DE10323941B4 - Process for the continuous production of continuous, optically imageable films, in particular webs and sheets of plastics - Google Patents

Process for the continuous production of continuous, optically imageable films, in particular webs and sheets of plastics Download PDF

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Publication number
DE10323941B4
DE10323941B4 DE10323941A DE10323941A DE10323941B4 DE 10323941 B4 DE10323941 B4 DE 10323941B4 DE 10323941 A DE10323941 A DE 10323941A DE 10323941 A DE10323941 A DE 10323941A DE 10323941 B4 DE10323941 B4 DE 10323941B4
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Germany
Prior art keywords
melt
plastic
belt
continuous
cooling plates
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Expired - Fee Related
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DE10323941A
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German (de)
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DE10323941A1 (en
Inventor
Michael Schröder
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Heinrich Friedrich Schroder KG
HEINRICH FRIEDRICH SCHROEDER K
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Heinrich Friedrich Schroder KG
HEINRICH FRIEDRICH SCHROEDER K
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D11/00Producing optical elements, e.g. lenses or prisms
    • B29D11/00009Production of simple or compound lenses
    • B29D11/00278Lenticular sheets
    • B29D11/00288Lenticular sheets made by a rotating cylinder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • B29C37/0067Using separating agents during or after moulding; Applying separating agents on preforms or articles, e.g. to prevent sticking to each other
    • B29C37/0075Using separating agents during or after moulding; Applying separating agents on preforms or articles, e.g. to prevent sticking to each other using release sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/22Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
    • B29C43/222Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length characterised by the shape of the surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/44Compression means for making articles of indefinite length
    • B29C43/48Endless belts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/05Filamentary, e.g. strands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911Cooling
    • B29C48/9135Cooling of flat articles, e.g. using specially adapted supporting means
    • B29C48/9145Endless cooling belts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/16Cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2021/00Use of unspecified rubbers as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2011/00Optical elements, e.g. lenses, prisms
    • B29L2011/0016Lenses
    • B29L2011/005Fresnel lenses

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Ophthalmology & Optometry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

Verfahren zur kontinuierlichen Herstellung von endlosen, optisch abbildungsfähigen Folien, insbesondere Bahnen und Platten aus Kunststoffen, mit folgenden Schritten;
Zubereitung einer Kunststoffschmelze in einem Extruder und Entnahme derselben als Schmelzenband aus der Breitschlitzdüse des Extruders, oder Erzeugung eines Schmelzenbandes durch Erwärmen eines vorgefertigten Kunststoffhalbzeuges und Überführung in den weichplastischen Zustand in einem Heizraum oder Heizkanal und
Weiterführung des Schmelzenbandes (9) in einen Kalander, wobei das Schmelzenband (9) zwischen zwei synchron laufenden, endlosen Bändern (1) und (2), vornehmlich aus Metall, nach gemeinsamen Teilumlauf der Formwalze (5) in eine mit zwei ebenen Kühlplatten (11) und (12) ausgetattete Kühlstation transportiert wird, in der das durchfahrende Schmelzenband unter Druck der Kühlplatten aus dem weichplastischen in den hartplastischen Zustand gebracht wird, wobei die Gravur des Gravurbandes (1) auf der Oberfläche des erstarrenden Schmelzenbandes abgeformt wird, wobei die zwischen den Kühlplatten (11), (12) durchgeführten Bänder jeweils auf einem Druckwasserfilm gleiten
Process for the continuous production of continuous, optically imageable films, in particular webs and sheets of plastics, with the following steps;
Preparation of a plastic melt in an extruder and removal of the same as a melt strip from the slot die of the extruder, or producing a melt ribbon by heating a prefabricated plastic semi-finished product and transfer to the soft plastic state in a boiler room or heating channel and
Continuation of the melt belt (9) in a calender, the melt belt (9) between two synchronously running, endless belts (1) and (2), mainly of metal, after common partial circulation of the forming roller (5) in a two-plane cooling plates ( 11) and (12) emptied cooling station is transported, in which the passing melt belt is brought under pressure of the cooling plates from the soft plastic in the hard plastic state, wherein the engraving of the gravure belt (1) is molded on the surface of the solidifying melt belt, the between each of the cooling plates (11), (12) passed belts on a pressurized water film

Figure 00000001
Figure 00000001

Description

Die Erfindung betrifft ein Verfahren zur kontinuierlichen Herstellung von endlosen, optisch abbildungsfähigen Folien, insbesondere Bahnen und Platten aus Kunststoffen.The The invention relates to a process for continuous production of endless, optically imageable films, in particular Webs and sheets of plastics.

