich daran an­ schließenden Drei-Wege-Hauptkatalysator 8b. Von letzterem aus gelangt der Ab­ gasstrom der Brennkraftmaschine 1 über eine Abgasleitung 9 zu einem nicht ge­ zeigten Schalldämpfer und von diesem aus letztendlich in die Umgebung. The exhaust system 3 consists of a the exhaust gases of the individual cylinders collect the exhaust manifold 4 , to which an exhaust pipe 5 connects, which opens into an adsorber 6 . From this adsorber 6 , the internal combustion engine exhaust gases are fed via a further exhaust line 7 to a catalyst designated in its entirety with the reference numeral 8 . This catalyst 8 consists of an electrically heatable so-called E-catalyst 8 a and an adjoining three-way main catalyst 8 b. From the latter, the gas flow from the internal combustion engine 1 passes through an exhaust pipe 9 to a muffler, not shown, and from this ultimately into the environment.

Im Katalysator 8 werden schädliche Abgasbestandteile in unschädliche Stoffe kon­ vertiert, wenn dieser Katalysator 8 seine Betriebstemperatur erreicht hat. Um das Erreichen dieser Betriebstemperatur im Anschluß an einen Kaltstart der Brennkraft­ maschine 1 zu beschleunigen, ist der E-Katalysator 8a elektrisch beheizbar. Dabei bringt die elektrisch zugeführte Energie nicht nur den E-Katalysator 8a schneller auf seine Betriebstemperatur, sondern auch den Drei-Wege-Hauptkatalysator 8b, da ein Teil dieser Energie auch dem letztgenannten über den Abgasstrom zugeführt wird.In the catalytic converter 8 , harmful exhaust gas constituents are converted into harmless substances when this catalytic converter 8 has reached its operating temperature. In order to accelerate the achievement of this operating temperature following a cold start of the internal combustion engine 1 , the e-catalyst 8 a is electrically heated. The electrical energy supplied not only brings the E-catalyst 8 a faster to its operating temperature, but also the three-way main catalyst 8 b, since a part of this energy and the latter is supplied via the exhaust stream.

Im Adsorber 6 ist insbesondere im Anschluß an einen Kaltstart der Brennkraftma­ schine 1 zumindest eine Komponente des Brennkraftmaschinen-Abgases kurzfristig speicherbar, und zwar wünschenswerterweise solange, bis der Katalysator 8 seine Betriebstemperatur erreicht hat. Insbesondere handelt es sich bei dieser kurzfristig speicherbaren Abgas-Komponente um Kohlenwasserstoffe. Derartige Adsorber sind bekannt und arbeiten zumeist auf Zeolithbasis. Bekannt ist auch, daß die Speicher­ fähigkeit des Adsorbers 6 nicht nur über der Zeit, sondern auch mit zunehmender Temperatur nachläßt. Hat somit der Adsorber 6, der selbstverständlich durch die heißen Abgase der Brennkraftmaschine 1 aufgewärmt wird, eine gewisse kritische Temperatur von ca. 100°C bis 200°C erreicht, so gibt er die zunächst gespeicher­ te(n) Abgas-Komponente(n) wieder ab. Wünschenswerterweise sollte zu diesem Zeitpunkt der Katalysator 8 bereits seine Betriebstemperatur erreicht haben, so daß er dann - neben den weiterhin kontinuierlich zugeführten Abgas-Komponenten - auch die vom Adsorber 6 zunächst gespeicherten und nunmehr wieder abgegebe­ nen Abgas-Schadstoffe konvertieren kann. Letzteres ist aber nicht immer gewährlei­ stet.In the adsorber 6 , in particular after a cold start of the internal combustion engine 1, at least one component of the internal combustion engine exhaust gas can be stored for a short time, and desirably until the catalytic converter 8 has reached its operating temperature. In particular, this short-term storable exhaust gas component is hydrocarbons. Such adsorbers are known and mostly work on a zeolite basis. It is also known that the storage ability of the adsorber 6 not only decreases over time, but also with increasing temperature. If the adsorber 6 , which is of course warmed up by the hot exhaust gases of the internal combustion engine 1 , has reached a certain critical temperature of approximately 100 ° C. to 200 ° C., it then gives the initially stored exhaust gas component (s). off again. Desirably, the catalytic converter 8 should already have reached its operating temperature at this point in time, so that it can then - in addition to the continuously supplied exhaust gas components - also convert the exhaust gas pollutants initially stored by the adsorber 6 and now released again. However, the latter is not always guaranteed.

