DE102009034140A1 - Use of new or known 2-hexyl decanol ester with fatty acid compound as oil body, and in and/or for preparing pharmaceutical and/or cosmetic preparations, e.g. hair shampoos, hair lotions, foam baths, creams, gels and lotions - Google Patents
Use of new or known 2-hexyl decanol ester with fatty acid compound as oil body, and in and/or for preparing pharmaceutical and/or cosmetic preparations, e.g. hair shampoos, hair lotions, foam baths, creams, gels and lotions Download PDFInfo
- Publication number
- DE102009034140A1 DE102009034140A1 DE200910034140 DE102009034140A DE102009034140A1 DE 102009034140 A1 DE102009034140 A1 DE 102009034140A1 DE 200910034140 DE200910034140 DE 200910034140 DE 102009034140 A DE102009034140 A DE 102009034140A DE 102009034140 A1 DE102009034140 A1 DE 102009034140A1
- Authority
- DE
- Germany
- Prior art keywords
- inci
- cetiol
- hexyldecyl
- lotions
- cognis gmbh
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/003—Esters of saturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
- C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
Description
Gebiet der ErfindungField of the invention
Die Erfindung betrifft Ester von Hexyldodecanol mit kurzkettigen Fettsäuren und ihre Verwendung in kosmetischen und/oder pharmazeutischen Zubereitungen.The This invention relates to esters of hexyldodecanol with short chain fatty acids and their use in cosmetic and / or pharmaceutical preparations.
Stand der TechnikState of the art
Im Bereich kosmetischer Zubereitungen für die Haut- und Haarpflege sowie im Bereich pharmazeutischer Zubereitungen werden vom Verbraucher eine Vielzahl von Anforderungen gestellt: Abgesehen von den reinigenden und pflegenden Effekten, die den Anwendungszweck bestimmen, wird Wert auf so unterschiedliche Parameter wie höchstmögliche dermatologische Verträglichkeit, gute rückfettende Eigenschaften, elegantes Erscheinungsbild, optimaler sensorischer Eindruck und Lagerstabilität gelegt.in the Area of cosmetic preparations for skin and hair care as well as in the field of pharmaceutical preparations are by the consumer a variety of requirements: Apart from the cleaning and nurturing effects that determine the intended use Value as different parameters as possible dermatological compatibility, good moisturizing Characteristics, elegant appearance, optimal sensory Impression and storage stability.
Zubereitungen, die zur Reinigung und Pflege der menschlichen Haut und der Haare eingesetzt werden, enthalten in der Regel neben einer Reihe von oberflächenaktiven Substanzen, vor allem Ölkörper und Wasser. Als Ölkörper/Emollients werden beispielsweise Kohlenwasserstoffe, Esteröle sowie pflanzliche und tierische Öle/Fette/Wachse eingesetzt. Um die hohen Anforderungen des Marktes bezüglich sensorischer Eigenschaften und optimaler dermatologischer Verträglichkeit zu erfüllen, werden kontinuierlich neue Ölkörper entwickelt und getestet.preparations to clean and care for human skin and hair Usually used in addition to a number of Surface-active substances, especially oil bodies and water. For example, oil bodies / emollients Hydrocarbons, ester oils and vegetable and animal oils / fats / waxes used. To meet the high demands of the market sensory properties and optimal dermatological compatibility To fulfill, new oil bodies are developed continuously and tested.
Ester
von Hexyldecanol mit Fettsäuren sind beispielsweise aus
Weiterhin wird die Verbindung Hexyldecyl 2-ethylhexanoate von der Fa. Kokyu Alcohol Co, Ltd unter dem Handelsnamen ICEH vertrieben.Farther the compound hexyldecyl 2-ethylhexanoate from the company. Kokyu Alcohol Co, Ltd. under the trade name ICEH.
-
G. Kirchner et al beschreiben im Journal of the American Society., Bd. 107, Nr. 24 von 1985 auf S. 7073 in Schema II als Beispiel 11 einen Ester aus 2-Hexadecanol und Butansäure
-
G. Kirchner et al, in Journal of the American Society., Vol. 107, No. 24, 1985, p. 7073 in Scheme II, as Example 11, describe an ester of 2-hexadecanol and butanoic acid
Es besteht weiterhin der Bedarf nach neuen Ölkörpern, die über ein flexibleres Einsatzspektrum verfügen (z. B. Kompatibilität mit weiteren kosmetischen Inhaltsstoffen) sowie den hohen Anforderungen an die Sensorik genügen. Von besonderem Interesse sind Ölkörper, welche auf der Haut eine als „leicht” bezeichnetes Gefühl erzeugen. Von großer Bedeutung sind die Verteilbarkeit und Spreitfähigkeit auf der Haut. Der moderne Verbraucher fordert von Ölkörper und den daraus hergestellten Zubereitungen, dass sie ein weiches Hautgefühl erzeugen und dass sich die Haut gepflegt anfühlt. Eine weitere Anforderung an moderne Rohstoffe für kosmetische und/oder pharmazeutische Zubereitungen ist, dass sie auf Basis nachwachsender, pflanzlicher Rohstoffe gewonnen werden können. Von besonderem Interesse sind Verbindungen, die sich durch eine vorteilhafte Sensorik auszeichnen, weiterhin von besonderem Interesse sind Verbindungen die lagerstabil sind, insbesondere lagerstabil bei erhöhten Temperaturen.It there is still a need for new oil bodies, which have a more flexible range of applications (eg compatibility with other cosmetic ingredients) as well as meet the high demands on the sensors. Of particular interest are oil bodies which on the skin a feeling called "light" produce. Of great importance are the distributability and spreading ability on the skin. The modern consumer calls for oil body and the produced from it Preparations that produce a soft skin feeling and that the skin feels well-groomed. Another requirement to modern raw materials for cosmetic and / or pharmaceutical Preparations is that they are based on renewable, vegetable Raw materials can be obtained. Of special interest are compounds that are characterized by advantageous sensors, furthermore of particular interest are compounds which are storage-stable, especially storage stable at elevated temperatures.
Aufgabe der vorliegenden Erfindung war es neue Stoffe bereit zu stellen, welche sich für kosmetischen und/oder pharmazeutischen Zubereitungen, insbesondere als Ölkörper/Emollients eignen und ein sensorisch besonders „leichtes” Hautgefühl erzeugen. Weiterhin sollten diese Stoffe auf Basis nachwachsender pflanzlicher Rohstoffe erhältlich sein.task the present invention was to provide new substances, which are for cosmetic and / or pharmaceutical Preparations, in particular as oil bodies / emollients suitable and a sensory particularly "light" skin feeling produce. Furthermore, these substances should be based on renewable vegetable raw materials available.
Gegenstand der ErfindungSubject of the invention
Überraschenderweise wurde gefunden, dass Ester von 2-Hexyldecanol mit kurzkettigen Fettsäuren sich eignen für kosmetische und/oder pharmazeutische Zubereitungen, und in diesen Zubereitungen insbesondere als sensorisch besonders vorteilhafte Ölkörper eingesetzt werden können.Surprisingly It has been found that esters of 2-hexyldecanol with short chain fatty acids themselves suitable for cosmetic and / or pharmaceutical preparations, and especially sensory in these preparations advantageous oil body can be used.
