DE10357893A1 - Oxidizing catalyst with variable activity - Google Patents
Oxidizing catalyst with variable activity Download PDFInfo
- Publication number
- DE10357893A1 DE10357893A1 DE10357893A DE10357893A DE10357893A1 DE 10357893 A1 DE10357893 A1 DE 10357893A1 DE 10357893 A DE10357893 A DE 10357893A DE 10357893 A DE10357893 A DE 10357893A DE 10357893 A1 DE10357893 A1 DE 10357893A1
- Authority
- DE
- Germany
- Prior art keywords
- exhaust gas
- oxidation
- nitrogen dioxide
- oxidation catalyst
- soot
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2053—By-passing catalytic reactors, e.g. to prevent overheating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
- F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
- F01N13/011—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more purifying devices arranged in parallel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
- F01N3/0231—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using special exhaust apparatus upstream of the filter for producing nitrogen dioxide, e.g. for continuous filter regeneration systems [CRT]
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
- F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2430/00—Influencing exhaust purification, e.g. starting of catalytic reaction, filter regeneration, or the like, by controlling engine operating characteristics
- F01N2430/08—Influencing exhaust purification, e.g. starting of catalytic reaction, filter regeneration, or the like, by controlling engine operating characteristics by modifying ignition or injection timing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/03—Adding substances to exhaust gases the substance being hydrocarbons, e.g. engine fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/02—Circuit arrangements for generating control signals
- F02D41/14—Introducing closed-loop corrections
- F02D41/1401—Introducing closed-loop corrections characterised by the control or regulation method
- F02D2041/1433—Introducing closed-loop corrections characterised by the control or regulation method using a model or simulation of the system
Abstract
Description
Die Erfindung betrifft ein Verfahren zum Betreiben einer Abgasreinigungsanlage mit einem Partikelfilter zur Abtrennung von Ruß aus dem Abgas einer selbstzündenden Brennkraftmaschine und mit einem dem Partikelfilter vorgeschalteten Oxidationskatalysator zur Erzeugung von Stickstoffdioxid aus im Abgas enthaltenem Stickstoffmonoxid und wobei der Ruß unter Verwendung des erzeugten Stickstoffdioxids kontinuierlich oder diskontinuierlich oxidiert wird sowie eine entsprechende Vorrichtung.The The invention relates to a method for operating an emission control system with a particulate filter for separating soot from the exhaust of a self-igniting Internal combustion engine and with a particle filter upstream Oxidation catalyst for the production of nitrogen dioxide from in the exhaust gas contained nitric oxide and wherein the carbon black produced using the Nitrogen dioxide oxidized continuously or discontinuously and a corresponding device.
Ein
derartiges Verfahren und eine derartige Vorrichtung sind aus der
Der Erfindung liegt die Aufgabe zugrunde, ein Verfahren zum Betreiben einer Abgasreinigungsanlage und eine entsprechende Vorrichtung anzugeben, mit denen die Gesamtemissionen einer Brennkraftmaschine vermindert werden.Of the Invention is based on the object, a method for operating specify an exhaust gas purification system and a corresponding device, with which the total emissions of an internal combustion engine reduced become.
Diese Aufgabe wird dadurch gelöst, dass die Oxidation des Stickstoffoxids zu Stickstoffdioxid in dem Oxidationskatalysator gesteuert wird. Die entsprechende Vorrichtung zeichnet sich dadurch aus, dass der Oxidationskatalysator gesteuert über eine Umgehungsleitung passierbar ist. In einer alternativen Ausführung der Vorrichtung ist keine Umgehungsleitung zu dem Oxidationskatalysator vorgesehen, dafür wird die Aktivität des Oxidationskatalysators durch die Abstimmung der Kraftstoff-Einspritzung in die Brennräume oder ins Abgassystem der Brennkraftmaschine gesteuert. Durch diese Steuerung liefert der Oxidationskatalysator in allen Betriebspunkten eine hinreichend hohe Stickstoffdioxid-Konzentration, die so eingestellt wird, dass eine vollständige Oxidation des im Partikelfilter gesammelten Rußes erreicht wird, ohne dass ein Überschuss von Stickstoffdioxid in die Umgebung emittiert wird.These Task is solved by that the oxidation of the nitrogen oxide to nitrogen dioxide in the Oxidation catalyst is controlled. The corresponding device is characterized in that the oxidation catalyst controlled by a bypass line is passable. In an alternative embodiment of the device is no Provided bypass to the oxidation catalyst, this is the activity of the oxidation catalyst by tuning the fuel injection in the combustion chambers or controlled in the exhaust system of the internal combustion engine. Through this Control supplies the oxidation catalyst in all operating points a sufficiently high nitrogen dioxide concentration, so adjusted that will be a complete one Oxidation of the collected in the particulate filter carbon black is achieved without that a surplus emitted by nitrogen dioxide into the environment.
