DE102011009888A1 - Method for manufacturing e.g. carbonated beverage-filled container from preforms, involves temporarily guiding and/or stretching preform in axial direction, and supplying filling medium with e.g. different contents of carbon dioxide - Google Patents

Abstract

The method involves thermally conditioning a preform (2) that is made of thermoplastic material, and transforming the preform into a container (11), within a mold by applying fluid pressure. The container is molded by using filling media. The preform is temporarily guided and/or stretched in an axial direction by a stretching rod during transformation into the container. The filling media are supplied with different contents of carbon dioxide and/or treated at different temperatures, at a point of time or in two or more process phases. An independent claim is also included for a device for manufacturing a filled container, comprising a heating device.

Description

The invention relates to a method for producing filled containers in which a preform of a thermoplastic material after thermal conditioning along a transport path in the region of a heating section within a mold is deformed by pressure into the container and in which as a fluid for container molding in the Container to be filled filling medium is used.

The invention further relates to a device for producing filled containers from a thermoplastic material, which has at least one heating path arranged along a transport path of a preform and a forming station provided with a mold, and in which the forming station comprises a feed device for a filling medium to be filled into the container having. In a container molding by blowing pressure preforms of a thermoplastic material, for example, preforms made of PET (polyethylene terephthalate), supplied to different processing stations within a blow molding machine. Typically, a blow molding machine of the type having a heating device and a blowing device, in the region of which the previously tempered preform is expanded by biaxial orientation to a container. The expansion takes place by means of compressed air, which is introduced into the preform to be expanded. The procedural sequence in such an expansion of the preform is in the DE-OS 43 40 291 explained. The introductory mentioned introduction of the pressurized gas also includes the introduction of compressed gas into the developing container bubble and the introduction of compressed gas into the preform at the beginning of the blowing process.

The basic structure of a blowing station for container molding is in the DE-OS 42 12 583 described. Possibilities for tempering the preforms are in the DE-OS 23 52 926 explained.

According to a typical processing method, the blow-molded containers produced as described above are fed to a subsequent filling device and filled here with the intended product. As a rule, a separate blowing machine and a separate filling machine are thus used. It is also already known to directly couple a separate blowing machine and a separate filling machine and to provide a so-called blocked blow-filling device.

Moreover, it is already known to make the shaping of the container by the filling material to be filled. A correspondingly tempered preform is used for this purpose in a suitable form and then the liquid filling medium is introduced into the preform and the resulting from this preform container bubble. The container bladder is in this case expanded until a complete contact with the inner contour of the mold is achieved and the container is filled. Such a process is also referred to as a hydraulic molding process.

In the case of container molding by the filling medium itself, only one machine is required, which, however, has an increased complexity for this. Initial test results with such devices, however, show that the quality of the containers produced is still well below the quality of conventionally produced blow-molded containers. This is essentially due to the fact that a large number of process parameters available during the execution of a blow process can either not be present in hydraulic container formation or have not yet been developed.

The object of the present invention is to improve a method of the aforementioned type such that with low mechanical engineering effort a high-quality container molding is supported at the same time high throughput rates.

This object is achieved in that the preform is at least temporarily performed during its transformation into the container.

Another object of the present invention is to construct a device of the aforementioned type in such a way that high throughput rates are supported with a simple structural design and good product quality. This object is achieved in that the forming station has a preform during its transformation into the container at least temporarily acting guide means.

By guiding the preform during the deformation of the preform into a developing container bladder and then into the containers provided with the final contour, it is achieved that a center, typically arranged in the region of a preform tip, is defined and reproducibly positioned. Such a defined positioning is important because during the expansion of the preform into the container, a biaxial orientation of the material of the preform is performed and for this purpose a specific and predeterminable material distribution within the wall of the molded container is required. In an uncontrolled container molding, however, are undesirable and in particular to expect uneven material distributions.

A particularly effective guidance during the molding process can take place in that the guide is made using a stretch rod.

According to one embodiment, it is provided that the filling medium is at least partially supplied through the stretching rod.

Alternatively or additionally, it is also thought that the filling medium is at least partially supplied to the stretch rod over.

A uniform shaping process is achieved in that the filling medium is at least temporarily supplied with a constant volume flow. Possibilities for influencing the material distribution within the wall of the molded container are achieved by supplying the filling medium at least temporarily with a variable volume flow.