In der deutschen Patentschrift DE 199 43 604 C2 ist ein Verfahren beschrieben welches ebenfalls die kontinuierliche Herstellung von endlosen, optisch abbildungsfähigen Folien, Bahnen und Platten aus Kunststoffen zum Inhalt hat wie auch die der Entgegenhaltungen in bezeichneter Patentschrift. Das angezogene, patentierte Verfahren setzt die Verwendung einer Gravurwalze voraus, die während einer Umderhung in einem definierten Durchgangsbereich auf die Temperatur der Kunststoffschmelze zu bringen und in einem weiteren, definierten Bereich auf Erstarrungstemperatur derselben abzusenken ist.In the German patent DE 199 43 604 C2 is a method described which also has the continuous production of endless, optically imageable films, sheets and plates made of plastics content as well as that of the references in said patent specification. The tightened, patented method requires the use of a gravure roll, which is to bring during a change in a defined passage area to the temperature of the plastic melt and lower in a further defined range to its solidification temperature.

Bei Bahnen und Platten mit Wandstärken über 1 mm sind thermische und rheologische Probeme zu bewältigen, die sich nur auf Kosten der Produktionswirtschaftlichkeit und Qualität der Produkte bedingt lösen lassen. Beispielsweise muß nach den bekannten Verfahren das wandstärkere Produkt vor der völligen Aushärtung im weichplastischen Zustand von der Gravurwalze abgenommen werden um es in der Planlage aushärten zu lassen. Dabei kommt es bei dem übergang des erstarrenden Schmelzenbandes aus der Rundung der Gravurwalze in die Planlage zur Stauchung der glatten Produktoberfläche und zur Streckung der strukturierten Fläche. Beim Ausgleich der Längendifferenz beider Flächen machen sich bei manchen Materialtypen der Schmelze Transmissionsbeeinträchtigungen bemerkbar. Je stärker das Schmelzenband bzw. das Endprodukt je größer ist die Differenz zwischen Stauchung und Streckung der sich gegenüberliegenden Oberflächen. Zudem ist die Abnahme des notwendigerweise noch weichplastischen Materials aus der formenden Gravur problematisch, da beim übergang der Kunststoffschmelze aus dem weichplastischen in den hartelastischen Zustand eine unkontrolierte Volumenkontraktion (Schwindung) zu eliminieren ist, die durch eine qualitätsmindernde Rundung spitzwinkeliger Strukturen in Erscheinung tritt.at Webs and panels with wall thicknesses greater than 1 mm There are thermal and rheological problems to deal with, which are only at the expense conditional on the production economy and quality of the products. For example, after the known method, the wall thicker product before complete curing in soft plastic state can be removed from the gravure roll around cure it in the flatness allow. It comes at the transition of the solidifying melt ribbon from the rounding of the gravure roll in the flat position for compression of the smooth product surface and for stretching the structured surface. When compensating the difference in length both surfaces With some types of material of the melt, transmission impairments occur noticeable. The stronger that Melt ribbon or the end product the larger the difference between Compression and extension of the opposite surfaces. moreover is the decrease of the necessarily soft plastic material from the forming engraving problematic, since the transition of the plastic melt the soft plastic in the hard elastic state an uncontrolled Volume contraction (shrinkage) is eliminated by a quality-reducing Rounding acute-angled structures appears.

Mit der Erfindung bedingt vergleichbare Verfahren zur Herstellung scharfkantig strukturierter Flächenprodukte aus Plaste sind u.a. in den Patentschriften JP 111 29 273 A und DE 198 45 652 A1 beschrieben, in denen jedoch nicht beschrieben ist wie die, bei der Erstarrung des Plastbandes (Schmelze) eintretende Materialkontraktion so eliminiert wird, daß eine Beeinträchtigung der optischen Wirkung des strukturierten Plastbandes absolut ausgeschlossen wird, die sich dadurch kennzeichnet, daß sich die scharfen Ausfomungen der abzubildenden Gravuren, beispielsweise prismatische Strukturen durch ungenügenden Nachdruck auf die erkaltende, kontraktierende Materialschmelze nicht ausreichend füllen. Demzufolge lag der Erfindung die Aufgabe zu Grunde die Vorrichtung zur Ausübung des Verfahrens zu befähigen, die Materialschwindung durch Anwendung hohen Druckes auf die erkaltende, kontraktierende Schmelze zu eliminieren. Diese Aufgabe wird durch ein Verfahren mit den Merkmalen des Patentanspruches 1 gelöst.With the invention conditionally comparable methods for producing sharp-edged structured surface products of plastic are, inter alia, in the patents JP 111 29 273 A and DE 198 45 652 A1 described in which, however, is not described as the, in the solidification of the plastic band (melt) entering material contraction is eliminated so that an impairment of the optical effect of the structured plastic band is absolutely excluded, which is characterized in that the sharp Ausfomungen of the imaged Engraving, for example prismatic structures, can not be sufficiently filled by insufficient emphasis on the cooling, contracting molten material. Accordingly, it was an object of the invention to enable the apparatus for practicing the method to eliminate material shrinkage by applying high pressure to the decaying, contracting melt. This object is achieved by a method having the features of claim 1.

