DE1151242B - Removal agent for colored keratin fiber material, especially for living hair - Google Patents

Removal agent for colored keratin fiber material, especially for living hair

Info

Publication number
DE1151242B
DE1151242B DEV20069A DEV0020069A DE1151242B DE 1151242 B DE1151242 B DE 1151242B DE V20069 A DEV20069 A DE V20069A DE V0020069 A DEV0020069 A DE V0020069A DE 1151242 B DE1151242 B DE 1151242B
Authority
DE
Germany
Prior art keywords
fiber material
living hair
keratin fiber
removal agent
hair
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEV20069A
Other languages
German (de)
Inventor
Dipl-Chem Dr Guenther Vogt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUENTHER VOGT DIPL CHEM DR
Original Assignee
GUENTHER VOGT DIPL CHEM DR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUENTHER VOGT DIPL CHEM DR filed Critical GUENTHER VOGT DIPL CHEM DR
Priority to DEV20069A priority Critical patent/DE1151242B/en
Priority claimed from US212157A external-priority patent/US3190803A/en
Publication of DE1151242B publication Critical patent/DE1151242B/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/08—Preparations for bleaching the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/13—Fugitive dyeing or stripping dyes
    • D06P5/138—Fugitive dyeing or stripping dyes fugitive dyeing

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Description

DEUTSCHESGERMAN

PATENTAMTPATENT OFFICE

kl. 8 m 12 kl. 8 m 12

INTERNATIONALE KL.INTERNATIONAL KL.

D 06p; A 61kD 06p; A 61k

V 20069 IVc/8mV 20069 IVc / 8m

ANMELDETAG: 31. J A N U A R 1961REGISTRATION DATE: JANUARY 31, 1961

BEKANNTMACHUNG DER ANMELDUNG UND AUSGABE DER AUSLEGESCHRIFT: 11. JULI 1963NOTICE THE REGISTRATION AND ISSUE OF THE EDITORIAL: JULY 11, 1963

Es ist bekannt und üblich, mit künstlichen organischen Farbstoffen gefärbte Textilfasern durch Behandlung mit reduzierend wirkenden Substanzen im alkalischen Medium abzuziehen oder aufzuhellen.It is known and customary to treat textile fibers dyed with artificial organic dyes peeled off or lightened with reducing substances in an alkaline medium.

Als wirksame Reduktionsmittel sind die Alkalisalze der dithionigen Säure oder Derivate der Sulfoxylsäure in Verwendung. Nachteilig für Keratinfasern, insbesondere für lebendes Haar, ist die hohe Alkalität, unter der diese Mittel zur Anwendung gelangen. Ein PH > 11 ist für empfindliches Keratinfasermaterial und lebendes Haar nicht vertretbar, da unter diesen Bedingungen beim Abziehprozeß erhebliche Schäden auftreten.The alkali salts of dithionic acid or derivatives of sulfoxylic acid are effective reducing agents in use. A disadvantage for keratin fibers, especially for living hair, is the high alkalinity, under which these funds are used. A PH> 11 is not justifiable for sensitive keratin fiber material and living hair, as it is among them Conditions during the peeling process significant damage occur.

Es wurde nun gefunden, daß Abziehmittel, die etwa 1 bis 2%. Thioharnstoffdioxyd (Formamidinsulfinsäure), etwa 3 bis 8% Polyvinylpyrrolidon und als Lösungsvermittler einen Glycolmonoalkyläther, zweckmäßig in einer Menge von 2 bis 7% enthalten, und die durch Puffersubstanzen auf ein pH zwischen 7 und etwa 9 abgepuffert sind, für gefärbtes Keratinmaterial, insbesondere für lebendes Haar, ein außerordentlich gutes Abziehvermögen besitzen, ohne daß das Substrat dabei geschädigt wird.It has now been found that stripping agents that contain about 1 to 2%. Thiourea dioxide (formamidine sulphinic acid), about 3 to 8% polyvinyl pyrrolidone and as solubilizer a Glycolmonoalkyläther, advantageously contained in an amount of 2 to 7%, and which are buffered by buffer substances to a p H of between 7 and about 9, for dyed keratinous material, in particular for living hair, have an extremely good peelability without damaging the substrate.

