DE19630453A1 - Hair bleach component to be mixed with hydrogen peroxide before use - Google Patents
Hair bleach component to be mixed with hydrogen peroxide before useInfo
- Publication number
- DE19630453A1 DE19630453A1 DE1996130453 DE19630453A DE19630453A1 DE 19630453 A1 DE19630453 A1 DE 19630453A1 DE 1996130453 DE1996130453 DE 1996130453 DE 19630453 A DE19630453 A DE 19630453A DE 19630453 A1 DE19630453 A1 DE 19630453A1
- Authority
- DE
- Germany
- Prior art keywords
- ammonium
- blondiermittel
- hydrogen peroxide
- alkali
- before use
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000007844 bleaching agent Substances 0.000 title abstract description 8
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 10
- 239000003513 alkali Substances 0.000 claims abstract description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 13
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 10
- 235000019270 ammonium chloride Nutrition 0.000 claims description 5
- 238000004061 bleaching Methods 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- -1 alkali metal bicarbonate Chemical class 0.000 claims description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 2
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000003868 ammonium compounds Chemical class 0.000 claims 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims 1
- CUXQLKLUPGTTKL-UHFFFAOYSA-M microcosmic salt Chemical compound [NH4+].[Na+].OP([O-])([O-])=O CUXQLKLUPGTTKL-UHFFFAOYSA-M 0.000 claims 1
- 235000019837 monoammonium phosphate Nutrition 0.000 claims 1
- 125000002081 peroxide group Chemical group 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 8
- 150000002978 peroxides Chemical class 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 230000003113 alkalizing effect Effects 0.000 description 2
- 230000002009 allergenic effect Effects 0.000 description 2
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical compound [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 2
- 235000019289 ammonium phosphates Nutrition 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 2
- 229910021485 fumed silica Inorganic materials 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- JSLISSGEILAIOU-UHFFFAOYSA-N (4-chloro-2-iodophenyl)hydrazine Chemical compound NNC1=CC=C(Cl)C=C1I JSLISSGEILAIOU-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 description 1
- KWIPUXXIFQQMKN-UHFFFAOYSA-N 2-azaniumyl-3-(4-cyanophenyl)propanoate Chemical compound OC(=O)C(N)CC1=CC=C(C#N)C=C1 KWIPUXXIFQQMKN-UHFFFAOYSA-N 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- 239000004251 Ammonium lactate Substances 0.000 description 1
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 229940090948 ammonium benzoate Drugs 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- VZTDIZULWFCMLS-UHFFFAOYSA-N ammonium formate Chemical compound [NH4+].[O-]C=O VZTDIZULWFCMLS-UHFFFAOYSA-N 0.000 description 1
- 229940107816 ammonium iodide Drugs 0.000 description 1
- 229940059265 ammonium lactate Drugs 0.000 description 1
- 235000019286 ammonium lactate Nutrition 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 229940039409 ammonium valerate Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- RZOBLYBZQXQGFY-HSHFZTNMSA-N azanium;(2r)-2-hydroxypropanoate Chemical compound [NH4+].C[C@@H](O)C([O-])=O RZOBLYBZQXQGFY-HSHFZTNMSA-N 0.000 description 1
- NGPGDYLVALNKEG-UHFFFAOYSA-N azanium;azane;2,3,4-trihydroxy-4-oxobutanoate Chemical compound [NH4+].[NH4+].[O-]C(=O)C(O)C(O)C([O-])=O NGPGDYLVALNKEG-UHFFFAOYSA-N 0.000 description 1
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 229960004025 sodium salicylate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
Description
Die vorliegende Erfindung betrifft ein Blondiermittel für menschliche Haare, vorzugsweise in Pulverform, das insbe sondere wesentlich verbesserte physiologische Eigenschaften aufweist.The present invention relates to a bleaching agent for human hair, preferably in powder form, the particular especially significantly improved physiological properties having.
Blondierpulver sind seit langem bekannt und im Einsatz. Sie enthalten in aller Regel eine pulverförmige Grundlage mit verschiedenen Zusätzen, insbesondere Alkalisierungsmitteln, um den pH-Wert bei der Anwendung bei etwa 9,5 bis 10,5 ein zustellen.Blondierpulver have long been known and in use. you usually contain a powdered base with various additives, in particular alkalizing agents, at the pH at the application at about 9.5 to 10.5 deliver.
