DE102008049459A1 - Smartcard for medical diagnostics, has micro-fluidic channel for filling cavity, and photodetector is provided, which comprises semi-transparent electrode layer, organic-based optically active layer and counter electrode layer - Google Patents
Smartcard for medical diagnostics, has micro-fluidic channel for filling cavity, and photodetector is provided, which comprises semi-transparent electrode layer, organic-based optically active layer and counter electrode layer Download PDFInfo
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- DE102008049459A1 DE102008049459A1 DE102008049459A DE102008049459A DE102008049459A1 DE 102008049459 A1 DE102008049459 A1 DE 102008049459A1 DE 102008049459 A DE102008049459 A DE 102008049459A DE 102008049459 A DE102008049459 A DE 102008049459A DE 102008049459 A1 DE102008049459 A1 DE 102008049459A1
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
- B01L3/00—Containers or dishes for laboratory use, e.g. laboratory glassware; Droppers
- B01L3/50—Containers for the purpose of retaining a material to be analysed, e.g. test tubes
- B01L3/502—Containers for the purpose of retaining a material to be analysed, e.g. test tubes with fluid transport, e.g. in multi-compartment structures
- B01L3/5027—Containers for the purpose of retaining a material to be analysed, e.g. test tubes with fluid transport, e.g. in multi-compartment structures by integrated microfluidic structures, i.e. dimensions of channels and chambers are such that surface tension forces are important, e.g. lab-on-a-chip
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
- G01N21/03—Cuvette constructions
- G01N21/05—Flow-through cuvettes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
- B01L2200/00—Solutions for specific problems relating to chemical or physical laboratory apparatus
- B01L2200/06—Fluid handling related problems
- B01L2200/0605—Metering of fluids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
- B01L2300/00—Additional constructional details
- B01L2300/06—Auxiliary integrated devices, integrated components
- B01L2300/0627—Sensor or part of a sensor is integrated
- B01L2300/0645—Electrodes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
- B01L2300/00—Additional constructional details
- B01L2300/08—Geometry, shape and general structure
- B01L2300/0809—Geometry, shape and general structure rectangular shaped
- B01L2300/0816—Cards, e.g. flat sample carriers usually with flow in two horizontal directions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01L—CHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
- B01L2300/00—Additional constructional details
- B01L2300/08—Geometry, shape and general structure
- B01L2300/0887—Laminated structure
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
- G01N21/03—Cuvette constructions
- G01N2021/0346—Capillary cells; Microcells
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
- G01N21/03—Cuvette constructions
- G01N21/05—Flow-through cuvettes
- G01N2021/058—Flat flow cell
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/06—Illumination; Optics
- G01N2201/062—LED's
- G01N2201/0628—Organic LED [OLED]
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/20—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising organic-organic junctions, e.g. donor-acceptor junctions
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/30—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains
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- H—ELECTRICITY
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K39/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic radiation-sensitive element covered by group H10K30/00
- H10K39/30—Devices controlled by radiation
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- H—ELECTRICITY
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K65/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element and at least one organic radiation-sensitive element, e.g. organic opto-couplers
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
- H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
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- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H10K85/615—Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
- H10K85/621—Aromatic anhydride or imide compounds, e.g. perylene tetra-carboxylic dianhydride or perylene tetracarboxylic di-imide
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- Life Sciences & Earth Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Immunology (AREA)
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Abstract
Description
Die Erfindung betrifft eine Chipkarte, wie beispielsweise die geplante Lap-on-Chip Carte, wobei die Strömung innerhalb der Mikrokanäle oder Mikrofluidikkanäle des Lab-on-Chip beobachtbar ist.The The invention relates to a smart card, such as the planned Lap-on-chip Carte, with the flow within the microchannels or microfluidic channels the lab-on-chip is observable.