An extremely compact construction is supported by the fact that the container is formed, filled and sealed on a rotating process wheel.

A further embodiment variant is that a generated stretching force is measured.

Only slight stretching forces to be applied by the stretching rod can be ensured by controlling a volume flow of the filling medium as a function of a measured stretching force.

In the drawings, embodiments of the invention are shown schematically. Show it:

1 a schematic representation of a basic structure of a device for carrying out a hydraulic container forming using a filling,

2 a schematic longitudinal section through a preform with already partially inserted stretch rod and a venting device,

3 a schematic longitudinal section through a molded container with partially introduced stretching and filling device,

4 a longitudinal section through a modified embodiment of the filling and shaping device,

5 a longitudinal section through a forming and filling device with a seal to prevent dripping,

6 an embodiment with controllable supply of the filling medium and separate controllable ventilation,

7 a schematic representation of a combined molding, filling and closing and

8th another embodiment of a combined device according to 7 ,

The basic structure of a combined forming and filling device is in 1 shown. From a feeder ( 1 ) are schematically shown preforms ( 2 ) using a transfer wheel ( 3 ) a heating device ( 4 ). In the area of the heating device ( 4 ), the preforms ( 1 ) depending on the application, for example with its mouth sections ( 5 ) are transported vertically upwards or vertically downwards. The heater ( 4 ) can be used, for example, with heating elements ( 6 ) provided along a transport device ( 7 ) are arranged. As a transport device ( 7 ), for example, a circulating chain can be used.

As heating elements ( 6 For example, IR radiators or light-emitting diodes or NIR radiators can be used. After sufficient tempering, the heated preforms ( 2 ) from a transfer wheel ( 8th ) to a rotatably arranged process wheel ( 9 ) to hand over. The process wheel ( 9 ) is connected to a plurality of forming stations ( 19 ), in whose area both a deformation of the preforms ( 2 ) in schematically represented containers ( 11 ) as well as a filling of the container ( 11 ) takes place with a designated filling medium. The container is formed here synchronously with the filling and controlled by the filling medium.

After forming and filling, the containers ( 11 ) from a picking wheel ( 12 ) from the process wheel ( 9 ) and a delivery line ( 13 ).

According to the embodiment in FIG 1 is it intended, the process wheel ( 9 ) via an input device ( 14 ) schematically illustrated closure elements ( 15 ). This makes it possible, on the process wheel ( 9 ) also ready to close the container ( 11 ) and using the sampling device ( 12 ) prefilled, filled and sealed containers ( 11 ) to handle. The closure element ( 15 ) can for example, be designed as a screw-on cap, a crown cap or a sealing foil.

As material for the preforms ( 1 ), different thermoplastic materials may preferably be used. Examples include polyethylene terephthalate (PET), polyethylene (PE), polyethylene naphthalate (PEN) or polypropylene (PP) called. The dimensioning of the preforms and the weight of the preforms ( 2 ) can be adapted to the size, weight and design of the containers ( 11 ) be adjusted.

In the area of the heating device ( 4 ) are typically arranged a plurality of electrical and electronic components. In addition, the heating elements ( 6 ) provided with moisture-sensitive reflectors. Because in the area of the process wheel ( 9 ) is carried out using the liquid filling medium filling and shaping of the container, it must be ensured that an inadvertent entry of moisture in the area of the heating device ( 4 ) is avoided. This can be done, for example, by a foreclosure ( 16 ), which provides at least one splash guard. In addition, it is also possible in the area of the transfer wheel ( 8th ) used transport elements for the preforms ( 2 ) suitable to temper or impact with collisions of pressurized gas such that adherent moisture is not in the range of the heater ( 4 ) can get.

Handling of the preforms ( 2 ) and / or the container ( 11 ) is preferably carried out using pliers and / or the mouth section ( 5 ) at least partially from the inside or from outside acting on clamping or plug-in elements.

2 shows a longitudinal section through a preform ( 2 ) into which a stretch rod ( 17 ) is introduced. The stretch rod serves the at least temporary guidance of the preform ( 1 ) during its transformation to the container ( 11 ). Typically, there is contact between a dome ( 18 ) of the stretch rod ( 17 ) and a floor ( 19 ) of the preform ( 2 ). In a further retraction of the stretch rod ( 17 ) in the preform ( 2 ) into it is a longitudinal extension of the preform ( 2 ) caused. After completion of the stretching process or at least temporarily already during the execution of the stretching process, a storage device ( 20 ) removed filling medium ( 21 ) in the preform ( 2 ).

