DE102019217981A1 - Special care and surfactant combination for rinse off products - Google Patents

Abstract

The present invention relates to a rinse-off composition comprising - based in each case on the total proportion of the composition - a component a with a proportion of 0.01% by weight to 0.2% by weight, including at least one glycerol ester, one component b with a proportion of 2.0% by weight to 25.0% by weight, comprising at least one anionic surfactant and a component c with a proportion of 1.0% by weight to 18.0% by weight, comprising at least one amphoteric surfactant and its use in cleaning compositions.

Description

The present invention comprises a rinse-off composition and its use in cleaning products.

Rinse-off compositions are normally used to cleanse the (human) body, in particular the skin and / or keratinic fibers, such as, for example, the hair. In order to be able to effectively remove the dirt, these compositions normally contain a large amount of surfactants or surfactant mixtures, since these emulsify or solubilize the impurities to be removed and remove them from the body by rinsing with water.

Disadvantageously, rinse-off products with a high surfactant content have a drying effect and leave the skin feeling uncomfortable for the end user, whereas a surfactant content that is too low can result in the individual components in the composition being poorly emulsified or homogenized. This gives the product a tough to slimy consistency, which the user perceives as unpleasant and as a negative quality feature.

For this reason, there is a constant need to provide new rinse-off products that have excellent cleaning properties, do not unnecessarily dry out or irritate the body part to be cleaned and at the same time have a consistency that is pleasant for the end user.

It is therefore the object of the invention to provide a composition which combines good washing performance with care properties. Such compositions have good foaming behavior, good foam quality and quantity, a pleasant feeling on the skin during washing and drying, and good rinsing properties.

The object is achieved by a rinse-off composition comprising - in each case based on the total proportion of the composition -
a component a with a proportion of 0.01 wt .-% to 0.2 wt .-%, comprising at least one glycerol ester,
a component b in a proportion of 2.0% by weight to 25.0% by weight, comprising at least one anionic surfactant and
a component c in a proportion of 1.0% by weight to 18.0% by weight, comprising at least one amphoteric surfactant.

The rinse-off composition is preferably aqueous. Aqueous rinse-off composition for the purposes of the invention denotes a composition whose cosmetically acceptable carrier component is water, preferably distilled water, very particularly distilled water without hydrogen peroxide (H ₂ O ₂ ). The proportion of water in the rinse-off composition is preferably 55 to 98% by weight, particularly preferably 60 to 95% by weight, very particularly preferably 65 to 85% by weight, even more preferably 70 to 80% by weight. -%, based on the total proportion of the rinse-off composition.

In a particularly preferred embodiment of the invention, the rinse-off composition comprises so much water that the other components contained in the composition are made up to 100% by weight, based on the total weight of the rinse-off composition, also referred to as " ad. 100 ".

The sum of all components of the rinse-off composition is 100% by weight, based on the total proportion of the rinse-off composition.

Component a is preferred, the at least one glycerol ester selected from glycerol mono- and / or diesters of glycerol with linear or branched, saturated or unsaturated C5-C24 carboxylic acids and mixtures thereof.

The glycerol is preferably esterified with one or two branched or unbranched, saturated or unsaturated C5-24 carboxylic acids, particularly preferably C6-20 carboxylic acids, very particularly preferably C8-16 carboxylic acids, even more preferably C9-14 carboxylic acids. In a preferred embodiment, the remaining hydroxyl groups of the glycerol ester which are not esterified with any fatty acid are free. Preferred carboxylic acids are selected from caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palm oleic acid, stearic acid, isostearic acid, oleic acid, Elaidic acid, petroselinic acid, linoleic acid, linolenic acid, eleostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid mixtures thereof, particularly preferably from caprylic acid, lauric acid and myristic acid, even more preferably from lauric acid.

