DE1520789A1 - Process for the production of epoxy resin preparations - Google Patents

Description

concerning
A process for Herateilung of Epo ^ e n resin composition.

The present invention is concerned with the manufacture of epoxy resin formulations which are suitable for many Applications are suitable, especially as a floor covering or as coating preparations

In the patent application S 70 877 a hardenable Preparation described, which consists of a polyepoxide with an epoxide equivalent of more than 1.0 and a kohlenwaseeretoff-substituted Phenol and optionally also consists of a bituminous product. According to this Registration, curing takes place in such a way that a curing agent is added to the preparation after it has been produced it has now been found that spoxy resin preparations with better coating and surface properties

9 0 9 8 3 1 / U 8 4

Shafts can be produced if a preparation (A) from a polyepoxide with an epoxide equivalent of more than 1.0 and aua a phenol or a hydrocarbon-substituted phenol with a preparation (B) from a curing agent, daa a comprises or more reactive / MH or -MBLg groups or serstoff-substituted phenol is mixed anhydride as a curing agent and a phenol or a hydrocar- w, wherein the weight amount of polyepoxide is in the overall mixture (a + B) at least 25%. According to a possible modification of the method according to the invention, both preparation (A) and preparation (B) or both can contain an extender oil. Both preparation (A) and preparation (B) or both can contain a smaller amount of a non-reactive diluent.

It has been found that by mixing the various components in the manner just described and not by mixing all the components present with one another at the beginning, the quantities required for the production of the preparations can be determined much better. The same applies to the viscosity properties of these preparations and generally to the properties (quality) of the products to be manufactured.

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The polyepoxide component of the preparations according to the invention is an organic polymer with more than one JBpoxy group. Bass Elbe can be a saturated or unsaturated, an aliphatic, cycloaliphatic, aromatic or heterocyclic polymer. Furthermore, it can, for example, be chlorine, hydroxyl and ether substitution groups exhibit.

Even if any polyepoxides with a Jäpoxyd equivalent of more than 1.0 in the tubs according to the invention can be used, but those with a Spoxyd equivalent between 140 and 525 »are for example «Between 170 and 290, preferred. In addition, polyepoxides old an average molecular weight of less than 1200, for example with one from 280 to 9G0 preferred. They also have a

Functionality tob. At least 1 and roraugawelß® you I ₁ J to £ _t 0-on «that means« in eeichee ΤΓ $ 3> »never keeps its molecular weight to itee © Spoxyd equivalent. Suitable polyepoxides are those made from an epihalohydrin, for example from chlorohydrin and from a

from ^ 2,2 ~ bis (4-hydroxyph.e3iyl) -propem / 0Ä «r mim . ■■ ..-; "■. ■"

Sin preferred Bölyepöatyd let a »olcüiöSt: d» ü dtucch

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Reaction of an epihalohydrin, such as spichlorohydrin, with diphenylolpropane (Biephenol A) with a Spoxyd-EquiTalent between 175 and 210, an average molecular weight between 350 and M-OO and a Hydroxy-Equiralent of about 1250 was produced is one which has been produced by the action of an epihalohydrin with glycerine and has an epoxy equivalent between 140 and 160 and an average molecular weight between 290 and 340, for example wise ron 300 Αϊ.

The polyepoxide component can also be a glycidyl ether

it it

a Horolac Haraes, i.e. a resin obtained by condensing an aldehyde with a polyphenol. An example of this is a polyepoxy resin made from formaldehyde and 2,2-bis (4-hydroxyphenyl) propane novolac resin was obtained.

Other suitable polyepoxides Bind esters of polyols and epoxy-substituted monocarboxylic acids, epoxidized TrigVceride beispielsweiee as ej> oxydierte8 soybean oil, sardine oil and Bauawollsaaenöl \ Seter from epoxy-substituted alcohols and polycarboxylic acids, for example Dlglycidyladipat and diglycidyl succinate; iister from epoxy-substituted alcohols and epoxy-substituted monocarboxylic acids, for example 3,4-apoxy-6-ethyl-cyclohexylmethyr; and

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3 ^ -Jäpoxy-e-methyl-cyclohexanecarboxylate *

