DE102008034386A1 - New protein hydrolyzates and derivatives, useful in textile treatment and cosmetic compositions, e.g. hair tonics, are obtained from hairs of mammals with high hair density - Google Patents

Abstract

New protein hydrolyzates (I) are obtained from hairs of mammals having a hair density of at least 400 hairs per cm 2>. Also new are protein hydrolyzate derivatives (II), obtained by chemical conversion of (I).

Description

The The present invention relates to protein hydrolysates and their derivatives and agents containing these protein hydrolysates and their derivatives, For example, cleaners for textiles, hard surfaces and the human body. In particular, the invention relates Hair treatment compositions and the use of these agents for cleaning and / or care of the skin and hair.

protein are either by splitting animal or vegetable protein by adding acids under high temperatures and pressure or obtained through the use of enzymes. This ever arises after processing, shorter protein chains and amino acids. The same principle applies to seasoning and soy sauces as well as gelatin.

protein are therefore hydrolysis products of certain proteins, eg. B. of animal based collagen (collagen hydrolysates) or of vegetable-based wheat protein (gluten). One differentiates in the production between alkaline, acidic and enzymatic Hydrolysis.

at the alkaline hydrolysis finds a statistical cleavage of Peptide chain instead. As the carboxy group of the peptides during hydrolysis as a salt, whereas the amino group is unprotected is and can be partially cleaved, results in a hydrolyzate, in which the polypeptides have a higher number of carboxy than Amino groups included; the isoelectric pH range of these products is <6. Generally, losses of amino acids (lysine, cysteine, Threonine and arginine). Also, the hydrolysis under acidic conditions leads to a non-specific opening of the peptide bond. Unlike the alkaline hydrolysis, is the acidic degradation the amino group as a salt and the carboxy function in free form before, however, a much higher stability as the unprotected amino group. On this Ways are obtained hydrolysates with an isoelectric pH range of <7. As a general rule In particular, lysine is partially destroyed.

Enzymatic hydrolysis is the most gentle. Depending on the reaction conditions and enzymes used, protein hydrolysates with a defined degree of degradation and a peptide spectrum are obtained. An enzymatic cleavage to the amino acids is possible only with considerable effort, since several enzymes with different, but complementary and thus effective in the complex activities must be equipped for this purpose. Far more favorable is to evaluate the enzymatic partial hydrolysis, which achieves degrees of hydrolysis of up to 35%; on average, every third peptide bond is cleaved here. For hydrolysis, preferred are enzymes having a very broad spectrum of activity to be used (eg. B. Pronase ^®).

protein are widely used in the cosmetics industry. The for the preparation of cosmetic agents suitable protein hydrolysates have molecular weights of about 2000, are readily soluble in water and no longer surface active. Because of their colloidal properties they are suitable as dispersants and support the soil-carrying capacity of surfactant solutions. They attract easily to the skin and can their moisture retention to improve. Because protein hydrolysates are microbiologically susceptible are, corresponding products must be preserved.

human Skin and human hair are becoming more diverse today Way treated with cosmetic preparations. This includes such as cleansing the hair with shampoos, with care and regeneration Rinses and cures and bleaching, dyeing and deforming the hair with colorants, tinting agents, Wells and styling preparations. But also in other Context, the human body comes into contact with different products, for example, when washing with manual Dishwashing, when using with detergents or Fabric softeners treated textiles, etc ..

It has therefore long been common for the corresponding products mild and skin-friendly or hair-care to shape or at least to provide another preparation, that following the application of the first a care benefit provides. In the case of hair treatment, usually in the form of a conditioner, the hair with special active ingredients, for example, quaternary ammonium salts or special ones Polymers, treated. This treatment will vary depending on the formulation the combability, the hold and the fullness of the hair improves and reduces the split rate.

Farther have recently been called so-called combination preparations designed to reduce the overhead of the usual multi-stage process, especially when used directly by consumers.

The available active ingredients for both separate aftertreatment as well as for Combination preparations generally have a preferential effect on the skin or hair surface. Thus, active ingredients are known which give the hair shine, hold, fullness, better wet or dry combabilities or prevent splitting. Just as important as the external appearance of the hair, however, is the internal structural cohesion of the hair fibers, which can be greatly influenced, in particular, by oxidative and reductive processes such as dyeing and perming.

The However, known active ingredients may not meet all needs cover adequately.

Especially When cleaning hair leads to increased hygiene awareness to an ever more frequent cleaning of the hair. Order here in addition to optimal cleaning and care of hair long-term use To be, the means used must be particularly mild to Hair and scalp. Although mild surfactants are in themselves known to the most diverse groups, but satisfy them not all consumer wishes sufficiently. The same applies mutatis mutandis to cleaning agents, which are used by the consumer in the household and for Detergents for textiles.

So For example, it has been shown that frequent Washing hair will affect the structure of the keratin fibers can, so that the addition of certain substances required is that strengthen the internal structure of the keratin fibers and thus the strength, feel and tensile strength of keratin fibers improve.

It is known to use protein hydrolysates in cosmetic products, to give the products a specific property profile. It has now been found that certain protein hydrolysates especially for use on the human body are suitable and that their effect by a special Formulation of the products can be increased by the products are formulated PEG-free.

In a first embodiment, the present application relates to protein hydrolysates obtained from hairs of mammals having a hair density of at least 400 hairs per cm ² .

As already stated, protein hydrolysates are degradation products of proteins (proteins, proteins). The name Protein goes back to Berzelius and is derived from Greek proteuein = "be the first". Proteins are natural occurring copolymers, which are usually composed of 20 different α-amino acids as monomers. Of the closely related polypeptides they are distinguished by their molecular size, though not always strictly demarcated: From about 100 monomer units (Amino acid residues) are usually called proteins. It relative molecular weights of 10,000 to several million.

The sequence of the individual building blocks (primary structure) is generally not subject to any obvious laws, so that potentially any combination is possible. It is estimated that about 10 ¹¹ different proteins occur in our habitat; A higher organism should contain about 10 ⁵ -10 ⁶ different proteins.

you divides the proteins according to shape and behavior against water and salts a in globular proteins z. Albumin, globulins, gluteline, Histones, prolamins, protamines, as well as scleroproteins, e.g. Eg keratins, Fibroin, elastin, collagens. After the composition you meet the division into simple proteins, their hydrolysis only amino acids yields, and composite proteins (conjugated proteins, obsolete Proteide), which except amino acids for the specific properties essential nonprotein component the prosthetic groups include: nucleoproteins (nucleic acids; Chromatin), glycoproteins (carbohydrates, lectins, antibodies, Blood group substances), lipoproteins (lipids), phosphoproteins (phosphoric acid; Casein, vitelline), chromoproteins (dyes, hemoglobin, Cytochromes, catalase, rhodopsin), metalloproteins (metals, ceruloplasmin, Transferrin, ferredoxin and other iron proteins) and others.

According to the invention, the protein hydrolysates are obtained from hairs of mammals having a hair density of at least 400 hairs per cm ² . Hair is an appendage of the skin consisting of keratin (a horny scleroprotein), which protects the body surface as a fur or fur in the mammal. In humans, this protective function has largely been lost.

keratin (from Greek kéras, genitive kératos = horn) or "horn substance" is a collective term for various water-insoluble fiber proteins derived from human or animal organisms are formed. Because of their molecular Conformation (α-helix or β-sheet) is different one obtains α- and β-keratins.

keratins are the main component of mammalian hair, reptilian scales, Feathers, nails and claws, horns and the beards the whales. The firmness of these keratins is due to fiber formation reinforced: form the individual amino acid chains a right-handed alpha helix. Several of these helices form a left-handed superhelix (= protofibril). Several protofibrils combine to form a microfibril; these in turn, combine to form bundles and form macrofibrils out. The fibers are the stiffer, the stronger their components by disulfide bridges of the amino acid L-cystine are cross-linked. So contains the Kerstin in horns and Cling more disulfide bridges than that in wool and hair.

Protein hydrolyzates according to the invention are obtained by at least partial cleavage of Kerstinen from mammalian hairs, wherein said mammal has a hair density of at least 400 hairs per cm ² .

By Further processing of protein hydrolysates produces protein hydrolyzate derivatives. Among protein hydrolyzate derivatives are within the scope of the present Invention chemically and / or chemoenzymatically modified protein hydrolysates to understand such as those under the INCI names Sodium Cocoyl Hydrolyzed Kerstin Protein, Laurdimonium Hydroxypropyl Hydrolyzed Kerstin Protein, Potassium Cocoyl Hydrolyzed Kerstin, Potassium Undecylenoyl Hydrolyzed Kerstin and Laurdimonium Hydroxypropyl Hydrolyzed Kerstin known compounds.

Another object of the present invention are therefore protein hydrolyzate derivatives obtained by chemical reaction of protein hydrolyzates from hair of mammals with a hair density of at least 400 hairs per cm ² .

Protein hydrolyzates according to the invention and their derivatives are obtained by at least partial cleavage (and optionally further processing) of Kerstinen from mammalian hairs, wherein said mammal has a hair density of at least 400 hairs per cm ² . Suitable animal species whose hair can be selected according to the invention as the starting substance are described below.

For example, mammals having a hair density of at least 400 hairs per cm ² may be insectivores, such as the European Mole and / or the Russian Desman.

The Coat color of the European mole is varying, dark bluish-blackish. The underside with greenish Irisierendem, blurred longitudinal stripes, especially at old animals is very pronounced. Sometimes that seems The coat is almost black, but there are no pure black skins. The summer coat is gray and dull. The coat is extreme short and tight. The Russian Desman, also Wychuchol or Vychuchol is with 20 to 25 cm and a tail length of 16 to 19 cm about the size of a hamster and thus much smaller than the muskrat. His coat is also known as "silver bisam".

The short, fine to silky, very shiny and dense hair is brownish-reddish, dark brown to chestnut brown with metallic shimmering deep purple tones that to the sides to become ever lighter around the dew a shiny one show silvery white color.

Mammals with a hair density of at least 400 hairs per cm ² may be, for example, small bears such as the Bassarisk or Katzenfrett and the Raccoon.

The two species, the North American and the Central American Cat fry, belonging to the family of the small bears, also American ringtail (cat), Bassarisk or Raccoonfox, from the Spanish-speaking population Cacomixtle ("cat squirrel") called. The coat is 61 to 100 cm long, with the tail added with 31 to 53 cm.

Of the Raccoon (Procyon lotor), also explicitly as North American Raccoon or anciently called Schupp, is the most widespread representative of the family of the small bears and was originally only in Central and North America. Since the middle of the 20th century he is also on the European mainland and the Caucasus native, having been there from fur farms and Gehhegen escaped or was suspended.

• – Füchse, beispielsweise Weißfuchs oder Eisfuchs, Blaufuchs, Weißfuchs oder Polarfuchs, Grisfuchs oder Graufuchs, Kitfuchs, Kreuzfuchs, Golden Island Fuchs, Korsak(-Fuchs), Rotfuchs, Silberfuchs, Seefuchs,
• – Tanuki, Marderhund oder Enok, Haushund,
• – Kojote (Coyote),
• – Schakal
• – Wolf

For example, mammals with a hair density of at least 400 hairs per cm ² may also be from the dog family, such as

• Foxes, for example white fox or fiery fox, blue fox, white fox or arctic fox, Grisfuchs or gray fox, kitfox, cruciform fox, golden island fox, korsak (fox), red fox, silver fox, sea fox,
• - Tanuki, raccoon dog or Enok, house dog,
• - Coyote (Coyote),
• - Jackal
• - Wolf

The Foxes are among the species with the most diverse Hair variations, both in color, hair length and hair texture. One differentiates between noble foxes, the silver, cross, Blue and white foxes, platinum fox (mutant foxes) and noblest varieties of red foxes. And all the rest Species of red foxes, as far as not under their species name be traded (Kitfuchs, Grisfuchs, Korsak, etc.).

Of the Ice or polar fox splits in two color shots, the blue fox and the white fox. The coat is about 46 to 68 cm long, the tail 30 to 40 cm, farm animals are average significantly larger. The paws are tight in winter hairy.

The Blue fox fur is considered more valuable than the felted and smaller Fur of white fox. Almost white blue foxes with only slightly indicated darker fur center are called Shadowfuchs traded. The furs from wild catches are about 50 to 65 cm long, the tail 25 to 35 cm, the male skins are only slightly larger than the females. The Skins from breeding are usually much larger. The long and very silky hair varies from blue-brown and bright "café au lait "to light blue gray and deep dark brown, sometimes almost black with shades of rusty red and loamy dirt, partly with Silver hair. The summer coat is dark black-brown and mostly something brownish than the winter coat.

Of the White fox, a color variant of the ice or polar fox, lives in the entire northern polar zone. Corresponding adapted to the climate is its white, dense, langgranniges and fine winter coat. The summer coat is stone gray to greyish brown, almost olive brown, sometimes even darker. The Russian qualities are after (not separately listed) stages of Development and provenances.

Of the Grisfuchs is daintier than the red fox, has also striking short legs but a relative long bushy tail. The coat is 53 to 73 cm long, the tail 28 to 40 cm. The awning hair is rough and stiff. The back is pepper- and salt-like colored, d. H. silvery or dark gray-black, from which the name of the animal is derived. The Cheeks, chest and dew are rusty yellow to coppery red, the tail is graymeliert and has a broad deep black stripe above. Zoologically, there are two species, the island gray fox and the mainland gray fox.

At the in North America native Kitfuchs or Steppenfuchs differs one two subspecies, the Swiftfuchs and the Großohrkitfuchs. The Swiftfuchs is with a body length of 35 up to 45 cm and a tail length of 25 to 30 cm the smallest Fox species of America. The dense and fine coat is reddish- to yellow-brown with white dew. Depending on provenance is it sometimes reddish, even lighter, the tail tip is black.

Of the Kreuzfuchs is a color variety of the red fox. characteristic Characteristic is the black or dark cross-like Drawing over the neck and shoulders, the back and the pages are pale or brown yellow, reddish or dark brown, often heavily silvered. It is widespread in Alaska, Canada Eastern Siberia and Kamchatka.

Of the Golden Iceland fox is a cross between polar fox and silver fox, with an interesting silver-reddish effect.

The Homeland of the Korsakfuchs (occasionally also Korsuk), Steppenfuchs or Sandfox are the steppes of Siberia, Central Asia of the Caspian Sea to Mongolia, Manchuria and Korea. The coat is only 50 up to 60 cm long, the densely hairy tail is much shorter as in the similar red fox; the legs are longer and the ears are bigger. The color is pale yellow to yellowish or reddish gray. The hair is dense; the back awns are silvery ringed, throat, chest and babies are yellowish white. The pale yellow tail is blackened black. The overall impression is reminiscent of a Kitfuchsfell.

Red foxes occur on all continents except the Antarctic. Corresponding great is the diversity of the races and the diversity the skins.

Typical is the fuchs- and brick-red color, the often black or brown-yellow interspersed Körpero over the side, white throat, white breast and white tail tip. However, the color variants are unlimited, even between the European darker fir and Kohlfuchs, the lighter Birk or Goldfuchs and the black-bellied Moorfuchs there are significant differences.

The Hairiness is short to long, silky to coarse, mostly dense. The Undercoat is fine and soft; generally dense to very dense (Penetrated). The back is the long-haired, to the sides down to the dew, the hair is much shorter. from time to time At the nape of the neck is a curly-like drapery. Numerous skins have bald spots on the chest. They come from mother animals, the hair during the nursing time to the Have removed teats.

Magellan (Mag (h) ellan-) Patagonischer- or Culpeo Fox, Andean jackal, "Firelander Fox", the fur denomination is mostly Magellanfuchs. His coat is very silky, but with something woolly character. The back is gray with a black one Strip in the midline of the body and the leg sides are reddish, a dark brown spot in the popliteal fossa, black tail tip. He is after the maned wolf the South America's largest wild dog with one Body length from 52 to 120 cm, tail length 30 to 51 cm.

Of the Silberfuchs, zoologically also Schwarzsilberfuchs, is actually a color variant of red fox (Schwärzling). In free Wild is the silver fox only a small number in the northern North America and Northeastern Siberia. The wild one American silver fox is a blackwing of the various Red Fox species in whose area of distribution he lives, accordingly different are the skins from the corresponding areas. Where the red fox fur different shades of color in the reddish brown Spectrum, are in the Silberfuchs all color pigments black. The more striking are the non-colored, silver-white Hair or hair sections, too, the tail tip is like the red fox White. The basic color of the coat is black (deep "blue") with varying degrees of silvering. Except the black ones Awning hair made from the more or less dark undercoat stick out, black granny hair with a white Cross bandage. Everything together then appears as "silvering", their intensity varies depending on the fashion becomes.

The Hairiness is long and silky to fine, shiny and tight, the under hair is covered well by the awn hair. The The finest hair is on the nape of the neck, often with a curly one Curtain near the shoulders. The tail is particularly bushy.

Of the originally only in eastern Siberia, northeastern China and Japan based raccoon dog is due to expatriation in Ukraine today to Finland and also to Germany penetrated. In the fur trade he is under the name of sea fox or Tanuki known. On the smoking auctions, the fur, probably because of its in part raccoon-like Appearance with the misleading name Finnraccoon or Chinese raccoon (raccoon). Sometimes he is also referred to as a raccoon dog. The about fox-sized, long-haired and close-haired fur has as simple Characteristic opposite the raccoon a stub tail; the strange whitish gray bandage over the eye area makes otherwise similar to the raccoon. The keynote the coat is a dirty earth-yellow or yellow gray, often with a more or less wide dark cross-shaped Back drawing. The rather rough awn hair reaches at the neck a length of 6.5 to 9 cm and is still there longer than the fox. Relatively Often there are color variations, albinos, yellow and white gray Skins.

invention Means can be one or more hydrolyzates of dog hair contain. Particularly preferred invention Means contain at least one hydrolyzate of hair at least one of the breeds listed below. Each in parentheses set terms correspond to the name of the Breed according to FCI (Fédération Cynologique Internationale), by far the largest World Cynological Federation based in Brussels (Belgium).

