DE1594817B2 - PROCESS FOR WASHING OUT WATER-SOLUBLE SUBSTANCES FROM WOVEN, KNITTED, FLEECE, YARN OR FEDERATION FROM NATURAL AND SYNTHETIC FIBERS OR TEXTILE BLENDINGS - Google Patents
PROCESS FOR WASHING OUT WATER-SOLUBLE SUBSTANCES FROM WOVEN, KNITTED, FLEECE, YARN OR FEDERATION FROM NATURAL AND SYNTHETIC FIBERS OR TEXTILE BLENDINGSInfo
- Publication number
- DE1594817B2 DE1594817B2 DE1966A0054069 DEA0054069A DE1594817B2 DE 1594817 B2 DE1594817 B2 DE 1594817B2 DE 1966A0054069 DE1966A0054069 DE 1966A0054069 DE A0054069 A DEA0054069 A DE A0054069A DE 1594817 B2 DE1594817 B2 DE 1594817B2
- Authority
- DE
- Germany
- Prior art keywords
- water
- washing
- textile
- additional
- woven
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 7
- 239000000126 substance Substances 0.000 title claims description 4
- 229920002994 synthetic fiber Polymers 0.000 title claims description 4
- 239000012209 synthetic fiber Substances 0.000 title claims description 3
- 230000008569 process Effects 0.000 title claims 3
- 239000004758 synthetic textile Substances 0.000 title 1
- 238000005406 washing Methods 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000004753 textile Substances 0.000 claims description 11
- 239000013505 freshwater Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 239000004745 nonwoven fabric Substances 0.000 claims description 2
- 239000002351 wastewater Substances 0.000 claims description 2
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims 1
- 238000002791 soaking Methods 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 14
- 238000011282 treatment Methods 0.000 description 9
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 235000011121 sodium hydroxide Nutrition 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- -1 especially alkalis Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/20—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics with means to improve the circulation of the treating material on the surface of the fabric
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0004—General aspects of dyeing
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatment Of Fiber Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Die Erfindung betrifft ein Verfahren zum kontinuierlichen oder semi-kontinuierlichen Auswaschen wasserlöslicher Substanzen, insbesondere Alkalien, Säuren und anderer Elektrolyte, aus Geweben, Gewirken, Vliesen, Garnen oder Fäden aus natürlichen und synthetischen Fasern oder deren textlien Mischungen.The invention relates to a method for continuous or semi-continuous washing out of water-soluble substances, especially alkalis, acids and other electrolytes, from woven, knitted, nonwovens, yarns or threads made from natural and synthetic Fibers or their textile mixtures.
Bei der Lösungswäsche, bei welcher ein zur Erzielung einer besonderen Wirkung auf die Ware aufgebrachtes Behandlungsmittel nach der erfolgten Behandlung wieder aus der Ware entfernt werden soll, wurde bisher immer so vorgegangen, daß die Warenbahn nacheinander durch verschiedene Behandlungsabteile geführt und dort mit Wasser zusammengebracht wurde, durch das die Konzentration des in der Ware noch vorhandenen Behandlungsmittels immer weiter herabgesetzt wurde mit dem Ziel, das Behandlungsmittel möglichst restlos aus der Ware auszuwaschen. Es ist einzusehen, daß es immer schwieriger wird, die Konzentration des Behandlungsmittels noch weiter herabzusetzen, je geringer die Konzentrationsdifferenz zwischen Ware und Waschwasser schon geworden istIn the case of solution washing, in which one is applied to the goods to achieve a special effect Treatment agent to be removed again from the goods after the treatment has been carried out so far always proceeded in such a way that the web of material passed through and through different treatment compartments one after the other There it was brought together with water, through which the concentration of what is still present in the goods Treatment agent was always further reduced with the aim of keeping the treatment agent as completely as possible to wash out of the goods. It can be seen that it is becoming more and more difficult to concentrate the Reduce treatment agent even further, the lower the concentration difference between goods and wash water has already become
Untersuchungen haben nun ergeben, daß auch bei lang andauerndem Waschen selbst mit enthärtetem Frischwasser immer ein Laugen- oder Säurerest im Textilgut verbleibt. Diese Reste sind nun aber, wie sich gezeigt hat, die Ursache vielfältiger Störungen bei nachfolgenden Veredlungsbehandlungen, wie empfindlichen Färbungen oder hochwertigen Endveredlungen.Studies have now shown that even with long-term washing even with softened With fresh water, a lye or acid residue always remains in the textile. These remnants are, however, like themselves has shown the cause of various disorders in subsequent finishing treatments, such as sensitive Dyeings or high-quality finishes.
