DE102016012612A1 - Backing material combined with a biodegradable carbon source and method of use - Google Patents
Backing material combined with a biodegradable carbon source and method of use Download PDFInfo
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- DE102016012612A1 DE102016012612A1 DE102016012612.4A DE102016012612A DE102016012612A1 DE 102016012612 A1 DE102016012612 A1 DE 102016012612A1 DE 102016012612 A DE102016012612 A DE 102016012612A DE 102016012612 A1 DE102016012612 A1 DE 102016012612A1
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- fat
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- carrier material
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- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 31
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 239000000463 material Substances 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000012876 carrier material Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 244000005700 microbiome Species 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 4
- 239000011148 porous material Substances 0.000 claims description 7
- 229910002651 NO3 Inorganic materials 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 238000009360 aquaculture Methods 0.000 claims description 2
- 244000144974 aquaculture Species 0.000 claims description 2
- 239000003651 drinking water Substances 0.000 claims description 2
- 235000020188 drinking water Nutrition 0.000 claims description 2
- 235000019197 fats Nutrition 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 2
- 235000003441 saturated fatty acids Nutrition 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims 3
- 230000001681 protective effect Effects 0.000 claims 3
- 238000011001 backwashing Methods 0.000 claims 2
- 238000012856 packing Methods 0.000 claims 2
- 235000009161 Espostoa lanata Nutrition 0.000 claims 1
- 240000001624 Espostoa lanata Species 0.000 claims 1
- 230000002745 absorbent Effects 0.000 claims 1
- 239000002250 absorbent Substances 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 239000010840 domestic wastewater Substances 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- -1 for example Substances 0.000 claims 1
- 239000010842 industrial wastewater Substances 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 239000004753 textile Substances 0.000 claims 1
- 238000006065 biodegradation reaction Methods 0.000 abstract description 2
- 230000001737 promoting effect Effects 0.000 abstract description 2
- 239000003925 fat Substances 0.000 description 13
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 239000003673 groundwater Substances 0.000 description 2
- BUHVIAUBTBOHAG-FOYDDCNASA-N (2r,3r,4s,5r)-2-[6-[[2-(3,5-dimethoxyphenyl)-2-(2-methylphenyl)ethyl]amino]purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol Chemical compound COC1=CC(OC)=CC(C(CNC=2C=3N=CN(C=3N=CN=2)[C@H]2[C@@H]([C@H](O)[C@@H](CO)O2)O)C=2C(=CC=CC=2)C)=C1 BUHVIAUBTBOHAG-FOYDDCNASA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004621 biodegradable polymer Substances 0.000 description 1
- 229920002988 biodegradable polymer Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000005067 remediation Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
- C02F3/305—Nitrification and denitrification treatment characterised by the denitrification
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F2003/001—Biological treatment of water, waste water, or sewage using granular carriers or supports for the microorganisms
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Microbiology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biological Treatment Of Waste Water (AREA)
- Apparatus Associated With Microorganisms And Enzymes (AREA)
Abstract
Die Erfindung bezieht sich auf ein Trägermaterial kombiniert mit einer biologisch abbaubaren Kohlenstoffquelle und Verfahren zur Anwendung mit den weiteren Merkmalen nach dem Oberbegriff des Patentanspruches 1. Trägermaterialien werden in der Wasseraufbereitung angewendet um Mikroorganismen auf Oberflächen in Biofilmen zu immobilisieren. Anwendungsbereiche sind die Nitrifikation, die Denitrifikation und biologischer Abbau verschiedener unerwünschter Substanzen. Kohlenstoffquellen sind dazu geeignet, das Wachstum von Mikroorganismen zu fördern.The invention relates to a carrier material combined with a biodegradable carbon source and method of use with the further features according to the preamble of claim 1. Support materials are used in water treatment to immobilize microorganisms on surfaces in biofilms. Applications include nitrification, denitrification and biodegradation of various undesirable substances. Carbon sources are suitable for promoting the growth of microorganisms.