Als Aktivsubstanz ist ein Peroxid, üblicherweise ein Per sulfat, insbesondere Ammonium-, Natrium- oder Kaliumpersul fat, in Mengen von etwa 30 bis 60 Gew.-% der Gesamtzusammen setzung enthalten. Diese Pulver werden bei der Anwendung mit wäßriger, vorzugsweise 6%iger Wasserstoffperoxid-Lösung ver mischt.As the active substance is a peroxide, usually a per sulfate, in particular ammonium, sodium or potassium persul fat, in amounts of about 30 to 60% by weight of the total included. These powders are used in the application aqueous, preferably 6% hydrogen peroxide solution ver mixed.
Es hat sich jedoch gezeigt, daß die Verwendung von Peroxi den, insbesondere Persulfaten, bei bestimmten Personen zu Allergien führen kann. Es wurde deshalb bereits versucht, persulfatfreie Blondiermittel oder solche mit niedrigem Per sulfat-Anteil zu verwenden und durch Erhöhung der Wasser stoffperoxidmenge die gleiche Konzentration an reagiblem Sauerstoff zur Verfügung zu stellen. Dabei wurde jedoch überraschenderweise festgestellt, daß durch diese Maßnahme eine qualitativ gleichwertige Aufhellung des Haares, wie sie mit persulfathaltigen Produkten in Kombination mit Wasser stoffperoxid erhalten wird, mit persulfatfreien Produkten nicht erzielt werden kann.However, it has been found that the use of Peroxi persons, in particular persulphates Allergies can result. It has therefore already been tried persulfate-free bleaching or low per-bleaching agents to use sulfate content and by increasing the water peroxide level the same concentration of reactiblem To provide oxygen. It was, however, surprisingly found that by this measure a qualitatively equivalent lightening of the hair, as they with persulfate-containing products in combination with water peroxide is obtained with persulfate-free products can not be achieved.
Es bestand daher die Aufgabe, ein Blondierpulver zu schaf fen, das in Kombination mit Wasserstoffperoxid voll wirksam ist, jedoch die mit konventionellen, peroxid-, insbesondere persulfathaltigen Produkten beobachteten physiologischen Probleme nicht aufweist.It was therefore the task to create a blonding powder fully effective in combination with hydrogen peroxide is, however, with conventional, peroxide, in particular persulphate-containing products observed physiological Does not have problems.
Aus der EP-A 609 796 sind bereits entsprechende Blondiermit tel bekannt, die einen niedrigen Anteil an Persulfaten ent halten, wobei die Blondierwirkung durch den Einsatz von 10 bis 60 Gew.-% eines Ammoniumsalzes anstelle der Persulfate erzielt wird.From EP-A 609 796 corresponding Blondiermit are already tel known that a low proportion of persulfates ent keeping the bleaching effect by using 10 to 60% by weight of an ammonium salt instead of the persulfates is achieved.
Als besonders geeignete Ammoniumsalze haben sich dabei Ammo niumcarbonat, Ammoniumhydrogencarbonat und Ammoniumcarbamat erwiesen. Particularly suitable ammonium salts have thereby Ammo ammonium carbonate, ammonium bicarbonate and ammonium carbamate proved.
Es hat sich jedoch gezeigt, daß gerade bei Anwendung dieser blondiertechnisch befriedigenden Substanzen ein störender Ammoniakgeruch auftritt.However, it has been shown that just when using this blonding technically satisfactory substances a disturbing Ammonia odor occurs.
Andererseits ergibt sich bei Anwendung anderer Ammonium salze, die grundsätzlich möglich ist und die keinen stören den Geruch entwickeln, eine gegenüber den obengenannten, be vorzugten Ammoniumsalzen verringerte Blondierwirkung.On the other hand, when using other ammonium salts, which is basically possible and which do not bother anyone develop the smell, one opposite to the above, be preferred ammonium salts reduced Blondierwirkung.
Die vorliegende Erfindung geht daher von der Aufgabe aus, dieses Problem zu lösen und Blondiermittel mit einem gerin gen Peroxidgehalt zur Verfügung zu stellen, die einen den peroxidhaltigen Produkten zumindest äquivalenten Blondier effekt ergeben, jedoch die geschilderten Nachteile nicht aufweisen.The present invention is therefore based on the task to solve this problem and bleach with a clot to provide peroxide, the one peroxide-containing products at least equivalent blondier effect, but not the disadvantages described respectively.
