DE10352641A1 - Charge-trapping memory cell especially SONOS- and NROM- storage cells, has memory layer sequence for charge-trapping with memory zone between confinement layers - Google Patents
Charge-trapping memory cell especially SONOS- and NROM- storage cells, has memory layer sequence for charge-trapping with memory zone between confinement layers Download PDFInfo
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- DE10352641A1 DE10352641A1 DE2003152641 DE10352641A DE10352641A1 DE 10352641 A1 DE10352641 A1 DE 10352641A1 DE 2003152641 DE2003152641 DE 2003152641 DE 10352641 A DE10352641 A DE 10352641A DE 10352641 A1 DE10352641 A1 DE 10352641A1
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- 230000015654 memory Effects 0.000 title claims abstract description 62
- 210000004027 cell Anatomy 0.000 title description 22
- 210000000352 storage cell Anatomy 0.000 title description 2
- 239000004065 semiconductor Substances 0.000 claims abstract description 22
- 239000002800 charge carrier Substances 0.000 claims abstract description 11
- 238000002347 injection Methods 0.000 claims abstract description 6
- 239000007924 injection Substances 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 6
- 239000000758 substrate Substances 0.000 claims abstract description 5
- 238000003860 storage Methods 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 22
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 239000002784 hot electron Substances 0.000 claims description 5
- 150000004767 nitrides Chemical group 0.000 description 11
- 125000006850 spacer group Chemical group 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 238000005530 etching Methods 0.000 description 4
- 239000013067 intermediate product Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000000231 atomic layer deposition Methods 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000002513 implantation Methods 0.000 description 2
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 241000293849 Cordylanthus Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- LPQOADBMXVRBNX-UHFFFAOYSA-N ac1ldcw0 Chemical compound Cl.C1CN(C)CCN1C1=C(F)C=C2C(=O)C(C(O)=O)=CN3CCSC1=C32 LPQOADBMXVRBNX-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000009412 basement excavation Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical group N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910001936 tantalum oxide Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/792—Field effect transistors with field effect produced by an insulated gate with charge trapping gate insulator, e.g. MNOS-memory transistors
- H01L29/7923—Programmable transistors with more than two possible different levels of programmation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66833—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a charge trapping gate insulator, e.g. MNOS transistors
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Ceramic Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Manufacturing & Machinery (AREA)
- Non-Volatile Memory (AREA)
- Semiconductor Memories (AREA)
Abstract
Description
Bei Charge-Trapping-Speicherzellen, insbesondere SONOS-Speicherzellen und NROM-Speicherzellen, bei denen zwei Bits pro Zelle nichtflüchtig gespeichert werden, tritt das Problem auf, die Ladungsträger in der Speicherschicht an den zwei Speicherplätzen zu lokalisieren. Beim Vorgang des Programmierens werden energiereiche Ladungsträger, heiße Elektronen aus dem Kanalbereich (CHE, Channel Hot Electrons), je nach Vorzeichen der angelegten Spannungen sourceseitig oder drainseitig in die Speicherschicht injiziert und bleiben dort lokalisiert. Es ist vorteilhaft, wenn der Speicherbereich auf einen engen Bereich beschränkt bleibt, da somit die Möglichkeit geschaffen wird, die Abmessungen der Speicherzelle weiter zu verringern. Außerdem soll die gespeicherte Information möglichst lange erhalten bleiben.at Charge trapping memory cells, in particular SONOS memory cells and NROM memory cells in which two bits per cell stored non-volatile If the problem arises, the charge carriers in the storage layer occur at the two memory locations to locate. The process of programming becomes high-energy Charge carriers, hot electrons from the channel area (CHE, Channel Hot Electrons), depending on the sign the applied voltages source side or drain side in the storage layer injected and remain localized. It is advantageous if the memory area remains limited to a narrow range, because thus the possibility is created to further reduce the dimensions of the memory cell. Furthermore the stored information should remain as long as possible.