Aufgabe der vorliegenden Erfindung ist es, ein Verfahren zu schaffen, bei dem Behandlungsmittel wie Säuren oder Laugen so vollständig aus. der WareThe object of the present invention is to provide a method in which treatment agents such as Acids or alkalis so completely. the goods
ίο ausgewaschen werden, daß sie die nachfolgenden Behandlungen nicht mehr stören können,ίο be washed out that they are the following Treatments can no longer interfere,
Zur Lösung dieser Aufgabe wird erfindungsgemäß ein Verfahren zum kontinuierlichen oder semi-kontinuierlichen Auswaschen wasserlöslicher Substanzen aus Geweben, Gewirken, Vliesen, Garnen oder Fäden vorgeschlagen, bei dem unmittelbar im Anschluß an ein Auswaschen in an sich bekannter Art mit normalem Frischwasser restliche im Textilgut verbliebene Spuren von Laugen oder Säuren in einer zusätzlichen Endwaschstufe dadurch aus dem Textilgut entfernt werden, daß die am Ende des normalen Waschprozesses stark abgequetschte Textilbahn mit destilliertem oder in einem Ionenaustauscher entsalztem Wasser voll durchtränkt, in diesem gespült und nach einer Einwirkungszeit von mindestens 6 bis 8 see noch einmal stark abgequetscht wird. Zur Einsparung von Wasser bei dem gesamten Waschprozeß kann vorteilhaft das Abquetschwasser aus der abschließenden Abquetschung und das Abwasser aus dem zusätzlichen Spülen dem vorausgehenden normalen Waschprozeß als zusätzliches Frischwasser zugeführt werden. Es ist zweckmäßig, in der zusätzlichen Endwaschstufe Kondensat zu verwenden, das innerhalb oder außerhalb der Waschanlage bei der Beheizung des Waschwassers der Hauptwaschstufe anfällt.To achieve this object, the invention provides a continuous or semi-continuous process Washing out of water-soluble substances from woven, knitted, non-woven, yarn or thread proposed in which immediately following a washout in a manner known per se with normal Fresh water remaining traces of alkalis or acids in the textile in an additional Final washing step can be removed from the textile material at the end of the normal washing process heavily squeezed textile web soaked in distilled water or water desalinated in an ion exchanger, rinsed in this and again strong after an exposure time of at least 6 to 8 seconds is squeezed. In order to save water during the entire washing process, the squeezing water can advantageously be used from the final squeezing and the wastewater from the additional rinsing previous normal washing process are supplied as additional fresh water. It is appropriate to use condensate in the additional final washing stage, inside or outside the washing system when heating the washing water of the main washing stage.
Die normalerweise mit mittlerer Temperatur in die zusätzliche Waschstufe eintretende Textilbahn kann vor oder in Verbindung mit dem Tränken mit destilliertem oder entsalztem Wasser einer Kondensationsaufheizung von 1000C unterworfen werden und während der gewünschten Einwirkzeit des Zusatzwaschprozesses im Wasserdampfmedium gehalten werden.The textile web normally occurring at medium temperature in the additional washing step may be subjected to a condensation heating of 100 0 C before or in connection to the impregnation with distilled or deionized water and held in the steam medium during the desired exposure time of the additional washing process.
An Hand der Zeichnung soll ein Waschprozeß gemäß der vorliegenden Erfindung näher erläutert werden.A washing process according to the present invention will be explained in more detail with reference to the drawing.