Die erfindungsgemäßen Ester zeichnen sich durch eine vorteilhafte Sensorik und durch eine erhöhte Stabilität gegenüber dem im Stand der Technik bekannten Verbindungen aus.The esters according to the invention are characterized by a advantageous sensor technology and increased stability over the compounds known in the art out.
Gegenstand
der Erfindung ist die Verwendung von einem oder mehreren Ester von
2-Hexyldecanol mit Fettsäuren der allgemeinen Formel (I)
Die erfindungsgemäßen Ester eignen sich insbesondere als Ölkörper in kosmetischen und/oder pharmazeutischen Zubereitungen.The esters of the invention are particularly suitable as an oil body in cosmetic and / or pharmaceutical Preparations.
Gegenstand
der Erfindung sind weiterhin Ester von 2-Hexyldecanol mit Fettsäuren
der allgemeinen Formel (I)
Als Alkoholkomponente des Esters wird 2-Hexyldecanol eingesetzt. 2-Hexyldecanol (synonym 2-Hexyl-1-decanol oder 2-Hexyldecylalcohol) ist kommerziell erhältlich, so z. B. unter dem Handelsnamen Eutanol® G 16 (Fa. Cognis Deutschland GmbH & Co. KG) oder als Exxal® 16 (Exxon Chemical Company). 2-Hexyldecanol ist ein so genannter Guerbet-Alkohol, der durch Selbstkondensation von (primären) Alkoholen unter dem Einfluss von Natrium oder Kupfer bei erhöhter Temperatur und Druck erhältlich ist. 2-Hexyldecanol besitzt ein chirales C-Atom und kann somit als R sowie als S Enantiomer vorliegen, als beliebige Mischung der zwei Enantiomere, sowie als Racemat. Ester von 2-Hexyldecanol im Sinne dieser Erfindung umfassen sowohl die Ester der jeweiligen Enantiomere, Mischungen dieser Enantiomere, als auch die entsprechenden Racemate. Kommerziell erhältliches 2-Hexyldecanol ist in der Regel das Racemat.The alcohol component of the ester is 2-hexyldecanol. 2-Hexyldecanol (synonymous 2-hexyl-1-decanol or 2-Hexyldecylalcohol) is commercially available, such. B. under the tradename Eutanol ® G 16 (Messrs. Cognis Germany GmbH & Co. KG) or as Exxal ® 16 (Exxon Chemical Company). 2-hexyldecanol is a so-called Guerbet alcohol obtainable by self-condensation of (primary) alcohols under the influence of sodium or copper at elevated temperature and pressure. 2-Hexyldecanol has a chiral carbon atom and can thus be present as R and S enantiomer, as any mixture of the two enantiomers, as well as a racemate. For the purposes of this invention, esters of 2-hexyldecanol include both the esters of the respective enantiomers, mixtures of these enantiomers, and the corresponding racemates. Commercially available 2-hexyldecanol is usually the racemate.
Als
Fettsäurekomponente des Esters werden Fettsäuren
der allgemeinen Formel (I)
Als R1 sind beispielsweise geeignet: Methyl, Ethyl, Propyl-, iso-Propyl [=1-Methylethyl-], Propenyl-, Isobutyl [=2-Methylpropyl], sec-Butyl [=1-Methylpropyl], tert-Butyl [=1,1-Dimethylethyl], But-2-enyl, But-3-enyl, But-1-enyl, n-Pentyl, 1-Methylbutyl-, 2-Methylbutyl-, 3-Methylbutyl, 1-Ethylpropyl, 1,1-Dimethylpropyl, 1,2-Dimethylpropyl, 2,2-Dimethylpropyl, 1-Pentenyl-, 2-Pentenyl-, 3-Pentenyl-, 4-Pentenyl, Hexyl-, 1-Methylpentyl-, 2-Methylpentyl, 3-Methylpentyl, 4-Methylpentyl, 1-Ethylbutyl-, 2-Ethylbutyl-, 3-Ethylbutyl-, 1-Hexenyl, 2-Hexenyl, 3-Hexenyl, 4-Hexenyl-, 5-Hexenyl.Examples of suitable R 1 are: methyl, ethyl, propyl, iso-propyl [= 1-methylethyl], propenyl, isobutyl [= 2-methylpropyl], sec-butyl [= 1-methylpropyl], tert-butyl [ = 1,1-dimethylethyl], but-2-enyl, but-3-enyl, but-1-enyl, n-pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1-ethylpropyl, 1, 1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, 1-pentenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl, hexyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl , 4-methylpentyl, 1-ethylbutyl, 2-ethylbutyl, 3-ethylbutyl, 1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl.
In einer bevorzugten Ausführungsform der Erfindung wird eine Fettsäure der allgemeinen Formel (I) eingesetzt, in der R1 einen linearen oder verzweigten, gesättigten Alkylrest mit 1 bis 6 C Atomen darstellt, besonders bevorzugt einen linearen, gesättigten Alkylrest mit 1 bis 6 C Atomen.In a preferred embodiment of the invention, a fatty acid of general formula (I) is used in which R 1 represents a linear or branched, saturated alkyl radical having 1 to 6 C atoms, particularly preferably a linear, saturated alkyl radical having 1 to 6 C atoms.
Besonders
geeignete Ester im Sinne der Erfindung sind
2-Hexyldecyl-essigsäureester
(R1 = CH3),
2-Hexyldecyl-propansäureester
(R1 = C2H5),
2-Hexyldecyl-pentansäureester
(R1 = C4H9),
2-Hexyldecyl-hexansäureester
(R1 = C5H11),
2-Hexyldecyl-heptansäureester
(R1 = C6H13),Particularly suitable esters according to the invention are
2-hexyldecylacetic acid ester (R 1 = CH 3 ),
2-hexyldecylpropanoic acid ester (R 1 = C 2 H 5 ),
2-hexyldecyl-pentanoic acid ester (R 1 = C 4 H 9 ),
2-hexyldecylhexanoic acid ester (R 1 = C 5 H 11 ),
2-hexyldecyl-heptanoic acid ester (R 1 = C 6 H 13 ),
Besonders
vorteilhaft im Sinne der Erfindung zur verwendende Ester sind
2-Hexyldecyl-essigsäureester
(R1 = CH3),
2-Hexyldecyl-propansäureester
(R1 = C2H5),
2-Hexyldecyl-butansäureester
(R1 = C3H7),
2-Hexyldecyl-pentansäureester
(R1 = C4H9),
2-Hexyldecyl-hexansäureester
(R1 = C5H11),
2-Hexyldecyl-heptansäureester
(R1 = C6H13),Particularly advantageous for the purposes of the invention to use esters
2-hexyldecylacetic acid ester (R 1 = CH 3 ),
2-hexyldecylpropanoic acid ester (R 1 = C 2 H 5 ),
2-hexyldecyl-butanoic acid ester (R 1 = C 3 H 7 ),
2-hexyldecyl-pentanoic acid ester (R 1 = C 4 H 9 ),
2-hexyldecylhexanoic acid ester (R 1 = C 5 H 11 ),
2-hexyldecyl-heptanoic acid ester (R 1 = C 6 H 13 ),
Herstellungmanufacturing
Die Herstellung der erfindungsgemäßen Ester erfolgt nach dem Fachmann bekannten Methoden der Veresterung. So kann z. B. die Fettsäure zusammen mit dem Hexyldecanol in Gegenwart eines Katalysators verestert werden.The Preparation of the esters of the invention takes place according to methods known in the art of esterification. So z. B. the fatty acid together with the hexyldecanol in the presence a catalyst to be esterified.