Further suitable polyepoxides are polyepoxy alkyl esters of dimers or trimers of long-chain / unsaturated aliphatic acids and mixtures thereof. The dimeric and / or trimeric acids forming the acid part of the polyepoxy esters can be derived from naturally occurring jet acids, for example from LinoMure, linolenic acid, λ

Jaleos tearic acid, resin acids and kicinoleic acid. A very suitable one Polyepoxide is obtained when a salt is dimerized Linoleic acid, for example the sodium salt, is reacted with a Jäpihalohydrin. This amounts to Jäpoxyd equivalent of the end product between 400 and 420. These polyepoxy esters give the cured products a high degree of flexibility other epoxy resins used, for example with the diglycidyl ether of 2,2-bis- (4-hydroxyphenyl) propane, so give the hardened products good flexibility did without thereby demanding the tensile strength or other physical properties thereof are significantly reduced.

If monohydroxybenzene can also be used as phenol in the preparations according to the invention, so will for this purpose, hydrocarbon-substituted phenols are preferred. This can be a mono- or polyphenol

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yours, the at least one hydrocarbon-substituted lüonsgruppe which is preferably an alkyl group. Examples of such compounds are cresols; Dinonylphenol; Dioctylphenol; Didodecylphenol; Ditetzadecylphenol; Dioctadecylphenol; Trinonylphenol; Nonylpnenol; Octylpnenol; Heptylphenol; Dodecylphenol; Diheptylphenol; Pentadecylphenol; Heptyldodecylphenol; Heptylditetradecylphenol; Jüicosanylphenol; Dinonylresorcinol; Dioctylresorcinol; 2,2-bis- (4-hydroxy-3-nonylphenol )propane; 2,2-bis (4-hydroxy-51 i? -Aioctylphenyl) propane; Bis (hydroxynonylphenyl) methane; 2,2-bis (4-hydroxy-2-decylphenyl) butane; Dioctenylphenol and tritetradecylphenol.

Preferred hydrocarbon-substituted phenols are those that have at least 7 carbon atoms in the or contain in at least one side chain, in particular the mono- and alkyl-substituted monophenols and diphenols, in which the alkyl side chain has 7 to 24 carbon atoms having. The most preferred phenols are the mono- and di-alkylated phenols having 9 to 18 carbon atoms in the alkyl group such as dinonylphenol, didodecylphenol, dodecylphenol and octadecylphenol.

The one or more reactive ^ -NH or -NIL, groups hardening agents containing a primary or secondary amine, an aliphatic, cycloaliphatic or

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aromatic polyamine or a polyamide resin. It can also be an amine adduct, for example a stable addit solder connection made of a monoepoxide or a polyepoxide and an amine *

Suitable hardeners are aliphatic and allcyclic Polyamines such as ethylenediamine, diethylenetriamine, triethylenetetraamine, propylenediamine, 2,4-diamino-2-methylpentane, dimethylamino and diethylamino propy leucine, aminoethylethanolamine, N (hydroxyethyl) diethylenetriamine, -imethyldiaminodlcyclohexyl-amine and Cyclohexy! Propylenediamine.

A preferred series of compounds with reactive / KH groups, also used as hardeners Are the substituted or unsubstituted piperazines that have an amino-substituted alkyl group on one of the Bing H atoms and the following formula (| haveι

i H

X-H <'^ .HH

^V HH

t I

C- -G

IT ^x H,

In which B is hydrogen or an alkyl or alkoxy reed

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and X is an amino-substituted alkyl radical. Examples of these compounds are N-aminobutylpiperazine, N-aminoisopropyl-3-butoxy-piperazine, N-amino-isopropyl-piperazine, 2,5-dibutyl-N-aminoethylpiperazine and 2,5-dioctyl-N-aminobutylpiperazine. The preferred compound is N-aminoethylpiperazine.

^ Polyamides can also be used as hardeners

will. These include, in particular, condensation products made from an aliphatic polyamine such as ethylene diamine or Diethylenetriamine and a Dimeien or Trimexen one Unsaturated fatty acid obtained from a drying oil, for example from linseed oil. The preferred polyamides have at least 3 bound to the amino nitrogen Hydrogen atoms in the molecule. Such condensation products are known under the trade name "polyamide resins". Examples of such products are the well-known "Versamid" 115,125 or 140 as well as Thiokol EM-308, Genamid 150 and Genaaid 310.