Diese Aufgabe wird erfindungsgemäß durch ein Blondiermittel gelöst, das eine Kombination aus mindestens einem Ammonium salz und mindestens einem Alkalicarbonat und/oder Alkali hydrogencarbonat enthält.This object is achieved by a Blondiermittel solved, which is a combination of at least one ammonium salt and at least one alkali carbonate and / or alkali contains hydrogencarbonate.
Durch die Anwendung dieses Mittels mit einer wäßrigen Was serstoffperoxidzubereitung wird eine ausgezeichnete Blondie rung des Haares ohne hautreizende oder allergisierende Ne benwirkungen erhalten, ohne daß ein unangenehmer Ammoniakge ruch während des Gebrauchs auftritt. By using this agent with an aqueous What Hydrogen peroxide preparation becomes an excellent blondie tion of the hair without irritating or allergenic Ne benwirkungen obtained without an unpleasant Ammoniakge smell occurs during use.
Der Anteil an Ammoniumsalzen in den erfindungsgemäßen Blon diermitteln liegt bei vorzugsweise etwa 10 bis etwa 50, ins besondere etwa 20 bis etwa 40 Gew.-%, der Gesamtzusammenset zung.The proportion of ammonium salts in Blon invention The average is preferably about 10 to about 50, ins especially about 20 to about 40% by weight, of the total composition Zung.
Das molare Verhältnis von Ammoniumsalz zu Alkali(hydrogen) carbonat liegt insbesondere bei etwa 1 : 2 bis 3 : 1; beson ders bevorzugt ist ein annähernd äquimolares Verhältnis.The molar ratio of ammonium salt to alkali (hydrogen) in particular, carbonate is about 1: 2 to 3: 1; special ders preferred is an approximately equimolar ratio.
Die erfindungsgemäßen Blondiermittel sind vorzugsweise so eingestellt, daß sie beim Vermischen mit einer wäßrigen H₂O₂-Zusammensetzung unmittelbar vor dem Aufbringen auf das Haar einen pH-Wert im Bereich von etwa 7,5 bis etwa 11,0, insbesondere zwischen etwa 8 und 9,5 ergeben.The bleaching agents according to the invention are preferably so adjusted to mix with an aqueous H₂O₂ composition immediately before application to the Hair has a pH in the range of about 7.5 to about 11.0, especially between about 8 and 9.5.
Es hat sich nämlich gezeigt, daß bei der Einstellung eines solchen pH-Wertes eine optimale Blondierwirkung erzielt werden kann.It has been shown that in the setting of a achieved such optimum pH Blonding effect can be.
Als Ammoniumsalze können beispielsweise Ammoniumchlorid, Am moniumsulfat, Ammoniumphosphate, Ammoniumnitrat, Ammonium bromid, Ammoniumjodid, Ammoniumthiosulfat, Ammoniummolybdat, Ammoniumvanadat, Ammoniumsulfamat, Ammoniumcitrat, Ammo niumsalicylat, Ammoniumvalerat, Ammoniumtartrat, Ammonium benzoat, Ammoniumacetat, Ammoniumformiat und Ammoniumlactat verwendet werden. As ammonium salts, for example, ammonium chloride, Am ammonium sulfate, ammonium phosphates, ammonium nitrate, ammonium bromide, ammonium iodide, ammonium thiosulfate, ammonium molybdate, Ammonium vanadate, ammonium sulfamate, ammonium citrate, ammo sodium salicylate, ammonium valerate, ammonium tartrate, ammonium benzoate, ammonium acetate, ammonium formate and ammonium lactate be used.
Bevorzugt sind hierbei Ammoniumchlorid, Ammoniumsulfat sowie Ammoniumphosphate wie NH₄H₂PO₄, (NH₄)₂HPO₄, (NH₄)₂NaPO₄, NaNH₄HPO₄ oder NH₄Na₂PO₄ und Diammoniumhydrogencitrat.Preferred here are ammonium chloride, ammonium sulfate and Ammonium phosphates such as NH₄H₂PO₄, (NH₄) ₂HPO₄, (NH₄) ₂NaPO₄, NaNH₄HPO₄ or NH₄Na₂PO₄ and Diammoniumhydrogencitrat.