The rinse-off composition preferably has monoesters of glycerol with a branched or unbranched, saturated or unsaturated C5-24 carboxylic acid, particularly preferably C6-20 carboxylic acid, very particularly preferably C8-16 carboxylic acid, even more preferably C9-14 carboxylic acid. Carboxylic acid. This carboxylic acid is preferably selected from caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palm oleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselic acid, linoleic acid, linolenic acid, elaeosteic acid, and also elaeosteic acid mixtures thereof, particularly preferably from caprylic acid, lauric acid and myristic acid, even more preferably from lauric acid. Glyceryl laurate, glyceryl palmitate, glyceryl stearate, glyceryl isostearate, glyceryl oleate and glyceryl behenate, which have a monoglyceride content in the range from 50 to 95, preferably 60 to 90% by weight, are also preferred.

In a preferred embodiment, the remaining hydroxyl groups of the glycerol ester which are not esterified with any fatty acid are free. The ester bond is preferably formed with a terminal hydroxyl group of glycerol.

The glyceryl ester is preferred as a mixture with at least one amphoteric surfactant, preferably cocoamidopropyl betaine (INCI). Such mixtures are commercially available, for example under the trade name ANTIL® HS 60.

Component a, the at least one glycerol ester, glyceryl laurate, is preferred.
Component b is preferred, the at least one anionic surfactant selected from alkyl sulfates, alkyl ether sulfates, alkane sulfonates, alkylbenzenesulfonates, olefin sulfonates and mixtures thereof.

• - lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen (Seifen),
• - Ethercarbonsäuren der Formel R-O-(CH2-CH2O)x-CH2-COOH, in der R eine lineare Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 16 ist,
• - Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe,
• - Acyltauride mit 8 bis 24 C-Atomen in der Acylgruppe,
• - Acylisethionate mit 8 bis 24 C-Atomen in der Acylgruppe,
• - Sulfobernsteinsäuremono- und -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremonoalkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkyl-gruppe und 1 bis 6 Oxyethylgruppen,
• - lineare Alkansulfonate mit 8 bis 24 C-Atomen,
• - lineare Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen,
• - Alpha-Sulfofettsäuremethylester von Fettsäuren mit 8 bis 30 C-Atomen,
• - Alkylsulfate und Alkylpolyglykolethersulfate der Formel R-O(CH2-CH2O)x-OSO3H, in der R eine bevorzugt lineare Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 12 ist,
• - Gemische oberflächenaktiver Hydroxysulfonate gemäß DE-A-37 25 030 ,
• - sulfatierte Hydroxyalkylpolyethylen- und/oder Hydroxyalkylenpropylenglykolether gemäß DE-A-37 23 354 ,
• - Sulfonate ungesättigter Fettsäuren mit 8 bis 24 C-Atomen und 1 bis 6 Doppelbindungen gemäß DE-A-39 26 344 ,
• - Ester der Weinsäure und Zitronensäure mit Alkoholen, die Anlagerungsprodukte von etwa 2-15 Molekülen Ethylenoxid und/oder Propylenoxid an Fettalkohole mit 8 bis 22 C-Atomen darstellen,
• - Alkyl- und/oder Alkenyletherphosphate der Formel (I),
  
  in der R29 bevorzugt für einen aliphatischen Kohlenwasserstoffrest mit 8 bis 30 Kohlenstoffatomen, R30 für Wasserstoff, einen Rest (CH2CH2O)nR29 oder X, n für Zahlen von 1 bis 10 und X für Wasserstoff, ein Alkali- oder Erdalkalimetall oder NR31 R32R33R34, mit R31 bis R34 unabhängig voneinander stehend für einen C1 bis C4 - Kohlenwasserstoffrest, steht,
• - sulfatierte Fettsäurealkylenglykolester der Formel (II) R35CO(AlkO)nSO3M Formel (II) in der R35CO- für einen linearen oder verzweigten, aliphatischen, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22 C-Atomen, Alk für CH2CH2, CHCH3CH2 und/oder CH2CHCH3, n für Zahlen von 0,5 bis 5 und M für ein Kation steht, wie sie in der DE-OS 197 36 906.5 beschrieben sind,
• - Monoglyceridsulfate und Monoglyceridethersulfate der Formel (III) wie sie beispielsweise in der EP-B1 0 561 825 , der EP-B1 0 561 999 , der DE-A1 42 04 700 oder von A.K.Biswas et al. in J.Am.Oil.Chem.Soc. 37, 171 (1960) und F.U.Ahmed in J.Am.Oil.Chem.Soc. 67, 8 (1990) beschrieben worden sind:
  