Da in der angeführten Zubereitung das Thioharnstoffdioxyd sich infolge der Anwesenheit eines GIykolmonoalkyläthers über längere Zeit stabil verhält, kann das Abziehmittel gebrauchsfertig abgefüllt und gelagert werden, was einen erheblichen Fortschritt gegenüber den bisher üblichen Abziehmitteln bedeutet, die aus getrennten Behältern unmittelbar vor der Anwendung gelöst und zusammengegeben werden müssen. Der Gehalt an Glykolmonoalkyläther bewirkt auch einen raschen Reaktionsverlauf.Since the thiourea dioxide in the preparation mentioned is due to the presence of a glycol monoalkyl ether remains stable over a long period of time, the release agent can be filled and ready to use be stored, which means a considerable advance compared to the previously common stripping agents, which are released from separate containers and put together immediately before use have to. The glycol monoalkyl ether content also causes the reaction to proceed rapidly.

Das Thioharnstoffdioxyd kann in guter Ausbeute nach dem Verfahren der USA.-Patentschrift 2150 921 hergestellt werden. Der Schmelzpunkt des so gewonnenen Produkts liegt bei 126 bis 128° C.The thiourea dioxide can be obtained in good yield by the process of US Pat. No. 2,150,921 getting produced. The melting point of the product obtained in this way is 126 to 128 ° C.

Das Polyvinylpyrrolidon, das an sich als mildes Aufhellungsmittel in der Textilveredlung bekannt ist, übt in dem erfindungsgemäßen Präparat eine stabilisierende und beim Abziehprozeß synergistische Wirkung auf das Thioharnstoffdioxyd aus.The polyvinylpyrrolidone, which is known as a mild brightening agent in textile finishing, has a stabilizing and synergistic effect in the preparation according to the invention on the thiourea dioxide.

Durch Zusatz eines alkali- und reduktionsmittelbeständigen Verdickungsmittels wird eine hohe Viskosität des Abziehmittels bewirkt und eine gute und gleichmäßige Applikation auf lebendem Haar ermöglicht. Beispiel The addition of an alkali-resistant and reducing agent-resistant thickener results in a high viscosity of the stripping agent and enables good and even application on living hair. example

1,5 Teile Thioharnstoffdioxyd, 5,0 Teile Polyvinylpyrrolidon, 5,0 Teile Glycolmonobutyläther, 1,0 Teil Abziehmittel für gefärbtes Keratinfasermaterial, insbesondere für lebendes Haar1.5 parts of thiourea dioxide, 5.0 parts of polyvinylpyrrolidone, 5.0 parts of glycol monobutyl ether, 1.0 part Stripping agents for colored keratin fiber material, in particular for living hair

Anmelder:Applicant:

DipL-Chem. Dr. Günther Vogt,
Schifferstadt (Pfalz), Am MühlwegDipL-Chem. Dr. Günther Vogt,
Schifferstadt (Palatinate), Am Mühlweg

DipL-Chem. Dr. Günther Vogt, Schifferstadt (Pfalz), ist als Erfinder genannt wordenDipL-Chem. Dr. Günther Vogt, Schifferstadt (Palatinate), has been named as the inventor

Ammoniumbicarbonat, 0,5 Teile Ammoniak (25%>ig) und 2,5 Teile Celluloseglycolat werden mit Wasser unter Rühren auf 100 Teile aufgefüllt. Man erhält ein nahezu farbloses hochviskoses Präparat.Ammonium bicarbonate, 0.5 parts of ammonia (25% strength) and 2.5 parts of cellulose glycolate are mixed with water made up to 100 parts with stirring. An almost colorless, highly viscous preparation is obtained.

Mit Oxydationsfarbstoffen und/oder Wollfarbstoffen aus wäßriger Lösung gefärbtes Haarmaterial ist nach einer Behandlungsdauer von 15 bis 30 Minuten bei Körpertemperatur nahezu abgezogen. Durch Erhöhung der Temperatur kann die Dauer des Prozesses verkürzt werden.Hair material dyed with oxidation dyes and / or wool dyes from an aqueous solution is almost withdrawn after 15 to 30 minutes of treatment at body temperature. The duration of the process can be shortened by increasing the temperature.

Physikalische und chemische Untersuchungen des behandelten Haares zeigten keine Schädigung.Physical and chemical tests of the treated hair showed no damage.