Description
Die Erfindung bezieht sich auf ein Trägermaterial kombiniert mit einer biologisch abbaubaren Kohlenstoffquelle und Verfahren zur Anwendung mit den weiteren Merkmalen nach dem Oberbegriff des Patentanspruches 1. Trägermaterialien werden in der Wasseraufbereitung angewendet um Mikroorganismen auf Oberflächen in Biofilmen zu immobilisieren. Anwendungsbereiche sind die Nitrifikation, die Denitrifikation und biologischer Abbau verschiedener unerwünschter Substanzen. Kohlenstoffquellen sind dazu geeignet, das Wachstum von Mikroorganismen zu fördern.The invention relates to a carrier material combined with a biodegradable carbon source and method of use with the further features according to the preamble of
Das Trägermaterial mit biologisch abbaubarer Kohlenstoffquelle dient dazu, die Nitratelimination mit Hilfe von Mikroorganismen in der Wasseraufbereitung zu verbessern.The carrier material with biodegradable carbon source serves to improve the nitrate removal with the help of microorganisms in the water treatment.
Stand der TechnikState of the art
Die heterotrophe Denitrifikation ist ein Verfahren, um Nitrat und weitere oxidierte Stickstoffverbindungen durch Mikroorganismen unter reduzierenden Bedingungen aus Wasser zu entfernen. Dazu sind u.U. zusätzliche organische Kohlenstoffquellen erforderlich. Üblicherweise werden lösliche Substrate wie Essigsäure, Methanol oder Ethanol zu dosiert (z.B. Menasveta et al., 2001, Van Rijn et al., 2006). Ihre Zugabe aber birgt die Gefahr der Fehldosierung. Bei Unterdosierung der C-Quelle ist keine vollständige Nitratelimination gewährleistet und Nitrit kann als Zwischenprodukt auftreten. Eine Überdosierung ist nicht nur unwirtschaftlich, sondern geht auch mit einer höheren Sauerstoffzehrung bei dem nachfolgenden aeroben Abbau einher. Zudem können anaerobe Prozesse begünstigt werden, was ggf. zur Bildung von giftigem H2S führt.Heterotrophic denitrification is a process for removing nitrate and other oxidized nitrogen compounds from water by microorganisms under reducing conditions. This may require additional organic carbon sources. Usually, soluble substrates such as acetic acid, methanol or ethanol are metered (eg Menasveta et al., 2001, Van Rijn et al., 2006). Their addition, however, carries the risk of misdosing. Underdosing of the C source does not ensure complete nitrate elimination and nitrite may occur as an intermediate. An overdose is not only uneconomical, but is also associated with a higher oxygen depletion in the subsequent aerobic degradation. In addition, anaerobic processes can be favored, possibly leading to the formation of toxic H 2 S.
Die Ansprüche beschreiben nur eine Anwendung für die Boden-Sanierung, nicht jedoch die Anwendung in wässrigen Milieus wie etwa speziell in der Aquakultur oder Wasseraufbereitung. Dieses Patent gibt keinen Hinweis darauf, dass Trägermaterialien eingesetzt werden.The claims describe only one application for soil remediation, but not the application in aqueous environments such as especially in aquaculture or water treatment. This patent gives no indication that support materials are used.
Aufgabenstellungtask
Aufgabe der Erfindung ist es, ein Trägermaterial kombiniert mit einer biologisch abbaubaren Kohlenstoffquelle und Verfahren zur Anwendung zur Verfügung zu stellen, das einfach in der Anwendung ist, insbesondere keine aufwendige Regelungstechnik erfordert, weil es ein sich selbstregulierendes biologisches System ist und kostengünstig im Betrieb einsetzbar ist.The object of the invention is to provide a carrier material combined with a biodegradable carbon source and method of use available, which is easy to use, in particular requires no complex control technology, because it is a self-regulating biological system and can be used inexpensively in operation ,
Es sollen deshalb Festsubstrate als Kohlenstoffquelle eingesetzt werden, die keine solche aufwendige Technik erforderlich machen. Festsubstrate dienen gleichzeitig als Aufwuchsfläche für die Mikroorganismen und als Kohlenstoffquelle für die Denitrifikation. Auf eine Zudosierung löslicher Kohlenstoffquellen kann verzichtet werden.It should therefore be used as a carbon source solid substrates that do not require such a complex technique. Solid substrates simultaneously serve as a growth area for the microorganisms and as a carbon source for denitrification. On a dosage of soluble carbon sources can be dispensed with.