  in der R36CO für einen linearen oder verzweigten Acylrest mit 6 bis 22 Kohlenstoffatomen, x, y und z in Summe für 0 oder für Zahlen von 1 bis 30, vorzugsweise 2 bis 10, und X für ein Alkali- oder Erdalkalimetall steht. Typische Beispiele für im Sinne der Erfindung geeignete Monoglycerid(ether)sulfate sind die Umsetzungsprodukte von Laurinsäuremonoglycerid, Kokosfettsäuremonoglycerid, Palmitinsäuremonoglycerid, Stearinsäuremonoglycerid, Ölsäuremonoglycerid und Talgfettsäuremonoglycerid sowie deren Ethylenoxidaddukte mit Schwefeltrioxid oder Chlorsulfonsäure in Form ihrer Natriumsalze. Vorzugsweise werden Monoglyceridsulfate der Formel (III) eingesetzt, in der R36CO für einen linearen Acylrest mit 8 bis 18 Kohlenstoffatomen steht.

Suitable anionic surfactants in rinse-off compositions according to the invention are all anionic surface-active substances suitable for use on the human body.
These are characterized by a water-solubilizing, anionic group such as. B. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group with about 8 to 30 carbon atoms. In addition, the molecule can contain glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups. Examples of suitable anionic surfactants are, in each case in the form of the sodium, potassium and ammonium as well as the mono-, di- and trialkanolammonium salts with 2 to 4 carbon atoms in the alkanol group,

• - linear and branched fatty acids with 8 to 30 carbon atoms (soaps),
• - ether carboxylic acids of the formula RO- (CH2-CH2O) x-CH2-COOH, in which R is a linear alkyl group with 8 to 30 carbon atoms and x = 0 or 1 to 16,
• - acyl sarcosides with 8 to 24 carbon atoms in the acyl group,
• - acyl taurides with 8 to 24 carbon atoms in the acyl group,
• - acyl isethionates with 8 to 24 carbon atoms in the acyl group,
• - sulfosuccinic acid mono- and dialkyl esters with 8 to 24 carbon atoms in the alkyl group and sulfosuccinic acid monoalkyl polyoxyethyl esters with 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups,
• - linear alkanesulfonates with 8 to 24 carbon atoms,
• - linear alpha-olefin sulfonates with 8 to 24 carbon atoms,
• - Alpha-sulfofatty acid methyl esters of fatty acids with 8 to 30 carbon atoms,
• - Alkyl sulfates and alkyl polyglycol ether sulfates of the formula RO (CH2-CH2O) x-OSO3H, in which R is a preferably linear alkyl group with 8 to 30 carbon atoms and x = 0 or 1 to 12,
• - Mixtures of surface-active hydroxysulfonates according to DE-A-37 25 030 ,
• - Sulphated hydroxyalkyl polyethylene and / or hydroxyalkylene propylene glycol ethers according to DE-A-37 23 354 ,
• - Sulphonates of unsaturated fatty acids with 8 to 24 carbon atoms and 1 to 6 double bonds according to DE-A-39 26 344 ,
• - Esters of tartaric acid and citric acid with alcohols which are adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols with 8 to 22 carbon atoms,
• - alkyl and / or alkenyl ether phosphates of the formula (I),
  