Preferred agents according to the invention contain at least one hydrolyzate of hair of dogs of the breed
Affenpinscher (2/1/186) (B)
Afghan Hound, Afghan (*) (10/1/228) (B)
Agassin
Aidi (2/2/247) (B)
Airedale Terriers (3/1/7) (B)
Akbaş (2/2/331) (Kangal) (B)
Akita Inu (5/5/255) (B)
Alangu Mastiff
Alan's
Alano, Dogo Canario (provisional 2/2/346) (B)
Alapaha Blue Blood Bulldog (B)
Alaskan Malamute (5/1/243) (B)
Alpine Dachsbracke (6/2/254) (B)
Old Danish Pointing Dog (7/1/281) (B)
Old German Shepherd Dog (B)
Old German shepherd dogs
Fox, see also Harzer fox (B)
Yellow cheek (B)
cow dog
Sheep Poodle (B)
Black (B)
Strobel
Stumper (B)
Tiger (B)
American Akita (5/4/344) (B)
American Bulldog (B)
American Collie (B)
American Eskimo Dog (B)
American Foxhound (6/1/303) (B)
American Hairless Terrier (B)
American Pit Bull Terrier (B)
American Staffordshire Terrier (3/3/286) (B)
American staghound
American Toy Terrier (B)
American Water Spaniel (8/3/301) (B)
American Canadian (AC) White Shepherd see Berger Blanc Suisse (B)
American Cocker Spaniel (8/2/167) (B)
American Collie (B)
Anatolian Shepherd Dog see Çoban Köpeği (B)
Anglo-Français de petite vènerie (6/1/325) (B)
Appenzell Mountain Dog (2/3/46) (B)
Arabian Greyhound see Sloughi (B)
Argentinean Great Dane see Dogo Argentino (B)
Ariégeois (6/1/20) (B)
Australian Cattle Dog (1/2/287) (B)
Australian Stumpy Tail Cattle Dog (provisional 1/2/351)
Australian Heeler see Australian Cattle Dog (B)
Australian Kelpie (1/1/293) (B)
Australian Shepherd (provisional 1/1/342) (B)
Miniature Australian Shepherd (B)
Australian Silky Terrier (3/4/236) (B)
Australian Terrier (3/2/8) (B)
Azawakh, Berber Greyhound, Tuareg Greyhound (10/3/307) (B)
Bakarwal, Kashmir Mastiff
Balearic Running Dog see Podenco Ibicenco (B)
Bali mountain dog, Kintamani dog (B)
Balkan racks (Balkanski gonic) (6/1/150) (B)
Bandog (Chain Dog, Watchdog)
Bangkaew Dog (B)
Barbet (8/3/105) (B)
Bardino see Perro de Ganado Majorero (B)
Borzoi, Russian Greyhound (10/1/193) (B)
Basenji (5/4/43) (B)
Basset artésien normand (6 / 1.3 / 34)
Basset bleu de Gascogne, Blue Basset of the Gascony (6 / 1.3 / 35) (B)
Basset d'Artois (extinct)
Basset fauve de Bretagne (6 / 1.3 / 36) (B)
Basset Hound (6/1/163) (B)
Bavarian Mountain Sweatdog (6/2/217) (B)
Beagle (6/1/161) (B)
Beagle-Harrier (6 / 1.2 / 290)
Bearded Collie (1/1/271) (B)
Beauceron (1/1/44) (B)
Bedlington Terrier (3/1/9) (B)
Belgian Shepherd Dog (1/1/15)
Groenendael (B)
Laekenois (B)
Malinois (B)
Tervueren (B)
Bergamask Shepherd Dog (1/1/194) (B)
Berber Greyhound see Azawakh (B)
Berger Blanc Suisse (provisional 1/1/347) (B) Old term: American Canadian AC White Shepherd
Berger de Beauce see Beauceron (B)
Berger de Laeken see Laekenois (B)
Berger de Picardie (Berger Picard) (1/1/176) (B)
Berger des Pyrenees see Pyrenean Shepherd (B)
Berger de Savoie also Berger de Alpes
Bernese running dog see also Swiss running dog (B)
Bernese Mountain Dog (2/3/45) (B)
St. Bernard, St. Bernard's Dog (2 / 2.2 / 61) (B)
Bichon Frisé, Curly Bichon (Bichon à poil frisé) (9 / 1.1 / 215) (B)
Billy (6 / 1/1/25)
Bisben, Himalayan sheepdog
Black and Tan Coonhound (6/1/300) (B)
Blenheim, English Toy Spaniel (B)
Bloodhound, Hubertushund, Chien de Saint-Hubert (6/1/84) (B)
Bluetick Coonhound (B)
Bobtail (1/1/16) (B)
Bohemian Rauhbart
Boerboel (B)
Bolognese (9 / 1.1 / 196) (B)
Bolonka franzuska (B)
Bolonka Zwetna (B)
Dogue de Bordeaux (Dogue de Bordeaux) (2/2/116) (B)
Border Collie (1/1/297) (B)
Border Terrier (3/1/10) (B)
Bosanski Ostrodlaki Gonic Barak, Bosnian Shaggy Running Dog (6/1/155)
Bosnian Shaggy Running Dog
Boston Terrier (9/11/140) (B)
Bouvier des Ardennes, Ardennes German Shepherd (1/2/171)
Bouvier des Flandres (1/2/191) (B)
Boxer German Boxer (2/2/144) (B)
Bracco Italiano (7/1/202) (B)
Brandlbracke (6/1/63) Vieräugel or Carinthian Bracke (B)
Braque Beige (extinct)
Braque de l'Ariège (7/1/177)
Braque d'Auvergne (7/1/180) (B)
Braque du Bourbonnais (7/1/179) (Bourbonnais Pointing Dog) (B) Braque Français
Braque Français, Type Gascogne (grande waist) (French Pointing Dog - Type Gascogne) (7/1/133)
Braque Français, Type Pyrénées (petite waist) (French Pointing Dog - Type Pyrenees) (7/1/134) (B)
Braque Saint-Germain (7/1/115) (B)
Brazilian Mastiff see Fila Brasileiro (B)
Brazilian Terrier see Terrier Brasileiro (B)
Briard (Bergerde Brie) (1/1/113) (B)
Briquet Griffon Vendéen (6/1/19)
Brussels Griffon see Griffon Bruxellois
Bulldog see English Bulldog (B)
Broholmer (2/2/315) (B)
Buhund see Norwegian Buhund (B)
Bullmastiff (2/2/157) (B)
Bull Terrier (3/3/11) (B)
Ca de Bestiar (1/1/321) (B)
Ca de Bou, Majorca Great Dane (2/2/249) (B)
Ca Rater Mallorquín (B)
Ca Rater Valenciano
Cairn Terrier (3/3/4) (B)
Cane Corso Italiano, also: Cane Di Maccelaio, Cane Corso (provisional 2/2/343) (B)
Cane da Pastore Bergamasco (1/1/194) (B)
Cane da Pastore Maremmano Abruzzese (1/1/201) (B)
Cão da Serra da Estrêla (2/2/173) (B)
Cão de Agua Português, Portuguese Water Dog (8/3/37) (B)
Cão de Castro Laboreiro Castro Laboreiro Dog (2/2/170) (B)
Cão Fila de São Miguel (provisional 1/2/340) (B)
Cão da Serra de Aires (1/1/93) (B)
Caravan Hound (B)
Carolina Dog (B)
Carpatin
Catahoula Bulldog (B)
Catahoula Leopard Dog (B)
Cavalier King Charles Spaniel (9/7/136) (B)
Ceský Fousek (Czech: Rauhbart) (7/1/245) (B)
Cesky Terrier, Czech Terrier (3/2/246) (B)
Chart Polski (10/3/333) Polish Greyhound (B)
Chesapeake Bay Retrievers (8/1/263) (B)
Chien d'Artois (6/1/28) (B)
Chien de Montagne des Pyrénées Pyrenees Mountain Dog, Patou (2/2/137) (B)
Chihuahua (9/6/218) (B)
Chin also Japan Chin (B)
Chinese Crested Dog (9/4/288) (B)
Chinese Chongqing Dog
Chinook (B)
chippiparai
Chortaj, Hortaya Borzaya (B)
Chongqing Dog
Chodsky pes, Chodenhund (B)
Chow Chow (5/5/205) (B)
Ciine de turme romanesc, Romanian herding dog
Carpatin (provisionally 1/1/350)
Mioritic (provisional 1/1/349) (B)
Cimarron Urugayo (provisional 2/2/353) (B)
Cirneco dell'Etna (5/7/199) (B)
Clumber Spaniel (8/2/109) (B)
Çoban Köğği (2/2/331) (Kangal) (B)
Cocker Spaniel, English Cocker Spaniel (8/2/5) (B)
Collie (B)
Long-haired (1/1/156) (B)
short-haired (1/1/296) (B)
combai
Continental Bulldog
coonhound:
Black and Tan Coonhound (6/1/300) (B)
Bluetick Coonhound (B)
English Coonhound, Redtick Coonhound
Plott Hound (B)
Redbone Coonhound (B)
Treeing Walker Coonhound (B)
Corgi see Welsh Corgi Cardigan (1/1/38) and Welsh Corgi Pembroke (1/1/39)
Coton de Tuléar (9/1/283) (B)
Curly Coated Retrievers (8/1/110) (B)
Cursinu (B)
Dachshund, Dachshund, Teckel (4/1/148) (B)
Dalmatian (6/3/153) (B)
Dandie Dinmont Terrier (3/2/168) (B)
Dansk-Svensk Gaardhound (B)
Danish Great Dane see Great Dane (B)
Deerhounds (10/2/164) (B)
Designer dog, hybrid dog
German Wirehaired Hair (7/1/98) (B)
German Shorthair (7/1/119) (B)
German Longhair (7/1/117) (B)
German Stichelhaar (7/1/232) (B)
German Brackie (6/1/299) (B)
Great Dane (2/2/235) (B)
German Boxer (2/2/144) (B)
German Hunting Terrier (3/1/103) (B)
German Pinscher (2/1/184) (B)
German Shepherd Dog (1/1/166) (B)
German Spitz see Spitz (breed of dog) (B)
United Spitz
Pomeranian
Mittelspitz
Wolfsspitz, Keeshond (B)
Pomeranian
German quail (8/2/104) (B)
Dingo (B)
New Guinea Dingo (Hallstrom Dog) (B)
Doberman (2/1/143) (B)
Dogo Argentino (2/2/292) (B)
Dogo Canario see Alano (2/2/346) (B)
Tri-color Serbian Running Dog (Srpski Trobojni Gonic) (6/1/229) (B)
Drentse Patrijshond (711/224) (B)
Drever (6/1/130)
DSH (*) see German Shepherd (B)
Dunker (6/1/203) (B)
Elk Dog (5/2/242) (B)
Elo (B)
English Bulldog, Bulldog (2/2/149) (B)
English Bull Terrier see Bull Terrier (B)
English Cocker Spaniel (8/2/5) (B)
English Coonhounds (B)
English Foxhound see Foxhound (B)
English Pointer (7/2/1) (B)
English Setter (7/2/2) (B)
English Springer Spaniel (8/2/125) (B)
English Toy Spaniel or English Toy Spaniel (King Charles Spaniel) (B)
English Toy Terrier (3/4/13) (B)
Entlebucher Sennenhund (2/3/47) (B)
Epagneul Breton (7/1/95) Breton Spaniel (B)
Epagneul bleu de Picardie (Blue Picardy Spaniel) (7/1/106) (B)
Epagneul de Pont-Audemer (7/1/114) Pont-Audemer Spaniel (B)
Epagneul Français (French Spaniel) (7/1/175) (B)
Epagneul Picard (Picardy Spaniel) (7/1/108) (B)
Erdélyi Kopó (Transylvanian Hound - Hungarian Hound) (6/1/241) (B)
Eskimo Dog (B)
Eurasier (5/5/291) (B)
European Husky / Scandinavian Hound (B)
Field Spaniel (8/2/123) (B)
Fila Brasileiro (2/2/225) (B)
Finnish hare (6/1/51)
Finnish Lapphund (Suomenlapinkoira) (5/3/189) (B)
Finnish Spitz (5/2/49) (B)
Flat-coated Retrievers, Flat Coated Retrievers (8/1/121) (B)
Foxhound English Foxhound (6/1/159) (B)
Fox Terrier
Fox Terrier (Smooth) (3/1/12) (Straight-Shaven) (B)
Fox Terrier (Wire) (3/1/169) (Wirehaired) (B)
French Bulldog (9/11/101) (B)
French running dogs
Billy (6/1/25)
Français tricolore (6/1/219) (French Tricolor Running Dog)
Français blanc et noir (6/1/220) (French White-Black Riding Dog)
Français blanc et orange (6/1/316) (French white-orange running dog)
Grand Anglo-Français blanc et noir (6/1/323)
Grand Anglo-Français blanc et orange (6/1/324)
Grand Anglo-Français tricolore (6/1/322)
Grand Bleu de Gascogne (6/1/22) (B)
Grand Gascon Saintongeois (6/1/21)
Grand Griffon Vendéen (6/1/282)
Grand Griffon Nivernais (6/1/17)
Griffon Fauve de Bretagne (6/1/66)
Poitevin (6/1/24) (B)
French Spaniel (B)
French Pointing Dog (B)
Frisian Water Dog see Wetterhond (B)
Galgo Español (10/3/285) (B)
Gammel Dansk Hønsehund Old Danish Pointing Dog (7/1/281) (B)
German Trailhound see European Husky
Glen of Imaal Terrier (3/1/302) (B)
Golden Retrievers (8/1/111) (B)
Gonczy Polski (provisional 2 / 1.2 / 254) (B)
Gordon Setter (7/2/6) (B)
Gos d'Atura see Catalan Shepherd Dog (B)
Grand Anglo-Français blanc et noir (6/1/323)
Grand Anglo-Français blanc et orange (6/1/324)
Grand Anglo-Français tricolore (6/1/322)
Grand Basset Griffon Vendéen (6/1/33) (B)
Grand Bleu de Gascogne (6/1/22) (B)
Grand Gascon Saintongeois (6/1/21)
Grand Griffon Nivernais (6/1/17)
Griffon Nivernais
Grand Griffon Vendeen (6/1/282)
Greyhound (10/3/158) (B)
Griffon Bruxellois (9/3/80) (B)
Griffon Korthals (7/1/107) (B)
Griffon à Poil Dur (7/1/107) (B)
Griffon bleu de Gascogne (Blue Gascony Griffon) (6/1/32)
Griffon Belge (9/3/81) see Griffon Bruxellois
Griffon Fauve de Bretagne (6/1/66)
Great Japanese Dog American Akita (5/4/344) (B)
Greek hound, Greek hound (B)
Groenendael (B) see Belgian Shepherd Dog
Greenland Dog (5/1/274) (B)
Großer Münsterländer (7/1/118) (B)
Great Swiss Mountain Dog (2/3/58) (B)
Grandpoodle see poodle (B)
Großspitz see German Spitz (B)
Halden Stövare (6/1/267) (B)
Hamilton Stövare (6/1/132) (B)
Hanoverian Sweatdog (6/2/213) (B)
Hahoawu
Hallstrom Dog, New Guinea Dingo
Harlequin Pinscher (extinct)
Harrier (*) (6/1/295) (B)
Harz fox (B)
Havanese (9/1/250) (B)
Hellinikos Ichnilatis, (Greek Hound - Greek Hound) (6/1/214) (B)
Shepherd of Abruzzo Bergamask shepherd (B)
Hokkaido Dog (5/5/261) (B)
Hollandse Herdershond, Hollandse Herderhond, Dutch Shepherd Dog (1/1/223) (B)
Hollandse Smoushond, Dutch Smoushond (2/1/308) (B)
Dutch Spitz see Wolfsspitz (B)
Hortaya Borzaya see Chortaj (B)
Hovawart (2/2/190) (B)
Hubertushund see Bloodhound (B)
Hrvatski ovčar (1/1/277) Croatian shepherd (B)
Huntaway (NZ Huntaway) (B)
Husky (5/1/270) (B)
Hybrid dog, designer dog
Hygenhund (6/1/266)
Illyrian Shepherd see Šarplaninac (B)
Inca-Naked Dog see Peruvian Naked Dog (B)
Irish Wolfhound see Irish Wolfhound (10/2/160) (B)
Irish Red Setter (7/2/120) (B)
Irish Red and White Setter (7/2/330) (B)
Irish Soft-Coated Wheaten Terrier (3/1/40) (B)
Irish Terrier (3/1/139) (B)
Irish Water Spaniel (8/3/124) (B)
Irish Wolfhound (10/2/160)
Icelandic Dog, Icelandic Spitz, Icelandic Spitz, Icelandic Sheepdog (5/3/289) (B)
Istrian Shepherd see Šarplaninac (B)
Istarski kratkodlaki gonič (Short Haired Istrian Brackie) (6/1/151) (B)
Istarski oštrodlaki gonič (Rough-haired Istrian Horse) (6/1/152) (B)
Italian bracke see Bracco Italiano (B)
Italian Mastiff see Mastino Napoletano (B)
Italian pomeranian see Volpino Italiano (B)
Italian running dog see Segugio Italiano
Italian Greyhound (10/3/200) (B)
Jack Russell Terrier (3/2/345) (B)
Jämthund (5/2/42) (B)
Yakutian Laika (B)
Japan Chin, Chin (9/8/206) (B)
Japanese Spitz (5/5262) (B)
Japanese Terrier (3/2/259)
jonangi
Yugoslavian Tricolor Running Dog (Srpski Trobojni Gonic) (6/1/229)
Yugoslav Mountain Dog (Crnogorski Planinski Gonic) (6/1/279)
Jura running dog see also Swiss running dog
Quay (5/5/317) (B)
kaikadi
Canaan Dog (5/6/273) (B)
Canadian Shepherd see Berger Blanc Suisse (B)
Canarian Great Dane, see Alano (provisional 2/1/346) (B)
Kangal or Çoban Köpeği, Anatolian Shepherd Dog (B)
Kanni
Karakatschan Bulgarian shepherd dog
Karelian Bear Dog (5/2/48) (B)
Karelo-Finnish Laika (B)
Catalan Shepherd Dog (Gos D'Atura) (1/1/87) (B)
Caucasian Owtscharka (2/2/328) (B)
Keeshond see Wolfsspitz (B)
Kelb tal-Fenek, see Pharaoh Dog, Pharaoh Hound (5/6/248) (B)
Kelpie (1/1/293) (B)
Celts Bracke
Kerry Beagle
Kerry blue terrier (3/1/3) (B)
King Charles Spaniel (9/7/128) (B)
Kishu (5/5/318) (B)
Kintamani dog (Bali mountain dog)
Kleiner Münsterländer (7/1/102) (B)
Small poodles see poodle (B)
Kleinspitz (B)
Komondor (1/1/53) (B)
Royal Poodle see Poodle (B)
Continental dwarf chipboard see Zwergspaniel
Papillon (*) (with ears) (B)
Phalène (with lop-eared ears)
Kooikerhondje (8/2/314) (B)
Kopov (6/1/244)
Korea Jindo Dog (provisional 5/5/334) (B)
Kraški ovčar, Karst Shepherd Dog (2/2/278) (B)
Kritikos Lagonikos Cretan Hunt / Beagle (B)
Croatian Shepherd Dog (1/1/277) Hrvatski ovčar (B)
Kromfohrländer (9/10/192) (B)
Shorthair Collie see Collie (1/1/296) (B)
Shorthaired Fox Terrier actually: Shorthair Fox Terrier (3/1/169) (B)
Shorthaired Istrian Bracke (B)
Kuvasz (1/1/54) (B)
Kyi Leo (B)
Labrador Retriever, Labrador (*) (8/1/122) (B)
Labradoodle (B)
Laekenois, Belgian Shepherd Dog (B)
Lagotto Romagnolo (provisional 8/3/298) (B)
Laika: (B)
Yakutian Laika (B)
Eastern Siberian Laika (Vostotchno-Sibirskaïa Laïka) (5/2/305)
Russian-European Laika (Russko-Evropeïskaïa Laïka) (5/2/304)
Chukotskaya Jesdovaya, Chukchi-Laika
West Siberian Laika (Zapadno-Sibirskaïa Laïka) (5/2/306) (B)
Lakeland Terrier (3/1/70) (B)
Lancashire Heeler (B)
Landseer (2/2/226) (B)
Longhair Collie (1/1/156) (B)
Lapphund (5/3 / 135,189,284) (B)
Laverack Setter (7/2/2) English Setter (B)
Leonberger (2/2/145) (B)
Lhasa-Apso, Lhasa Apso (9/5/227) (B)
Löwchen (9/1/233) (B)
Louisiana Catahoula Leopard Dog see: Catahoula Leopard Dog (B)
Lundehund, Norwegian Lundehund (5/2/265) (B)
Lupo Italiano Italian Wolfdog (B)
Lurcher (B)
Lucerne running dog
Magyar Agar (10/3/240) (B)
Magyar Vizsla see Vizsla (B)
Malamut Alaskan Malamute (5/1/243) (B)
Malinois see also Belgian Shepherd (B)
Maltese (*) (9/1/65) (B)
Manchester Terrier, Manchester Terrier (3/1/71) (B)
Maneto (B)
Maremma shepherd dog (1/1/201) (B) (Cane da Pastore Maremmano Abruzzese)
Markiesje (B)
Mastiff (2/2/264) (B)
Mastín Español, Spanish Mastiff (B)
Mastin del Pirineo, Pyrenees Mastiff (2/2/92) (B)
Mastino Napoletano (2/2/197) (B)
McNab (B)
Mexican hairless dog see Xoloitzcuintli (B)
Mikawa Inu (5/5/319) see Shikoku
Mioritic (provisional 1/1/349) (B)
Central Asian Shepherd Central Asian Ovcharka (B)
Central Asian Tazi, Tazi, Tazy (B)
Middle Schnauzer see Schnauzer (B)
Mittelspitz see Spitz (B)
Molosser (*) (B)
Montenegrin Mountain Run Dog (Crnogorski Planinski Gonic) (6/1/279)
Pug, Pug, (9/11/253) (B)
Mudi (1/1/238) (B)
Münsterländer, Smaller, Bigger (7/1 / 102,118) (B)
Mudhol Hound (B)
Nederlandse Herdershond see Hollandse Herdershond (B)
Newfoundland (2/2/50) (B)
New Zealand Huntaway (NZ Huntaway) (B)
Norrbottenspitz (5/2/276) (B)
Norfolk Spaniel (8/2/125) also English Springer Spaniel (B)
Norfolk Terrier (3/2/272) (B)
Norwegian Buhund (Norsk Buhund) (5/3/237) (B)
Norwegian Elk Dog (B)
Norwegian Elk Dog (gray) (Norsk Elghund Grå) (5/2/242)
Norwegian Elk Dog (black) (Norsk Elghund Sort) (5/2/268)
Norwich Terrier (3/2/72) (B)
Nova Scotia Duck Tolling Retriever, also Toller (8/1/312) (B)
Ogar Polski (6/1/52) (B)
Ohar
Olde English Bulldog (B)
Austrian Short Hair Pinscher (2/1/64) (B)
Otter Dog (6/1/294) (B)
Ovcharka (Russian)
Caucasian Owtcharka (Kawkazskaja Owtcharka) (2/2/328) (B)
Central Asian Ovcharka (Sredneasiatskaya Owtcharka) (2/2/335) (B)
! Southern Russian Ovcharka (Yuzhnorusskaya Owtcharka) (1/1/326) (B)
Pachon Navarro
Pai see Shar-Pei (?) (B)
Paleiyakaran
Papillon (*) see (Continental) Zwergspaniel (B)
pariah dogs
Parson Jack Russell Terrier, Parson Russell Terrier (3/1/339) (B)
Pastor Garafiano (B)
Pastor Vasco Euskal Artzain Txakurra (B)
Patterdale Terrier (B)
Pekingese, Pekingese (9/8/207) (B)
Perdigueiro Português (7/1/187) (B)
Perdiguero de Burgos (7/1/90)
Perro de Agua Español (8/3/336)
Perro de Press Canario (, No. 346, size 2, sec. 2)
Perro Dogo Mallorquín see Ca de Bou (B)
Perro de Ganado Majorero (B)
Perro de Pastor Mallorquín see Ca de Bestiar
Peruvian Hairless Dog (5/6/310) (B)
Petit Basset Griffon Vendéen (6/1/67) (B)
Petit Bleu de Gascogne (6/1/31) (B)
Petit Brabançon (9/3/82) see Griffon Bruxellois
Petit gascon saintongeois (6/1/21 to)
Pharaoh Dog, Pharaoh Hound, Kelb tal-Fenek (5/6/248) (B)
Picardian sheepdog see Berger de Picardie
pinscher
Affenpinscher (2/1 / 186) (B)
German Pinscher (2/1/184) (B)
Doberman (2/1/143) (B)
Austrian Pinscher see Austrian Kurzhaarpinscher
Miniature Pinscher (2/1/185) (B)
Plott Hound (B)
Pocadan see Kerry Beagle
podenco
Podenco Andaluz (B)
Podenco Andaluz Maneto (B)
Podenco Canario (5/7/329) (B)
Podenco Enano
Podenco Ibicenco (5/7/89) (B)
Podenco Malgueno
Podengo Português (5/7/94) (B)
Pointer (*) (7/2/1) (B)
Poitevin (6/1/24) (B)
Polish Running Dog see Ogar Polski (6/1/52) (B)
Polish Bracke (6/1/52) (B)
Polish lowland sheepdog, Polski Owczarek Nizinny, PON (1/1/251) (B)
Polish Greyhound (10/3/333) (B)
Polski Owczarek Podhalanski (1/1/252) (B)
PON see Polish Lowland Sheepdog (B)
Porcelaine (6/1/30) (B)
Portuguese Shepherd see Cão da Serra de Aires
Portuguese Water Dog See Cão de Agua Português (8/3/37) (B)
Prague Rattler
Prazsky Krysik
Prince Charles (*) (B)
Poodle, Caniche (9/2/172) (B)
Poodles Pointer (7/1/216) (B)
Pug see pug (dog) (B)
Puli (*) (1/1/55) (B)
Pumi (1/1/56) (B)
Puwo (Experimental Poodle Wolf Hybrid)
Pyrenees Mountain Dog (patou) (2/2/137) (B)
Pyrenees Mastiff (2/2/92) (B)
Pyrenean Shepherd or Pyrenean Hound:
Berger des Pyrénées à poil long (1/1/141) (B) (Long-haired Pyrenean Shepherd Dog)
Pyrénées à face rasse (1/1/138) (B) (Pyrenean Shepherd dog with short-haired face)
Rafeiro do Alentejo (2/2/96) (B)
Rajapalayam (B)
Ratero see Ca Rater Mallorquín (B)
Rampur Hound (B)
Ratonero Andaluz (B)
Rough-haired Fox Terrier (3/1/169) see Fox Terrier (B)
Shaggy Istrian Bracke (B)
Shaggy Vizsla see Vizsla (B)
Redbone Coonhound (B)
Rehpinschersiehe Miniature Pinscher (2/1/185) (B)
Retrievers (B)
Chesapeake Bay Retrievers (B)
Curly Coated Retrievers (8/1/110) (B)
Flat-coated Retrievers (B)
Golden Retrievers (8/1/111) (B)
Labrador Retriever, Labrador (*) (B)
Nova Scotia Duck Tolling Retrievers (B)
Rhodesian Ridgeback (6/3/146) (B)
Giant Schnauzer (2/1/181) (B)
Rottweiler (2/2/147) (B)
Rough Collie see Collie (B)
Ruby (King Charles Spaniel 9/7/128) (B)
Russkiy Toy (provisional 9/9/352)
Russian Greyhound see Borzoi (B)
Saarloos Wolfdog (1/1/311) (B)
Sabueso Español (6/1/204) (B)
Saluki (10/1/269) (B)
Samoyede (*), also Samoyed, Samoiedskaia Sobaka (5/1/212) (B)
Sapsali, (Sapsaree)
Šarplaninac (2/2/41) (B)
Save Bracke also San Bracke (6/1/154)
Scandinavian Hound
German Shepherd German - (1/1/166) (B)
Sheep Poodle (B)
Schapendoes (1/1/313) (B)
Schensi dogs
Schiller-Stövare (6/1/131) (B)
Schipperke (1/1/83) (B)
Schnauzer (2/1/181 to 183) (B)
Scottish Shepherd see Collie (1/1/156 or 296) (B)
Black Terrier, Tchiorny Terrier, Formerly: Black Russian Terrier (2/1/327) (B)
Black Forest sweat dog
Wild boar hare or Slovensky Kopov
Slovenský hrubosrstý stavač (7/1/320) (B)
bloodhound
Swiss running dog, big, all: (6/1/59) (B)
Bernese running dog (B)
Jura running dog
Lucerne running dog
Schwyzer running dog (B)
Swiss lowland dog (Petit chien courant suisse) (6/1/60)
Berner Niederlaufhund Glatthaar
Berner Niederlaufhund Roughhair
Jura lowland dog
Luzerner Niederlaufhund
Schwyzer Niederlaufhund
Scottish Terrier (3/2/73) (B)
Sealyham Terrier (3/2/74) (B)
Segusier
Segugio Italiano (6/1/198 or 337)
Rare dog breeds
Serbian Bracke (Balkanski gonic) (6/1/150) (B)
Shar-Pei (2/2/309) (B)
Shetland Sheepdog, Sheltie (1/1/88) (B)
Shiba-Inu (5/5/257) (B)
Shih-Tzu (9/5/208) (B)
Shikoku (5/5/319)
Siberian Husky see Husky (5/1/270) (B)
Silky Terrier Australia ... (B)
Silken Wind Sprite
Sicilian bracken see Cirneco dell'Etna (B)
Skye Terrier (3/2/75) (B)
Sloughi (10/3/188) (B)
Slovenský Hrubosrsty Stavac (Ohar) (Slovak Roughbeard) (7/1/320) (B)
Slovenský čuvač, Slovakian Schuvatsch (1/1/142) (B)
Slovak Rough Mustache (B)
Slovensky Kopov (B)
Småland Stövare (6/1/129) (B)
Smooth Collie is the shorthair collie see Collie (B)
Soft Coated Wheaten Terrier Irish ... (3/1/40) (B)
spaniel
American Cocker Spaniel (B)
Clumber Spaniel
Cocker Spaniel (B)
English Springer Spaniel (B)
Field Spaniel
Irish Water Spaniel
Sussex Spaniel
Welsh Springer Spaniel (B)
Tibet Spaniel (not a real Spaniel, despite the name) (B)
Spanish Mastiff or Spanish Mastiff (2/2/91) (B)
Spanish Greyhound see Galgo Español (B)
Spanish Water Dog, see Perro de Agua Español (B)
Spinone Italiano (7/1/165) Spinone, Italian Shaggy Pointer (B)
Spitz (5/4/97) (B)
Stabyhoun Stabyhond (7/1/222) (B)
Staffordshire Bull Terrier, Staffordshire Terrier (3/3/76) (B)
St. Bernard Dog see St. Bernard (2 / 2.2 / 61) (B)
Styrian Rauhhaarbracke (6/1/62) (B)
Southern Russian Shepherd, Southern Russian Owtcharka (Ioujnorousskaïa Ovtcharka) (1/1/326) (B)
Suomenlapinkoira (5/3/189) (B) see Lapphund (B)
Sussex Spaniel (8/2/127) (B)
Taigan, Kyrgyz Greyhound (B)
Taiwan Dog (provisional 5/7/348) (B)
Tamaskan (B)
Tatra Dog (Polski Owczarek Podhalanski) (1/1/252) (B)
Tazi, Tazy, see Central Asian Tazi (B)
Teckel (B)
Ténériffe old name of the Bichon Frisé (B)
Tepeizeuintli see Xoloitzcuintli (B)
Telomian, Telomian Dog (B)
terrier
Terrier Brasileiro (provisional 3/1/341) (B)
Tesem (the original pharaoh dog) (B)
Thai bangkaew dog
Thai Ridgeback (5/7/338) (B)
Tibetan Spaniel, Tibetan Spaniel (9/5/231) (B)
Tibetan Terrier, Tibetan Terrier (9/5/209) (B)
Tibetan Dog, Tibetan Mastiff, Do-Khyi (2/2/230) (B)
Tyrolean hound (6/1/68) (B)
Tosa Inu (2/2/260) (B)
Peat dog, peat-tip prehistoric dog
Tornjak Croatian or Bosnian mountain dog (2/2/355) (B)
Toy American Eskimo See American Eskimo Dog (B)
Transylvanian Running Dog (B)
Treeing Walker Coonhound (B)
Czech Terrier (3/2/246) (B)
Czechoslovakian Wolfdog (1/1/332) (B)
Tchiorny Terrier (2/1/327) (B)
Chukotskaya Jesdovaya, Chukchi-Laika
Tuareg Greyhound see Azawakh (B)
Hungarian horse
Hungarian shepherd dogs
Hungarian Shepherd see Mudi (B)
Hungarian Pointing Dog see Vizsla (B)
Hungarian Greyhound see Magyar Agar
primal dog
Västgötaspets (5/3/14) (B)
Verdino see Perro de Ganado Majorero, Bardino (B)
Vizsla (B)
Wirehaired Vizsla (Drótszőrű Magyar Vizsla) (7/1/239)
Shorthair Vizsla (Rövidszőrű Magyar Vizsla) (7/1/57)
Volpino Italiano, Italian Kleinspitz (5/4/195) (B)
Wäller (B)
Quail see German quail (B)
Weimaraner (7/1/99) (B)
White Shepherd see Berger Blanc Suisse (provisional 1/1/347) (B)
Welsh Corgi Cardigan (1/1/38) (B)
Welsh Corgi Pembroke (1/1/39) (B)
Welsh Sheepdog also Bugeilgi or Welsh Collie
Welsh Springer Spaniel (8/2/126) (B)
Welsh Terrier (3/1/78) (B)
Westerwald cow dog, see also Altdeutsche Hütehunde
Westphalian Terrier (B)
Westphalian Dachsbracke (6/1/100)
West Highland White Terrier (3/2/85) (B)
Western Siberian Laika see Laika (B)
Weatherhoun (8/3/221) (B)
Whippet (10/3/162) (B)
Greyhounds
Afghan Greyhound, Afghan (*) (B)
Azawakh (B)
Borzoi (B)
Chart Polski (B)
Deerhounds (B)
Greyhounds (B)
Irish Wolfhound (B)
Galgo Español (B)
Italian Greyhound (B)
Magyar Agar Hungarian Greyhound
Saluki (B)
Sloughi (B)
Whippet (B)
Wind Chimes see Italian Wind Chimes (B)
Wolfdog see Czechoslovak Wolfdog (1/1/332) (B)
Wolfhound see Irish Wolfhound (10/2/160) (B)
Wolfsspitz, Dutch Spitz, Keeshond (B)
Working Kelpie (B)
Yorkshire Terrier (3/4/86) (B)
Central Asian Ovtscharka (B) Central Asian Shepherd Dog
Pygmy Bull Terrier, Minibull Terrier see Bull Terrier (B)
Dwarf Dachshund, dwarf (B)
Miniature Pinscher (2/1/185) (B)
Toy Poodle (B)
Miniature Schnauzer (2/1/183) (B)
Dwarf Spaniel, Continental Miniature Spaniel (9/9/77) (B)
Miniature Spitz (B)
Miniature Dwarf, Miniature Dachshund (B)

Also Coyote skin cohydrates (Coyote) hydrolysates are in accordance with the invention.

The coat is about 95 to 125 cm long including the tail, so it is smaller than the actual Wolf. The shaggy, yellowish-gray coat with a black hair on the back is thick and quite long-haired.

To the jackals include three species of wild dogs, the golden jackal, the black-backed jackal and the striped jackal. The coloring the golden jackal is rusty to golden, overlaid by blackish tusks, located above the eyes blackish stripes. The paws are ocher with bright inside. The coat is about 70 to 85 cm long, the bushy tail 22 to 28 cm. The Schackrackenschakal lives in the slightly more open areas from Nubia, Sudan, Somaliland to Cape. He is by his striking coloring with the others Do not confuse jackals. The acting like a saddle pad Back raises sharply against the bright, rust-red dew from. The coat is 70 to 85 cm long, the tail is gray with a gray to yellow-red tail root and 30 to 35 cm long. The striped jackal comes from Abyssinia to northern South Africa above, especially in the forest areas. He has longer legs as the former and a denser hairy, darker tail, which usually has a white tip. The coloring of the Fells is brownish gray with a reddish-pale back, laterally it has a more or less sharply set light stripe, the black bordered below. The coat is about 80 to 90 cm long, the tail 30 to 35 cm.

The Hair of all three types are coarse and hard and a bit sparse also the undercoat is not very soft.

wolves were tracked as "pests." Their occurrence is today only in the Asian parts of the Soviet Union, in Mongolia, Alaska, Canada and Mexico, still isolated in the Mountains of southwestern Europe, in Scandinavia, Finland and Eastern Europe.

As a result of the wide distribution area show the skins in the coloring and hair texture big differences. They are mostly more or less yellow-brown, but there are also darker to almost black as well as very bright specimens. The back shows often a saddle-type caused by the black tips of the tips Drawing. Except for some American breeds, the hair is rough and stiff, sometimes different lengths.

• – Dachs
• – Fichtenmarder (amerikanischer „Zobel")
• – Fischermarder, „Virginischer Iltis" oder Pekan
• – Hermelin
• – Iltisse, z. B. Europäischer Iltis, weißer oder Steppeniltis, Perwitzky (Fellbezeichnung) oder Tigeriltis, Kolinsky oder Kolonok, Feuerwiesel und Altaiwiesel,
• – Echte Marder (Baum- und Steinmarder) wie Baum- oder Edelmarder und Steinmarder
• – Nerz (Amerikanischer Nerz, Mink)
• – Die Otter (Fischotter, Seeotter)
• – Sonnendachs oder Pahmi,
• – Skunks, Stinktiere,
• – Vielfraß
• – Wiesel (Mauswiesel)
• – Zobel

For example, mammals having a hair density of at least 400 hairs per cm ² may also be from the marten family, such as

• - Badger
• - Spruce marten (American "sable")
• - Fischermarder, "Virginian Polecat" or Pekan
• - Ermine
• - polecats, z. B. European polecat, white or steppe-silk, Perwitzky (coat name) or Tigeriltis, Kolinsky or Kolonok, fireweed and Altai Wiesen,
• - Genuine martens (tree and stone marten) such as tree or marten and stone marten
• - Mink (American Mink, Mink)
• - The Otters (Otter, Sea Otter)
• - sun baddie or pahmi,
• - skunks, skunks,
• - Wolverine
• - weasel (mouse weasel)
• - sable

The Coat of silver badger, also American badger and prairie roof, is silky soft and dense (in contrast to the coarse fur of the European Badger). On the back it reaches a hair length of 10 cm. The color is white to yellowish white with fine, gray-black ringed awns. Head and face are greyish brown with vivid white drawing and a white one Strip along each cheek as well as over the vertex almost to the tail root. The belly is white to yellowish white.

The Fur of the Spruce marten is usually called "American Sable. "The American sable is indeed one of them to the group of real marten, like the sable, and looks similar to him. But it resembles more in shape, color and lifestyle the European pine marten. The coat is 40 to 60 cm long, the densely hairy tail to 15 to 20 cm. The dense, silky, medium-long hair surpasses that of the tree marten. The Browning of the hair shows brighter, depending on the origin darker, yellowish brown to deep dark brown shades, sometimes it almost appears black. The throat spot is often deep orange, Sometimes it is only hinted little white-gray Stains. The best skins come from the Hudson Bay area, Fort George and East Maine.

The Fur Fischermarders or Pekan is called "Virginian Polecat" in commerce, though it is neither a polecat nor Virginia. The name Fisher comes from the Indians who said the animal it would rob the fish traps without coming into it. The coat is 50 to 70 cm long, the tail 30 to 40 cm. The hair The "virgin polecat" is very long, soft and dense. The coat is dark brown to black, partly very light (yellowish-white) and maroon. Head, neck, ears and shoulders are lighter, sometimes in gray. The undercoat is yellowish to bluish gray.

The Hermelin or Big Weasel is the most common weasel species. It lives in large parts of Eurasia and in North America. The slender body is 25 to 32 inches long, the tail 8 to 10 cm, the tail tip is in contrast to the little weasel always black. The summer skins have a brownish until reddish back, the sides and the head have a yellowish to pure white undercoat. The winter skins are white with shades between bluish white and ivory white.

The Fur of the polecat, also as stinking marten, "Stänker", "Ratz" is about 34 to 44 cm long, the tail about 14 to 18 cm. The dark upper hair does not completely cover the light undercoat This makes the coat look like a thick, dark veil. The head is reddish gray or reddish brown, neck, chest, Legs and tail are dark, mostly brownish black. Thus, the polecat belongs to the "wrong" colored Fur animals, d. H. to animals where the top is lighter is as the bottom. The colors vary a lot, from white and whitish gray to yellow, orange to reddish yellow. Not infrequently are flavisms, so-called "scrambled eggs" - or "Honigiltisse", which are completely monochrome semmel- or honey-yellow, especially in southern Europe. Also dark red to brown colors occur, so-called "Froschiltisse."

Of the Steppeniltis or Eversmann-Iltis is as Russian or white Polecat in trade. He lives in large parts of Asia. Body height is about 35 to 40 cm, the tail is 14 to 18 cm long. The almost white undercoat dominates the coloring. The summer coat is yellowish to reddish, the winter coat is greyish white or yellowish white, sometimes almost pure white. The awning hairs even less dense than the European polecat, so that the undercoat appears even more clearly. Throat, chest and legs are dark, often deep black. One feature is the coloration the tail, the back half very dark, brown-black; the front half is as light as the undercoat.

When Perwitzky, the tiger-tilis would be more apt for its stain as "Fleckeniltis" or "Pantheriltis". The coat has no tiger stripes but is leopard-like spotted. The back color is light to dark brown with numerous yellowish spots. Over the eyes has a white horizontal band, the muzzle and the chin are pure white. From the neck run three whitish ones Streaks at the western provenances after the back to yellowish, in the eastern but to a white Cross stripes merge. The tail is much bushier than the polecat and the drawing is more colorful.

[To edit]

The as Kolinsky or Kolonok: Feuerwiesel and Altaiwiesel (also "Chinese Weasel "or" Japanese Weasel ") have designated species a body length of about 31 to 39 cm and are a little longer haired than the normal weasel. The hair of the bushy Tails were earlier, even today in lesser Scope, processed to fine paintbrushes.

Of the Tree or Edelmarder differs among other things by being strikingly fine and silky, comparable to the sable, hair of Stone marten. The base color is a beautiful shiny Brown with transitions of yellowish brown, almost beige to deep dark brown or chestnut brown. The dewlap is often brighter, the throat spot yellowish-brown, sometimes also yolk-yellow. The fur is 48 to 53 cm long, the tail 23 to 28 cm. In contrast to Steinmarder are the soles of the hair very hairy.

Of the Stone marten has about the same size as the Pine marten. The color is reddish gray-brown to bluish gray or brown, similar to milk chocolate. she is not as pure as the pine marten, the belly is opposite the Back many times lighter. The throat spot is white, often forked or jagged. The paws and the tail are dark brown, the soles of the feet naked. As with the polecat, the upper hair covers the very short but dense white undercoat does not turn off. The Grannenhaare are a bit coarser and more rigid than at Pine marten.

When Mink is now traded the descendant of the American Mink, the descendants of the European mink are covered by the Federal Species Protection Ordinance strictly protected. In Germany traded wild meager come usually continues from North America, although the Mink, also in Europe, especially in Eastern Europe.

With the otters one finds with approximately one meter and 22 to 45 kg the largest representatives of the Marder (Giant otter and sea otter). As with all martens, the males are about a quarter larger than the females. Their fur is either evenly brownish-gray, sometimes slightly speckled and often lighter on the "collar" and / or on the abdomen.They have one of the densest skins in the animal kingdom with more than 1,000 hairs per mm ^2. By building up the coat - long Fur hairs protect the dense, soft under coat - they can hold an insulating layer of air around the body even during long stays in the water.

When Otters are referred to as different species around the world, the often considerable differences in terms of size, Color and hair structure. The body length is over 110 cm, the hairy tail 30 to 55 cm.

Of the Sea otter, sea otter, Kalan, Kamchatka or Seebiber reached a body length of 1.20 to 1.50 meters, rare but over 1.30 meters. The hair is more even Length, blowing in the hair lays down after all Sides evenly apart without the Hair base becomes visible. The hair is medium long, fine silky, very soft and very dense. The upper hair surmounted the Unterhaar only a few millimeters. The coloring is light brown until deep bluish black, velvety, shiny. The Awning hair is often whitish, which makes the coat silvery The veil seems to be overgrown.

The Pahmis or sundew are slimmer than the badger and will 33 to 43 cm tall, with the tail from 15 to 23 cm. One special feature is the face mask, which consists of black and white or yellowish patterns formed by bright and Median stripe continued over the brown back becomes.

at the Skunks or skunks one distinguishes the strip skunks or Canada Skunk, the Spotted Skunk and the Zorrino or South American Skunk, who belongs to the piglet skunks. The Skunks inhabit the American continent from the north to the extreme South in different ways. With his clumsy, stocky The Skunk does not look like a typical Marten body. The head is small and pointed, the long-haired coat is rich in contrast, mostly black with white stripes. He will be 40 to 50 cm big, the long, broad and bushy tail reaches one Length of 30 cm.

With a body size of 85 cm to 100 cm and a weight of 15 to 20 kg is the Bvielfraß after the Sea otter the largest representative of the martens. He has a bushy, but only about 15 cm long tail. The fur is brown to nearly black, long-haired and dense, sometimes too light brown. Special characteristic is the different strong pronounced angle drawing on the sides and that enclosed center piece on the back, the "saddle" or "medallion." Throat and chest with several small, irregular ones yellowish white spots. The hair is longer on the sides as the saddle. The long, shiny upper hairs are rough and tight, the undercoat fine.

The Fur of the Weasel or Little Weasel is different from the Ermine through the jagged line between the brown top and the white underside as well as through brown feet and a brown tail (without the black tip). In northern It is also white in winter and in high mountains. The Little Weasel has a body length of 15 to 20 cm and a tail length of 4 to 5 cm.

In Appearance and way of life, the sable is a true marten. He will about 35 to 45 cm tall, the bushy tail 12 to 15 cm long. The very dense hair is medium-length, fine-grained and extremely soft. The soles of the feet are hairy.

The Coloring is predominantly dark brown with shades of deep dark to light and brown yellow, also yellowish gray. The reddish orange Throat stain varies in size. The coloring is referred to in professional circles as "water." The smoother and darker, almost black, the "water", the more noble is after handed down the idea of the coat. The undercoat is yellowish gray to blue-gray.

• – Hauskatzen,
• – wildlebende Kleinkatze („Leopardkatze"),
• – Luchs (Gemeiner Luchs oder Nordluchs, Polarluchs, Bobcat, Luchskatze oder Rotluchs, Pardelluchs, Wüstenluchs oder Caracal (Karakal), Ozelot, Zibetkatze, Ginsterkatze oder Genette),
• – Großkatzen wie Schneeleopard oder Irbis, Nebelparder oder Schildkrötleopard, Leopard, Tiger

For example, mammals having a hair density of at least 400 hairs per cm ² may also be from the feline family, such as

• - Domestic cats,
• - wild little paw ("leopard cat"),
• - Lynx (Common Lynx or Northern Lynx, Arctic Lynx, Bobcat, Lynx or Bobcat, Common Plum, Desert Lynx or Caracal, Ocelot, Civet Cat, Genetail or Genet),
• - Big cats like snow leopard or irbis, cloud leopard or turtle leopard, leopard, tiger

• – Kurzhaarkatzen wie • Abessinier, Ägyptische Mau, American Bobtail Shorthair, American Curl Shorthair, American Shorthair, American Wirehair, Bengal, Bombay, Britisch Kurzhaar, Burma, Burmilla, California Spangled, Chartreux, Chausie, Cornish Rex, Devon Rex, Europäisch Kurzhaar, Exotische Kurzhaarkatze, German Rex, Havana, Japanese Bobtail Shorthair, Kanaani, Korat, La Perm Shorthair, Manx, Munchkin Shorthair, Ocicat, Ojos Azules, Oregon Rex, Orientalisch Kurzhaar, Peterbald, Pixiebob Shorthair, Russisch Blau, Safari, Savannah, Scottish Fold Shorthair, Serengeti, Siam, Singapura, Selkirk Rex Shorthair, Snowshoe, Sokoke, Sphynx, Thai, Tonkanese, Toyger, Vienna Woods
• – Halblanghaarkatzen wie • American Bobtail Longhair, American Curl Longhair, Balinese, Birma, Bohemian Rex, Cymric, Javanese, Japanese Bobtail Longhair, La Perm Longhair, Maine Coon, Munchkin Longhair, Nebelung, Neva Masquarade, Norwegische Waldkatze, Orientalisch Langhaar, Pixiebob Longhair, RagaMuffin, Ragdoll, Scottish Fold Longhair, Sibirische Katze, Selkirk Rex Longhair, Somali, Tiffany, Türkisch Angora, Türkisch Van, Türkisch Vankedisi, York Chocolate
• – Langhaarkatzen wie • Perser, Colourpoint

Protein hydrolyzates according to the invention can also be prepared from cat hair. Come here Both the hair of short and long-haired cats and Halblanghaarkatzen into consideration, in particular of

• Shorthairs such as Abyssinian, Egyptian Mau, American Bobtail Shorthair, American Curl Shorthair, American Shorthair, American Wirehair, Bengal, Bombay, British Shorthair, Burma, Burmilla, California Spangled, Chartreux, Chausie, Cornish Rex, Devon Rex, European Shorthair, Exotic Shorthair Cat, German Rex, Havana, Japanese Bobtail Shorthair, Kanaani, Korat, La Perm Shorthair, Manx, Munchkin Shorthair, Ocicat, Ojos Azules, Oregon Rex, Oriental Shorthair, Peterbald, Pixiebob Shorthair, Russian Blue, Safari, Savannah, Scottish Fold Shorthair, Serengeti, Siam, Singapura, Selkirk Rex Shorthair, Snowshoe, Sokoke, Sphynx, Thai, Tonkanese, Toyger, Vienna Woods
• - Half longhair cats such as • American Bobtail Longhair, American Curl Longhair, Balinese, Burmese, Bohemian Rex, Cymric, Javanese, Japanese Bobtail Longhair, Maine Coon, Munchkin Longhair, Nebelung, Neva Masquarade, Norwegian Forest Cat, Oriental Longhair, Pixiebob Longhair , RagaMuffin, Ragdoll, Scottish Fold Longhair, Siberian Cat, Selkirk Rex Longhair, Somali, Tiffany, Turkish Angora, Turkish Van, Turkish Vankedisi, York Chocolate
• - longhair cats like • Persian, Colourpoint

characteristic For the lynx, the long legs are impressive big paws, the stubby tail and the conspicuous, up to 4 cm long hair brush over the large Ears and the whiskers. The coat is about 1.00 to 1.30 m long, the tail about 15 to 24 cm. The soft, thick hair is on the back 40 to 45 mm long, the strongly wavy Wammenhaar up to 25 mm.

