DE102011004121A1 - Nourishing cosmetic cleanser - Google Patents

Abstract

The invention relates to cosmetic cleaning agents which, in a cosmetic carrier a) at least one polysiloxane of the following formula (I) in which - R1 to R5 independently of one another denote a radical from the group consisting of alkyl, aryl or alkylaryl with 1 to 30 carbon atoms, - R6 denotes a radical which carries at least one quaternary ammonium group, - x denotes a number in the range from 2 to 200, and b) contains at least two amphoteric and / or zwitterionic surfactants from the groups of the following formulas (i) to (v), in which the radical R is in each case a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms, with the proviso that surfactants from at least two of groups (i) to (v) in are included in the agent. The agents clean and care for damaged hair, in particular, and give them improved combability and improved hair grip.

Description

The invention is in the field of cosmetics and relates to detergents which contain a special polysiloxane in addition to two different amphoteric and / or zwitterionic surfactants.

The invention further relates to the use of cosmetic cleansing agents for improving the feel and combability of wet and dry hair and for improving the resistance of the hair surface to physical and / or chemical hair damage.

Cosmetic hair cleansers have long been known and are regularly improved or adapted to the changing needs of consumers.

For example, consumers expect a modern hair cleanser to leave a long-lasting, tactile and visual care effect on the cleansed hair so that no hair aftertreatment agent needs to be applied for time, cost and environmental considerations.

Cleaning is usually understood to mean the removal of unwanted odors, dirt, dandruff, sebum deposits and styling agent residues.

By "haptic and visually perceptible care effect" is meant that the hair after the treatment (cleaning) are smooth, easy to comb, soft, shiny and easy to style. Furthermore, cleaned hair should have an increased volume.

It is known to add hair cleansers to improve the care silicones. For example, in the document DE 10 2008 041 020 hair conditioning shampoos containing surfactants and polysiloxanes. The shampoos protect human hair from heat damage.

However, the known shampoos can not meet all the needs of consumers sufficiently.

Especially in already damaged hair that has become dry, brittle, brittle and / or dull as a result of chemical treatments or excessive exposure to UV light, it is particularly important to smooth the hair structure during hair washing again and to prevent knotting the hair after shampooing ,

There continues to be a need for hair cleansers that provide a conditioning benefit for optically and haptically unattractive hair without detracting from the cleansing and / or conditioning benefits.

It is an object of the present invention to provide nourishing hair cleansers which impart an improved feel to the hairs treated therewith. In particular, hair damaged by chemical treatments or exposure to ultraviolet light should not be knotted or easily knotted after treatment with the care hair cleaners and should be easy to untangle.

Another object of the invention was to find care agents or combinations of active ingredients for hair cleansers, which increase the resistance of the hair surface against chemical and physical damage to the hair.

• a) mindestens ein Polysiloxan der folgenden Formel (I)
  
  in der – R¹ bis R⁵ unabhängig voneinander einen Rest aus der Gruppe Alkyl, Aryl oder Alkylaryl mit 1 bis 30 C-Atomen bedeuten, – R⁶ einen Rest bedeutet, der mindestens eine quaternäre Ammoniumgruppe trägt, und – x eine Zahl im Bereich von 2 bis 200 bedeutet, sowie
• b) mindestens zwei amphotere und/oder zwitterionische Tenside aus den Gruppen der folgenden Formeln (i) bis (v) enthalten, in denen der Rest R jeweils für einen geradkettigen oder verzweigten, gesättigten oder ein- bzw. mehrfach ungesättigten Alkyl- oder Alkenlyrest mit 8 bis 24 Kohlenstoffatomen steht,
  
  mit der Maßgabe, dass Tenside aus mindestens zwei der Gruppen (i) bis (v) in dem Mittel enthalten sind.

The invention relates to cosmetic cleansing compositions which are in a cosmetically acceptable carrier

• a) at least one polysiloxane of the following formula (I)
  
  in which - R ¹ to R ⁵ independently of one another represent a radical from the group consisting of alkyl, aryl or alkylaryl having 1 to 30 C atoms, - R ^{6 is} a radical which carries at least one quaternary ammonium group, and - x is a number in the range of 2 to 200, as well as
• b) contain at least two amphoteric and / or zwitterionic surfactants from the groups of the following formulas (i) to (v), in which the radical R in each case represents a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical 8 to 24 carbon atoms,
  
  with the proviso that surfactants from at least two of groups (i) to (v) are included in the composition.

The cleaning agents according to the invention contain the components a) and b) in a cosmetic carrier, which may preferably be aqueous or aqueous-alcoholic. The cosmetic carrier preferably contains at least 40% by weight of water.

Furthermore, the cosmetic carrier may contain 0.01 to 50% by weight, preferably 0.05 to 45% by weight and in particular 0.1 to 40% by weight of at least one alcohol which may be selected from ethanol, ethyl diglycol, 1-propanol, 2-propanol, isopropanol, 1,2-propylene glycol, glycerol, 1-butanol, 2-butanol, 1,2-butanediol, 1,3-butanediol, 1-pentanol, 2-pentanol, 1,2- Pentanediol, 1,5-pentanediol, 1, hexanol, 2-hexanol, 1,2-hexanediol, 1,6-hexanediol, sorbitol, benzyl alcohol, phenoxyethanol or mixtures of these alcohols.

Preference is given to the water-soluble alcohols.

Particularly preferred are ethanol, ethyl diglycol, 1-propanol, 2-propanol, isopropanol, 1,2-propylene glycol, glycerol, benzyl alcohol and / or phenoxyethanol and mixtures of these alcohols.

• – x für eine Zahl von 3 bis 120 steht,
• – der Rest R¹ einen Arylrest, bevorzugt einen Phenylrest bedeutet,
• – die Reste R² bis R⁵ für gleiche C₁-C₄-Alkylreste, bevorzugt für Methylreste stehen,
• – der Rest R⁶ für einen Rest mit dem Aufbau -R⁷-R⁶ steht, wobei
• – die Gruppierung -R⁷- für mindestens eine Gruppierung der folgenden Formeln (II) bis (V) steht
  
  in der y eine Zahl von 2 bis 18, z eine Zahl von 0 bis 3 und R⁹ für Wasserstoff, eine C₁-C₄-Alkylgruppe, eine C₂-C₄-Hydroxyalkylgruppe oder eine -OH-Gruppe steht, und
• – die Gruppe -R⁶ mindestens einer der folgenden Formeln (VI) oder (VII) entspricht,
  
  in der R¹⁰ und R¹² jeweils unabhängig voneinander für Wasserstoff oder einen Alkylrest mit 1 bis 30 C-Atomen stehen, R¹¹ für einen Alkylrest mit 1 bis 30 C-Atomen oder eine Gruppierung -(CH₂)_b-NR¹⁰R¹² steht, in der b eine Zahl von 2 bis 18 bedeutet, R¹³ für eine Gruppierung -O- oder -N(H)- steht, R¹⁴ für einen Alkylrest mit 1 bis 30 C-Atomen steht, a für eine Zahl von 2 bis 18 steht und A für anorganische oder organische Säureanionen steht.

Preferred polysiloxanes a) correspond to the formula (I) wherein

• X is a number from 3 to 120,
• The radical R ^{1 is} an aryl radical, preferably a phenyl radical,
• The radicals R ² to R ^{5 are} identical C ₁ -C ₄ -alkyl radicals, preferably methyl radicals,
• - The radical R ^{6 is} a radical having the structure -R ⁷ -R ⁶ , where
• - the group -R ⁷ - represents at least one grouping of the following formulas (II) to (V)
  
  in which y is a number from 2 to 18, z is a number from 0 to 3 and R ^{9 is} hydrogen, a C ₁ -C ₄ -alkyl group, a C ₂ -C ₄ -hydroxyalkyl group or an -OH group, and
• - the group -R ⁶ corresponds to at least one of the following formulas (VI) or (VII),
  
  in which R ¹⁰ and R ^{12 are} each independently of one another hydrogen or an alkyl radical having 1 to 30 C atoms, R ^{11 is} an alkyl radical having 1 to 30 C atoms or a grouping - (CH ₂ ) _b -NR ¹⁰ R ¹² in which b is a number from 2 to 18, R ^{13 is} a grouping -O- or -N (H) -, R ^{14 is} an alkyl radical having 1 to 30 carbon atoms, a is a number of 2 to 18 and A is an inorganic or organic acid anions.

Suitable C ₁ -C ₄ -alkyl groups include methyl, ethyl, n-propyl, isopropyl and n-butyl groups. Preference is given to methyl and ethyl groups. Especially preferred are methyl groups.

Suitable C ₂ -C ₄ -hydroxyalkyl groups are to be understood as meaning hydroxyethyl, 1-hydroxypropyl, 2-hydroxypropyl, 1-hydroxybutyl and / or 2-hydroxybutyl groups. Suitable inorganic or organic acid anions K are preferably halide ions, preferably chloride or bromide ions.

• – x eine Zahl von 3 bis 120 bedeutet,
• – der Rest R¹ einen Phenylrest bedeutet,
• – die Reste R² bis R⁵ für Methylreste stehen,
• – der Rest R⁶ für einen Rest mit dem Aufbau -R⁷-R⁸ steht, wobei
• – die Gruppierung -R⁷- einer Gruppierung der Formel (II) entspricht, und
• – die Gruppe -R⁸ der Formel (VII) entspricht.

Particularly preferred polysiloxanes a) correspond to the formula (I) wherein

• X is a number from 3 to 120,
• The radical R ¹ denotes a phenyl radical,
• The radicals R ² to R ^{5 are} methyl radicals,
• - The radical R ^{6 is} a radical having the structure -R ⁷ -R ⁸ , where
• - the grouping -R ⁷ - corresponds to a grouping of formula (II), and
• - The group -R ⁸ corresponds to the formula (VII).