  in R29 preferably for an aliphatic hydrocarbon radical with 8 to 30 carbon atoms, R30 for hydrogen, a radical (CH2CH2O) nR29 or X, n for numbers from 1 to 10 and X for hydrogen, an alkali or alkaline earth metal or NR31 R32R33R34, with R31 to R34, independently of one another, represent a C1 to C4 hydrocarbon radical,
• - sulfated fatty acid alkylene glycol esters of the formula (II) R35CO (AlkO) nSO3M Formula (II) in R35CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical with 6 to 22 carbon atoms, Alk for CH2CH2, CHCH3CH2 and / or CH2CHCH3, n for numbers from 0.5 to 5 and M for a cation stands as it is in the DE-OS 197 36 906.5 are described
• - Monoglyceride sulfates and monoglyceride ether sulfates of the formula (III) as they are, for example, in the EP-B1 0 561 825 , the EP-B1 0 561 999 , the DE-A1 42 04 700 or by AKBiswas et al. in J.Am.Oil.Chem.Soc. 37, 171 (1960) and FUAhmed in J.Am.Oil.Chem.Soc. 67, 8 (1990) have been described:
  
  in which R36CO stands for a linear or branched acyl radical with 6 to 22 carbon atoms, x, y and z in total for 0 or for numbers from 1 to 30, preferably 2 to 10, and X stands for an alkali or alkaline earth metal. Typical examples of monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts in the form of their sodium sulfonic acid or their sodium sulfonic acid adducts. Preference is given to using monoglyceride sulfates of the formula (III) in which R36CO is a linear acyl radical having 8 to 18 carbon atoms.

Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids with 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule and sulfosuccinic acid mono- and dialkyl esters with 8 to 18 carbon atoms in the alkyl group and sulfosuccinic acid monoalkyl polyoxyethyl esters with 8 to 18 carbon atoms Atoms in the alkyl group and 1 to 6 oxyethyl groups.
Particularly preferred anionic surfactants are straight-chain or branched alkyl ether sulfates which contain an alkyl radical with 8 to 18 and in particular with 10 to 16 carbon atoms and 1 to 6 and in particular 2 to 4 ethylene oxide units, preferably sodium lauryl ether sulfate with 2 ethylene oxide units.
Further particularly preferred anionic surfactants are straight-chain or branched alkyl sulfates which contain an alkyl radical with 8 to 18 and in particular with 10 to 16 carbon atoms. The sodium, magnesium and / or triethanolamine salts of linear or branched lauryl, tridecyl and / or myristyl sulfates are particularly preferred.

Component c is preferred, the at least one amphoteric surfactant selected from alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines, sulfobetaines and mixtures thereof.

Amphoteric or zwitterionic surfactants carry both a cationic and an anionic charge in the molecule. Amphoteric surfactants preferably have at least one quaternary ammonium group and at least one —COO (-) or —SO3 (-) group, in addition to a preferably C8-C24 alkyl or acyl group, in the molecule. They are also able to form internal salts. Particularly preferred amphoteric surfactants are betaines such as the N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyl-dimethylammonium glycinate, N-acyl-aminopropyl-N, N-dimethylammonium glycinate, for example cocoacylaminopropyl-dimethylammonium glycinate, and 2-alkyl-3-alkyl -carboxymethyl-3-hydroxyethyl-imidazolines, each with 8 to 18 carbon atoms in the alkyl or acyl group, and cocoacylaminoethylhydroxyethylcarboxymethylglycinate. A preferred amphoteric surfactant is the fatty acid amide derivative known under the INCI name Cocamidopropyl Betaine. With regard to the structure and manufacture of these substances, reference should be made to relevant reviews, for example J.Falbe (ed.), “Surfactants in Consumer Products”, Springer Verlag, Berlin, 1987, pp. 54-124 or J.Falbe (ed.), “Catalysts, Tenside and Mineral Oil Additives”, Thieme Verlag, Stuttgart, 1978, pp. 123-217 referenced.