A dosage of the filling medium ( 21 ) is carried out using a metering valve ( 22 ). In the illustrated embodiment, the stretch rod ( 17 ) at least partially hollow and the filling medium ( 21 ) is an interior ( 23 ) of the stretch rod ( 17 ). In the area of a wall of the stretch rod ( 17 ) are outflow openings ( 24 ) arranged by a check valve ( 25 ) opposite the metering valve ( 22 ) are lockable. This may result in unintentional dripping of filling medium ( 21 ) from the stretch rod ( 17 ) can be avoided or minimized.

A ventilation of the preform ( 2 ) can be carried out using a venting valve ( 26 ) respectively. The bleed valve ( 26 ) is with an outflow opening ( 27 ) in the region of the preform ( 1 ) acting on connecting element ( 28 ) is arranged. Through the connecting element ( 28 ) through is the stretch rod ( 17 ) positionable. The preform ( 2 ) is opposite the connection element ( 28 ) of a seal ( 29 ) sealed, which may be formed for example as an O-ring. An interior ( 30 ) of the preform ( 2 ) can via an annular gap ( 31 ) with the outflow opening ( 27 ). The annular gap ( 31 ) encloses here in some areas the stretch rod ( 17 ).

3 schematically shows a similar device as in the illustration according to 2 using a hollow stretch rod ( 17 ) with a built-in check valve ( 25 ). However, an already finished container is shown ( 11 ). It can be recognized both in 2 as well as in 3 in that preferably a plurality of outflow openings ( 24 ) in the area of the stretch rod ( 17 ) to be ordered. In the illustrated embodiment, such outflow openings ( 24 ) at different height levels along a longitudinal axis ( 32 ) of the stretch rod ( 17 ). Also, the illustrated embodiment shows an orientation of the outflow openings ( 24 ) with a substantially horizontal outflow direction. Both the arrangement of the outflow openings ( 24 ) in the area of the stretch rod ( 17 ) as well as the orientation of the outflow openings ( 24 ) is variable. The aim is typically a quiet and low-emission discharge behavior.

According to the embodiment in FIG 4 becomes a massive stretch rod ( 17 ) used. A feed of the filling medium ( 21 ) takes place along at least one flow channel on the stretch rod ( 17 ) past. Preferably, for this purpose, the annular gap ( 31 ) used. Also in this embodiment, it is possible to perform a targeted venting.

5 shows an embodiment in which the stretch rod ( 17 ) has an optimized for preventing a drip off embodiment. In the area of the dome ( 17 ) is a sealing element ( 33 ) arranged. The sealing element ( 33 ) can, for example, by an increase in diameter of the stretch rod ( 17 ) to be provided. Also, a suitable material selection is conceivable. At the Pull back the stretch rod ( 17 ) from the container ( 11 ) out the sealing element ( 33 ) in contact with a counter element ( 33 ), which in the region of the connecting element ( 28 ) is arranged. The counter element ( 34 ) is preferably designed as a seal. The discharge openings ( 24 ) of the stretch rod ( 17 ) are after a corresponding positioning of the stretch rod ( 17 ) sealed from the container ( 11 ) arranged separately, so that dripping from the interior ( 23 ) of the stretch rod ( 17 ) can be safely avoided. In the area of the connecting element ( 28 ) is typically at least one warehouse ( 35 ) for guiding the stretch rod ( 17 ) arranged.

6 shows an embodiment in which in turn a massive stretching rod ( 17 ) is used. By on the stretch rod ( 17 ) passing flow channels, in particular through the annular gap ( 31 ), both the metering valve ( 22 ) for the filling medium ( 21 ) as well as the vent valve ( 26 ) with the interior ( 30 ) of the preform ( 2 ) or the container ( 11 ) connected. In the illustrated embodiment, the outflow opening ( 27 ) in a radial direction of the connecting element ( 28 ) opposite to a feed opening ( 36 ) arranged with the metering valve ( 22 ) connected is.

