DE1668256A1 - Metal carbonyl derivatives - Google Patents

Metal carbonyl derivatives

Info

Publication number
DE1668256A1
DE1668256A1 DE19671668256 DE1668256A DE1668256A1 DE 1668256 A1 DE1668256 A1 DE 1668256A1 DE 19671668256 DE19671668256 DE 19671668256 DE 1668256 A DE1668256 A DE 1668256A DE 1668256 A1 DE1668256 A1 DE 1668256A1
Authority
DE
Germany
Prior art keywords
metal carbonyl
transition metal
derivative
substituted
carbonyl derivatives
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19671668256
Other languages
German (de)
Inventor
Thompson David Thomas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB34740/65A external-priority patent/GB1129554A/en
Priority claimed from GB999167A external-priority patent/GB1156336A/en
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Publication of DE1668256A1 publication Critical patent/DE1668256A1/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0013—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0086—Platinum compounds
    • C07F15/0093—Platinum compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)

Claims (2)

Imperial Chemical Industries Limited PATENTANSPRÜCHE :Imperial Chemical Industries Limited PATENT CLAIMS: 1. übergangsmetallcarbony!derivat, dadurch gekennzeichnet,1. Transition metal carbony derivative, characterized in that dass im Molekül mindestens ein Ligand der Formelthat in the molecule at least one ligand of the formula - h - h vorliegt, worin E Phosphor, Arsen oder Antimon bedeutet, R ein Kohlenwasserstoff- oder substituiertes Kohlenwasserstoffradikal, vorzugsweise ein Phenylradikal, ist und X ein Wasserstoffatom oder Halogenatom, vorzugsweise ein Chloratom, bedeutet.is present, where E is phosphorus, arsenic or antimony, R is a hydrocarbon or substituted hydrocarbon radical, preferably a phenyl radical, and X is a hydrogen atom or halogen atom, preferably a chlorine atom. 2. Verfahren zur Herstellung eines übergangsmetallcarbonylderivats, dadurch gekennzeichnet, dass man ein substituiertes oder unsubstituiertes mono- oder polynukleares übergangsmetallcarbonyl in einem Lösungsmittel mit einem Phosphin, Arsin oder Stibin der allgemeinen Formel2. Process for the preparation of a transition metal carbonyl derivative, characterized in that a substituted or unsubstituted mono- or polynuclear transition metal carbonyl in a solvent with a phosphine, arsine or stibine of the general formula E R2 XER 2 X in Berührung bringt, worin die Symbole die in Anspruch 1 angegebenen Bedeutungen besitzen.brings into contact, wherein the symbols are those given in claim 1 Have meanings. NN'//*.! M NN '// *.! M. BMNCMtHrK1 ,.,·. . iNG.H.IQHt «rUNO 5IBMNCMtHrK 1 ,., ·. . iNG.H.IQHt «rUNO 5I 109831/2176109831/2176
DE19671668256 1965-08-13 1967-08-02 Metal carbonyl derivatives Pending DE1668256A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB34740/65A GB1129554A (en) 1965-08-13 1965-08-13 Dinuclear bridged transition metal complexes
GB999167A GB1156336A (en) 1966-08-02 1966-08-02 Transition Metal Carbonyl Derivatives
GB642967 1967-02-10
GB873667 1967-02-23

Publications (1)

Publication Number Publication Date
DE1668256A1 true DE1668256A1 (en) 1971-07-29

Family

ID=27447519

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19671668256 Pending DE1668256A1 (en) 1965-08-13 1967-08-02 Metal carbonyl derivatives

Country Status (2)

Country Link
DE (1) DE1668256A1 (en)
FR (1) FR1557658A (en)

Also Published As

Publication number Publication date
FR1557658A (en) 1969-02-21

Similar Documents

Publication Publication Date Title
Stephenson et al. New complexes of ruthenium (II) and (III) with triphenylphosphine, triphenylarsine, trichlorostannate, pyridine and other ligands
Parshall et al. Fluoroolefin Complexes of Transition Metals
Walker et al. 4-methyl-pyridine adducts of copper (II) β-diketone chelates
Recknagel et al. Synthese von metallacyclophosphazenen mit praseodym, neodym, uran und thorium
DE1668256A1 (en) Metal carbonyl derivatives
DE2952585A1 (en) ELECTROLUMINESCENCE DISPLAY DEVICE
DE2455614C2 (en) Stabilization of halogen-containing polymers
Berka et al. Transition metal complexes of 1, 10-phenanthroline and 2, 2'-bipyridine
Pinnavaia et al. Crystal and molecular structure of tetrakis (2, 2, 6, 6-tetramethyl-3, 5-heptanedionato) niobium (IV). Square antiprismatic M (bidentate) 4 stereoisomer
Powell et al. Triallylrhodium (III) and a crotyl–butadiene complex of rhodium
DE1768739A1 (en) Cycloaliphatic alkyl hydroxyphenyl alkanoates
Armit et al. Ruthenium complexes containing group 5b donor ligands: Part VII. Rearrangement reactions of some ruthenium (II) complexes containing triphenylphosphine, tri-p-tolylphosphine or ethyldiphenylphosphine ligands.
Critchlow et al. A review of platinum metal nitrato complexes
Contreras et al. The Crystal and Molecular Structure of Dichloro (acetylacetonato)-2, 2′-bipyridylindium (III)
DE2431796A1 (en) PROCESS FOR THE PREPARATION OF N, N, N ', N'-TETRAARYLQUINONE DIIMONIUM SALT
DE1594349A1 (en) Lubricant mixture
Malatesta Palladium (0) compounds. Part I. Diisonitrilopalladium (0) compounds
Shih et al. Square planar platinum (II) complexes: synthesis, IR spectroscopy, and hydration equilibria of PtIIL (CN) 2 (L= 4, 4'-di-tert-butyl-2, 2'-bipyridine)
US4188234A (en) Chelation
DE2739096A1 (en) PROCESS FOR MANUFACTURING ISOBUTTER ACID ESTERS
Burseyd et al. Electron-impact ionization potentials of successively substituted acetylacetonates of rhodium (III)
EP0355296A3 (en) Tungsten-halophosphine complexes suitable for cvd, and process for their production
GB1502014A (en) Cyclo-olefin polymerization catalysts and their use
ES347852A1 (en) Process for manufacturing new polymerization catalysts,the resulting new catalysts and their uses
DE1243489B (en) Bath and process for the galvanic deposition of shiny silver coatings