DE10335510A1 - Coated catalyst carrier body - Google Patents

Coated catalyst carrier body Download PDF

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Publication number
DE10335510A1
DE10335510A1 DE10335510A DE10335510A DE10335510A1 DE 10335510 A1 DE10335510 A1 DE 10335510A1 DE 10335510 A DE10335510 A DE 10335510A DE 10335510 A DE10335510 A DE 10335510A DE 10335510 A1 DE10335510 A1 DE 10335510A1
Authority
DE
Germany
Prior art keywords
catalyst carrier
coating
carrier body
producing
acrolein
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE10335510A
Other languages
German (de)
Inventor
Torsten Balduf
De Oliveira Armin Lange
Werner Burkhardt
Guido Stochniol
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Stockhausen GmbH
Chemische Fabrik Stockhausen GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH, Stockhausen GmbH, Chemische Fabrik Stockhausen GmbH filed Critical Degussa GmbH
Priority to DE10335510A priority Critical patent/DE10335510A1/en
Priority to JP2006521544A priority patent/JP2007500588A/en
Priority to CNA2004800222834A priority patent/CN1832799A/en
Priority to ZA200601079A priority patent/ZA200601079B/en
Priority to BRPI0413096-0A priority patent/BRPI0413096A/en
Priority to PCT/EP2004/008590 priority patent/WO2005011858A1/en
Priority to EP04763669A priority patent/EP1648602A1/en
Priority to US10/566,453 priority patent/US20060276334A1/en
Publication of DE10335510A1 publication Critical patent/DE10335510A1/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/249—Plate-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/32—Packing elements in the form of grids or built-up elements for forming a unit or module inside the apparatus for mass or heat transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F3/00—Plate-like or laminated elements; Assemblies of plate-like or laminated elements
    • F28F3/12—Elements constructed in the shape of a hollow panel, e.g. with channels
    • F28F3/14—Elements constructed in the shape of a hollow panel, e.g. with channels by separating portions of a pair of joined sheets to form channels, e.g. by inflation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2453—Plates arranged in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2456—Geometry of the plates
    • B01J2219/2459—Corrugated plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2461—Heat exchange aspects
    • B01J2219/2462—Heat exchange aspects the reactants being in indirect heat exchange with a non reacting heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2477—Construction materials of the catalysts
    • B01J2219/2479—Catalysts coated on the surface of plates or inserts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2483—Construction materials of the plates
    • B01J2219/2485—Metals or alloys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/3221—Corrugated sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/32213—Plurality of essentially parallel sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322—Basic shape of the elements
    • B01J2219/32203—Sheets
    • B01J2219/32224—Sheets characterised by the orientation of the sheet
    • B01J2219/32227—Vertical orientation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32408—Metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32466—Composition or microstructure of the elements comprising catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/324—Composition or microstructure of the elements
    • B01J2219/32466—Composition or microstructure of the elements comprising catalytically active material
    • B01J2219/32475—Composition or microstructure of the elements comprising catalytically active material involving heat exchange

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Die Erfindung betrifft einen Katalysator-Trägerkörper (1), aufweisend eine Oberfläche (2), auf der eine mit der Oberfläche verbundene Beschichtung (3) vorgesehen ist, wobei die Beschichtung (3) Risse (4) mit einer Länge (5) aufweist, wobei diese Längen eine Gesamtrisslänge von mindestens 500 m/m·2· [Meter pro Quadratmeter] zeigen und wobei die Beschichtung (3) eine Haftzugfestigkeit von mindestens 500 N/m·2· [Newton pro Quadratmeter] aufweist. Solche Katalysator-Trägerkörper dienen der katalytischen Umsetzung von Reaktionspartner, beispielsweise bei der Partialoxidation von Propen und Acrolein zu Acrolein bzw. Acrylsäure. Die Erfindung betrifft weiterhin ein Verfahren zur Herstellung einer Beschichtung für einen Katalysator-Trägerkörper, ein Verfahren zur Herstellung eines organischen mindestens eine Doppelbindung und Sauerstoff aufweisenden Moleküls, ein Verfahren zur Herstellung eines wasserabsorbierenden Polymers, ein Verfahren zur Herstellung eines wasserabsorbierenden Hygieneartikels sowie chemische Produkte oder die Verwendung von (Meth)Acrylsäure in chemischen Produkten.The invention relates to a catalyst carrier body (1), comprising a surface (2) on which a coating (3) connected to the surface is provided, the coating (3) having cracks (4) with a length (5), these lengths exhibiting a total crack length of at least 500 m / m x 2 x [meter per square meter], and wherein the coating (3) has an adhesive tensile strength of at least 500 N / m x 2 x [Newton per square meter]. Such catalyst carrier bodies are used for the catalytic conversion of reactants, for example in the partial oxidation of propene and acrolein to acrolein or acrylic acid. The invention further relates to a process for the preparation of a coating for a catalyst carrier body, a process for producing an organic molecule having at least one double bond and oxygen, a process for producing a water-absorbing polymer, a process for producing a water-absorbent hygiene article and chemical products or the Use of (meth) acrylic acid in chemical products.