Sowohl die Alkoholkomponenten als auch die Fettsäurekomponente können aus pflanzlichen Rohstoffen, wie beispielsweise Palmkern- oder Kokosöl gewonnen werden. Somit sind die erfindungsgemäßen Ester vollständig auf Basis nachwachsender Rohstoffe erhältlich.Either the alcohol components as well as the fatty acid component can be made from plant-based raw materials, such as Palmkernel or coconut oil are obtained. Thus, the completely on the invention Base of renewable resources available.
Verwendung in kosmetischen und/oder pharmazeutischen ZubereitungenUse in cosmetic and / or pharmaceutical preparations
Überraschenderweise wurde festgestellt, dass sich die erfindungsgemäßen Ester besonders eignen zur Herstellung von kosmetischen Zubereitungen, sie eignen sich insbesondere als Ölkörper/Emollients und/oder Konsistenzgeber in kosmetischen Zubereitungen. Die erfindungsgemäßen Ester eignen sich weiterhin zur Herstellung von pharmazeutischen Zubereitungen, wobei die erfindungsgemäßen als technische Hilfsstoffe, wie z. B. Ölkörper eingesetzt werden. Die erfindungsgemäßen Ester können zur Herstellung von kosmetischen Zubereitungen, wie beispielsweise Haarshampoos, Haarlotionen, Schaumbäder, Duschbäder, Cremes, Gele, Lotionen, alkoholische und wässrig/alkoholische Lösungen, Emulsionen, Wachs/Fett-Massen, Stiftpräparaten, Pudern oder Salben dienen. Diese Mittel können ferner als weitere Hilfs- und Zusatzstoffe milde Tenside, Ölkörper, Emulgatoren, Perlglanzwachse, Konsistenzgeber, Verdickungsmittel, Überfettungsmittel, Stabilisatoren, Polymere, Siliconverbindungen, Fette, Wachse, Lecithine, Phospholipide, biogene Wirkstoffe, UV-Lichtschutzfaktoren, Antioxidantien, Deodorantien, Antitranspirantien, Antischuppenmittel, Filmbildner, Quellmittel, Insektenrepellentien, Selbstbräuner, Tyrosininhibitoren (Depigmentierungsmittel), Hydrotrope, Solubilisatoren, Konservierungsmittel, Parfümöle, Farbstoffe und dergleichen enthalten. Bevorzugt ist die Verwendung der erfindungsgemäßen Ester als Ölkörper.Surprisingly it was found that the inventive Esters are particularly suitable for the preparation of cosmetic preparations, they are particularly suitable as oil bodies / emollients and / or Bodying agent in cosmetic preparations. The invention Esters are also suitable for the production of pharmaceutical Preparations, wherein the invention as technical auxiliaries, such. B. oil body used become. The esters of the invention can for the preparation of cosmetic preparations, such as Hair shampoos, hair lotions, bubble baths, shower baths, creams, Gels, lotions, alcoholic and aqueous / alcoholic solutions, Emulsions, wax / fat compounds, stick preparations, powders or ointments. These funds can also be further Auxiliaries and additives mild surfactants, oil bodies, Emulsifiers, pearlescent waxes, bodying agents, thickeners, superfatting agents, Stabilizers, polymers, silicone compounds, fats, waxes, lecithins, Phospholipids, biogenic agents, UV protection factors, antioxidants, deodorants, Antiperspirants, antidandruff agents, film formers, swelling agents, Insect repellents, self-tanner, tyrosine inhibitors (Depigmenting agent), hydrotropes, solubilizers, preservatives, Perfume oils, dyes and the like included. Preference is given to the use of the invention Ester as oil body.
Die erfindungsgemäßen Ester können in kosmetischen Formulierungen als sog. ,light emollients' verwenden werden, um spezielle Eigenschaften, wie z. B. Spreitverhalten oder Flüchtigkeit einzustellen. Die erfindungsgemäßen Ester ermöglichen weiterhin viskositätsstabile kosmetische Formulierungen herzustellen. Die erfindungsgemäßen Ester zeichnen sich gegenüber den 1-Methylverzweigten Estern des Standes der Technik durch eine verbesserte Sensorik sowie durch eine erhöhte Stabilität, insbesondere bei Temperaturbelastung aus.The Esters of the invention can be used in cosmetic Formulations as so-called, light emollients' use to special properties, such. B. spreading or volatility adjust. Allow the esters of the invention furthermore viscous-stable cosmetic formulations manufacture. The esters according to the invention are characterized towards the 1-methyl branched esters of the prior art the technology by an improved sensor technology as well as by an increased Stability, especially when exposed to temperature.
Die erfindungsgemäßen Ester können sowohl einzeln als auch in beliebigen Mischungen untereinander eingesetzt werden.The esters according to the invention can both used individually or in any mixtures with one another become.
BeispieleExamples
Herstellungsbeispiel:Preparation:
1 mol Hexansäure (116 g), 1,1 rot (297 g) 2-Hexyldecanol (Guerbitol® 16) 16 sowie 0,22 g Fascat® 2001 (Zinnoxalat) wurden zusammen gegeben und für 3 h auf 240°C am Wasserabscheider erhitzt, Anschließend wurde das Produkt über eine 30 cm Kolonne destilliert (153–168°C bei 0,8 mbar). Das Produkt fallt als farbloses und geruchloses Öl an.1 mol hexanoic acid (116 g), 1,1 red (297 g) of 2-hexyldecanol (Guerbitol ® 16) 16 and 0.22 g of Fascat ® 2001 (tin oxalate) were added together and for 3 h at 240 ° C on a water heated Subsequently, the product was distilled over a 30 cm column (153-168 ° C at 0.8 mbar). The product is obtained as a colorless and odorless oil.