Aus diesem Grunde ist eine weitere Maßnahme zur beschleunigten Erwärmung des Katalysators 8 anschließend an einen Kaltstart der Brennkraftmaschine 1 vorgese­ hen. Demzufolge können unverbrannte Kohlenwasserstoffe, die sich auch stromab des Adsorbers 6 noch im Abgasstrom befinden, im Katalysator 8 nachverbrannt werden, und zwar durch Beimengung von Frischluft zum Abgasstrom. Dieser Frischluftstrom wird über eine Frischluftleitung 10 in die Abgasleitung 7 stromab des Adsorbers 6 sowie stromauf des Katalysators 8 eingeleitet. Dabei zweigt diese Frischluftleitung 10 vom Ansaugtrakt 2 der Brennkraftmaschine 1 ab.For this reason, a further measure for accelerated heating of the catalytic converter 8 is hen hen a cold start of the internal combustion engine 1 . As a result, unburned hydrocarbons, which are still in the exhaust gas stream downstream of the adsorber 6 , can be afterburned in the catalytic converter 8 , specifically by adding fresh air to the exhaust gas stream. This fresh air flow is introduced via a fresh air line 10 into the exhaust line 7 downstream of the adsorber 6 and upstream of the catalytic converter 8 . This fresh air line 10 branches off from the intake tract 2 of the internal combustion engine 1 .

Wie ersichtlich ist diese Frischluftleitung 10 derart geführt, daß der darin geführte Frischluftstrom vor der Einleitung in die Abgasleitung 7 mit dem Abgasstrom strom­ auf des Adsorbers 6 in eine wärmetauschende Verbindung gebracht wird. Hierzu ist die Frischluftleitung 10 durch einen die Abgasleitung 5 (stromauf des Adsorbers 6) umgebenden Wärmetauscher 11 geführt. Da der vom Ansaugtrakt 2 abgezweigte Frischluftstrom selbstverständlich erheblich kälter als der Abgasstrom der Brenn­ kraftmaschine 1 ist, wird letztgenannter im Wärmetauscher 11 zumindest geringfü­ gig abgekühlt, d. h. der Frischluftstrom entnimmt dem Abgasstrom einen Teil der darin enthaltenen Wärmemenge und wird hierbei selbst erwärmt.As can be seen, this fresh air line 10 is guided in such a way that the fresh air flow carried therein before the introduction into the exhaust line 7 is brought into a heat-exchanging connection with the exhaust gas flow on the adsorber 6 . For this purpose, the fresh air line 10 is guided through a heat exchanger 11 surrounding the exhaust gas line 5 (upstream of the adsorber 6 ). Since the fresh air flow branched off from the intake tract 2 is of course considerably colder than the exhaust gas flow from the internal combustion engine 1 , the latter is cooled at least slightly in the heat exchanger 11 , ie the fresh air flow takes part of the heat quantity contained in the exhaust gas flow and is itself heated here.