So genannte Lab-On-Chip Technologien gewinnen zunehmend an Bedeutung für die medizinische Diagnostik und andere Untersuchungen. Mit dieser Technologie lassen sich mit sehr geringen Mengen an Ausgangssubstanzen und Reagenzien (Piko- bis Milliliter) vollautomatisierte und integrierte Analysen auf einem einzigen Chip realisieren. Flüssigkeiten lassen sich gezielt durch Ausnutzung der Kapillarkraft sowie durch die Kontrolle der Benetzungseigenschaften der Chipoberfläche bewegen. Die anwendungsspezifischen biologischen, chemischen und physikalischen Prozesse finden in Reaktionskammern (Kavitäten) statt, die über Mikrokanäle definiert befüllt werden.So These lab-on-chip technologies are becoming increasingly important for the medical diagnostics and other examinations. With this technology can be treated with very small amounts of starting substances and reagents (pico to milliliters) fully automated and integrated analyzes realize a single chip. Liquids can be targeted by exploiting the capillary force and by controlling the Move wetting properties of the chip surface. The application-specific biological, chemical and physical processes take place in reaction chambers (Cavities) instead, over Defined microchannels filled become.
Auf einem Glassubstrat von einigen cm2 Größe befinden sich kleine Flüssigkeitskanäle mit einer Breite von 10 µm bis etwa 200 µm und einer Höhe von 10–800 µm. Durch diese kleinen Kanäle wird die Fluidik in die Reaktionskammern (einige mm2 groß) transportiert. In der Anwendung als Zellchip werden einige Zellen in die Reaktionskammer transportiert.On a glass substrate of a few cm 2 size are small liquid channels with a width of 10 microns to about 200 microns and a height of 10-800 microns. Through these small channels, the fluid is transported into the reaction chambers (a few mm 2 large). When used as a cell chip, some cells are transported into the reaction chamber.
Bisher werden die Befüllungen der Kavitäten durch externe Mikroskop-Kamerasysteme überprüft. Diese Systeme sind groß und teuer.So far become the fillings the cavities through external microscope camera systems checked. These Systems are big and expensive.
Aufgabe der vorliegenden Erfindung ist es deshalb, eine Vorrichtung zur Beobachtung der Strömungen in Mikrofluidiksystemen zur Verfügung zu stellen, die als one-way-product mit der Chipkarte hergestellt werden kann.task It is therefore an object of the present invention to provide a device for Observation of the currents in microfluidic systems to make that produced as a one-way product with the smart card can be.
Lösung der Aufgabe und Gegenstand der Erfindung ist daher eine Chipkarte mit zumindest einem Mikrofluidikkanal zur Befüllung einer Kavität, wobei auf der Unterseite des Mikrofluidikkanals eine zumindest semitransparente Elektrodenschicht, darauf eine organisch basierte optisch aktive Schicht und darüber schließlich eine Gegenelektrodenschicht so angeordnet wird, dass der Photodetektor eine von oben in den Mikrofluidikkanal fallende Strahlung detektiert.Solution of Object and subject of the invention is therefore a smart card with at least one microfluidic channel for filling a cavity, wherein on the bottom of the microfluidic channel an at least semitransparent Electrode layer, then an organic based optically active Layer and above after all a counter electrode layer is arranged so that the photodetector detects a falling from above into the microfluidic channel radiation.
Nach einer vorteilhaften Ausführungsform umfasst der Aufbau des Photodetektors zusätzlich noch eine Lochleitschicht zwischen der transparenten Elektrode und der optisch aktiven Schicht.To an advantageous embodiment the structure of the photodetector additionally a Lochleitschicht between the transparent electrode and the optically active layer.
Nach einer vorteilhaften Ausführungsform sind die optisch aktive Schicht und gegebenenfalls die Lochtransportschicht des Photodetektors aus Lösung prozessierbar, so dass der Photodetektor als One-way-Produkt herstellbar ist.To an advantageous embodiment the optically active layer and optionally the hole transport layer of the photodetector from solution Processable, making the photodetector as a one-way product is.
In der Regel fungieren Lochtransportkomponenten als Elektronendonatoren und Elektronentransportkomponenten als Elektronenakzeptoren.In As a rule, hole transport components act as electron donors and electron transport components as electron acceptors.
Nach einer bevorzugten Ausführungsform werden zwei oder mehrere Lochtransportkomponenten kombiniert, da in der Regel diese das Absorptionsverhalten des Elends dominieren.To a preferred embodiment two or more hole transport components combined because in the Usually these dominate the absorption behavior of the misery.