• – x eine Zahl von 8 bis 80 bedeutet,
• – der Rest R¹ einen Phenylrest bedeutet,
• – die Reste R² bis R⁵ für Methylreste stehen,
• – der Rest R⁶ für einen Rest mit dem Aufbau -R⁷-R⁸ steht, wobei
• – die Gruppierung -R⁷- einer Gruppierung der Formel (II) entspricht, in der y die Zahl 3, z die Zahl 1 und R⁹ eine -OH-Gruppe bedeutet, und
• – die Gruppe -R⁸ der Formel (VII) entspricht, in der R¹⁰ und R¹² für Methylgruppen stehen, a die Zahl 3, R¹³ die Gruppierung -N(H)- und R¹⁴ eine C₈-C₁₈-Alkylgruppe bedeutet.

Particularly preferred polysiloxanes a) correspond to the formula (I) wherein

• X is a number from 8 to 80,
• The radical R ¹ denotes a phenyl radical,
• The radicals R ² to R ^{5 are} methyl radicals,
• - The radical R ^{6 is} a radical having the structure -R ⁷ -R ⁸ , where
• - the grouping -R ⁷ - corresponds to a grouping of the formula (II), in which y is the number 3, z is the number 1 and R ^{9 is} an -OH group, and
• - the group -R ^{8 of} the formula (VII) corresponds, in which R ¹⁰ and R ^{12 are} methyl, a is the number 3, R ^{13 is} the grouping -N (H) - and R ^{14 is} a C ₈ -C ₁₈ alkyl group means.

A polysiloxane a) which is suitable for the cosmetic cleansing compositions according to the invention is known, for example, under the INCI name Silicone Quaternium-22 and is commercially available.

An example of a based on a polysiloxane a) with the INCI designation Silicone Quaternium-22 commercial product that can be used in the inventive cleaning compositions is Abil Quat ^® T 60 from Evonik.

Abil ^® T Quat 60 comprises a mixture of the ingredients known as the INCI names Silicone Quaternium-22 (65%) and PPG-3 Myristyl Ether (35%).

The cosmetic cleaners contain the polysiloxane a) - based on their total weight - preferably in an amount of 0.01 to 7.5 wt .-%, more preferably from 0.05 to 5 wt .-% and in particular from 0.2 to 3% by weight.

Particularly suitable amphoteric / zwitterionic surfactants b) which can be used in the cleaning agents according to the invention are alkylamidoalkylbetaines and / or alkylampho (di) acetates of the abovementioned formulas (i) to (v).

The particularly suitable amphoteric / zwitterionic surfactants b) include the surfactants cocamidopropylbetaine and disodium cocoamphodiacetate known under the INCI name.

The cosmetic cleansing compositions contain the zwitterionic / amphoteric surfactants - based on their weight - preferably in an amount of 0.01 to 15 wt .-%, more preferably from 0.025 to 10 wt .-% and in particular from 0.05 to 5 wt. -%.

Preferably, the cosmetic cleaning agents contain - based on their weight - 0.05 to 7.5 wt .-%, more preferably 0.5 to 5 wt .-% and in particular 1 to 2.5 wt .-% of surfactant (s) of Formula (iii) and 0.01 to 7.5 wt .-%, more preferably 0.05 to 3 wt .-% and in particular 0.1 to 2 wt .-% of surfactant (s) of the formula (v).

• a) 0,01 bis 7,5 Gew.-% mindestens eines Polysiloxans der Formel (I), in der – x eine Zahl von 3 bis 120 bedeutet, – der Rest R¹ einen Phenylrest bedeutet, – die Reste R² bis R⁵ für Methylreste stehen, – der Rest R⁶ für einen Rest mit dem Aufbau -R⁷-R⁸ steht, wobei – die Gruppierung -R⁷- einer Gruppierung der Formel (II) entspricht, und – die Gruppe -R⁸ der Formel (VII) entspricht,
• b) 0,05 bis 7,5 Gew.-% Tensid(e) der Formel (iii) und
• c) 0,01 bis 7,5 Gew.-% Tensid(e) der Formel (v).

In a first preferred embodiment, a cosmetic cleaning agent according to the invention contains, based on its weight,

• a) 0.01 to 7.5 wt .-% of at least one polysiloxane of the formula (I), in which - x is a number from 3 to 120, - the radical R ^{1 is} a phenyl radical, - the radicals R ² to R ^{5 represents} methyl radicals, - the radical R ^{6 is} a radical having the structure -R ⁷ -R ⁸ , where - the grouping -R ⁷ - corresponds to a grouping of the formula (II), and - the group -R ^{8 of} the formula (VII) corresponds
• b) 0.05 to 7.5 wt .-% of surfactant (s) of the formula (iii) and
• c) 0.01 to 7.5 wt .-% of surfactant (s) of the formula (v).

• a) 0,05 bis 5 Gew.-% mindestens eines Polysiloxans mit der INCI-Bezeichnung Silicone Quaternium-22,
• b) 1 bis 2,5 Gew.-% Alkylamidoalkylbetain(e) und
• c) 0,1 bis 2 Gew.-% Alkylampho(di)acetat(e) enthält.

Within this embodiment, it is particularly preferred if the cleaning agent according to the invention - based on its total weight -

• a) 0.05 to 5 wt .-% of at least one polysiloxane with the INCI name Silicone Quaternium-22,
• b) 1 to 2.5 wt .-% Alkylamidoalkylbetain (e) and
• c) 0.1 to 2 wt .-% alkylampho (di) acetate (s).

An improvement of the hair grip is an object of the present invention.

In order to achieve this goal, it is advantageous if the nourishing component (s) b) can penetrate into the hair fibers from the hair cleaners and / or hair care agents or can be deposited on the fibers.

To further assist the penetration or the deposition of the polysiloxanes a) and / or optionally further optional care components, the inventive cosmetic Detergent in a second preferred embodiment, additionally 0.01 to 5 wt .-%, preferably 0.05 to 3 wt .-% and in particular 0.1 to 2 wt .-% of at least one cationic polymer c).

• – quaternisierte Cellulose-Derivate, wie sie unter den Bezeichnungen Celquat^® und Polymer JR^® im Handel erhältlich sind,
• – hydrophob modifizierte Cellulosederivate, beispielsweise die unter dem Handelsnamen SoftCat^® vertriebenen kationischen Polymere,
• – kationische Alkylpolyglycoside,
• – kationiserter Honig, beispielsweise das Handelsprodukt Honeyquat^® 50,
• – kationische Guar-Derivate, wie insbesondere die unter den Handelsnamen Cosmedia^® Guar und Jaguar^® vertriebenen Produkte,
• – polymere Dimethyldiallylammoniumsalze und deren Copolymere mit Estern und Amiden von Acrylsäure und Methacrylsäure. Die unter den Bezeichnungen Merquat^® 100 (Poly(dimethyldiallylammoniumchlorid)) und Merquat^® 550 (Dimethyldiallylammoniumchlorid-Acrylamid-Copolymer) im Handel erhältlichen Produkte sind Beispiele für solche kationischen Polymere,
• – Copolymere des Vinylpyrrolidons mit quaternierten Derivaten des Dialkylaminoalkylacrylats und -methacrylats, wie beispielsweise mit Diethylsulfat quaternierte Vinylpyrrolidon-Dimethylaminoethylmethacrylat-Copolymere. Solche Verbindungen sind unter den Bezeichnungen Gafquat^® 734 und Gafquat^® 755 im Handel erhältlich,
• – Vinylpyrrolidon-Vinylimidazoliummethochlorid-Copolymere, wie sie unter den Bezeichnungen Luviquat^® FC 370, FC 550, FC 905 und HM 552 angeboten werden,
• – quaternierter Polyvinylalkohol, sowie die unter den Bezeichnungen
• – olyquaternium 2, Polyquaternium 17, Polyquaternium 18, Polyquaternium-24, Polyquaternium 27, Polyquaternium-32, Polyquaternium-37, Polyquaternium 74 und Polyquaternium 89 bekannten Polymere.

Suitable cationic polymers are, for example:

• - quaternized cellulose derivatives, such as are available under the names of Celquat ^® and Polymer JR ^® commercially
• - hydrophobically modified cellulose derivatives, for example those sold under the trade name SOFTCAT ^® cationic polymers,
• Cationic alkyl polyglycosides,
• - cationized honey, for example the commercial product Honeyquat ^® 50,
• - cationic guar derivatives, such as in particular the products sold under the trade names Cosmedia® ^® Guar and Jaguar ^®,
• - Dimethyldiallylammoniumsalze polymeric and their copolymers with esters and amides of acrylic acid and methacrylic acid. Under the names Merquat ^® 100 (Poly (dimethyldiallylammonium chloride)) and Merquat ^® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers,
• - Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate, such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers. Such compounds are sold under the names Gafquat ^® 734 and Gafquat ^® 755 commercially,
• - vinylpyrrolidone vinylimidazoliummethochloride copolymers, such as those offered under the names Luviquat.RTM ^® FC 370, FC 550, FC 905 and HM 552,
• - Quaternized polyvinyl alcohol, as well as those under the names
• - Polyquaternium 2, Polyquaternium 17, Polyquaternium 18, Polyquaternium-24, Polyquaternium 27, Polyquaternium-32, Polyquaternium-37, Polyquaternium 74 and Polyquaternium 89 known polymers.