Other compounds which are also suitable as hardening agents are diketimines, i.e. condensation products of aliphatic ketones and polyamine compounds or the Imidazolines, especially amino- and aminoalkyl-substituted imidazolines such as Synolide 960.

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Other curing agents are aromatic polyamines, for example ortho-, meta- and para-phenylenediamine, Diaminodiphenylmethane, 2,4-diamino-toluene, 1,3-diamino-4-isopropyl-benzene and Ν, Ν'-diphenylethylenediamine. The aromatic In addition to the amino groups, polyamines preferably contain no other reactive groups with the epoxy groups Groups.

The anhydride hardeners can be aliphatic or ^ be cyclic, but also aromatic or alicyclic. Examples of preferred alicyclic curing agents are Hexahydrophthalic anhydride, methyl-endo-methylene-tetrahydrophthalic anhydride and tetrahydrophthalic anhydride. Examples of suitable aromatic anhydrides are Phthalic anhydride and pyromellitic anhydride. An example of a suitable aliphatic anhydride is succinic anhydride .

Wähx ^ end of their use as curing agents need the aromatic compounds having a reactive ^ NH- or -NHP group as well as the anhydrides of the supply of heat, thus, for example, a processing temperature of 60-200 ⁰ C during a processing period of 12-1 hours. They are well suited for various electrical applications, such as castings and encapsulation material. However, the preferred hardening agents are the aliphatic

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and alicyclic compounds with reactive ^S , NH or -NHo groups, since they are able to exert their hardening effect at ordinary temperature. They can therefore also be used when heat cannot be supplied due to the particular type of use.

According to a preferred way of carrying out the process according to the invention, preparation (B) or else both preparations (A) and (B) use an oil as an extender can be added. This extender oil is an oil with

a high boiling point of more than 250 G and with a ίο low viscosity of less than 2,300 SSU at 50 C. The same is usually, though not necessarily, a petroleum-derived hydrocarbon such as a transformer oil, a lubricating oil, a fuel oil or ' an aromatic extract obtained by solvent extraction from smear oil distillates.

The transformer oil has a high naphthenic content Distillate, so that it is resistant to oxidation and free from impurities, due to which a low electrical Strength or poor dielectric properties will. The percentage of aromatic components in the transformer oil is of great importance for the performance of such an oil during its use. It was found that the acid boilers

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sludge value and the neutralization number of a transformer oil after its oxidation according to the information from "Appendix B of British Standard 148; 1951" as well as the inhibitor susceptibility, which is determined according to the same test, strongly depend on the concentration of the aromatic oil components. For example, the acid precipitation value with increasing concentration of the aromatic constituents will first be clearly, by running at a concentration of about 8 wt .-% to% aromatic constituents, a maximum and then decreases again quickly to at a concentration of about 14 wt .-% of aromatic constituents to go through a clearly pronounced minimum. The acid value obtained after oxidation also decreases rapidly with an increase in the concentration of aromatic constituents, but remains conspicuously constant at a concentration of more than 11% by weight of aromatic constituents. The iuiilin point (aniline point), which is a measure of the content of aromatic constituents, is approximately 60 ° C. for a typical transformer oil.

The lubricating oils that can be used are not always mineral lubricating oils, but can also aliphatic diesters, phosphate esters, aliphatic esters of pentaerythritol, silicate esters, siloxanes and polyoxyalkylene ethers and -ester be.

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Examples of suitable mineral lubricating oils are those having a viscosity in the range of about 50 SSU at 50 ^° G (122 ^P F) to about 2000 SSU at 50 ^° C (122 ^° F). The viscosity index of the oil can vary from less than 0 to more than 100. The oil can have an average molecular weight in the range of about 250 to 800. If desired, it can be a highly refined and solvent treated "oil" in a known manner. The hydrocarbon oil can be a synthetic or a mineral oil, although mineral oils are preferred.