Die Speicherschicht befindet sich zwischen Begrenzungsschichten aus einem Material einer höheren Energiebandlücke als die Energiebandlücke der Speicherschicht, so dass die Ladungsträger, die in der Speicherschicht eingefangen sind, dort lokalisiert bleiben. Als Material für die Speicherschicht kommt vorzugsweise ein Nitrid in Frage; als umgebendes Material ist vorrangig ein Oxid geeignet. Bei einer Speicherzelle im Materialsystem von Silizium ist die Speicherschicht in dem Beispiel einer ONO-Schichtfolge Siliziumnitrid mit einer Energiebandlücke von etwa 5 eV; die umgebenden Begrenzungsschichten sind Siliziumoxid mit einer Energiebandlücke von etwa 9 eV. Die Speicherschicht kann ein anderes Material sein, dessen Energiebandlücke kleiner als die Energiebandlücke der Begrenzungsschichten ist, wobei die Differenz der Energiebandlücken für einen guten elektrischen Einschluss der Ladungsträger (confinement) möglichst groß sein soll. In Verbindung mit Siliziumoxid als Begrenzungsschichten kann z. B. Tantaloxid, Hafniumsilicat, Titanoxid (im Fall stöchiometri scher Zusammensetzung TiO2), Zirkonoxid (im Fall stöchiometrischer Zusammensetzung ZrO2), Aluminiumoxid (im Fall stöchiometrischer Zusammensetzung Al2O3) oder intrinsisch leitendes (undotiertes) Silizium als Material der Speicherschicht eingesetzt werden.The storage layer is located between boundary layers of a material of a higher energy band gap than the energy band gap of the storage layer, so that the charge carriers that are trapped in the storage layer remain localized there. As the material for the storage layer is preferably a nitride in question; as the surrounding material, an oxide is primarily suitable. In a memory cell in the material system of silicon, the memory layer in the example of an ONO layer sequence is silicon nitride with an energy band gap of about 5 eV; the surrounding confinement layers are silicon oxide with an energy band gap of about 9 eV. The storage layer may be another material whose energy band gap is smaller than the energy band gap of the confinement layers, the difference of the energy band gaps for a good electrical confinement of the charge carriers should be as large as possible. In conjunction with silicon oxide as boundary layers can, for. As tantalum oxide, hafnium silicate, titanium oxide (in the case stoichiometric shear composition TiO 2 ), zirconium oxide (in the case of stoichiometric composition ZrO 2 ), alumina (in the case of stoichiometric composition Al 2 O 3 ) or intrinsically conductive (undoped) silicon as the material of the storage layer become.
In
der
In der WO 98/06139 ist eine nichtflüchtige Speicherzelle beschrieben, bei der auf einem Halbleiterkörper in vertikaler Richtung übereinanderfolgend Bereiche von Source, Kanal und Drain angeordnet sind. Eine ONO-Speicherschichtfolge befindet sich an der Flanke dieser Anordnung und ist auf der gegenüberliegenden Seite mit einer spacerartig ausgebildeten Gate-Elektrode versehen.In WO 98/06139 is a nonvolatile memory cell described in that on a semiconductor body in the vertical direction following one another Regions of source, channel and drain are arranged. An ONO storage layer sequence is located on the flank of this arrangement and is on the opposite side Side provided with a spacer-like formed gate electrode.
In der Veröffentlichung von T. Ogura et al.: "Embedded Twin MONOS Flash Memories with 4ns and 15ns Fast Access Times", 2003 Symposium on VLSI Circuits Digest of Technical Papers, ist eine so genannte Twin-MONOS-Speicherzelle beschrieben, bei der eine ONO-Schichtfolge an der Oberseite eines Halbleiterkörpers in der Ebene dieser Oberseite unterhalb einer jeweiligen, als Seitenwandspacer einer Wortleitungs-Gate-Elektrode ausgebildeten Kontroll-Gate-Elektrode angeordnet ist. Die Programmierung erfolgt durch CHE-Injektion.In the publication by T. Ogura et al .: "Embedded Twin MONOS Flash Memories with 4ns and 15ns Fast Access Times ", 2003 Symposium on VLSI's Circuits Digest of Technical Papers, is a so-called Twin-MONOS memory cell described in which an ONO layer sequence at the top of a semiconductor body in the plane of this top below a respective, as Seitenwandspacer a word line gate electrode trained control gate electrode is arranged. The programming done by CHE injection.