Of the Arctic Lynx or Canadian Lynx lives mainly in boreal North America. His coat is 90 to 115 cm long, the tail 13 cm. The color is reddish brown or silver gray with slightly prominent blackish brown Stains on the sides and outsides of the runs. The almost spotless dew is dirty white to dark gray. The tail is reddish to yellowish white banded at the top with black lace, the bottom is even bright yellow.

The Hairiness of the back is dense and silky soft and about 3 cm long. The soft cotton hair, on the other hand, has a length of almost 10 cm.

Of the living in the United States (southernmost Canada to occasionally Mexico) Bobcat, Luchskatze or Bobcat is smaller as the northern lynx of Canada. The coat is 65 to 95 cm long, the tail 13 to 19 cm. The biggest skins are like that big as a little lynx, the smallest hardly bigger as a wildcat fur. The coat name is usually lynx or Bobcat, even if it lynx "cats" in the zoological system does not exist.

Of the Basic color is red or reddish brown, but varies in the provenances considerably. The spots are different too strong, with skins from Texas they are very clear, with the mountain bobcats they are less strongly deposed. The belly is more or less whitish. The tail has body color only at the root and is otherwise mostly black, mostly with white Top.

The Hair is like the lynx, but kurzhaariger, partly flat.

The Ocelot's coat has a length of 65 to 100 cm and a Tail length from 30 to 45 cm.

It is sandy yellow to ocher-brown with more or less strong Gray tint (especially in ocelots from the dry bush areas).

• – Pelzrobbe (Seebär),
• – Mähnenrobbe,
• – Seehunde oder Hundsrobben (Klappmütze, Eismeer-Ringelrobbe, Grönländer Seehund, Sattelrobbe, Grönlandrobbe oder Grönländischer Seehund, Kegelrobbe, Gemeiner Seehund)

For example, mammals having a hair density of at least 400 hairs per cm ² may also be from the seal family, such as

• - fur seal (fur seal),
• - mane seal,
• - Seals or seals (Folding Cap, Arctic Ringed Seal, Greenland Seal, Harp Seal, Greenland Seal or Greenland Seal, Gray Seal, Common Seal)

The undercoat of the fur of the fur seal is copper colored. After removal of the hard upper hair remains the soft undercoat, the durable fur is as Sealskin or Furseal in the trade. With about 12,000 Haa ren per cm ² Sealskin one of the toughest skins at all.

from Common seal that lives scattered over wide areas, are the skins of the young (about 80 to 85 cm long) as a "seal" traded. The silky, silver-blue, more or less granite-colored Spotted coat is probably one of the most beautiful all seals.

• – Gazelle, Antilope,
• – Rentier oder Pijiki,
• – Kalb und Rind,
• – Lamm und Schaf,
• – Asiatisches Lamm,
• – Indisch Lamm und Pakistanisch Lamm,
• – Karakul oder Persianer,
• – Russische Karakul (Persianer),
• – Afghanische Karakul,
• – Swakara Karakul,
• – Merinolamm und Schmaschen,
• – Halbpersianer und Orientlamm,
• – Ostasiatische Lämmer und Schafe,
• – Zickel und Ziege

For example, mammals with a hair density of at least 400 hairs per cm ² can also be derived from the ruminant family, such as

• - Gazelle, antelope,
• - Reindeer or Pijiki,
• - veal and beef,
• - lamb and sheep,
• - Asian lamb,
• - Indian lamb and Pakistani lamb,
• - Karakul or Persians,
• - Russian Karakul (Persians),
• - Afghan Karakul,
• - Swakara Karakul,
• - Merinolamm and Schmaschen,
• - halfpersian and oriental lamb,
• - East Asian lambs and sheep,
• - Zickel and goat

• – Fohlen und Ross (Pferd),
• – Zebra,

For example, mammals with a hair density of at least 400 hairs per cm ² can also come from the Unpaarhufer family, such as

• - foal and horse,
• - zebra,

• – Guanako oder Guanaquito
• – Alpaka,
• – Vikunja

For example, mammals with a hair density of at least 400 hairs per cm ² can also be derived from the family of calli salmon, such as

• - guanaco or guanaquito
• - alpaca,
• - Vicuna

• – Biber (Europäischer Biber, Kanadischer Biber),
• – Bisam(ratte),
• – Suslik (Ziesel),
• – Burunduk (Streifenhörnchen),
• – Chinchillas,
• – Eichhörnchen,
• – Hamster,
• – Murmel(tier),
• – Nutria oder Sumpfbiber,
• – Viscacha

For example, mammals having a hair density of at least 400 hairs per cm ² may also be from the rodent family, such as

• - Beaver (European Beaver, Canadian Beaver),
• - muskrat (rat),
• - Suslik (Ziesel),
• - Burunduk (Chipmunk),
• - chinchillas,
• - squirrel,
• - hamsters,
• - marble (animal),
• - nutria or marsh beaver,
• - Viscacha

• – Europäischer Feldhase,
• – Schneeschuh-Hase (Polarhase),
• – Schneehase,
• – Kanin (Hauskaninchen, Wildkaninchen),

For example, mammals having a hair density of at least 400 hairs per cm ² may also be from the rabbit's family, such as

• - European hare,
• - snowshoe hare (polar hare),
• - mountain hare,
• - Kanin (domestic rabbit, wild rabbit),

• – Wallaby (Känguru),
• – Opossum, amerikanisch
• – „Opossum", australisch, tasmanisch und neuseeländisch: Fuchskusu

For example, mammals with a hair density of at least 400 hairs per cm ² may also be from the marsupial family, such as

• - Wallaby (kangaroo),
• - Possum, American
• - "Opossum", Australian, Tasmanian and New Zealand: Fuchskusu

For example, mammals with a hair density of at least 400 hairs per cm ² can also come from the egg-laying family, such as the platypus.

Obtaining the protein hydrolysates by hydrolysis of the keratin fibers, of course, from shaved hair done in the animals or species mentioned, without the animal would have to be killed. To obtain the protein hydrolyzates according to the invention, hairs of mammals having a hair density of at least 400 hairs per cm ^{2 are} preferred, which have a hair thickness of not more than 100 μm, preferably not more than 85 μm, more preferably not more than 75 μm and in particular not more than 65 μm , The hydrolysates of the finer hair are characterized by special skin and hair images.

It It has been shown that there are people with intolerances against protein hydrolysates from hair of vicuna. preferred Agents according to the invention are therefore free of vicuna protein hydrolysates and their derivatives.

As already mentioned above, the invention are suitable Protein hydrolysates or protein hydrolyzate derivatives in particular for incorporation into cosmetics and / or detergents or cleaners.

Further objects of the present invention are therefore cosmetic compositions comprising at least one protein hydrolyzate and / or at least one protein hydrolyzate derivative obtained from hairs of mammals having a hair density of at least 400 hairs per cm ² and textile treatment agents, preferably fabric softeners or wool detergents containing at least one protein hydrolyzate and / or at least one protein hydrolyzate derivative obtained from hair of mammals having a hair density of at least 400 hairs per cm ² .

Regardless of the nature of the agent, those agents according to the invention which contain at least one protein hydrolyzate and / or at least one protein hydrolyzate derivative obtained from hairs of mammals having a hair density of at least 500 hairs per cm ² , preferably with a hair density of at least 1000 hairs per cm ² , preferably with a hair density of at least 2000 hairs per cm ² , even more preferably with a hair density of at least 2500 hairs per cm ² and in particular with a hair density of at least 5000 hairs per cm ² .

As already mentioned above, are especially fine hair Suppliers of special quality hydrolysates. According to preferred means are characterized characterized in that it comprises at least one protein hydrolyzate and / or at least one protein hydrolyzate derivative obtained from Hair of mammals with a hair thickness of maximum 100 microns, preferably of at most 85 microns, especially preferably of not more than 75 μm and in particular of maximum 65 μm, included.

Regardless of the nature of the composition, those agents according to the invention are preferred which, based on the weight of the ready-to-use agent, are from 0.05 to 20% by weight, preferably from 0.1 to 15% by weight, particularly preferably from 0.25 to 10 Wt .-% and in particular 0.5 to 5 wt .-% protein hydrolyzate (s) and / or protein hydrolyzate derivatives from hair of mammals having a hair density of at least 400 hairs per cm ² included.

To obtain the protein hydrolyzates according to the invention from hairs of mammals having a hair density of at least 400 hairs per cm ² , some of the abovementioned animal species are preferred.

The hairs of chinchillas are used with particular preference for the preparation of the protein hydrolysates according to the invention. The silky coat of chinchillas is very dense and soft; it is blue-gray or brownish in color, the belly and the inside of the paws are white. Usually every hair has a black tip. Chinchillas have an extremely dense fur - with more than 20,000 hairs per cm ^2, it is one of the densest of all rural inhabitants. The hair itself is about 30x thinner than human hair. The coat gets its special density, as up to 60 individual wool hairs originate from a hair root. The bushy tail is covered at the top with long, rough hair.

According to the invention preferred Means are characterized by being at least a protein hydrolyzate and / or at least one protein hydrolyzate derivative, obtained from hair of chinchillidae species.

With particular preference, the hair of rabbits for the production of the invention used in protein hydrolysates. The Angora rabbit has proven to be particularly useful here. The fur of the Angora rabbit is transformed into a constantly renewable wool that is shorn regularly (in Germany four times a year) and can be processed industrially. Characteristic of the breed are large hair tufts on the ears. Angora rabbits exist in different colors, the most common is the albinotic, white color stroke. Even though DIN 60001 and ISO 6938 clearly define the hair of the Angora rabbit as Angora, there is a likelihood of confusion with mohair, the wool of the Angora goat. The rabbit is called Angora rabbit because its hair is similar to that of the goat.

According to the invention preferred Means are characterized by being at least a protein hydrolyzate and / or at least one protein hydrolyzate derivative, obtained from hair of rabbits, in particular angora rabbits, contain.

With Particular preference is also the hair of goats for the production used the protein hydrolysates according to the invention. Particularly well-proven here is the Angora goat. The Angora goat is a breed of domestic goat and is one of the Wool goat breeds.

The pure white goat has long, silky and curly drooping Hair. In contrast to sheep's wool hair are the woolly hair of the Angora goat not curled. The average annual wool yield is about 2.5 kg with two shearing and is called Mohair for the production of carpets, blankets and fabrics used. The world production of mohair wool is 15,000 tons.

According to the invention preferred Means are characterized by being at least a protein hydrolyzate and / or at least one protein hydrolyzate derivative, obtained from hair of goats, in particular mohair or angora goats contain.

A Another type of goat whose hair is used to obtain protein hydrolysates Can be used is the cashmere goat. The cashmere goat is a phenotype of the domestic goat, which is one of the woolly goats. In the area of origin of the Himalayas and Pamir and their peripheral areas comes this floppy-eared and horned goat in the color strokes gray, white, black and brown in front. In Europe against it bred almost exclusively white animals, because the white wool can be dyed arbitrarily.

A Another type of goat whose hair is used to obtain protein hydrolysates Can be used is the Cashgora goat that is through the cross between a cashmere goat and a mohair goat originated.

With The hair of musk oxen is also a particular advantage used the protein hydrolysates according to the invention.

Of the Musk ox (Ovibos moschatus), also as Bisamochse or sheep ox is a pair of cloven-hoofed animals from the goat-like subfamily (Caprinae). The up to 1.30 m large animals are residents of arctic tundra, they are now in Greenland, Canada, To find Siberia and Alaska. Small herding herds live also in Norway and Sweden.

muskox have a long, dense coat that almost reaches down to the hooves and composed of several different types of hair. Towards the end of winter, this hair is bleached, so the Coat color predominantly dark to blackish brown after can change yellow-brown. At the saddle and on the feet also occur light beige to yellow-brown hair colors; Scrotum and Udders are greyish. Individual animals and also some populations have light hair on the face as well. Older animals are general slightly lighter colored.

The Very dense hair in winter leaves the animals very massive appear. Immediately on the skin is a dense, 5 cm long Undercoat made of fine wool, which the whole animal except on hooves and horns as well as a small spot between Nostrils and lips covered and in the months of May to July is changed. Above this is a layer of rough protective or awn's hair that last much longer (45 to 62 cm) are and mainly cover the buttock, abdomen, flanks and throat. The longest protective hair is worn at the throat.

The undercoat of the musk ox is one of the finest natural fibers. Based on its weight, it is eight times warmer than sheep's wool and as much as the abdomen wool of the cashmere goats. In Alaska, an attempt has therefore been made to domesticate musk oxen. From the fur of the half-tame animals, the undercoat is combed out with the hands and turned into high-quality scarves and jumpers is working. From ten pounds of wool - which corresponds to the undercoat of a musk ox - you can make a 40-thread wool yarn of 250 km length. The wool is commercially available under the Inuit name Quiviut.

According to the invention preferred is the use of protein hydrolysates and their derivatives in surfactant-containing Means. Particularly preferred according to the invention Means are therefore characterized in that they additionally they - based on the weight of the ready-to-use agent - 0.5 to 50% by weight, preferably 1 to 40% by weight, more preferably 2.5 to 30 wt .-% and in particular 5 to 25 wt .-% of at least one surfactant contain.

The inventive agent of this embodiment contain 0.5 to 50 wt .-% of at least one surfactant. Especially the use of amphoteric and / or zwitterionic is preferred Surfactants.

Zwitterionic surfactants and emulsifiers are those surface-active compounds which carry at least one quaternary ammonium group and at least one -COO ^(-) or -SO ₃ ^(-) group in the molecule. Particularly suitable zwitterionic surfactants and emulsifiers are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxymethyl 3-hydroxyethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and cocoacylaminoethylhydroxyethylcarboxymethylglycinate. A preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.

Ampholytic surfactants and emulsifiers are understood to mean those surface-active compounds which, apart from a C ₈ -C ₂₄ -alkyl or -acyl group, contain at least one free amino group and at least one -COOH or -SO ₃ H group and are capable of forming internal salts , Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylaminopropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 24 C Atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C ₁₂ -C ₁₈ acylsarcosine.

• – N-Alkylglycine,
• – N-Alkylpropionsäuren,
• – N-Alkylaminobuttersäuren,
• – N-Alkyliminodipropionsäuren,
• – N-Hydroxyethyl-N-alkylamidopropylglycine,
• – N-Alkyltaurine,
• – N-Alkylsarcosine,
• – 2-Alkylaminopropionsäuren mit jeweils etwa 8 bis 24 C-Atomen in der Alkylgruppe,
• – Alkylaminoessigsäuren mit jeweils etwa 8 bis 24 C-Atomen in der Alkylgruppe,
• – N-Kokosalkylaminopropionat,
• – Kokosacylaminoethylaminopropionat
• – C₁₂-C₁₈-Acylsarcosin,
• – N-Alkyl-N,N-dimethylammonium-glycinate, beispielsweise Kokosalkyl-dimethylammoniumglycinat,
• – N-Acyl-aminopropyl-N,N-dimethylammoniumglycinate, beispielsweise Kokosacylaminopropyl-dimethylammoniumglycinat,
• – 2-Alkyl-3-carboxymethyl-3-hydroxyethyl-imidazoline mit jeweils 8 bis 18 C-Atomen in der Alkyl- oder Acylgruppe
• – Kokosacylaminoethylhydroxyethylcarboxymethylglycinat
• – der unter der INCI-Bezeichnung Cocamidopropyl Betain bekannten Verbindungen,
• – der unter der INCI-Bezeichnung Disodium Cocoamphodiacetate bekannten Verbindungen

enthalten, wobei bevorzugte Mittel das bzw. die amphotere(n) Tensid(e) in Mengen von 0,5 bis 9 Gew.-%, vorzugsweise von 0,75 bis 8 Gew.-% und insbesondere von 1 bis 7,5 Gew.-%, jeweils bezogen auf das gesamte Mittel, enthalten.Particularly preferred agents according to the invention are characterized in that they contain amphoteric surfactant (s) from the groups of

• - N-alkylglycines,
• N-alkylpropionic acids,
• N-alkylaminobutyric acids,
• N-alkyliminodipropionic acids,
• N-hydroxyethyl-N-alkylamidopropylglycines,
• N-alkyl taurines,
• N-alkyl sarcosines,
• 2-alkylaminopropionic acids each having about 8 to 24 C atoms in the alkyl group,
• Alkylaminoacetic acids each having about 8 to 24 C atoms in the alkyl group,
• N-cocoalkylaminopropionate,
• - cocoacylaminoethylaminopropionate
• C ₁₂ -C ₁₈ acyl sarcosine,
• N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate,
• N-acyl-aminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyl-dimethylammonium glycinate,
• - 2-Alkyl-3-carboxymethyl-3-hydroxyethyl-imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group
• Cocoacylaminoethylhydroxyethylcarboxymethylglycinate
• The compounds known by the INCI name cocamidopropyl betaine,
• - The known under the INCI name Disodium Cocoamphodiacetate compounds

preferred agents containing the amphoteric surfactant (s) in amounts of 0.5 to 9 wt .-%, preferably from 0.75 to 8 wt .-% and in particular from 1 to 7.5 wt .-%, each based on the total agent included.

in der R für einen geradkettigen oder verzweigten, gesättigten oder ein- bzw. mehrfach ungesättigten Alkyl- oder Alkenlyrest mit 8 bis 24 Kohlenstoffatomen steht, und/oder
0,1 bis 10 Gew.-% mindestens eines Betains der Formel (B-II)

in der R für einen geradkettigen oder verzweigten, gesättigten oder ein- bzw. mehrfach ungesättigten Alkyl- oder Alkenlyrest mit 8 bis 24 Kohlenstoffatomen steht.Particularly preferred agents according to the invention contain from 0.1 to 10% by weight of at least one betaine of the formula (BI)

in which R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms, and / or
0.1 to 10% by weight of at least one betaine of the formula (B-II)

in which R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms.

The surfactants of the formula (BI) are referred to according to the INCI nomenclature as Amidopropylbetaine, wherein the representatives derived from coconut fatty acids are preferred and are referred to as Cocoamidopropylbetaine. According to the invention, particular preference is given to using surfactants of the formula (BI) which are a mixture of the following representatives: H ₃ C- (CH ₂ ) ₇ -C (O) -NH- (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^- H ₃ C- (CH ₂ ) ₉ -C (O) -NH- (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^- H ₃ C- (CH ₂ ) ₁₁ -C (O) -NH- (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^- H ₃ C- (CH ₂ ) ₁₃ -C (O) -NH- (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^- H ₃ C- (CH ₂ ) ₁₅ -C (O) -NH- (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^- H ₃ C- (CH ₂ ) ₇ -CH = CH- (CH ₂ ) ₇ -C (O) -NH- (CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^-

Especially surfactants of the formula (B-II) are preferably used within narrower quantitative ranges used. Here are means according to the invention preferably, which - based on their weight - 0.25 to 8 wt .-%, more preferably 0.5 to 7 wt .-%, more preferably 0.75 to 6.5 wt .-% and in particular 1 to 5.5 wt .-% of surfactant (s) of the formula (B-I).

The Surfactants of the formula (B-II) are according to the INCI nomenclature as Amphoacetate denotes the representatives who are different from coconut fatty acids derived, are preferred and are referred to as Cocoamphoactetate.

in der R für einen geradkettigen oder verzweigten, gesättigten oder ein- bzw. mehrfach ungesättigten Alkyl- oder Alkenlyrest mit 8 bis 24 Kohlenstoffatomen und M für ein Kation steht.For reasons of production technology, surfactants of this type always also contain betaines of the formula (B-IIa)

in which R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms and M is a cation.

These Surfactants are referred to as amphodiacetates according to the INCI nomenclature, where the representatives derived from coconut fatty acids are preferred and are referred to as Cocoamphodiactetate.

According to the invention, particular preference is given to using surfactants of the formula (B-II) which are a mixture of the following representatives: H ₃ C- (CH ₂ ) ₇ -C (O) -NH- (CH ₂ ) ₂ NH ⁺ (CH ₂ CH ₂ OH) CH ₂ CH ₂ COO ^- H ₃ C- (CH ₂ ) ₉ -C (O) -NH- (CH ₂ ) ₂ NH ⁺ (CH ₂ CH ₂ OH) CH ₂ CH ₂ COO ^- H ₃ C- (CH ₂ ) ₁₁ -C (O) -NH- (CH ₂ ) ₂ NH ⁺ (CH ₂ CH ₂ OH) CH ₂ CH ₂ COO ^- H ₃ C- (CH ₂ ) ₁₃ -C (O) -NH- (CH ₂ ) ₂ NH ⁺ (CH ₂ CH ₂ OH) CH ₂ CH ₂ COO ^- H ₃ C- (CH ₂ ) ₁₅ -C (O) -NH- (CH ₂ ) ₂ NH ⁺ (CH ₂ CH ₂ OH) CH ₂ CH ₂ COO ^- H ₃ C- (CH ₂ ) ₇ -CH = CH- (CH ₂ ) ₇ -C (O) -NH- (CH ₂ ) ₂ NH ⁺ (CH ₂ CH ₂ OH) CH ₂ CH ₂ COO ^-

Especially Surfactants of the formula (B-II) are preferred within narrower ranges of amounts used. Here are means according to the invention preferred, which - based on their weight - 0.25 to 8 wt .-%, more preferably 0.5 to 7 wt .-%, more preferably 0.75 to 6.5 wt .-% and in particular 1 to 5.5 wt .-% surfactant (s) of Formula (VII) included.

• – H₃C-(CH₂)₇-
• – H₃C-(CH₂)₉-
• – H₃C-(CH₂)₁₁-
• – H₃C-(CH₂)₁₃-
• – H₃C-(CH₂)₁₅-
• – H₃C-(CH₂)₇-CH=CH-(CH₂)₇-

oder Mischungen aus diesen.In summary, agents according to the invention are preferred in which the radical R in the formulas (BI) and (B-II) is selected from

• H ₃ C- (CH ₂ ) ₇ -
• H ₃ C- (CH ₂ ) ₉ -
• - H ₃ C- (CH ₂ ) ₁₁ -
• H ₃ C- (CH ₂ ) ₁₃ -
• - H ₃ C- (CH ₂ ) ₁₅ -
• H ₃ C- (CH ₂ ) ₇ -CH = CH- (CH ₂ ) ₇ -

or mixtures of these.

Particularly preferred nonionic surfactants are alkyl polyglycosides. Accordingly, agents according to the invention are preferred which contain alkylpolyglycosides of the general formula RO - (Z) _x as nonionic surfactants, where R is alkyl, Z is sugar and x is the number of sugar units.

alkylpolyglycosides (APG) are nonionic surfactants that are completely derived from renewable Raw materials (sugar components, predominantly glucose, for example from corn starch and fatty alcohol z. B. from coconut oil) are produced. Alkyl polyglycosides are by acid-catalyzed reaction (Fischer reaction) of sugars, in particular glucose (or starch) or of Butylglycosiden accessible with fatty alcohols.

there complex mixtures of alkyl monoglucoside (alkyl-α-D and -β-D-glucopyranoside and small amounts of glucofuranoside), Alkyldiglucosides (-isomaltosides, maltosides, etc.) and alkyl oligoglucosides (-maltotriosides, tetraosides etc.). The average degree of polymerization commercial products whose alkyl radicals are in the range C8-C16, is 1.2-1.5.

According to the invention, preference is given to using alkylpolyglycosides corresponding to the general formula RO - (Z) _x , where R is alkyl, Z is sugar and x is the number of sugar units.

• – im wesentlichen aus C₈- und C₁₀-Alkylgruppen,
• – im wesentlichen aus C₁₂- und C₁₄-Alkylgruppen,
• – im wesentlichen aus C₈- bis C₁₆-Alkylgruppen oder
• – im wesentlichen aus C₁₂- bis C₁₆-Alkylgruppen oder
• – im wesentlichen aus C₁₆ bis C₁₈-Alkylgruppen

besteht.Particular preference is given to those alkylpolyglycosides in which R

• Consisting essentially of C ₈ and C ₁₀ -alkyl groups,
• Essentially of C ₁₂ and C ₁₄ alkyl groups,
• - Essentially from C ₈ - to C ₁₆ alkyl groups or
• - Essentially from C ₁₂ - to C ₁₆ alkyl groups or
• - Substituted from C ₁₆ to C ₁₈ alkyl groups

consists.

When Sugar building block Z can be any mono- or oligosaccharides be used. Usually, sugars with 5 or 6 carbon atoms and the corresponding oligosaccharides used. Such sugars are, for example, glucose, fructose, galactose, Arabinose, ribose, xylose, lyxose, allose, altrose, mannose, gulose, Idose, talose and sucrose. Preferred sugar building blocks are glucose, Fructose, galactose, arabinose and sucrose; Glucose is special prefers.

The Alkylpolyglycosides which can be used according to the invention contain on average 1.1 to 5 sugar units. alkylpolyglycosides with x values of 1.1 to 2.0 are preferred. Very particularly preferred are alkyl glycosides in which x is 1.1 to 1.8.

additionally to the surfactants mentioned, the inventive Medium also anionic, cationic and possibly also further contain amphoteric or zwitterionic or nonionic surfactants.

• – lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen (Seifen),
• – Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acyltauride mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acylisethionate mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Sulfobernsteinsäuremono- und -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe,
• – lineare Alkansulfonate mit 8 bis 24 C-Atomen,
• – lineare Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen,
• – Alpha-Sulfofettsäuremethylester von Fettsäuren mit 8 bis 30 C-Atomen,
• – Alkylsulfate,
• – Gemische oberflächenaktiver Hydroxysulfonate,
• – Sulfonate ungesättigter Fettsäuren mit 8 bis 24 C-Atomen und 1 bis 6 Doppelbindungen,
• – Monoglyceridsulfate,
• – Kondensationsprodukte aus C₈-C₃₀-Fettalkoholen mit Proteinhydrolysaten und/oder Aminosäuren und deren Derivaten, welche dem Fachmann als Eiweissfettsäurekondensate bekannt sind, wie beispielsweise die Lamepon^®-Typen, Gluadin^®-Typen, Hostapon^® KCG oder die Amisoft^®-Typen.

Suitable anionic surfactants are in principle all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, ester, ether and amide groups as well as hydroxyl groups can be contained in the molecule. Examples of suitable anionic surfactants are, in each case in the form of the sodium, potassium and ammonium as well as the mono-, di- and trialkanolammonium salts having 2 to 4 C atoms in the alkanol group,

• - linear and branched fatty acids with 8 to 30 carbon atoms (soaps),
• Acylsarcosides having 8 to 24 C atoms in the acyl group,
• Acyltaurides having 8 to 24 carbon atoms in the acyl group,
• Acyl isethionates having 8 to 24 C atoms in the acyl group,
• Sulfosuccinic acid mono- and dialkyl esters having 8 to 24 C atoms in the alkyl group,
• - linear alkanesulfonates having 8 to 24 carbon atoms,
• - linear alpha-olefin sulfonates having 8 to 24 carbon atoms,
• Alpha-sulfofatty acid methyl esters of fatty acids having 8 to 30 C atoms,
• - alkyl sulfates,
• Mixtures of hydroxysulfonates,
• Sulfonates of unsaturated fatty acids having 8 to 24 C atoms and 1 to 6 double bonds,
• - monoglyceride sulphates,
• - condensation products of C ₈ -C ₃₀ fatty alcohols with protein hydrolysates and / or amino acids and their derivatives, which are known to the skilled person as protein fatty acid condensates, such as Lamepon ^® grades, Gluadin ^® grades, Hostapon ^® KCG or Amisoft ^® grades ,

It is preferred according to the invention, to the use abstain from alkyl and / or alkenyl sulfates to pronounced to get mild properties of the funds. Preferred inventive Agents are characterized by the absence of alkyl and alkenyl sulfates.

in the With regard to particularly mild formulations is also the use of alkyl or alkenyl ether sulfates according to the invention not prefers. Here are preferred agents which contain no alkyl and Alkenylethersulfate.

As a general rule is the use of sulfate surfactants in the invention Means rather contraindicated, so that particularly preferred Inventive agents are sulfate-free.

Usable according to the invention are cationic surfactants of the quaternary ammonium type, the esterquats and the amidoamines. Preferred quaternary Ammonium compounds are ammonium halides, especially chlorides and bromides such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides. The long alkyl chains of this Surfactants preferably have 10 to 18 carbon atoms, such as. In cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, Distearyldimethylammonium chloride, lauryldimethylammonium chloride, Lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride. Other preferred cationic surfactants are those under the INCI names Quaternium-27 and quaternium-83 known imidazolium compounds.

• – Alkyltrimethylammoniumchloriden mit vorzugsweise 10 bis 18 Kohlenstoffatomen im Alkylrest und/oder
• – Dialkyldimethylammoniumchloride mit vorzugsweise 10 bis 18 Kohlenstoffatomen im Alkylrest und/oder
• – Trialkylmethylammoniumchloride mit vorzugsweise 10 bis 18 Kohlenstoffatomen im Alkylrest und/oder
• – Cetyltrimethylammoniumchlorid und/oder
• – Stearyltrimethylammoniumchlorid und/oder
• – Distearyldimethylammoniumchlorid und/oder
• – Lauryldimethylammoniumchlorid und/oder
• – Lauryldimethylbenzylammoniumchlorid und/oder
• – Tricetylmethylammoniumchlorid
• – Quaternium-27 und/oder
• – Quaternium-83 und/oder
• – N-Methyl-N(2-hydroxyethyl)-N,N-(ditalgacyloxyethyl)ammonium-methosulfat und/oder
• – N-Methyl-N(2-hydroxyethyl)-N,N-(distearoyloxyethyl)ammonium-methosulfat und/oder
• – N N-Dimethyl-N,N-distearoyloxyethyl-ammoniumchlorid und/oder
• – N,N-Di-(2-hydroxyethyl)-N,N-(fettsäureesterethyl)-ammoniumchlorid.

Particularly preferred agents according to the invention are characterized in that they contain as cationic care substance - based on their weight - 0.05 to 7.5 wt .-%, preferably 0.1 to 5 wt .-%, especially preferably from 0.2 to 3.5% by weight and in particular from 0.25 to 2.5% by weight of cationic surfactant (s) from the group of the quaternary ammonium compounds and / or the esterquats and / or the amidoamines wherein preferred cationic surfactant (s) is / are selected

• - Alkyltrimethylammoniumchloriden having preferably 10 to 18 carbon atoms in the alkyl radical and / or
• - Dialkyldimethylammoniumchloride having preferably 10 to 18 carbon atoms in the alkyl radical and / or
• - Trialkylmethylammoniumchloride preferably having 10 to 18 carbon atoms in the alkyl radical and / or
• Cetyltrimethylammonium chloride and / or
• Stearyltrimethylammonium chloride and / or
• Distearyldimethylammonium chloride and / or
• - Lauryldimethylammonium chloride and / or
• - Lauryldimethylbenzylammoniumchlorid and / or
• - tricetylmethylammonium chloride
• - Quaternium-27 and / or
• - Quaternium-83 and / or
• - N-methyl-N (2-hydroxyethyl) -N, N- (ditalgacyloxyethyl) ammonium methosulfate and / or
• - N-methyl-N (2-hydroxyethyl) -N, N- (distearoyloxyethyl) ammonium methosulfate and / or
• - N N-dimethyl-N, N-distearoyloxyethyl ammonium chloride and / or
• - N, N-di (2-hydroxyethyl) -N, N- (fatty acid ethyl) ammonium chloride.

In addition, preferred agents according to the invention are free of polyethylene glycols of the general formula (I) H- (O-CH ₂ CH ₂ ) _n -OH (I), in which n stands for integers between 1 and 100,000, ie they contain neither ethylene glycol (n = 1) nor products with a degree of polymerisation P _n = 2-4 (diethylene glycol, triethylene glycol and tetraethylene glycol) or polyethylene glycols with higher degrees of polymerization P _n of about 5 to 100,000, which are no longer mol.-uniform produce, but polydisperse.

Surprisingly the omission of compounds of the formula (I) leads to that the protein hydrolysates have their effect on the skin and unfold the hair significantly better. In particular, the strengthening of keratinic fibers, resulting in improved combabilities shows in dry and especially in wet condition and the fullness and smoothness are improved.

Preferably, the agents according to the invention are not only free of polyethylene glycols but also of polypropylene glycols (PPG). Agents preferred according to the invention are characterized in that they do not contain any compounds of the formula (I)) H- (O-CH (CH ₃ ) CH ₂ ) _n -OH (II), in which n stands for integers between 1 and 100,000.

Such preferred agents according to the invention are free of polypropylene glycols of the general formula (II), ie they contain neither propylene glycol (n = 1) nor products with a degree of polymerisation P _n = 2-4 (dipropylene glycol, tripropylene glycol and tetrapropylene glycol) or polypropylene glycols with higher degrees of polymerization P _n from about 5 to 100,000, which are no longer molar-uniform producible, but polydisperse.

Also these compounds hinder the unfolding of the action of the protein hydrolysates on the hair, so that by renouncing their use the improved effects can be observed.

Eds has shown that preferably also on the use of ethoxylated compounds should be verzchtet. In particular, nonionic surfactants of the alkyl or alkenyl ethoxylate type also reduce the positive effects of the protein hydrolysates and should therefore not be used in the formulations. Further preferred agents according to the invention are therefore characterized in that they do not contain compounds of the formula (IIII) R- (O-CH ₂ CH ₂ ) _n -OH (III), wherein R represents any alkyl or alkenyl radical and n represents integers between 1 and 10,000.