Further suitable cationic polymers are the so-called "temporary cationic" polymers. These polymers usually contain an amino group which, at certain pH values, is present as quaternary ammonium group and thus cationic. For example, chitosan and its derivatives are preferred as Hydagen CMF ^®, Hydagen HCMF ^®, Kytamer ^® PC and Chitolam ^® NB / 101 are freely available commercially, for example under the trade names. Chitosans are deacetylated chitins, which are commercially available in different degrees of deacetylation and different degrees of degradation (molecular weights).

Particularly preferred cationic polymers c) which can be used in the cosmetic cleansing compositions according to the invention are quaternized cellulose polymers, cationic guar derivatives and / or cationic polymers based on acrylic acid (derivative), which may be selected, for example, from the polymers Polyquaternium known under the INCI names -6, Polyquaternium-7, Polyquaternium-10, Polyquaternium-37 and / or Polyquaternium-67.

Particular preference is given to the cationic polymers guar hydroxypropyltrimonium chlorides, polyquaternium-6, polyquaternium-10 and / or polyquaternium-67 known under the INCI names.

• a) 0,01 bis 7,5 Gew.-% eines Polysiloxans der Formel (I), in der – x eine Zahl von 3 bis 120 bedeutet, – der Rest R¹ einen Phenylrest bedeutet, – die Reste R² bis R⁵ für Methylreste stehen, – der Rest R⁶ für einen Rest mit dem Aufbau -R⁷-R⁸ steht, wobei – die Gruppierung -R⁷- einer Gruppierung der Formel (II) entspricht, und – die Gruppe -R⁸ der Formel (VII) entspricht,
• b) 0,05 bis 7,5 Gew.-% Tensid(e) der Formel (iii),
• c) 0,01 bis 7,5 Gew.-% Tensid(e) der Formel (v) und
• d) 0,01 bis 5 Gew.-% mindestens eines kationischen Polymeren.

In a third preferred embodiment, a cosmetic cleaning agent according to the invention contains, based on its weight,

• a) 0.01 to 7.5 wt .-% of a polysiloxane of the formula (I), in which - x is a number from 3 to 120, - the radical R ^{1 is} a phenyl radical, - the radicals R ² to R ⁵ are methyl radicals, - the radical R ^{6 is} a radical having the structure -R ⁷ -R ⁸ , where - the grouping -R ⁷ - corresponds to a group of the formula (II), and - the group -R ^{8 of} the formula ( VII),
• b) 0.05 to 7.5% by weight of surfactant (s) of the formula (iii),
• c) 0.01 to 7.5 wt .-% of surfactant (s) of the formula (v) and
• d) 0.01 to 5 wt .-% of at least one cationic polymer.

• a) 0,05 bis 5 Gew.-% mindestens eines Polysiloxans mit der INCI-Bezeichnung Silicone Quaternium-22,
• b) 1 bis 2,5 Gew.-% Alkylamidoalkylbetain(e),
• c) 0,1 bis 2 Gew.-% Alkylampho(di)acetat(e) und
• d) 0,1 bis 2 Gew.-% mindestens eines der unter den INCI-Bezeichnungen bekannten kationischen Polymere Guar Hydroxypropyltrimonium Chloride, Polyquaternium-6, Polyquaternium-10 und/oder Polyquaternium-67 enthält.

Within this embodiment, it is particularly preferred if the cleaning agent according to the invention - based on its total weight -

• a) 0.05 to 5 wt .-% of at least one polysiloxane with the INCI name Silicone Quaternium-22,
• b) 1 to 2.5% by weight of alkylamidoalkylbetaine (e),
• c) 0.1 to 2 wt .-% Alkylampho (di) acetate (e) and
• d) 0.1 to 2 wt .-% of at least one of the known under the INCI names cationic polymers guar hydroxypropyltrimonium chlorides, Polyquaternium-6, Polyquaternium-10 and / or Polyquaternium-67 contains.

In a fourth preferred embodiment of the invention, the cosmetic cleansing compositions according to the invention are transparent. This embodiment may be preferred by consumers in some cases because it is aesthetically pleasing and has the advantage that the transparent phase and the phase dispersed therein (optionally containing dyes) can be better visualized.

"Transparent" cosmetic cleaning compositions are cleaning compositions whose non-dispersed (transparent) phase preferably has an NTU value (Nephelomteric Turbidity Unit) of not more than 100, more preferably not more than 75, particularly preferably not more than 50 and in particular not more than 30.

In a fifth preferred embodiment of the invention, the cosmetic cleaners contain - based on their weight - preferably 3 to 25 wt .-%, more preferably 4 to 20 wt .-% and in particular 5 to 15 wt .-% of at least one anionic surfactant.

• – lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen (Seifen),
• – Ethercarbonsäuren der Formel R-O-(CH₂-CH₂O)_x-CH₂-COOH, in der R eine lineare oder verzweigte, gesättigte oder ungesättigte Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 16 ist,
• – Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acyltauride mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acylisethionate mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Sulfobernsteinsäuremono- und/oder -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen,
• – Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen,
• – Alkylsulfat- und/oder Alkylpolyglykolethersulfatsalze der Formel R-O(CH₂-CH₂O)_x-OSO₃ ^–X⁺, in der R eine bevorzugt lineare oder verzweigte, gesättigte oder ungesättigte Alkylgruppe mit 8 bis 30 C-Atomen, x = 0 oder 1 bis 12 und X ein Alkali- oder Ammoniumion ist,
• – Sulfonate ungesättigter Fettsäuren mit 8 bis 24 C-Atomen und 1 bis 6 Doppelbindungen,
• – Ester der Weinsäure und Zitronensäure mit Alkoholen, die Anlagerungsprodukte von etwa 2–15 Molekülen Ethylenoxid und/oder Propylenoxid an Fettalkohole mit 8 bis 22 C-Atomen darstellen,
• – Alkyl- und/oder Alkenyletherphosphate der Formel,
  
  in der R¹ bevorzugt für einen aliphatischen Kohlenwasserstoffrest mit 8 bis 30 Kohlenstoffatomen, R² für Wasserstoff, einen Rest (CH₂CH₂O)_nR¹ oder X, n für Zahlen von 0 bis 10 und X für Wasserstoff, ein Alkali- oder Erdalkalimetall oder NR³R⁴R⁵R⁶, mit R³ bis R⁶ unabhängig voneinander stehend für einen C₁ bis C₄-Kohlenwasserstoffrest, steht.

Suitable anionic surfactants which may be used in the compositions of the invention include:

• - linear and branched fatty acids with 8 to 30 carbon atoms (soaps),
• Ether carboxylic acids of the formula RO- (CH ₂ -CH ₂ O) _x -CH ₂ -COOH, in which R is a linear or branched, saturated or unsaturated alkyl group having 8 to 30 C atoms and x = 0 or 1 to 16,
• Acylsarcosides having 8 to 24 C atoms in the acyl group,
• Acyltaurides having 8 to 24 carbon atoms in the acyl group,
• Acyl isethionates having 8 to 24 C atoms in the acyl group,
• Sulfosuccinic acid mono- and / or dialkyl esters having 8 to 24 C atoms in the alkyl group and sulfosuccinic acid monoalkyl polyoxyethyl esters having 8 to 24 C atoms in the alkyl group and 1 to 6 oxyethyl groups,
• Alpha-olefin sulfonates having 8 to 24 C atoms,
• - Alkyl sulfate and / or Alkylpolyglykolethersulfatsalze of the formula RO (CH ₂ -CH ₂ O) _x -OSO ₃ ^- X ⁺ , in which R is a preferably linear or branched, saturated or unsaturated alkyl group having 8 to 30 carbon atoms, x = 0 or 1 to 12 and X is an alkali or ammonium ion,
• Sulfonates of unsaturated fatty acids having 8 to 24 C atoms and 1 to 6 double bonds,
• Esters of tartaric acid and citric acid with alcohols which are adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols containing 8 to 22 carbon atoms,
• Alkyl and / or alkenyl ether phosphates of the formula
  
  in the R ^{1 is} preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms, R ^{2 is} hydrogen, a radical (CH ₂ CH ₂ O) _n R ¹ or X, n is from 0 to 10 and X is hydrogen, an alkali metal radical or alkaline earth metal or NR ³ R ⁴ R ⁵ R ⁶ , where R ³ to R ⁶ are each independently a C ₁ to C ₄ hydrocarbon radical.

Preferred anionic surfactants are ether carboxylic acids of the abovementioned formula, acylsarcosides having 8 to 24 C atoms in the acyl group, sulfosuccinic acid mono- and / or dialkyl esters having 8 to 24 C atoms in the alkyl group and sulfosuccinic acid monoalkylpolyoxyethyl esters having 8 to 24 C atoms in the alkyl group and 1 to 6 oxyethyl groups, alpha-olefin sulfonates having 8 to 24 carbon atoms and / or alkyl sulfate and / or Alkylpolyglykolethersulfatsalze the aforementioned formula.

Particularly preferred anionic surfactants are straight-chain or branched alkyl ether sulfates which contain an alkyl radical having 8 to 18 and in particular 10 to 16 C atoms and 1 to 6 and in particular 2 to 4 ethylene oxide units.

Further particularly preferred anionic surfactants are straight-chain or branched alkyl sulfonates which contain an alkyl radical having 8 to 18 and in particular 10 to 16 carbon atoms. Particular preference is given to the sodium, magnesium and / or triethanolamine salts of linear or branched lauryl, tridecyl and / or myristyl sulfates which have a degree of ethoxylation of from 2 to 4.

