DE10304104B3 - Multi-layer composite film for surface coating of thin metal sheets has a metal layer between carrier film and facing layer which combines with a printed layer to look like brushed metal - Google Patents

Multi-layer composite film for surface coating of thin metal sheets has a metal layer between carrier film and facing layer which combines with a printed layer to look like brushed metal Download PDF

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Publication number
DE10304104B3
DE10304104B3 DE10304104A DE10304104A DE10304104B3 DE 10304104 B3 DE10304104 B3 DE 10304104B3 DE 10304104 A DE10304104 A DE 10304104A DE 10304104 A DE10304104 A DE 10304104A DE 10304104 B3 DE10304104 B3 DE 10304104B3
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Prior art keywords
layer
metal
film
carrier film
brushed
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DE10304104A
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German (de)
Inventor
Markus Dipl.-Ing. Hamulski
Leonidas Dipl.-Chem. Dr. Kiriazis
Dieter Homölle
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Mondi Gronau GmbH
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Nordenia Deutschland Gronau GmbH
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/14—Printing or colouring
    • B32B38/145—Printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F9/00—Designs imitating natural patterns
    • B44F9/10—Designs imitating natural patterns of metallic or oxidised metallic surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/584—Scratch resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/738—Thermoformability
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00—Metals, their alloys or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/10—Polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2333/00—Polymers of unsaturated acids or derivatives thereof
    • B32B2333/04—Polymers of esters
    • B32B2333/12—Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2509/00—Household appliances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/08—Cars

Landscapes

  • Laminated Bodies (AREA)

Abstract

A metal layer(12) is located between a polyolefin-based carrier film(6) and a facing layer(9) with a printed motif(10) on the inside and an adhesive coating(11) below. The metal layer is formed either by metallizing the carrier film, a metallized plastic film or a metal foil. The printed motif(10) forms a brushed metal sheet structure, which in conjunction with the metal layer gives the appearance of a brushed metal surface. The metal layer may be coated with adhesive(11) on both sides for bonding with the facing layer(9) and carrier film(6).

Description

Die Erfindung betrifft eine mehrschichtige Verbundfolie zur Oberflächenbeschichtung, insbesondere von Blechen, mit einem Schichtenaufbau bestehend aus zumindest
einer durch Koextrusion hergestellten polyolefinischen Trägerfolie, die eine unterseitige Haftvermittlerschicht auf der Basis von Polyolefinen oder Reaktionsharzen und mindestens eine weitere Schicht aus Polypropylen oder einem Polypropylen-Polyolefin-Mischpolymerisat aufweist, und
einer Folie aus einem linearen Polyester (PET) oder aus Polymethylmethacrylat (PMMA) als Deckschicht,
wobei die Deckschicht innenseitig mit einem Druckmotiv bedruckt und mittels einer Klebstoffschicht mit dem unterseitigen Material verbunden ist. Die beschriebene Verbundfolie dient der Oberflächenveredlung von Blechtafeln, Kunststoffplatten, Holzwerkstoffen und dergleichen, die nach ihrer Beschichtung durch Umformung und/oder spanende Bearbeitungen weiter verarbeitet werden. Die fest aufgebrachte Verbundfolie bildet eine dekorative und kratzfeste Oberfläche und ist ausreichend flexibel, so dass ein mit der Verbundfolie beschichtetes Material durch Biege- und Tiefziehverfahren umgeformt werden kann. Eine bevorzugte Anwendung der Verbundfolie ist die Beschichtung von Blechen, die beispielsweise im Automobilbau und bei der Herstellung von Haushaltsmaschinen zum Einsatz kommen.The invention relates to a multilayer composite film for surface coating, in particular of sheet metal, with a layer structure consisting of at least
a polyolefin carrier film produced by coextrusion, which has an underside adhesion promoter layer based on polyolefins or reactive resins and at least one further layer made of polypropylene or a polypropylene-polyolefin copolymer, and
a film made of a linear polyester (PET) or of polymethyl methacrylate (PMMA) as a top layer,
wherein the cover layer is printed on the inside with a print motif and is connected to the underside material by means of an adhesive layer. The composite film described is used for the surface finishing of metal sheets, plastic plates, wood-based materials and the like, which are further processed after being coated by forming and / or machining. The firmly applied composite film forms a decorative and scratch-resistant surface and is sufficiently flexible that a material coated with the composite film can be formed by bending and deep-drawing processes. A preferred application of the composite film is the coating of sheets, which are used, for example, in automobile construction and in the manufacture of household machines.