The lubricating oils can also consist solely of mineral lubricating oils. You can too replace with or mix with other hydrophobic lubricating oils, including tricresyl phosphate, irioctyl phosphate, Tributyl phosphate, diesters such as bis (2-ethylhexyl) sebacate, Dinonyl adipate; Fentaerythritol esters such as mixed Ο «- C ^ -alkyl pentaerythritol esters, tetrahexyl pentaerythritol esters; Silicic acid esters such as tetraoctyl silicate; Polyoxyalkylene compounds such as copolymers of ethylene oxide and propylene oxide in which the terminal groups are either are esterified or etherified; Silicone oils such as dimethyl silicone, methylphenyl silicone or chlorinated methylphenyl silicone.

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The aniline temperature of a typical lubricating oil is between 60 and 65 ° C and is approximately 63 ° 0, for example.

Suitable fuels include petroleum hydrocarbon oils, for example fuel fractions »produced by cracking or reforming petroleum hydrocarbons or Mixtures of various hydrocarbon oils, such as mixtures of cracked distillates and immediate distillates ™ can be obtained. Other suitable fuel oils are those petroleum hydrocarbon oils which are suitable for spark-ignited Internal combustion propulsion turbines, for internal combustion engines, internal combustion turbine engines and suitable for heating or alternators.

The aniline temperature of a typical fuel oil is between 5 and 15 ° C and is for example about 10 ⁰ C.. (

The lubricating oil distillates from which the aromatic extracts are obtained by solvent extraction have preferably a viscosity between 150 and 300 SSÜ at 50 ° C. Usable solvents include Sulfur dioxide, iädeleanu solvent and furfural · Unrefined lubricating oil can be separated into two phases, namely into a paraffin raffinate and an aromatic one

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Extract. The solvent is recovered from both phases by distillation. The refined aromatic extract is a complex mixture of aromatic and naphthene hydrocarbons. Br has a low aniline temperature. The extracted using an aromatic solvent extract preferably has an aromatic content of at least 50 wt .-% and in particular from 60 to 65 wt .-%, and preferably a viscosity zwisehen 100 and 2,300 Hsu on at 50 ⁰ C.

The preferred solvent extracted aromatic extract has at 15.5 ⁰ C (60 ⁰ P), a specific gravity of about 0.99, a viscosity at 21 ° C (70 ⁰ F) of about 256 SSU, an aniline point of about -13 ° C, a pour point of about -37 ° C (-35 ° F), a refractive index at 50 ⁰ C of about 1.55 and a "Pensky Martin - ( ⁰ F) (open cup)" flash point of about 330 ( 165.5 ⁰ C).

According to a further implementation of the invention Both preparation Δ and preparation B or preferably both preparations can be used can be diluted by adding a neutral diluent or a plasticizer. Examples of such Diluents are aromatic hydrocarbons, for example alkylbenzenes such as toluene, the xylenes and ethylbenzenes as well as alkyl naphthalenes. Also halogen-substituted Hydrocarbons in which the halogen is preferably present

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~ ¹⁵ ~ 152Q789

attached to the aromatic nucleus, such as chlorobenzene, can be used. Preferred diluents are high-boiling hydrocarbon solvents rich in aromatic constituents, especially those with an aromatic content of at least 80% by volume. They are mixtures of aromatic hydrocarbons and usually have a fairly wide range, for example from 250 to 275 ° C, 180-215 ⁰ C, 160-275 ° C, of 160 to 180 ⁰ C and 155-195 ° C. Conversely, purfuryl alcohol, tetrahydrofurfuryl alcohol or gamma-butyrolactone can also be used.

Suitable plasticizers including pine oil and dibutyl phthalate can also be used. The lesser one Part of the neutral diluent or plasticizer can be added instead of the extender oil. Preferably however, the extender oil is mixed in as an additive.

The new preparations according to the invention contain a compatible mixture of a curing agent with one or more reactive ^> HH or N ^ groups or of an anhydride curing agent, a phenol or a hydrocarbon-substituted phenol and a Transformer oil, a lubricating oil, or one like the one before

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solvent-extracted aromatic extract mentioned above. Compatible mixture is to be understood as one in which the components are at normal temperature be mixed with one another to form a homogeneous liquid and without the presence of a phase separation can. Preparations consisting solely of a polyamine and a! transformer oil apply (but not as compatible. A small amount of a neutral diluent or a Plasticizer may be included.