Also ethoxylated anionic surfactants can - albeit in lesser extent - the beneficial effects of protein hydrolysates diminish. Here I have in particular alkyl ether sulfates have proved problematic while alkyl ether carboxylates show less effect-reducing effects than the ether sulfates.

Preferred agents according to the invention therefore contain no compounds of the formula (IV) R- (O-CH ₂ CH ₂ ) _n -OSO ₃ H (IV), where R is any alky or alkenyl radical and n is an integer between 1 and 10,000.

In particularly preferred inventive agents is completely dispensed with the use of compounds having ethoxylated groups. Interestingly, a hydroxyethyl moiety (eg, in certain surfactants) does not affect the action of the plant extracts, while ethylene glycol affects the effect. Preferred agents according to the invention therefore contain no compound which contains the grouping - (O-CH ₂ CH ₂ ) _n -O- with n = 1-10,000. Particularly preferred agents according to the invention are characterized in that they contain no compounds which contain the grouping of the formula (V) - (O-CH ₂ CH ₂ ) _n - (V), in which n stands for integers between 2 and 100,000.

As already mentioned, cosmetic products are special Field of the present invention. Under these means, the Hair treatment agent has a special meaning, so that preferred Composition according to the invention hair treatment agent are.

Hair treatment agents For the purposes of the present invention, for example, hair shampoos, hair conditioners, conditioning shampoos, hairsprays, hair conditioners, Hair treatments, hair wraps, hair tonics, perming solutions, Hair dye shampoos, hair dyes, hair fixatives, Hair products, hair styling preparations, fönwell lotions, Mousse, hair gels, hair waxes or combinations thereof. in the Regarding the fact that men are often the Application of several different means and / or multiple application steps shy, agents according to the invention are preferred such means that the man uses anyway. Preferred inventive Agents are therefore shampoos, conditioners or hair tonics.

The Nursing effects of such agents according to the invention can be further enhanced by care enhancers be used. These are preferably made up of specific groups selected nursing substances, since these care enhancers formulation-technical and the care effect with the excellent Protein hydrolyzates used according to the invention harmonize.

• i. L-Carnitin und/oder seiner Salze;
• ii. Panthenol und/oder Panthothensäure;
• iii. der 2-Furanone und/oder deren Derivate, insbesondere Pantolacton;
• iv. Taurin und/oder seiner Salze;
• v. Niacinamid;
• vi. Ubichinon
• vii. Ectoin;
• viii. Allantoin;
• ix. Extrakten von Echinacea

enthalten.Agents which are preferred according to the invention are characterized in that they are hair treatment compositions which additionally contain, in a cosmetically acceptable carrier, at least one care enhancer from the group

• i. L-carnitine and / or its salts;
• ii. Panthenol and / or panthothenic acid;
• iii. the 2-furanones and / or their derivatives, in particular pantolactone;
• iv. Taurine and / or its salts;
• v. niacinamide;
• vi. ubiquinone
• vii. Ectoin;
• viii. allantoin;
• ix. Extracts of Echinacea

contain.

In Hair treatment compositions of this invention Embodiment is the protein hydrolyzate or the surfactant / protein hydrolyzate combination combined with at least one Nursing Enhancer selected is from L-carnitine and / or its salts, panthenol and / or panthothenic acid, 2-furanones and / or their derivatives, in particular pantolactone, Taurine and / or its salts, niacinamide, ubiquinones, ectoine, allantoin, Extracts of Echinacea. These care enhancers are below described.

L-carnitine (IUPAC-Name (R) - (3-carboxy-2-hydroxypropyl) -N, N, N-trimethylammonium) is a naturally occurring, vitamin-like Substance. It plays an essential role in energy metabolism human, animal and plant cells. L-carnitine can over different ways are gained on an industrial scale. For example, one, the body's biosynthesis imitating, biotechnological process: in large fermentation tanks is the precursor of L-carnitine (γ-butyrobetaine) with the help of Gram-negative bacteria (rhizobia) in L-carnitine implemented.

When Betaine can form L-carnitine addition compounds and double salts. According to the invention preferred L-carnitine derivatives are in particular selected from acetyl-L-carnitine, L-carnitine fumarate, L-carnitine citrate, lauroyl L-carnitine and especially preferred L-carnitine tartrate. The L-carnitine compounds mentioned are, for example, of the Company Lonza GmbH (Wuppertal, Germany) available.

invention preferred hair treatment compositions are characterized in that they - related on their weight - 0.001 to 10 wt .-%, preferably 0.005 to 7.5 wt .-%, particularly preferably 0.01 to 5 wt .-% and in particular Contain 0.05 to 2.5% by weight of L-carnitine or L-carnitine derivatives, preferred L-carnitine derivatives are selected from Acetyl-L-carnitine, L-carnitine fumarate, L-carnitine citrate, lauroyl-L-carnitine and in particular L-carnitine tartrate.

panthenol (IUPAC name: (+) - (R) -2,4-dihydroxy-N- (3-hydroxypropyl) -3,3-dimethylbutyramide) is converted into pantothenic acid in the body. Pantothenic acid is a vitamin from the group of B vitamins (Vitamin 65).

invention preferred hair treatment compositions are characterized in that they - related on its weight - 0.01 to 5 wt .-%, preferably 0.05 to 2.5 wt .-%, particularly preferably 0.1 to 1.5 wt .-% and in particular 0.25 to 1% by weight of panthenol ((±) -2,4-dihydroxy-N- (3-hydroxypropyl) -3,3-dimethyl-butyramide) contain.

in welchen die Reste R¹ bis R¹⁰ unabhängig voneinander stehen für:

• – Wasserstoff, -OH, einen Methyl-, Methoxy-, Aminomethyl- oder Hydroxymethylrest,
• – -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest,
• – -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Triaminokohlenwasserstoffrest,
• – eine Gruppe -OR¹¹, mit R¹¹ als einem -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, -C₂- C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – eine Gruppe -NR¹²R¹³, wobei R¹² und R¹³ jeweils unabhängig voneinander stehen für Wasserstoff, einen Methyl-, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – eine Gruppe -COOR¹⁴, wobei R¹⁴ steht für Wasserstoff, einen Methyl-, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₄ – gesättigten ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Triaminokohlenwasserstoffrest,
• – eine Gruppe -CONR¹⁵R¹⁶, wobei R¹⁵ und R¹⁶ jeweils stehen für Wasserstoff, Methyl-, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₄ – gesättigten ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Triaminokohlenwasserstoffrest,
• – eine Gruppe -COR¹⁶, wobei R¹⁶ steht für einen Methyl-, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Triaminokohlenwasserstoffrest,
• – eine Gruppe -OCOR¹⁷, wobei R¹⁷ steht für einen Methyl-, einen -C₂-C₃₀ – gesättigten oder ein- oder mehrfach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₃₀ – gesättigten oder ein- oder mehrfach ungesättigten, verzweigten oder linearen Mono-, Di-, Tri- oder Polyhydroxykohlenwasserstoffrest, einen -C₂-C₃₀ – gesättigten oder ein- oder mehrfach ungesättigten, verzweigten oder linearen Mono-, Di-, Tri- oder Polyaminokohlenwasserstoffrest,

mit der Maßgabe, daß für den Fall, wenn R⁷ und R⁸ für -OH und gleichzeitig R⁹ oder R¹⁰ für Wasserstoff stehen, die verbleibende Gruppe R⁹ oder R¹⁰ nicht für einen Dihydroxyethylrest steht.According to the invention preferred hair treatment compositions contain - based on their weight - 0.01 to 15 wt .-%, preferably 0.025 to 12.5 wt .-%, particularly preferably 0.05 to 10 wt .-%, more preferably 0.1 to 7 , 5% by weight and in particular 0.5 to 5% by weight of at least one 2-furanone derivative of the formula (Fur-I) and / or of the formula (Fur-II)

in which the radicals R ¹ to R ^{10 are} independently of one another

• Hydrogen, -OH, a methyl, methoxy, aminomethyl or hydroxymethyl radical,
• --C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear hydrocarbon radical,
• - C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear mono-, di- or Trihydroxykohlenwasserstoffrest,
• --C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbon radical,
• A group -OR ¹¹ , with R ¹¹ as a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear Mono-, di- or trihydroxyhydrocarbyl radical,
• - a group -NR ¹² R ¹³ , wherein R ¹² and R ¹³ each independently represent hydrogen, a methyl, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxyhydrocarbyl radical,
• A group -COOR ¹⁴ , where R ¹⁴ is hydrogen, a methyl, a C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ -saturated hydrocarbon radical, or diunsaturated, branched or linear mono-, di- or trihydroxy hydrocarbon radical, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbyl radical,
• A group -CONR ¹⁵ R ¹⁶ , wherein R ¹⁵ and R ¹⁶ each represent hydrogen, methyl, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ - saturated mono- or diunsaturated, branched or linear mono-, di- or trihydroxy hydrocarbon, a -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear mono-, di- or triamino hydrocarbon,
• A group -COR ¹⁶ , where R ¹⁶ is a methyl, a C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ -saturated or -or- or di-unsaturated, branched or linear mono-, di- or trihydroxyhydrocarbyl radical, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbon radical,
• - a group -OCOR ¹⁷ , wherein R ¹⁷ is a methyl, a -C ₂ -C ₃₀ -saturated or mono- or polyunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₃₀ -saturated or one or polyunsaturated, branched or linear mono-, di-, tri- or polyhydroxy hydrocarbon radical, a -C ₂ -C ₃₀ -saturated or mono- or polyunsaturated, branched or linear mono-, di-, tri- or polyamino hydrocarbon radical,

with the proviso that when R ⁷ and R ^{8 are} -OH and at the same time R ⁹ or R ^{10 is} hydrogen, the remaining group R ⁹ or R ¹⁰ does not represent a dihydroxyethyl radical.

The Compounds of the formulas (Fur-I) and (Fur-II) are used as intermediates in the synthesis of natural products as well as the production of medicines and vitamins used. The preparation of the active ingredients according to the Formulas (Fur-I) and (Fur-II) can be converted, for example, by reaction of primary alcohols with acrylic acids. Furthermore, compounds of the formula (Fur-I) are obtained by reactions starting from hydroxypivaldehyde. Also carry carbonylations of alkyls to substituted 2-furanones of the formula (Fur-I) or (Fur-II). Finally, the connections can of the formula (Fur-I) or of the formula (Fur-II) by intramolecular Esterification of the corresponding hydroxycarboxylic obtained become. For example, the following connections are on one of the above-identified synthetic routes: 2,5-dihydro-5-methoxy-2-furanone, Tetrahydro-5-oxo-2-furancarboxylic acid, dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone, or 3,4-dimethyl-5-pentylidenedihydro-2 (5H) -furanone or 4-hydroxy-2,5-dimethyl-3 (2H) -furanone. The 2-furanones according to the invention include of course all possible stereoisomers as well as their mixtures. By the 2-furanone according to the invention becomes the odor the cosmetic product is not permanently affected, so that a perfuming of the funds done separately got to.

• – Wasserstoff, einen -OH-, einen Methyl-, Methoxy-, Aminomethyl-, Hydroxymethylrest,
• – einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Triaminokohlenwasserstoffrest,
• – eine Gruppe -OR¹¹, mit R¹¹ als einem -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – eine Gruppe -NR¹²R¹³, wobei R¹² und R¹³ jeweils unabhängig voneinander stehen für Wasserstoff, einen Methyl-, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – eine Gruppe -COOR¹⁴, wobei R¹⁴ steht für Wasserstoff, einen Methyl-, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Triaminokohlenwasserstoffrest,
• – eine Gruppe -COR¹⁶, wobei R¹⁶ steht für einen Methyl-, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Triaminokohlenwasserstoffrest,
• – eine Gruppe -COOR¹⁷, wobei R¹⁷ steht für einen Methyl-, einen -C₂-C₃₀ – gesättigten oder ein- oder mehrfach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₃₀ – gesättigten oder ein- oder mehrfach ungesättigten, verzweigten oder linearen Mono-, Di-, Tri- oder Polyhydroxyalkylrest, oder einen -C₂-C₃₀ – gesättigten oder ein- oder mehrfach ungesättigten, verzweigten oder linearen Mono-, Di-, Tri- oder Polyaminokohlenwasserstoffrest.

Preferred compounds of the formula (fur-I) and / or of the formula (fur-II) may be compounds in which the substituents R ¹ , R ² and R ⁷ independently of one another represent:

• Hydrogen, an -OH, a methyl, methoxy, aminomethyl, hydroxymethyl radical,
• A C ₂ -C ₄ saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxy hydrocarbon radical,
• A C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbon radical,
• - a group -OR ¹¹ , with R ¹¹ as a -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear Mono-, di- or trihydroxyhydrocarbyl radical,
• - a group -NR ¹² R ¹³ , wherein R ¹² and R ¹³ each independently represent hydrogen, a methyl, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxyhydrocarbyl radical,
• A group -COOR ¹⁴ , wherein R ¹⁴ is hydrogen, a methyl, a C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ -saturated or - or diunsaturated, branched or linear mono-, di- or trihydroxy hydrocarbon radical, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbon radical,
• A group -COR ¹⁶ , where R ¹⁶ is a methyl, a C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ -saturated or -or- or di-unsaturated, branched or linear mono-, di- or trihydroxyhydrocarbyl radical, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbon radical,
• - a group -COOR ¹⁷ , wherein R ¹⁷ is a methyl, a -C ₂ -C ₃₀ - saturated or mono- or polyunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₃₀ - saturated or on or - polyunsaturated, branched or linear mono-, di-, tri- or polyhydroxyalkyl radical, or a -C ₂ -C ₃₀ -saturated or mono- or polyunsaturated, branched or linear mono-, di-, tri- or polyamino hydrocarbon radical.

• – Wasserstoff, einen -OH-, einen Methyl-, Methoxy-, Aminomethyl-, Hydroxymethylrest,
• – einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest,
• – einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest oder
• – einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Triaminokohlenwasserstoffrest.

In a further embodiment of the teaching according to the invention, it has been found that in the case of the compounds of the formula (Fur-I) or of the formula (Fur-II), the radicals R ³ , R ⁴ and R ^{8 are} preferably, independently of one another,

• Hydrogen, an -OH, a methyl, methoxy, aminomethyl, hydroxymethyl radical,
• A C ₂ -C ₄ saturated or mono- or diunsaturated, branched or linear hydrocarbon radical,
• - a -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxy hydrocarbon radical or
• - a -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbon.

• – Wasserstoff, einen -OH-, einen Methyl-, Methoxy-, Aminomethyl-, Hydroxymethylrest,
• – einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest,
• – einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest oder
• – einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Triaminokohlenwasserstoffrest.

Furthermore, it may be preferred for the radicals R ⁵ , R ⁶ , R ⁹ and R ¹⁰ in the active substance according to the formula (I) and / or formula (II) according to the invention independently of one another to be:

• Hydrogen, an -OH, a methyl, methoxy, aminomethyl, hydroxymethyl radical,
• A C ₂ -C ₄ saturated or mono- or diunsaturated, branched or linear hydrocarbon radical,
• - a -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxy hydrocarbon radical or
• - a -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbon.

• – Wasserstoff, einen -OH-, einen Methyl-, Methoxy-, Aminomethyl-, Hydroxymethylrest,
• – einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – eine Gruppe -OR¹¹, mit R¹¹ als einem -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – eine Gruppe -COOR¹⁴, wobei R¹⁴ steht für Wasserstoff, einen Methyl-, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₄ – gesättigten ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – eine Gruppe -COR¹⁶, wobei R¹⁶ steht für einen Methyl-, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – eine Gruppe -OCOR¹⁷, wobei R¹⁷ steht für einen Methyl-, einen -C₂-C₃₀ – gesättigten oder ein- oder mehrfach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₃₀ – gesättigten oder ein- oder mehrfach ungesättigten, verzweigten oder linearen Mono-, Di-, Tri- oder Polyhydroxykohlenwasserstoffrest.

In a particularly preferred embodiment of the teaching according to the invention, a compound of the formula (Fur-I) is used. It may be preferred that in a compound of the formula (fur-I), the radicals R ¹ and R ^{2 are} independently of one another:

• Hydrogen, an -OH, a methyl, methoxy, aminomethyl, hydroxymethyl radical,
• A C ₂ -C ₄ saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxy hydrocarbon radical,
• - a group -OR ¹¹ , with R ¹¹ as a -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear Mono-, di- or trihydroxyhydrocarbyl radical,
• A group -COOR ¹⁴ , where R ¹⁴ is hydrogen, a methyl, a C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ -saturated hydrocarbon radical, or diunsaturated, branched or linear mono-, di- or trihydroxyhydrocarbyl radical,
• A group -COR ¹⁶ , where R ¹⁶ is a methyl, a C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ -saturated or -or- or diunsaturated, branched or linear mono-, di- or trihydroxyhydrocarbyl radical,
• - a group -OCOR ¹⁷ , wherein R ¹⁷ is a methyl, a -C ₂ -C ₃₀ -saturated or mono- or polyunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₃₀ -saturated or one or polyunsaturated, branched or linear mono-, di-, tri- or Polyhydroxykohlenwasserstoffrest.

• – Wasserstoff, einen -OH-, einen Methyl-, Methoxy-, Aminomethyl-, Hydroxymethylrest,
• – einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – eine Gruppe -OR¹¹, mit R¹¹ als einem -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – eine Gruppe -COOR¹⁴, wobei R¹⁴ steht für Wasserstoff, einen Methyl-, einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₄ – gesättigten ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – eine Gruppe -OCOR¹⁷, wobei R¹⁷ steht für einen Methyl-, einen -C₂-C₃₀ – gesättigten oder ein- oder mehrfach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, einen -C₂-C₃₀ – gesättigten oder ein- oder mehrfach ungesättigten, verzweigten oder linearen Mono-, Di-, Tri- und/oder Polyhydroxykohlenwasserstoffrest.

Furthermore, in this particularly preferred embodiment of the teaching according to the invention, it may be advantageous if in the compounds of the formula (Fur-I) the radicals R ³ and R ⁴ independently of one another represent:

• Hydrogen, an -OH, a methyl, methoxy, aminomethyl, hydroxymethyl radical,
• A C ₂ -C ₄ saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxy hydrocarbon radical,
• - a group -OR ¹¹ , with R ¹¹ as a -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear Mono-, di- or trihydroxyhydrocarbyl radical,
• A group -COOR ¹⁴ , where R ¹⁴ is hydrogen, a methyl, a C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ -saturated hydrocarbon radical, or diunsaturated, branched or linear mono-, di- or trihydroxyhydrocarbyl radical,
• - a group -OCOR ¹⁷ , wherein R ¹⁷ is a methyl, a -C ₂ -C ₃₀ -saturated or mono- or polyunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₃₀ -saturated or one or polyunsaturated, branched or linear mono-, di-, tri- and / or polyhydroxy hydrocarbon radical.

• – einen -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest,
• – eine Gruppe -OR¹¹, mit R¹¹ als einem -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Kohlenwasserstoffrest, -C₂-C₄ – gesättigten oder ein- oder zweifach ungesättigten, verzweigten oder linearen Mono-, Di- oder Trihydroxykohlenwasserstoffrest.

In this preferred embodiment, it may furthermore be advantageous for the compounds of the formula (Fur I) for the radicals R ⁵ and R ^{6 to} stand independently for:

• A C ₂ -C ₄ saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxy hydrocarbon radical,
• - a group -OR ¹¹ , with R ¹¹ as a -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, -C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear Mono-, di- or trihydroxyhydrocarbon radical.

• – (R)-(–)-4-Hydroxymethyl-γ-butyrolacton und/oder
• – D,L-4-Hydroxymethyl-γ-butyrolacton und/oder
• – (S)-(+)-4-Hydroxymethyl-γ-butyrolacton und/oder
• – R-(–)-2-Hydroxy-3,3-dimethyl-γ-butyrolacton und/oder
• – D,L-2-Hydroxy-3,3-dimethyl-γ-butyrolacton und/oder
• – S(+)-2-Hydroxy-3,3-dimethyl-γ-butyrolacton und/oder
• – 4-Hydroxy-2,5-dimethyl-3(2H)-furanon und/oder
• – Tetrahydro-5-oxo-2-furancarbonsäure und/oder
• – Tetrahydro-5-oxo-2-furancarbonsäure, Na-Salz und/oder
• – Tetrahydro-5-oxo-2-furancarbonsäure, K-Salz und/oder
• – 2,5-Dihydro-5-methoxy-2-furanon und/oder
• – Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon

eingesetzt. In einer ganz besonders bevorzugten Ausführungsform der erfindungsgemäßen Lehre wird als Verbindung entsprechend der Formel (Fur-I) Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon eingesetzt.In a particularly preferred embodiment of the teaching according to the invention is used as the compound according to the formula (Fur-I)

• - (R) - (-) - 4-hydroxymethyl-γ-butyrolactone and / or
• - D, L-4-hydroxymethyl-γ-butyrolactone and / or
• - (S) - (+) - 4-hydroxymethyl-γ-butyrolactone and / or
• - R - (-) - 2-hydroxy-3,3-dimethyl-γ-butyrolactone and / or
• - D, L-2-hydroxy-3,3-dimethyl-γ-butyrolactone and / or
• - S (+) - 2-hydroxy-3,3-dimethyl-γ-butyrolactone and / or
• 4-hydroxy-2,5-dimethyl-3 (2H) -furanone and / or
• - Tetrahydro-5-oxo-2-furancarbonsäure and / or
• - Tetrahydro-5-oxo-2-furancarbonsäure, Na salt and / or
• Tetrahydro-5-oxo-2-furancarboxylic acid, K salt and / or
• 2,5-dihydro-5-methoxy-2-furanone and / or
• Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone

used. In a very particularly preferred embodiment of the teaching according to the invention is used as a compound corresponding to the formula (Fur-I) dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone.

One Another, more preferred care enhancer, the activating Possesses properties, is the taurine. According to the invention preferred Hair treatment products contain - based on their weight - 0.01 to 15% by weight, preferably 0.025 to 12.5% by weight, more preferably 0.05 to 10 wt .-%, more preferably 0.1 to 7.5 wt .-% and in particular 0.5 to 5 wt .-% taurine (2-aminoethanesulfonic acid).

Another preferred group of skin care enhancers in the compositions of the invention are vitamins, provitamins or vitamin precursors. These are described below:
The group of substances called vitamin A includes retinol (vitamin A ₁ ) and 3,4-didehydroretinol (vitamin A ₂ ). The β-carotene is the provitamin of retinol. As vitamin A component according to the invention, for example, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as the palmitate and the acetate into consideration. The agents according to the invention preferably contain the vitamin A component in amounts of 0.05-1% by weight, based on the total preparation.

• – Vitamin B₁ (Thiamin)
• – Vitamin B₂ (Riboflavin)
• – Vitamin B₃. Unter dieser Bezeichnung werden häufig die Verbindungen Nicotinsäure und Nicotinsäureamid (Niacinamid) geführt. Erfindungsgemäß bevorzugt ist das Nicotinsäureamid, das in den erfindungsgemäß verwendeten Mitteln bevorzugt in Mengen von 0,05 bis 1 Gew.-%, bezogen auf das gesamte Mittel, enthalten ist.
• – Vitamin B₅ (Pantothensäure, Panthenol und Pantolacton). Im Rahmen dieser Gruppe wird bevorzugt das Panthenol und/oder Pantolacton eingesetzt (siehe weiter unten). Erfindungsgemäß einsetzbare Derivate des Panthenols sind insbesondere die Ester und Ether des Panthenols sowie kationisch derivatisierte Panthenole. Einzelne Vertreter sind beispielsweise das Panthenoltriacetat, der Panthenolmonoethylether und dessen Monoacetat sowie die in der WO 92/13829 offenbarten kationischen Panthenolderivate. Die genannten Verbindungen des Vitamin B₅-Typs sind in den erfindungsgemäßen Mitteln bevorzugt in Mengen von 0,05–10 Gew.-%, bezogen auf das gesamte Mittel, enthalten. Mengen von 0,1–5 Gew.-% sind besonders bevorzugt.
• – Vitamin B₆ (Pyridoxin sowie Pyridoxamin und Pyridoxal).

The vitamin B group or the vitamin B complex include, among others

• - Vitamin B ₁ (thiamine)
• - Vitamin B ₂ (riboflavin)
• - Vitamin B ₃ . Under this name, the compounds nicotinic acid and nicotinamide (niacinamide) are often performed. Preferred according to the invention is the nicotinic acid amide which is contained in the agents used according to the invention preferably in amounts of from 0.05 to 1% by weight, based on the total agent.
• - Vitamin B ₅ (pantothenic acid, panthenol and pantolactone). Panthenol and / or pantolactone are preferably used in the context of this group (see below). Derivatives of panthenol which can be used according to the invention are, in particular, the esters and ethers of panthenol and also cationically derivatized panthenols. Individual representatives are for example the Panthenoltriacetat, the Panthenolmonoethylether and its monoacetate as well as in the WO 92/13829 disclosed cationic panthenol derivatives. The said compounds of the vitamin B ₅ type are preferably present in the agents according to the invention in amounts of 0.05-10% by weight, based on the total agent. Amounts of 0.1-5 wt .-% are particularly preferred.
• - Vitamin B ₆ (pyridoxine and pyridoxamine and pyridoxal).

vitamin C (ascorbic acid). Vitamin C is in the inventive Agents preferably in amounts of 0.1 to 3 wt .-%, based on the entire funds used. The use in the form of palmitic acid ester, the glucoside or phosphates may be preferred. The usage in combination with tocopherols may also be preferred.

vitamin E (tocopherols, especially α-tocopherol). tocopherol and its derivatives, including in particular the esters such as the acetate, nicotinate, phosphate and succinate are in the agents according to the invention preferably in amounts from 0.05 to 1% by weight, based on the total agent.

vitamin F. The term "vitamin F" usually becomes essential Fatty acids, especially linoleic acid, linolenic acid and arachidonic acid, understood.

vitamin H. As vitamin H, the compound becomes (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] imidazole-4-valeric acid but for the meantime the trivial name Biotin has prevailed. Biotin is in the invention Agents preferably in amounts of 0.0001 to 1.0 wt .-%, in particular in amounts of 0.001 to 0.01 wt .-%.

In summary, hair-treatment compositions according to the invention are preferred which, based on their weight, are 0.1 to 5% by weight, preferably 0.2 to 4% by weight, more preferably 0.25 to 3.5% by weight, more preferably Contain 0.5 to 3 wt .-% and in particular 0.5 to 2.5 wt .-% vitamins and / or pro-vitamins and / or vitamin precursors, preferably the groups A, B, C, E, F and H. 2,4,4-dihydroxy-N- (3-hydroxypropyl) -3,3-dimethylbutyramide, provitamin B ₅ ) and / or pantothenic acid (vitamin B ₃ , vitamin B ₅ ) and / or niacin , Niacinamide or nicotinamide (vitamin B ₃ ) and / or L-ascorbic acid (vitamin C) and / or thiamine (vitamin B ₁ ) and / or riboflavin (vitamin B ₂ , vitamin G) and / or biotin (vitamin B ₇ , Vitamin H) and / or folic acid (vitamin B ₉ , vitamin B _c or vitamin M) and / or vitamin B ₆ and / or vitamin B ₁₂ .

enthalten in der
X, Y, Z stehen unabhängig voneinander für -O- oder -NH- oder NR⁴- oder eine chemische Bindung
R¹, R², R³ stehen unabhängig voneinander für ein Wasserstoffatom oder eine gegebenenfalls substituierte Arylgruppe oder eine gegebenenfalls substituierte (C₁-C₆)-Alkylgruppe oder eine Hydroxyalkylgruppe oder eine Polyhydroxyalkylgruppe oder eine gegebenenfalls substituierte (C₁-C₆)-Alkylengruppe, oder einen (C₁-C₆)-Acylrest, wobei bevorzugte Reste unabhängig voneinander ausgewählt sind aus -H, -CH₃, -CH₂CH₃, -(CH₂)₂CH₂, -CH(CH₃)₂, -(CH₂)₃CH₃, -CH(CH₃)CH₂CH₃, -CH₂CH(CH₃)₂, -C(CH₃)₃
R⁴ steht für -CH₃, -CH₂CH₃, -(CH₂)₂CH₂, -CH(CH₃)₂, -(CH₂)₃CH₃, -CH(CH₃)CH₂CH₃, -CH₂CH(CH₃)₂, -C(CH₃)₃
n steht für Werte von 1 bis 20, vorzugsweise von 2 bis 15 und insbesondere für 5, 6, 7, 8, 9, 10.It has been shown that certain quinones have particular suitability as a care enhancer. As a further care enhancer, the compositions according to the invention may therefore contain from 0.0001 to 5% by weight of at least one biochinone of the formula (Ubi)

contained in the
X, Y, Z are independently -O- or -NH- or NR ⁴ - or a chemical bond
R ¹ , R ² , R ³ independently of one another represent a hydrogen atom or an optionally substituted aryl group or an optionally substituted (C ₁ -C ₆ ) -alkyl group or a hydroxyalkyl group or a polyhydroxyalkyl group or an optionally substituted (C ₁ -C ₆ ) - Alkylene group, or a (C ₁ -C ₆ ) -acyl radical, preferred radicals being selected independently of one another from -H, -CH ₃ , -CH ₂ CH ₃ , - (CH ₂ ) ₂ CH ₂ , -CH (CH ₃ ) ₂ , - (CH ₂ ) ₃ CH ₃ , -CH (CH ₃ ) CH ₂ CH ₃ , -CH ₂ CH (CH ₃ ) ₂ , -C (CH ₃ ) ₃
R ⁴ is -CH ₃ , -CH ₂ CH ₃ , - (CH ₂ ) ₂ CH ₂ , -CH (CH ₃ ) ₂ , - (CH ₂ ) ₃ CH ₃ , -CH (CH ₃ ) CH ₂ CH ₃ , -CH ₂ CH (CH ₃ ) ₂ , -C (CH ₃ ) ₃
n stands for values from 1 to 20, preferably from 2 to 15 and in particular for 5, 6, 7, 8, 9, 10.

in denen
R¹, R², R³ stehen jeweils unabhängig voneinander für -H, -CH₃, -CH₂CH₃, -(CH₂)₂CH₂, -CH(CH₃)₂, -(CH₂)₃CH₃, -CH(CH₃)CH₂CH₃, -CH₂CH(CH₃)₂, -C(CH₃)₃
R⁴ steht für -CH₃, oder -CH₂CH₃, oder -(CH₂)₂CH₂, oder -CH(CH₃)₂
n steht für Werte von 1 bis 20, vorzugsweise von 2 bis 15 und insbesondere für 5, 6, 7, 8, 9, 10.Preferred compounds of the formula (Ubi) according to the invention are, for example

in which
R ¹ , R ² , R ³ are each independently -H, -CH ₃ , -CH ₂ CH ₃ , - (CH ₂ ) ₂ CH ₂ , -CH (CH ₃ ) ₂ , - (CH ₂ ) ₃ CH ₃ , -CH (CH ₃ ) CH ₂ CH ₃ , -CH ₂ CH (CH ₃ ) ₂ , -C (CH ₃ ) ₃
R ⁴ is -CH ₃ , or -CH ₂ CH ₃ , or - (CH ₂ ) ₂ CH ₂ , or -CH (CH ₃ ) ₂
n stands for values from 1 to 20, preferably from 2 to 15 and in particular for 5, 6, 7, 8, 9, 10.

in der n für die Werte = 6, 7, 8, 9 oder 10, besonders bevorzugt für 10 (Coenzym Q10) steht.Particularly preferred hair treatment compositions according to the invention are characterized in that they contain as care substance - based on their weight - 0.0001 to 1 wt .-%, preferably 0.001 to 0.5 wt .-% and particularly preferably 0.005 to 0.1 wt .-% containing at least one ubiquinone and / or at least one ubiquinol and / or at least one derivative of these substances, preferred agents containing a ubiquinone of the formula (Ubi)

in which n stands for the values = 6, 7, 8, 9 or 10, particularly preferably 10 (coenzyme Q10).

in der n für Werte von 1 bis 20, vorzugsweise von 2 bis 15 und insbesondere für 5, 6, 7, 8, 9, 10 steht, wobei besonders bevorzugt Mittel Plastochinon PQ-9 der Formel

enthalten.As an alternative to the particularly preferred ubiquinones or in addition to them, the agents according to the invention may also contain plastoquinones. Here, preferred agents according to the invention are characterized in that they are 0.0002 to 4 wt .-%, preferably 0.0005 to 3 wt .-%, particularly preferably 0.001 to 2 wt .-%, more preferably 0.0015 to 1 and in particular 0.002 to 0.5 wt .-% of at least one plastoquinone of the formula (Ubi-b)

in which n stands for values of 1 to 20, preferably of 2 to 15 and in particular for 5, 6, 7, 8, 9, 10, whereby particularly preferred means Plastochinon PQ-9 of the formula

contain.

As a further care enhancer, the agents according to the invention may contain ectoin. Ectoine ((4S) -2-methyl-1,4,5,6-tetrahydropyrimidine-4-carboxylic acid) is a natural product belonging to the group of compatible solutes. The highly water-binding low molecular weight organic compound occurs in halophilic bacteria and allows these extremophilic organisms to survive under stress conditions. Hair treatment compositions which are preferred according to the invention are characterized in that they contain, based on their weight, from 0.001 to 10% by weight, preferably from 0.01 to 5% by weight, particularly preferably from 0.05 to 2.5% by weight and in particular from 0 , 1 to 1% by weight of (S) -2-methyl-1,4,5,6-tetrahydro-4-pyrimidinecarboxylic acid (ectoine) and the physiologically tolerated salts of this compound and / or (S, S) -5- hydroxy-2-methyl-1,4,5,6-tetrahydro dro-4-pyrimidinecarboxylic acid (hydroxyectoine) and the physiologically acceptable salts of this compound.