Eine mehrschichtige Verbundfolie des beschriebenen Aufbaus ist aus EP 0 795 398 B1 bekannt. Das Material kann sowohl in der Deckschicht als auch in der Trägerfolie transparent und/oder pigmentiert sein, wobei außerdem auch eine glänzende oder matte Außenfläche geschaffen werden kann. Bekannt ist es auch, die Deckschicht innenseitig oder außenseitig zu bedrucken oder zwischen der Trägerfolie und der Deckschicht eine Farbdruckschicht anzuordnen ( EP 0 522 240 A2 ). Die bekannten Verbundfo1ien bilden Beschichtungen, die den optischen Eindruck einer lackierten Fläche vermitteln und einer hochwertigen Lackierung gleichwertig sind.A multilayer composite film of the structure described is made EP 0 795 398 B1 known. The material can be transparent and / or pigmented both in the cover layer and in the carrier film, it also being possible to create a glossy or matt outer surface. It is also known to print on the inside or outside of the cover layer or to arrange a color print layer between the carrier film and the cover layer ( EP 0 522 240 A2 ). The well-known composite foils form coatings that give the visual impression of a painted surface and are equivalent to high-quality painting.

Im Modetrend liegen Geräte, die eine metallische Oberfläche aufweisen bzw. deren Oberfläche einer gebürsteten Aluminium oder Edelstahlfläche nachgebildet ist. Vor diesem Hintergrund liegt der Erfindung die Aufgabe zugrunde, eine Verbundfolie zur Oberflächenbeschichtung anzugeben, die den metallischen Charakter einer gebürsteten Metallfläche, insbesondere einer gebürsteten Edelstahlfläche, nachahmt.Devices that are in fashion trend a metallic surface have or the surface of one brushed Replicated aluminum or stainless steel surface is. Against this background, the invention is based on the object a composite film for surface coating specify the metallic character of a brushed Metal surface, in particular one brushed Stainless steel surface, imitated.

Ausgehend von einer mehrschichtigen Verbundfolie mit den eingangs beschriebenen Merkmalen wird die Aufgabe erfindungsgemäß dadurch gelöst, dass zwischen der polyolefinischen Trägerfolie und der Deckschicht eine Metallschicht angeordnet ist, die von einer Metallisierung der Trägerfolie gebildet wird oder aus einer metallischen Kunststofffolie oder einer Metallfolie besteht, und dass das Druckmotiv an der Innenseite der Deckschicht die Struktur eines gebürsteten Bleches nachbildet, wobei durch das Zusammenwirken des Druckmotivs und der Metallschicht die Optik einer gebürsteten Metalloberfläche erzeugt wird. Die Metallschicht verleiht der Oberfläche ihren metallischen Glanz. Das Druckmotiv besteht aus einer faserförmigen, in einer Richtung orientierten Struktur, durch welche die durch Bürsten erzeugte Rauhigkeit nachempfunden wird. Das Druckmotiv und die Metallschicht sind durch eine transparente Klebstoffschicht getrennt in unterschiedlichen Schichtenebenen angeordnet. Durch die beschriebene Schichtenanordnung wird ein räumlicher Effekt erzielt, der den typischen metallischen Charakter einer gebürsteten Metalloberfläche erzeugt. Durch die Trägerfolie ist die Verbundfolie ausreichend biegsam und flexibel, so dass das mit der Verbundfolie beschichtete Material durch Tiefziehen oder Kaltverformung weiterverarbeitet werden kann. Durch ihre Deckschicht aus PET oder PMMA ist die Oberfläche kratzfest und hart. Die Deckschicht kann matt oder glänzend ausgebildet werden.Starting from a multilayer Laminated film with the features described above becomes the task according to the invention solved, that between the polyolefinic base film and the top layer a metal layer is arranged by a metallization the carrier film is formed or from a metallic plastic film or There is metal foil, and that the print motif on the inside of the Replicates the structure of a brushed sheet, by the interaction of the print motif and the metal layer the look of a brushed metal surface is produced. The metal layer gives the surface its metallic sheen. The print motif consists of a fibrous, in a directional structure through which the through to brush generated roughness is modeled. The print motif and the metal layer are separated by a transparent adhesive layer in different layer levels arranged. The layer arrangement described creates a spatial Effect achieved the typical metallic character of a brushed metal surface generated. Through the carrier film the composite film is sufficiently flexible and flexible that the material coated with the composite film by deep drawing or Cold forming can be processed further. Through their top layer the surface made of PET or PMMA is scratch-resistant and hard. The top layer can be made matt or glossy.