DE10335510A 2003-07-31 2003-07-31 Coated catalyst carrier body Ceased DE10335510A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DE10335510A DE10335510A1 (en) 2003-07-31 2003-07-31 Coated catalyst carrier body
JP2006521544A JP2007500588A (en) 2003-07-31 2004-07-30 Coated catalyst carrier
CNA2004800222834A CN1832799A (en) 2003-07-31 2004-07-30 Coated catalyst carrier body
ZA200601079A ZA200601079B (en) 2003-07-31 2004-07-30 Coated catalyst support body
BRPI0413096-0A BRPI0413096A (en) 2003-07-31 2004-07-30 coated catalyst support body, reactor comprising said catalyst support body and process for producing a catalyst support body coating
PCT/EP2004/008590 WO2005011858A1 (en) 2003-07-31 2004-07-30 Coated catalyst carrier body
EP04763669A EP1648602A1 (en) 2003-07-31 2004-07-30 Coated catalyst carrier body
US10/566,453 US20060276334A1 (en) 2003-07-31 2004-07-30 Coated catalyst support body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10335510A DE10335510A1 (en) 2003-07-31 2003-07-31 Coated catalyst carrier body

Publications (1)

Publication Number Publication Date
DE10335510A1 true DE10335510A1 (en) 2005-03-10

Family

ID=34111873

Family Applications (1)

Application Number Title Priority Date Filing Date
DE10335510A Ceased DE10335510A1 (en) 2003-07-31 2003-07-31 Coated catalyst carrier body

Country Status (8)

Country Link
US (1) US20060276334A1 (en)
EP (1) EP1648602A1 (en)
JP (1) JP2007500588A (en)
CN (1) CN1832799A (en)
BR (1) BRPI0413096A (en)
DE (1) DE10335510A1 (en)
WO (1) WO2005011858A1 (en)
ZA (1) ZA200601079B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005019000A1 (en) * 2005-04-22 2006-10-26 Degussa Ag Catalytically coated support, process for its preparation and thus equipped reactor and its use

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JP2008264766A (en) * 2007-03-29 2008-11-06 Nippon Shokubai Co Ltd Oxide catalyst, manufacturing method of acrolein or acrylic acid and manufacturing method of water-absorptive resin using acrylic acid
DE102008060888A1 (en) 2008-12-09 2010-06-10 Evonik Stockhausen Gmbh A process for producing acrolein comprising the processing of a crude glycerol phase
KR101297597B1 (en) * 2011-04-19 2013-08-19 한국화학연구원 Reactor system for producing hydrocarbons from synthetic gas
FR2975922B1 (en) 2011-06-06 2013-05-31 Arkema France PLATE REACTOR WITH INJECTION IN SITU
CN105150709B (en) * 2014-06-25 2017-12-29 上海宜瓷龙新材料股份有限公司 Bat printing or the construction method of silk-screen technology are used on a kind of ceramic coating
EP3266757B1 (en) 2016-07-08 2019-12-25 Evonik Operations GmbH Producing at least 1-hexene and octen from ethene
US10227279B2 (en) 2016-09-12 2019-03-12 Evonik Degussa Gmbh Dehydrogenation of LPG or NGL and flexible utilization of the olefins thus obtained
US10531174B2 (en) * 2016-10-13 2020-01-07 Bose Corporation Earpiece employing cooling and sensation inducing materials
US10602250B2 (en) 2016-10-13 2020-03-24 Bose Corporation Acoustaical devices employing phase change materials
US11253844B2 (en) 2018-03-14 2022-02-22 Evonik Operations Gmbh Oligomerization catalyst and process for the production thereof
US10882027B2 (en) 2018-03-14 2021-01-05 Evonik Operations Gmbh Process for producing an oligomerization catalyst
US10882028B2 (en) 2018-03-14 2021-01-05 Evonik Operations Gmbh Ni-containing catalyst for the oligomerization of olefins
US10850261B2 (en) 2018-03-14 2020-12-01 Evonik Operations Gmbh Oligomerization catalyst and process for the production thereof
CA3049521A1 (en) 2018-07-25 2020-01-25 Evonik Degussa Gmbh Process for oligomerization of butene with determination of the proportion of acidic catalysis
US20200166293A1 (en) * 2018-11-27 2020-05-28 Hamilton Sundstrand Corporation Weaved cross-flow heat exchanger and method of forming a heat exchanger
ES2953108T3 (en) 2019-01-08 2023-11-08 Evonik Operations Gmbh Procedure for removing polyunsaturated hydrocarbons from C4 hydrocarbon streams in the presence of mercaptan, disulfides and C5 hydrocarbons
US11186782B2 (en) 2019-01-08 2021-11-30 Evonik Operations Gmbh Catalyst and process for removing mercaptans from hydrocarbon streams
DE102019120862A1 (en) * 2019-08-01 2021-02-04 Benteler Automobiltechnik Gmbh Process for manufacturing a plate heat exchanger and plate heat exchanger
US11332421B2 (en) 2019-08-21 2022-05-17 Evonik Operations Gmbh Process for oligomerization of olefins with optimized distillation
US11254631B2 (en) 2019-08-21 2022-02-22 Evonik Operations Gmbh Process for oligomerization of olefins with optimized distillation
CN111569643A (en) * 2020-04-29 2020-08-25 江苏卓高环保科技有限公司 Composite purifying material for purifying PM2.5 formaldehyde and air purifier prepared from composite purifying material

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005019000A1 (en) * 2005-04-22 2006-10-26 Degussa Ag Catalytically coated support, process for its preparation and thus equipped reactor and its use
US7981830B2 (en) 2005-04-22 2011-07-19 Uhde Gmbh Catalyst-coated support, method for producing the same, reactor comprising the same and use thereof
US8227034B2 (en) 2005-04-22 2012-07-24 Evonik Degussa Gmbh Catalyst-coated support, method for producing the same, reactor comprising the same and use thereof

Also Published As

Publication number Publication date
EP1648602A1 (en) 2006-04-26
CN1832799A (en) 2006-09-13
BRPI0413096A (en) 2006-10-03
ZA200601079B (en) 2007-09-26
US20060276334A1 (en) 2006-12-07
JP2007500588A (en) 2007-01-18
WO2005011858A1 (en) 2005-02-10

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