Eine Ausgestaltung des Verfahrens ist dem Unteranspruch zu entnehmen.A Embodiment of the method is given in the dependent claim.

Auf der Zeichnung ist ein Ausführungsbeispiel der Vorrichtung zur Ausübung des erfindungsgemäßen Verfahrens dargestellt.On The drawing is an embodiment the device for exercise the method according to the invention shown.

Es bedeutenIt mean

1 Schemazeichnung eines Ausführungsbeispiels der Einrichtung zur Ausübung des erfindungsgemäßen Verfahrens der kontinuierlichen Herstellung abbildungsfähiger Folien, Bahnen und Platten aus Kunststoff. 1 Schematic drawing of an embodiment of the device for carrying out the method according to the invention of the continuous production of imageable films, sheets and plates made of plastic.

2 Stark vergrößerter Ausbruch gemäß dem Schnitt A,A des Ausführungsbeispiels der Kühleinrichtung nach 1. 2 Greatly enlarged outbreak according to the section A, A of the embodiment of the cooling device according to 1 ,

Aus der Breitschlitzdüse (8) fließt das Schmelzenband (9) zwischen das, die Formwalze (5) halb umschlingende Gravurband (1) und das, die Einlaufwalze (7) halb umschlingendes Spiegelband (2) und mit beiden Bändern zwischen die Kühlplatten (11) und (12), wobei das Schmelzenband (9) unter hohem Druck zum fertigen Produkt (4) aushärtet. Um das Bandpaket, bestehend aus dem Gravurband (1) und dem Schmelzenband (9), und dem Spiegelband (2) zwischen den, unter hohem gegeneinandeer gerichteten Druck stehenden Kühlplatten durchziehen zu können, wird erfindungsgemäß vorgerschlagen, das Kühlwasser durch Bohrungen (13) in den Kühlplatten, mit angepasstem Druck zwischen die gegeneinander pressenden Flächen zu bringen und die Reibung durch den eintretenden Aquaplaningeffekt der Druck- und Kühlwasserschicht (14) aufzuheben.From the slot die ( 8th ) flows the melt ribbon ( 9 ) between that, the molding roll ( 5 ) semi-wrap gravure tape ( 1 ) and that, the inlet roller ( 7 ) half-wrap mirror tape ( 2 ) and with both bands between the cooling plates ( 11 ) and ( 12 ), wherein the melt ribbon ( 9 ) under high pressure to the finished product ( 4 ) hardens. To the band package, consisting of the engraving tape ( 1 ) and the melt ribbon ( 9 ), and the mirror band ( 2 ) to be able to pull through between the, under high gegeneinandeer directed pressure cooling plates, according to the invention vorgerschlagen, the cooling water through holes ( 13 ) in the cooling plates to bring with adjusted pressure between the pressing surfaces against each other and the friction by the incoming aquaplaning effect of the pressure and cooling water layer ( 14 ).

11
Gravurbandengraved belt
22
Spiegelbandimage band
44
Produktproduct
55
Formwalzeforming roll
66
Ablaufwalzedelivery rolls
77
Einlaufwalzeinlet roller
88th
Breitschlitzdüseslot die
99
Schmelzenbandmelt ribbon
1010
Spannwalzetension roller
1111
Kühlplatte Acooling plate A
1212
Kühlplatte Bcooling plate B
1313
Kühl- und DruckwasserbohrungenCold and Pressure water holes
1414
Druck- und KühlwasserschichtPrint- and cooling water layer

Claims (2)