Diese zumindest geringfügige Abkühlung des Abgasstromes stromauf des Adsor­ bers 6 hat nun zur Folge, daß der Adsorber 6 durch den Abgasstrom weniger er­ wärmt wird und er somit die oben genannte kritische Temperatur, bei Erreichen wel­ cher er die zuvor gespeicherten Abgas-Komponente(n) wieder abgibt, ausgehend von einem Kaltstart später erreicht. Dabei geht jedoch vorteilhafterweise die dem Abgasstrom stromauf des Adsorbers 6 durch den Frischgasstrom entnommene Wärme nicht verloren, d. h. diese Wärmemenge steht weiterhin zur erwünschten Erwärmung des Katalysators 8 zur Verfügung, nachdem diese Wärmemenge über den Frischluftstrom dem Abgasstrom stromauf des Katalysators 8 wieder zugeführt wird, und zwar durch die beschriebene Einleitung in die Abgasleitung 7.This at least slight cooling of the flue gas stream upstream of the Adsor bers 6 has for its result that the adsorber 6 is less it is heated by the exhaust gas flow, and it hence the above-mentioned critical temperature, upon reaching wel cher it the previously stored off-gas component (s) releases again, reached later from a cold start. However, the heat removed from the exhaust gas stream upstream of the adsorber 6 by the fresh gas stream is advantageously not lost, ie this amount of heat is still available for the desired heating of the catalytic converter 8 after this amount of heat is fed back to the exhaust gas stream upstream of the catalytic converter 8 via the fresh air stream, and through the described introduction into the exhaust gas line 7 .

Die Frischluftleitung 10 kann zumindest abschnittsweise isoliert ausgeführt sein, um einen unerwünschten Wärmetausch mit der Umgebung (d. h. eine Erwärmung stromauf des Wärmetauschers 11 sowie eine Abkühlung stromab desselben) zu verhindern. Ferner kann in der Frischluftleitung 10 ein Mengensteuerorgan vorgese­ hen sein, welches hier in eine Fördervorrichtung 12 für den Frischluftstrom integriert ist, jedoch kann dies sowie eine Vielzahl weiterer Details insbesondere konstruktiver Art durchaus abweichend vom gezeigten Ausführungsbeispiel gestaltet sein, ohne den Inhalt der Patentansprüche zu verlassen. So kann insbesondere auch der Ad­ sorber 6 selbst zusätzlich mit einer katalytisch wirksamen Beschichtung versehen sein, d. h. nach Erreichen von deren Betriebstemperatur zusätzlich als Katalysator wirken.The fresh air line 10 can be at least partially insulated in order to prevent undesired heat exchange with the surroundings (ie heating upstream of the heat exchanger 11 and cooling downstream thereof). Furthermore, a quantity control element can be provided in the fresh air line 10 , which is integrated here in a conveying device 12 for the fresh air flow, but this and a large number of further details, in particular of a constructive type, can be designed quite differently from the exemplary embodiment shown, without leaving the content of the claims . In particular, the ad sorber 6 itself can also be additionally provided with a catalytically active coating, ie, after its operating temperature has been reached, it can additionally act as a catalyst.

BezugszeichenlisteReference list

11

Brennkraftmaschine
Internal combustion engine

22nd

Ansaugtrakt
Intake tract

33rd

Abgasanlage
Exhaust system

44th

Abgaskrümmer
Exhaust manifold

55

Abgasleitung (zwischen Exhaust pipe (between

44th

und and

66

)
)

66

Adsorber
Adsorber

77

Abgasleitung (zwischen Exhaust pipe (between

66

und and

88th

)
)

88th

Katalysator
catalyst

88th

a elektrisch beheizbarer E-Katalysator
a electrically heated e-catalyst

88th

b Drei-Wege-Hauptkatalysator
b Three-way main catalytic converter

99

Abgasleitung (stromab von Exhaust pipe (downstream of

88th

b)
b)

1010th

Frischluftleitung
Fresh air line

1111

Wärmetauscher
Heat exchanger

1212th

Fördervorrichtung
Conveyor

Claims (2)