Ammonium(hydrogen)carbonat und Ammoniumcarbamat sind, wenn überhaupt, in den erfindungsgemäßen Mitteln nur in unterge ordneten Mengen, d. h. < 10 Gew.-%, enthalten.Ammonium (hydrogen) carbonate and ammonium carbamate are when at all, in the inventive compositions only in Unterge ordered quantities, d. H. <10 wt .-%, included.
Die erfindungsgemäßen Blondiermittel sind entweder völlig peroxidfrei oder enthalten Peroxide wie Persulfate nur in untergeordneten Mengen; vorzugsweise weniger als 20 Gew.-%, insbesondere weniger als 15, besonders bevorzugt weniger als 10 Gew.-%, berechnet auf die Gesamtzusammensetzung des Mit tels.The bleaching agents according to the invention are either completely peroxide-free or contain peroxides such as persulfates only in subordinate quantities; preferably less than 20% by weight, in particular less than 15, more preferably less than 10 wt .-%, calculated on the total composition of Mit means of.
Neben den Ammoniumsalzen enthalten die erfindungsgemäßen Blondiermittel mit verringertem allergenen Potential die in solchen Mitteln üblichen Bestandteile, insbesondere, wenn es sich um ein Pulver handelt, inerte pulverförmige Träger stoffe, beispielsweise pyrogenes Siliciumdioxid, Stärkepul ver, etc., Alkalisierungsmittel wie Natriummetasilikat, oberflächenaktive Substanzen, Bindemittel, etc.; zur Vermei dung von Wiederholungen wird auf die einschlägigen Standard werke, beispielsweise K.Schrader, "Grundlagen und Rezepturen der Kosmetika", 2. Aufl. (1989, Hüthig Buchverlag), S. 815 bis 823, verwiesen. In addition to the ammonium salts, the inventive Bleaching agent with reduced allergenic potential in conventional ingredients such, in particular, if it is a powder, inert powdered carrier substances, for example fumed silica, starch powder ver, etc., alkalizing agents such as sodium metasilicate, surfactants, binders, etc .; to avoid repetition will be based on the relevant standard works, for example K. Schrader, "Grundlagen und Rezepturen der Kosmetika ", 2nd ed. (1989, Hüthig Buchverlag), p. 815 to 823, referenced.
Diese Pulver können auch, wie aus der DE-A 42 07 475 be kannt, mit Öl bzw. mit einem flüssigen Wachs beschichtet sein oder, wie es in der DE-A 42 17 120 beschrieben ist, als mit Binde- und Verdickungsmitteln verfestigtes Agglomerat vorliegen.These powders can also, as described in DE-A 42 07 475 be knows, coated with oil or with a liquid wax be or, as described in DE-A 42 17 120, as agglomerated with binders and thickeners available.
Obwohl die bevorzugte Ausführungsform des erfindungsgemäßen Mittels ein wasserfreies Blondierpulver darstellt, ist es auch möglich, andere Trägermaterialien zu verwenden, bei spielsweise wasserfreie Suspensionen oder Pasten, wie sie z. B. in der DE-A 38 14 356 beschrieben sind.Although the preferred embodiment of the invention By means of an anhydrous blonding powder, it is also possible to use other substrates, at For example, anhydrous suspensions or pastes, as they z. B. in DE-A 38 14 356 are described.
Auch der Einsatz wasserhaltiger Emulsionen, Gele etc. ist prinzipiell möglich, obwohl aus Stabilitätsgründen wasser freie Produkte bevorzugt werden.The use of water-containing emulsions, gels, etc. is in principle possible, although for stability reasons water free products are preferred.
Die folgenden Beispiele illustrieren die Erfindung.The following examples illustrate the invention.
Es wird eine Grundrezeptur A für ein Blondierpulver herge stellt, die in den Beispielen A-1 und A-2 sowie B-1 bis B-4 als Grundlage verwendet wird:It will herge a basic recipe A for a Blondierpulver in Examples A-1 and A-2 and B-1 to B-4 used as a basis:
Auf Basis der Grundrezeptur A wurden die folgenden Beispiele hergestellt.On the basis of the basic formula A, the following examples were manufactured.