Aufgabe der vorliegenden Erfindung ist es, eine verbesserte Charge-Trapping-Speicherzelle für die Speicherung zweier Bits bei verkleinerten Abmessungen und ein zugehöriges Herstellungsverfahren anzugeben.task It is the object of the present invention to provide an improved charge trapping memory cell for the Storage of two bits with reduced dimensions and an associated manufacturing process specify.
Diese Aufgabe wird mit der Charge-Trapping-Speicherzelle mit den Merkmalen des Anspruchs 1 bzw. mit dem Herstellungsverfahren mit den Merkmalen des Anspruchs 9 gelöst. Ausgestaltungen ergeben sich aus den abhängigen Ansprüchen.These Task is with the charge trapping memory cell with the characteristics of claim 1 or with the manufacturing method with the features of claim 9 solved. Embodiments emerge from the dependent claims.
Die Grundidee der im Folgenden beschriebenen Charge-Trapping-Speicherzelle ist es, die grundlegende Transistorstruktur der Zelle mit Source und Drain im Halbleiterkörper beizubehalten, aber die Speicherschichtfolge an die sourceseitigen und drainseitigen Flanken der Gate-Elektrode zu verlagern. Zwischen dem Kanalbereich und der Gate-Elektrode kann sich daher ein herkömmliches Gate-Dielektrikum befinden. Die Speicherschichtfolge kann insbesondere nach Art eines modifizierten Seitenwandspacers aus Nitrid hergestellt werden. Für den Speicherbereich kommen aber im Prinzip alle für Charge-Trapping-Speicherzellen geeigneten Speichermedien in Frage. Vorzugsweise wird die Gate-Elektrode mit sourceseitigen und drainseitigen überhängenden Flanken ausgebildet, so dass die Speicherbereiche und die Grenzflächen von Source und Drain zum Kanal hin (Junctions) jeweils seitlich der Gate-Elektrode angeordnet sein können, aber trotzdem ein für das Programmieren ausreichend starkes elektrisches Feld durch die an der Gate-Elektrode anzulegende Spannung erzeugt werden kann.The basic idea of the charge trapping memory cell described below is to maintain the basic transistor structure of the cell with source and drain in the semiconductor body, but to shift the storage layer sequence to the source side and drain side edges of the gate electrode. Therefore, a conventional gate dielectric may be located between the channel region and the gate electrode. The memory layer sequence can be produced in particular in the manner of a modified sidewall spacer made of nitride. In principle, all storage media suitable for charge-trapping storage cells are suitable for the storage area. Preferably, the gate electrode is formed with source side and drain side overhanging edges, so that the memory areas and the interfaces of source and drain to the channel (junctions) each side The gate electrode can be arranged, but nevertheless a sufficiently strong electric field for programming can be generated by the voltage to be applied to the gate electrode.
Es folgt eine genauere Beschreibung von Beispielen der Speicherzelle und bevorzugter Herstellungsverfahren.It follows a more detailed description of examples of the memory cell and preferred manufacturing method.