Wird das Trägermaterial kombiniert mit einer biologisch abbaubaren Kohlenstoffquelle im Bereich von Trinkwasser eingesetzt, ist der Vorteil auch darin zu sehen, dass Fette, Fettsäuren, gesättigten Fettsäuren oder fettähnliche Substanzen - im Folgenden als „Fett“ bezeichnet - als Kohlenstoffquelle verwendet wird. Fett wird als Lebensmittel eingesetzt und ist insoweit unbedenklich.When the carrier material combined with a biodegradable carbon source in the drinking water sector is used, the advantage is also that fats, fatty acids, saturated fatty acids or fat-like substances - hereinafter referred to as "fat" - are used as the carbon source. Fat is used as a food and is safe in this respect.
Fette als Festsubstrate sind im Vergleich zu alternativ einsetzbaren biologisch abbaubaren Polymeren relativ kostengünstig.Fats as solid substrates are relatively inexpensive compared to alternatively usable biodegradable polymers.
Fette können aber auf Grund ihrer Eigenschaften wie Sprödigkeit und geringer Abriebfestigkeit nicht direkt für diesen Zweck eingesetzt werden.Due to their properties such as brittleness and low abrasion resistance, fats can not be used directly for this purpose.
Die technische Herausforderung ist es, ein Trägermaterial zur Verfügung zu stellen, mit dem sich Fett als biologisch abbaubare Kohlenstoffquelle in der Wasseraufbereitung einsetzen lässt. Eine Aufgabe des Trägermaterials ist deshalb, den Schutz der Fette vor Abrieb und Zerbrechen zur Verfügung zu stellen. Damit soll das Austragen von Fettpartikeln vermindert werden, was ansonsten zu erheblichen Problemen bei den anschließenden Verfahrensschritten führen kann. Gleichzeitig ist es Ziel, die Dichte des kombinierten Trägermaterials mit Kohlenstoffquelle je nach den verfahrenstechnischen Anforderungen beeinflussen zu können.The technical challenge is to provide a carrier material that can be used as a biodegradable source of carbon in water treatment. An object of the carrier material is therefore to provide the protection of the fats from abrasion and breakage. This is intended to reduce the discharge of grease particles, which can otherwise lead to considerable problems in the subsequent process steps. At the same time, the goal is to increase the density of the combined carrier material Depending on the process requirements to influence carbon source.
Die Aufgabe ist erfindungsgemäß durch die Merkmale des Anspruchs 1 gelöst. Vorteilhafte Ausführungsformen des erfindungsgemäßen Trägermaterials kombiniert mit einer biologisch abbaubaren Kohlenstoffquelle sind in den weiteren Ansprüchen angegeben.The object is achieved by the features of
Figurenlistelist of figures
- In
1 wird erkennbar, dass es auch Hohlräume (3) im Trägermaterial (2) geben kann, in die das Fett (1) nicht eindringt. Außerdem ist beispielhaft eine offene Pore (4) im Trägermaterial sichtbar, durch die im Herstellungsprozess das Fett (1), im Betrieb das Wasser und die Mikroorganismen in die Pore eindringen und sie wieder verlassen können. -
2 : Dargestellt ist ein spezieller Füllkörper als Trägermaterial (2) mit Fett (1), der eine überwiegend zylindrische Grundform hat, mit einer zentralen Öffnung (3). -
3 : Entspricht2 in dreidimensionaler Form, ohne Fett (1) -
4 :Entspricht 3 , jedoch mit Fett (1)
- In
1 It can be seen that there can also be cavities (3) in the carrier material (2) into which the grease (1) does not penetrate. In addition, by way of example, an open pore (4) in the carrier material is visible, through which the fat and the microorganisms can penetrate into the pore during operation and can leave it again. -
2 : Shown is a special filler as a carrier material (2) with fat (1), which has a predominantly cylindrical basic shape, with a central opening (3). -
3 : Corresponds2 in three-dimensional form, without fat (1) -
4 : Corresponds3 , but with fat (1)
BezugszeichenlisteLIST OF REFERENCE NUMBERS
ZITATE ENTHALTEN IN DER BESCHREIBUNG QUOTES INCLUDE IN THE DESCRIPTION
Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.