The amphoteric surfactant in a mixture with a glyceryl ester, component a, is particularly preferred. Such mixtures are commercially available, for example under the trade name ANTIL® HS 60.

In a particularly preferred embodiment of the invention, the rinse-off composition comprises, as component a, the glycerol ester, glyceryl laurate, as component b, the anionic surfactant, sodium lauryl ether sulfate and, as component c, the amphoteric surfactant cocoamidopropyl betaine.

Component a is preferred, the at least one glycerol ester, with a proportion of 0.01 to 0.17% by weight, preferably 0.02 to 0.15% by weight, particularly preferably 0.03 to 0.14% by weight. -%, even more preferably 0.04 to 0.13% by weight, based on the total proportion of the composition, contained in the composition.

Component b is preferred, the at least one anionic surfactant, with a proportion of 2.5 to 20.0% by weight, preferably 3.0 to 15.0% by weight, particularly preferably 3.5 to 14.0% by weight .-%, even more preferably 4.0 to 11.0% by weight, based on the total proportion of the composition, contained in the composition.

Component c, the at least one amphoteric surfactant, with a proportion of 1.2 to 16.0% by weight, preferably 1.5 to 13.0% by weight, particularly preferably 1.8 to 9.0% by weight, is preferred .-%, even more preferably 2.0 to 5.0% by weight, based on the total proportion of the composition, contained in the composition.

The total proportion of the amphoteric surfactants in the composition is preferably 1.0 to 21.0% by weight, preferably 1.3 to 18.0% by weight, particularly preferably 1.5 to 16.0% by weight, still more preferably 2.0 to 12.0% by weight, based on the total proportion of the composition.

The ratio of component b, the at least one anionic surfactant, to the total amount of amphoteric surfactants in the composition is preferably 1: 1 to 4.5: 1, preferably 1.5: 1 to 4: 1, very particularly preferably 1.9: 1 to 3.5: 1, more preferably 2.1: 1 to 3: 1.

The composition preferably has a viscosity from 3000 mPas to 16000 mPas, preferably from 3500 mPas to 14000 mPas, particularly preferably from 4000 mPas to 13000 mPas, even more preferably from 5000 mPas to 11000 mPas, (each measured with a Haake rotary viscometer VT550; 20 ° C; measuring device MV; spindle MV II; 8 RPM).

The composition preferably contains further components different from components a, b and c selected from surfactants, preservatives, humectants, pH adjustment agents, care products, dyes, conditioning agents, perfumes and mixtures of these.

In a particular embodiment of the invention, the rinse-off composition can additionally contain nonionic, anionic, cationic and / or amphoteric or amphoteric surfactants which differ from components b and c. Examples of anionic surfactants are soaps, alkylbenzenesulfonates, alkanesulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, α-methyl ester sulfonates, Sulfocarboxylic acids, alkyl sulfates, fatty alcohol ether sulfates, Glycerol ether, Hydroxymischethersulfate, monoglyceride (ether) sulfates, fatty acid amide (ether) sulfates, mono- and dialkyl sulfosuccinates, mono- and dialkyl sulfosuccinamates, Sulfotriglycerid, amide soaps, ether carboxylic acids and salts thereof, fatty acid taurides, N Acylamino acids, such as acyl lactylates, acyl tartrates, acyl glutamates and acyl aspartates, alkyl oligoglucoside sulfates, protein fatty acid condensates (in particular vegetable products based on wheat) and alkyl (ether) phosphates. If the anionic surfactants contain polyglycol ether chains, these can have a conventional, but preferably a narrow, homolog distribution. Examples of nonionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, mixed ethers or mixed formals, optionally partially oxidized alk (en) yloligoglycosides, if appropriate, partially oxidized alk (en) yloligoglycosides, plant-based alkyl, fatty acid-based products, protein-based, fatty acid-based products, fatty acid derivatives or glucoronic acid derivatives Polyol fatty acid esters, sugar esters, sorbitan esters, polysorbates and amine oxides. If the nonionic surfactants contain polyglycol ether chains, these can have a conventional, but preferably a narrow, homolog distribution. Examples of cationic surfactants are quaternary ammonium compounds and esterquats, in particular quaternized fatty acid trialkanolamine ester salts. Typical examples of amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines. The surfactants mentioned are exclusively known compounds. With regard to the structure and production of these substances, reference should be made to relevant reviews, for example J.Falbe (ed.), “Surfactants in Consumer Products”, Springer Verlag, Berlin, 1987, pp. 54-124 or J.Falbe (ed.), “Catalysts, Tenside und Mineralöladditive”, Thieme Verlag, Stuttgart, 1978 , Pp. 123-217 referenced.

