DE1931302A1 - Steel alloys - Google Patents

Steel alloys

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Publication number
DE1931302A1
DE1931302A1 DE19691931302 DE1931302A DE1931302A1 DE 1931302 A1 DE1931302 A1 DE 1931302A1 DE 19691931302 DE19691931302 DE 19691931302 DE 1931302 A DE1931302 A DE 1931302A DE 1931302 A1 DE1931302 A1 DE 1931302A1
Authority
DE
Germany
Prior art keywords
iron
niobium
vanadium
cobalt
boron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19691931302
Other languages
German (de)
Inventor
Arthur Hogg
Kirkby Henry William
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Firth Brown Ltd
Original Assignee
Firth Brown Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firth Brown Ltd filed Critical Firth Brown Ltd
Publication of DE1931302A1 publication Critical patent/DE1931302A1/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)
  • Soft Magnetic Materials (AREA)

Description

DR. BERG DIPL.-ING. STAPF 1QQIDR. BERG DIPL.-ING. STAPF 1QQI

PATENTANWÄLTE ' ^ V JPATENT Attorneys' ^ V J

8 MÜNCHEN 2. HILBLESTRAS8E 2O8 MUNICH 2. HILBLESTRAS8E 2O

20, Juni20th June

Anwalt3-Akte 18 584Attorney3 file 18 584

Firth Brown Limited, Sheffield, Yorkshire/ EnglandFirth Brown Limited, Sheffield, Yorkshire / England

"Stahllegierungen11 "Steel alloys 11

Diese Erfindung "betrifft Stahllegierungen für Verweildung "bei hohen Temperaturen und im besonderen Stahllegierungen, welche zur Herstellung von Kompressoren und Turbi*. nenläufer in Gasturbinen und für ähnliche Zwecke geeignet sind.This invention "relates to steel alloys for dwell "at high temperatures and in particular steel alloys, which are used in the manufacture of compressors and Turbi *. nenläufer in gas turbines and suitable for similar purposes are.

Die erfindungsgemäßen Stahllegierungen haben die nachfolgenden Zusammensetzungen in Gewichtsprozentsätzen: The steel alloys according to the invention have the following compositions in percentages by weight:

009835/1159009835/1159

. Kohlenstoff Silicium . Carbon silicon

' Mangan Chrom Wickel Molybdän Vanadium Niobium Kobalt Kupfer Bor
Stickstoff
'' Manganese Chromium Winding Molybdenum Vanadium Niobium Cobalt Copper Boron
nitrogen

0,02 - 0,25 0,05 - 1,5 0,1 - 1,5 7,0 - 12,0 0,2 - 4-,O 0,2 - 5,0 0,10 - 0,60 0,05 - 0,70 bis zu 7,0 bis zu 5,0 0,002 - 0,050.02 - 0.25 0.05 - 1.5 0.1 - 1.5 7.0 - 12.0 0.2 - 4-, O 0.2 - 5.0 0.10 - 0.60 0.05 - 0.70 up to 7.0 up to 5.0 0.002-0.05

wenigstens 0,010, aber weniger als 0,050at least 0.010 but less than 0.050

wobei der Rest Eisen und nebensächliche Verunreinigungen sind.the remainder being iron and incidental impurities.

In den Fällen, bei denen hohe Kriechfestigkeit kombiniert mit hoher Streckgrenze, hoker Zugfestigkeit mit und ohne Kerbe gewünscht wird, werden Legierungen in den folgenden Bereichen ±n Gew.'/o bevorzugt.In cases where high creep resistance combined with high yield strength, tensile strength and hok it is desired without notch, alloys within the following ranges ± n are wt. '/ O preferred.

Kohlenstoff Silicium Mangan Öhrom NickelCarbon silicon manganese ohrom nickel

0,05 - 0,10 0,10 - 0,8Q 0,50 - 1VQ 9,0 - 11,0 0,2 - 1,00.05 to 0.10 0.10 - 0,8Q 0.50 to 1 V Q 9.0 to 11.0 0.2 to 1.0

009835/1159009835/1159

-3--3-

Molybdän 1,5-3,0Molybdenum 1.5-3.0

Vanadium 0,2-0,5Vanadium 0.2-0.5

Niobium 0,3-0,6Niobium 0.3-0.6

Kobalt 3,0 - 5,0Cobalt 3.0-5.0

Kupfer , , 1,0 - 3,0 Bor 0,005 - 0,,020Copper, 1.0-3.0 boron 0.005-0.020

Stickstoff wenigstens 0,010,Nitrogen at least 0.010,

aber weniger alsbut less than

0,0500.050

wobei der Rest Eisen und nebensächliche Verunreinigungen sind.the remainder being iron and incidental impurities.