One Another nurse enhancer is allantoin. Allantoin (5-ureido-hydantoin, N- (2,5-dioxo-4-imidazolidinyl) urea) is at various Animal species, especially in mammals, in addition to uric acid the end product of the degradation of nucleic acids, especially of Purine bases.

allantoin is used in cosmetics in skin creams, sunscreens, shaving waters, in toothpaste and in remedies against excessive Perspiration (hyperhidrosis) and skin irritations used. It causes the acceleration of cell building, cell formation or cell regeneration and soothes the skin. Also the cure hard-healing wounds is supported, but possesses Allantoin no antiseptic properties.

invention contain particularly preferred hair treatment agent - related on their weight - 0.001 to 10% by weight, preferably 0.01 to 5 wt .-%, particularly preferably 0.05 to 2.5 wt .-% and in particular 0.1 to 1% by weight of 5-ureidohydantoin (allantoin).

to Improvement of elasticity and strengthening of the inner Structure of treated with agents of the invention Hair can the agents of the invention Purine and / or purine derivatives as a care enhancer included. Especially the combination of purine and / or purine derivatives with ubiquinones and / or plastoquinones as a care enhancer causes that the treated with appropriate means hair, among others higher values for differential thermal analysis and show improved wet and dry combabilities.

Purine (7H-imidazo [4,5-d] pyrimidine) does not occur freely in nature, but forms the main body of purines. Purines, in turn, are a group of important compounds naturally involved in human, animal, plant and microbial metabolic processes which are different from the parent by substitution with OH, NH ₂ , SH at the 2-, 6-, and 8-positions and / or with CH ₃ in 1-, 3-, 7-position derived. Purine can be prepared, for example, from aminoacetonitrile and formamide. Purines and purine derivatives are often isolated from natural products, but are also synthetically accessible in many ways.

preferred agents according to the invention contain purine and / or Purine derivatives in narrower ranges. Here are preferred according to the invention Cosmetic compositions characterized in that they - related on their weight - 0.001 to 2.5 wt .-%, preferably 0.0025 to 1 wt .-%, particularly preferably 0.005 to 0.5 wt .-% and in particular 0.01 to 0.1 wt .-% purine (s) and / or purine derivative (s) included.

in der die Reste R¹, R² und R³ unabhängig voneinander ausgewählt sind aus -H, -OH, NH₂, -SH und die Reste R⁴, R⁵ und R⁶ unabhängig voneinander ausgewählt sind aus -H, -CH₃ und -CH₂-CH₃, wobei folgende Verbindungen bevorzugt sind:

• – Purin (R¹ = R² = R³ = R⁴ = R⁵ = R⁶ = H)
• – Adenin (R¹ = NH₂, R² = R³ = R⁴ = R⁵ = R⁶ = H)
• – Guanin (R¹ = OH, R² = NH₂, R³ = R⁴ = R⁵ = R⁶ = H)
• – Harnsäure (R¹ = R² = R³ = OH, R⁴ = R⁵ = R⁶ = H)
• – Hypoxanthin (R¹ = OH, R² = R³ = R⁴ = R⁵ = R⁶ = H)
• – 6-Purinthiol (R¹ = SH, R² = R³ = R⁴ = R⁵ = R⁶ = H)
• – 6-Thioguanin (R¹ = SH, R² = NH₂, R³ = R⁴ = R⁵ = R⁶ = H)
• – Xanthin (R¹ = R² = OH, R³ = R⁴ = R⁵ = R⁶ = H)
• – Coffein (R¹ = R² = OH, R³ = H, R⁴ = R⁵ = R⁶ = CH₃)
• – Theobromin (R¹ = R² = OH, R³ = R⁴ = H, R⁵ = R⁶ = CH₃)
• – Theophyllin (R¹ = R² = OH, R³ = H, R⁴ = CH₃, R⁵ = CH₃, R⁶ = H).

Among purine, the purines and the purine derivatives, some representatives are particularly preferred according to the invention. Hair treatment compositions which are preferred according to the invention are characterized in that they contain, as care-enhancers, based on their weight, from 0.001 to 2.5% by weight, preferably from 0.0025 to 1% by weight, particularly preferably from 0.005 to 0.5% by weight. % and in particular 0.01 to 0.1 wt .-% purine (s) and / or purine derivative (s), wherein preferred agents purine and / or purine derivative (s) of the formula (Pur-I)

in which the radicals R ¹ , R ² and R ^{3 are} independently selected from -H, -OH, NH ₂ , -SH and the radicals R ⁴ , R ⁵ and R ^{6 are} independently selected from -H, -CH ₃ and -CH ₂ -CH ₃ , where the following compounds are preferred:

• Purine (R ¹ = R ² = R ³ = R ⁴ = R ⁵ = R ⁶ = H)
• Adenine (R ¹ = NH ₂ , R ² = R ³ = R ⁴ = R ⁵ = R ⁶ = H)
• Guanine (R ¹ = OH, R ² = NH ₂ , R ³ = R ⁴ = R ⁵ = R ⁶ = H)
• Uric acid (R ¹ = R ² = R ³ = OH, R ⁴ = R ⁵ = R ⁶ = H)
• Hypoxanthine (R ¹ = OH, R ² = R ³ = R ⁴ = R ⁵ = R ⁶ = H)
• 6-purethiol (R ¹ = SH, R ² = R ³ = R ⁴ = R ⁵ = R ⁶ = H)
• 6-thioguanine (R ¹ = SH, R ² = NH ₂ , R ³ = R ⁴ = R ⁵ = R ⁶ = H)
• Xanthine (R ¹ = R ² = OH, R ³ = R ⁴ = R ⁵ = R ⁶ = H)
• Caffeine (R ¹ = R ² = OH, R ³ = H, R ⁴ = R ⁵ = R ⁶ = CH ₃ )
• - Theobromine (R ¹ = R ² = OH, R ³ = R ⁴ = H, R ⁵ = R ⁶ = CH ₃ )
• Theophylline (R ¹ = R ² = OH, R ³ = H, R ⁴ = CH ₃ , R ⁵ = CH ₃ , R ⁶ = H).

It is also advantageous, purine or purine derivatives and biochinones in a certain relationship to each other. Here, agents according to the invention are preferred in the weight ratio of purine (derivative (s)) and Biochinone (s) 10: 1 to 1: 100, preferably 5: 1 to 1:50, especially preferably 2: 1 to 1:20 and in particular 1: 1 to 1:10.

As already mentioned, caffeine is a particularly preferred Purine derivative, and the coenzyme Q10 is a particularly preferred Bioquinone. Particularly preferred invention Means are therefore characterized in that they - related on their weight - 0.001 to 2.5 wt .-%, preferably 0.0025 to 1 wt .-%, particularly preferably 0.005 to 0.5 wt .-% and in particular 0.01 to 0.1% by weight of caffeine and 0.0002 to 4% by weight, preferably 0.0005 to 3 wt .-%, particularly preferably 0.001 to 2 wt .-%, further preferably 0.0015 to 1 and in particular 0.002 to 0.5 wt .-% coenzyme Q10 included.

When Nursing enhancers may be the invention Agents also contain flavonoids. The flavonoids are a group of water-soluble plant dyes and play one important role in the metabolism of many plants. you belong along with the phenolic acids to the polyphenols. There are Well over 6,500 different flavonoids are known into flavonols, flavones, flavanones, isoflavonoids and anthocyanins to divide.

According to the invention Flavonoids are used from all six groups, with specific representatives from the individual groups as a care-enhancer because of their particular intense effect are preferred. Preferred flavonols are quercetin, Rutin, kaempferol, myricetin, isorhamnetin, preferred flavonols are catechin, gallocatechin, epicatechin, epigallocatechin gallate, Theaflavin, thearubigin, preferred flavones are luteolin, apigenin, Morin, preferred flavanones are hesperetin, naringenin, eriodictyol, preferred isofiavonoids are genistein, daidzein, and preferred Anthocyanins (anthocyanins) are cyanidin, delphinidin, malvidin, Pelargonidin, peonidin, petunidin.

Particularly according to the invention preferred hair treatment compositions are characterized in that they - related on their weight - 0.001 to 2.5 wt .-%, preferably 0.0025 to 1 wt .-%, particularly preferably 0.005 to 0.5 wt .-% and in particular 0.01 to 0.1 wt .-% flavonoids, especially flavonols, especially preferably 3,3 ', 4', 5,7-pentahydroxyflavone (quercetin) and / or 3,3 ', 4', 5,7-pentahydroxyflavone-3-O-rutinoside (Rutin), included.

enthalten.Preference is also the use of bisabolol and / or bisabololoxides as care enhancers in the inventive compositions. Here, hair treatment compositions according to the invention are preferred which additionally contain 0.001 to 5 wt .-%, preferably 0.01 to 4 wt .-%, particularly preferably 0.02 to 2.5 wt .-% and in particular 0.1 to 1.5 wt % Bisabolol and / or oxides of bisabolol, preferably (-) - alpha-bisabolol

contain.

Also Creatine is suitable according to the invention as a care enhancer. Creatine (3-methylguanidinoacetic acid) is an organic Acid present in vertebrates u. a. to supply the muscles contributes with energy. Creatine is in the kidney, the liver and synthesized in the pancreas. She leads Formally derived from the amino acids glycine and arginine is 95% present in skeletal muscle. Particularly preferred invention Hair treatment products contain - based on their weight - 0.01 to 15% by weight, preferably 0.025 to 12.5% by weight, more preferably 0.05 to 10 wt .-%, more preferably 0.1 to 7.5 wt .-% and in particular 0.5 to 5 wt .-% N-methyl-guanidino-acetic acid (creatine).

The compositions according to the invention can be used in addition to the above-mentioned ingredients and op Other ingredients include other substances that prevent, alleviate or cure hair loss. In particular, a content of hair root stabilizing agents is advantageous. These substances are described below:
Propecia (Finasteride) is currently the only preparation that is approved worldwide and has been proven in many studies to be effective and tolerable. Propecia causes less DHT to form from testosterone.

minoxidil is probably the oldest with or without supplementary additives proven hair restorer. For the treatment of hair loss it may only be used for external application. There are hair lotions that contain 2% -5% minoxidil, as well Gels with up to 15% minoxidil. The effectiveness decreases with the dosage to, in hair waters Minoxidil but only up to 5% proportion is soluble. In many countries, hair tonic is minoxidil content up to 2% available without prescription.

to Combating hormonal effects on The hair follicle may be used externally for spironolactone applied in the form of hair tonic and in combination with minoxidil become. Spironolactone acts as an androgen receptor blocker, ie. the binding of DHT to the hair follicles is prevented.

In summary hair treatment compositions according to the invention are preferred, the additional - based on its weight - 0.001 up to 5% by weight hair root stabilizing substances, in particular minoxidil and / or finasteride and / or ketoconazole.

By additional antidandruff active ingredients (for example climbazole, Piroctone oil amines or zinc pyrithione) will increase the amount of Shed-causing yeast specifically reduces the germ flora again reaches the normal percentage composition and the Desquamation is reduced to the physiological level. However, laboratory tests have proven that the different Species representatives of the Pityrosporum ovale do well on the Antidandruff active ingredients react. To maximize all dandruff To fight is therefore a combination of anti-dandruff agents most successful.

In summary hair treatment compositions according to the invention are preferred, the additional - based on their weight - 0.001 to 5% by weight of anti-dandruff active ingredients, in particular Piroctone oil amines (1-Hydroxy-4-methyl-6- (2,4,4-trimethyl-pentyl) -pyridine-2 (1H) -one, Compound with 2-aminoethanol, 1: 1) and / or zinc pyrithione and / or selenium sulfide and / or climbazole and / or salicylic acid or fumaric acid contain.

additionally to the care enhancers can di according to the invention Means contain further care substances. Their presence is for the achievement of the effects of the invention not absolutely necessary, but further effects, like a pleasant grip or a pleasant application feel result from the use of these care substances.

When another ingredient can the inventive Agent with particular preference one or more amino acids contain. Particularly preferred according to the invention usable amino acids are from the group glycine, Alanine, valine, leucine, isoleucine, phenylalanine, tyrosine, tryptophan, Proline, aspartic acid, glutamic acid, asparagine, Glutamine, serine, threonine, cysteine, methionine, lysine, arginine, histidine, β-alanine, 4-aminobutyric acid (GABA), betaine, L-cystine (L-Cyss), L-carnitine, L-citrulline, L-theanine, 3 ', 4'-dihydroxy-L-phenylalanine (L-dopa), 5'-hydroxy-L-tryptophan, L-homocysteine, S-methyl-L-methionine, S-allyl-L-cysteine sulfoxide (L-alliin), L-trans-4-hydroxyproline, L-5-oxoproline (L-pyroglutamic acid), L-phosphoserine, creatine, 3-methyl-L-histidine, L-ornithine, where Both the individual amino acids and mixtures are used can.

preferred Compositions according to the invention contain one or more Amino acids in narrower ranges. Here are preferred according to the invention Hair treatment preparations, characterized in that they act as Nursing material - based on its weight - 0.01 to 5 wt .-%, preferably 0.02 to 2.5 wt .-%, more preferably 0.05 to 1.5 wt .-%, more preferably 0.075 to 1 wt .-% and in particular 0.1 to 0.25 wt .-% amino acid (s), preferably from the Group glycine and / or alanine and / or valine and / or lysine and / or leucine and / or threonine.

• – Monosachhariden, insbesondere
• – D-Ribose und/oder
• – D-Xylose und/oder
• – L-Arabinose und/oder
• – O-Glucose und/oder
• – D-Mannose und/oder
• – D-Galactose und/oder
• – O-Fructose und/oder
• – Sorbose und/oder
• – L-Fucose und/oder
• – L-Rhamnose
• – Disacchariden, insbesondere
• – Saccharose und/oder
• – Maltose und/oder
• – Lactose und/oder
• – Trehalose und/oder
• – Cellobiose und/oder
• – Gentiobiose und/oder
• – Isomaltose.

As a further component, the agents according to the invention may contain at least one carbohydrate from the group of monosaccharides, disaccharides and / or oligosaccharides. Here are preferred hair treatment compositions according to the invention characterized in that they are used as care substance - based on their weight - 0.01 to 5 wt .-%, preferably 0.05 to 4.5 wt .-%, particularly preferably 0.1 to 4 wt. -%, more preferably 0.5 to 3.5 wt .-% and in particular 0.75 to 2.5 wt .-% carbohydrate (s) selected from Monosac charids, disaccharides and / or oligosaccharides, preferred carbohydrates being selected from

• - Monosaccharides, in particular
• D-ribose and / or
• - D-xylose and / or
• - L-arabinose and / or
• - O-glucose and / or
• - D-mannose and / or
• D-galactose and / or
• - O-fructose and / or
• - sorbose and / or
• - L-fucose and / or
• - L-rhamnose
• - Disaccharides, in particular
• - sucrose and / or
• - maltose and / or
• - lactose and / or
• - Trehalose and / or
• Cellobiose and / or
• - Gentiobiose and / or
• - Isomaltose.

• – 0,005 bis 0,015 Gew.-% Coffein und 0,75 bis 1,5 Gew.-% Glucosemonohydrat,
• – 0,005 bis 0,015 Gew.-% Coffein und 0,75 bis 1,5 Gew.-% Saccharose,
• – 0,005 bis 0,015 Gew.-% Coffein und 0,75 bis 1,5 Gew.-% Fructose.

Particularly preferred agents according to the invention contain based on their weight

• 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of glucose monohydrate,
• 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of sucrose,
• 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of fructose.

As already mentioned, contain preferred inventive Middle (one) amino acid (s).

Particularly according to the invention preferably usable amino acids are from the group Glycine, alanine, valine, leucine, isoleucine, phenylalanine, tyrosine, Tryptophan, proline, aspartic acid, glutamic acid, Asparagine, glutamine, serine, threonine, cysteine, methionine, lysine, Arginine, histidine, ß-alanine, 4-aminobutyric acid (GABA), Betaine, L-cystine (L-Cyss), L-carnitine, L-citrulline, L-theanine, 3 ', 4'-dihydroxy-L-phenylalanine (L-dopa), 5'-hydroxy-L-tryptophan, L-homocysteine, S-methyl-L-methionine, S-allyl-L-cysteine sulfoxide (L-alliin), L-trans-4-hydroxyproline, L-5-oxoproline (L-pyroglutamic acid), L-phosphoserine, creatine, 3-methyl-L-histidine, L-ornithine, where both the individual amino acids as well as mixtures can be used.

preferred Compositions according to the invention contain one or more Amino acids in narrower ranges. Here are preferred according to the invention Cosmetic agents, characterized in that they additionally - 0.05 to 5 wt .-%, preferably 0.1 to 2.5 wt .-%, more preferably 0.15 to 1% by weight and in particular 0.2 to 0.5% by weight of amino acid (s), preferably (an) amino acid (s) from the group glycine and / or Alanain and / or valine and / or lysine and / or leucine and / or threonine contain.

• – 0,005 bis 0,015 Gew.-% Coffein und 0,75 bis 1,5 Gew.-% Glucosemonohydrat und 0,1 bis 0,25 Gew.-% Glycin,
• – 0,005 bis 0,015 Gew.-% Coffein und 0,75 bis 1,5 Gew.-% Saccharose und 0,1 bis 0,25 Gew.-% Glycin,
• – 0,005 bis 0,015 Gew.-% Coffein und 0,75 bis 1,5 Gew.-% Fructose und 0,1 bis 0,25 Gew.-% Glycin,
• – 0,005 bis 0,015 Gew.-% Coffein und 0,75 bis 1,5 Gew.-% Glucosemonohydrat und 0,1 bis 0,25 Gew.-% Alanin,
• – 0,005 bis 0,015 Gew.-% Coffein und 0,75 bis 1,5 Gew.-% Saccharose und 0,1 bis 0,25 Gew.-% Alanin,
• – 0,005 bis 0,015 Gew.-% Coffein und 0,75 bis 1,5 Gew.-% Fructose und 0,1 bis 0,25 Gew.-% Alanin,
• – 0,005 bis 0,015 Gew.-% Coffein und 0,75 bis 1,5 Gew.-% Glucosemonohydrat und 0,1 bis 0,25 Gew.-% Valin,
• – 0,005 bis 0,015 Gew.-% Coffein und 0,75 bis 1,5 Gew.-% Saccharose und 0,1 bis 0,25 Gew.-% Valin,
• – 0,005 bis 0,015 Gew.-% Coffein und 0,75 bis 1,5 Gew.-% Fructose und 0,1 bis 0,25 Gew.-% Valin.

Particularly preferred agents according to the invention contain based on their weight

• 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of glucose monohydrate and 0.1 to 0.25% by weight of glycine,
• 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of sucrose and 0.1 to 0.25% by weight of glycine,
• 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of fructose and 0.1 to 0.25% by weight of glycine,
• 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of glucose monohydrate and 0.1 to 0.25% by weight of alanine,
• 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of sucrose and 0.1 to 0.25% by weight of alanine,
• 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of fructose and 0.1 to 0.25% by weight of alanine,
• 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of glucose monohydrate and 0.1 to 0.25% by weight of valine,
• 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of sucrose and 0.1 to 0.25% by weight of valine,
• 0.005 to 0.015% by weight of caffeine and 0.75 to 1.5% by weight of fructose and 0.1 to 0.25% by weight of valine.

A particularly preferred group of ingredients are the silicones represents.

• (i) Polyalkylsiloxanen, Polyarylsiloxanen, Polyalkylarylsiloxanen, die flüchtig oder nicht flüchtig, geradkettig, verzweigt oder cyclisch, vernetzt oder nicht vernetzt sind;
• (ii) Polysiloxanen, die in ihrer allgemeinen Struktur eine oder mehrere organofunktionelle Gruppen enthalten, die ausgewählt sind unter: a) substituierten oder unsubstituierten aminierten Gruppen; b) (per)fluorierten Gruppen; c) Thiolgruppen; d) Carboxylatgruppen; e) hydroxylierten Gruppen; f) alkoxylierten Gruppen; g) Acyloxyalkylgruppen; h) amphoteren Gruppen; i) Bisulfitgruppen; j) Hydroxyacylaminogruppen; k) Carboxygruppen; l) Sulfonsäuregruppen; und m) Sulfat- oder Thiosulfatgruppen;
• (iii) linearen Polysiloxan(A)-Polyoxyalkylen(B)-Blockcopoylmeren vom Typ (A-B)_n mit n > 3;
• (iv) gepfropften Siliconpolymeren mit nicht siliconhaltigem, organischen Grundgerüst, die aus einer organischen Hauptkette bestehen, welche aus organischen Monomeren gebildet wird, die kein Silicon enthalten, auf die in der Kette sowie gegebenenfalls an mindestens einem Kettenende mindestens ein Polysiloxanmakromer gepfropft wurde;
• (v) gepfropften Siliconpolymeren mit Polysiloxan-Grundgerüst, auf das nicht siliconhaltige, organische Monomere gepfropft wurden, die eine Polysiloxan-Hauptkette aufweisen, auf die in der Kette sowie gegebenenfalls an mindestens einem ihrer Enden mindestens ein organisches Makromer gepfropft wurde, das kein Silicon enthält;

oder deren Gemischen.Preferred agents according to the invention are characterized in that they contain at least one silicone, preferably contain a silicone selected from:

• (i) polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes which are volatile or nonvolatile, straight chain, branched or cyclic, crosslinked or uncrosslinked;
• (ii) polysiloxanes containing in their general structure one or more organofunctional groups selected from: a) substituted or unsubstituted aminated groups; b) (per) fluorinated groups; c) thiol groups; d) carboxylate groups; e) hydroxylated groups; f) alkoxylated groups; g) acyloxyalkyl groups; h) amphoteric groups; i) bisulfite groups; j) hydroxyacylamino groups; k) carboxy groups; l) sulfonic acid groups; and m) sulfate or thiosulfate groups;
• (iii) linear polysiloxane (A) polyoxyalkylene (B) block copolymers of the (AB) _{n type} with n>3;
• (iv) grafted silicone polymers having a non-silicone organic backbone consisting of an organic backbone formed from organic monomers containing no silicone grafted with at least one polysiloxane macromer in the chain and optionally at least one chain end;
• (v) grafted polysiloxane backbone silicone polymers having grafted thereto non-silicone organic monomers having a polysiloxane backbone to which at least one organic macromer not containing silicone has been grafted in the chain, and optionally at least at one of its ends ;

or their mixtures.

Particularly according to the invention preferred agents preferably contain the silicone (s) in amounts of from 0.1 to 10% by weight, preferably from 0.25 to 7% by weight and in particular from 0.5 to 5 wt .-%, each based on the total Medium.

preferred Silicones are described below.

Particularly preferred agents according to the invention are characterized in that they contain at least one silicone of the formula Si-I (CH ₃ ) ₃ Si- [O-Si (CH ₃ ) ₂ ] _x -O-Si (CH ₃ ) ₃ (Si-I), in which x is a number from 0 to 100, preferably from 0 to 50, more preferably from 0 to 20 and in particular 0 to 10.

These silicones are called DIMETHICONE according to the INCI nomenclature. In the context of the present invention, as the silicone of the formula Si-1, the compounds are preferably:
(CH ₃ ) ₃ Si-O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si-O- (CH ₃ ) ₂ Si-O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₂ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₃ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₄ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₅ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₆ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₇ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₈ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₉ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₁₀ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₁₁ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₁₂ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₁₃ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₁₄ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₁₅ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₁₆ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₁₇ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₁₈ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₁₉ -O-Si (CH ₃ ) ₃
(CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₂₀ -O-Si (CH ₃ ) ₃
where (CH ₃ ) ₃ Si-O-Si (CH ₃ ) ₃ , (CH ₃ ) ₃ Si-O- (CH ₃ ) ₂ Si-O-Si (CH ₃ ) ₃ and / or (CH ₃ ) ₃ Si [O- (CH ₃ ) ₂ Si] ₂ -O-Si (CH ₃ ) _{3 are} particularly preferred.

Of course can also mixtures of o. g. Silicones in the invention Be included means.

Preferred silicones which can be used according to the invention have viscosities of from 0.2 to 2 mm ² s ^-1 at 20 ° C., silicones having viscosities of from 0.5 to 1 mm ² s ^{-1 being} particularly preferred.

Particularly preferred agents according to the invention contain one or more amino-functional silicones. Such silicones may, for. B. by the formula M (R _a Q _b SiO _{(4-ab) / 2) x} (R _c SiO _{(4-c) / 2) y} M wherein R in the above formula is a hydrocarbon or a hydrocarbon group of 1 to about 6 carbon atoms, Q is a polar group of the general formula -R ¹ HZ wherein R ^{1 is} a divalent linking group attached to hydrogen and the group Z is an organic, amino-functional radical containing at least one amino-functional group, carbon and hydrogen atoms, carbon, hydrogen and oxygen atoms or carbon, hydrogen and nitrogen atoms; "a" assumes values in the range of about 0 to about 2, "b" assumes values in the range of about 1 to about 3, "a" + "b" is less than or equal to 3, and "c" is a number in the range from about 1 to about 3, and x is a number ranging from 1 to about 2,000, preferably from about 3 to about 50, and most preferably from about 3 to about 25, and y is a number ranging from about 20 to about 10,000 , preferably from about 125 to about 10,000, and most preferably from about 150 to about 1,000, and M is a suitable silicone end group as known in the art, preferably trimethylsiloxy. Non-limiting examples of the groups represented by R include alkyl groups such as methyl, ethyl, propyl, isopropyl, isopropyl, butyl, isobutyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; preferably R is an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R is methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , -OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ ) ₃ CC (O) OCH ₂ CH ₂ -, C ₆ H ₄ C ₆ H ₄ -, -C ₆ H ₄ CH ₂ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ -.

Z is an organic, amino-functional radical containing at least one functional amino group. A possible formula for Z is NH (CH ₂ ) _z NH ₂ , wherein z is 1 or more. Another possible formula for Z is -NH (CH ₂ ) _z (CH ₂ ) _zz NH, wherein both z and zz are independently 1 or more, which structure includes diamino ring structures, such as piperazinyl. Z is most preferably a -NHCH ₂ CH ₂ NH ₂ radical. Another possible formula for Z is -N (CH ₂ ) (CH ₂ ) _zz NX ₂ or -NX ₂ , wherein each X of X _{2 is} independently selected from the group consisting of hydrogen and alkyl groups of 1 to 12 carbon atoms, and zz 0 is.

Q is most preferably a polar, amine functional group of the formula -CH ₂ CH ₂ CH ₂ NHCH ₂ CH ₂ NH ₂ . In the formulas, "a" assumes values in the range of about 0 to about 2, "b" assumes values in the range of about 2 to about 3, "a" + "b" is less than or equal to 3, and "c "is a number in the range of about 1 to about 3. The molar ratio of the R _a Q _b SiO _{(4-ab) / 2} units to the R _c SiO _{(4-c) / 2} units is in the range of about 1: 2 to 1:65, preferably from about 1: 5 to about 1:65, and most preferably from about 1:15 to about 1:20. When one or more silicones of the above formula are used, the various variable substituents in the above formula may be different for the various silicone components present in the silicone blend.

Preferred agents according to the invention are characterized in that they contain an amino-functional Si Formula of the formula (Si-II) R _'a G _3-a -Si (OSiG _{2) n} - (OSiG _b R' _{2-b) m} -O-SiG _3-a -R _'a (Si-II), contain, in which means:

• G is -H, a phenyl group, -OH, -O-CH ₃ , -CH ₃ , -O-CH ₂ CH ₃ , -CH ₂ CH ₃ , -O-CH ₂ CH ₂ CH ₃ , -CH ₂ CH ₂ CH ₃ , -O-CH (CH ₃ ) ₂ , -CH (CH ₃ ) ₂ , -O-CH ₂ CH ₂ CH ₂ CH ₃ , -CH ₂ CH ₂ CH ₂ CH ₃ , -O-CH ₂ CH (CH ₃ ) ₂ , -CH ₂ CH (CH ₃ ) ₂ , -O-CH (CH ₃ ) CH ₂ CH ₃ , -CH (CH ₃ ) CH ₂ CH ₃ , -OC (CH ₃ ) ₃ , -C (CH ₃ ) ₃
• - a stands for a number between 0 and 3, in particular 0;
• - b is a number between 0 and 1, in particular 1,
• - m and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, wherein n preferably values from 0 to 1999 and in particular from 49 to 149 and m are preferably values from 1 to 2000, in particular from 1 until 10,
• R 'is a monovalent radical selected from • -QN (R'') - CH ₂ -CH ₂ -N (R'') ₂ • -QN (R'') ₂ • -QN ⁺ H (R'') ₂ A ^- • -QN ⁺ H ₂ (R '') A ^- • -QN (R '') - CH ₂ -CH ₂ -N ⁺ R''H ₂ A ^- , where each Q is a chemical bond, CH ₂ -, -CH ₂ -CH ₂ -, -CH ₂ CH ₂ CH-, -C (CH ₃ ) ₂ -, -CH ₂ CH ₂ CH ₂ CH ₂ -, -CH ₂ C (CH ₃ ) ₂ - , -CH (CH ₃ ) CH ₂ CH ₂ -, R "is identical or different radicals from the group -H, -phenyl, -benzyl, -CH ₂ -CH (CH ₃ ) Ph, the C _1-20 -Alkyl radicals, preferably -CH ₃ , -CH ₂ CH ₃ , -CH ₂ CH ₂ CH ₃ , -CH (CH ₃ ) ₂ , -CH ₂ CH ₂ CH ₂ H ₃ , -CH ₂ CH (CH ₃ ) ₂ , -CH (CH ₃ ) CH ₂ CH ₃ , -C (CH ₃ ) ₃ , and A represents an anion, which is preferably selected from chloride, bromide, iodide or methosulfate.

enthalten, worin m und n Zahlen sind, deren Summe (m + n) zwischen 1 und 2000, vorzugsweise zwischen 50 und 150 beträgt, wobei n vorzugsweise Werte von 0 bis 1999 und insbesondere von 49 bis 149 und m vorzugsweise Werte von 1 bis 2000, insbesondere von 1 bis 10 annimmt.Particularly preferred agents according to the invention are characterized in that they contain at least one amino-functional silicone of the formula (Si-IIa)

in which m and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n preferably values of 0 to 1999 and in particular of 49 to 149 and m preferably values of 1 to 2000 , in particular from 1 to 10 assumes.

These Silicones are classified as trimethylsilylamodimethicones according to the INCI declaration designated.

enthalten, worin R für -OH, -O-CH₃ oder eine -CH₃-Gruppe steht und m, n1 und n2 Zahlen sind, deren Summe (m + n1 + n2) zwischen 1 und 2000, vorzugsweise zwischen 50 und 150 beträgt, wobei die Summe (n1 + n2) vorzugsweise Werte von 0 bis 1999 und insbesondere von 49 bis 149 und m vorzugsweise Werte von 1 bis 2000, insbesondere von 1 bis 10 annimmt.Also particularly preferred are agents according to the invention which are an amino-functional silicone of the formula (Si-IIb)

in which R is -OH, -O-CH ₃ or a -CH ₃ group and m, n1 and n2 are numbers whose sum (m + n1 + n2) is between 1 and 2,000, preferably between 50 and 150 , where the sum (n1 + n2) preferably assumes values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10.

These Silicones are called amodimethicones according to the INCI declaration.

Independently of which amino-functional silicones are used are agents according to the invention which are an amino-functional Silicone contain its amine number above 0.25 meq / g, preferably above 0.3 meq / g and in particular above 0.4 meq / g. The amine number stands for the milliequivalents Amine per gram of amino-functional silicone. It can be done by titration determined and also in the unit mg KOH / g.

According to the invention preferred Agents are characterized by having 0.01, based on their weight to 10% by weight, preferably 0.1 to 8% by weight, more preferably 0.25 to 7.5% by weight and in particular 0.5 to 5% by weight of amino-functional (s) Silicone (s) included.

enthalten, in der x für eine Zahl von 3 bis 200, vorzugsweise von 3 bis 10, weiter bevorzugt von 30 bis 7 und insbesondere 3, 4, 5 oder 6, steht.The INCI CYCLOMETHICONE designated cyclic dimethicones are inventively used with preference. Here, agents according to the invention are preferred which contain at least one silicone of the formula Si-III

in which x is a number from 3 to 200, preferably from 3 to 10, more preferably from 30 to 7 and in particular 3, 4, 5 or 6.

The silicones described above have a backbone, which is composed of -Si-O-Si units. Of course These Si-O-Si units can also be replaced by carbon chains be interrupted. Corresponding molecules are by chain extension reactions accessible and preferably come in the form of silicone-in-water emulsions for use.

Agents which are likewise preferred according to the invention are characterized in that they contain at least one silicone of the formula Si-IV R ₃ Si [O-SiR ₂ ] _x - (CH ₂ ) _n - [O-SiR ₂ ] _y -O-SiR ₃ (Si-IV), in which R is identical or different radicals from the group -H, -phenyl, -benzyl, -CH ₂ -CH (CH ₃ ) Ph, the C _1-20 -alkyl radicals, preferably -CH ₃ , -CH ₂ CH ₃ , -CH ₂ CH ₂ CH ₃ , -CH (CH ₃ ) ₂ , -CH ₂ CH ₂ CH ₂ H ₃ , -CH ₂ CH (CH ₃ ) ₂ , -CH (CH ₃ ) CH ₂ CH ₃ , - C (CH ₃ ) ₃ , x and y are a number from 0 to 200, preferably from 0 to 10, more preferably from 0 to 7 and especially 0, 1, 2, 3, 4, 5 or 6, stand and n is a number from 0 to 10, preferably from 1 to 8 and in particular from 2, 3, 4, 5, 6.

With The silicones are preferably water-soluble. According to the invention preferred Means are characterized by being at least contain a water-soluble silicone.

From aesthetic Reasons become "clear" products of consumers often preferred. Hair treatment agents preferred according to the invention are therefore characterized by being transparent or translucent.

Under transparent or translucent is within the scope of the present invention understood a composition having an NTU value of less than 100 having. The NTU value (Nephelometric Turbidity Unit, Nephelometric Turbidity value; NTU) is one used in water treatment Unit for turbidity measurements in liquids. It is the unit of a measured with a calibrated nephelometer Turbidity of a liquid.

Farther may in a preferred embodiment of the invention an agent according to the invention also UV filter (I) contain. The invention to be used UV filters are subject to structural and physical considerations Features no general restrictions. Much more All UV filters that can be used in the cosmetics sector are suitable Absorption maximum in UVA (315-400 nm) -, in UVB (280-315 nm) - or in the UVC (<280 nm) range. UV filter with an absorption maximum in the UVB range, especially in the range of about 280 to about 300 nm, are particularly prefers. The UV filters used according to the invention For example, they can be selected from substituted ones Benzophenones, p-aminobenzoic acid esters, diphenylacrylic acid esters, Cinnamic acid esters, salicylic acid esters, benzimidazoles and o-aminobenzoic acid esters.