According to the invention, the amount of polyepoxide is im Total mixture (A + B) preferably not more than 75% by weight, for example 50 to 60% by weight · Bas reactive): NH or curing agents containing NI ^ groups or that Anhydride hardening agent is preferably included in preparation (B) in an amount of 0.5 to 1.5 parts of the stoichi) ometriech for the reaction with the JSpoxydgruppen in the Preparation (A) the amount of polyepoxide present,

The amount of the neutral diluent is preferably not more than 20 and, for example, less than 15 wt .- # of the polyepoxide · The amount of the plasticizer is preferably not more than 50 wt .- # of the polyepoxide, for example about 5 to 30% by weight of the polyepoxide. Bas • Diluents or the plasticizer are preferred

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approximately evenly on the two preparations (A) laid (B) distributed.

Both in preparation (a) and in (B) or in both preparations, the extender oil or the phenol or the hydrocarbon-substituted phenol makes up the remainder of the preparation. In ealle where both an extender oil etc. exist as a phenol or a hydrocarbon-substituted phenol in the preparation, the relative amounts of the extender oil, and the phenol or hydrocarbon-substituted phenol greatly from the aniline point of the extender * tJles from »The lower the aniline point, the higher the aromatic content of the extender oil. * A smaller amount of phenol or hydrocarbon-substituted phenol is then required accordingly. Conversely, the higher the aniline point, the lower the aromatic content of the extender oil. In a corresponding manner, a larger amount of phenol or of hydrocarbon-substituted phenol is then required.

The preparations produced according to the invention are suitable for many types of use. So they can have a use as a surface coating with a strong adhesive strength on a base made of cement, asphalt and on metal surfaces find that is accompanied by a good resistance to wear and tear and chemical attack

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will «The coatings are of particular importance as they Manufactured at low cost and easy to cover large areas can be used without the aid of solvents.

If small-dimensioned, neutral particles are added to the preparations before or during their hardening If aggregate or pigments are added, the cured coatings also have excellent slip resistance on. The covers are particularly suitable for use in laying floors and building roads and railways, because they can be easily applied to large areas and quickly without the presence of special ones Curing conditions become solid.

The preparations according to the invention can also be used as binders for stone plastering, as coating compounds for already produced concrete and metal surfaces, and as binding agents for units used in the construction of new roads and pavement or as coating compounds for ship ceilings. In the case of their use for binding stone throws, the preparations are combined with a relatively large amount of hard, abrasion-resistant and neutral particles, which are preferably in a finely divided state and have a sieve size of approximately M- 500. To preferred used in this context

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Building materials include sand, crushed rock, ground Quartz, alumina, silicon carbide and sheep gel. Preferred The materials to be used are minerals and, in particular, substances containing silicon such as sand and crushed rock. Mixtures of different types of particles can also be used.

If preparations are used as aggregate binders in the construction of new roads, the above-mentioned Preparations mixed with different types of aggregates, for example with crushed rock, the larger dimensions than the debris possesses. These fabrics preferably have an H pocket size of approximately 0 to 50.

The amount of neutral particles or aggregates, which is preferably used, at least 50 wt .-%, the above mentioned preparations, and most preferably 75 to 1,000 wt. ~% Of these preparations. If the preparations are used together with units in road construction, they are preferably applied in layers with a thickness of approximately 1.0 to 10 cm.

In the production of stone layers and road surface preparations the! particles and the aggregate can or even at any point during manufacture after the preparation of the polyepoxide-containing preparations

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added »-Ss is also possible, preferably im In the case of stone pavement layers, the preparations according to the invention to apply in the form of a coating and then to spray the neutral particles on the surface of the coating layer and then to roll them to make compact.

If the preparations according to the invention are used as a coating mass, they can be applied as such to any « Surface can be applied. In this context, they are mainly suitable as coating preparations for cement, asphalt, asbestos, wood and steel. The cement surface can be of the common and well-known type, How do you know about hydraulic cements such as Port-Xand-Zeaent and other types of aluminous cement. The asphalt surfaces can be those from direct Asphalt fractions or from further refined or modified oils. Be asphalt. The preparations can be in the form of a »very thin coating or a very thick one Coating come to apply. You kind of applying the Preparations on the surface to be coated can be a be known and suitable; Is the material thick or if it contains a large number of neutral cords, so can this "materials on bed *" "with a grooming brush, a trowel, a shovel or "in" a broom. Is the same more liquid, it can be painted or sprayed on

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will. The applied layer usually has a thickness ▼ on about 1.5 to 12 am.