Die
folgenden kosmetischen Rezepturen wurden erhalten, in dem der nach
Beispiel 1 hergestellte 2-Hexyldecyl-hexansäureester eingesetzt
wurde. In gleicher Weise werden die entsprechenden kosmetischen Rezepturen
erhalten, in dem man den 2-Hexyldecyl-hexansäureester durch
einen der folgenden Ester austauscht:
2-Hexyldecyl-essigsäureester
(R1 = CH3),
2-Hexyldecyl-propansäureester
(R1 = C2H5),
2-Hexyldecyl-butansäureester
(R1 = C3H7),
2-Hexyldecyl-pentansäureester
(R1 = C4H9),
2-Hexyldecyl-heptansäureester
(R1 = C6H13),The following cosmetic formulations were obtained by using the 2-hexyldecylhexanoic acid ester prepared according to Example 1. In the same way, the corresponding cosmetic formulations are obtained by exchanging the 2-hexyldecyl-hexanoic acid ester with one of the following esters:
2-hexyldecylacetic acid ester (R 1 = CH 3 ),
2-hexyldecylpropanoic acid ester (R 1 = C 2 H 5 ),
2-hexyldecyl-butanoic acid ester (R 1 = C 3 H 7 ),
2-hexyldecyl-pentanoic acid ester (R 1 = C 4 H 9 ),
2-hexyldecyl-heptanoic acid ester (R 1 = C 6 H 13 ),
Alle
Angaben sind Gew.-% bezogen auf das Gesamtgewicht der kosmetischen
Zubereitung. Tabelle 1: O/W Body Care Emulsionen
- 1/2 – Antiperspirant/Deo Creme, 3 – Antiperspirant Creme (W/0), 4 – Antiperspirant/Deo Spray, 5 – Antiperspirant Stift mit Vitamin E, 6 – Antiperspirant Creme, 7 – Antiperspirant Creme 'Soft Solid'
- (*)National Starch, (**)Nederland, (***)Dow Corning; pH angepasst auf 3.5–5.0
- (****)Dow Corning; pH adjusted to 3.5–5.0
- (*)Dow Corning, (**)Penreco, (***)Wacker
- 1/2 - Antiperspirant / Deodorant Cream, 3 - Antiperspirant Cream (W / 0), 4 - Antiperspirant / Deodorant Spray, 5 - Antiperspirant Pen with Vitamin E, 6 - Antiperspirant Cream, 7 - Antiperspirant Cream 'Soft Solid'
- (*) National Starch, (**) Nederland, (***) Dow Corning; pH adjusted to 3.5-5.0
- (****) Dow Corning; pH adjusted to 3.5-5.0
- (*) Dow Corning, (**) Penreco, (***) Wacker
Appendix – InhaltsstoffeAppendix - Ingredients
- AMP-95, INCI: Aminomethyl Propanol, Dow Chemical Co; Abil® EM 90; INCI: Cetyl Dimethicone Copolyol; Tego Cosmetics (Goldschmidt); Allianz® OPT; INCI: Acrylates/C12-22 Alkyl Methacrylate Copolymer; Rohm und Haas; Amphisol® K; INCI: Potassium Cetyl Phosphate; Hoffmann La Roche; Admul® WOL 1403, INCI: Polyricinoleate of polyglycerol, Quest; Antaron® V 220; INCI: PVP/Eicosene Copolymer; GAF General Aniline Firm Corp. (IPS-Global); Antaron® V 216; INCI: PVP/Hexadecene Copolymer: GAF General Aniline Firm Corp. (IPS-Global); Arlacel® 83; INCI: Sorbitan Sesquioleate, Uniqema (ICI Surfacants); Arlacel® P 135, INCI: PEG-30 Dipolyhydroxystearate, Uniqema (ICI Surfacants); Bentone® 38, INCI: Quaternium-18 Hectorite, Rheox (Elementis Specialties); Carbopol® 980, INCI: Carbomer, Goodrich; Carbopol® 2984, INCI: Carbomer, Noveon, Inc.; Carbopol® ETD 2001, INCI: Carbomer, Noveon, Inc.; Carbopol® Ultrez 10, INCI: Carbomer; Noveon, Inc.; Cegesoft® C 17, Myristyl Lactate, Cognis GmbH; Cegesoft® PFO, INCI: Passiflora Incarnata (EU); Cognis GmbH; Cegesoft® PS 6, INCI: Olus, Cognis GmbH, Cegesoft® SH, INCI: Shorea Stenoptera Seed Butter Cognis GmbH; Ceraphyl® 45, INCI: Diethylhexyl Malate, International Specialty Products; Cetiol® 868, INCI: Ethylhexyl Stearate, Hersteller: Cognis GmbH; Cetiol® A, INCI: Hexyl Laurate, Cognis GmbH; Cetiol® B, INCI: Dibutyl Adipate, Cognis GmbH; Cetiol® CC, INCI: Dicaprylyl Carbonate; Cognis GmbH; Cetiol® J 600, INCI: Oleyl Erucate, Cognis GmbH; Cetiol® LC, INCI: Coco-Caprylate/Caprate, Cognis GmbH; Cetiol® MM, INCI: Myristyl Myristate, Cognis GmbH; Cetiol® OE, INCI: Dicaprylyl Ether, Cognis GmbH, Cetiol® PGL, INCI: Hexyldecanol, Hexyldecyl Laurate, Cognis GmbH; Cetiol® S, INCI: Diethylhexylcyclohexane, Cognis GmbH; Cetiol® SB 45, INCI: Shea Butter Butyrospermum Parkii (Linne), Cognis GmbH; Cetiol® SN, INCI: Cetearyl Isononanoate, Cognis GmbH, Copherol® F 1300 C, INCI: Tocopherol, Cognis GmbH; Copherol 1250 C, INCI: Tocopheryl Acetate, Cognis GmbH; Cosmedia® DC, INCI: Hydrogenated Dimer Dilinoleyl/Dimethylcarbonate Copolymer; Cognis GmbH; Cosmedia® SP, INCI: Sodium Polyacrylate; Cognis GmbH; Cutina® E 24, INCI: PEG-20 Glyceryl Stearate; Cognis GmbH; Cutina® HR, INCI: Hydrogenated Castor Oil, Cognis GmbH; Cutina® MD, INCI: Glyceryl Stearate, Cognis GmbH; Cutina® PES, INCI: Pentaerythrityl Distearate, Cognis GmbH; Cutina® FS-45, INCI: Palmitic Acid, Stearic Acid, Cognis GmbH; Cutina® GMS-SE, INCI Glyceryl Stearate SE, Cognis GmbH; Cutina® LM conc, INCI: Polyglyceryl-2 Dipolyhydroxystearate, Octyldodecanol, Copernicia Cerifera (Carnauba) Wax, Euphorbia Cerifera (Candelilla) Wax, Beeswax, Cetearyl Glucoside, Cetearyl Alcohol, Cognis GmbH; Dehymuls® FCE, INCI: Dicocoyl Pentaerythrityl Distearyl Citrate, Cognis GmbH; Dehymuls® HRE 7, INCI: PEG-7 Hydrogenated Castor Oil, Cognis GmbH; Dehymuls® PGPH, INCI: Polyglyceryl-2 Dipolyhydroxystearate, Cognis GmbH; Crodesta® F-50, INCI Sucrosedistearate, Croda; Dehymuls® LE, INCI: PEG-30 Dipolyhydroxystearate, Cognis GmbH; Dow Corning® 244 Fluid, INCI: Cyclomethicone, Dow Corning DC® 245 INCI: Cyclopentasiloxane, Dow