Verfahren zur kontinuierlichen Herstellung von endlosen, optisch abbildungsfähigen Folien, insbesondere Bahnen und Platten aus Kunststoffen, mit folgenden Schritten; Zubereitung einer Kunststoffschmelze in einem Extruder und Entnahme derselben als Schmelzenband aus der Breitschlitzdüse des Extruders, oder Erzeugung eines Schmelzenbandes durch Erwärmen eines vorgefertigten Kunststoffhalbzeuges und Überführung in den weichplastischen Zustand in einem Heizraum oder Heizkanal und Weiterführung des Schmelzenbandes (9) in einen Kalander, wobei das Schmelzenband (9) zwischen zwei synchron laufenden, endlosen Bändern (1) und (2), vornehmlich aus Metall, nach gemeinsamen Teilumlauf der Formwalze (5) in eine mit zwei ebenen Kühlplatten (11) und (12) ausgetattete Kühlstation transportiert wird, in der das durchfahrende Schmelzenband unter Druck der Kühlplatten aus dem weichplastischen in den hartplastischen Zustand gebracht wird, wobei die Gravur des Gravurbandes (1) auf der Oberfläche des erstarrenden Schmelzenbandes abgeformt wird, wobei die zwischen den Kühlplatten (11), (12) durchgeführten Bänder jeweils auf einem Druckwasserfilm gleitenProcess for the continuous production of continuous, optically imageable films, in particular webs and sheets of plastics, with the following steps; Preparation of a plastic melt in an extruder and removal thereof as a melt strip from the slot die of the extruder, or production of a melt ribbon by heating a prefabricated plastic semi-finished product and transfer to the soft plastic state in a heating chamber or heating channel and continuation of the melt ribbon ( 9 ) into a calender, the melt ribbon ( 9 ) between two synchronously running, endless bands ( 1 ) and ( 2 ), mainly of metal, after common partial circulation of the molding roll ( 5 ) into one with two flat cooling plates ( 11 ) and ( 12 ) cooled cooling station is transported, in which the passing melt ribbon is brought under pressure of the cooling plates from the soft plastic in the hard plastic state, wherein the engraving of the gravure belt ( 1 ) is molded on the surface of the solidifying melt belt, wherein the between the cooling plates ( 11 ) 12 ) each slide on a pressurized water film Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß der Druckwasserfilm auch zur Kühlung des Kunststoffschmelzenbandes dient.Method according to claim 1, characterized in that that the Druckwasserfilm also for cooling the Plastic melt ribbon serves.
DE10323941A 2003-05-27 2003-05-27 Process for the continuous production of continuous, optically imageable films, in particular webs and sheets of plastics Expired - Fee Related DE10323941B4 (en)

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20130136493A (en) * 2010-11-30 2013-12-12 애버리 데니슨 코포레이션 Cooling unit for microreplication
CN113580549B (en) * 2021-08-20 2022-03-11 安徽玺越新材料科技有限公司 Hot press unit is used in dull and stereotyped processing of FRP
CN116198067B (en) * 2023-05-05 2023-07-11 江苏明途新材料科技有限公司 Cooling device is used in reflective membrane production

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3329868A1 (en) * 1983-08-18 1985-03-07 Killar, Erich, 8000 München Device for embossing product webs made of thermoplastics material and process for producing the embossing tool
JPH11129273A (en) * 1997-10-29 1999-05-18 Ishikawajima Harima Heavy Ind Co Ltd Equipment for forming calendar
DE19845652A1 (en) * 1998-10-05 2000-04-13 Adolf Seide Apparatus for smoothing and cooling an extruded thermoplastic strip comprises components for effecting a surface of the strip comprising a base element, a metal band in contact with the strip, a roller, and a drive
DE19943604C2 (en) * 1999-09-11 2002-06-27 Schroeder Heinrich Friedrich Process for the continuous production of endless, optically imageable films, sheets and plates made of plastics and device for carrying out the process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3329868A1 (en) * 1983-08-18 1985-03-07 Killar, Erich, 8000 München Device for embossing product webs made of thermoplastics material and process for producing the embossing tool
JPH11129273A (en) * 1997-10-29 1999-05-18 Ishikawajima Harima Heavy Ind Co Ltd Equipment for forming calendar
DE19845652A1 (en) * 1998-10-05 2000-04-13 Adolf Seide Apparatus for smoothing and cooling an extruded thermoplastic strip comprises components for effecting a surface of the strip comprising a base element, a metal band in contact with the strip, a roller, and a drive
DE19943604C2 (en) * 1999-09-11 2002-06-27 Schroeder Heinrich Friedrich Process for the continuous production of endless, optically imageable films, sheets and plates made of plastics and device for carrying out the process

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