Examples of UV filters which can be used according to the invention are 4-aminobenzoic acid, N, N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline-methylsulfate, 3,3,5-trimethyl-cyclohexylsalicylate (homosalates), 2-hydroxy-4-methoxy-benzophenone (benzophenone-3; Uvinul ^® M 40, Uvasorb MET ^{®, ®} Neo Heliopan BB, Eusolex 4360), 2-phenylbenzimidazole-5-sulfonic acid and potassium, sodium and triethanolamine salts (phenylbenzimidazole sulfonic acid; Parsol ^® HS; Neo Heliopan Hydro ^®), 3,3 '- (1,4-phenylenedimethylene) -bis (7,7-dimethyl-2-oxo-bicyclo [2.2.1] hept-1-yl methane-sulfonic acid) and salts thereof, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) Methoxydibenzoylmethane -propane-1,3-dione (butyl; Parsol ^® 1789 Eusolex 9020), α- ( 2-oxoborn-3-ylidene) toluene-4-sulfonic acid and salts thereof, ethoxylated 4-aminobenzoic acid ethyl ester (PEG-25 PABA; Uvinul ^® P 25), 4-dimethylaminobenzoic acid 2-ethylhexyl (octyl dimethyl PABA; Uvasorb ^® DMO , Escalol ^® 507, Eusolex ^® 6007), salicylic acid 2-ethylhexyl ester (Octyl salicylate; Escalol ^® 587, Neo Heliopan OS ^®, Uvinul ^® 018), 4-methoxycinnamic acid isopentyl (isoamyl p-methoxycinnamate; Neo Heliopan ^® E 1000), 4-Metho xyzimtsäure-2-ethylhexyl ester (Octyl Methoxycinnamate; Parsol ^® MCX, Escalol ^® 557, Neo Heliopan ^® AV), 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its sodium salt (Benzophenone-4; Uvinul ^® MS 40; Uvasorb ^® S5), 3- (4'-methylbenzylidene) -D, L-camphor (4-methylbenzylidene camphor; Parsol ^® 5000, Eusolex ^® 6300), 3-benzylidene camphor (3-benzylidene camphor), 4-isopropylbenzyl, 2 , 4,6-Trianilino- (p-carbo-2'-ethylhexyl-1'-oxi) -1,3,5-triazine, 3-imidazol-4-yl-acrylic acid and its ethyl ester, polymers of N - {( 2 and 4) - [2-oxoborn-3-ylidenemethyl] benzyl} acrylamide, 2,4-dihydroxy (benzophenone-1; Uvasorb ^® 20 H, Uvinul ^® 400), 1,1'-Diphenylacrylonitrilsäure-2-ethylhexyl ester (Octocrylene; Eusolex OCR, Neo Heliopan ^® Type 303, Uvinul ^® N 539 SG), o-aminobenzoic acid menthyl ester (menthyl Anthranilate; Neo Heliopan MA ^®), 2,2 ', 4,4'-tetrahydroxy benzophenone (benzophenone-2; Uvinul ^® D-50), 2,2'-dihydroxy-4,4'-dimethoxybenzophenone (Benzophenone-6), 2,2'-Dihydr oxy-4,4'-dimethoxybenzophenone-5-sodium sulfonate and 2-cyano-3,3-diphenylacrylic acid 2'-ethylhexyl ester. Preference is given to 4-aminobenzoic acid, N, N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline methylsulfate, 3,3,5-trimethylcyclohexyl salicylate, 2-hydroxy-4-methoxybenzophenone , 2-phenylbenzimidazole-5-sulfonic acid and its potassium, sodium and triethanolamine salts, 3,3 '- (1,4-phenylenedimethylene) -bis (7,7-dimethyl-2-oxo-bicyclo- [2.2.1] hept-1-yl-methanesulfonic acid) and its salts, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) -propane-1,3-dione, α- (2-oxoborn-3-yl) yliden) -toluene-4-sulfonic acid and its salts, ethoxylated 4-aminobenzoic acid ethyl ester, 2-ethylhexyl 4-dimethylaminobenzoate, 2-ethylhexyl salicylate, isopentyl 4-methoxycinnamate, 2-ethylhexyl 4-methoxycinnamate, 2 Hydroxy-4-methoxybenzophenone-5-sulfonic acid and its sodium salt, 3- (4'-methylbenzylidene) -D, L-camphor, 3-benzylidene-camphor, 4-isopropylbenzylsalicylate, 2,4,6-trianilino- (p-) carbo-2'-ethylhexyl-1'-oxi) -1,3,5-triazine, 3-imidazol-4-yl-acrylic acid and its ethyl ester, polymers of N - {(2 and 4) - [2- oxoborn-3-ylidenemethyl] benzyl} acrylamide. Very particularly preferred according to the invention are 2-hydroxy-4-methoxybenzophenone, 2-phenylbenzimidazole-5-sulfonic acid and its potassium, sodium and triethanolamine salts, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) Propan-1,3-dione, 4-methoxycinnamic acid 2-ethylhexyl ester and 3- (4'-methylbenzylidene) -D, L-camphor.

Prefers are those UV filters whose molar extinction coefficient at the absorption maximum above 15,000, especially above 20,000.

Farther was found to be structurally similar UV filters in many cases, the water-insoluble Compound within the scope of the teaching of the invention the higher effect over such water-soluble Compounds that are distinguished from it by one or more additionally differentiate ionic groups. As water insoluble Within the scope of the invention, UV filters are to be understood which at 20 ° C to not more than 1 wt .-%, in particular to not more than 0.1% by weight, dissolve in water. Farther These compounds should be used in usual cosmetic oil components at room temperature to at least 0.1, in particular at least 1 wt .-% be soluble). The use of water-insoluble UV filter can therefore be preferred according to the invention be.

According to one Another embodiment of the invention are those UV filters preferably a cationic group, in particular a quaternary Ammonium group.

These UV filters have the general structure U-Q.

• – substituierte Benzophenone,
• – p-Aminobenzoesäureester,
• – Diphenylacrylsäureester,
• – Zimtsäureester,
• – Salicylsäureester,
• – Benzimidazole und
• – o-Aminobenzoesäureester.

The structural part U stands for a UV-absorbing group. This group can in principle be derived from the known UV filters which can be used in the cosmetics sector, in which a group, generally a hydrogen atom, of the UV filter is replaced by a cationic group Q, in particular having a quaternary amino function , Compounds from which the structural part U can derive are, for example

• Substituted benzophenones,
• P-aminobenzoic acid ester,
• - diphenylacrylic acid ester,
• - cinnamic acid ester,
• Salicylic acid ester,
• Benzimidazoles and
• O-aminobenzoic acid ester.

structural parts U, derived from cinnamic acid amide or N, N-dimethylamino-benzoic acid amide derive, are preferred according to the invention.

The structural parts U can in principle be chosen so that the absorption maximum of the UV filters can be both in the UVA (315-400 nm) and in the UVB (280-315 nm) or in the UVC (<280 nm) range , UV filters with an absorption maximum in the UVB range, in particular in the range from about 280 to about 300 nm, are particularly preferred.

Farther becomes the structural part U, also depending on structural part Q, preferably chosen so that the molar extinction coefficient of the UV filter at the absorption maximum above 15,000, in particular above from 20000, lies.

Of the Structural part Q preferably contains as a cationic group a quaternary ammonium group. This quaternary ammonium group can in principle be connected directly to the structural part U, so the structural part U is one of the four substituents of the represents a positively charged nitrogen atom. However, it is preferred one of the four substituents on the positively charged nitrogen atom a group, in particular an alkylene group having 2 to 6 carbon atoms, as the connection between the structural part U and the positively charged Nitrogen atom acts.

Advantageously, the group Q has the general structure - (CH ₂ ) _x -N ⁺ R ¹ R ² R ³ X ^- , in which x is an integer from 1 to 4, R ¹ and R ² independently of one another are C _{1 -4} alkyl groups, R ³ is a C _1-22 alkyl group or a benzyl group and X ^{- is} a physiologically acceptable anion. In the context of this general structure, x preferably represents the number 3, R ¹ and R ² each represent a methyl group and R ^{3 represents} either a methyl group or a saturated or unsaturated, linear or branched hydrocarbon chain having 8 to 22, in particular 10 to 18, carbon atoms.

physiological Compatible anions are, for example, inorganic anions such as halides, especially chloride, bromide and fluoride, sulfate ions and phosphate ions and organic anions such as lactate, citrate, acetate, Tartrate, methosulfate and tosylate.

Two preferred UV filters with cationic groups are the commercially available compounds cinnamic acid trimethyl ammonium chloride (Incroquat ^® UV-283) and dodecyl tosylate (Escalol ^® HP 610).

Of course includes the teaching of the invention also the use of a combination of multiple UV filters. As part of In this embodiment, the combination is at least one water-insoluble UV filter with at least one UV filter preferred with a cationic group.

The UV filters (I) are customary in the compositions according to the invention in amounts of 0.1-5% by weight, based on the total agent, contain. Levels of 0.4-2.5 wt .-% are preferred.

The compositions of the invention may further contain a 2-pyrrolidinone-5-carboxylic acid and its derivatives (J). Preference is given to the sodium, potassium, calcium, magnesium or ammonium salts in which the ammonium ion carries, in addition to hydrogen, one to three C ₁ - to C ₄ -alkyl groups. The sodium salt is most preferred. The amounts used in the compositions according to the invention are preferably 0.05 to 10 wt .-%, based on the total agent, particularly preferably 0.1 to 5, and in particular 0.1 to 3 wt .-%.

additionally It may prove advantageous if in the inventive Agents contain penetration aids and / or swelling agents (M) are. These include, for example, urea and Urea derivatives, guanidine and its derivatives, arginine and its Derivatives, water glass, imidazole and its derivatives, histidine and its derivatives, benzyl alcohol, glycerol, glycol and glycol ether, Propylene glycol and propylene glycol ether, for example propylene glycol monoethyl ether, Carbonates, bicarbonates, diols and triols, and in particular 1,2-diols and 1,3-diols such as 1,2-propanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-dodecanediol, 1,3-propanediol, 1,6-hexanediol, 1,5-pentanediol, 1,4-butanediol.

Advantageous For the purposes of the invention may additionally short-chain Carboxylic acids (N) support the active ingredient complex (A). Among short-chain carboxylic acids and their derivatives in the For the purposes of the invention, carboxylic acids are understood which saturated or unsaturated and / or straight-chain or branched or cyclic and / or aromatic and / or heterocyclic may be and have a molecular weight less than 750. For the purposes of the invention, preference may be given to saturated or unsaturated straight-chain or branched carboxylic acids with a chain length of 1 to 16 C atoms in the chain be particularly preferred are those with a chain length from 1 to 12 C atoms in the chain.

The short-chain carboxylic acids according to the invention may contain one, two, three or more carboxy groups pen. Preferred within the meaning of the invention are carboxylic acids having a plurality of carboxy groups, in particular di- and tricarboxylic acids. The carboxy groups may be wholly or partly present as esters, acid anhydride, lactone, amide, imidic acid, lactam, lactim, dicarboximide, carbohydrazide, hydrazone, hydroxam, hydroxime, amidine, amidoxime, nitrile, phosphonic or phosphate ester. The carboxylic acids used according to the invention may of course be substituted along the carbon chain or the ring skeleton. The substituents of the carboxylic acids used according to the invention include, for example, C 1 -C 8 -alkyl, C 2 -C 8 -alkenyl, aryl, aralkyl and aralkenyl, hydroxymethyl, C 2 -C 8 -hydroxyalkyl, C 2 -C 8 -hydroxyalkenyl , Aminomethyl, C 2 -C 8 -aminoalkyl, cyano, formyl, oxo, thioxo, hydroxy, mercapto, amino, carboxy or imino groups. Preferred substituents are C 1 -C 8 alkyl, hydroxymethyl, hydroxy, amino and carboxy groups. Particular preference is given to substituents in the ⎕-position. Very particularly preferred substituents are hydroxy, alkoxy and amino groups, where the amino function may optionally be further substituted by alkyl, aryl, aralkyl and / or alkenyl radicals. Furthermore, preferred carboxylic acid derivatives are the phosphonic and phosphate esters.

• – Anlagerungsprodukte von 4 bis 30 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare Fettalkohole mit 8 bis 22 C-Atomen, an Fettsäuren mit 12 bis 22 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – C₁₂-C₂₂-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Polyole mit 3 bis 6 Kohlenstoffatomen, insbesondere an Glycerin,
• – Ethylenoxid- und Polyglycerin-Anlagerungsprodukte an Methylglucosid-Fettsäureester, Fettsäurealkanolamide und Fettsäureglucamide,
• – C₈-C₂₂-Alkylmono- und -oligoglycoside und deren ethoxylierte Analoga, wobei Oligomerisierungsgrade von 1,1 bis 5, insbesondere 1,2 bis 2,0, und Glucose als Zuckerkomponente bevorzugt sind,
• – Gemische aus Alkyl-(oligo)-glucosiden und Fettalkoholen zum Beispiel das im Handel erhältliche Produkt Montanov^®68,
• – Anlagerungsprodukte von 5 bis 60 Mol Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl,
• – Partialester von Polyolen mit 3-6 Kohlenstoffatomen mit gesättigten Fettsäuren mit 8 bis 22 C-Atomen,
• – Sterine. Als Sterine wird eine Gruppe von Steroiden verstanden, die am C-Atom 3 des Steroid-Gerüstes eine Hydroxylgruppe tragen und sowohl aus tierischem Gewebe (Zoosterine) wie auch aus pflanzlichen Fetten (Phytosterine) isoliert werden. Beispiele für Zoosterine sind das Cholesterin und das Lanosterin. Beispiele geeigneter Phytosterine sind Ergosterin, Stigmasterin und Sitosterin. Auch aus Pilzen und Hefen werden Sterine, die sogenannten Mykosterine, isoliert.
• – Phospholipide. Hierunter werden vor allem die Glucose-Phospolipide, die z. B. als Lecithine bzw. Phospahtidylcholine aus z. B. Eidotter oder Pflanzensamen (z. B. Sojabohnen) gewonnen werden, verstanden.
• – Fettsäureester von Zuckern und Zuckeralkoholen, wie Sorbit,
• – Polyglycerine und Polyglycerinderivate wie beispielsweise Polyglycerinpoly-12-hydroxystearat (Handelsprodukt Dehymuls^® PGPH),
• – Lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen und deren Na-, K-, Ammonium-, Ca-, Mg- und Zn-Salze.

In a further preferred embodiment, the agents according to the invention may contain emulsifiers (F). Emulsifiers effect at the phase interface the formation of water- or oil-stable adsorption layers, which protect the dispersed droplets against coalescence and thus stabilize the emulsion. Emulsifiers are therefore constructed like surfactants from a hydrophobic and a hydrophilic part of the molecule. Hydrophilic emulsifiers preferably form O / W emulsions and hydrophobic emulsifiers preferably form W / O emulsions. An emulsion is to be understood as meaning a droplet-like distribution (dispersion) of a liquid in another liquid under the expense of energy in order to create stabilizing phase interfaces by means of surfactants. The selection of these emulsifying surfactants or emulsifiers depends on the substances to be dispersed and the respective outer phase and the fineness of the emulsion. Emulsifiers which can be used according to the invention are, for example

• Addition products of from 4 to 30 mol of ethylene oxide and / or from 0 to 5 mol of propylene oxide onto linear fatty alcohols having from 8 to 22 carbon atoms, to fatty acids containing from 12 to 22 carbon atoms and to alkylphenols having from 8 to 15 carbon atoms in the alkyl group,
• C ₁₂ -C ₂₂ -fatty acid mono- and diesters of addition products of from 1 to 30 mol of ethylene oxide onto polyols having from 3 to 6 carbon atoms, in particular to glycerol,
• Ethylene oxide and polyglycerol addition products to methyl glucoside fatty acid esters, fatty acid alkanolamides and fatty acid glucamides,
• C ₈ -C ₂₂ -alkylmono- and -oligoglycosides and their ethoxylated analogues, preference being given to degrees of oligomerization of from 1.1 to 5, in particular from 1.2 to 2.0, and glucose as the sugar component,
• Glucosides mixtures of alkyl (oligo) and fatty alcohols, for example, the commercially available product ^® Montanov 68, -
• Adducts of 5 to 60 moles of ethylene oxide with castor oil and hydrogenated castor oil,
• Partial esters of polyols having 3-6 carbon atoms with saturated fatty acids having 8 to 22 C atoms,
• - sterols. Sterols are understood to mean a group of steroids which have a hydroxyl group on C-atom 3 of the steroid skeleton and are isolated both from animal tissue (zoosterols) and from vegetable fats (phytosterols). Examples of zoosterols are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. Mushrooms and yeasts are also used to isolate sterols, the so-called mycosterols.
• - Phospholipids. These include, above all, the glucose phospholipids, which are z. B. as lecithins or Phospahtidylcholine from z. Egg yolks or plant seeds (eg soybeans) are understood.
• Fatty acid esters of sugars and sugar alcohols, such as sorbitol,
• - polyglycerols and polyglycerol derivatives such as polyglycerol poly-12-hydroxystearate (commercial product Dehymuls ^® PGPH),
• - Linear and branched fatty acids with 8 to 30 carbon atoms and their Na, K, ammonium, Ca, Mg and Zn salts.

The agents according to the invention contain the emulsifiers preferably in amounts of 0.1-25 wt .-%, in particular 0.5-15 Wt .-%, based on the total agent.

Prefers can the compositions of the invention at least one nonionic emulsifier having an HLB value of 8 to 18 included. Nonionic emulsifiers with an HLB value from 10-15 can according to the invention especially be preferred.

It has furthermore proven to be advantageous if, in addition to the polymer (s) from the group of cationic and / or amphoteric polymers, further polymers (G) are contained in the agents according to the invention. In a preferred embodiment, therefore, the agents according to the invention added other polymers, both anionic and nonionic polymers have proven to be effective.

at the anionic polymers (G2) are anionic polymers, which have carboxylate and / or sulfonate groups. Examples for anionic monomers that make up such polymers can, are acrylic acid, methacrylic acid, Crotonic acid, maleic anhydride and 2-acrylamido-2-methylpropanesulfonic acid. The acidic groups can be used in whole or in part as Sodium, potassium, ammonium, mono- or triethanolammonium salt available. Preferred monomers are 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid.

When anionic polymers have proven to be particularly effective as the sole or co-monomer 2-acrylamido-2-methylpropanesulfonic acid contain, wherein the sulfonic acid group completely or partially as sodium, potassium, ammonium, mono- or triethanolammonium salt may be present.

More preferably, the homopolymer of 2-acrylamido-2-methyl propane sulfonic acid, which is available for example under the name Rheothik ^® 11-80 is commercially.

Within In this embodiment, it may be preferable to use copolymers from at least one anionic monomer and at least one nonionic Use monomer. Regarding the anionic monomers Reference is made to the substances listed above. preferred non-ionic monomers are acrylamide, methacrylamide, acrylic esters, Methacrylic acid esters, vinylpyrrolidone, vinyl ethers and vinyl esters.

Preferred anionic copolymers are acrylic acid-acrylamide copolymers and in particular polyacrylamide copolymers with sulfonic acid-containing monomers. A particularly preferred anionic copolymer consists of 70 to 55 mol% of acrylamide and 30 to 45 mol% of 2-acrylamido-2-methylpropanesulfonic acid, wherein the sulfonic acid group is wholly or partly in the form of sodium, potassium, ammonium, mono- or triethanolammonium Salt is present. This copolymer may also be crosslinked, with crosslinking agents preferably polyolefinically unsaturated compounds such as tetraallyloxyethane, allylsucrose, allylpentaerythritol and methylene-bisacrylamide are used. Such a polymer is contained in the commercial product Sepigel ^® 305 from SEPPIC. The use of this compound, which in addition to the polymer component contains a hydrocarbon mixture (C ₁₃ -C ₁₄ isoparaffin) and a nonionic emulsifier (laureth-7), has proved to be particularly advantageous within the scope of the teaching according to the invention.

Also sold under the name Simulgel ^® 600 as a compound with isohexadecane and polysorbate-80 Natriumacryloyldimethyltaurat copolymers have proved to be particularly effective according to the invention.

Likewise preferred anionic homopolymers are uncrosslinked and crosslinked polyacrylic acids. Allyl ethers of pentaerythritol, sucrose and propylene may be preferred crosslinking agents. Such compounds are for example available under the trademark Carbopol ^® commercially.

Copolymers of maleic anhydride and methyl vinyl ether, especially those with crosslinks, are also color-retaining polymers. A 1.9-decadienes crosslinked maleic acid-methyl copolymer available under the name Stabileze® ^® QM.

The agents according to the invention can be used in one further embodiment nonionogenic polymers (G4).

• – Vinylpyrrolidon/Vinylester-Copolymere, wie sie beispielsweise unter dem Warenzeichen Luviskol^® (BASF) vertrieben werden. Luviskol^® VA 64 und Luviskol^® VA 73, jeweils Vinylpyrrolidon/Vinylacetat-Copolymere, sind ebenfalls bevorzugte nichtionische Polymere.
• – Celluloseether, wie Hydroxypropylcellulose, Hydroxyethylcellulose und Methylhydroxypropylcellulose, wie sie beispielsweise unter den Warenzeichen Culminal^® und Benecel^® (AQUALON) und Natrosol^®-Typen (Hercules) vertrieben werden.
• – Stärke und deren Derivate, insbesondere Stärkeether, beispielsweise Structure^® XL (National Starch), eine multifunktionelle, salztolerante Stärke;
• – Schellack
• – Polyvinylpyrrolidone, wie sie beispielsweise unter der Bezeichnung Luviskol^® (BASF) vertrieben werden.
• – Siloxane. Diese Siloxane können sowohl wasserlöslich als auch wasserunlöslich sein. Geeignet sind sowohl flüchtige als auch nichtflüchtige Siloxane, wobei als nichtflüchtige Siloxane solche Verbindungen verstanden werden, deren Siedepunkt bei Normaldruck oberhalb von 200°C liegt. Bevorzugte Siloxane sind Polydialkylsiloxane, wie beispielsweise Polydimethylsiloxan, Polyalkylarylsiloxane, wie beispielsweise Polyphenylmethylsiloxan, ethoxylierte Polydialkylsiloxane sowie Polydialkylsiloxane, die Amin- und/oder Hydroxy-Gruppen enthalten.
• – Glycosidisch substituierte Silicone.

Suitable nonionic polymers are, for example:

• - Vinylpyrrolidone / vinyl ester copolymers, such as those sold under the trademark Luviskol ^® (BASF). Luviskol ^® VA 64 and Luviskol ^® VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are also preferred nonionic polymers.
• - cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and methylhydroxypropyl cellulose, as for example under the trademark Culminal® ^® and Benecel ^® (AQUALON) and Natrosol ^® grades (Hercules) are distributed.
• - starch and its derivatives, in particular starch, such as Structure XL ^® (National Starch), a multifunctional, salt-tolerant starch;
• - shellac
• - polyvinylpyrrolidones, as for example under the name Luviskol ^® (BASF).
• - siloxanes. These siloxanes can be both water-soluble and water-insoluble. Suitable are so probably volatile as well as non-volatile siloxanes, non-volatile siloxanes being understood to mean those compounds whose boiling point is above 200 ° C. under normal pressure. Preferred siloxanes are polydialkylsiloxanes, such as, for example, polydimethylsiloxane, polyalkylarylsiloxanes, such as, for example, polyphenylmethylsiloxane, ethoxylated polydialkylsiloxanes and polydialkylsiloxanes which contain amine and / or hydroxyl groups.
• - Glycosidically substituted silicones.

It It is also possible according to the invention that the Preparations several, especially two different polymers same Charge and / or in each case an ionic and an amphoteric and / or contain nonionic polymer.

The other polymers (G) are in the inventive Agents preferably in amounts of 0.05 to 10 wt .-%, based on the entire remedy, included. Amounts of 0.1 to 5, in particular from 0.1 to 3% by weight are particularly preferred.

One Another object of the present invention is a method for the treatment of skin and hair, in which an inventive Agents applied to the skin and / or hair, distributed and after a contact time of a few seconds up to 45 minutes with Water is rinsed out again.

One Another object of the present invention is a method for the treatment of textiles, in which an inventive Diluted or undiluted on the textiles, distributed and after a contact time of a few seconds up to Rinsed with water for 45 minutes.

In terms of preferred embodiments of the invention Method applies mutatis mutandis to the invention Means said.

• – Zugfestigkeit von keratinischen Fasern, insbesondere menschlichen Haaren;
• – Stabilisierung des Feuchtigkeitshaushaltes von keratinischen Fasern, insbesondere menschlichen Haaren;
• – Kämmbarkeit von keratinischen Fasern, insbesondere menschlichen Haaren;
• – Verzögerung des Alterungsprozesses von keratinischen Fasern, insbesondere menschlichen Haaren;
• – Restrukturierbarkeit von keratinischen Fasern, insbesondere menschlichen Haaren, während des und nach dem Dauerwellprozeß;
• – Verringerung der Elastizitätsabnahme von keratinischen Fasern, insbesondere menschlichen Haaren bei Beschädigung durch atmosphärische Einwirkungen.

Another object of the present invention is a use of hair treatment agent according to the invention for improving at least one of the properties

• Tensile strength of keratinic fibers, in particular human hair;
• Stabilization of the moisture balance of keratinic fibers, in particular human hair;
• Combability of keratinic fibers, in particular human hair;
• Delaying the aging process of keratinic fibers, in particular human hair;
• - Restrukturability of keratinic fibers, especially human hair, during and after the permanent wave process;
• - Reduction in the elasticity of keratin fibers, especially human hair when damaged by atmospheric agents.

In terms of preferred embodiments of the invention Use applies mutatis mutandis to the invention Means said.

Examples and proofs of effect

All Quantities are, unless otherwise stated, parts by weight.

I. Examples of inventive Protein hydrolysates and derivatives from the wool of chinchillas

To the known method of acidic, alkaline and / or enzymatic hydrolysis of the prior art The following hydrolyzates and derivatives were obtained from wool Chinchillas shown. All information on the concentrations in % By weight are to be understood as after the end of the active content quantities of active substance obtained. Also, the pH is that pH which after adjustment of the pH with usual Setting agents was received. The indicated pH was chosen to get the final products with as low as possible Amounts of preservatives, ideally with no preservatives, to have to offset. Furthermore, the following are listed Examples are only examples of the invention and are not for the only representable invention Products. Of course, any molecular weight in both a narrow and a broad molecular weight distribution getting produced.

Hydrolyzate 1:

mw about 800 to 1000 D, 20% by weight of active substance, pH 3 to 4, pale yellow, clear liquid with very little odor, made with the aid of the alkaline hydrolysis process

Hydrolyzate 2

mw about 2000 D, 30% by weight of active substance, pH 3 to 4, pale yellow, clear liquid with low odor, produced with the aid of the alkaline-enzymatic hydrolysis process

Hydrolyzate 3:

mw about 5000 D, 30% by weight of active substance, pH 3 to 4, pale yellow, clear liquid with very little odor, made with the help of the acidic hydrolysis process

Hydrolyzate 4:

mw about 20,000 D, 25% by weight of active substance, pH 3 to 4, yellowish, clear liquid with a slight odor, produced with the aid of the enzymatic-acidic hydrolysis process

Hydrolyzate 5:

mw about 10000 D, 25% by weight of active substance, pH 3 to 4, yellowish, clear liquid with a slight odor, produced with the help of the enzymatic hydrolysis process

Derivative 1: cationized hydrolyzate

The hydrolyzate 1 is quaternized by the methods of the prior art with a quaternizing reagent, N, N-dimethyl-N- (n-lauryl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 1 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 2: cationized hydrolyzate

The hydrolyzate 2 is quaternized according to the methods of the prior art with a quaternizing reagent, N, N-dimethyl-N- (n-cocyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 2 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 3: cationized hydrolyzate

The hydrolyzate 1 is quaternized by the prior art methods with a quaternizing reagent, N, N-dimethyl-N- (n-stearyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 1 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 4: cationized hydrolyzate

The hydrolyzate 2 is quaternized by the prior art methods with a quaternizing reagent, N, N-dimethyl-N- (n-lauryl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 2 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 5: cationized hydrolyzate

The hydrolyzate 3 is quaternized by the methods of the prior art with a quaternizing reagent, N, N-dimethyl-N- (n-lauryl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 3 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 6: anionic hydrolyzate

The Hydrolyzate 1 is prepared by the methods of the prior art by means of known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the lauric acid chloride, condensed. After that is neutralized, for example, with sodium hydroxide solution. The thus obtained anionic hydrolyzate 1 is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 7: anionic hydrolyzate

The Hydrolyzate 2 is by the methods of the prior art means known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the coconut acid chloride, condensed. After that is neutralized with potassium hydroxide, for example. The thus obtained anionic hydrolyzate 2 is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 8: anionic hydrolyzate

The Hydrolyzate 3 is by the methods of the prior art means known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the stearic acid chloride condensed. After that is neutralized, for example, with sodium hydroxide solution. The thus obtained anionic hydrolyzate 3 is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 9: anionic hydrolyzate

The Hydrolyzate 2 is by the methods of the prior art means known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the behenic acid chloride, condensed. After that is neutralized, for example, with sodium hydroxide solution. The thus obtained anionic hydrolyzate 2 is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 10: anionic hydrolyzate

The Hydrolyzate 2 is by the methods of the prior art means known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the palmitic acid chloride, condensed. After that is neutralized, for example, with sodium hydroxide solution. The thus obtained anionic hydrolyzate 2 is a pale yellow liquid. The pH is adjusted to about 3-4.

II. Examples of inventive Protein hydrolyzates and derivatives from the wool of the Angora rabbits

To the known method of acidic, alkaline and / or enzymatic hydrolysis of the prior art The following hydrolyzates and derivatives were obtained from wool Angora rabbit shown. All information on the concentrations in% by weight are to be understood as after the end of the active content quantities of active substance obtained. Also, the pH is the one pH, which after adjustment of the pH with usual Setting agents was received. The indicated pH was chosen to get the final products with as low as possible Amounts of preservatives, ideally with no preservatives, to have to offset. Furthermore, the following are listed Examples are only examples of the invention and are not for the only representable invention Products. Of course, any molecular weight in both a narrow and a broad molecular weight distribution getting produced.

Hydrolyzate 11:

mw about 800 to 1000 D, 20% by weight of active substance, pH 3 to 4, pale yellow, clear liquid with very little odor, made with the aid of the alkaline hydrolysis process

Hydrolyzate 12

mw about 2000 D, 30% by weight of active substance, pH 3 to 4, pale yellow, clear liquid with low odor, produced with the aid of the alkaline-enzymatic hydrolysis process

Hydrolyzate 13:

mw about 5000 D, 30% by weight of active substance, pH 3 to 4, pale yellow, clear liquid with very little odor, made with the help of the acidic hydrolysis process

Hydrolyzate 14:

mw about 20,000 D, 25% by weight of active substance, pH 3 to 4, yellowish, clear liquid with a slight odor, produced with the aid of the enzymatic-acidic hydrolysis process

Hydrolyzate 15:

mw about 10000 D, 25% by weight of active substance, pH 3 to 4, yellowish, clear liquid with a slight odor, produced with the help of the enzymatic hydrolysis process

Derivative 10: cationized hydrolyzate

The hydrolyzate 11 is quaternized by the methods of the prior art with a quaternizing reagent, N, N-dimethyl-N- (n-lauryl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 1 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 12: cationized hydrolyzate

The hydrolyzate 12 is quaternized by the methods of the prior art with a quaternizing reagent, N, N-dimethyl-N- (n-cocyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 2 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 13: cationized hydrolyzate

The hydrolyzate 11 is quaternized by the methods of the prior art with a quaternizing reagent, N, N-dimethyl-N- (n-stearyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 1 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 14: cationized hydrolyzate

The hydrolyzate 12 is quaternized by the methods of the prior art with a quaternizing reagent, N, N-dimethyl-N- (n-lauryl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 2 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 15: cationized hydrolyzate

The hydrolyzate 13 is quaternized by the methods of the prior art with a quaternizing reagent, N, N-dimethyl-N- (n-lauryl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 3 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 16: anionic hydrolyzate

The hydrolyzate 11 is condensed according to the methods of the prior art by means of the known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the lauric acid chloride. Following this example, with sodium hydroxide neutrali Siert. The anionic hydrolyzate 1 thus obtained is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivat 17: anionic hydrolyzate

The Hydrolyzate 12 is prepared by the methods of the prior art means known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the coconut acid chloride, condensed. After that is neutralized with potassium hydroxide, for example. The thus obtained anionic hydrolyzate 2 is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 18: anionic hydrolyzate

The Hydrolyzate 13 is prepared by the methods of the prior art means known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the stearic acid chloride condensed. After that is neutralized, for example, with sodium hydroxide solution. The thus obtained anionic hydrolyzate 3 is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 19: anionic hydrolyzate

The Hydrolyzate 12 is prepared by the methods of the prior art means known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the behenic acid chloride, condensed. After that is neutralized, for example, with sodium hydroxide solution. The thus obtained anionic hydrolyzate 2 is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 20: anionic hydrolyzate

The Hydrolyzate 12 is prepared by the methods of the prior art means known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the palmitic acid chloride, condensed. After that is neutralized, for example, with sodium hydroxide solution. The thus obtained anionic hydrolyzate 2 is a pale yellow liquid. The pH is adjusted to about 3-4.

III. Examples of inventive Protein hydrolysates and derivatives from wool of the mohair goat

To the known method of acidic, alkaline and / or enzymatic hydrolysis of the prior art The following hydrolyzates and derivatives were obtained from wool Mohair goat shown. All information on the concentrations in % By weight are to be understood as after the end of the active content quantities of active substance obtained. Also, the pH is that pH which after adjustment of the pH with usual Setting agents was received. The indicated pH was chosen to get the final products with as low as possible Amounts of preservatives, ideally with no preservatives, to have to offset. Furthermore, the following are listed Examples are only examples of the invention and are not for the only representable invention Products. Of course, any molecular weight in both a narrow and a broad molecular weight distribution getting produced.