• a) 0,01 bis 7,5 Gew.-% eines Polysiloxans der Formel (I), in der – x eine Zahl von 3 bis 120 bedeutet, – der Rest R¹ einen Phenylrest bedeutet, – die Reste R² bis R⁵ für Methylreste stehen, – der Rest R⁶ für einen Rest mit dem Aufbau -R⁷-R⁶ steht, wobei – die Gruppierung -R⁷- einer Gruppierung der Formel (II) entspricht, und – die Gruppe -R⁶ der Formel (VII) entspricht,
• b) 0,05 bis 7,5 Gew.-% Tensid(e) der Formel (iii),
• c) 0,01 bis 7,5 Gew.-% Tensid(e) der Formel (v),
• d) 0,01 bis 5 Gew.-% mindestens eines kationischen Polymeren und
• e) 3 bis 25 Gew.-% mindestens eines anionischen Tensids.

In a sixth preferred embodiment, a cosmetic cleaning agent according to the invention contains, based on its weight,

• a) 0.01 to 7.5 wt .-% of a polysiloxane of the formula (I), in which - x is a number from 3 to 120, - the radical R ^{1 is} a phenyl radical, - the radicals R ² to R ⁵ are methyl radicals, - the radical R ^{6 is} a radical having the structure -R ⁷ -R ⁶ , where - the grouping -R ⁷ - corresponds to a group of the formula (II), and - the group -R ^{6 of} the formula ( VII),
• b) 0.05 to 7.5% by weight of surfactant (s) of the formula (iii),
• c) 0.01 to 7.5% by weight of surfactant (s) of the formula (v),
• d) 0.01 to 5 wt .-% of at least one cationic polymer and
• e) 3 to 25 wt .-% of at least one anionic surfactant.

• b) 0,05 bis 5 Gew.-% mindestens eines Polysiloxans mit der INCI-Bezeichnung Silicone Quaternium-22,
• b) 1 bis 2,5 Gew.-% Alkylamidoalkylbetain(e),
• c) 0,1 bis 2 Gew.-% Alkylampho(di)acetat(e)
• d) 0,1 bis 2 Gew.-% mindestens eines der unter den INCI-Bezeichnungen bekannten kationischen Polymere Guar Hydroxypropyltrimonium Chloride, Polyquaternium-6, Polyquaternium-10 und/oder Polyquaternium-67, und
• e) 5 bis 15 Gew.-% mindestens eines anionischen Tensids enthält, das ausgewählt ist aus geradkettigen oder verzweigten Alkylsulfonaten mit einem Alkylrest von 8 bis 18, insbesondere von 10 bis 16 C-Atomen und/oder geradkettigen oder verzweigten Alkyl(ether)sulfaten mit einem Alkylrest von 8 bis 18, insbesondere von 10 bis 16 C-Atomen und mit 0 bis 10, bevorzugt mit 1 bis 6 und insbesondere mit 2 bis 4, Ethylenoxideinheiten.

Within this embodiment, it is particularly preferred if the cleaning agent according to the invention - based on its total weight -

• b) from 0.05 to 5% by weight of at least one polysiloxane having the INCI name Silicone Quaternium-22,
• b) 1 to 2.5% by weight of alkylamidoalkylbetaine (e),
• c) 0.1 to 2% by weight of alkylampho (di) acetate (e)
• d) 0.1 to 2 wt .-% of at least one of the known under the INCI names cationic polymers guar hydroxypropyltrimonium chlorides, Polyquaternium-6, Polyquaternium-10 and / or Polyquaternium-67, and
• e) contains 5 to 15 wt .-% of at least one anionic surfactant which is selected from straight-chain or branched alkyl sulfonates having an alkyl radical of 8 to 18, in particular from 10 to 16 carbon atoms and / or straight-chain or branched alkyl (ether) sulfates with an alkyl radical of 8 to 18, in particular of 10 to 16 C atoms and with 0 to 10, preferably with 1 to 6 and in particular with 2 to 4, ethylene oxide units.

In a further preferred embodiment of the invention, the cosmetic cleaning compositions contain - based on their weight - preferably 0.01 to 10 wt .-%, more preferably 0.05 to 5 wt .-% and in particular 0.1 to 3 wt .-% at least one C ₂ -C ₄ mono- and / or dialkanolamide of at least one C ₈ -C ₂₄ carboxylic acid.

Particular preference is given to the mono- and / or diethanolamides of coconut fatty acids, as are commercially available, for example, under the INCI names Cocamide MEA and Cocamide DEA.

• a) 0,01 bis 7,5 Gew.-% eines Polysiloxans der Formel (I), in der – x eine Zahl von 3 bis 120 bedeutet, – der Rest R¹ einen Phenylrest bedeutet, – die Reste R² bis R⁵ für Methylreste stehen, – der Rest R⁶ für einen Rest mit dem Aufbau -R⁷-R⁸ steht, wobei – die Gruppierung -R⁷- einer Gruppierung der Formel (II) entspricht, und – die Gruppe -R⁸ der Formel (VII) entspricht,
• b) 0,05 bis 7,5 Gew.-% Tensid(e) der Formel (iii),
• c) 0,01 bis 7,5 Gew.-% Tensid(e) der Formel (v),
• d) 0,01 bis 5 Gew.-% mindestens eines kationischen Polymeren,
• e) 3 bis 25 Gew.-% mindestens eines anionischen Tensids und
• f) 0,01 bis 10 Gew.-% mindestens eines C₂-C₄-Mono- und/oder Dialkanolamids mindestens einer C₈-C₂₄-Carbonsäure.

In a seventh preferred embodiment, a cosmetic cleaning agent according to the invention contains, based on its weight,

• a) 0.01 to 7.5 wt .-% of a polysiloxane of the formula (I), in which - x is a number from 3 to 120, - the radical R ^{1 is} a phenyl radical, - the radicals R ² to R ⁵ are methyl radicals, - the radical R ^{6 is} a radical having the structure -R ⁷ -R ⁸ , where - the grouping -R ⁷ - corresponds to a group of the formula (II), and - the group -R ^{8 of} the formula ( VII),
• b) 0.05 to 7.5% by weight of surfactant (s) of the formula (iii),
• c) 0.01 to 7.5% by weight of surfactant (s) of the formula (v),
• d) from 0.01 to 5% by weight of at least one cationic polymer,
• e) 3 to 25 wt .-% of at least one anionic surfactant and
• f) 0.01 to 10 wt .-% of at least one C ₂ -C ₄ mono- and / or Dialkanolamids of at least one C ₈ -C ₂₄ carboxylic acid.

• a) 0,05 bis 5 Gew.-% mindestens eines Polysiloxans mit der INCI-Bezeichnung Silicone Quaternium-22,
• b) 1 bis 2,5 Gew.-% Alkylamidoalkylbetain(e),
• c) 0,1 bis 2 Gew.-% Alkylampho(di)acetat(e)
• d) 0,1 bis 2 Gew.-% mindestens eines der unter den INCI-Bezeichnungen bekannten kationischen Polymere Guar Hydroxypropyltrimonium Chloride, Polyquaternium-6, Polyquaternium-10 und/oder Polyquaternium-67,
• e) 5 bis 15 Gew.-% mindestens eines anionischen Tensids, das ausgewählt ist aus geradkettigen oder verzweigten Alkylsulfonaten mit einem Alkylrest von 8 bis 18, insbesondere von 10 bis 16 C-Atomen und/oder geradkettigen oder verzweigten Alkyl(ether)sulfaten mit einem Alkylrest von 8 bis 18, insbesondere von 10 bis 16 C-Atomen und mit 0 bis 10, bevorzugt mit 1 bis 6 und insbesondere mit 2 bis 4, Ethylenoxideinheiten, und
• f) 0,1 bis 3 Gew.-% mindestens eines unter der INCI-Bezeichnung Cocamide MEA oder Cocamide DEA bekannten Alkanolamids enthält.

Within this embodiment, it is particularly preferred if the cleaning agent according to the invention - based on its total weight -

• a) 0.05 to 5 wt .-% of at least one polysiloxane with the INCI name Silicone Quaternium-22,
• b) 1 to 2.5% by weight of alkylamidoalkylbetaine (e),
• c) 0.1 to 2% by weight of alkylampho (di) acetate (e)
• d) from 0.1 to 2% by weight of at least one of the cationic polymers guar hydroxypropyltrimonium chlorides, polyquaternium-6, polyquaternium-10 and / or polyquaternium-67 known under the INCI names,
• e) from 5 to 15% by weight of at least one anionic surfactant selected from straight-chain or branched alkyl sulfonates having an alkyl radical of 8 to 18, in particular of 10 to 16 carbon atoms and / or straight-chain or branched alkyl (ether) sulfates an alkyl radical of 8 to 18, in particular of 10 to 16 carbon atoms and having 0 to 10, preferably having 1 to 6 and in particular having 2 to 4, ethylene oxide units, and
• f) 0.1 to 3 wt .-% of at least one known under the INCI name cocamide MEA or cocamide DEA alkanolamide.

In addition to the aforementioned active ingredients, the cosmetic cleansing compositions according to the invention may also contain a number of other active ingredients which give them advantageous properties.

• – weitere nichtionische Tenside und/oder nichtionische Emulgatoren, die in den kosmetischen Reinigungsmitteln (bezogen auf ihr Gesamtgewicht) bevorzugt in einer Menge von 0,1 bis 7,5 Gew.-%, bevorzugt 0,25 bis 5 Gew.-% und insbesondere 0,5 bis 3 Gew.-% eingesetzt werden können,
• – weitere Öl-, Wachs- und/oder Fettkomponenten, die in den kosmetischen Reinigungsmitteln (bezogen auf ihr Gesamtgewicht) bevorzugt in einer Menge von 0,01–20 Gew.-%, besonders bevorzugt von 0,05–15 Gew.-% und insbesondere von 0,1–10 Gew.-% eingesetzt werden können,
• – Antischuppenwirkstoffe, die in den in den kosmetischen Reinigungsmitteln (bezogen auf ihr Gesamtgewicht) bevorzugt in einer Menge von 0,025 bis 7,5 Gew.-%, besonders bevorzugt von 0,05 bis 5 Gew.-% und insbesondere von 0,075 bis 3 Gew.-% eingesetzt werden können.