Bevorzugte Ausführungen der erfindungsgemäßen Verbundfolie sind in den nachgeordneten Ansprüchen 2 bis 4 beschrieben und werden im Folgenden anhand von Ausführungsbeispielen erläutert. Es zeigen schematisch:Preferred embodiments of the composite film according to the invention are in the subordinate claims 2 to 4 are described and are described below using exemplary embodiments explained. They show schematically:

1 den Schichtenaufbau eines mit einer Verbundfolie beschichteten Substrates, 1 the layer structure of a substrate coated with a composite film,

2 und 3 weitere Ausgestaltungen der auf einem Substrat aufgebrachten Verbundfolie. 2 and 3 further configurations of the composite film applied to a substrate.

Das in den Figuren dargestellte Substrat 1 besteht aus einem Stahlblech 2, das mit einer Korrosionsschutzschicht 3 und einer rückseitigen Lackierung 4 versehen ist. Das Substrat 1 ist mit einer mehrschichtigen Verbundfolie 5 beschichtet. Diese besteht aus einer durch Koextrusion hergestellten polyolefinischen Trägerfolie 6, die eine unterseitige Haftvermittlerschicht 7 auf der Basis von Polyolefinen oder Reaktionsharzen und mindestens eine weitere Schicht 8 aus Polypropylen oder einem Polypropylen-Polyolefin-Mischpolymerisat aufweist, und einer Folie aus einem linearen Polyester (PET) oder aus Polymethylmethacrylat (PMMA) als Deckschicht 9. Die transparente Deckschicht 9 ist innenseitig mit einem Druckmotiv 10 bedruckt und mittels einer Klebstoffschicht 11 mit dem unterseitigen Material verbunden. Die Deckschicht 9 bildet eine harte, kratzfeste Oberfläche. Eine zusätzliche Lackierung der Oberfläche mit einem z. B. UV-beständigen Lack soll jedoch nicht ausgeschlossen sein. Zwischen der polyolefinischen Trägerfolie 6 und der Deckschicht 9 ist eine Metallschicht 12 angeordnet, die im Ausführungsbeispiel der 1 aus einer metallisierten Polyester- oder Polymethylmethacrylatfolie besteht, im Ausführungsbeispiel der 2 aus einer Aluminiumfolie besteht und im Ausführungsbeispiel der 3 von einer Metallisierung der Trägerfolie gebildet wird. In den Ausführungsbeispielen der 2 und 3 ist die Metallschicht mit jeweils einer Klebstoffschicht 11 mit der Deckschicht 9 und der polyolefinischen Trägerfolie 6 verbunden. Das an der Innenseite der Deckschicht vorgesehene Druckmotiv 10 bildet die Struktur eines gebürsteten Bleches nach. Dabei wird durch das Zusammenwirken des Druckmotivs 10 und der Metallschicht 12 die Optik einer gebürsteten Edelstahloberfläche erzeugt.The substrate shown in the figures 1 consists of a sheet steel 2 that with a corrosion protection layer 3 and a paint on the back 4 is provided. The substrate 1 is with a multilayer composite film 5 coated. This consists of a polyolefin carrier film produced by coextrusion 6 that have an underside of adhesion promoter layer 7 based on polyolefins or reactive resins and at least one additional layer 8th comprises polypropylene or a polypropylene-polyolefin copolymer, and a film made of a linear polyester (PET) or of polymethyl methacrylate (PMMA) as a covering layer 9 , The transparent top layer 9 is printed on the inside 10 printed and by means of an adhesive layer 11 connected to the underside material. The top layer 9 forms a hard, scratch-resistant surface. An additional painting of the surface with a z. B. UV-resistant paint should not be excluded. Between the polyolefini carrier film 6 and the top layer 9 is a layer of metal 12 arranged in the embodiment of the 1 consists of a metallized polyester or polymethyl methacrylate film, in the embodiment of 2 consists of an aluminum foil and in the embodiment of the 3 is formed by a metallization of the carrier film. In the embodiments of the 2 and 3 is the metal layer, each with an adhesive layer 11 with the top layer 9 and the polyolefinic base film 6 connected. The print motif provided on the inside of the cover layer 10 reproduces the structure of a brushed sheet. This is due to the interaction of the print motif 10 and the metal layer 12 creates the look of a brushed stainless steel surface.