The proportion of the additional surfactants, in particular the amphoteric surfactants, in the rinse-off composition is preferably 0.05 to 5.5% by weight, particularly preferably 0.1 to 3.5% by weight, very particularly preferably 0.2 up to 3.5% by weight, based on the total proportion of the rinse-off composition.

Furthermore, the rinse-off composition can contain agents for adjusting the pH. Preferred agents are, for example, primary amino alcohols such as aminomethyl propanol (INCI), which is commercially available for example under the name AMP- ^ULTRA® PC, for example AMP- ^ULTRA® PC 2000. Further agents for adjusting the pH can be selected from alkali hydroxides , in particular sodium hydroxide and potassium hydroxide, organic acids such as lactic acid, citric acid, hydrochloric acid, sulfuric acid, phosphoric acid, adipic acid, hydroxysuccinic acid, succinic acid, tartaric acid or malic acid, especially from tetrahydroxypropyl ethylenediamine, known under the trade names Neutral TE and triethylamine (TEA).

The proportion of agents for pH adjustment in the rinse-off composition is preferably 0.01 to 1.0% by weight, particularly preferably 0.05 to 0.9% by weight, very particularly preferably 0.05 to 0 , 8% by weight, based on the total proportion of the rinse-off composition.

The rinse-off composition can additionally contain a conditioning agent such as a natural oil, selected from, for example, jojoba oil, almond oil, olive oil, grape seed oil, hemp oil, soybean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, castor oil, corn oil, rapeseed oil, sesame oil, safflower oil, wheat germ oil , Peach kernel oil, which contain liquid portions of coconut oil and mixtures thereof.

The proportion of conditioning agents in the rinse-off composition is preferably 0.01 to 5.0% by weight, particularly preferably 0.05 to 3.0% by weight, very particularly preferably 0.1 to 1.0% by weight. -%, based on the total proportion of the rinse-off composition.

Furthermore, the rinse-off composition can contain a preservative, in particular those specified in the Regulation on cosmetic products in Annex V (Regulation (EC) No. 122 + 3/2009 of the European Parliament and of the Council of 30 November 2009 on cosmetic products) are shown, particularly preferably benzoic acid and benzoates and mixtures thereof.
The proportion of preservatives in the rinse-off composition is preferably 0.05 to 1.0% by weight, particularly preferably 0.075 to 0.6% by weight, very particularly preferably 0.1 to 0.4% by weight , based on the total proportion of the rinse-off composition.

Preferably the rinse-off composition is used in a cleaning composition. Preferred cleaning compositions are shampoos, shower gels, hair conditioners, shaving products, such as shaving foam and shaving gel, as well as soaps and bath additives.