Typische Beispiele einer solchen Zubereitung sind:Typical examples of such a preparation are:

Beisp. 1Example 1 Beisp. 2Example 2 Beisp. 3Example 3 Beisp.4Example 4 Beisp. 5Example 5 00 0,050.05 0,070.07 0,060.06 0,070.07 0,040.04 SiSi 0,450.45 0,500.50 0,450.45 0,400.40 0,200.20 MnMn 0,800.80 Q,ßOQ, ßO 0,850.85 0,900.90 0,750.75 GrSize 10,510.5 9,09.0 10,710.7 10,510.5 10,110.1 NiNi 0,50.5 0,40.4 0,40.4 0,50.5 0,30.3 MoMon 1,51.5 1,51.5 1,61.6 1,61.6 1,51.5 VV 0,220.22 0,200.20 0,210.21 0,210.21 0,220.22 NbNb 0,450.45 0,600.60 0,460.46 0,460.46 0,480.48 CoCo 4,04.0 4,04.0 4,24.2 4,24.2 4,24.2 GuGu 2,02.0 1,351.35 " 1,8"1.8 2,92.9 2,02.0 BB. 0,0100.010 0,0100.010 0,0100.010 0,0120.012 0,0090.009 N2 - N 2 - 0,0250.025 0,0200.020 0,0250.025 0,0120.012 0,0310.031

Eisen und nebensächliche Verunreinigungen: RestIron and minor impurities: remainder

009835/1159009835/1159

Es wurden die nachfolgenden Ergebnisse bei Standardunter suohungen mit Stahllegierungen der angegebenen Zusammensetzung erhalten:The following results were obtained from standard sub Solutions with steel alloys of the specified composition are obtained:

.-5-009835/1159.-5-009835 / 1159

inin

to •r to • r

P co •H ω pnP co • H ω pn

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IHIH

0 09835/ ff S90 09835 / ff S9

BADBATH

■ _■ _

In den Fällen, wo höhere" Streckgrenze und Zugfestigkeit zusammen mit einer besseren.Schlagfestigkeit'"und Ker"b-Schlagzähigkeit gefordert werden, werden Zubereitungen mit den nachfolgenden .Bereichen der Gewichtsproaentsätze bevorzugt ; ·'' '. "In those cases where higher 'yield strength and tensile strength together with better impact strength and Ker "b impact strength are required, preparations with the following ranges of percentages by weight are preferred ; · '' '. "

t . ■t. ■

Kohlenstoff" · - - 0,10 - 0,20Carbon "· - - 0.10-0.20

Silicium 0,10 - 0,80Silicon 0.10-0.80

Mangan 0,50 - 1,0Manganese 0.50 - 1.0

Chrom 9,0 - 11,0Chromium 9.0-11.0

Nickel 1,5 - 3,5Nickel 1.5-3.5

Molybdän 1,5-3,0Molybdenum 1.5-3.0

Vanadium 0,20 - 0,50Vanadium 0.20-0.50

Niobium 0,10 - 0,40Niobium 0.10-0.40

Kobalt 2,0 - 3,5·Cobalt 2.0 - 3.5

Kupfer . bis zu 2,0Copper. up to 2.0

Bor 0,005 - 0,020Boron 0.005-0.020

Stickstoff wenigstens 0,010, aberNitrogen at least 0.010, but

■ · weniger als 0,050■ · less than 0.050

wobei der Rest Eisen und nebensächliche Verunreinigungen sind.the remainder being iron and minor impurities are.

Typische Beispiele dieser aweiten bevorzugten Zubereiü sind:Typical examples of this other preferred preparation are:

,Beisp.7 Beisp.»8 Beisp«9 , For sp .7 example "8 example" 9

O ;O; OO »15»15 OO ,16., 16. OO ,11, 11 OO ,16, 16 OO ,10, 10 BlBl OO ,35, 35 OO ,18, 18 OO • 51• 51 OO ,49, 49 ■ο■ ο ,32, 32