7 shows an embodiment in which in the region of the process wheel ( 9 ) according to 1 also closing the containers ( 11 ) he follows. The container ( 11 ) is still in the range of a shape ( 37 ) which forms part of the forming station ( 10 ) according to 1 formed. A closing device ( 38 ) is in this embodiment with respect to the longitudinal axis ( 32 ) coaxial with the connection element ( 28 ) arranged. The closing device ( 38 ) has, for example, pivotable grippers ( 39 ), which for applying the closure element ( 15 ) are provided. In particular, it is intended that the closing device ( 38 ) rotatably relative to the connecting element ( 28 ). This allows the closure element ( 15 ) with an internal thread on an external thread of the mouth section ( 5 ) are screwed.

8th shows an alternative embodiment of the construction according to 7 , The closing device ( 38 ) and the connecting element ( 28 ) are not arranged coaxially relative to each other here, but are from a tool carrier ( 40 ) alternately positioned in a work arrangement or a rest arrangement. The tool carrier ( 40 ), for example, revolver-like and with a rotation axis ( 41 ) be provided.

In the following, some typical process parameters are explained in more detail by way of example. The filling medium ( 21 ) is the connection element ( 28 ), preferably at a temperature of the surrounding space, for example in the range of 20 ° C to 30 ° C supplied. The filling medium ( 21 ) thereby cools the material of the container ( 11 ) and supports a fast dimensional stability of the molded container ( 11 ). This supports a very short cycle time. But it is also possible, the filling medium ( 21 ) supplied more cooled or heated.

During the molding of the container ( 11 ), the filling medium ( 21 ) at least temporarily with a constant volume flow into the preform ( 2 ) or the container ( 11 ) be initiated. However, it is also possible to specify a suitable time profile for the volume flow in such a way that differently sized volume flows are generated at different times.

Before an introduction of the filling medium ( 21 ) it is possible within the preform ( 1 ) and / or to replace it with an inert gas. This is particularly recommended for oxidation-sensitive filling media ( 21 ).

As filling medium ( 21 ) either pure liquids or with added liquids can be used. In particular, it is intended to supply carbonized filling media. Since the filling medium ( 21 ) the preform ( 1 ) or the container ( 2 ) is supplied under pressure, for example, with a pressure of 10 bar, it proves useful, all flow paths for the filling medium ( 21 ) such that local decompressions are avoided by the flow processes. Local or temporary decompression could otherwise lead to outgassing of carbon dioxide.

Alternatively to the in 1 illustrated heating of preferably injection-molded preforms ( 2 ) it is also possible to use the preforms ( 2 ) immediately before its transformation into the containers ( 11 ). This can be done for example by an injection molding process as in a so-called single-stage injection-blow molding process, also a compression molding is possible. Such a shaping of the preforms ( 2 ) avoids the use of electrical and electronic components in the region of a heating device or at least substantially reduces the extent of use of such parts, since these are then required only for a possibly required temperature profiling.

As materials for the components of the process wheel ( 9 ) are preferably used corrosion-resistant materials. In particular, it is intended to use stainless steels and plastics. In particular, it is thought that To shape ( 37 ) completely or partially form of a suitable plastic.

In order to minimize the required stretching forces, it is intended to control the stretching process by supplying the filling medium ( 21 ) to support. However, such support should ensure that the leadership of the preform ( 2 ) by the stretching rod ( 17 ) is ensured. This can be done, for example, by measuring the acting stretching force and controlling the volume flow of the filling medium ( 21 ) takes place in such a way that always a minimum stretching force is maintained. The size of the stretching force can be determined very easily in electrically driven stretching systems by the measurement of the drive current or in pneumatic stretching systems by a pressure measurement.

When filling containers ( 11 ) with the filling medium ( 21 ) it is often desirable, after closing the container ( 11 ) provide a gas-filled headspace. This free headspace can be generated by the volume reduction resulting from the retraction of the stretch rod (FIG. 17 ) results.

The material selection already explained above takes place in particular taking into account given hygiene requirements. In this case, a sterilizability or sterilizability is ensured. Also, a structural design is made such that the requirements for good cleanability are met.

One or more of the transfer wheels may be equipped with servo drives.

This particularly helps to ensure complete separation of the heater ( 4 ) from the process wheel ( 9 ) during the execution of cleaning operations. It is also conceivable to arrange retractable handling elements in the region of at least one of the transfer wheels. Further moisture protection can be achieved by using a dry air tunnel.