Soll ein Bild mit dem Flachbilddetektor durch den Mikrofluidikkanal hindurch aufgenommen werden, so durchdringt die dem Bild zugeordnete Lichtverteilung die der Lichtverteilung zugewandte Elektrode, die daher aus einem zumindest semitransparentem Material gefertigt ist. Des Weiteren wandelt die Halbleiterschicht in Verbindung mit den beiden Elektroden die Lichtverteilung in elektrische Signale um, die an den einzelnen Teilelektroden der strukturierten Elektrode anliegen.Should a picture with the flat panel detector through the microfluidic channel are received, so penetrates the light distribution associated with the image the light distribution electrode facing, therefore, from a made at least semi-transparent material. Furthermore converts the semiconductor layer in conjunction with the two electrodes the light distribution into electrical signals to those at the individual Abut partial electrodes of the structured electrode.
In dieser Halbleiterschicht befindet sich beispielsweise ein Elend aus den beiden Komponenten P3HT (Absorber-, Elektronen donator und Lochtransportkomponente) und PCBM (Elektronenakzeptor und -transportkomponente), die als Bulk-Heterojunction wirkt, das heißt die Trennung der Ladungsträger erfolgt an den Grenzflächen der beiden Materialien, die sich innerhalb des gesamten Schichtvolumens ausbilden. Ebenso gut kann die Halbleiterschicht als eine mehrere Einzelschichten umfassende Schicht aufgebaut sein, in der Lochtransportkomponente und Elektronentransportkomponente in separaten Schichten vorliegen.In This semiconductor layer is, for example, a misery from the two components P3HT (absorber, electron donor and Hole transport component) and PCBM (electron acceptor and transport component), which acts as a bulk heterojunction, that is, the separation of the charge carriers takes place at the interfaces the two materials that form within the entire layer volume. Equally well, the semiconductor layer can be as a multiple individual layers comprehensive layer be constructed in the hole transport component and electron transport component in separate layers.
Die Erfindung betrifft nicht nur Photodioden auf polymerer Basis, sondern kann auch auf photoaktive Schichten, die auf so genannten small molecules oder auf Nanopartikel basieren, angewendet werden.The The invention relates not only to photodiodes on a polymeric basis, but also can also apply to photoactive layers, which are so-called small molecules or based on nanoparticles.
Bei der Herstellung des Photodetektors nach der Erfindung wird beispielsweise wie folgt vorgegangen: Auf eine zumindest semitransparente Bottomelektrode (z. B. ITO) wird eine Blendschicht aufgeschleudert. Dazu werden die Blendkomponenten in einem geeigneten Lösungsmittel (z. B. Chloroform oder Xylol) gelöst. Auf die Blendschicht wird eine semitransparente Topelektrode (z. B. ein dünnes Schichtsysteme aus Ca und Ag) aufgebracht (z. B. durch thermisches Aufdampfen).at the production of the photodetector according to the invention is, for example proceeded as follows: on an at least semitransparent bottom electrode (eg ITO) a glare layer is spin coated. To do this the blend components in a suitable solvent (eg, chloroform or Xylene). On the blend layer is a semi-transparent top electrode (z. B. a thin layer systems from Ca and Ag) (eg by thermal vapor deposition).
Organisch basierte Photodetektoren können relativ einfach hergestellt werden, indem die organische Halbleiterschicht mit drucktechnischen Methoden aus der Lösung aufgebracht wird. Beispielsweise kann die organische Halbleiterschicht auch durch sein coating, Rakeln oder Siebdrucken aufgebracht werden. Außerdem weisen organische Photodetektoren eine relativ hohe Kompatibilität zu verschiedenen elektronischen Ansteuerungstechnologien auf.Organic-based photodetectors can be produced relatively simply by applying the organic semiconductor layer from the solution by means of printing technology. For example, the organic semiconductor layer can also be applied by coating, knife coating or screen printing. In addition, organic photodetectors have a relatively high compatibility with various NEN electronic control technologies on.