1. Abgasanlage einer Brennkraftmaschine (1) mit einem Katalysator (8) zur Konvertierung schädlicher Abgasbestandteile sowie mit einem diesem vorgeschalteten Adsorber (6), in welchem insbesondere nach einem Kaltstart der Brennkraftmaschine (1) zumindest eine Kompo­ nente des Brennkraftmaschinen-Abgases kurzfristig speicherbar ist, dadurch gekennzeichnet, daß dem Brennkraftmaschinen-Abgas stromab des Adsorbers (6) sowie stromauf des Katalysators (8) ein Frischluftstrom beimengbar ist, der zuvor mit dem Abgasstrom strom­ auf des Adsorbers (6) in eine wärmetauschende Verbindung gebracht wird.1. Exhaust system of an internal combustion engine ( 1 ) with a catalyst ( 8 ) for converting harmful exhaust gas components and with an upstream adsorber ( 6 ), in which at least one component of the internal combustion engine exhaust gas can be stored for a short time, particularly after a cold start of the internal combustion engine ( 1 ) , characterized in that the internal combustion engine exhaust gas downstream of the adsorber ( 6 ) and upstream of the catalyst ( 8 ) can be admixed with a fresh air stream which is previously brought into a heat-exchanging connection with the exhaust gas stream on the adsorber ( 6 ). 2. Abgasanlage nach Anspruch 1, gekennzeichnet durch eine vom Ansaugtrakt (2) der Brennkraftma­ schine (1) abzweigende und in der das Brennkraftmaschinen-Abgas führenden Abgasleitung (7) stromab des Adsorbers (6) sowie stromauf des Katalysators (8) mündende Frischluftleitung (10), die durch einen an der das Abgas dem Adsorber (6) zuführenden Abgasleitung (5) vorgesehenen Wärmetauscher (11) geführt ist, und in der ein Men­ gensteuerorgan und/oder eine Fördervorrichtung (12) für den Frisch­ luftstrom vorgesehen ist.2. Exhaust system according to claim 1, characterized by a from the intake tract ( 2 ) of the internal combustion engine ( 1 ) branching and in the exhaust gas line leading to the internal combustion engine exhaust gas ( 7 ) downstream of the adsorber ( 6 ) and upstream of the catalyst ( 8 ) opening fresh air line ( 10 ) which is guided through a heat exchanger ( 11 ) provided on the exhaust gas line ( 5 ) supplying the adsorber ( 6 ), and in which a quantity control element and / or a conveying device ( 12 ) is provided for the fresh air flow.
DE19850373A 1998-11-02 1998-11-02 Exhaust system with adsorber for internal combustion engine, in which fresh air flow can be mixed with exhaust gas downstream of adsorber and upstream of catalytic converter Withdrawn DE19850373A1 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001090541A1 (en) * 2000-05-24 2001-11-29 Johnson Matthey Public Limited Company Method of treating gasoline exhaust gases
EP1336749A3 (en) * 2002-02-14 2006-04-26 Mann + Hummel GmbH Intake system for an internal combustion engine
EP1888886A1 (en) * 2005-05-26 2008-02-20 Volvo Lastvagnar Ab Method for regeneration of an exhaust aftertreatment system
CN103670640A (en) * 2013-12-06 2014-03-26 王才本 Automobile exhaust pipe

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996024756A1 (en) * 1995-02-07 1996-08-15 Engelhard Corporation Method and apparatus for performance enhancement of the manifold catalyst in the automotive exhaust system

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996024756A1 (en) * 1995-02-07 1996-08-15 Engelhard Corporation Method and apparatus for performance enhancement of the manifold catalyst in the automotive exhaust system

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001090541A1 (en) * 2000-05-24 2001-11-29 Johnson Matthey Public Limited Company Method of treating gasoline exhaust gases
EP1336749A3 (en) * 2002-02-14 2006-04-26 Mann + Hummel GmbH Intake system for an internal combustion engine
EP1888886A1 (en) * 2005-05-26 2008-02-20 Volvo Lastvagnar Ab Method for regeneration of an exhaust aftertreatment system
CN103670640A (en) * 2013-12-06 2014-03-26 王才本 Automobile exhaust pipe
CN103670640B (en) * 2013-12-06 2016-02-17 王才本 A kind of automobile exhaust pipe

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