The preferred optional active substances that can be used in the cleaning agents according to the invention include, for example:

• - Further nonionic surfactants and / or nonionic emulsifiers, in the cosmetic detergents (based on their total weight) preferably in an amount of 0.1 to 7.5 wt .-%, preferably 0.25 to 5 wt .-% and in particular 0.5 to 3 wt .-% can be used,
• - Further oil, wax and / or fat components, in the cosmetic cleaning agents (based on their total weight) preferably in an amount of 0.01-20 wt .-%, particularly preferably from 0.05 to 15 wt .-% and in particular from 0.1-10% by weight,
• - Antidandruff active ingredients, which in the cosmetic cleaners (based on their total weight) preferably in an amount of 0.025 to 7.5 wt .-%, particularly preferably from 0.05 to 5 wt .-% and in particular from 0.075 to 3 wt .-% can be used.

• – C₈-C₃₀-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Glycerin,
• – Aminoxide,
• – Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – Sorbitanfettsäureester und Anlagerungeprodukte von Ethylenoxid an Sorbitanfettsäureester wie beispielsweise Polysorbate,
• – Zuckerfettsäureester und Anlagerungsprodukte von Ethylenoxid an Zuckerfettsäureester,
• – Alkylpolyglucoside.

Suitable further nonionic surfactants / emulsifiers include, for example

• C ₈ -C ₃₀ -fatty acid mono- and diesters of addition products of 1 to 30 mol of ethylene oxide with glycerol,
• - amine oxides,
• - Addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group,
• Sorbitan fatty acid esters and adducts of ethylene oxide with sorbitan fatty acid esters such as polysorbates,
• Sugar fatty acid esters and addition products of ethylene oxide with sugar fatty acid esters,
• - Alkyl polyglucosides.

Particularly suitable nonionic surfactants are alkyl oligoglucosides, in particular alkyl oligoglucosides based on hydrogenated C _12/14 coconut alcohol having a DP of 1-3, as are commercially available, for example, under the INCI name "Coco-Glucoside". Further preferred nonionic surfactants are the C ₈ -C ₃₀ fatty acid mono- and diesters of addition products of 1 to 30 moles of ethylene oxide with glycerol. Particularly preferred are the C ₁₀ -C ₁₆ -Fetsäuremono- and diesters of addition products of 1 to 10 moles of ethylene oxide to glycerol. Especially preferred is the PEG-7 glyceryl cocoate known under the INCI name.

Suitable oil and / or fat components may preferably be selected from mineral, natural and synthetic oil components and / or fatty substances.

As natural (vegetable) oils usually triglycerides and mixtures of triglycerides are used. Preferred natural oils are coconut oil, (sweet) almond oil, walnut oil, peach kernel oil, apricot kernel oil, avocado oil, tea tree oil, soybean oil, sesame oil, sunflower oil, tsubaki oil, evening primrose oil, rice bran oil, palm kernel oil, mango seed oil, meadowfoam seed oil, thistle oil, macadamia nut oil, grapeseed oil, Amaranth seed oil, argan oil, bamboo oil, olive oil, wheat germ oil, pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, canola oil, sasanqua oil, jojoba oil, rambutan oil, cocoa butter and shea butter.

As mineral oils are used in particular mineral oils, paraffin and Isoparaffinöle and synthetic hydrocarbons. An example of a usable hydrocarbon is for example that available as a commercial product 1,3-di- (2-ethylhexyl) -cyclohexane (Cetiol ^® S).

As the oil component may further serve a dialkyl ether.

Useful dialkyl ethers are in particular di-n-alkyl ethers having a total of from 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, di-n -undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n-undecyl n-dodecyl ether and n-hexyl n-undecyl ether and di tert-butyl ether, di-isopentyl ether, di-3-ethyl decyl ether, tert-butyl n-octyl ether, iso-pentyl n-octyl ether and 2-methylpentyl n-octyl ether.

Particularly preferred is the di-n-octyl ether, which is commercially available under the name Cetiol ^® OE.

Suitable synthetic oils are silicone compounds.

Silicones have excellent conditioning properties on the hair. In particular, they cause better combability of the hair in the wet and dry state and in many cases have a positive effect on the hair and the softness of the hair.

• (i) Polyalkylsiloxanen, Polyarylsiloxanen, Polyalkylarylsiloxanen, die flüchtig oder nicht flüchtig, geradkettig, verzweigt oder cyclisch, vernetzt oder nicht vernetzt sind;
• (ii) Polysiloxanen, die in ihrer allgemeinen Struktur eine oder mehrere organofunktionelle Gruppen enthalten, die ausgewählt sind unter: a) substituierten oder unsubstituierten aminierten Gruppen; b) (per)fluorierten Gruppen; c) Thiolgruppen; d) Carboxylatgruppen; e) hydroxylierten Gruppen; f) alkoxylierten Gruppen; g) Acyloxyalkylgruppen; h) amphoteren Gruppen; i) Bisulfitgruppen; j) Hydroxyacylaminogruppen; k) Carboxygruppen; l) Sulfonsäuregruppen; und m) Sulfat- oder Thiosulfatgruppen;
• (iii) linearen Polysiloxan(A)- Polyoxyalkylen(B)-Blockcopoylmeren vom Typ (A-B)_n mit n > 3;
• (iv) gepfropften Siliconpolymeren mit nicht siliconhaltigem, organischen Grundgerüst, die aus einer organischen Hauptkette bestehen, welche aus organischen Monomeren gebildet wird, die kein Silicon enthalten, auf die in der Kette sowie gegebenenfalls an mindestens einem Kettenende mindestens ein Polysiloxanmakromer gepfropft wurde;
• (v) gepfropften Siliconpolymeren mit Polysiloxan-Grundgerüst, auf das nicht siliconhaltige, organische Monomere gepfropft wurden, die eine Polysiloxan-Hauptkette aufweisen, auf die in der Kette sowie gegebenenfalls an mindestens einem ihrer Enden mindestens ein organisches Makromer gepfropft wurde, das kein Silicon enthält;
• (vi) oder deren Gemischen.

It is therefore desirable to use silicones in the cosmetic hair treatment compositions. Suitable silicones (other than silicone a) may be selected from:

• (i) polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes which are volatile or nonvolatile, straight chain, branched or cyclic, crosslinked or uncrosslinked;
• (ii) polysiloxanes containing in their general structure one or more organofunctional groups selected from: a) substituted or unsubstituted aminated groups; b) (per) fluorinated groups; c) thiol groups; d) carboxylate groups; e) hydroxylated groups; f) alkoxylated groups; g) acyloxyalkyl groups; h) amphoteric groups; i) bisulfite groups; j) hydroxyacylamino groups; k) carboxy groups; l) sulfonic acid groups; and m) sulfate or thiosulfate groups;
• (Iii) linear polysiloxane (A) - polyoxyalkylene (B) -Blockcopoylmeren type (AB) _n with n>3;
• (iv) grafted silicone polymers having a non-silicone organic backbone consisting of an organic backbone formed from organic monomers containing no silicone grafted with at least one polysiloxane macromer in the chain and optionally at least one chain end;
• (v) grafted polysiloxane backbone silicone polymers having grafted thereto non-silicone organic monomers having a polysiloxane backbone to which at least one organic macromer not containing silicone has been grafted in the chain, and optionally at least at one of its ends ;
• (vi) or mixtures thereof.

Fatty substances are to be understood fatty acids, fatty alcohols and natural and synthetic waxes which may be in solid form as well as liquid in aqueous dispersion. As fatty acids can be used linear and / or branched, saturated and / or unsaturated fatty acids with 6-30 carbon atoms. Preferred are fatty acids with 10-22 carbon atoms. Among these could be mentioned, for example, isostearic as the commercial products Emersol ^® 871 and Emersol ^® 875, and isopalmitic acids such as the commercial product Edenor ^® IP 95, and all other products sold under the trade names Edenor ^® (Cognis) fatty acids. Further typical examples of such fatty acids are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, Linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures.

Particularly preferred are usually the fatty acid cuttings obtainable from coconut oil or palm oil; In particular, the use of stearic acid is usually preferred. As fatty alcohols it is possible to use saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C ₆ -C ₃₀ -, preferably C ₁₀ -C ₂₂ - and very particularly preferably C ₁₂ -C ₂₂ -carbon atoms. For example, decanol, octanol, octenol, dodecenol, decenol, octadienol, dodecadienol, decadienol, oleyl alcohol, erucalcohol, ricinoleic alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, arachidyl alcohol, capryl alcohol, capric alcohol, linoleyl alcohol, linolenyl alcohol and behenyl alcohol, as well as their guerbet alcohols can be used , this list should have exemplary and non-limiting character. However, the fatty alcohols are derived from preferably natural fatty acids, which can usually be based on recovery from the esters of fatty acids by reduction. Also usable according to the invention are those fatty alcohol cuts which are produced by reduction of naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or fatty acid esters formed from their transesterification products with corresponding alcohols, and thus represent a mixture of different fatty alcohols. Such substances are, for example, under the names Stenol ^® , z. B. Stenol ^® 1618 or Lanette ^®, z. B. Lanette ^® O or Lorol ^®, z. B. Lorol® ^® C8, Lorol® ^® C14, C18 Lorol® ^{®, ®} Lorol® C8-18, HD Ocenol ^®, Crodacol ^®, z. B. Crodacol CS ^{®, ®} Novol, Eutanol ^® G, Guerbitol ^® 16, Guerbitol ^® 18, Guerbitol ^® 20, Isofol ^® 12, Isofol ^® 16, Isofol ^® 24, Isofol ^® 36, Isocarb 12 ^{®, ®} Isocarb 16 or Isocarb ^® 24 for sale. It is of course also possible according to the invention to use WoLlwachsalkohole, as they are commercially available, for example, under the names Corona ^® , White Swan ^® , Coronet ^® or Fluilan ^® . As natural or synthetic waxes there may be used solid paraffins or isoparaffins, carnauba waxes, beeswaxes, candelilla waxes, ozokerites, ceresin, spermaceti, sunflower wax, fruit waxes such as apple wax or citrus wax, microwaxes of PE or PP. Such waxes are available, for example, from Kahl & Co., Trittau.