Ein organischer Photodetektor kann zusätzlich zur photoaktiven Schicht, die beispielsweise P3HT/PCBM, CuPc/PTCBI, ZNPC/C60, konjugierte Polymer-Komponenten oder Fulleren-Komponenten umfasst, eine Elektron/Loch blockierende Schicht, so genannte Hilfsschichten, umfassen. Elektron/Loch blockierende Schichten sind aus der Technologie für organische LEDs bekannt. Ein geeignetes organisches Material für die Elektron blockierende Schicht ist zum Beispiel TFB.One organic photodetector can be used in addition to the photoactive layer, For example, P3HT / PCBM, CuPc / PTCBI, ZNPC / C60, conjugated polymer components or fullerene components, an electron / hole blocking layer, called auxiliary layers, include. Electron / hole blocking layers are from technology for organic LEDs known. A suitable organic material for the electron blocking layer is for example TFB.
Im
Folgenden wird die Erfindung noch einer Figur, die eine Ausführungsform
der Erfindung zeigt, näher
erläutert:
Die
Figur zeigt ein Beispiel für
einen Schichtaufbau eines Photodetektors Ein Ausführungsbeispiel
für den
Aufbau der organischen Photodioden ist aus der Figur ersichtlich.
Der Aufbau ist in Form eines Stacks dargestellt, bestehend aus Topelektrode
The figure shows an example of a layer structure of a photodetector. An exemplary embodiment of the structure of the organic photodiodes can be seen from the figure. The structure is shown in the form of a stack, consisting of top electrode
Es
ist ein Beispiel für
den Aufbau eines organischen Photodetektors im Schichtaufbau (Stack)
mit zwei aktiven organischen Schichten
Die
Bottomelektrode
Nach einer bevorzugten Ausführungsform der Erfindung wird die zumindest semitransparente Bottomelektrode oder untere Elektrode strukturiert aufgebracht, so dass ein Photodetektorarray resultiert. Die darauffolgende Halbleiterschicht mit eventuellen Hilfsschichten kann sowohl strukturiert als auch vollflächig aufgebracht werden. Die zweite Elektrode wird bevorzugt aus Kostengründen vollflächig aufgebracht. Damit resultiert eine Vorrichtung zur bildlichen Messung der Strömung in einem Mikrofluidikkanal, deren Auflösung dem Durchmesser der Photodetektoren entspricht.To a preferred embodiment of Invention is the at least semitransparent bottom electrode or structured lower electrode so that a photodetector array results. The subsequent semiconductor layer with possible auxiliary layers can be applied both structured and full-surface. The second electrode is preferably applied over the entire surface for cost reasons. This results a device for the visual measurement of the flow in a microfluidic channel, their resolution corresponds to the diameter of the photodetectors.
Das einfallende Licht zur Beleuchtung des Kanals von oben kann beispielsweise eine organische Leuchtdiode (OLED) sein. Sowohl die OLED als auch der organische Photodetektor haben eine Dicke von kleiner 1 µm und können somit einfach in den Chip integriert werden.The incident light to illuminate the channel from above, for example an organic light emitting diode (OLED). Both the OLED and the organic photodetector have a thickness of less than 1 micron and thus can easy to be integrated into the chip.
Claims (4)
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DE102008049459A DE102008049459A1 (en) | 2008-09-29 | 2008-09-29 | Smartcard for medical diagnostics, has micro-fluidic channel for filling cavity, and photodetector is provided, which comprises semi-transparent electrode layer, organic-based optically active layer and counter electrode layer |
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DE102008049459A DE102008049459A1 (en) | 2008-09-29 | 2008-09-29 | Smartcard for medical diagnostics, has micro-fluidic channel for filling cavity, and photodetector is provided, which comprises semi-transparent electrode layer, organic-based optically active layer and counter electrode layer |
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DE102008049459A Withdrawn DE102008049459A1 (en) | 2008-09-29 | 2008-09-29 | Smartcard for medical diagnostics, has micro-fluidic channel for filling cavity, and photodetector is provided, which comprises semi-transparent electrode layer, organic-based optically active layer and counter electrode layer |
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