Die vier ersten Abteile einer Gegenstrom-Waschmaschine mit sechs Kästen 1 bis 6, durch die die Warenbahn 7 in der durch Pfeile angedeuteten Richtung hindurch geführt wird, sind miteinander verbunden. Sie erhalten den benötigten Frischwasserzusatz A amThe four first compartments of a countercurrent washing machine with six bins 1 to 6, through which the web of material 7 is guided in the direction indicated by arrows, are connected to one another. You will receive the required fresh water additive A am
4. Abteil. Das Wasser wird dann nach Durchlaufen der Abteile 3, 2, 1 bei B in die Abflußleitung 8 abgelassen. Die Abteile 5 und 6 arbeiten ebenfalls im Gegenstrom, jedoch wird das Wasser nicht hinter dem Abteil 5 in die Abflußleitung 8 abgelassen, sondern über Austauschfilter 10, 11 durch eine Pumpe 12 zurückgefördert. Der Durchsatz kann beispielsweise 2 bis 2,5 m3/h betragen, wobei das Austauschharz, etwa ein stark saurer Kationenaustauscher, die Natriumionen bindet. Das entalkalisierte Wasser wird dann wieder in das Abteil 6 zurückgeführt.4th compartment. The water is then drained into the drain line 8 after passing through the compartments 3, 2, 1 at B. The compartments 5 and 6 also work in countercurrent, but the water is not drained into the drain line 8 behind the compartment 5, but is conveyed back through a pump 12 via exchange filters 10, 11. The throughput can be, for example, 2 to 2.5 m 3 / h, the exchange resin, for example a strongly acidic cation exchanger, binding the sodium ions. The dealkalized water is then returned to the compartment 6.
Bei Inbetriebnahme werden die beiden Abteile 5 und 6 mit Kondenswasser gefüllt und während einer Arbeitszeit von mehreren Stunden das gesamte Volumen über die Austauschfilter umgewälzt. Wenn die Filter erschöpft sind, erfolgt eine Regeneration mit Salzsäure. Gegebenenfalls kann, um den kontinuierlichen Betrieb nicht zu stören, auf ein Wechselfilter 10,11, wie in der Figur dargestellt ist, umgeschaltet werden.When commissioning the two compartments 5 and 6 are filled with condensation and during a Working time of several hours, the entire volume circulated through the replacement filter. If the If the filters are exhausted, regeneration with hydrochloric acid takes place. Possibly can to the continuous Operation not to be disturbed, on an easy-change filter 10,11, as shown in the figure.
3 43 4
Die Funktion des lonenaustausches verläuft dabei etwa wie folgt:The function of the ion exchange is roughly as follows:
H NaH Well
Austauscherharz + NaOH = Austauscherharz + 2H2OExchange resin + NaOH = exchange resin + 2H 2 O
H NaH Well
Regeneration des Filters:Regeneration of the filter:
Na HClose
Austauscherharz + 2HCl = Austauscherharz + 2NaClExchange resin + 2HCl = exchange resin + 2NaCl
Na HClose
Alkaligehaltes gehen in den Kreislauf über, d. h. 1,8 g/kg B e l s P l e' Gewebe, beispielsweise 0,36 g/lfm (5 m = 1 kg). DieThe alkali content goes into the cycle, ie 1.8 g / kg B els P l e 'fabric, for example 0.36 g / running meter (5 m = 1 kg). the
Waschgeschwindigkeit beträgt 80 m/min.Washing speed is 80 m / min.
1 Liter eines handelsüblichen stark sauren Kationen- Somit beträgt der Anfall an Ätznatron pro Stunde in1 liter of a commercially available strongly acidic cation - thus the amount of caustic soda per hour is in
austauschers auf der Basis von vernetzten Polystyrol 20 den Abteilen 5 + 6 = 1,73 kg und in 4 Stunden 6,9 kg. (Korngröße 0,3-1,2 mm, Schüttgewicht 800-900 g/l Als Filterfüllung werden für diese Arbeitsweiseexchanger based on crosslinked polystyrene 20 compartments 5 + 6 = 1.73 kg and 6.9 kg in 4 hours. (Grain size 0.3-1.2 mm, bulk density 800-900 g / l
und Totalkapazität feuchtes Harz 2,2 Vol/1) binden ca. 80—100 Liter Basenaustauscher oder beispielsweise 80 g NaOH 100%ig. Aus dem 4. Waschabteil werden 2 χ 75 Liter bei Wechselbetrieb benötigt, bei einem pro kg Gewebe beispielsweise 2 g NaOH 100%ig in den Flottendurchsatz durch das Austauschfilter von Kreislauf der Spülabteile eingeschleppt. 90% dieses 25 2 — 2,5 m3 pro Stunde.and total capacity wet resin 2.2 vol / 1) bind approx. 80-100 liters of base exchanger or, for example, 80 g of 100% NaOH. From the 4th washing compartment, 2 χ 75 liters are required for alternating operation, with one per kg of fabric, for example, 2 g of 100% NaOH is dragged into the liquor throughput through the exchange filter of the circuit of the washing compartments. 90% of this 25 2 - 2.5 m 3 per hour.