Corning; Dow Corning® 246 Fluid, Cyclopentasiloxane, Dow Corning; Dow Corning® 2502, INCI: Cetyl Dimethicone, Dow Corning; Dehyquart® C 4046, INCI: Cetearyl Alcohol, Dipalmitoylethyl Hydroxyeethylmonium Methosulfate, Ceteareth-20, Cognis GmbH; Dry Flo Plus, INCI: Aluminium Starch Octenylsuccinate, National Starch; Dry® Flo PC, INCI: Aluminum Starch Octenylsuccinate, Akzo Nobel; Elfacos® ST 37, INCI: PEG-22 Dodecyl Glycol Copolymer, Akzo-Nobel; Elfacos® ST 9, INCI: PEG-45 Dodecyl Glycol Copolymer, Akzo-Nobel; Emery® 1780, INCI: Lanolin Alcohol, Cognis Corp.; Emulgade® CM, INCI: Cetearyl Isononanoate and Ceteareth-20 and Cetearyl Alcohol and Glyceryl Stearate and Glycerin and Ceteareth-12 and Cetyl Palmitate, Cognis GmbH; Emulgade® PL 68/50, INCI: Cetearyl Glucoside, Cetearyl Alcohol, Cognis GmbH; Emulgade® SE-PF, INCI: Glyceryl Stearate (and) Ceteareth-20 (and) Ceteareth-12 (and) Cetearyl Alcohol (and) Cetyl Palmitate; Cognis GmbH, Emulgade® SUCRO, INCI: Sucrose Polystearate (and) Hydrogenated Polyisobutene, Cognis GmbH; Eumulgin® B1, INCI: Ceteareth-12, Cognis GmbH, Eumulgin® B 2, INCI: Ceteareth-20, Cognis GmbH; Eumulgin® HRE 40, INCI: PEG-40 Hydrogenated Castor Oil, Cognis GmbH; Eumulgin® SG, INCI: Sodium Stearoyl Glutamate, Cognis GmbH; Eumulgin® VL 75, INCI: Lauryl Glucoside (and) Polyglyceryl-2 Dipolyhydroxystearate (and) Glycerin; Cognis GmbH; Eusolex® OCR, INCI: Octocrylene, Merck; Eusolex® T 2000, INCI: Titanium Dioxide, Alumina, Simethicone, Merck; Eusolex® T AQUA, INCI: Water and Titanium Dioxide and Alumina and Sodium Metaphosphate and Phenoxyethanol and Sodium Methylparaben, Merck; Eutanol® G, INCI: Octyldodecanol, Cognis GmbH; Eutanol® G 16, INCI: Hexyldecanol, Cognis GmbH; Eutanol® G 16 S, INCI: Hexyldecyl Stearate, Cognis GmbH; Finsolv® TN, INCI: C 12/15 Alkyl Benzoate, Findex (Nordmann/Rassmann); Fitoderm®, INCI Squalane, Cognis GmbH; Generol® R, INCI: Brassica Campestris (Rapseed) Sterols, Cognis GmbH; Glucate DO, INCI: Methyl Glucose Dioleate, NRC Nordmann/Rassmann; Hispagel® 200, INCI: Glycerin, Glyceryl Polyacrylate, Cognis GmbH; Hostaphat® KL 340 N, INCI: Trilaureth-4 Phosphate, Clariant; Hydagen® C. A. T., INCI Triethyl Citrate, Cognis GmbH; Hydagen® DCMF, INCI: Chitosan, Cognis GmbH; Insect Repellent® 3535, INCI: Ethyl Butylacetylaminopropionate, EMD Chemicals Inc; Isolan® PDI, INCI: Diisostearoyl Polyglyceryl-3 Diisostearate, Goldschmidt AG; Isolan® GPS, INCI: Polyglyceryl-4 Diisostearate/Polyhydroxystearate/Sebacate, Evonik Goldschmidt; Isolan® GI 34, INCI: Polyglyceryl-4 Isostearate, Evonik Goldschmidt; Irwinol® LS 9319, INCI: Octyldecanol, Irvingia Gabonensis Kernel Butter, Hydrogenated Coco-Glycerides, Keltrol® T, INCI: Xanthan Gum, CP Kelco; Lameform® TGI, INCI: Polyglyceryl-3 Diisostearate, Cognis GmbH; Lanette® 14, INCI: Myristyl Alcohol, Cognis GmbH; Lanette® 18, INCI: Stearyl Alcohol, Cognis GmbH; Lanette® 22, INCI: Behenyl Alcohol, Cognis GmbH; Lanette® E, INCI: Sodium Cetearyl Sulfate, Cognis GmbH; Lanette® O, INCI: Cetearyl Alcohol, Cognis GmbH; Locron® L, INCI: Aluminium Chlorhydrate, Clariant; Lucentite® SAN, INCI: Quaternium-18 Hectorit, Co-Op Chemical Co., Ltd.; Monomuls® 90-O 18, INCI: Glyceryl Oleate, Cognis GmbH; Monomuls® 90 L 12, INCI: Glyceryl Laurate, Cognis GmbH; Myrj® 51, INCI: PEG-30-Sterate, Uniqema; Myritol® 312, INCI: Caprylic/Capric Triglyceride, Cognis GmbH; Myritol® 331, INCI: Cocoglycerides, Cognis GmbH; Myritol® PC, INCI: PropyleneGlycol Dicaprylate/Dicaprate, Cognis GmbH; Neo Heliopan® 303, INCI: Octocrylene, Symrise; Neo Heliopan® AP, INCI: Disodium Phenyl Dibenzimidazole Tetrasulfonate, Symrise; Neo Heliopa® AV, INCI: Ethylhexyl Methoxycinnamate, Symrise; Neo Heliopan® BB, INCI: Benzophenone-3, Symrise; Neo Heliopan® E 1000, INCI: Isoamyl-p-Methoxycinnamate, Symrise; Neo Heliopan® Hydro, INCI: Phenylbenzimidazole Sulfonic Acid, Symrise; Neo Heliopan® MBC, INCI: 4-Methylbenzylidene Camphor, Symrise; Neo Heliopan® OS, INCI: Ethylhexyl Salicylate, Symrise; Novata® AB, INCI: Cocoglycerides, Cognis GmbH; Parsol® 1789, INCI: Butyl Methoxydibenzoylmethane, Hoffmann-La Roche (Givaudan); Pemulen® TR-2 Polymer, INCI: Acrylates/C10-30 Alkylacrylate Crosspolymer, Noveon, Inc.; Photonyl® LS, INCI: Arginine, Disodium Adenosine Triphosphate, Mannitol, Pyridoxine HCL, Phenylalanine, Tyrosine, Laboratoires Serobiologiques (Cognis); Prisorine® 3505, INCI: Isostearic Acid; Uniqema; Prisorine® 3758, INCI: Hydrogenated Polyisobutene, Uniqema; Rezal 36G, INCI: Aluminum Zirconium Tetrachlorohydrex GLY, Reheis, Inc; Rheocare® C Plus, INCI Carbomer, Cognis GmbH; SFE® 839, INCI: Cyclopentasiloxane and Dimethicone/Vinyl Dimethicone Crosspolymer, GE Silicones; Silikonöl Wacker AK® 350, INCI: Dimethicone, Wacker; Ronasphere® LDP, INCI: Silica, Titaniumdioxide; Iron oxides; Squatol® S, INCI: Hydrogenated Polyisobutene, BASF Corp.; Poloxamer® 101, INCI: Poloxamer, BASF SE; Tego® Care 450, INCI: Polyglyceryl-3 Methylglucose Distearate, Goldschmidt; Tego® Care CG 90, INCI: Cetearyl Glucoside, Goldschmidt; Tegosoft® DEC, INCI: Diethylhexyl