Embodiments

Some further preferred rinse-off compositions can be found in the following tables (data in% by weight based on the total weight of the rinse-off composition, unless stated otherwise). component formula 1 Formula 2 Formula 3 Formula 4 Formula 5 Glycerol ester 0.01-0.2 0.01-0.17 0.02-0.15 0.03-0.14 0.05-0.13 anionic surfactant 2.0-25.0 2.5-20.0 3.0-15.0 3.5-14.0 4.0-11.0 amphoteric surfactant 1.0-18.0 1.2-16.0 1.5-13.0 1.8-9.0 2.0-5.0 optional components and distilled water ad. 100 ad.100 ad. 100 ad. 100 ad. 100 component Formula 6 Formula 7 Formula 8 Formula 9 Formula 10 Glyceryl laurate 0.01-0.2 0.01-0.17 0.02-0.15 0.03-0.14 0.05-0.13 anionic surfactant 2.0-25.0 2.5-20.0 3.0-15.0 3.5-14.0 4.0-11.0 amphoteric surfactant 1.0-18.0 1.2-16.0 1.5-13.0 1.8-9.0 2.0-5.0 optional components and distilled water ad.100 ad. 100 ad. 100 ad. 100 ad. 100 component Formula 11 Formula 12 Formula 13 Formula 14 Formula 15 Glyceryl laurate 0.01-0.2 0.01-0.17 0.02-0.15 0.03-0.14 0.05-0.13 Sodium leuyl sulfate (SLS) 2.0-25.0 2.5-20.0 3.0-15.0 3.5-14.0 4.0-11.0 amphoteric surfactant 1.0-18.0 1.2-16.0 1.5-13.0 1.8-9.0 2.0-5.0 optional components and distilled water ad.100 ad. 100 ad. 100 ad. 100 ad. 100 component Formula 16 Formula 17 Formula 18 Formula 19 Formula 20 Glycerol ester 0.01-0.2 0.01-0.17 0.02-0.15 0.03-0.14 0.05-0.13 anionic surfactant 2.0-25.0 2.5-20.0 3.0-15.0 3.5-14.0 4.0-11.0 Cocoamidopropyl betaine 1.0-18.0 1.2-16.0 1.5-13.0 1.8-9.0 2.0-5.0 optional components 0.01-3.0 0.05 - 2.0 0.1-1.5 0.5-1.3 0.9 - 1.2 distilled water ad.100 ad. 100 ad. 100 ad. 100 ad.100 component Formula 16 Formula 17 Formula 18 Formula 19 Formula 20 Glycerol ester 1.3 - 7.5 1.8-5.5 2.5-4.5 2.7-4.0 2.8-3.5 Sodium leuyl sulfate (SLS) 0.2 - 6.5 0.7-5.0 1.3-3.5 1.5-3.0 1.9 - 2.5 Cocoamidopropyl betaine 0.03-1.3 0.06-0.9 0.09-0.85 0.15-0.7 0.25-0.04 optional components 0.01-3.0 0.05 - 2.0 0.1-1.5 0.5-1.3 0.9 - 1.2 distilled water ad.100 ad. 100 ad. 100 ad. 100 ad.100 component Formula 17 Formula 18 Formula 19 Formula 20 Formula 21 ANTIL® HS 60 0.05-1.5 0.1-1.0 0.15-0.8 0.2-0.5 0.3 Cocoamidopropyl betaine, 37%, acidic 3.0-15.0 5.0 - 12.0 6.5-10.5 7.0-9.5 8.5 FAEOS-Na C12-14 2EO 70% 6.0-20.0 9.0-18.0 11.0-16.0 11.5-14.5 13.0 Sodium hydroxide 50% standard 0.01-1.0 0.04-0.6 0.08-0.3 0.1-0.2 0.13 Citric acid dry, fine granules 0.01-1.5 0.05-1.0 0.1-0.7 0.15-0.5 0.3 Sodium benzoate 0.01-1.0 0.05-0.9 0.07-0.6 0.1-0.4 0.2 Sodium salicylate 0.01-1.0 0.05-0.9 0.07-0.6 0.1-0.4 0.2 Sodium chloride 0.01-1.0 0.05-0.9 0.07-0.6 0.1-0.4 0.2 distilled water, without H ₂ O ₂ ad.100 ad. 100 ad. 100 ad. 100 ad. 100

QUOTES INCLUDED IN THE DESCRIPTION

This list of the documents listed by the applicant was generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Patent literature cited