Die Deckschicht 9 kann matt oder glänzend ausgebildet werden. Die polyolefinische Trägerfolie 6 besteht im Ausführungsbeispiel aus zwei Schichten 7, 8. Sie kann auch aus mehreren Schichten aus verschiedenen Polypropylenen oder Polypropylen-Polyolefinen-Mischpolymerisaten aufgebaut sein.The top layer 9 can be made matt or glossy. The polyolefinic carrier film 6 consists of two layers in the exemplary embodiment 7 . 8th , It can also be constructed from several layers of different polypropylenes or polypropylene-polyolefin copolymers.

Claims (4)

Mehrschichtige Verbundfolie zur Oberflächenbeschichtung, insbesondere von Blechen, mit einem Schichtenaufbau bestehend aus zumindest einer durch Koextrusion hergestellten polyolefinischen Trägerfolie (6), die eine unterseitige Haftvermittlerschicht (7) auf der Basis von Polyolefinen oder Reaktionsharzen und mindestens eine weitere Schicht (8) aus Polypropylen oder einem Polypropylen-Polyolefin-Mischpolymerisat aufweist, und einer Folie aus einem linearen Polyester (PET) oder aus Polymethylmethacrylat (PMMA) als Deckschicht (9), wobei die Deckschicht (9) innenseitig mit einem Druckmotiv (10) bedruckt und mittels einer Klebstoffschicht (11) mit dem unterseitigen Material verbunden ist, dadurch gekennzeichnet, dass zwischen der polyolefinischen Trägerfolie (6) und der Deckschicht (9) eine Metallschicht (12) angeordnet ist, die von einer Metallisierung der Trägerfolie gebildet wird oder aus einer metallisierten Kunststofffolie oder einer Metallfolie besteht, und dass das Druckmotiv (10) an der Innenseite der Deckschicht (9) die Struktur eines gebürsteten Bleches nachbildet, wobei durch das Zusammenwirken des Druckmotivs (10) und der Metallschicht (12) die Optik einer gebürsteten Metalloberfläche erzeugt wird.Multi-layer composite film for surface coating, in particular of sheet metal, with a layer structure consisting of at least one polyolefinic carrier film produced by coextrusion ( 6 ), which has an underside of adhesion promoter layer ( 7 ) based on polyolefins or reactive resins and at least one additional layer ( 8th ) made of polypropylene or a polypropylene-polyolefin copolymer, and a film made of a linear polyester (PET) or of polymethyl methacrylate (PMMA) as a cover layer ( 9 ), the top layer ( 9 ) inside with a print motif ( 10 ) printed and by means of an adhesive layer ( 11 ) is connected to the underside material, characterized in that between the polyolefinic carrier film ( 6 ) and the top layer ( 9 ) a metal layer ( 12 ) is arranged, which is formed by a metallization of the carrier film or consists of a metallized plastic film or a metal foil, and that the print motif ( 10 ) on the inside of the top layer ( 9 ) reproduces the structure of a brushed sheet, whereby the interaction of the print motif ( 10 ) and the metal layer ( 12 ) the look of a brushed metal surface is created. Verbundfolie nach Anspruch 1, dadurch gekennzeichnet, dass zwischen der Deckschicht (9) und der polyolefinischen Trägerfolie (6) eine metallisierte Folie aus Polyester (PET) oder Polymethylmethacrylat (PMMA) als Metallschicht (12) angeordnet ist, die mit jeweils einer Klebstoffschicht (11) mit der Deckschicht (9) und der polyolefinischen Trägerfolie (6) verbunden