The preparations according to the invention are suitable for many and different types of use. They can be used, for example, in roofing, in pottery, as castings and as sink encapsulation material, sealing material and impregnation preparations, furthermore as coatings for drilling and drilling pipes protruding into the army floor, as coatings for external weather influences exposed wood and metal lausrustungen, as cable connection material and for stretchable joints, such as those in concrete and when rolling products, such as for the production of glass foils, etc. are used. The polyepoxide used in the following examples as "Polyepoxide A" was prepared by the reaction of an epihalohydrin with diphenylolpropane which had an epoxide equivalent of 175 to 210, an average molecular weight of 550 to and a hydroxide equivalent of approximately 1,250.

A high-boiling, strongly aromatic hydrocarbon solvent with an aromatic content of at least 80% by volume and a boiling point in the range of 205 to 275 ° C is used.

The "aromatic extract" used was solvent extracted aromatic extract with a special

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see gravity of about 0.99 at 15.5 ° C (60 ⁰ F), a viscosity of about 256 SSU at 21.1 ° C (7O ⁰ F), an aniline temperature of about -12 ⁰ C, a pour point of about -34.5 ° C (-30 ⁰ F), a refractive index of about 1.55 at 50 ⁰ C and a flash point by "Penksy Martin (open cup) of about 330 ⁰ F" of about 165.5 ° C.

example 1

By mixing 50 parts by weight of polyepoxide A with 15 parts by weight of dodecylphenol and 3 parts by weight of one Preparation (A) was prepared using a neutral thinner.

By mixing 10 parts by weight of N-aminoethylpiperazine with 30 parts by weight of an aromatic extract, 25 parts by weight of dodecylphenol and 3 parts by weight of a neutral diluent, the preparation (B) was obtained.

By mixing preparations (A) and (B) with one another in a weight ratio of 1.1, a Obtainable preparation which can be hardened at ordinary temperature.

Example 2

Preparation (A) was made by mixing 50 parts by weight of polyepoxide A with 15 parts by weight of dodecylphenol

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manufactured"

Preparation (B) was obtained by mixing 10 parts by weight of N-Aainoäthylpiperazin, 25 parts by weight of aroma « deep extract, 25 parts by weight of dodecylphenol and 5 parts by weight obtained from a neutral solvent.

By mixing preparations (A) and (B) with one another in a weight ratio of 1: 1 was one at ™ Ordinary temperature curable preparation obtained.

Example 5

Preparations (A) and (B) from Example 1 were mixed with a mineral filler to form a preparation which was applied with a trowel and cured after 7 days at a temperature of 2J ° C to form a hard, tough, chemically resistant preparation could. (

Example 4-

Preparations (A) and (B) from Example 2 were mixed with a mineral filler to form a preparation which was applied with a trowel and a hard, tough, chemically resistant preparation over the course of 7 days at a temperature of 25 ° C could be cured.

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Example 5

The preparation (A) was' by mixing 50 parts by weight of Bolyepoxide A with 5 parts by weight of dodecylphenol manufactured and pigmented with titanium dioxide.

The preparation (B) was by mixing 10 parts by weight. »Parts of N-Aminoäthylpiperaaln with 35 parts by weight of a aromatic extracts and 10 parts by weight of dodecylphenol.

The preparations (A + B) were mixed with one another in a weight ratio of 1s1. The resulting Geaisch could be applied with the help of a brush and im Course «of 7 days at a temperature of 23 ° C to be hardened to a hard, tough and chemically resistant coating ·

Patents claims

31/14

Claims (1)