009835/1159009835/1159

BAD ORIGINALBATH ORIGINAL

Beisp.6Example 6 Beisp·7Example 7 BBisp.8BBisp. 8 Beisp.9Example 9 Beisp.10Example 10 MnMn 0,700.70 0,650.65 0,:72 0: 72 0,660.66 0,870.87 CrCr 10,010.0 9,69.6 11,011.0 10,110.1 10,110.1 NiNi 2,52.5 2,42.4 2,32.3 2,32.3 2,42.4 MoMon 2,52.5 2,82.8 2,02.0 3,03.0 3,0 -3.0 - V.V. 0,350.35 0,350.35 0,310.31 0,370.37 0,380.38 NbNb o, 25o, 25 0,150.15 0,110.11 0,200.20 0,230.23 CoCo 3,03.0 ■?t9■? T9 2,92.9 3,P3, P 3,13.1 CuCu 0,250.25 0,400.40 0,300.30 0,250.25 0,250.25 BB. 0,0100.010 0,0090.009 0,0060.006 0,0050.005 0,0060.006 NoNo 0,0200.020 0,0160.016 0,p250, p25 0,0280.028 Q, 024Q, 024

Eisen und nebensächliche Verunreinigungen: RestIron and minor impurities: remainder

-8-00 9 835/1159-8-00 9 835/1159

(1) Zu 5ur.~: e rs nc !gun,? en(1) To 5ur. ~: E rs nc! Gun ,? en

(s.) Zlmertenreratur 0,1^ Streckgrenze tons/s.in. (t/cm2)(s.) Zlmertenratur 0.1 ^ yield strength tons / s.in. (t / cm2)

Zugfestigkeit ·Tensile strenght ·

tons/sq.in.tons / sq.in.

(t/cn2) _ Dehnung in fj Querschnittverininderung "1T m Cf(t / cn2) _ elongation in fj reduction in cross-section " 1 T m Cf

i'i . X . D tons/sq.in.i'i. X D tons / sq.in.

(0)(0)

ο ο CO OO ω cn ο ο CO OO ω cn

coco

i 500 0C O9 V/i Streckgrenze i 500 0 C O 9 V / i yield point

tons/sq.. in. (t/cm2)tons / sq .. in. (t / cm2)

Zugfestigkeit tons/sσ.in. (t/2)-Tensile strength tons / sσ.in. (t / 2) -

■Deimung in fi Querschnittverninderung■ Dimming in fi cross-section reduction

■fr m* q ■ ·■ for m * q ■ ·

tons/s α. in-. (/27 tons / s α. in-. (/ 27

S eis T). 6S ice T). 6th Beisn.7Beisn. 7 Beis-o.SBeis-o.S. 3eisp.93eisp.9 72
(11,3)
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(11.3)
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(11,45)(11.45)
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(10,0)
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(10.0)
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(10,9),(10.9),
'98'98
(15S35)(15 S 35)
■ 95
(14,9)
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(14,1)(14.1)
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(15,0)(15.0)
2020th
2121 2020th 1818th 1919th 6060 6161 59'59 ' ,. 59,. 59 6060 164
(25,9)
164
(25.9)
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(24,5)
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(24.5)
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136
(21,2) -
136
(21.2) -
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• (25)• (25)
51
(S,00)
51
(S, 00)
5050
(7,S5)(7, S5)
. 49 ■
• (7,77)
. 49 ■
• (7.77)
4343
(6,57)(6.57)
74
(11,62)
74
(11.62)
70
(11,0)
70
(11.0)
70
(11,0) "
70
(11.0) "
62
(9,73)
62
(9.73)
7373
(11,45) .(11.45).
1919th
1919th 1515th 1616 . .17. .17 * 64* 64 5353 5353 65,65, 6666 .«- ■. «- ■ 118
(18,5) "
118
(18.5) "
' 117'117
(18,35)(18.35)
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009035/1159009035/1159

Claims (3)