ist.Composite film according to claim 1, characterized in that between the cover layer ( 9 ) and the polyolefin carrier film ( 6 ) a metallized film made of polyester (PET) or polymethyl methacrylate (PMMA) as a metal layer ( 12 ) is arranged, each with an adhesive layer ( 11 ) with the top layer ( 9 ) and the polyolefin carrier film ( 6 ) connected is. Verbundfolie nach Anspruch 1, dadurch gekennzeichnet, dass zwischen der Deckschicht und der polyolefinischen Trägerfolie eine Aluminiumfolie als Metallschicht (12) angeordnet ist, die mit jeweils einer Klebstoffschicht (11) mit der Deckschicht (9) und der polyolefinischen Trägerfolie (6) verbunden ist.Composite film according to claim 1, characterized in that between the cover layer and the polyolefin carrier film, an aluminum film as the metal layer ( 12 ) is arranged, each with an adhesive layer ( 11 ) with the top layer ( 9 ) and the polyolefin carrier film ( 6 ) connected is. Verbundfolie nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Trägerfolie (6) aus mehreren Schichten aus verschiedenen Polypropylenen oder Polypropylen-Polyolefinen-Mischpolymerisaten besteht.Composite film according to one of claims 1 to 3, characterized in that the carrier film ( 6 ) consists of several layers of different polypropylenes or polypropylene-polyolefin copolymers.
DE10304104A 2003-01-31 2003-01-31 Multi-layer composite film for surface coating of thin metal sheets has a metal layer between carrier film and facing layer which combines with a printed layer to look like brushed metal Expired - Fee Related DE10304104B3 (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010001177A1 (en) 2010-01-25 2011-07-28 Robert Bosch GmbH, 70469 Film, useful as a packing material of lithium-ion cell or battery, comprises composite of a lower side and an upper side, a lower corrosion layer with an aluminum layer at lower side, a lower plastic layer, and an upper plastic layer
ITMI20100235A1 (en) * 2010-02-16 2011-08-17 Willcox Invest S A METAL SUBSTRATE COATED AND RELATED PREPARATION PROCEDURE
CN102390216A (en) * 2011-07-22 2012-03-28 惠州Tcl移动通信有限公司 Plastic shell with metallic appearance effect and method for realizing hardware wire-drawing hand feeling
CN102452434A (en) * 2010-11-03 2012-05-16 昆山市山山塑胶制品厂 Novel electric bicycle mud removing device
EP2979894A1 (en) * 2014-08-01 2016-02-03 Hueck Folien Ges.m.b.H Decorative film

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010001177A1 (en) 2010-01-25 2011-07-28 Robert Bosch GmbH, 70469 Film, useful as a packing material of lithium-ion cell or battery, comprises composite of a lower side and an upper side, a lower corrosion layer with an aluminum layer at lower side, a lower plastic layer, and an upper plastic layer
ITMI20100235A1 (en) * 2010-02-16 2011-08-17 Willcox Invest S A METAL SUBSTRATE COATED AND RELATED PREPARATION PROCEDURE
CN102452434A (en) * 2010-11-03 2012-05-16 昆山市山山塑胶制品厂 Novel electric bicycle mud removing device
CN102390216A (en) * 2011-07-22 2012-03-28 惠州Tcl移动通信有限公司 Plastic shell with metallic appearance effect and method for realizing hardware wire-drawing hand feeling
EP2979894A1 (en) * 2014-08-01 2016-02-03 Hueck Folien Ges.m.b.H Decorative film

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