Die Nullemission von Stickstoffdioxid in die Umgebung ist anzustreben, da Stickstoffdioxid ein aktives Atemgift mit einem sehr niedrigen MAK-Wert (maximale Arbeitsplatzkonzentration) ist. Das Stickstoffdioxid wird aber – wie ausgeführt – andererseits zur Rußoxidation in dem Partikelfilter benötigt und bei einer optimalen Abstimmung bei der Rußverbrennung zumindest weitgehend wieder vollständig zu Stickstoffmonoxid umgewandelt. Dieses System kann insbesondere bei kontinuierlich regenerierenden Partikelfiltern eingesetzt werden.The Zero emission of nitrogen dioxide into the environment is to be strived for, Nitrogen dioxide is an active respiratory poison with a very low MAK value (maximum workplace concentration) is. The nitrogen dioxide but will - like executed - on the other hand to soot oxidation needed in the particle filter and at least largely at optimum tuning during soot combustion completely again converted to nitric oxide. In particular, this system can be used in continuously regenerating particulate filters.
Bei
der Einstellung der Stickstoffdioxidkonzentration sind die nachfolgenden
Gegebenheiten zu berücksichtigen:
Der
Oxidationskatalysator hat zu Beginn (Neuzustand) die höchste Aktivität, die im
Laufe der Zeit nachlässt.
Gleichzeitig hat die Brennkraftmaschine am Anfang (Neuzustand) die
niedrigste Rußemission,
die im Laufe der Zeit aber höher
wird. Somit existieren zwei gegenläufige, sich nicht ausgleichende Alterungsprozesse.When adjusting the nitrogen dioxide concentration, the following conditions must be taken into account:
The oxidation catalyst at the beginning (new state) has the highest activity, which decreases over time. At the same time, the engine has the lowest soot emission at the beginning (new condition), but becomes higher over time. Thus, there are two opposing, non-balancing aging processes.
Weiterhin kann eine zeitweilige Verschlechterung des Oxidationskatalysators auftreten. Dieses ist beispielsweise bei Verwendung von einem Kraftstoff mit einem erhöhten Schwefelgehalt der Fall.Farther may be a temporary deterioration of the oxidation catalyst occur. This is for example when using a fuel with an elevated Sulfur content of the case.
Bei einem (akuten) Regenerationsbedarf des Partikelfilters kann eine bewusste Erhöhung der Aktivität des Oxidationskatalysators (hohe Stickstoffdioxidwerte sind erwünscht) nötig sein.at an (acute) regeneration needs of the particulate filter can a conscious increase the activity of the oxidation catalyst (high nitrogen dioxide levels are desired).
Die bekannten Stickstoffdioxidspitzenwerte, die bei bestimmten Kombinationen von Oxidationskatalysatortemperatur, Motorlast und Motordrehzahl auftreten können, sind zu vermeiden.The known nitrogen dioxide levels, which in certain combinations of oxidation catalyst temperature, engine load and engine speed occur can, should be avoided.
Ebenso sind hohe Stickstoffdioxidemissionswerte bei niedriger Fahrzeuggeschwindigkeit und im Stillstand des Fahrzeugs, die allesamt Zustände mit geringer natürlicher Verdünnung der Abgase am Endrohr darstellen, zu vermeiden. Dabei können Emissionen in einer sensiblen Umgebung durch Nutzung von GPS-Informationen vermieden werden.As well are high nitrogen dioxide emissions at low vehicle speed and at standstill of the vehicle, all of which states lower naturally dilution represent the exhaust gases at the tailpipe, to avoid. This can be emissions in a sensitive environment by using GPS information be avoided.