Die
Die
Die
Die
Die
Die
Die
Die
Die
Bei
diesem Ausführungsbeispiel
befinden sich die Grenzflächen
Die
Der
Kanal der Charge-Trapping-Speicherzelle muss mittels der Gate-Spannung
steuerbar sein, so dass zum Zweck der Programmierung Ladungsträger aus
dem Kanal in den Speicherbereich
In
der
Die
Injektion von negativen Ladungsträgern in den Speicherbereich
Ein
bevorzugtes Herstellungsverfahren wird als Beispiel anhand der
In
der
Anschließend wird
die Oxidschicht
Die
Die
- 11
- HalbleiterkörperSemiconductor body
- 22
- Source-/Drain-BereichSource / drain region
- 33
- Kanalbereichchannel area
- 44
- Gate-DielektrikumGate dielectric
- 55
- Gate-ElektrodeGate electrode
- 66
- Flankeflank
- 77
- Begrenzungsschichtboundary layer
- 88th
- Speicherbereichstorage area
- 99
- Begrenzungsschichtboundary layer
- 1010
- Grenzflächeinterface
- 1111
- Oxidschichtoxide
- 1212
- Nitridschichtnitride
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2003152641 DE10352641A1 (en) | 2003-11-11 | 2003-11-11 | Charge-trapping memory cell especially SONOS- and NROM- storage cells, has memory layer sequence for charge-trapping with memory zone between confinement layers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2003152641 DE10352641A1 (en) | 2003-11-11 | 2003-11-11 | Charge-trapping memory cell especially SONOS- and NROM- storage cells, has memory layer sequence for charge-trapping with memory zone between confinement layers |
Publications (1)
Publication Number | Publication Date |
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DE10352641A1 true DE10352641A1 (en) | 2005-02-17 |
Family
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DE2003152641 Ceased DE10352641A1 (en) | 2003-11-11 | 2003-11-11 | Charge-trapping memory cell especially SONOS- and NROM- storage cells, has memory layer sequence for charge-trapping with memory zone between confinement layers |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5408115A (en) * | 1994-04-04 | 1995-04-18 | Motorola Inc. | Self-aligned, split-gate EEPROM device |
WO1998006139A1 (en) * | 1996-08-01 | 1998-02-12 | Siemens Aktiengesellschaft | Non-volatile storage cell |
US5838041A (en) * | 1995-10-02 | 1998-11-17 | Kabushiki Kaisha Toshiba | Nonvolatile semiconductor memory device having memory cell transistor provided with offset region acting as a charge carrier injecting region |
WO1999065083A1 (en) * | 1998-06-12 | 1999-12-16 | Hitachi, Ltd. | Semiconductor integrated circuit device and method of its manufacture |
US20030053345A1 (en) * | 2000-10-27 | 2003-03-20 | Hiroyuki Moriya | Nonvolatile semiconductor storage device and production method therefor |
WO2003044868A1 (en) * | 2001-11-21 | 2003-05-30 | Sharp Kabushiki Kaisha | Semiconductor storage device, its manufacturing method and operating method, and portable electronic apparatus |
-
2003
- 2003-11-11 DE DE2003152641 patent/DE10352641A1/en not_active Ceased
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5408115A (en) * | 1994-04-04 | 1995-04-18 | Motorola Inc. | Self-aligned, split-gate EEPROM device |
US5838041A (en) * | 1995-10-02 | 1998-11-17 | Kabushiki Kaisha Toshiba | Nonvolatile semiconductor memory device having memory cell transistor provided with offset region acting as a charge carrier injecting region |
WO1998006139A1 (en) * | 1996-08-01 | 1998-02-12 | Siemens Aktiengesellschaft | Non-volatile storage cell |
WO1999065083A1 (en) * | 1998-06-12 | 1999-12-16 | Hitachi, Ltd. | Semiconductor integrated circuit device and method of its manufacture |
US20030053345A1 (en) * | 2000-10-27 | 2003-03-20 | Hiroyuki Moriya | Nonvolatile semiconductor storage device and production method therefor |
WO2003044868A1 (en) * | 2001-11-21 | 2003-05-30 | Sharp Kabushiki Kaisha | Semiconductor storage device, its manufacturing method and operating method, and portable electronic apparatus |
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