Jeweils 20 g der Grundrezeptur A und der Zusammensetzungen nach den Beispielen A-1, A-2 und B-1 wurden mit jeweils 40 ml 6prozentiger Wasserstoffperoxid-Lösung vermischt und mit der erhaltenen Mischung (pH 8,5-8,7) Haarsträhnen bei 40°C 30 Minuten blondiert.In each case 20 g of the basic formulation A and the compositions according to Examples A-1, A-2 and B-1 were each with 40 ml of 6 percent hydrogen peroxide solution mixed and with the resulting mixture (pH 8.5-8.7) hair strands at 40 ° C bleached for 30 minutes.
Anschließend wurden die Strähnen gewaschen, getrocknet und der Grad der erzielten Aufhellung verglichen. Die Ergebnisse sind in der folgenden Tabelle wiedergegeben:Subsequently, the strands were washed, dried and compared the degree of lightening achieved. The results are given in the following table:
Die Resultate dieser Versuche zeigen die aufhellende Wirk samkeit der erfindungsgemäßen Zusammensetzungen auch in Ab wesenheit von Persulfat und deren zusätzliche Geruchsfrei heit.The results of these experiments show the lightening effect sity of the compositions according to the invention also in Ab presence of persulphate and their additional odor-free Ness.
Claims (7)
- a) mindestens einem Ammoniumsalz und
- b) mindestens einem Alkalicarbonat und/oder Alkali hydrogencarbonat enthält.
- a) at least one ammonium salt and
- b) at least one alkali carbonate and / or alkali hydrogencarbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1996130453 DE19630453C2 (en) | 1996-07-27 | 1996-07-27 | Blonding agent for human hair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1996130453 DE19630453C2 (en) | 1996-07-27 | 1996-07-27 | Blonding agent for human hair |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE19630453A1 true DE19630453A1 (en) | 1998-01-29 |
| DE19630453C2 DE19630453C2 (en) | 1998-07-02 |
Family
ID=7801099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1996130453 Revoked DE19630453C2 (en) | 1996-07-27 | 1996-07-27 | Blonding agent for human hair |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE19630453C2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002020897A1 (en) * | 2000-09-08 | 2002-03-14 | Tfl Ledertechnik Gmbh | Dyed leather and method for dyeing tanned leather |
| EP2005854B1 (en) * | 2007-06-15 | 2017-04-12 | Noxell Corporation | A system for highlighting hair |
| WO2022269195A1 (en) * | 2021-06-23 | 2022-12-29 | Scea Du Chateau Montrose | Composition comprising potassium bicarbonate and use thereof for treating and/or protecting crops |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0609796A2 (en) * | 1993-02-01 | 1994-08-10 | GOLDWELL GmbH | Hairbleaching composition |
-
1996
- 1996-07-27 DE DE1996130453 patent/DE19630453C2/en not_active Revoked
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0609796A2 (en) * | 1993-02-01 | 1994-08-10 | GOLDWELL GmbH | Hairbleaching composition |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002020897A1 (en) * | 2000-09-08 | 2002-03-14 | Tfl Ledertechnik Gmbh | Dyed leather and method for dyeing tanned leather |
| AU2001284036B9 (en) * | 2000-09-08 | 2002-03-22 | Tfl Ledertechnik Gmbh | Dyed leather and method for dyeing tanned leather |
| US6916348B2 (en) | 2000-09-08 | 2005-07-12 | Tfl Ledertechnik Gmbh | Dyed leather and method for dyeing tanned leather |
| AU2001284036B2 (en) * | 2000-09-08 | 2006-12-07 | Tfl Ledertechnik Gmbh | Dyed leather and method for dyeing tanned leather |
| AU2001284036B8 (en) * | 2000-09-08 | 2007-02-15 | Tfl Ledertechnik Gmbh | Dyed leather and method for dyeing tanned leather |
| EP2005854B1 (en) * | 2007-06-15 | 2017-04-12 | Noxell Corporation | A system for highlighting hair |
| WO2022269195A1 (en) * | 2021-06-23 | 2022-12-29 | Scea Du Chateau Montrose | Composition comprising potassium bicarbonate and use thereof for treating and/or protecting crops |
| FR3124356A1 (en) * | 2021-06-23 | 2022-12-30 | Scea Du Chateau Montrose | Composition comprising potassium bicarbonate and use for treating and/or protecting crops. |
Also Published As
| Publication number | Publication date |
|---|---|
| DE19630453C2 (en) | 1998-07-02 |
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