Godparents ta η »ρ r ü ο h · 1. A process for the production of an epoxy resin preparation, which means that it pays off, ie a * preparation (A) made from a polyepoxide with an epoxy equivalent of more than 1.0 and phenol or a hydrocarbon-substituted phenol with a preparation (B) consisting of a hardener, a compound with a | or more reactive HH or K ^ groups or an anhydride and a phenol or a hydrocarbon-substituted phenol can react, the ole weight of the polyepoxide being at least 25 $> 4 ^er 8 · - total mass (A + B). 2 * Process for the preparation of an epoxy resin, characterized in that a preparation (A) is made from a polyoxide with an epoxy equivalent of more than 1.0 and from a phenol or hydrocarbon-substituted phenol with the preparation (B) from a hardener a compound with one or more »reactive IH or NH ₂ groups or an anhydride made from a phenol or a hydrocarbon-substituted phenol and an extender oil can react with one another, the total amount of the polyepoxide being at least (A + B) 25 1 ° betrL-gt. 909831 / —2— SU 3 Process for the production of an epoxy resin preparation, characterized in that a preparation (A) from a polyepoxide with an epoxy equivalent of more than 1.0, a phenol or a hydrocarbon-substituted phenol and a sprinkling agent oil is mixed with a preparation (B ) from a hardener of a compound with one or more VH or MH ₂ groups or an anhydride from a phenol or a carbon-hydrogen-substituted phenol and an extender oil lets react with each other, the weight of the polyepoxide being at least 25 ί> of the total mass (A + B). 4. Process according to Claims 1 to 3, characterized in that a polyepoxide with an average molecular weight between 280 and 900 is used. 5. The method according to claim 1 to 4, characterized f that a glycidyl polyether of a polyphenol is used as the polyepoxide. 6. The method according to claim 5, thereby gekennzeidi net that one is a glycidyl polyether of diphenylol propane used. -3 908831/1484 IA-25 119 7. The method according to claim 1 to 6, characterized in that that the polyepoxide is the reaction product of a salt of dimerized linoleic acid with a Epihalohydrin used, which has an epoxy equivalent has between 400 and 420 8. The method according to claim 1 to 4 »characterized in that als.Polyepoxyd the reaction product from an epihalohydrin and glycerine used, which has an epoxy equivalent between 140 and 160 and an average molecular weight between 290 and 340 has « 9 · Process according to claims 1 to 8, characterized in that a hydrocarbon-subetted Phenol uses at least 7 carbon atoms in at least has a side chain 10. Method according to Claim 9t, characterized in that g e k β η η -> draws that as a hydrocarbon-substituted * Phenol is a mono- or dialhyl-substituted mono- or Bi henol is used, with the Älky! Group being 7 to 24 carbon has atoms. 11. The method according to claim 8, characterized in that one or dinonylphenol Dodeoylphenol r- rwendet · ~ 4 ~ 909831 / U84 BATH ORIGINAL 1A-25 119 12. The method according to claim 1 to 11, characterized in that a polyamine is used as the hardener. 13. Process according to claim 12, characterized in that N-amine ethylpipera is used in H. The method according to claim 1 to 11, characterized ge indicates that a polyamide resin is used as a hardener · 15. Method naoh Ampraol: 1 hie 9 »characterized in that βχβ hardener is a cyclischeβ Anhydride used; 16. The method naoh claim 2 to 15 »characterized in that one al * streokmittel-oil a transformer oil used 1? · Procedure according to Anopruoh 2 to 15, thereby g β - kennseichnet that maa "in oil Wed fine viscosity of about 50 am 2000 SSU used at 50 ⁰ C. te. Verfaiuren according Ausprueö t to 15, dudureh ge · k ι η a tκ 1 e H ι t, AaS mea eiaett löeuu ^ eeittel- sroaatiaehea Extract «ine« Lubricant Deetlllate 809831 / U8 / *. BATH ORIGINAL 1A-25 119 1520783 used. 19. The method according to claim 18, characterized in that one uses an aromatic extract with an aromatic content of at least 50% Weight-56 used. 20. The method according to ^A nepruoh 19, characterized in that an aromatic extract with an aromatic content of 60 to 65 wt .