An example of a concrete process flow will be described below. Before or after the insertion of the preform ( 2 ) in the form ( 37 ) first gas exchange takes place in the interior of the preform, in particular to displace oxygen or to reduce the proportion of oxygen. An operation of purging and / or evacuating typically takes at most 0.1 second. Stretching the preform ( 2 ) using the stretch rod ( 17 ) typically takes about 0.2 seconds. Likewise, for the filling and the resulting deformation of the preform ( 2 ) in the container ( 11 ) provided a period of about 0.2 seconds. For the subsequent creation of a headspace typically a maximum of 0.2 seconds is needed. The process of calming and deflating the filled container is very fast with still drinks, with carbonated drinks this process can take up to 5 seconds.

A treatment of the headspace can then be carried out, for example, using a high-pressure foaming or a metered addition of nitrogen. The subsequent feeding of a cap may take up to 1.5 seconds for carbonated drinks. Also, the process of closing or screwing, for example, a period of 1.5 seconds to complete.

After the finished closing of the container ( 11 ) opens the form ( 37 ) and the filled containers ( 11 ) is removed and transported away.

During the introduction of the contents into the preform to be formed ( 2 ) or the still in the forming container ( 11 ) usually results in a typical pressure curve in the filling system. Due to the widening of the container ( 11 ) is initially a comparatively low pressure, which increases at the end of the molding process. The corresponding increase in pressure or the amount of pressure increase in the filling system, in particular in the filling line, can be used as a control variable for a subsequent process step and optionally determine the time of initiation of this next process step. Alternatively or additionally, it is also intended to use as control variables the characteristic of the pressure profile and / or the volume flow of the filling material.

With regard to the temperature of the filling is especially thought to supply the contents with an ambient temperature. Depending on the respective application boundary conditions, however, an increase in temperature or a reduction in temperature is also conceivable in comparison with a filling with ambient temperature.

According to a further variant, it is intended to carry out the filling process in two stages, wherein during the first process stage, the filling material is supplied at a temperature which is greater than the temperature during the second process step. The first process step can be carried out, for example, if, via the stretching rod ( 11 ) the longitudinal extension of the preform ( 2 ) is carried out. The second process step then follows the execution of the stretching process and corresponds to the transverse expansion of the container ( 11 ).

In the already briefly mentioned calming in the head space after the pressure relief, it is also intended, if appropriate, to perform an extraction of forming gases and / or foam.

With regard to the closure of the finished molded and filled containers ( 11 ) Different variants are also feasible. In a variant, it is possible to provide a part of the treatment station on the blowing wheel with a turret. The turret comprises on the one hand a blowing and filling head and on the other hand a closing head. This corresponds to the schematic representation in FIG 8th , However, it is also conceivable to use an integrated construction in which the respective head performs both the blowing, the filling and the closing process.

According to a further variant, although the blowing filling head and the closing head are formed as separate components, but arranged pivotably at each forming and filling station. According to a third variant, only the blowing and filling head is arranged on the blowing wheel and there is a transfer of the still open container to a separate closure device, such as a transport wheel, which is equipped with a capping.

The application of the closures, such as the closure caps, for example, immediately after the opening of the forms ( 37 ) respectively. This would thus be a task of the caps on the blowing wheel. In particular, it is thought, before a task of the caps the mouth space of the filled container ( 11 ) to apply an inert gas.

It has proven particularly advantageous if a sublayering is achieved in the abovementioned method.

It has been found to be problematic, in the case of full or partial carbonation of the filling medium to make without rapid loss of product, the rapid pressure relief after molding to the closure of the container. Massive foaming and subsequent product loss hitherto prevented the use of this hydraulic molding technique for CO2-containing products.

Here it turned out that it is particularly advantageous if the filling medium ( 21 ) or parts of the filling medium ( 21 ) is supplied at least two times or in at least two process phases with different contents of carbon dioxide and / or with different temperatures. It is proposed, in particular in the second process phase, the filling medium ( 21 ) or the proportion of filling medium ( 12 ) with the higher concentration of carbon dioxide. This has the advantage that the contents are already calm and run off first further solution process in the liquid volume.

A variant consists in the filling medium ( 21 ) or the proportion of filling medium ( 12 ) with the higher concentration of carbon dioxide before being introduced, and then in the aforementioned second process phase, this filling medium ( 21 ) or the corresponding proportion with the higher concentration of carbon dioxide, at a lower temperature than the filling medium ( 21 ) or the proportion of filling medium ( 21 ) of the first phase of the process. Thus, an underlayer with CO2-rich filling medium sets in and the foaming is reduced.