Hydrolyzate 21:

mw about 800 to 1000 D, 20% by weight of active substance, pH 3 to 4, pale yellow, clear liquid with very little odor, made with the aid of the alkaline hydrolysis process

Hydrolyzate 22

mw about 2000 D, 30% by weight of active substance, pH 3 to 4, pale yellow, clear liquid with low odor, produced with the aid of the alkaline-enzymatic hydrolysis process

Hydrolyzate 23:

mw about 5000 D, 30% by weight of active substance, pH 3 to 4, pale yellow, clear liquid with very little odor, made with the help of the acidic hydrolysis process

Hydrolyzate 24:

mw about 20,000 D, 25% by weight of active substance, pH 3 to 4, yellowish, clear liquid with a slight odor, produced with the aid of the enzymatic-acidic hydrolysis process

Hydrolyzate 25:

mw about 10000 D, 25% by weight of active substance, pH 3 to 4, yellowish, clear liquid with a slight odor, produced with the help of the enzymatic hydrolysis process

Derivative 30: cationized hydrolyzate

Hydrolyzate 21 is quaternized by the methods of the prior art with a quaternizing reagent, N, N-dimethyl-N- (n-lauryl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 1 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 32: cationized hydrolyzate

The hydrolyzate 22 is quaternized by the methods of the prior art with a quaternizing reagent, N, N-dimethyl-N- (n-cocyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 2 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 33: cationized hydrolyzate

The hydrolyzate 21 is quaternized by the methods of the prior art with a quaternizing reagent, N, N-dimethyl-N- (n-stearyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 1 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 34: cationized hydrolyzate

The hydrolyzate 12 is quaternized by the methods of the prior art with a quaternizing reagent, N, N-dimethyl-N- (n-lauryl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 2 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 35: cationized hydrolyzate

The hydrolyzate 23 is quaternized by the prior art methods with a quaternizing reagent, N, N-dimethyl-N- (n-lauryl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halide. Such reagents can be purchased under the trade names Quab ^®, for example, from Degussa. The hydrolyzate 3 thus cationized is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 36: anionic hydrolyzate

The Hydrolyzate 21 is prepared by the methods of the prior art by means of known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the lauric acid chloride, condensed. After that is neutralized, for example, with sodium hydroxide solution. The thus obtained anionic hydrolyzate 1 is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 37: anionic hydrolyzate

The Hydrolyzate 22 is prepared by the methods of the prior art means known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the coconut acid chloride, condensed. After that is neutralized with potassium hydroxide, for example. The thus obtained anionic hydrolyzate 2 is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 38: anionic hydrolyzate

The Hydrolyzate 23 is prepared by the methods of the prior art means known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the stearic acid chloride condensed. After that is neutralized, for example, with sodium hydroxide solution. The thus obtained anionic hydrolyzate 3 is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 39: anionic hydrolyzate

The Hydrolyzate 22 is prepared by the methods of the prior art means known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the behenic acid chloride, condensed. After that is neutralized, for example, with sodium hydroxide solution. The thus obtained anionic hydrolyzate 2 is a pale yellow liquid. The pH is adjusted to about 3-4.

Derivative 40: anionic hydrolyzate

The Hydrolyzate 22 is prepared by the methods of the prior art means known Schotten-Baumann reaction with a fatty acid halide, preferably a fatty acid chloride, in this example the palmitic acid chloride, condensed. After that is neutralized, for example, with sodium hydroxide solution. The thus obtained anionic hydrolyzate 2 is a pale yellow liquid. The pH is adjusted to about 3-4.

II. Formulation Examples:

All formulation examples may, of course, be formulated with any of the previously described hydrolyzates and derivatives of the wool of the chinchillas and / or the angora rabbits and / or the mohair goat. Although in each of the following examples only one hydrolyzate or derivative is mentioned, it is possible according to the invention without any disadvantages for the stability or the effect of any hydrolyzate or derivative of the wool of the chinchillas and / or the angora rabbits and / or the mohair goat and / or other mammals with a hair density of at least 400 hairs per cm ² .

Examples

• ¹Cetylstearylalkohol + 20 EO (INCI-Bezeichnung: Ceteareth-20) (COGNIS)
• ²Trimethylhexadecylammoniumchlorid ca. 25% Aktivsubstanz (INCI-Bezeichnung: Cetrimonium Chloride) (COGNIS)
• ³N,N,N-Trimethyl-2[(methyl-1-oxo-2-propenyl)oxy]-Ethanaminiumchlorid-Homopolymer (50% Aktivsubstanz; INCI-Bezeichnung: Polyquaternium-37 (and) Propylenglycol Dicaprilate Dicaprate (and) PPG-1 Trideceth-6) (ALLIED COLLOIDS)
• ⁴Kationisiertes Weizenproteinhydrolysat ca. 31% Aktivsubstanz (INCI-Bezeichnung: Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein) (COGNIS)
• ⁵Hydroxybenzoesäuremethylester-Hydroxybenzoesäureethylester-Hydroxybenzoesäurepropylester-Hydroxybenzoesäurebutylester-Phenoxyethanol-Gemisch (ca. 28% Aktivsubstanz; INCI-Bezeichnung: Phenoxyethanol, Methylparaben, Ethylparaben, Propylparaben, Butylparaben) (NIPA)

33. Haarspülung Eumulgin^® B2 0,3 Cetyl/Stearylalkohol 3,3 Isopropylmyristat 0,5 Paraffinöl perliquidum 15 cSt. DAB 9 0,3 Dehyquart^®L 80⁶ 0,4 Derivat 1 0,5 Cosmedia Guar^® C 261 1,5 Promois^® Milk-CAQ⁸ 3,0 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Citronensäure 0,4 Phenonip 0,8 Wasser ad 100

• ⁶Bis(cocoylethyl)-hydroxyethyl-methyl-ammonium-methosulfat (ca. 76% Aktivsubstanz in Propylenglykol; INCI-Bezeichnung: Dicocoylethyl Hydroxyethylmonium Methosulfat, Propylene Glycol) (COGNIS)
• ⁷Guarhydroxypropyltrimethylammonium Chlorid; INCI-Bezeichnung: Guar Hydroxypropyl Trimonium Chloride (COGNIS)
• ⁸INCI-Bezeichnung: Cocodimonium Hydroxypropyl Hydrolyzed Casein (SEIWA KASEI)

34. Haarkur Dehyquart^® F75⁹ 4,0 Cetyl/Stearylalkohol 4,0 Paraffinöl perliquidum 15 cSt DAB 9 1,5 Dehyquart^®A-CA 4,0 Hydrolysat 1 1,0 Champagnerextrakt 2,0 Koffein 1,0 Taurin 0,5 Carnitintartrat 3,0 Salcare^®SC 96 1,5 Amisafe-LMA-60^®10 1,0 Gluadin^®W 20¹¹ 3,0 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Citronensäure 0,15 Phenonip^® 0,8 Wasser ad 100

• ⁹Fettalkohole-Methyltriethanolammoniummethylsulfatdialkylester-Gemisch (INCI-Bezeichnung: Distearoylethyl Hydroxyethylmonium Methosulfate, Cetearyl Alcohol) (COGNIS)
• ¹⁰INCI-Bezeichnung Hydroxypropyl Arginine Lauryl/Myristyl EtherHCl (Ajinomoto)
• ¹¹Weizenproteinhydrolysat (20% Aktivsubstanz in Wasser; INCI-Bezeichnung: Aqua (and) Hydrolized Wheat Protein (and) Sodium Benzoate (and) Phenoxyethanol (and) Methylparaben (and) Propylparaben) (COGNIS)

35. Haarkur Dehyquart^® L80 2,0 Cetyl/Stearylalkohol 6,0 Paraffinöl perliquidum 15 cSt DAB 9 2,0 Rewoquat^®W 75¹² 2,0 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Hydrolysat 3 0,75 Champagnerextrakt 2,0 Copherol 1200 (Vitamin E) 1,0 Cosmedia Guar^® C261 0,5 Seeigel^®305¹³ 3,5 Honeyquat^® 50¹⁴ 1,0 Gluadin^® WQ 2,5 Gluadin^®W 20 3,0 Citronensäure 0,15 Phenonip^® 0,8 Wasser ad 100

• ¹²1-Methyl-2-nortalgalkyl-3-talgfettsäureamidoethylimidazolinium-methosulfat (ca. 75% Aktivsubstanz in Propylenglykol; INCI-Bezeichnung: Quaternium-27, Propylene Glycol) (WITCO)
• ¹³Copolymer aus Acrylamid und 2-Acrylamido-2-methylpropansulfonsäure (INCI-Bezeichnung: Polyacrylamide (and) C₁₃-C₁₄ Isoparaffin (and) Laureth-7) (SEPPIC)
• ¹⁴INCI-Bezeichnung: Hydroxypropyltrimonium Honey (BROOKS)

36. Haarkur Dehyquart^® F75 0,3 Salcare^®SC 96 5,0 Gluadin^® WQ 1,5 Hydrolysat 1 0,5 Dow Corning^®200 Fluid, 5 cSt.¹⁵ 1,5 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Champagnerextrakt 0,5 Gafquat^®755N¹⁶ 1,5 Biodocarb^®17 0,02 Parfümöl 0,25 Wasser ad 100

• ¹⁵Polydimethylsiloxan (INCI-Bezeichnung: Dimethicone) (DOW CORNING)
• ¹⁶Dimethylaminoethylmethacrylat-Vinylpyrrolidon-Copolymer, mit Diethylsulfat quaterniert (19% Aktivsubstanz in Wasser; INCI-Bezeichnung: Polyquaternium-11) (GAF)
• ¹⁷3-Iod-propinyl-n-butylcarbamat (INCI-Bezeichnung: Iodopropynyl Butylcarba-mate) (MILKER & GRÜNING)

37. Haarkur Sepigel^®305 5,0 Dow Corning^®Q2-5220¹⁸ 1,5 Promois^® Milk Q¹⁹ 3,0 Hydrolysat 1 1,0 Champagnerextrakt 1,0 Polymer P1 entsprechend DE 3929173 0,6 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Genamin^®DSAC²⁰ 0,3 Phenonip^® 0,8 Parfümöl 0,25 Wasser ad 100

• ¹⁸Silicon-Glykol-Copolymer (INCI-Bezeichnung: Dimethicone Copolyol) (DOW CORNING)
• ¹⁹INCI-Bezeichnung Hydroxypropyltrimonium Hydrolyzed Casein ca. 30% Aktivsubstanz (SEIWA KASEI)
• ²⁰Dimethyldistearylammoniumchlorid (INCI-Bezeichnung: Distearyldimonium Chloride) (CLARIANT)

38. Shampoo Texapon^® NSO²¹ 40,0 Dehyton^® G²² 6,0 Derivat 7 2,5 Polymer JR 400^®23 0,5 Cetiol^® HE²⁴ 0,5 Ajidew^® NL 50²⁵ 1,0 Gluadin^® WQT²⁶ 2,5 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Champagnerextrakt 1,0 Carnitintartrat 0,5 Taurin 0,5 Koffein 0,5 Coenzym Q10 0,005 Gluadin^®W 20 0,5 Panthenol (50%) 0,3 Vitamin E 0,1 Vitamin H 0,1 Citronensäure 0,5 Natriumbenzoat 0,5 Parfüm 0,4 NaCl 0,5 Wasser ad 100

• ²¹Natriumlaurylethersulfat ca. 28% Aktivsubstanz (INCI-Bezeichnung: Sodium Laureth Sulfate) (COGNIS)
• ²²INCI-Bezeichnung: Sodium Cocoamphoacetate ca. 30% Aktivsubstanz (COGNIS)
• ²³quaternierte Hydroxyethylcellulose (INCI-Bezeichnung: Polyquaternium-10) (UNION CARBIDE)
• ²⁴Polyol-Fettsäure-Ester (INCI-Bezeichnung: PEG-7 Glyceryl Cocoate) (COGNIS)
• ²⁵Natrium-Salz der 2-Pyrrolidinon-5-carbonsäure (AJINOMOTO)
• ²⁶INCI-Bezeichnung Hydroxypropyltrimonium Hydrolyzed Wheat Protein COGNIS

39. Shampoo Texapon^® NSO 43,0 Dehyton^® K²⁷ 10,0 Plantacare^® 1200 UP²⁸ 4,0 Derivat 6 3,0 Euperlan^®PK 3000²⁹ 1,6 Arquad^®316³⁰ 0,8 Polymer JR^® 400 0,3 Gluadin^® WQ 4,0 Glucamate DOE 120³¹ 0,5 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Coenzym Q10 0,005 Coffein 0,5 Carnitintartrat 0,5 Champagnerextrakt 1,0 Natriumchlorid 0,2 Wasser ad 100

• ²⁷INCI-Bezeichnung: Cocamidopropyl Betaine ca. 30% Aktivsubstanz (COGNIS)
• ²⁸C12-C16 Fettalkoholglycosid ca. 50% Aktivsubstanz (INCI-Bezeichnung: Lauryl Glucoside) (COGNIS)
• ²⁹Flüssige Dispersion von perlglanzgebenden Substanzen und Amphotensid (ca. 62% Aktivsubstanz; CTFA-Bezeichnung: Glycol Distearate (and) Glycerin (and) Laureth-4 (and) Cocoamidopropyl Betaine) (COGNIS)
• ³⁰Tri-C₁₆-alkylmethylammoniumchlorid (AKZO)
• ³¹ethoxyliertes Methylglucosid-dioleat (CTFA-Bezeichnung: PEG-120 Methyl Glucose Dioleate) (AMERCHOL)

40. Shampoo Texapon^®N 70³² 21,0 Plantacare^® 1200 UP 8,0 Derivat 8 3,5 Gluadin^® WQ 1,5 Cutina^® EGMS³³ 0,6 Honeyquat^® 50³⁴ 2,0 Ajidew^® NL 50 2,8 Antil^® 141³⁵ 1,3 Champagnerextrakt 0,5 Carnitin 0,25 Weinsäure 0,25 Coenzym Q 10 0,005 Koffein 0,5 Panthenol 0,5 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Natriumchlorid 0,2 Magnesiumhydroxid ad pH 4,5 Wasser ad 100

• ³²Natriumlaurylethersulfat mit 2 Mol EO ca. 70% Aktivsubstanz (INCI-Bezeichnung: Sodium Laureth Sulfate) (COGNIS)
• ³³Ethylenglykolmonostearat (ca. 25–35% Monoester, 60–70% Diester; INCI: Bezeichnung: Glycol Stearate) (COGNIS)
• ³⁴INCI-Bezeichnung: Hydroxypropyltrimonium Honey (ca. 50% Aktivsubstanz) (BROOKS)
• ³⁵Polyoxyethylen-propylenglykoldioleat (40% Aktivsubstanz; INCI-Bezeichnung: Propylene Glycol (and) PEG-55 Propylene Glycol Oleate) (GOLDSCHMIDT)

41. Shampoo Texapon^® K14 S³⁶ 50,0 Dehyton^® K 10,0 Plantacare^® 818 UP³⁷ 4,5 Derivat 9 4,0 Polymer P1, entsprechend DE 39 29 973 0,6 Cutina^® AGS³⁸ 2,0 D-Panthenol 0,5 Glucose 1,0 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Champagnerextrakt 0,5 Koffein 0,5 Salicylsäure 0,4 Natriumchlorid 0,5 Gluadin^®WQ 2,0 Wasser ad 100

• ³⁶Natriumlaurylmyristylethersulfat ca 28% Aktivsubstanz (INCI-Bezeichnung: Sodium Myreth Sulfate) (COGNIS)
• ³⁷C8-C16 Fettalkoholglycosid ca. 50% Aktivsubstanz (INCI-Bezeichnung: Coco Glucoside) (COGNIS)
• ³⁸Ethylenglykolstearat (ca. 5–15% Monoester, 85–95% Diester; INCI-Bezeichnung: Glycol Distearate) (COGNIS)

42. Haarkur Celquat^® L 200³⁹ 0,6 Luviskol^® K30⁴⁰ 0,2 D-Panthenol 0,5 Polymer P1, entsprechend DE 39 29 973 0,6 Dehuquart^® A-CA⁴¹ 1,0 Gluadin^®W 40⁴² 1,0 Derivat 1 1,0 Natrosol^® 250 HR⁴³ 1,1 Champagnerextrakt 0,5 Gluadin^®WQ 2,0 Wasser ad 100

• ³⁹quaterniertes Cellulose-Derivat (95% Aktivsubstanz; CTFA-Bezeichnung: Polyquaternium-4) (DELFT NATIONAL)
• ⁴⁰Polyvinylpyrrolidon (95% Aktivsubstanz; CTFA-Bezeichnung: PVP) (BASF)
• ⁴¹Cetyltrimethylammoniumchlorid (INCI-Bezeichnung: Cetrimonium Chloride) (COGNIS)
• ⁴²Partialhydrolysat aus Weizen ca. 40% Aktivsubstanz (INCI-Bezeichnung: Hydrolyzed Wheat Gluten Hydrolyzed Wheat Protein) (COGNIS)
• ⁴³Hydroxyethylcellulose (AQUALON)

43. Färbecreme C_12-18-Fettalkohol 1,2 Lanette^® O⁴⁴ 4,0 Eumulgin^® B2 0,8 Cutina^® KD 16⁴⁵ 2,0 Derivat 10 1,5 Natriumsulfit 0,5 L(+)-Ascorbinsäure 0,5 Ammoniumsulfat 0,5 1,2-Propylenglykol 1,2 Polymer JR^®400 0,3 p-Aminophenol 0,35 p-Toluylendiamin 0,85 2-Methylresorcin 0,14 6-Methyl-m-aminophenol 0,42 Cetiol^® OE⁴⁶ 0,5 Champagnerextrakt 0,5 Honeyquat^® 50 1,0 Ajidew^® NL 50 1,2 Gluadin^® WQ 1,0 Ammoniak 1,5 Wasser ad 100

• ⁴⁴Cetylstearylalkohol (INCI-Bezeichnung: Cetearyl Alcohol) (COGNIS)
• ⁴⁵Selbstemulgierendes Gemisch aus Mono-/Diglyceriden höherer gesättigter Fettsäuren mit Kaliumstearat (INCI-Bezeichnung: Glyceryl Stearate SE) (COGNIS)
• ⁴⁶Di-n-octylether (INCI-Bezeichnung: Dicaprylyl Ether) (COGNIS)

44. Entwicklerdispersion für Färbecreme 12. Texapon^®NSO 2,1 Derivat 7 1,5 Wasserstoffperoxid (50%ig) 12,0 Turpinal^® SL⁴⁷ 1,7 Latekoll^® D⁴⁸ 12,0 Champagnerextrakt 0,5 Gluadin^®WQ 0,3 Salcare^® SC 96 1,0 Wasser ad 100

• ⁴⁷1-Hydroxyethan-1,1-diphosphonsäure (60% Aktivsubstanz; INCI-Bezeichnung: Etidronic Acid) (COGNIS)
• ⁴⁸Acrylester-Methacrylsäure-Copolymer (25% Aktivsubstanz) (BASF)