• – Esteröle. Unter Esterölen sind zu verstehen die Ester von C₆-C₃₀-Fettsäuren mit C₂-C₃₀-Fettalkoholen. Bevorzugt sind die Monoester der Fettsäuren mit Alkoholen mit 2 bis 24 C-Atomen. Beispiele für eingesetzte Fettsäurenanteile in den Estern sind Capronsäure, Caprylsäure, 2-Ethylhexansäure, Caprinsäure, Laurinsäure, Isotridecansäure, Myristinsäure, Palmitinsäure, Palmitoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Linolsäure, Linolensäure, Elaeostearinsäure, Arachinsäure, Gadoleinsäure, Behensäure und Erucasäure sowie deren technische Mischungen. Beispiele für die Fettalkoholanteile in den Esterölen sind Isopropylalkohol, Capronalkohol, Caprylalkohol, 2-Ethylhexylalkohol, Caprinalkohol, Laurylalkohol, Isotridecylalkohol, Myristylalkohol, Cetylalkohol, Palmoleylalkohol, Stearylalkohol, Isostearylalkohol, Oleylalkohol, Elaidylalkohol, Petroselinylalkohol, Linolylalkohol, Linolenylalkohol, Elaeostearylalkohol, Arachylalkohol, Gadoleylalkohol, Behenylalkohol, Erucylalkohol und Brassidylalkohol sowie deren technische Mischungen. Besonders bevorzugt sind Isopropylmyristat (Rilanit^® IPM), Isononansäure-C16-18-alkylester (Cetiol^® SN), 2-Ethylhexylpalmitat (Cegesoft^® 24), Stearinsäure-2-ethylhexylester (Cetiol^® 868), Cetyloleat, Glycerintricaprylat, Kokosfettalkoholcaprinat/-caprylat (Cetiol^® LC), n-Butylstearat, Oleylerucat (Cetiol^® J 600), Isopropylpalmitat (Rilanit^® IPP), Oleyl Oleate (Cetiol^®), Laurinsäurehexylester (Cetiol^® A), Di-n-butyladipat (Cetiol^® B), Myristylmyristat (Cetiol^® MM), Cetearyl Isononanoate (Cetiol^® SN), Ölsäuredecylester (Cetiol^® V).
• – Dicarbonsäureester wie Di-n-butyladipat, Di-(2-ethylhexyl)-adipat, Di-(2-ethylhexyl)-succinat und Di-isotridecylacelaat sowie Diolester wie Ethylenglykol-dioleat, Ethylenglykol-di-isotridecanoat, Propylenglykol-di(2-ethylhexanoat), Propylenglykol-di-isostearat, Propylenglykol-di-pelargonat, Butandiol-di-isostearat, Neopentylglykoldicaprylat,
• – symmetrische, unsymmetrische oder cyclische Ester der Kohlensäure mit Fettalkoholen,
• – Glycerincarbonat oder Dicaprylylcarbonat (Cetiol^® CC),
• – ethoxylierte oder nicht ethoxylierte Mono,- Di- und Trifettsäureester von gesättigten und/oder ungesättigten linearen und/oder verzweigten Fettsäuren mit Glycerin, wie beispielsweise Monomuls^® 90-O18, Monomuls^® 90-L12, Cetiol^® HE oder Cutina^® MD.

Other fatty substances are, for example

• - Ester oils. Ester oils are understood as meaning the esters of C ₆ -C ₃₀ -fatty acids with C ₂ -C ₃₀ -fatty alcohols. The monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms are preferred. Examples of fatty acid components used in the esters are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and Erucic acid and its technical mixtures. Examples of the fatty alcohol components in the ester oils are isopropyl alcohol, caproic alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol, Behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures. Particularly preferred are isopropyl myristate (IPM Rilanit ^®), isononanoic acid C16-18 alkyl ester (Cetiol ^® SN), 2-ethylhexyl palmitate (Cegesoft ^® 24), stearic acid-2-ethylhexyl ester (Cetiol ^® 868), cetyl oleate, glycerol tricaprylate, Kokosfettalkoholcaprinat / - caprylate (Cetiol ^® LC), n-butyl stearate, oleyl erucate (Cetiol ^® J 600), isopropyl palmitate (Rilanit ^® IPP), oleyl Oleate (Cetiol ^®), hexyl laurate (Cetiol ^® A), di-n-butyl adipate (Cetiol ^® B) , myristyl myristate (Cetiol ^® MM), Cetearyl Isononanoate (Cetiol ^® SN), decyl oleate (Cetiol ^® V).
• Dicarboxylic acid esters such as di-n-butyl adipate, di (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate, and diol esters such as ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2 ethylhexanoate), propylene glycol diisostearate, propylene glycol di-pelargonate, butanediol diisostearate, neopentyl glycol dicaprylate,
• Symmetrical, unsymmetrical or cyclic esters of carbonic acid with fatty alcohols,
• - glycerol carbonate or dicaprylyl ether (Cetiol ^® CC)
• - ethoxylated or non ethoxylated mono, - di- and trifatty acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol such as ^® Monomuls 90-O18, Monomuls 90-L12 ^®, Cetiol ^® HE or Cutina ^® MD.

Suitable antidandruff active ingredients may be selected from Piroctone olamine, climbazole, zinc pyrithione, ketoconazole, salicylic acid, sulfur, selenium sulfide, tar preparations, undecenoic acid derivatives, burdock root extracts, poplar extracts, nettle extracts, walnut shell extracts, birch extracts, willow bark extracts, rosemary extracts and / or arnica extracts.

Preferred are climbazole, zinc pyrithione and piroctone olamine.

• – Vitamine, Vitaminderivate und/oder Vitaminvorstufen,
• – Pflanzenextrakte und/oder
• – Feuchthaltemittel.

Other optional components that may be used in the detergents of the invention include, for example

• - vitamins, vitamin derivatives and / or vitamin precursors,
• - Plant extracts and / or
• - Humectants.

• • Vitamin B₁ (Thiamin)
• • Vitamin B₂ (Riboflavin)
• • Vitamin B₃. Unter dieser Bezeichnung werden häufig die Verbindungen Nicotinsäure und Nicotinsäureamid (Niacinamid) geführt.
• • Vitamin B₅ (Pantothensäure und Panthenol). Im Rahmen dieser Gruppe wird bevorzugt das Panthenol eingesetzt. Einsetzbare Derivate des Panthenols sind insbesondere die Ester und Ether des Panthenols sowie kationisch derivatisierte Panthenole. Einzelne Vertreter sind beispielsweise das Panthenoltriacetat, der Panthenolmonoethylether und dessen Monoacetat sowie kationische Panthenolderivate.
• • Vitamin B₆ (Pyridoxin sowie Pyridoxamin und Pyridoxal).

Vitamin C (Ascorbinsäure): die Verwendung in Form des Palmitinsäureesters, der Glucoside oder Phosphate kann bevorzugt sein. Die Verwendung in Kombination mit Tocopherolen kann ebenfalls bevorzugt sein.
Vitamin E (Tocopherole, insbesondere α-Tocopherol).
Vitamin F: unter dem Begriff ”Vitamin F” werden üblicherweise essentielle Fettsäuren, insbesondere Linolsäure, Linolensäure und Arachidonsäure, verstanden.
Vitamin H: Als Vitamin H wird die Verbindung (3aS,4S,6aR)-2-Oxohexahydrothienol[3,4-d]-imidazol-4-valeriansäure bezeichnet, für die sich aber zwischenzeitlich der Trivialname Biotin durchgesetzt hat.Suitable vitamins are preferably the following vitamins, provitamins and vitamin precursors and their derivatives:
Vitamin A: the group of substances called vitamin A includes retinol (vitamin A ₁ ) and 3,4-didehydroretinol (vitamin A ₂ ). The β-carotene is the provitamin of retinol. As vitamin A component, for example, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as palmitate and acetate into consideration.
Vitamin B: belong to the vitamin B group or to the vitamin B complex among others

• • Vitamin B ₁ (thiamine)
• • Vitamin B ₂ (riboflavin)
• • Vitamin B ₃ . Under this name, the compounds nicotinic acid and nicotinamide (niacinamide) are often performed.
• • Vitamin B ₅ (pantothenic acid and panthenol). Within this group the panthenol is preferred. Useful derivatives of panthenol are, in particular, the esters and ethers of panthenol, as well as cationically derivatized panthenols. Individual representatives are, for example, panthenol triacetate, panthenol monoethyl ether and its monoacetate, as well as cationic panthenol derivatives.
• • Vitamin B ₆ (pyridoxine and pyridoxamine and pyridoxal).