Carbonate, Goldschmidt; Tinosorb® S, INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; Ciba Specialty Chemicals Corporation; Tinosorb® M, INCI: Methylene Bis-Benzotriazolyl Tetramethylbutylphenol, Ciba Specialty Chemicals Corporation; Tween® 60, INCI: Polysorbate 60, Uniqema (ICI Surfactants), Uvasorb® HEB, INCI: Diethylhexyl Butamido Triazone, 3 V Inc.; Unirep® U-18, INCI: Dimethyl Phthalate and Diethyl Toluamide and Ethyl Hexanediol, Induchem AG; Uvinul® T 150, INCI: Ethylhexyl Triazone, BASF; Uvinul® A plus, INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate, BASF; Veegum® Ultra, INCI: Magnesium Aluminium Silicate, R. T. Vanderbilt Company, Inc; Veegum® Plus, INCI: Magnesium Aluminum Silicate and Cellulose Gum, R. T. Vanderbilt Company, Inc; Z-Cote® HP 1, INCI: Zinc Oxide and Triethoxy-caprylylsilane, BASF, Zinc Oxide NDM, INCI: Zinc Oxide, Symrise.AMP-95, INCI: Aminomethyl Propanol, Dow Chemical Co; Abil ® EM 90; INCI: cetyl dimethicone copolyol; Tego Cosmetics (Goldschmidt); Allianz® OPT; INCI: Acrylates / C12-22 alkyl methacrylate copolymer; Rohm and Haas; Amphisol ® K; INCI: Potassium Cetyl Phosphate; Hoffmann La Roche; Admul ® WOL 1403 INCI: Polyricinoleate of polyglycerol, Quest; Antaron V ® 220; INCI: PVP / eicosene copolymer; GAF General Aniline Firm Corp. (IPS-Global); Antaron V ® 216; INCI: PVP / Hexadecene Copolymer: GAF General Aniline Firm Corp. (IPS-Global); Arlacel ® 83; INCI: Sorbitan Sesquioleate, Uniqema (ICI Surfacants); Arlacel P 135 ®, INCI: PEG-30 dipolyhydroxystearate, Uniqema (ICI surfacants); Bentone ® 38, INCI: Quaternium-18 Hectorite, Rheox (Elementis Specialties); Carbopol ® 980, INCI: Carbomer, Goodrich; Carbopol ® 2984, INCI: Carbomer, Noveon, Inc .; Carbopol ® ETD 2001, INCI: Carbomer, Noveon, Inc .; Carbopol ® Ultrez 10, INCI: carbomer; Noveon, Inc .; Cegesoft ® C 17, Myristyl Lactate, Cognis GmbH; Cegesoft ® PFO, INCI: Passiflora incarnata (EU); Cognis GmbH; Cegesoft ® PS 6, INCI: Olus, Cognis GmbH, Cegesoft ® SH, INCI: Shorea Stenoptera Seed Butter Cognis GmbH; Ceraphyl ® 45, INCI: diethylhexyl malate, International Specialty Products; Cetiol ® 868, INCI: Ethylhexyl Stearate, Cognis GmbH; Cetiol ® A, INCI: hexyl laurate, Cognis GmbH; Cetiol ® B, INCI: Dibutyl Adipate, Cognis GmbH; Cetiol ® CC, INCI: Dicaprylyl Carbonate; Cognis GmbH; Cetiol ® J 600, INCI: oleyl erucate, Cognis GmbH; Cetiol ® LC, INCI: coco-caprylate / caprate, Cognis GmbH; Cetiol ® MM INCI: myristyl myristate, Cognis GmbH; Cetiol ® OE, INCI: Dicaprylyl ether, Cognis GmbH, Cetiol ® PGL, INCI: hexyldecanol, Hexyldecyl laurates, Cognis GmbH; Cetiol ® S, INCI: Diethylhexylcyclohexane, Cognis GmbH; Cetiol ® SB 45, INCI: Shea butter Butyrospermum Parkii (Linnaeus), Cognis GmbH; Cetiol ® SN, INCI: Cetearyl Isononanoate, Cognis GmbH, Copherol® ® F 1300 C, INCI: tocopherol, Cognis GmbH; Copherol 1250C, INCI: Tocopheryl Acetate, Cognis GmbH; Cosmedia ® DC, INCI: Hydrogenated Dimer Dilinoleyl / copolymer dimethyl carbonates; Cognis GmbH; Cosmedia® ® SP, INCI: Sodium polyacrylate; Cognis GmbH; Cutina ® E 24, INCI: PEG-20 Glyceryl Stearate; Cognis GmbH; Cutina ® HR, INCI: Hydrogenated Castor Oil, Cognis GmbH; Cutina ® MD, INCI: glyceryl stearate, Cognis GmbH; Cutina ® PES, INCI: pentaerythrityl distearate, Cognis GmbH; Cutina ® FS-45, INCI: Palmitic Acid, Stearic Acid, Cognis GmbH; Cutina ® GMS SE, INCI Glyceryl Stearate SE, Cognis GmbH; Cutina ® LM conc, INCI: Polyglyceryl-2 Dipolyhydroxystearate, Octyldodecanol, Copernicia Cerifera (Carnauba) Wax, Euphorbia Cerifera (Candelilla) Wax, Beeswax, Cetearyl Glucoside, Cetearyl Alcohol, Cognis GmbH; Dehymuls® ® FCE, INCI: Dicocoyl pentaerythrityl distearyl citrate, Cognis GmbH; Dehymuls® ® HRE 7, INCI: PEG-7 Hydrogenated Castor Oil, Cognis GmbH; Dehymuls® ® PGPH, INCI: Polyglyceryl-2 Dipolyhydroxystearate, Cognis GmbH; Crodesta F-50 ®, INCI Sucrosedistearate, Croda; Dehymuls® ® LE, INCI: PEG-30 Dipolyhydroxystearate, Cognis GmbH; Dow Corning® 244 Fluid, INCI: Cyclomethicone, Dow Coming DC® 245 INCI: Cyclopentasiloxane, Dow Corning; Dow Corning® 246 Fluid, Cyclopentasiloxanes, Dow Corning; Dow Corning ® 2502 INCI: Cetyl Dimethicone, Dow Corning; Dehyquart® ® C 4046, INCI: Cetearyl Alcohol, Dipalmitoylethyl Hydroxyeethylmonium methosulfate, ceteareth-20, Cognis GmbH; Dry Flo Plus, INCI: Aluminum Starch Octenylsuccinate, National Starch; Dry ® Flo PC, INCI: Aluminum Starch Octenylsuccinate, Akzo Nobel; Elfacos ® ST 37, INCI: PEG-22 Dodecyl Glycol Copolymer, Akzo-Nobel; Elfacos ST 9 ®, INCI: PEG-45 Dodecyl Glycol Copolymer, Akzo-Nobel; Emery® 1780, INCI: Lanolin Alcohol, Cognis Corp .; Emulgade® ® CM, INCI: Cetearyl Isononanoate and Ceteareth-20 and Cetearyl Alcohol and Glyceryl Stearate and glycerin and ceteareth-12 and cetyl Palmitate, Cognis GmbH; Emulgade® ® PL 68/50, INCI: Cetearyl Glucoside, Cetearyl Alcohol, Cognis GmbH; Emulgade SE-PF ®, INCI: Glyceryl Stearate (and) Ceteareth-20 (and) Ceteareth-12 (and) Cetearyl Alcohol (and) Cetyl Palmitate; Cognis GmbH, Emulgade® ® Sucro, INCI: sucrose polystearate (and) Hydrogenated Polyisobutene, Cognis GmbH; Eumulgin ® B1, INCI: