DE10347870A1 - Thermoplastic molding compositions comprise a polyamide with a piperidine compound-derived end-group and a copolymer with a functional group reactive with the polyamide end-group - Google Patents

Thermoplastic molding compositions comprise a polyamide with a piperidine compound-derived end-group and a copolymer with a functional group reactive with the polyamide end-group Download PDF

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Publication number
DE10347870A1
DE10347870A1 DE2003147870 DE10347870A DE10347870A1 DE 10347870 A1 DE10347870 A1 DE 10347870A1 DE 2003147870 DE2003147870 DE 2003147870 DE 10347870 A DE10347870 A DE 10347870A DE 10347870 A1 DE10347870 A1 DE 10347870A1
Authority
DE
Germany
Prior art keywords
group
polyamide
copolymer
alkyl
thermoplastic molding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE2003147870
Other languages
German (de)
Inventor
Martin Weber
Axel Gottschalk
Werner Haensel
Walter Heckmann
Hans Hoenl
Juergen Deininger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE2003147870 priority Critical patent/DE10347870A1/en
Priority to US10/595,337 priority patent/US20070106022A1/en
Priority to EP04790200A priority patent/EP1678257A1/en
Priority to PCT/EP2004/011255 priority patent/WO2005040281A1/en
Priority to KR1020067006689A priority patent/KR20060135620A/en
Publication of DE10347870A1 publication Critical patent/DE10347870A1/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3435—Piperidines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L35/06—Copolymers with vinyl aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A thermoplastic molding composition comprises (a) a polyamide containing an end-group derived from a specified piperidine compound; and (b) a specified copolymer containing a functional group which can react with the end-group in (a). A thermoplastic molding composition comprises (a) a polyamide containing an end-group derived from a piperidine compound of formula (I); and (b) a copolymer which is (i) a rubber-free statistical copolymer containing a styrene, a monomer with a group reacting with the end-group of polyamide (a) and a monomer with no groups reactive with (a); (ii) a 95-99.5/0.5-5 Y/X block copolymer with Y being a mixture of a styrene with an ethylenically unsaturated ester or with a monomer other than maleic anhydride and X being an alternating structure of a styrene and an acid and/or anhydride comonomer; or (iii) a rubber-free statistical copolymer of methyl methacrylate, an acid and/or anhydride comonomer and optionally also a (meth)acrylic ester. [Image] R : an amide-forming group R7> or a functional group containing 1-4 same or different amide-forming groups R7>; R1>H, 1-20C alkyl, cycloalkyl, benzyl or OR6> with R6> = H, 1-20C alkyl, cycloalkyl or benzyl; R2> - R5>1-10C alkyl; R7>-(NHR9>), carboxyl or a carboxylic acid derivative; and R9>H, 1-8C alkyl, 3-10C cycloalkyl or 2-20C alkylene.
DE2003147870 2003-10-10 2003-10-10 Thermoplastic molding compositions comprise a polyamide with a piperidine compound-derived end-group and a copolymer with a functional group reactive with the polyamide end-group Withdrawn DE10347870A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DE2003147870 DE10347870A1 (en) 2003-10-10 2003-10-10 Thermoplastic molding compositions comprise a polyamide with a piperidine compound-derived end-group and a copolymer with a functional group reactive with the polyamide end-group
US10/595,337 US20070106022A1 (en) 2003-10-10 2004-10-08 Thermoplastic molding compositions
EP04790200A EP1678257A1 (en) 2003-10-10 2004-10-08 Thermoplastic molding compositions
PCT/EP2004/011255 WO2005040281A1 (en) 2003-10-10 2004-10-08 Thermoplastic molding compositions
KR1020067006689A KR20060135620A (en) 2003-10-10 2004-10-08 Thermoplastic molding compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2003147870 DE10347870A1 (en) 2003-10-10 2003-10-10 Thermoplastic molding compositions comprise a polyamide with a piperidine compound-derived end-group and a copolymer with a functional group reactive with the polyamide end-group

Publications (1)

Publication Number Publication Date
DE10347870A1 true DE10347870A1 (en) 2005-05-04

Family

ID=34399519

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2003147870 Withdrawn DE10347870A1 (en) 2003-10-10 2003-10-10 Thermoplastic molding compositions comprise a polyamide with a piperidine compound-derived end-group and a copolymer with a functional group reactive with the polyamide end-group

Country Status (1)

Country Link
DE (1) DE10347870A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008101888A1 (en) * 2007-02-19 2008-08-28 Basf Se Molding compounds with reduced anisotropy regarding impact resistance
CN101265360B (en) * 2007-03-16 2013-01-30 上海普利特复合材料有限公司 High heat resistance nylon/acrylonitrile-butadiene-styrene resin mixing material

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008101888A1 (en) * 2007-02-19 2008-08-28 Basf Se Molding compounds with reduced anisotropy regarding impact resistance
KR20090123888A (en) * 2007-02-19 2009-12-02 바스프 에스이 Molding compounds with reduced anisotropy regarding impact resistance
US8119723B2 (en) 2007-02-19 2012-02-21 Styrolution GmbH Molding compounds with reduced anisotropy regarding impact resistance
CN101265360B (en) * 2007-03-16 2013-01-30 上海普利特复合材料有限公司 High heat resistance nylon/acrylonitrile-butadiene-styrene resin mixing material

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