Vitamin C (ascorbic acid): use in the form of palmitic acid ester, glucosides or phosphates may be preferred. The use in combination with tocopherols may also be preferred.
Vitamin E (tocopherols, especially α-tocopherol).
Vitamin F: the term "vitamin F" is usually understood as meaning essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.
Vitamin H: Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] -imidazole-4-valeric acid, for which, in the meantime, the trivial name biotin has prevailed.

The cosmetic cleansing compositions according to the invention may preferably contain vitamins, provitamins and vitamin precursors from groups A, B, E and H.

Particularly preferred are nicotinic acid amide, biotin, pantolactone and / or panthenol. Vitamins, vitamin derivatives and / or vitamin precursors may be present in the hair cleansing and / or hair conditioning agents (based on their total weight) preferably in an amount of 0.001 to 10% by weight, preferably 0.005 to 7.5% by weight and in particular 0.01 be used to 5 wt .-%.

Suitable plant extracts are extracts that can be made from any part of a plant.

Usually these extracts are produced by extraction of the whole plant. However, in individual cases it may also be preferred to prepare the extracts exclusively from flowers and / or leaves of the plant.

Particularly suitable are the extracts of green tea, oak bark, stinging nettle, witch hazel, hops, chamomile, burdock root, horsetail, linden, lychee, almond, aloe vera, spruce needle, horse chestnut, sandalwood, juniper, coconut, mango, apricot, lime , Wheat, Kiwi, Melon, Orange, Grapefruit, Sage, Rosemary, Birch, Mallow, Meadowfoam, Quendel, Yarrow, Thyme, Melissa, Hominy, Coltsfoot, Marshmallow, Ginseng, Ginger root, Echinacea purpurea, Olea europea, Boerhavia diffusa roots, Foeniculum vulgaris and Apim graveolens.

Particularly preferred for use in the hair treatment compositions according to the invention are the extracts of green tea, stinging nettle, witch hazel, chamomile, aloe vera, ginseng, Echinacea purpurea, Olea europea and / or Boerhavia diffusa roots.

As extraction agent for the preparation of said plant extracts water, alcohols and mixtures thereof can be used. Among the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as sole extractant as well as in admixture with water, preferred. Plant extracts based on water / propylene glycol in a ratio of 1:10 to 10: 1 have proven to be particularly suitable.

The plant extracts can be used both in pure and in diluted form. If they are used in diluted form, they usually contain about 2-80 wt .-% of active substance and as a solvent used in their extraction agent or extractant mixture.

The plant extracts may be present in the inventive compositions (based on their total weight) preferably in an amount of from 0.01 to 10% by weight, more preferably from 0.05 to 7.5% by weight and in particular from 0.1 to 5 % By weight.

Suitable humectants or penetrants and / or swelling agents which can be added to the cleaning compositions according to the invention are, for example, urea and urea derivatives, guanidine and its derivatives, arginine and its derivatives, water glass, imidazole and its derivatives, histidine and its derivatives, benzyl alcohol, glycerol, Glycol and glycol ethers, propylene glycol and propylene glycol ethers, for example propylene glycol monoethyl ether, carbonates, bicarbonates, diols and triols, and in particular 1,2-diols and 1,3-diols such as 1,2-propanediol, 1,2-pentanediol, 1,2- Hexanediol, 1,2-dodecanediol, 1,3-propanediol, 1,6-hexanediol, 1,5-pentanediol, 1,4-butanediol.

The humectants may in the compositions of the invention - based on the total weight - preferably in amounts of 0.01 to 10 wt .-%, more preferably in amounts of 0.05 to 5 wt .-% and in particular in amounts of 0.1 to 3 wt .-% are used.

• – UV-Filter,
• – Verdickungsmittel wie Gelatine oder Pflanzengumme, beispielsweise Agar-Agar, Guar-Gum, Alginate, Xanthan-Gum, Gummi arabicum, Karaya-Gummi, Johannisbrotkernmehl, Leinsamengummen, Dextrane, Cellulose-Derivate, z. B. Methylcellulose, Hydroxyalkylcellulose und Carboxymethylcellulose, Stärke-Fraktionen und Derivate wie Amylose, Amylopektin und Dextrine, Tone und Schichtsilikate wie z. B. Bentonit oder vollsynthetische Hydrokolloide wie z. B. Polyvinylalkohol, die Ca-, Mg- oder Zn-Seifen,
• – Strukturanten wie Maleinsäure und Milchsäure,
• – Farbstoffe zum Anfärben des Mittels,
• – Substanzen zur Einstellung des pH-Wertes, beispielsweise α- und β-Hydroxycarbonsäuren wie Citronensäure, Milchsäure, Äpfelsäure, Glycolsäure,
• – Wirkstoffe wie Bisabolol,
• – Komplexbildner wie EDTA, NTA, β-Alanindiessigsäure und Phosphonsäuren,
• – Ceramide. Unter Ceramiden werden N-Acylsphingosin (Fettsäureamide des Sphingosins) oder synthetische Analogen solcher Lipide (sogenannte Pseudo-Ceramide) verstanden,
• – Treibmittel wie Propan-Butan-Gemische, N₂O, Dimethylether, CO₂ und Luft,
• – Antioxidantien,
• – Perlglanzmittel wie EGDS oder PEG-3 Distearate,
• – Konservierungsmittel, wie beispielsweise Natriumbenzoat oder Salicylsäure,
• – Viskositätsregler wie Salze (NaCl).

Further active ingredients, auxiliaries and additives which can be used in the hair cleansing compositions according to the invention are, for example:

• - UV filters,
• Thickeners such as gelatin or vegetable gums, for example agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. As methylcellulose, hydroxyalkylcellulose and carboxymethylcellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays and phyllosilicates such. As bentonite or fully synthetic hydrocolloids such. As polyvinyl alcohol, the Ca, Mg or Zn soaps,
• - structurants such as maleic acid and lactic acid,
• Dyes for staining the agent,
• Substances for adjusting the pH, for example α- and β-hydroxycarboxylic acids such as citric acid, lactic acid, malic acid, glycolic acid,
• - active substances such as bisabolol,
• Complexing agents such as EDTA, NTA, β-alaninediacetic acid and phosphonic acids,
• - Ceramides. Ceramides are understood as meaning N-acylsphingosine (fatty acid amides of sphingosine) or synthetic analogues of such lipids (so-called pseudo-ceramides),
• Propellants such as propane-butane mixtures, N ₂ O, dimethyl ether, CO ₂ and air,
• - antioxidants,
• Pearlescing agents such as EGDS or PEG-3 distearates,
• Preservatives, such as sodium benzoate or salicylic acid,
• - Viscosity regulator such as salts (NaCl).

The cosmetic cleansing compositions according to the invention preferably have pH values in the range from 2 to 7, preferably from 3 to 6 and in particular from 4.5 to 5.5.

The cleaning agents of the invention have excellent properties in the application to the hair.

In addition to cleaning, they give the treated hair better visual and tactile properties.

Treated dry hair (especially damaged hair) has an improved hair grip and improved combability.

Treated wet hair (especially damaged hair) have less or no knots and can be easily untangled.

Another advantage of the cleaning agents according to the invention is that they support the resistance of the hair surface to physical and / or chemical hair damage.

Another advantage is that transparent cleaning compositions can be produced.

A second object of the invention is the use of a cosmetic cleaning agent according to the invention for improving the feel and combability of wet and dry hair and for improving the resistance of the hair surface to physical and / or chemical hair damage.

Examples:

1) Preparation of inventive (I) / non-inventive shampoos (II-V): 1 II III IV V Sodium Laureth Sulfate 10.5 10.5 10.5 10.5 10.5 Disodium Cocoamphodiacetate 1.2 3 1.2 Cocamidopropyl betaines 1.5 3 3 1.5 Cocamide MEA 0.4 0.4 0.4 0.4 0.4 PEP-120 methyl glucose dioleate 0.2 0.2 0.2 0.2 0.2 Amodimethicone (Wacker ^Belsil®1 ADM 8020) 1 1 Silicone Quaternium-22 ( ^Abil®2 T Quat 60) 1 1 1 Polyquaternium-67 0.4 0.4 0.4 0.4 0.4 PEG-40 Hydrogenated Castor Oil 0.1 0.1 0.1 0.1 0.1 Perfume, preservative qs qs qs qs qs Citric acid (up to pH 4.9 to 5.1) 0.2-0.6 0.2-0.6 0.2-0.6 0.2-0.6 0.2-0.6 NaCl (to viscosity 8,000 to 10,000 [Brookfield 20RM / 20 ° C] +/- 1000 mPas) 1-1,5 1-1,5 1-1,5 1-1,5 1-1,5 water ad 100 ad 100 ad 100 ad 100 ad 100

• 1 INCI-Bezeichnung: Amodimethicone, Trideceth-5, Glycerin, Trideceth-10; (Wacker)
• 2 INCI-Bezeichnung: Silicone Quaternium-22 (65%), PPG-3 Myristyl Ether (35%); (Evonik),

The following commercial products were used:

• 1 INCI name: Amodimethicone, Trideceth-5, Glycerin, Trideceth-10; (Wacker)
• 2 INCI name: Silicone Quaternium-22 (65%), PPG-3 Myristyl Ether (35%); (Evonik)

2) Assessment of shampoos:

2.1 Assessment of wet combability

a) Hair strands / measuring device:

Hair strands of the company Kerling International (Backnang, Germany) were used: European natural hair 7/0; lot # 04/2010; N72; Length: 12 cm; Weight: 1 +/- 0.05 g. Measuring instrument: Hercules Sägemann (Hamburg, Germany) and hard rubber comb, fine-toothed

b) Treatment of the hair strands and measurement:

The strands of hair were first predamaged by bleaching twice and then stored at 25 ° C and 25% humidity for 48 hours. 0.25 g of the respective shampoo were applied per g of hair strand.

