DE10637C - Process for the separation of the sodium chloride and magnesium chloride from the potassium magnesium sulfate in kainite - Google Patents
Process for the separation of the sodium chloride and magnesium chloride from the potassium magnesium sulfate in kainiteInfo
- Publication number
- DE10637C DE10637C DENDAT10637D DE10637DA DE10637C DE 10637 C DE10637 C DE 10637C DE NDAT10637 D DENDAT10637 D DE NDAT10637D DE 10637D A DE10637D A DE 10637DA DE 10637 C DE10637 C DE 10637C
- Authority
- DE
- Germany
- Prior art keywords
- kainite
- magnesium
- chloride
- potassium
- separation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 title claims description 14
- 239000011780 sodium chloride Substances 0.000 title claims description 13
- BMQVDVJKPMGHDO-UHFFFAOYSA-K magnesium;potassium;chloride;sulfate;trihydrate Chemical compound O.O.O.[Mg+2].[Cl-].[K+].[O-]S([O-])(=O)=O BMQVDVJKPMGHDO-UHFFFAOYSA-K 0.000 title claims description 9
- OJXVUEMVNWMNCR-UHFFFAOYSA-L magnesium;potassium;sulfate Chemical compound [Mg+2].[K+].[O-]S([O-])(=O)=O OJXVUEMVNWMNCR-UHFFFAOYSA-L 0.000 title description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L MgCl2 Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 title description 3
- 238000000034 method Methods 0.000 title description 3
- 238000000926 separation method Methods 0.000 title description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 title 1
- 235000002639 sodium chloride Nutrition 0.000 claims description 12
- CSNNHWWHGAXBCP-UHFFFAOYSA-L mgso4 Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 150000003839 salts Chemical class 0.000 description 4
- OTYBMLCTZGSZBG-UHFFFAOYSA-L Potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 2
- -1 magnesium chlorine Chemical compound 0.000 description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 description 2
- 235000011151 potassium sulphates Nutrition 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical class [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Chemical class 0.000 description 1
- 229910052749 magnesium Chemical class 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical class [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000001120 potassium sulphate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
- C01D5/12—Preparation of double sulfates of magnesium with sodium or potassium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Description
1879.1879.
KlasseGreat
H. PRECHT in NEU-STASSFURT bei STASSFURT.H. PRECHT in NEW STASSFURT at STASSFURT.
im Kainit.in the kainite.
Patentirt im Deutschen Reiche vom 5. August 1879 ab.Patented in the German Empire on August 5, 1879.
Der Kainit (K'1 SO4, MgSO", MgCl'2, 6J72 O), welcher in den Kalisalzbergwerken gewonnen wird, ist fast immer von Steinsalz begleitet, dessen Menge etwa 30 pCt. beträgt. Ein für den Fabrikbetrieb sich eignendes Verfahren zur Trennung des Chlornatriums vom Kainit kennt man bisher nicht, und daher ist eine Verarbeitung des Kainits zu reinen Kalisalzen mit Erfolg nie zur Ausführung gekommen. Auf folgende einfache Weise wird die Trennung des Chlornatriums vom Kainit ermöglicht.The kainite (K ' 1 SO 4 , MgSO ", MgCl' 2 , 6J7 2 O), which is extracted in the potash salt mines, is almost always accompanied by rock salt, the amount of which is about 30 pCt. A process suitable for factory operation Separation of sodium chloride from kainite is not known so far, and therefore processing of kainite into pure potassium salts has never been successfully carried out.
Das Princip dieser Methode besteht in der Behandlung des Kainits mit Wasser oder Salzlösungen bei 120 bis 1500C. unter einem Dampfdruck von 2 bis 5 Atmosphären. Der Kainit wird in Stücken von beliebiger Gröfse zu dieser Operation verwendet, er zerfällt dabei in ein feines Krystallmehl von Kaliummagnesiumsulfat, während Chlormagnesium in Lösung geht. Zum Aufschliefsen dient eine Salzlösung, welche beim Waschen des ausgeschiedenen Kaliummagnesiumsulfats gewonnen wird, und Salze des Kaliums, Natriums und Magnesiums in beliebiger Menge gelöst enthält.The principle of this method consists in the treatment of kainite with water or salt solutions at 120 to 150 0 C. under a steam pressure of 2 to 5 atmospheres. The kainite is used for this operation in pieces of any size; it breaks down into a fine crystalline powder of potassium magnesium sulphate, while chlorine magnesium dissolves. A salt solution, which is obtained by washing the excreted potassium magnesium sulphate and which contains salts of potassium, sodium and magnesium in any amount, is used to break it up.
ι Theil Salzlösung genügt, um 3 bis 4 Theile Kainit in ein feines Krystallmehl überzuführen. Das Steinsalz wird durch diese Operation nicht verändert, es bleibt in dem natürlichen Zustande in gröfseren oder kleineren Stücken zurück und kann sehr leicht durch ein Sieb getrennt werden. Die Trennung mittelst Sieb geschieht im feuchten Zustande in der Lauge, welche zum Aufschliefsen diente. Das grobe Salz, welches im Siebe zurückbleibt, ist fast reines Chlornatrium, das feine Salz besteht aus Kaliumsulfat und Magnesiumsulfat, es wird mit Wasser gewaschen und zu Düngesalz oder zu reinem Kaliumsulfat nach bekannten Methoden weiter verarbeitet.One part of saline solution suffices, by 3 to 4 parts To convert kainite into a fine crystal flour. The rock salt is not changed by this operation, it remains in the natural state in larger or smaller pieces and can be separated very easily through a sieve. The separation by means of a sieve takes place in the moist conditions in the lye which served to open up. The coarse salt, which What remains in the sieve is almost pure sodium chloride, the fine salt consists of potassium sulfate and magnesium sulfate, it is washed with water and made into fertilizer salt or pure Potassium sulphate is further processed using known methods.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE10637C true DE10637C (en) | 1879-08-05 |
Family
ID=287930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT10637D Expired DE10637C (en) | Process for the separation of the sodium chloride and magnesium chloride from the potassium magnesium sulfate in kainite |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE10637C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4384788A (en) * | 1979-11-12 | 1983-05-24 | Basf Aktiengesellschaft | Self-supporting stirrer for mixing a bed of free-flowing solids |
-
0
- DE DENDAT10637D patent/DE10637C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4384788A (en) * | 1979-11-12 | 1983-05-24 | Basf Aktiengesellschaft | Self-supporting stirrer for mixing a bed of free-flowing solids |
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