Patentansprüche:Patent claims: 1. Stahllegierung, die im wesentlichen aus den nachfolgenden Elementen in den angegebenen Gewichtsprozentsätzen1. Steel alloy consisting essentially of the following Elements in the specified weight percentages besteht:consists: Kohlenstoff 0,02 - 0,25Carbon 0.02-0.25 Silicium. Q,05 - 1,5Silicon. Q.05 - 1.5 Mangan 0,,1 -1,5Manganese 0.1-1.5 Ohrom 7,0 - 12,0Ohrom 7.0 - 12.0 Nickel 0,2 - 4,0Nickel 0.2-4.0 Molybdän 0,2 -5,0Molybdenum 0.2 -5.0 Vanadium 0,10-0,60Vanadium 0.10-0.60 Niobium 0,P5 - 0,70Niobium 0, P5 - 0.70 Kobalt bis zu 7,0Cobalt up to 7.0 Kupfer bis zu 5,PCopper up to 5, p Bor 0,002 bis 0,03Boron 0.002 to 0.03 Stickstoff wenigstens 0,010, aberNitrogen at least 0.010, but weniger als 0,050less than 0.050 Eisen und nebensächliche Verunreinigungen: der Rest.Iron and minor impurities: the rest. 2. Legierung gemäß Anspruch 1, wobei sie im wesentlichen aus den nachfolgenden Elementen in den angegebenen Gewichtsprozentsätzen besteht:2. Alloy according to claim 1, wherein it consists essentially of consists of the following elements in the specified weight percentages: Kohlenstoff, 0,05-0,10Carbon, 0.05-0.10 Silicium Ο,,ΙΟ - 0,80Silicon Ο ,, ΙΟ - 0.80 Mangan 0,50 - 1,0Manganese 0.50 - 1.0 Ohrom 9,0 - 11,αOhrom 9.0-11, α 009835/1159009835/1159 Nickel 0,2 - 1,0Nickel 0.2-1.0 Molybdän 1,5 - 3,0Molybdenum 1.5-3.0 Vanadium 0,2.-0,5Vanadium 0.2-0.5 - Niobium . 0,3 - 0,6- niobium. 0.3-0.6 Kobalt 3,G- 5,0Cobalt 3, G-5.0 Kupfer 1,Q-3,PCopper 1, Q-3, P Bor - 0,005 - 0,020Boron - 0.005-0.020 Stickstoff wenigstens 0,010, aberNitrogen at least 0.010, but weniger als 0,050less than 0.050 Eisen und nebensächliche Verunreinigungen: der RestIron and minor impurities: the rest 3. Legierung gemäß Anspruch 1, wobei sie im wesentlichen aus den nachfolgenden Elementen in den angegebenen Gewichtsprozentsätzen besteht:3. Alloy according to claim 1, wherein it consists essentially of the following elements in the specified weight percentages consists: Kohlenstoff 0,10 - 0,20Carbon 0.10-0.20 Silicium 0,10 - 0,80Silicon 0.10-0.80 Mangan 0,50 - 1,0Manganese 0.50 - 1.0 Chrom 9,0 - 11,0Chromium 9.0-11.0 Nickel 1,5 - 3,5Nickel 1.5-3.5 Molybdän' 1,5 - 3,0Molybdenum 1.5-3.0 Vanadium 0,20 - 0,50Vanadium 0.20-0.50 Niobium 0,10 - 0,40 Kobalt - 2,0-3,5 Kupfer · bis zu 2,0Niobium 0.10 - 0.40 cobalt - 2.0-3.5 copper up to 2.0 Bor . 0,005 - 0,020Boron. 0.005-0.020 Stickstoff wenigstens 0,ß10, aberNitrogen at least 0, ß10, but weniger als 0,Q50less than 0, Q50 Eisen und nebensächliche Verunreinigungen: der RestIron and minor impurities: the rest 009835/1159009835/1159
DE19691931302 1968-06-20 1969-06-20 Steel alloys Pending DE1931302A1 (en)

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Application Number Priority Date Filing Date Title
GB2947368 1968-06-20

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US (1) US3663208A (en)
DE (1) DE1931302A1 (en)
FR (1) FR2011320A1 (en)
GB (1) GB1250898A (en)
SE (1) SE349332B (en)

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US4058417A (en) * 1975-02-24 1977-11-15 General Electric Company Turbine bucket alloy
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US5424028A (en) * 1993-12-23 1995-06-13 Latrobe Steel Company Case carburized stainless steel alloy for high temperature applications
JP3480061B2 (en) * 1994-09-20 2003-12-15 住友金属工業株式会社 High Cr ferritic heat resistant steel
US6737018B2 (en) * 2001-01-16 2004-05-18 Jfe Steel Corporation Corrosion-resistant chromium steel for architectural and civil engineering structural elements
PL2912200T3 (en) * 2012-10-24 2019-10-31 Crs Holdings Inc Quench and temper corrosion resistant steel alloy
US11634803B2 (en) 2012-10-24 2023-04-25 Crs Holdings, Llc Quench and temper corrosion resistant steel alloy and method for producing the alloy
US10094007B2 (en) 2013-10-24 2018-10-09 Crs Holdings Inc. Method of manufacturing a ferrous alloy article using powder metallurgy processing
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US2793113A (en) * 1952-08-22 1957-05-21 Hadfields Ltd Creep resistant steel
US2880085A (en) * 1956-03-29 1959-03-31 Firth Vickers Stainless Steels Ltd Ferritic alloy steels for use at elevated temperatures
US3152934A (en) * 1962-10-03 1964-10-13 Allegheny Ludlum Steel Process for treating austenite stainless steels

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GB1250898A (en) 1971-10-20
US3663208A (en) 1972-05-16
SE349332B (en) 1972-09-25
FR2011320A1 (en) 1970-02-27

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