Hierzu 1 Blatt Zeichnungen1 sheet of drawings
Claims (4)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1572567D CH1572567D (en) | 1966-11-12 | ||
| DE1966A0054069 DE1594817B2 (en) | 1966-11-12 | 1966-11-12 | PROCESS FOR WASHING OUT WATER-SOLUBLE SUBSTANCES FROM WOVEN, KNITTED, FLEECE, YARN OR FEDERATION FROM NATURAL AND SYNTHETIC FIBERS OR TEXTILE BLENDINGS |
| FR126927A FR1542273A (en) | 1966-11-12 | 1967-11-03 | Method for washing without electrolyte |
| ES346926A ES346926A1 (en) | 1966-11-12 | 1967-11-08 | A Process for Washing Acids, Lyes and Water-Soluble Treating Media out of Textile Webs |
| GB50820/67A GB1174837A (en) | 1966-11-12 | 1967-11-08 | A Process for Washing Acids, Lyes and Water-Soluble Treating Media out of Textile Webs |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1966A0054069 DE1594817B2 (en) | 1966-11-12 | 1966-11-12 | PROCESS FOR WASHING OUT WATER-SOLUBLE SUBSTANCES FROM WOVEN, KNITTED, FLEECE, YARN OR FEDERATION FROM NATURAL AND SYNTHETIC FIBERS OR TEXTILE BLENDINGS |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE1594817A1 DE1594817A1 (en) | 1970-07-09 |
| DE1594817B2 true DE1594817B2 (en) | 1976-10-21 |
Family
ID=6939288
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1966A0054069 Granted DE1594817B2 (en) | 1966-11-12 | 1966-11-12 | PROCESS FOR WASHING OUT WATER-SOLUBLE SUBSTANCES FROM WOVEN, KNITTED, FLEECE, YARN OR FEDERATION FROM NATURAL AND SYNTHETIC FIBERS OR TEXTILE BLENDINGS |
Country Status (5)
| Country | Link |
|---|---|
| CH (1) | CH1572567D (en) |
| DE (1) | DE1594817B2 (en) |
| ES (1) | ES346926A1 (en) |
| FR (1) | FR1542273A (en) |
| GB (1) | GB1174837A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3739346A1 (en) * | 1987-11-20 | 1989-06-01 | Babcock Textilmasch | METHOD AND DEVICE FOR WATER-SAVING WASHING OF RUNNING PRODUCTS |
| CN103643555A (en) * | 2013-11-27 | 2014-03-19 | 常熟市赵市圣丹龙制衣厂 | Production process of copper ammonia wool blended fabric |
-
0
- CH CH1572567D patent/CH1572567D/xx unknown
-
1966
- 1966-11-12 DE DE1966A0054069 patent/DE1594817B2/en active Granted
-
1967
- 1967-11-03 FR FR126927A patent/FR1542273A/en not_active Expired
- 1967-11-08 GB GB50820/67A patent/GB1174837A/en not_active Expired
- 1967-11-08 ES ES346926A patent/ES346926A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ES346926A1 (en) | 1969-02-01 |
| DE1594817A1 (en) | 1970-07-09 |
| GB1174837A (en) | 1969-12-17 |
| FR1542273A (en) | 1968-10-11 |
| CH1572567D (en) |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| EHJ | Ceased/non-payment of the annual fee |