Weitere
vorteilhafte Ausgestaltungen der Erfindung sind der Zeichnungsbeschreibung
zu entnehmen, in der ein in der Figur dargestelltes Ausführungsbeispiel
der Erfindung näher
beschrieben ist. Das von einer Brennkraftmaschine
Die
Kenntnis dieser Abhängigkeit
wird bei der Steuerung der Umwandlung von Stickstoffmonoxid zu Stickstoffdioxid
in dem Oxidationskatalysator
Wie
ausgeführt,
ist der Anteil an überschüssigem Stickstoffdioxid,
der über
die Abgasleitung
- 11
- BrennkraftmaschineInternal combustion engine
- 2a, 2c, 2d2a, 2c, 2d
- weiterführende Abgasleitungfurther exhaust pipe
- 2b2 B
- Umgehungsleitungbypass line
- 3, 3a3, 3a
- Oxidationskatalysatoroxidation catalyst
- 44
- Partikelfilterparticulate Filter
Claims (6)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10357893A DE10357893A1 (en) | 2003-12-11 | 2003-12-11 | Oxidizing catalyst with variable activity |
DE502004010968T DE502004010968D1 (en) | 2003-12-11 | 2004-12-09 | Oxidizing catalyst with variable activity |
AT04029134T ATE462874T1 (en) | 2003-12-11 | 2004-12-09 | OXIDATION CATALYST WITH VARIABLE ACTIVITY |
EP04029134A EP1541818B1 (en) | 2003-12-11 | 2004-12-09 | Oxidation catalyst with variable activity |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10357893A DE10357893A1 (en) | 2003-12-11 | 2003-12-11 | Oxidizing catalyst with variable activity |
Publications (1)
Publication Number | Publication Date |
---|---|
DE10357893A1 true DE10357893A1 (en) | 2005-07-07 |
Family
ID=34485310
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE10357893A Withdrawn DE10357893A1 (en) | 2003-12-11 | 2003-12-11 | Oxidizing catalyst with variable activity |
DE502004010968T Active DE502004010968D1 (en) | 2003-12-11 | 2004-12-09 | Oxidizing catalyst with variable activity |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE502004010968T Active DE502004010968D1 (en) | 2003-12-11 | 2004-12-09 | Oxidizing catalyst with variable activity |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1541818B1 (en) |
AT (1) | ATE462874T1 (en) |
DE (2) | DE10357893A1 (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1057519A1 (en) * | 1999-05-18 | 2000-12-06 | Kemira Metalkat Oy | Purification system for diesel engine exhaust gases |
DE19961166A1 (en) * | 1999-12-17 | 2001-06-21 | Volkswagen Ag | Method and device for reducing harmful components in the exhaust gas of an internal combustion engine |
DE10130633A1 (en) * | 2001-06-26 | 2003-01-02 | Man Nutzfahrzeuge Ag | Continuous process for cleaning a particle filter coupled with an oxidation catalyzer, used for particle filters in diesel engines, involves analyzing the amount of carbon black |
US20030089104A1 (en) * | 2001-11-13 | 2003-05-15 | Christophe Colignon | System for helping to regenerate a catalysed particulate filter arranged in a motor vehicle diesel engine exhaust line |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3758389B2 (en) * | 1998-12-09 | 2006-03-22 | 三菱ふそうトラック・バス株式会社 | Diesel engine exhaust gas purification system |
DE19923781C2 (en) | 1999-05-22 | 2001-04-26 | Degussa | Method and device for removing soot from the exhaust gas of a diesel engine |
JP3904768B2 (en) * | 1999-09-06 | 2007-04-11 | 日野自動車株式会社 | Diesel engine exhaust gas particulate filter cleaning and regeneration device |
DE10043613A1 (en) * | 2000-08-02 | 2002-02-14 | Fev Motorentech Gmbh | Filter arrangement, used for cleaning exhaust gases from IC engines, comprises porous particle filter body having catalytically active coating, oxidation catalyst, and adjusting element for adjusting feeds |
DE10062956A1 (en) * | 2000-12-16 | 2002-06-20 | Bosch Gmbh Robert | Emission control system and method for emission control |
JP3788501B2 (en) | 2001-06-28 | 2006-06-21 | 三菱ふそうトラック・バス株式会社 | Exhaust gas purification device for internal combustion engine |
-
2003
- 2003-12-11 DE DE10357893A patent/DE10357893A1/en not_active Withdrawn
-
2004
- 2004-12-09 EP EP04029134A patent/EP1541818B1/en not_active Not-in-force
- 2004-12-09 DE DE502004010968T patent/DE502004010968D1/en active Active
- 2004-12-09 AT AT04029134T patent/ATE462874T1/en active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1057519A1 (en) * | 1999-05-18 | 2000-12-06 | Kemira Metalkat Oy | Purification system for diesel engine exhaust gases |
DE19961166A1 (en) * | 1999-12-17 | 2001-06-21 | Volkswagen Ag | Method and device for reducing harmful components in the exhaust gas of an internal combustion engine |
DE10130633A1 (en) * | 2001-06-26 | 2003-01-02 | Man Nutzfahrzeuge Ag | Continuous process for cleaning a particle filter coupled with an oxidation catalyzer, used for particle filters in diesel engines, involves analyzing the amount of carbon black |
US20030089104A1 (en) * | 2001-11-13 | 2003-05-15 | Christophe Colignon | System for helping to regenerate a catalysed particulate filter arranged in a motor vehicle diesel engine exhaust line |
Also Published As
Publication number | Publication date |
---|---|
EP1541818B1 (en) | 2010-03-31 |
EP1541818A1 (en) | 2005-06-15 |
DE502004010968D1 (en) | 2010-05-12 |
ATE462874T1 (en) | 2010-04-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
OM8 | Search report available as to paragraph 43 lit. 1 sentence 1 patent law | ||
8110 | Request for examination paragraph 44 | ||
R119 | Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee |
Effective date: 20120703 |