After 2 minutes, the hair tresses were rinsed with water (32 ° C, 0.5 L / min) for 18 seconds while being automatically combed. This procedure was repeated again.

Before the measurement, each strand of hair was moistened with water for 2 seconds. After combing each strand of hair (3 strokes), each strand of hair was combed 10 times, measuring the work done (the hair strands were slowly rotated).

The work done was related to the reduction of wet combability. (The higher the numerical value for reducing wet combability, the lower the work required to pull the comb through the hair strand). For each shampoo wet combability was measured on 12 strands of hair. b) Result: I II III IV V Reduction of wet combability (%) 81 66 59 64 76

2.2 Assessment of disentanglement and hairgrip in hairstrip tests by experts

In a second test, four strands of hair were evaluated by two independent experts (a, b) with respect to the entanglement (wet) and the feel (softness, suppleness) of the hair strands in a dry state in four test series.

The hair strands used were machine straps made of Euro-natural-hair; draw; pulled twice; Color 7/0; 3 cm wide, 25 cm total length; about 2 g total weight (Kerling Int. Haarfabrik GmbH).

The hair tresses were previously pretreated by treating with a hair dye (80 g "Igora Royal color & care developer" mixed with 20 g "Igora blue dust-free bleach") and rinsing with water after 30 minutes for 20 seconds ,

Subsequently, the strands were washed with 1 ml each of a 10% sodium lauryl ether sulfate solution, rinsed with water for 20 seconds, and wrung out.

1 g of each test shampoo was filled in each case a Petri dish. Subsequently, the previously damaged strands of hair were briefly immersed in the respective test shampoos and rinsed with water.

The tresses were evaluated by the two experts in dry and wet condition (see below).

+2

signifikant besser als der Standard (Zusammensetzung V)

+1

leicht besser als der Standard (Zusammensetzung V)

0

vergleichbar zum Standard (Zusammensetzung V)

–1

leicht verschlechtert gegenüber dem Standard (Zusammensetzung V)

–2

signifikant verschlechtert gegenüber dem Standard (Zusammensetzung V)

Versuchsreihe 1 Zusammensetzung I gegen Zusammensetzung V Haarsträhnen (1–3) 1 2 3 Durchschnitt Experten (a, b) a b a b a b Entwirrbarkeit 1 1 1 0 1 0 0,7 Geschmeidigkeit 1 0 1 0 1 0 0,5 Versuchsreihe 2 Zusammensetzung II gegen Zusammensetzung V Haarsträhnen (1–3) 1 2 3 Durchschnitt Experten (a, b) a b a b a b Entwirrbarkeit 0 –1 –1 –1 –2 –1 –1,0 Geschmeidigkeit 1 0 –1 0 –1 –1 –0,3 Versuchsreihe 3 Zusammensetzung III gegen Zusammensetzung V Haarsträhnen (1–3) 1 2 3 Durchschnitt Experten (a, b) a b a b a b Entwirrbarkeit –1 0 –1 –1 0 –1 –0,7 Geschmeidigkeit 0 1 0 0 0 0 0,2 Versuchsreihe 4 Zusammensetzung IV gegen Zusammensetzung V Haarsträhnen (1–3) 1 2 3 Durchschnitt Experten (a, b) a b a b a b Entwirrbarkeit 0 0 –1 –1 0 1 –0,2 Geschmeidigkeit –1 1 0 0 1 –1 0 The grading scale +2, +1, 0, -1, -2 means:

+2

significantly better than the standard (Composition V)

+1

slightly better than the standard (Composition V)

0

comparable to the standard (composition V)

-1

slightly worse than the standard (Composition V)

-2

significantly worse than the standard (composition V)

Test series 1 Composition I vs Composition V Hair strands (1-3) 1 2 3 average Experts (a, b) a b a b a b detangling 1 1 1 0 1 0 0.7 suppleness 1 0 1 0 1 0 0.5 Series 2 Composition II vs Composition V Hair strands (1-3) 1 2 3 average Experts (a, b) a b a b a b detangling 0 -1 -1 -1 -2 -1 -1.0 suppleness 1 0 -1 0 -1 -1 -0.3 Trial Series 3 Composition III vs Composition V Hair strands (1-3) 1 2 3 average Experts (a, b) a b a b a b detangling -1 0 -1 -1 0 -1 -0.7 suppleness 0 1 0 0 0 0 0.2 Trial 4 Composition IV vs. Composition V Hair strands (1-3) 1 2 3 average Experts (a, b) a b a b a b detangling 0 0 -1 -1 0 1 -0.2 suppleness -1 1 0 0 1 -1 0

QUOTES INCLUDE IN THE DESCRIPTION

This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Cited patent literature

• DE 102008041020 [0007]

Claims (10)

Cosmetic cleanser containing in a cosmetically acceptable carrier a) at least one polysiloxane of the following formula (I)

in which R ¹ to R ⁵ independently of one another are a radical from the group consisting of alkyl, aryl or alkylaryl having 1 to 30 C atoms, R ^{6 is} a radical which carries at least one quaternary ammonium group, n is the number 3 and - x is an integer in the range from 2 to 200, and b) at least two amphoteric and / or zwitterionic surfactants from the groups of the following formulas (i) to (v), in which the radical R is in each case a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms,

with the proviso that surfactants from at least two of groups (i) to (v) are included in the composition. Cosmetic cleaning agent according to claim 1, characterized in that in formula (I) - the radical R ^{1 is} an aryl radical, preferably a phenyl radical, - the radicals R ² to R ^{5 are the} same C ₁ -C ₄ -alkyl radicals, preferably methyl radicals , - the radical R ^{6 is} a radical having the structure -R ⁷ -R ⁸ , wherein - the grouping -R ⁷ - is at least one grouping of the following formulas (II) to (V)

in which y is a number from 2 to 18, z is a number from 0 to 3 and R ^{9 is} hydrogen, a C ₁ -C ₄ -alkyl group, a C ₂ -C ₄ -hydroxyalkyl group or an -OH group, and the group -R ⁸ corresponds to at least one of the following formulas (VI) or (VII),

in which R ¹⁰ and R ^{12 are} each independently of one another hydrogen or an alkyl radical having 1 to 30 C atoms, R ^{11 is} an alkyl radical having 1 to 30 C atoms or a grouping - (CH ₂ ) _b -NR ¹⁰ R ¹² in which b is a number from 2 to 18, R ^{13 is} a grouping -O- or -N (H) -, R ^{14 is} an alkyl radical having 1 to 30 carbon atoms, a is a number of 2 to 18 and A ^{- stands} for inorganic or organic acid anions. Cosmetic cleaning agent according to one of claims 1 or 2, characterized in that in formula (I) - the radical R ^{1 is} a phenyl radical, - the radicals R ² to R ^{8 are} methyl radicals, - the radical R ^{6 is} a radical with the Structure -R ⁷ -R ⁸ , wherein - the group -R ⁷ - corresponds to a group of the formula (II) in which y is the number 3, z is the number 1 and R ^{9 is} an -OH group, and - the Group -R ⁸ corresponds to the formula (VII) in which R ¹⁰ and R ^{12 are} methyl groups, a is the number 3, R ^{13 is} the grouping -N (H) - and R ^{14 is} a C ₈ -C ₁₈ -alkyl group. Cosmetic cleaning agent according to one of claims 1 to 3, characterized in that it - based on its total weight - 0.01 to 7.5 wt .-%, preferably 0.05 to 5 wt .-% and in particular 0.2 to 3 Wt .-% of the polysiloxane a). Cosmetic cleaning agent according to one of claims 1 to 4, characterized in that it - based on its weight - 0.05 to 7.5 wt .-%, preferably 0.5 to 5 wt .-% and in particular 1 to 2.5 % By weight of surfactant (s) of the formula (iii) and 0.01 to 7.5% by weight, preferably 0.05 to 3% by weight and in particular 0.1 to 2% by weight of surfactant (e ) of formula (v). Cosmetic cleaning agent according to one of claims 1 to 5, characterized in that it - based on its total weight - 0.01 to 5 wt .-%, preferably 0.05 to 3 wt .-% and in particular 0.1 to 2 wt. -% of a cationic polymer c) contains. Cosmetic cleaning agent according to claim 6, characterized in that the cationic polymer c) is selected from polymers having the INCI names guar hydroxypropyltrimonium chlorides, polyquaternium-6, polyquaternium-10 and / or polyquaternium-67. Cosmetic cleaning agent according to one of claims 1 to 7, characterized in that it - based on its weight - 3 to 25 wt .-%, preferably 4 to 20 wt .-% and in particular 5 to 15 wt .-% of at least one anionic surfactant which is selected from straight-chain or branched alkyl sulfonates having an alkyl radical of 8 to 18, in particular of 10 to 16 carbon atoms and / or straight-chain or branched alkyl (ether) sulfates having an alkyl radical of 8 to 18, in particular from 10 to 16 C atoms and with 0 to 10, preferably with 1 to 6 and in particular with 2 to 4, ethylene oxide units. Cosmetic cleaning agent according to one of claims 1 to 8, characterized in that it - based on its weight - 0.01 to 10 wt .-%, preferably 0.05 to 5 wt .-% and in particular 0.1 to 3 wt. -% of at least one C ₂ -C ₄ mono- and / or dialkanolamide of at least one C ₈ -C ₂₄ carboxylic acid. Use of a cosmetic cleaning agent according to any one of claims 1 to 9 for improving the feel and combability of wet and dry hair and for improving the resistance of the hair surface against physical and / or chemical hair damage.