In this case, if possible, the carbon dioxide content in the second process phase should be 30% by weight above the first process phase, in particular 50 to 100% by weight above that of the first phase, ie. This means that ideally a silent, CO2-free and a CO2-rich phase is brought together.

A variant is that the temperature of the filling medium ( 21 ) or the proportion of the filling medium ( 21 ) of the second process phase is cooled, or at least 10 ° C below that of the first or a previous process phase, in particular less than 10 ° C and ideally is between 4 ° C and 8 ° C.

It has proved to be advantageous if the pressure of the filling medium ( 21 ) or the proportion of the filling medium ( 21 ), which has the higher carbon dioxide concentration and / or the lower temperature, at least temporarily during the molding process is higher than at least one other or the remaining portion of the filling medium ( 21 ), in particular by at least 1 bar higher.

Furthermore, the pressure on a sub-line section should be higher than the pressure of the filling medium ( 21 ) or the proportion of the filling medium ( 21 ), for the portion which has the higher carbon dioxide concentration and / or the lower temperature. This should be at least temporarily during the molding process by 2 bar to 5 bar higher than at least one other or the remaining portion of the filling medium ( 21 ).

One embodiment provides that on the flow path of the inside of the stretching rod ( 17 ) flowing filling medium ( 21 ) or the proportion of the filling medium ( 21 ), a throttle element or cross-sectional constriction is provided, wherein the throttle element in particular shortly before the at least one outlet ( 24 ) is arranged. Thus, the maintain favorable high pressure until just before the first relaxation. This can be further increased if a part of the filling material is fed past the stretching rod and another part is fed through the stretching rod.

In this case, the more carbon dioxide-containing fraction should be fed through the stretching rod. It is advantageous if the stretch rod is at least partially thermally isolated relative to the filling material.

The device thus comprises for the production of filled containers made of a thermoplastic material, which has at least one heating path arranged along a transport path of a preform (US Pat. 4 ) and a forming station provided with a mold.

Furthermore, the forming station comprises a feeding device ( 1 ) for one in the container ( 11 ) filling medium to be filled ( 21 ), and further comprising a carbonation unit, by means of which at least in a partial flow of the filling medium ( 21 ) Carbon dioxide can be dissolved, the forming station ( 10 ) one the preform ( 2 ) during its transformation into the container ( 11 ) at least temporarily acting guide means in the form of a stretch rod ( 17 ) and in the interior ( 23 ) the stretching rod ( 17 ) at least part of the filling medium ( 21 ) is conductive, wherein at least at the lower end of the stretch rod outlet openings ( 24 ) are provided.

Advantageously, a cooling unit along the line for at least the proportion of the filling medium ( 21 ) is provided in which downstream carbon dioxide is dissolved or which flows from the Karbonatisierungseinheit.

In this case, at least one line section, in which the carbon dioxide-rich filling medium ( 21 ) or a portion thereof is isolated, in particular consists of Teflon or Teflon-containing material or is lined.

LIST OF REFERENCE NUMBERS

1

feeder

2

preform

3

transfer wheel

4

heater

5

mouth portion

6

heating element

7

transport means

8th

transfer wheel

9

Prozessrad

11

container

12

extraction wheel

13

delivery line

14

input device

15

closure element

16

Form foreclosure

17

stretching rod

18

Dome of the stretch rod

19

Bottom of the preform

20

Vorradseinrichtung

21

filling medium

22

metering valve

23

Interior of the stretch rod

24

outlet

25

check valve

26

vent valve

27

outlet

28

connecting element

29

poetry

30

Interior of the preform

31

annular gap

32

Longitudinal axis of the bottle or stretch rod

33

sealing element

34

counter-element

35

camp

36

feed

37

shape

38

closing

39

grab

40

tool carrier

41

axis of rotation

42

QUOTES INCLUDE IN THE DESCRIPTION

This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Cited patent literature

• DE 4340291 A [0002]
• DE 4212583 A [0003]
• DE 2352926 A [0003]

Claims (15)