Ceteareth-12, Cognis GmbH, Eumulgin ® B 2, INCI: Ceteareth-20, Cognis GmbH; Eumulgin ® HRE 40, INCI: PEG-40 Hydrogenated Castor Oil, Cognis GmbH; Eumulgin ® SG, INCI: Sodium Stearoyl Glutamate, Cognis GmbH; Eumulgin ® VL 75, INCI: Lauryl Glucoside (and) Polyglyceryl-2 Dipolyhydroxystearate (and) Glycerin; Cognis GmbH; Eusolex ® OCR, INCI: Octocrylene, Merck; Eusolex ® T 2000, INCI: Titanium Dioxide, Alumina, Simethicone, Merck; Eusolex ® T AQUA, INCI: Water and Titanium Dioxide and Alumina and Sodium metaphosphates and phenoxyethanol and sodium methylparaben, Merck; Eutanol ® G, INCI: Octyldodecanol, Cognis GmbH; Eutanol ® G 16, INCI: hexyldecanol, Cognis GmbH; Eutanol ® G 16 S, INCI: Hexyldecyl Stearate, Cognis GmbH; Finsolv ® TN, INCI: C 12/15 alkyl benzoates, Findex (Nordmann / Rassmann); Fitoderm ®, INCI squalane, Cognis GmbH; GenerolTM ® R, INCI: Brassica campestris (Rapseed) Sterols, Cognis GmbH; Glucate DO, INCI: Methyl Glucose Dioleate, NRC Nordmann / Rassmann; Hispagel ® 200, INCI: glycerin, glyceryl polyacrylate, Cognis GmbH; Hostaphat KL 340 N ®, INCI: Trilaureth-4 Phosphate, Clariant; Hydagen® ® CAT, INCI Triethyl Citrate, Cognis GmbH; Hydagen® ® DCMF, INCI: chitosan, Cognis GmbH; ® Insect Repellent 3535, INCI: ethyl butylacetylaminopropionate, EMD Chemicals Inc; Isolani ® PDI, INCI: Diisostearoyl Polyglyceryl-3 diisostearate, Goldschmidt AG; Isolani ® GPS, INCI: Polyglyceryl-4 diisostearate / polyhydroxystearate / sebacates, Evonik Goldschmidt; Isolan ® GI 34, INCI: Polyglyceryl-4 Isostearate, Evonik Goldschmidt; Irwinol ® LS 9319, INCI: Octyldecanol, Irvingia gabonensis kernel butter, Hydrogenated Coco-Glycerides, Keltrol ® T, INCI: xanthan gum, CP Kelco; Lame form ® TGI, INCI: polyglyceryl-3 diisostearate, Cognis GmbH; Lanette ® 14, INCI: Myristyl Alcohol, Cognis GmbH; Lanette ® 18, INCI: Stearyl Alcohol, Cognis GmbH; Lanette ® 22, INCI: behenyl alcohol, Cognis GmbH; Lanette ® E, INCI: Sodium Cetearyl Sulfate, Cognis GmbH; Lanette ® O, INCI: Cetearyl Alcohol, Cognis GmbH; Locron ® L, INCI: aluminum chlorohydrates, Clariant; Lucentite ® SAN, INCI: quaternium-18 hectorite, Co-Op Chemical Co., Ltd .; Monomuls® ® 90 O 18, INCI: glyceryl oleates, Cognis GmbH; Monomuls® ® 90 L 12, INCI: Glyceryl Laurate, Cognis GmbH; Myrj ® 51, INCI: PEG-30 Sterate, Uniqema; Myritol ® 312 INCI: Caprylic / Capric Triglyceride, Cognis GmbH; Myritol ® 331, INCI: Cocoglycerides, Cognis GmbH; Myritol ® PC, INCI: propyleneglycol dicaprylate / dicaprate, Cognis GmbH; Neo Heliopan ® 303 INCI: Octocrylene, Symrise; Neo Heliopan AP ®, INCI: Disodium Phenyl Dibenzimidazole Tetrasulfonate, Symrise; Neo Heliopa ® AV, INCI: Ethylhexyl Methoxycinnamate, Symrise; Neo Heliopan BB ®, INCI: benzophenone-3, Symrise; Neo Heliopan ® E 1000, INCI: Isoamyl p-Methoxycinnamate, Symrise; Neo Heliopan Hydro ®, INCI: Phenylbenzimidazole Sulfonic Acid, Symrise; Neo Heliopan ® MBC, INCI: 4-methylbenzylidene camphor, Symrise; Neo Heliopan ® OS, INCI: ethylhexyl salicylate, Symrise; Novata ® AB, INCI: Cocoglycerides, Cognis GmbH; Parsol ® 1789 INCI: Butyl Methoxydibenzoylmethane, Hoffmann-La Roche (Givaudan); Pemulen ® TR-2 polymer, INCI: Acrylates / C10-30 alkyl acrylates crosspolymer, Noveon, Inc .; Photonyl ® LS, INCI: Arginine, Disodium Adenosine Triphosphate, mannitol, Pyridoxine HCL, Phenylalanine, Tyrosine, Laboratoires Serobiologiques (Cognis); Prisorine ® 3505, INCI: Isostearic Acid; Uniqema; Prisorine ® 3758, INCI: Hydrogenated Polyisobutene, Uniqema; Rezal 36G, INCI: Aluminum Zirconium Tetrachlorohydrex GLY, Reheis, Inc .; Rheocare ® C Plus, INCI Carbomer, Cognis GmbH; SFE ® 839, INCI: Cyclopentasiloxane and Dimethicone / Vinyl Dimethicone Crosspolymer, GE Silicones; Silicone oil Wacker AK ® 350, INCI: Dimethicone, Wacker; Ronasphere LDP ®, INCI: silica, titanium dioxides; Iron oxides; Squatol ® S, INCI: Hydrogenated Polyisobutene, BASF Corp .; Poloxamer ® 101, INCI: poloxamer, BASF SE; Tego® Care 450, INCI: Polyglyceryl-3 Methylglucose Distearate, Goldschmidt; Tego ® Care CG 90, INCI: cetearyl glucosides, Goldschmidt; Tegosoft ® DEC, INCI: diethylhexyl carbonates, Goldschmidt; Tinosorb ® S, INCI: bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; Ciba Specialty Chemicals Corporation; Tinosorb ® M, INCI: Methylene Bis-benzotriazolyl Tetramethylbutylphenol, Ciba Specialty Chemicals Corporation; Tween ® 60, INCI: Polysorbate 60, Uniqema (ICI Surfactants), Uvasorb HEB ®, INCI: Diethylhexyl Butamido Triazone, 3 V Inc .; Unirep ® U-18, INCI: dimethyl phthalate and diethyl Toluamide and ethyl hexanediol, Induchem AG, Uvinul ® T 150, INCI: Ethylhexyltriazone, BASF; Uvinul ® A plus, INCI: diethylamino hydroxybenzoyl hexyl benzoate, BASF; Veegum ® Ultra, INCI: Magnesium Aluminum Silicate, RT Vanderbilt Company, Inc; Veegum ® Plus, INCI: Magnesium Aluminum Silicate and cellulose gum, RT Vanderbilt Company, Inc; Z- Cote® HP 1, INCI: Zinc Oxide and Triethoxy-caprylyl silanes, BASF, Zinc Oxide NDM, INCI: Zinc Oxide, Symrise.
ZITATE ENTHALTEN IN DER BESCHREIBUNGQUOTES INCLUDE IN THE DESCRIPTION
Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.