- ^ is used. 21 · ^A method according to nepruch 18 to 20, characterized in that there is used an aromatic extract having a viscosity of 100 to 2500 SSIT at 50 ⁰ C. 22. The method according to claim 18, characterized in that an aromatic extract having a specific gravity of about 0.99 at 15 "5 ° E (60 ° F) _# a ^v iscosity of about 256 ssu at 21 * 0 ⁽⁰ 7O F), an aniline point of approximately -13 ⁰ O, a pour point of approximately -57 * 0 (-55 ⁰ F), a refractive index of approximately 1.55 at 50 ⁰ O and a flash point according to * Pen # ky Martin - open cup "of about 165 * 5 * 0 (53O ⁰ F) is used. 909831 / U84 - * - - \ - 1A-25 119 23 · Method according to claims 1 to 22 »thereby g · - * indicates that the preparation (A) a neutral diluent or a white earmonger gueatxt 24. The method according to claim 1 to 23 »characterized in that that preparation (B) can be mixed with a neutral diluent or a plasticizer P adds » 25 «Method according to claim 23 or 24» characterized »that one is used as a neural diluent a high-boiling, strongly aromatic solvent - with an aromatic content τοη at least 80 vol. 56 used, 26. The method according to claim 23 to 25, characterized in that - L indicates that you have a lot of the neutral Diluent τοη not more than 20 wt * -9fc of the amount of polyepoxide used· 27. Process according to claims 1 to 26 , characterized in that an amount of the foly epoxide in the total mass (A + B) between 30 and 60 wt .- # is used · -7-909831 / U8Ü 1A-25 119 28. Epoxy resin Härtersttbereiturii, characterized by one, oil on a hardener preparation from a hardener with one or more reactive BH or NHg groups or an anhydride hardener, from a hydrocarbon-substituted phenol and off an extender oil. 29 * Preparation according to claim 28, be known by keeping H-Aminoäthylpiperazin ice hardener. 30.Preparation according to ^ nspruoh 28 or 29, g e k * a η - ζ e i c h net; due to a content of a hydrocarbon * substituted phenol of at least 7 carbon atoms in at least »one side chain. 31. Preparation according to claim 30, characterized by eii, en content of dodecylphenol or Dinony! Phenol 32. Preparation according to claims 28 to 31 »g» Ic ι ä η ζ eieh η et by a content of a StreekmitteX oil · In ΐctm of an aromatiseheff Xö »ttng ** itt» l- * xtrahi »ri * i ßeh * iei? - bl-Eitraict »xtlt a s ^ Hifieshe» ftewicht τοη 0.99 at Ι5.5 ^β β (60 ⁰ Ih # ΐΑβ »Tiekosltät " im, 256 SSü at TQ ⁹ C, «in · * attachment point of un« #fftSwr -15 * 3, a pour point of wkgasst & a? -37 * 0 6-35 ^β ϊ) » mim * index of about 1 _? 55 asked §§% naä «in« e $ l & MMpvskt wattk - .909831 / 1464 ^; - - / "' ^: BATH ORIGINAL - ^ - 1A-25 11.9 "Pensky Martin - open cup" of about 165.5 ° E (53O ⁰ F). 33 «Preparation according to claim 28 to 32, g e k e η η.-Ζ ei ο hne t through a content of a neutral Thinner or an egg maker 34 · Epoxy resin preparation, characterized in that it was produced by a method according to claim 1 to 27 · 35. Haosmaeae, marked thereby, dafl the same was produced by curing an epoxy resin preparation according to claim 34 36 «A method of applying a Übersujes to a surface, characterized g exe η η ζ e ic hne t, £ as a preparation according to claim 34 for use bringti" 37 · ^A method according to nspruch 36, characterized gik e Anzeichnet in that the preparation erfindungsgemät'SMn gate or dimensioned during their curing "neutral small" particles, aggregates or pigments susetst · 38. A method for binding threads from Steineohotter b "eteh" layers, characterized GEK · η η% β i ο h η et that. a preparation according to claim 34 as a coating on (a concrete or metal surface or in the case of * road construction, 90 9831/1484. _ ^. ^: 1A-25 119 when laying paving or on a »deck of a ship. 39 · The method of claim 38, characterized g * ke η η ζ η et verifiable that _r>: el .ehen abbindet or aggregates of sand, crushed rock, ground 4uarz, alumina, Silieiumoarbid, Schmi ^ rsäel or ground rock. 40 «Method according to claim 39» characterized in that geke η η. _v that an amount of the particles or the aggregate of at least 50% is brought to processing according to the preparation according to the invention. 41. A process for the production of roof stencils, of products for pottery, you (rieüäingen, encapsulation material, of sealing or impregnation preparations, covers for pipes, connecting pieces for cables, stretchable connection pieces or of grass foils, characterized in that one a preparation according to claim 34 used « 6126 909831/148 BADORIGfNAL