Process for producing filled containers ( 11 ) from preforms ( 2 ), so-called preforms, made of a thermoplastic material, wherein a preform is thermally conditioned and then within a mold ( 37 ) by pressure by means of a fluid in the container ( 11 ) is formed, wherein for container molding one or more in the container ( 11 ) filling media to be filled ( 21 ), and the preform ( 2 ) during its transformation into the container ( 11 ) at least temporarily by a stretch rod ( 17 ) or is stretched in the axial direction, wherein the preform ( 2 ) during its transformation into the container ( 11 ) at least temporarily by a stretch rod ( 17 ), characterized in that the filling medium ( 21 ) or parts of the filling medium ( 21 ) is supplied to at least two time points or in at least two process phases with different levels of carbon dioxide and / or at different temperatures. A method according to claim 1, characterized in that in the second process phase, the filling medium ( 21 ) or the proportion of filling medium ( 12 ) is conducted with the higher concentration of carbon dioxide. Method according to claim 2, characterized in that the filling medium ( 21 ) or the proportion of filling medium ( 12 ) is cooled with the higher concentration of carbon dioxide before the introduction and in the second process phase the filling medium ( 21 ) or the proportion of filling medium ( 12 ) with the higher concentration of carbon dioxide a lower temperature than the filling medium ( 21 ) or the proportion of filling medium ( 21 ) of the first process phase. Method according to one of claims 1 to 3, characterized in that the carbon dioxide content in a second process phase 30 wt .-% is above the first process phase, in particular 50 to 100 wt .-% is above that of the first phase. Method according to one of claims 1 to 4, characterized in that the temperature of the filling medium ( 21 ) or the proportion of the filling medium ( 21 ) of the second process phase is less than 10 ° C, in particular between 4 ° C and 8 ° C. Method according to one of the preceding claims, characterized in that the pressure of the filling medium ( 21 ) or the proportion of the filling medium ( 21 ), which has the higher carbon dioxide concentration and / or the lower temperature, at least temporarily during the molding process is higher than at least one other or the remaining portion of the filling medium ( 21 ), in particular by at least 1 bar higher. A method according to claim 6, characterized in that the pressure on a partial line section is higher than the pressure of the filling medium ( 21 ) or the proportion of the filling medium ( 21 ), which has the higher carbon dioxide concentration and / or the lower temperature, at least temporarily during the molding process by 2 bar to 5 bar higher than at least one other or the remaining portion of the filling medium ( 21 ). Method according to one of claims 6 or 7, characterized in that on the flow path of the inside of the stretching rod ( 17 ) flowing filling medium ( 21 ) or the proportion of the filling medium ( 21 ), a throttle element or cross-sectional constriction is provided, wherein the throttle element in particular shortly before the at least one outlet ( 24 ) is arranged. Method according to one of the preceding claims, characterized in that a part of the filling material is fed past the stretching rod and another part is fed through the stretching rod. Method according to one of the preceding claims, characterized in that, the more carbon dioxide-containing fraction of the filling material is cooled. Method according to one of the preceding claims, characterized in that, the more carbon dioxide-containing portion is fed through the stretching rod. Method according to one of the preceding claims, characterized in that the stretching rod is at least partially thermally insulated relative to the filling material. Device for producing filled containers made of a thermoplastic material, which has at least one heating section arranged along a transport path of a preform (US Pat. 4 ) and a forming station provided with a mold, and in which the forming station has a feeding device ( 1 ) for one in the container ( 11 ) filling medium to be filled ( 21 ), and further comprising a carbonation unit, by means of which at least in a partial flow of the filling medium ( 21 ) Carbon dioxide can be dissolved, characterized in that the forming station ( 10 ) one the preform ( 2 ) during its transformation into the container ( 11 ) at least temporarily acting guide means in the form of a stretch rod ( 17 ) and in the interior ( 23 ) the stretching rod ( 17 ) at least part of the filling medium ( 21 ) is conductive, wherein at least at the lower end of the stretch rod outlet openings ( 24 ) are provided. Apparatus according to claim 13, characterized in that a cooling unit along the line for at least the proportion of the filling medium ( 21 ) is provided, in which downstream carbon dioxide is dissolved or which flows from the Karbonatisierungseinheit. Apparatus according to claim 13 or 14, characterized in that at least one line section in which the carbon dioxide-rich filling medium ( 21 ) or a portion thereof is isolated, in particular consists of Teflon or Teflon-containing material or is lined.

Images