Zitierte PatentliteraturCited patent literature
- EP 1249283 B1 [0004]EP 1249283 B1 [0004]
- DE 102007033078 [0006]DE 102007033078 [0006]
- DE 19919806 [0007]DE 19919806 [0007]
Claims (9)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102016012612.4A DE102016012612A1 (en) | 2016-10-19 | 2016-10-19 | Backing material combined with a biodegradable carbon source and method of use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102016012612.4A DE102016012612A1 (en) | 2016-10-19 | 2016-10-19 | Backing material combined with a biodegradable carbon source and method of use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102016012612A1 true DE102016012612A1 (en) | 2018-04-19 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE102016012612.4A Withdrawn DE102016012612A1 (en) | 2016-10-19 | 2016-10-19 | Backing material combined with a biodegradable carbon source and method of use |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE102016012612A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109052635A (en) * | 2018-08-07 | 2018-12-21 | 济南大学 | A kind of slow release carbon source collaboration short distance nitration biomembrane strengthened denitrification device and method |
| CN110606563A (en) * | 2019-10-17 | 2019-12-24 | 浙江工业大学 | Slow-release carbon source filler for enhancing denitrification and preparation method thereof |
| CN114426676A (en) * | 2021-12-20 | 2022-05-03 | 南京师范大学 | Magnetic iron-based MOF microbial carrier material and preparation method thereof |
| CN115784430A (en) * | 2022-12-07 | 2023-03-14 | 华夏碧水环保科技股份有限公司 | Rapid co-culture method of aerobic granular sludge and biological carrier |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19919806A1 (en) | 1999-03-17 | 2000-09-21 | Sanyo Electric Co | Carrier for extracting bacteria comprises a porous material |
| EP1249283B1 (en) | 2001-04-13 | 2008-12-10 | Panasonic Corporation | Method of decreasing nitrate nitrogen and volatile organic compound in soil and groundwater |
| DE102007033078A1 (en) | 2007-07-13 | 2009-01-15 | Institut für Oberflächenmodifizierung e.V. | Polymeric carrier material for the cultivation of cells |
-
2016
- 2016-10-19 DE DE102016012612.4A patent/DE102016012612A1/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19919806A1 (en) | 1999-03-17 | 2000-09-21 | Sanyo Electric Co | Carrier for extracting bacteria comprises a porous material |
| EP1249283B1 (en) | 2001-04-13 | 2008-12-10 | Panasonic Corporation | Method of decreasing nitrate nitrogen and volatile organic compound in soil and groundwater |
| DE102007033078A1 (en) | 2007-07-13 | 2009-01-15 | Institut für Oberflächenmodifizierung e.V. | Polymeric carrier material for the cultivation of cells |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109052635A (en) * | 2018-08-07 | 2018-12-21 | 济南大学 | A kind of slow release carbon source collaboration short distance nitration biomembrane strengthened denitrification device and method |
| CN110606563A (en) * | 2019-10-17 | 2019-12-24 | 浙江工业大学 | Slow-release carbon source filler for enhancing denitrification and preparation method thereof |
| CN110606563B (en) * | 2019-10-17 | 2024-04-16 | 浙江工业大学 | Sustained-release carbon source filler for strengthening denitrification and preparation method thereof |
| CN114426676A (en) * | 2021-12-20 | 2022-05-03 | 南京师范大学 | Magnetic iron-based MOF microbial carrier material and preparation method thereof |
| CN115784430A (en) * | 2022-12-07 | 2023-03-14 | 华夏碧水环保科技股份有限公司 | Rapid co-culture method of aerobic granular sludge and biological carrier |
| CN115784430B (en) * | 2022-12-07 | 2024-02-20 | 华夏碧水环保科技股份有限公司 | Rapid co-culture method for aerobic granular sludge and biological carrier |
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