• DE 3725030 A [0016]
• DE 3723354 A [0016]
• DE 3926344 A [0016]
• DE 197369065 [0016]
• EP 0561825 B1 [0016]
• EP 0561999 B1 [0016]
• DE 4204700 A1 [0016]

Non-patent literature cited

• Verlag, Berlin, 1987, pp. 54-124 or J.Falbe (ed.), "Catalysts, Tenside and Mineral Oil Additives", Thieme Verlag, Stuttgart, 1978, pp. 123-217 [0019]
• J.Falbe (ed.), “Surfactants in Consumer Products”, Springer Verlag, Berlin, 1987, pp. 54-124 or J.Falbe (ed.), “Catalysts, Tenside und Mineralöladditive”, Thieme Verlag, Stuttgart, 1978 , Pp. 123-217 [0029]

Claims (10)

Rinse-off composition comprising - each based on the total proportion of the composition - a component a with a proportion of 0.01 wt .-% to 0.2 wt .-%, comprising at least one glycerol ester, a component b in a proportion of 2.0% by weight to 25.0% by weight, comprising at least one anionic surfactant and a component c in a proportion of 1.0% by weight to 18.0% by weight, comprising at least one amphoteric surfactant. Rinse-off composition after Claim 1 , characterized in that component a, the at least one glycerol ester, is selected from glycerol mono- and / or diesters of glycerol with linear or branched, saturated or unsaturated C ₈ -C ₂₄ carboxylic acids and mixtures thereof, preferably glyceryl laurate. Rinse-off composition according to one of the Claims 1 or 2 , characterized in that component b, the at least one anionic surfactant, is selected from alkyl sulfates, alkyl ether sulfates, alkane sulfonates, alkyl benzene sulfonates, olefin sulfonates and mixtures thereof. Rinse-off composition according to one of the Claims 1 to 3rd , characterized in that component c, the at least one amphoteric surfactant, is selected from alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines, sulfobetaines and mixtures thereof. Rinse-off composition according to one of the Claims 1 to 4th , characterized in that component a, the at least one glycerol ester, in a proportion of 0.01 to 0.17% by weight, preferably 0.02 to 0.15% by weight, particularly preferably 0.03 to 0, 14% by weight, even more preferably 0.04 to 0.13% by weight, based on the total proportion of the composition, is contained in the composition. Rinse-off composition according to one of the Claims 1 to 5 , characterized in that component b, the at least one anionic surfactant, in a proportion of 2.5 to 20.0% by weight, preferably 3.0 to 15.0% by weight, particularly preferably 3.5 to 14 , 0% by weight, even more preferably 4.0 to 11.0% by weight, based on the total proportion of the composition, is contained in the composition. Rinse-off composition according to one of the Claims 1 to 6th , characterized in that component c, the at least one amphoteric surfactant, in a proportion of 1.2 to 16.0% by weight, preferably 1.5 to 13.0% by weight, particularly preferably 1.8 to 9 , 0% by weight, even more preferably 2.0 to 5.0% by weight, based on the total proportion of the composition, is contained in the composition. Rinse-off composition according to one of the Claims 1 to 7th , characterized in that the total proportion of amphoteric surfactants in the composition is 1.0 to 21.0% by weight, preferably 1.3 to 18.0% by weight, particularly preferably 1.5 to 16.0% by weight %, even more preferably 2.0 to 12.0% by weight, based on the total proportion of the composition. Rinse-off composition according to one of the Claims 1 to 8th , characterized in that the ratio of component b, the at least one anionic surfactant, to the total proportion of amphoteric surfactants in the composition is 1: 1 to 4.5: 1, preferably 1.5: 1 to 4: 1, very particularly preferably 1 , 9: 1 to 3.5: 1, more preferably 2.1: 1 to 3: 1. Use of a composition according to one of the Claims 1 to 9 in a cleaning composition.