Claims (2)

PATENTANSPRÜCHE:PATENT CLAIMS: 1. Abziehmittel für gefärbtes Keratinfasermaterial, insbesondere für lebendes Haar, dadurch gekennzeichnet, daß es etwa 1 bis 2% Thioharnstoffdioxyd, etwa 3 bis 8% Polyvinylpyrrolidon und einen Glycolmonoalkyläther enthält und daß es durch Puffersubstanzen auf ein pH zwischen 7 und etwa 9 abgepuffert ist.1. removers colored Keratinfasermaterial, particularly for living hair, characterized in that it contains about 1 to 2% thiourea dioxide, about 3 to 8% of polyvinyl pyrrolidone and a Glycolmonoalkyläther and in that it is buffered by buffer substances to a p H of between 7 and about 9 . 2. Mittel nach Anspruch 1, dadurch gekennzeichnet, daß es ein alkali- und reduktionsmittelbeständiges Verdickungsmittel enthält.2. Agent according to claim 1, characterized in that it is an alkali and reducing agent resistant Contains thickeners. In Betracht gezogene Druckschriften:
Deutsche Patentschrift Nr. 973 799;
britische Patentschrift Nr. 816 930;
französische Patentschrift Nr. 1150 224.Considered publications:
German Patent No. 973,799;
British Patent No. 816,930;
French patent specification No. 1150 224.
DEV20069A 1961-01-31 1961-01-31 Removal agent for colored keratin fiber material, especially for living hair Pending DE1151242B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEV20069A DE1151242B (en) 1961-01-31 1961-01-31 Removal agent for colored keratin fiber material, especially for living hair

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEV20069A DE1151242B (en) 1961-01-31 1961-01-31 Removal agent for colored keratin fiber material, especially for living hair
US212157A US3190803A (en) 1962-07-24 1962-07-24 Pvp-formamidine sulfinic acid color stripping medium

Publications (1)

Publication Number Publication Date
DE1151242B true DE1151242B (en) 1963-07-11

Family

ID=26001506

Family Applications (1)

Application Number Title Priority Date Filing Date
DEV20069A Pending DE1151242B (en) 1961-01-31 1961-01-31 Removal agent for colored keratin fiber material, especially for living hair

Country Status (1)

Country Link
DE (1) DE1151242B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003030849A1 (en) * 2001-10-04 2003-04-17 Henkel Kommanditgesellschaft Auf Aktien Method for dyeing and subsequent bleaching of hair
WO2007107308A2 (en) * 2006-03-21 2007-09-27 Henkel Ag & Co. Kgaa Reductive colour removal
WO2012069599A2 (en) 2010-11-25 2012-05-31 L'oreal Process for stripping keratin fibres using a composition comprising a sulfinic acid derivative and an acidic aqueous composition
EP2502613A3 (en) * 2008-03-10 2015-04-01 Perachem Limited Hair treatment composition and methods
EP2502614A3 (en) * 2008-09-16 2016-06-15 Perachem Limited Hair treatment methods
EP2736481B1 (en) 2011-07-29 2017-07-19 Perachem Limited Method of removing colour from oxidatively dyed hair

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1150224A (en) * 1955-06-03 1958-01-09 Basf Ag Process for removing dyes
GB816930A (en) * 1956-08-31 1959-07-22 Hardman & Holden Ltd Improved process for printing textile materials
DE973799C (en) * 1954-08-22 1960-06-09 Basf Ag Process for whitening dyes with Kuepen dyes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE973799C (en) * 1954-08-22 1960-06-09 Basf Ag Process for whitening dyes with Kuepen dyes
FR1150224A (en) * 1955-06-03 1958-01-09 Basf Ag Process for removing dyes
GB816930A (en) * 1956-08-31 1959-07-22 Hardman & Holden Ltd Improved process for printing textile materials

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003030849A1 (en) * 2001-10-04 2003-04-17 Henkel Kommanditgesellschaft Auf Aktien Method for dyeing and subsequent bleaching of hair
WO2007107308A2 (en) * 2006-03-21 2007-09-27 Henkel Ag & Co. Kgaa Reductive colour removal
WO2007107308A3 (en) * 2006-03-21 2008-05-15 Henkel Kgaa Reductive colour removal
EP2502613A3 (en) * 2008-03-10 2015-04-01 Perachem Limited Hair treatment composition and methods
EP2502614A3 (en) * 2008-09-16 2016-06-15 Perachem Limited Hair treatment methods
WO2012069599A2 (en) 2010-11-25 2012-05-31 L'oreal Process for stripping keratin fibres using a composition comprising a sulfinic acid derivative and an acidic aqueous composition
EP3494956A2 (en) 2010-11-25 2019-06-12 L'Oréal Procédé pour le décapage de fibres kératiniques utilisant une composition comprenant un dérive dacide sulfinique et une composition aqueuse acide
US11406578B2 (en) 2010-11-25 2022-08-09 L'oreal Process for stripping keratin fibres using a composition comprising a sulfinic acid derivative and an acidic aqueous composition
EP2736481B1 (en) 2011-07-29 2017-07-19 Perachem Limited Method of removing colour from oxidatively dyed hair

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