Zitierte PatentliteraturCited patent literature
- - US 6391287 [0004] - US 6391287 [0004]
- - US 5656664 [0006] US 5656664 [0006]
Zitierte Nicht-PatentliteraturCited non-patent literature
- - G. Kirchner et al beschreiben im Journal of the American Society., Bd. 107, Nr. 24 von 1985 auf S. 7073 in Schema II als Beispiel 11 einen Ester aus 2-Hexadecanol und Butansäure [0006] - G. Kirchner et al describe in the Journal of the American Society., Vol. 107, No. 24 of 1985 on page 7073 in Scheme II as Example 11 an ester of 2-hexadecanol and butanoic acid [0006]
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200910034140 DE102009034140A1 (en) | 2009-07-22 | 2009-07-22 | Use of new or known 2-hexyl decanol ester with fatty acid compound as oil body, and in and/or for preparing pharmaceutical and/or cosmetic preparations, e.g. hair shampoos, hair lotions, foam baths, creams, gels and lotions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200910034140 DE102009034140A1 (en) | 2009-07-22 | 2009-07-22 | Use of new or known 2-hexyl decanol ester with fatty acid compound as oil body, and in and/or for preparing pharmaceutical and/or cosmetic preparations, e.g. hair shampoos, hair lotions, foam baths, creams, gels and lotions |
Publications (1)
Publication Number | Publication Date |
---|---|
DE102009034140A1 true DE102009034140A1 (en) | 2010-05-06 |
Family
ID=42063168
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE200910034140 Withdrawn DE102009034140A1 (en) | 2009-07-22 | 2009-07-22 | Use of new or known 2-hexyl decanol ester with fatty acid compound as oil body, and in and/or for preparing pharmaceutical and/or cosmetic preparations, e.g. hair shampoos, hair lotions, foam baths, creams, gels and lotions |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE102009034140A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9511144B2 (en) | 2013-03-14 | 2016-12-06 | The Proctor & Gamble Company | Cosmetic compositions and methods providing enhanced penetration of skin care actives |
EP2793831B1 (en) | 2011-12-20 | 2018-10-03 | L'Oréal | Cosmetic composition comprising an anionic surfactant, a solid fatty alcohol and a solid fatty ester, and cosmetic treatment process |
WO2021005104A1 (en) * | 2019-07-11 | 2021-01-14 | Basf Se | Cosmetic composition of liquid crystal lipid particles for hair care composition |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5656664A (en) | 1995-04-13 | 1997-08-12 | Siltech Inc. | Branched esters in skin care applications |
US6391287B1 (en) | 1999-05-06 | 2002-05-21 | L'oreal | Composition containing at least one bicyclic aromatic compound and at least one lipophilic sunscreen, and uses thereof |
-
2009
- 2009-07-22 DE DE200910034140 patent/DE102009034140A1/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5656664A (en) | 1995-04-13 | 1997-08-12 | Siltech Inc. | Branched esters in skin care applications |
US6391287B1 (en) | 1999-05-06 | 2002-05-21 | L'oreal | Composition containing at least one bicyclic aromatic compound and at least one lipophilic sunscreen, and uses thereof |
Non-Patent Citations (1)
Title |
---|
G. Kirchner et al beschreiben im Journal of the American Society., Bd. 107, Nr. 24 von 1985 auf S. 7073 in Schema II als Beispiel 11 einen Ester aus 2-Hexadecanol und Butansäure |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2793831B1 (en) | 2011-12-20 | 2018-10-03 | L'Oréal | Cosmetic composition comprising an anionic surfactant, a solid fatty alcohol and a solid fatty ester, and cosmetic treatment process |
US9511144B2 (en) | 2013-03-14 | 2016-12-06 | The Proctor & Gamble Company | Cosmetic compositions and methods providing enhanced penetration of skin care actives |
WO2021005104A1 (en) * | 2019-07-11 | 2021-01-14 | Basf Se | Cosmetic composition of liquid crystal lipid particles for hair care composition |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2601166B1 (en) | Cosmetic preparations | |
ES2503731T3 (en) | Mixtures of alkylsulfosuccinates and their use | |
US8329147B2 (en) | Alkyl benzoate mixtures | |
US9072917B2 (en) | Linear alkyl esters and their use in cosmetic and/or pharmaceutical compositions | |
DE102008012457A1 (en) | Hydrocarbon mixture, useful e.g. in decorative cosmetics, preferably lipsticks, lip gloss, eye shade, mascara, eye pencil, nail polish and make-up formulations and eye shade, comprises linear hydrocarbons | |
US8846065B2 (en) | Ester mixtures and compositions comprising such ester mixtures | |
DE102008017031A1 (en) | Hydrocarbon mixtures and their use | |
US8921430B2 (en) | Ester mixtures and compositions comprising such ester mixtures | |
EP1443896A1 (en) | Cosmetic preparation containing polycarbonates | |
DE10162697A1 (en) | Cosmetic and / or pharmaceutical sunscreens | |
EP2179986A1 (en) | Mixtures of alkylsulfosuccinates and their use | |
EP2116221A1 (en) | Cosmetic preparation containing hydrocarbons | |
DE102008052520A1 (en) | Cosmetic and / or pharmaceutical preparations | |
DE102008052521A1 (en) | Cosmetic and/or pharmaceutical preparations, useful e.g. to counteract body odor and as sunscreen formulations, comprise an ester of 2-propylheptanol with optionally saturated carboxylic acids and antiperspirant/deodorant material | |
DE102009050430A1 (en) | Cosmetic preparation, useful as e.g. body oil, baby oil, creams, lotions, sunscreen, liquid and bar soaps, and shower bath foam, comprises a glycerol monoalkyl ether, glycerin dialkylether and cationic surface-active compound | |
DE102008022434A1 (en) | Cosmetic preparations containing hydrocarbons | |
DE102009034140A1 (en) | Use of new or known 2-hexyl decanol ester with fatty acid compound as oil body, and in and/or for preparing pharmaceutical and/or cosmetic preparations, e.g. hair shampoos, hair lotions, foam baths, creams, gels and lotions | |
DE102008052053A1 (en) | Cosmetic or pharmaceutical preparation, useful e.g. as styling wax, comprises dialkyl carbonate compound, an emulsifier, an antiperspirant/deodorant active agent, a pigment and/or a dye, an emulsifier, a surfactant and/or a wax component | |
DE102008021844A1 (en) | Cosmetic composition containing esters based on 2-propylheptanoic acid | |
DE102008052054A1 (en) | Cosmetic and/or pharmaceutical preparation, useful e.g. for hair care, hair cleaning and hair coloring, and for decorative cosmetics e.g. lipstick and for post-sun treatment or sanitary wipes, comprises dialkyl(ene) ether compound | |
EP2269567A1 (en) | Ester mixtures and compositions comprising such ester mixtures |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
OAV | Applicant agreed to the publication of the unexamined application as to paragraph 31 lit. 2 z1 | ||
R081 | Change of applicant/patentee |
Owner name: DIERKER, MARKUS, DR., DE Free format text: FORMER OWNER: COGNIS IP MANAGEMENT GMBH, 40589 DUESSELDORF, DE Effective date: 20130523 |
|
R119 | Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee | ||
R119 | Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee |
Effective date: 20150203 |