 1st shower gel component Wt.% Wt.% Wt.% Na laureth sulfate (70% AS) 12.5 12.5 12.5 Cocamidopropylbetaine (45% AS) 10.0 10.0 10.0 Derivative 7 7.5 Derivative 17 7.5 Derivative 27 7.5 Polyquaternium-7 1.5 1.5 1.5 Polyglyceryl-3 caprate 1.0 1.0 1.0 champagne extract 1.0 1.0 1.0 Cetiol ^® HE 0.5 0.5 0.5 NaCl 0.4 0.4 0.4 Acidifier, UV filter, preservative, water ad 100 ad 100 ad 100   Second Deodorant roll-on component INCI name Wt.% Wt.% Wt.% Methocel ^® E4M Premium EP (DOW) Hydroxypropyl methyl cellulose 0.8 0.8 0.8 water 49.2 49.2 49.2 Hydrolyzate 5 2.0 Hydrolyzate 15 2.0 Hydrolyzate 25 2.0 Hydagen HCMF ^® (Cognis) chitosan 0.2 0.2 0.2 Glycolic acid (Merk) glycolic acid 0.08 0.08 0.08 water ad 100 ad 100 ad 100 ethanol 25.0 25.0 25.0 champagne extract 0.5 0.5 0.5 CETIOL ^® HE (Cognis) PEG-7 glyceryl cocoate 3.0 3.0 3.0  Third Deodorant pump spray component INCI declaration Wt.% Plantacare® ^® 818 UP Coco glucoside 4.0 4.0 4.0 ethanol 40.0 40.0 40.0 Hydagen® ^® CAT Triethyl citrate 2.0 2.0 2.0 Hydrolyzate 4 2.5 2.5 Hydrolyzate 14 2.5 2.5 Hydrolyzate 24 2.5 water ad 100 ad 100 ad 100 champagne extract 3.0 3.0 3.0 HYDAGEN ^® DCMF chitosan 0.1 0.1 0.1 Glycolic acid (Merk) glycolic acid 0.04 0.04 0.04   4th After Shave cream component INCI declaration Wt.% Wt.% Wt.% Emulgade SE ^® (Cognis) Glyceryl Stearate (and) Ceteareth-20 (and) Ceteareth-12 (and) Cetearyl Alcohol (and) Cetyl Palmitate 4.0 4.0 4.0 Hydrolyzate 4 3.0 Hydrolyzate 14 3.2 Hydrolyzate 24 3.0 LANETTE O ^® (Cognis) Cetearyl Alcohol 1.0 1.0 1.0 Myritol ^® 312 (Cognis) Caprylic / Capric Triglycerides 3.0 3.0 3.0 CETIOL ^® PGL (Cognis) Hexyldecanol (and) hexyldecyl laurate 7.0 7.0 7.0 ^DC® 190 (Dow Corning) Dimethicone 0.5 0.5 0.5 Gluadin ^® AGP (Cognis) Hydrolyzed Wheat Protein 0.5 0.5 0.5 allantoin 0.1 0.1 0.1 Panthenol (50%) 0.5 0.5 0.5 water ad 100 ad 100 ad 100 champagne extract 3.0 3.0 3.0 CETIOL ^® PGL (Cognis) Hexyldecanol (and) hexyldecyl laurate 1.0 1.0 1.0 KOH, 20% Potasium hydroxides 0.5 0.5 0.5 HYDAGEN ^® B (Cognis) bisabolol 0.2 0.2 0.2 ethanol 10.0 10.0 10.0   5th Moisturizer with Vitamin E component INCI declaration Wt.% Wt.% Wt.% EMULGADE ^® PL 68/50 Cetearyl Glucoside (and) Cetearyl Alcohol 5.0 5.0 5.0 LANETTE ^® E powder (Cognis) Sodium Cetearyl Sulfate 0.25 0.25 0.25 CUTINA GMS ^® (Cognis) Glyceryl stearate 2.0 2.0 2.0 Hydrolyzate 5 1.0 Hydrolyzate 15 1.0 Hydrolyzate 25 1.0 Myritol ^® 312 (Cognis) Caprylic / Capric Triglycerides 5.0 5.0 5.0 CETIOL LC ^® (Cognis) Coco-caprylate / caprate 5.0 5.0 5.0 EUTANOL ^® G 16 (Cognis) hexyldecanol 2.0 2.0 2.0 Copherol® ^® F 1300 (Cognis) tocopherol 1.0 1.0 1.0 Wacker Silicone Oil AK 350 (Wacker) Dimethicone 0.5 0.5 0.5 champagne extract 1.5 1.5 1.5 Glycerin 86% 3.0 3.0 3.0 D-panthenol USP 0.5 0.5 0.5 water ad 100 ad 100 ad 100   6th Rich night care component INCI name Wt.% Wt.% Wt.% EMULGADE ^® PL 68/50 (Cognis) Cetearyl Glucoside (and) Cetearyl Alcohol 3.0 3.0 3.0 LANETTE O ^® (Cognis) Cetearyl Alcohol 4.0 4.0 4.0 CETIOL J ^® 600 (Cognis) Oleyl erucate 4.0 4.0 4.0 CETIOL ^® V (Cognis) Decyl Oleate 4.0 4.0 4.0 CETIOL ^® OE (Cognis) Dicaprylyl ether 4.0 4.0 4.0 Hydrolyzate 5 2.5 Hydrolyzate 15 2.5 Hydrolyzate 25 2.5 Myritol ^® 318 (Cognis) Caprylic / Capric Triglycerides 3.5 3.5 3.5 Baysilon ^® M 350 (Bayer) Dimethicone 0.5 0.5 0.5 Copherol® ^® F 1300 (Cognis) tocopherol 1.0 1.0 1.0 water ad 100 ad 100 ad 100 Glycerin 86% 3.0 3.0 3.0 Carbopol ^® 981 at 2% Carbomer 10.0 10.0 10.0 KOH 20% 0.3 0.3 0.3 LIPOCUTIN ^® (Cognis) Aqua (and) Lecithin (and) Cholesterol (and) Decetyl Phosphate 5.0 5.0 5.0 champagne extract 2.0 2.0 2.0 Viscosity (mPas), Brookfield RVF, 23 ° C, Sp. TE, 4 rpm, with Helipath 137500   7th All Purpose cream component INCI name Wt.% Wt.% Wt.% DEHYMULS ^® PGPH (Cognis) Polyglyceryl poly-12-hydroxystearates 4.5 4.5 4.5 MYRITOL ^® 331 (Cognis) Cocoglycerides 5.0 5.0 5.0 Hydrolyzate 4 1.0 Hydrolyzate 14 1.0 Hydrolyzate 24 1.0 CETIOL ^® OE (Cognis) Dicaprylyl ether 5.0 5.0 5.0 champagne extract 1.0 1.0 1.0 Zinc stearate (Bärlocher) Zincstearate 1.0 1.0 1.0 Glycerine (86%) 5.0 5.0 5.0 MgSO ₄ .7H ₂ O 0.5 0.5 0.5 water ad 100 ad 100 ad 100 Viscosity (mPas), Brookfield RVF, 23 ° C, spindle TE, 4 rpm, with helipath about 200,000   8th. Rich W / O cream component INCI name Wt.% Wt.% Wt.% DEHYMULS ^® PGPH (Cognis) Polyglyceryl poly-12-hydroxystearates 3.0 3.0 3.0 LAMEFORM ^® TGI (Cognis) Polyglyceryl-3 diisostearate 3.0 3.0 3.0 Beeswax 8100 (Kahl & Co.) Cera Alba 3.0 3.0 3.0 Hydrolyzate 3 1.0 Hydrolyzate 3 1.0 Hydrolyzate 3 1.0 Zincum ^® N 29 (Fa. Baerlocher) Zinc stearate 1.0 1.0 1.0 CETIOL ^® OE (Cognis) Dicaprylyl ether 3.0 3.0 3.0 CETIOL ^® IC (Cognis) Coco Caprylate / Caprate 6.0 6.0 6.0 Myritol ^® 312 (Cognis) Caprylic / Capric Triglycerides 8.0 8.0 8.0 Almond Oil Almond Oil 8.0 8.0 8.0 champagne extract 1.0 1.0 1.0 Copherol® ^® F 1300 (Cognis) tocopherol 1.0 1.0 1.0 glycerin 5.0 5.0 5.0 MgSO ₄ × 7H ₂ O 1.0 1.0 1.0 water ad 100 ad 100 ad 100 Viscosity (mPas) / Brookfield, RVF, 23 ° C, spindle TE, 4 rpm, with Helipath 150000   9th Naturally sounding day cream component INCI name Wt.% Wt.% Wt.% Emulgade SE ^® (Cognis) Glyceryl Stearate (and) Ceteareth-20 (and) Ceteareth-12 (and) Cetearyl Alcohol (and) Cetyl Palmitate 6.0 6.0 6.0 CUTINA ^® MD (Cognis) Glyceryl stearate 2.0 2.0 2.0 Hydrolyzate 3 1.0 Hydrolyzate 13 1.0 Hydrolyzate 23 1.0 CETIOL ^® MM (Cognis) Myristyl myristate 1.0 1.0 1.0 Myritol ^® 312 (Cognis) Caprylic / Capric Triglycerides 5.0 5.0 5.0 CETIOL SN ^® (Cognis) Cetearyl Isononanoate 5.0 5.0 5.0 CETIOL ^® OE (Cognis) Dicaprylyl ether 5.0 5.0 5.0 Grape Seed Oil Grape Seed Oil 0.5 0.5 0.5 Copherol ^® 1250 (Cognis) Tocopheryl acetate 1.0 1.0 1.0 champagne extract 2.0 2.0 2.0 Eusolex ^® 8020 (Merck) 4 isopropyl dibenzoylmethane 1.0 1.0 1.0 Vitamin A palmitate 0.2 0.2 0.2 Titanium dioxide 1.0 1.0 1.0 talc 1.0 1.0 1.0 Glycerin 86% 5.0 5.0 5.0 water ad 100 ad 100 ad 100 KOH, 20% Potasium hydroxides 0.3 0.3 0.3   10th lipstick component INCI name % % % Myritol ^® 318 (Cognis) Caprylic / Capric Triglycerides 14.0 14.0 14.0 MYRITOL ^® PC (Cognis) Propylene Glycol Dicaprylate / Dicaprate 6.0 6.0 6.0 EUTANOL G ^® (Cognis) octyldodecanol 17.0 17.0 17.0 Candelilla wax Candelilla cera 7.0 7.0 7.0 Carnauba wax Carnauba cera 5.5 5.5 5.5 Beeswax 8100 (Kahl) Cera alba 6.5 6.5 6.5 Hydrolyzate 5 0.5 Hydrolyzate 15 0.5 Hydrolyzate 25 0.5 Generol N 122 ^® (Cognis) Soybean (Glycine soy) sterol 2.5 2.5 2.5 Monomuls 90 L ^® 12 (Cognis) Glyceryl laurate 3.0 3.0 3.0 DEHYMULS ^® PGPH (Cognis) Polyglyceryl-2 dipolyhydroxystearates 4.0 4.0 4.0 Castor oil Ricinus communis 18.0 18.0 18.0 champagne extract 1.0 1.0 1.0 color pigments 2.0 2.0 2.0 Hydagen CMF ^® (Cognis) Chitosan glycolate 10.0 10.0 10.0 Copherol® ^® F 1300 (Cognis) tocopherol 2.0 2.0 2.0   11th Cold wave fixing component Chem. Designation INCI name Wt.% DEHYTON ^® K (Cognis) Genuine betaine. Fatty acid amide derivative with betaine structure (about 32%) Cocamidopropyl betaines 6.0 NUTRILAN ^® H (Cognis) Protein partial hydrolyzate (about 36%) Hydrolyzed collagen 5.0 LAMEQUAT ^® L (Cognis) Cationised protein hydrolyzate (about 36%) Laurdimonium Hydroxypropyl Hydrolyzed Collagen 3.0 Hydrolyzate 1 1.0 Hydrogen peroxide 35% 7.5 Keltrol T (1% swelling) Xanthan gum 15.0 water ad 100 champagne extract 1.0 PH value 3.5  12th Coldwell fixation, emulsion-shaped component Chem. Designation INCI name Wt.% DEHYQUART ^® C 4046 (Cognis) Mixture of esterquat, fatty alcohol and nonionic emulsifier Cetearyl Alcohol (and) Dipalmitoylethyl Hydroxyethylmonium Methosulfate (and) Ceteareth-20 3.0 water ad 100 TURPINAL ^® SL (Cognis) Etidronic Acid 0.3 Derivative 1 1.0 Hydrogen peroxides (35%) Hydrogen peroxides 7.5 PLANTACARE ^® 2000 UP (Cognis) C8-C16 Fettalkoholglycosid Decyl glucosides 1.0 champagne extract 0.5 PH value 2.7 Viscosity (mPas), Brookfield RVT, 23 ° C, Sp. TC, 10 rpm 3600   13th sprayable conditioner, leave-on component INCI name Wt.% Wt.% Wt.% Monomuls ^® 60-35 C (Cognis) Hydrogenated Palm Glycerides 1.24 1.24 1.24 Eumulgin ^® B1 (Cognis) Ceteareth-12 2.76 2.76 2.76 Derivative 3 2.0 Derivative 13 2.0 Derivative 23 2.0 CETIOL ^® S (Cognis) Dioctylcyclohexane 9.0 9.0 9.0 CETIOL ^® OE (Cognis) Dicaprylyl ether 9.0 9.0 9.0 Dow Corning DC ^345® , (Dow Corning) Cyclomethicone 2.0 2.0 2.0 champagne extract 2.0 2.0 2.0 carnitintartrat 0.5 0.5 0.5 caffeine 0.5 0.5 0.5 water ad 100 ad 100 ad 100 Gluadin ^® WQ (Cognis) Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein 1.0 1.0 1.0 PLANTACARE ^® 2000 UP (Cognis) Decyl glucosides 1.00 1.00 1.00   14th Leave-on hair cure component INCI name Wt.% Wt.% Wt.% DEHYQUART ^® F 75 (Cognis) Distearoylethyl Hydroxyethylmonium Methosulfate (and) Cetearyl Alcohol 0.7 0.7 0.7 DEHYMULS ^® PGPH (Cognis) Polyglyceryl-2 dipolyhydroxystearates 1.0 1.0 1.0 LANETTE O ^® (Cognis) Cetearyl Alcohol 3.0 3.0 3.0 Derivative 4 1.5 Derivative 14 1.5 Derivative 24 1.5 EUTANOL G ^® (Cognis) octyldodecanol 0.2 0.2 0.2 CETIOL J ^® 600 (Cognis) Oleyl erucate 0.1 0.1 0.1 PLANTACARE ^® 1200 UP (Cognis) Lauryl glucoside 2.5 2.5 2.5 pantolactone 1.0 1.0 1.0 champagne extract 4.0 4.0 4.0 carnitintartrat 2.0 2.0 2.0 taurine 1.0 1.0 1.0 Ecchinaceaextrakt 1.0 1.0 1.0 caffeine 2.0 2.0 2.0 water ad 100 ad 100 ad 100 Gluadin ^® W 40 (Cognis) Hydrolyzed Wheat Protein 2.0 2.0 2.0 Panthenol (50%) 0.7 0.7 0.7 PH value 4 Viscosity (mPas) / Brookfield, RVF 23 ° C, spindle 5, 10 rpm 6800   15th Leave-on hair cure component INCI name Wt.% Wt.% Wt.% Sepigel ^® 305 (Seppic) Polyacrylamide (and) C13-14 isoparaffin (and) laureth-7 3.0 3.0 3.0 COMPERLAN ^® KD (Cognis) Cocamide DEA 2.0 2.0 2.0 pantolactone 3.0 3.0 3.0 champagne extract 2.0 2.0 2.0 carnitintartrat 2.0 2.0 2.0 taurine 1.0 1.0 1.0 caffeine 1.0 1.0 1.0 Echinacea extract 2.0 2.0 2.0 water ad 100 ad 100 ad 100 Derivative 5 1.5 Derivative 15 1.5 Derivative 25 1.5 PLANTACARE ^® 1200 UP (Cognis) Lauryl glucoside 0.5 0.5 0.5 CETIOL J ^® 600 (Cognis) Oleyl erucate 0.5 0.5 0.5 Copherol ^® 1250 (Cognis) tocopherol 0.2 0.2 0.2 Gluadin ^® ALMOND (Cognis) Hydrolyzed Sweet Almond Protein 3.0 3.0 3.0 Gluadin ^® WQ (Cognis) Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein 0.8 0.8 0.8 ethanol 10.0 10.0 10.0 PH value 7 Viscosity (mPas) / Brookfield RVF, 23 ° C, spindle 4, 10 rpm 6700   16th hair conditioner component INCI name Wt.% Wt.% Wt.% DEHYQUART ^® C 4046 (Cognis) Cetearyl Alcohol (and) Dipalmitoylethyl Hydroxyethylmonium Methosulfate (and) Ceteareth20 4.0 4.0 4.0 CETIOL SN ^® (Cognis) Cetearyl Isononanoate 1.0 1.0 1.0 Derivative 1 1.0 Derivative 11 1.0 1.0 Derivative 21 1.0 Gluadin ^® ALMOND (Cognis) Hydrolyzed Sweet Almond Protein 2.1 2.1 2.1 champagne extract 1.5 1.5 1.5 water ad 100 ad 100 ad 100 PH value 3.5 Viscosity (mPas) / Brookfield RVF, 23 ° C, spindle 4, 10 rpm 4000   17th conditioner component INCI name Wt.% Wt.% Wt.% Dehyquart ^® L 80 (Cognis) Dicocoylethyl Hydroxyethylmonium Methosulfate (and) Propylene Glycol 0.9 0.9 0.9 LANETTE O ^® (Cognis) Cetearyl Alcohol 3.5 3.5 3.5 Derivative 2 2.0 Derivative 12 2.0 2.0 Derivative 22 2.0 Monomuls ^® 60-35 C (Cognis) Hydrogenated Palm Glycerides 1.0 1.0 1.0 Eumulgin ^® B2 (Cognis) Ceteareth-20 0.8 0.8 0.8 Cosmedia GUAR ^® C 261 (Cognis) Guar hydroxypropyl trimonium chlorides 0.3 0.3 0.3 champagne extract 2.0 2.0 2.0 water ad 100 ad 100 ad 100 PH value 3.5   18th hair mask component INCI name Wt.% Wt.% Wt.% DEHYQUART ^® F 75 (Cognis) Distearoylethyl Hydroxyethylmonium Methosulfate (and) Cetearyl Alcohol 3.0 3.0 3.0 LANETTE O ^® (Cognis) Cetearyl Alcohol 4.0 4.0 4.0 Derivative 5 3.0 Derivative 5 3.0 Derivative 5 3.0 CUTINA GMS ^® (Cognis) Glyceryl stearate 1.0 1.0 1.0 Eumulgin ^® B2 (Cognis) Ceteareth-20 1.5 1.5 1.5 champagne extract 2.0 2.0 2.0 NUTRILAN ^® KERATIN W (Cognis) Hydrolyzed Kerstin 5.0 5.0 5.0 panthenol 0.8 0.8 0.8 Aloe vera gel 2.0 2.0 2.0 water ad 100 ad 100 ad 100 PH value 3-4   19th Intensivhaarkur component INCI name Wt.% DEHYQUART ^® L 80 (Cognis) Dicocoylethyl Hydroxyethylmonium Methosulfate (and) Propylene Glycol 2.5 CUTINA GMS ^® (Cognis) Glyceryl stearate 0.5 Derivative 4 3.0 LANETTE O ^® (Cognis) Cetearyl Alcohol 4.0 Hydagen ^® HSP (Cognis) Trimethylolpropane-Hydroxymethylstearate ether 0.5 champagne extract 3.0 Lamesoft ^® PO 65 (Cognis) Coco-Glucoside (and) Glyceryl Oleate 2.5 water ad 100 PH value 3.5 Viscosity (mPas), Brook. RVF, 23 ° C, spindle 4, 10 rpm 4400   20th Haarspitzenfliud component INCI name Wt.% Hydagen HCMF ^® (Cognis) chitosan 0.4 Glycolic acid (Merck) Glycolic acid 0.2 Hydrolyzate 1 1.0 Glycerin 86% 55.0 Tylose ^® H 100,000 VP (Hoechst) 0.4 champagne extract 3.0 Plantacare® ^® 818 UP 2.0 Gluadin ^® R (Cognis) Hydrolyzed Rice Protein (and) Hydrolyzed Vegetable Protein 4.0 Panthenol 50% 1.0 ethanol 10.0 water ad 100 PH value 4.5   21st Leave-on hair milk component INCI name Wt.% DEHYQUART ^® L 80 (Cognis) Dicocoylethyl Hydroxyethylmonium Methosulfate (and) Propylene Glycol 2.0 Hydrolyzate 2 2.0 Lamesoft ^® PO 65 (Cognis) Coco Glucoside (and) Glyceryl Oleate 2.0 champagne extract 2.0 water ad 100 PH value 3.5  22nd Pump spray lotion component INCI name Wt.% Hydagen HCMF ^® (Cognis) chitosan 1.0 Glycolic acid (Merk) 0.4 champagne extract 0.5 Hydrolyzate 1 0.5 PLANTACARE ^® 1200 UP (Cognis) Lauryl glucoside 0.2 Gluadin ^® WQ (Cognis) Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein 1.0 ethanol 40.0 water ad 100 4.0   23rd mousse component INCI name Wt.% Hydagen HCMF ^® (Cognis) chitosan 0.4 Glycolic acid (Merck) glycolic acid 0.2 champagne extract 1.0 DEHYQUART ^® A (Cognis) Cetrimonium chlorides 1.0 Hydrolyzate 2 1.0 Gluadin ^® W 40 (Cognis) Hydrolyzed Wheat Protein 2.0 water ad 100  24th Styling Wax component INCI name % CUTINA ^® MD (Cognis) Glyceryl stearate 5.0 Eumulgin ^® B1 (Cognis) Ceteareth-12 1.0 CETIOL ^® V (Cognis) Decyl Oleate 5.0 Paraffin oil 10.0 Hydrolyzate 5 0.5 Hydagen HCMF ^® (Cognis) chitosan 0.8 Glycolic acid (Merck) 0.4 champagne extract 1.0 water ad 100   25th 2-in-1 shampoo component INCI name Wt.% Wt.% Wt.% TEXAPON ^® N 70 (Cognis) Sodium Laureth Sulfate 12.0 12.0 12.0 Dehyton ^® PK 45 (Cognis) Cocamidopropyl betaines 2.5 2.5 2.5 PLANTACARE ^® 818 UP (Cognis) Coco Glucoside 3.0 3.0 3.0 Derivative 6 3.0 Derivative 16 3.0 Derivative 26 3.0 Lamesoft ^® PO 65 (Cognis) Coco-Glucoside (and) Glyceryl Oleate 3.0 3.0 3.0 Cosmedia GUAR ^® C 261 N (Cognis) Guar hydroxypropyl trimonium chlorides 0.3 0.3 0.3 EUPERLAN ^® PK 1200 (Cognis) Coco Glucoside (and) Glycol Distearate (and) Glycerol 5.0 5.0 5.0 sodium chloride 1.2 1.2 1.2 pantolactone 0.3 0.3 0.3 champagne extract 1.0 1.0 1.0 caffeine 1.0 1.0 1.0 carnitintartrat 1.0 1.0 1.0 Euxyl K 400 ^® (Schulke & Mayr) 0.1 0.1 0.1 water ad 100 ad 100 ad 100 PH value 5.5 Viscosity (mPas), Brookfield RFT, 23 ° C, Sp. 4, 10 rpm 6300   26th conditioning shampoo component INCI name Wt.% Wt.% Wt.% TEXAPON ^® N 70 (Cognis) Sodium Laureth Sulfate 10.0 10.0 10.0 PLANTACARE ^® 818 UP (Cognis) Coco Glucoside 4.0 4.0 4.0 DEHYTON ^® K (Cognis) Cocamidopropyl betaines 5.0 5.0 5.0 Lamesoft ^® PO 65 (Cognis) Coco Glucoside (and) Glyceryl Oleate 1.5 1.5 1.5 Derivative 1 1.5 Derivative 11 1.5 Derivative 21 1.5 EUPERLAN ^® PK 3000 AM (Cognis) Glycol distearate (and) laureth 4 (and) cocamidopropyl betaine 3.2 3.2 3.2 panthenol 1.5 1.5 1.5 champagne extract 2.0 2.0 2.0 carnitintartrat 1.0 1.0 1.0 caffeine 1.0 1.0 1.0 taurine 1.0 1.0 1.0 Ecchinaceaextrakt 1.0 1.0 1.0 Vitamin E 0.5 0.5 0.5 Polymer JR ^® 400 (Amerchol) Polyquaternium 10 0.3 0.3 0.3 sodium chloride 1.5 1.5 1.5 water ad 100 ad 100 ad 100 PH value 5.5 Viscosity (mPas), Brookfield RVF, 23 ° C, spindle 4, 10 rpm 8500   27th Baby shampoo component Chem. Designation INCI name Wt.% water ad 100 Polymer ^® JR 400 (Amerchol) Polyquaternium-10 0.4 TEXAPON ^® K 14 S Special 70% (Cognis) Sodium lauryl myristyl ether sulfate (about 70%) Sodium myreth sulfate 11.0 Dehyton ^® PK 45 (Cognis) Fatty acid amide derivative with betaine structure (about 45%) Cocamidopropyl betaines 5.0 PLANTACARE ^® 818 UP (Cognis) C8-C16 fatty alcohol glycoside (about 50%) Coco Glucoside 5.0 Derivative 8 2.0 Lamesoft ^® PO 65 (Cognis) Coco-Glucoside (and) Glyceryl Oleate Coco-Glucoside (and) Glyceryl Oleate 5.0 Euxyl K 400 ^® (Schulke & Mayr) 1,2-dibromocyananobutane and 2-phenoxyethanol 0.1 Sodium chloride champagne extract 1.8 PH value 5.5 Viscosity (mPas), Brookfield RVF, 23 ° C, spindle 4, 10 rpm 3900   28th Pearlescent care shampoo component Chem. Designation INCI name Wt.% TEXAPON ^® NSO (Cognis) Sodium lauryl ether sulfate (about 28%) Sodium Laureth Sulfate 29.0 PLANTACARE ^® 818 UP (Cognis) C8-C16 fatty alcohol glycoside (about 50%) Coco Glucoside 5.0 TEXAPON ^® SB 3 KC (Cognis) Sulfosuccinic monoester based on an alkyl polyglycol ether, di-Na salt (about 40%) Disodium Laureth Sulfosuccinate 3.8 Derivative 9 2.0 Hydagen ^® HSP (Cognis) Trimethylolpropane-Hydroxymethylstearate ether 0.5 champagne extract 1.0 EUPERLAN ^® PK 3000 AM (Cognis) Liquid dispersion of pearlescing substances and amphoteric surfactant Glycol distearate (and) laureth-4 (and) cocamidopropyl betaine 3.0 NaCl 2.0 water ad 100 PH value 5.5 Viscosity (mPas), Brook. RVF, 23 ° C, spindle 4, 10 rpm 4100   29th Cream hair color component Chem. Designation INCI name Wt.% Lanette ^® O (Cognis) Cetylstearylalkohol Cetearyl Alcohol 17.0 CUTINA ^® AGS (Cognis) Ethylene glycol Glycol distearate 1.5 Eumulgin ^® 82 (Cognis) Polyoxyethylene 20 Cetylstearylalkohol Ceteareth-20 3.0 Eumulgin ^® B1 (Cognis) Polyoxyethylene-12 cetylstearyl Ceteareth-12 3.0 Eumulgin ^® O5 (Cognis) Polyoxyethylene-5-oleyl cetyl alcohol Oleth-5 1.0 Eumulgin ^® O10 (Cognis) Polyoxyethylene 10 oleyl cetyl alcohol Oleth-10 1.0 COMPERLAN ^® KD (Cognis) coconut fatty acid diethanolamide Cocamide DEA 5.0 water ad 100 Hydrolyzate 1 1.0 DEHYQUART ^® 180 (Cognis) Mixture of esterquat and propylene glycol Dicocoylethyl Hydroxyethylmonium Methosulfate (and) Propylene Glycol 1.5 propylene glycol 5.0 p-aminophenol 0.35 p-toluenediamine 0.85 2-methyl 0.14 6-methyl-m-aminophenol 0.42 champagne extract 1.0 sodium 0.6 EDTA Tetrasodium EDTA 0.2 Ammonia, 28% 5.0   30th foam bath component Chem. Designation INCI name Wt.% TEXAPON ^® NSO Sodium lauryl ether sulfate (about 28%) Sodium Laureth Sulfate 27.0 PLANTACARE ^® 818 UP C8-C16 fatty alcohol glycoside (about 50%) Coco Glucoside 9.0 DEHYTON ^® PK 45 Genuine betaine, fatty acid amide derivative with betaine structure (about 45%) Cocamidopropyl betaines 4.0 Derivative 10 1.5 GLUADIN ^® W 40 Partial hydrolyzate from wheat Hydrolyzed Wheat Protein 4.0 champagne extract 1.0 sodium chloride Sodium Chloride 0.3 water ad 100   31st cleansing milk component Chem. Designation INCI name Wt.% Emulgade SE ^® (Cognis) Mixture of partial glycerides, fatty alcohols, wax esters and ethoxylated fatty alcohols Glyceryl Stearate (and) Ceteareth 20 (and) Ceteareth 12 (and) Cetearyl Alcohol (and) Cetyl Palmitate 6.0 EUTANOL G ^® (Cognis) 2-octyldodecanol (Guerbet alcohol) octyldodecanol 7.0 champagne extract 2.0 CETIOL ^® 868 (Cognis) isooctyl Octyl stearate 8.0 Derivative 7 1.0 Glycerin 86% 3.0 Carbopol ^® 981 (Goodrich) Carbomer / 2% swelling 10.0 NaOH 10% 0.8 water ad 100 Viscosity (mPas), Brookfield RVF, 23 ° C, spindle. 5, 10 rpm 8000   32nd hair conditioner Eumulgin ^® 62 ¹ 0.3 Cetyl / stearyl 3.3 isopropyl 0.5 Paraffin oil perliquidum 15 cSt. DAB 9 0.3 Dehyquart® ^® A-CA ² 2.0 Salcare ^® SC 96 ³ 1.0 champagne extract 1.0 Hydrolyzate 2 2.0 citric acid 0.4 Gluadin® ^® WQ ⁴ 2.0 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 ^Phenonip®5 0.8 water ad 100

• ¹ cetylstearyl alcohol + 20 EO (INCI name: Ceteareth-20) (COGNIS)
• ² trimethylhexadecylammonium chloride approx. 25% active ingredient (INCI name: Cetrimonium Chloride) (COGNIS)
• ³ N, N, N-Trimethyl-2 [(methyl-1-oxo-2-propenyl) oxy] ethanaminium chloride homopolymer (50% active ingredient; INCI name: Polyquaternium-37 (and) propylene glycol dicaprilate dicaprate (and) PPG -1 Trideceth-6) (ALLIED COLLOIDS)
• ⁴ Cationized wheat protein hydrolyzate approx. 31% active ingredient (INCI name: Lauridimonium Hydroxypropyl Hydrolyzed Wheat Protein) (COGNIS)
• ^5- hydroxybenzoic acid methyl ester-hydroxybenzoic acid ethyl ester-hydroxybenzoic acid propyl ester-hydroxy butyl benzoate-phenoxyethanol mixture (about 28% active ingredient, INCI name: phenoxyethanol, methylparaben, ethylparaben, propylparaben, butylparaben) (NIPA)

 33rd hair conditioner Eumulgin ^® B2 0.3 Cetyl / stearyl 3.3 isopropyl 0.5 Paraffin oil perliquidum 15 cSt. DAB 9 0.3 Dehyquart ^® L 80 ⁶ 0.4 Derivative 1 0.5 Cosmedia® guar ^® C 261 1.5 Promois® ^® Milk-CAQ ⁸ 3.0 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 citric acid 0.4 Phenonip 0.8 water ad 100

• ⁶ bis (cocoylethyl) -hydroxyethyl-methyl-ammonium-methosulfate (about 76% active substance in propylene glycol, INCI name: dicocoylethyl hydroxyethylmonium methosulfate, propylene glycol) (COGNIS)
• ⁷ guar hydroxypropyltrimethylammonium chloride; INCI name: Guar Hydroxypropyl Trimonium Chloride (COGNIS)
• ⁸ INCI name: Cocodimonium Hydroxypropyl Hydrolyzed Casein (SEIWA KASEI)

 34th conditioner Dehyquart ^® F75 ⁹ 4.0 Cetyl / stearyl 4.0 Paraffin oil perliquidum 15 cSt DAB 9 1.5 Dehyquart® ^® A-CA 4.0 Hydrolyzate 1 1.0 champagne extract 2.0 caffeine 1.0 taurine 0.5 carnitintartrat 3.0 Salcare ^® SC 96 1.5 Amisafe-LMA- ^60®10 1.0 Gluadin ^® W 20 ¹¹ 3.0 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 citric acid 0.15 Phenonip ^® 0.8 water ad 100  

• ⁹ fatty alcohols-Methyltriethanolammoniummethylsulfatdialkylester mixture (INCI name: distearoylethyl hydroxyethylmonium methosulfate, cetearyl alcohol) (COGNIS)
• ¹⁰ INCI name hydroxypropyl arginine lauryl / myristyl ether HCl (Ajinomoto)
• ¹¹ Wheat protein hydrolyzate (20% active in water, INCI name: Aqua (and) Hydrolized Wheat Protein (and) Sodium Benzoate (and) Phenoxyethanol (and) Methylparaben (and) Propylparaben) (COGNIS)

 35th conditioner Dehyquart® ^® L80 2.0 Cetyl / stearyl 6.0 Paraffin oil perliquidum 15 cSt DAB 9 2.0 Rewoquat ^® W 75 ¹² 2.0 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 Hydrolyzate 3 0.75 champagne extract 2.0 Copherol 1200 (Vitamin E) 1.0 Cosmedia® guar ^® C261 0.5 Sea urchin ^® 305 ¹³ 3.5 Honeyquat ^® 50 ¹⁴ 1.0 Gluadin® ^® WQ 2.5 Gluadin® ^® W 20 3.0 citric acid 0.15 Phenonip ^® 0.8 water ad 100

• ¹² 1-Methyl-2-nortalgalkyl-3-tallow fatty acid amidoethylimidazolinium methosulfate (about 75% active ingredient in propylene glycol, INCI name: Quaternium-27, propylene glycol) (WITCO)
• ¹³ Copolymer of acrylamide and 2-acrylamido-2-methylpropanesulfonic acid (INCI name: polyacrylamide (and) C ₁₃ -C ₁₄ isoparaffin (and) laureth-7) (SEPPIC)
• ¹⁴ INCI name: Hydroxypropyltrimonium Honey (BROOKS)

 36th conditioner Dehyquart® ^® F75 0.3 Salcare ^® SC 96 5.0 Gluadin® ^® WQ 1.5 Hydrolyzate 1 0.5 Dow ^Corning® 200 Fluid, 5 cSt. ¹⁵ 1.5 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 champagne extract 0.5 Gafquat ^® 755N ¹⁶ 1.5 ^{Biodocarb®17} 0.02 perfume oil 0.25 water ad 100  

• ¹⁵ polydimethylsiloxane (INCI name: dimethicone) (DOW CORNING)
• ¹⁶ Dimethylaminoethyl methacrylate-vinylpyrrolidone copolymer, quaternized with diethyl sulfate (19% active substance in water, INCI name: Polyquaternium-11) (GAF)
• ¹⁷ 3-iodo-propynyl-n-butylcarbamate (INCI name: Iodopropynyl Butylcarbamate) (MILKER & GRÜNING)

 37th conditioner Sepigel ^® 305 5.0 Dow Corning ^® Q2-5220 ¹⁸ 1.5 Promois ^® Milk Q ¹⁹ 3.0 Hydrolyzate 1 1.0 champagne extract 1.0 Polymer P1 accordingly DE 3929173 0.6 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 Genamin ^® DSAC ²⁰ 0.3 Phenonip ^® 0.8 perfume oil 0.25 water ad 100

• ¹⁸ silicone glycol copolymer (INCI name: dimethicone copolyol) (DOW CORNING)
• ¹⁹ INCI name Hydroxypropyltrimonium Hydrolyzed Casein approx. 30% active substance (SEIWA KASEI)
• ²⁰ Dimethyldistearylammonium chloride (INCI name: Distearyldimonium Chloride) (CLARIANT)

 38th shampoo Texapon.RTM ^® NSO ²¹ 40.0 Dehyton ^® G ²² 6.0 Derivative 7 2.5 Polymer JR 400 ^®23 0.5 Cetiol ^® HE ²⁴ 0.5 Ajidew ^® NL 50 ²⁵ 1.0 Gluadin® ^® WQT ²⁶ 2.5 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 champagne extract 1.0 carnitintartrat 0.5 taurine 0.5 caffeine 0.5 Coenzyme Q10 0.005 Gluadin® ^® W 20 0.5 Panthenol (50%) 0.3 Vitamin E 0.1 Vitamin H 0.1 citric acid 0.5 sodium benzoate 0.5 Perfume 0.4 NaCl 0.5 water ad 100

• ²¹ sodium lauryl ether sulfate approx. 28% active ingredient (INCI name: Sodium Laureth Sulfate) (COGNIS)
• ²² INCI name: Sodium cocoamphoacetate approx. 30% active ingredient (COGNIS)
• ²³ quaternized hydroxyethylcellulose (INCI name: Polyquaternium-10) (UNION CARBIDE)
• ²⁴ Polyol fatty acid esters (INCI name: PEG-7 Glyceryl Cocoate) (COGNIS)
• ²⁵ sodium salt of 2-pyrrolidinone-5-carboxylic acid (AJINOMOTO)
• ²⁶ INCI name Hydroxypropyltrimonium Hydrolyzed Wheat Protein COGNIS

 39th shampoo Texapon.RTM ^® NSO 43.0 Dehyton ^® K ²⁷ 10.0 Plantacare ^® 1200 UP ²⁸ 4.0 Derivative 6 3.0 Euperlan ^® PK 3000 ²⁹ 1.6 Arquad ^® 316 ³⁰ 0.8 Polymer ^JR® 400 0.3 Gluadin® ^® WQ 4.0 Glucamate DOE 120 ³¹ 0.5 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 Coenzyme Q10 0.005 caffeine 0.5 carnitintartrat 0.5 champagne extract 1.0 sodium chloride 0.2 water ad 100

• ²⁷ INCI name: Cocamidopropyl Betaine approx. 30% active ingredient (COGNIS)
• ²⁸ C12-C16 fatty alcohol glycoside approx. 50% active ingredient (INCI name: lauryl glucoside) (COGNIS)
• ²⁹ Liquid dispersion of pearlescent agents and amphoteric surfactant (ca. 62% active substance; CTFA name: Glycol Distearate (and) Glycerin (and) Laureth-4 (and) Cocoamidopropyl Betaine) (Cognis)
• ³⁰ Tri-C ₁₆ -alkylmethylammonium chloride (AKZO)
• ³¹ ethoxylated methylglucoside dioleate (CTFA name: PEG-120 methyl glucose dioleate) (AMERCHOL)

 40th shampoo Texapon ^® N 70 ³² 21.0 Plantacare ^® 1200 UP 8.0 Derivative 8 3.5 Gluadin® ^® WQ 1.5 Cutina ^® EGMS ³³ 0.6 Honeyquat ^® 50 ³⁴ 2.0 Ajidew ^® NL 50 2.8 Antil ^® 141 ³⁵ 1.3 champagne extract 0.5 carnitine 0.25 tartaric acid 0.25 Coenzyme Q 10 0.005 caffeine 0.5 panthenol 0.5 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 sodium chloride 0.2 magnesium hydroxide ad pH 4.5 water ad 100  

• ³² sodium lauryl ether sulfate with 2 mol EO approx. 70% active substance (INCI name: Sodium Laureth Sulfate) (COGNIS)
• ³³ ethylene glycol monostearate (about 25-35% monoester, 60-70% diester, INCI: name: glycol stearate) (COGNIS)
• ³⁴ INCI name: Hydroxypropyltrimonium Honey (about 50% active ingredient) (BROOKS)
• ³⁵ Polyoxyethylene propylene glycol dioleate (40% active ingredient, INCI name: Propylene Glycol (and) PEG-55 Propylene Glycol Oleate) (GOLDSCHMIDT)

 41st shampoo Texapon ^® K14 S ³⁶ 50.0 Dehyton ^® K 10.0 Plantacare ^® 818 UP ³⁷ 4.5 Derivative 9 4.0 Polymer P1, according to DE 39 29 973 0.6 Cutina ^® AGS ³⁸ 2.0 D-panthenol 0.5 glucose 1.0 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 champagne extract 0.5 caffeine 0.5 salicylic acid 0.4 sodium chloride 0.5 Gluadin® ^® WQ 2.0 water ad 100

• ³⁶ sodium lauryl myristyl ether sulfate approx. 28% active ingredient (INCI name: Sodium Myreth Sulfate) (COGNIS)
• ³⁷ C8-C16 fatty alcohol glycoside approx. 50% active ingredient (INCI name: Coco Glucoside) (COGNIS)
• ³⁸ ethylene glycol stearate (about 5-15% monoester, 85-95% diester, INCI name: glycol distearate) (COGNIS)

 42nd conditioner Celquat ^® L 200 ³⁹ 0.6 Luviskol ^® K30 ⁴⁰ 0.2 D-panthenol 0.5 Polymer P1, according to DE 39 29 973 0.6 Dehuquart ^{® A-41} CA 1.0 Gluadin ^® W 40 ⁴² 1.0 Derivative 1 1.0 Natrosol ^® 250 HR ⁴³ 1.1 champagne extract 0.5 Gluadin® ^® WQ 2.0 water ad 100

• ³⁹ quaternized cellulose derivative (95% active, CTFA name: Polyquaternium-4) (DELFT NATIONAL)
• ⁴⁰ polyvinylpyrrolidone (95% active substance, CTFA name: PVP) (BASF)
• ⁴¹ Cetyltrimethylammonium chloride (INCI name: Cetrimonium Chloride) (COGNIS)
• ⁴² partial hydrolyzate from wheat approx. 40% active ingredient (INCI name: Hydrolyzed Wheat Gluten Hydrolyzed Wheat Protein) (COGNIS)
• ⁴³ hydroxyethylcellulose (AQUALON)

 43rd coloring cream C _12-18 fatty alcohol 1.2 Lanette ^® O ⁴⁴ 4.0 Eumulgin ^® B2 0.8 Cutina ^® KD 16 ⁴⁵ 2.0 Derivative 10 1.5 sodium 0.5 L (+) - ascorbic acid 0.5 ammonium sulfate 0.5 1,2-propylene glycol 1.2 Polymer ^JR® 400 0.3 p-aminophenol 0.35 p-toluenediamine 0.85 2-methyl 0.14 6-methyl-m-aminophenol 0.42 Cetiol OE ^{® 46} 0.5 champagne extract 0.5 Honeyquat ^® 50 1.0 Ajidew ^® NL 50 1.2 Gluadin® ^® WQ 1.0 ammonia 1.5 water ad 100  

• ⁴⁴ Cetylstearyl alcohol (INCI name: Cetearyl Alcohol) (COGNIS)
• ⁴⁵ Self-emulsifying mixture of mono- / diglycerides of higher saturated fatty acids with potassium stearate (INCI name: Glyceryl Stearate SE) (COGNIS)
• ⁴⁶ Di-n-octyl ether (INCI name: dicaprylyl ether) (COGNIS)

 44th Developer dispersion for coloring cream 12. Texapon.RTM ^® NSO 2.1 Derivative 7 1.5 Hydrogen peroxide (50%) 12.0 Turpinal SL ^{® 47} 1.7 Latekoll ^® D ⁴⁸ 12.0 champagne extract 0.5 Gluadin® ^® WQ 0.3 Salcare ^® SC 96 1.0 water ad 100

• ⁴⁷ 1-Hydroxyethane-1,1-diphosphonic acid (60% active ingredient, INCI name: Etidronic Acid) (COGNIS)
• ⁴⁸ Acrylic ester-methacrylic acid copolymer (25% active substance) (BASF)

• ⁴⁹Laurylalkohol + 4,5 Ethylenoxid-essigsäure-Natriumsalz (20,4% Aktivsubstanz) (CHEM-Y)
• ⁵⁰Rizinus-Öl, hydriert + 45 Ethylenoxid (INCI-Bezeichnung: PEG-40 Hydrogenated Castor Oil) (BASF)
• ⁵¹2-Octyldodecanol (Guerbet-Alkohol) (INCI-Bezeichnung: Octyldodecanol) (COGNIS)

The staining cream had a pH of 10.0. It caused an intense red tint of the hair. 45. Tinting shampoo Texapon.RTM ^® N 70 14.0 Dehyton ^® K 10.0 Derivative 8 7.5 Akypo RLM 45 ^® NV ⁴⁹ 14.7 Plantacare ^® 1200 UP 4.0 Polymer P1, according to DE 39 29 973 0.3 Cremophor ^® RH 40 ⁵⁰ 0.8 Dye CI 12 719 0.02 Dye CI 12 251 0.02 Dye CI 12 250 0.04 champagne extract 0.5 Dye CI 56 059 0.03 preservation 0.25 perfume oil qs Eutanol ^® G ⁵¹ 0.3 Gluadin® ^® WQ 1.0 Hydrolyzate 2 0.5 Honeyquat ^® 50 1.0 Salcare ^® SC 96 0.5 water ad 100

• ⁴⁹ lauryl alcohol + 4.5 ethylene oxide-acetic acid sodium salt (20.4% active substance) (CHEM-Y)
• ⁵⁰ castor oil, hydrogenated + 45 ethylene oxide (INCI name: PEG-40 Hydrogenated Castor Oil) (BASF)
• ⁵¹ 2-Octyldodecanol (guerbet alcohol) (INCI name: Octyldodecanol) (COGNIS)

• ⁵²C8-C10-Alkylglucosid mit Oligomerisationsgrad 1,6 (ca. 60% Aktivsubstanz) (COGNIS)

Fixierlösung Plantacare^® 810 UP 5,0 gehärtetes Rizinusöl 2,0 Kaliumbromat 3,5 Nitrilotriessigsäure 0,3 Zitronensäure 0,2 Hydrolysat 1 0,5 Derivat 1 1,5 Champagnerextrakt 0,5 Merquat^® 550⁵³ 0,5 Hydagen^® HCMF⁵⁴ 0,5 Gluadin^®WQ 0,5 Parfümöl q. s. Wasser ad 100

• ⁵³Dimethyldiallylammoniumchlorid-Acrylamid-Copolymer (8% Aktivsubstanz; INCI-Bezeichnung: Polyquarternium 7) (MOBIL OIL)
• ⁵⁴Chitosan Pulver (INCI-Bezeichnung: Chitosan) (COGNIS)

47. Gesichtswässer 47.1 47.2 47.3 Pluronic^®L 64⁵⁵ 3,0 4,0 5,0 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,25 0,25 0,25 Hydrolysat 2 0,5 0,3 0,8 Champagnerextrakt 0,5 0,25 1,0 Koffein 0,3 0,3 0,75 Taurin 0,25 0,25 0,5 Carnitintartrat 0,5 0,5 0,5 Vitamin E 0,5 0,5 1,0 Dipropylenglycol 10,0 10,0 10,0 Emulgator TD9/PEG40HCO⁵⁶ 0,5 0,5 0,5 Duftstoff 0,2 0,2 0,2 Zn-Gluconat 0,05 0,07 0,10 Hydagen^®CMF⁵⁷ 3,5 6,0 9,5 Wasser (NaOH bis pH = 5) ad 100 ad 100 ad 100

• ⁵⁵EO-PO-EO-Blockpolymer (EO = 40 Gew.-%), OHZ = 39,1
• ⁵⁶Trideceth 9 und PEG40-hydrogenated castor oil
• ⁵⁷Lösung von Chitosan (ca. 1 Gew.-%) in einer 0,4%igen wäßrigen Glycolsäure-Lösung

48. Hautemulsionen (O/W) 48.1 48.2 Emulgade^®SE⁵⁹ 8,0 8,0 Cutina^®MD-A⁶⁰ 1,5 1,5 Cetyl-/Stearylalkohol 1,5 1,5 Myritol^®318⁶¹ 10,0 10,0 Derivat 7 2,5 1,0 2-Ethylhexyl-Stearat 5,0 5,0 Dimethylpolysiloxan (350 at) 1,0 1,0 Controx^®KS⁶² 0,05 0,05 PHB-Propylester 0,2 0,2 PHB-Methylester 0,2 0,2 Champagnerextrakt 0,5 0,25 1,2-Propylenglycol 3,0 3,0 Hydagen^®CMF 3,0 8,0 Zn-Gluconat 0,04 0,10 Wasser (NaOH bis pH = 5) ad 100 ad 100

• ⁵⁹Gemisch aus: Glyceryl Stearate, Ceteareth-20, Ceteareth-12, Cetearyl Alcohol und Cetylpalmitat (COGNIS)
• ⁶⁰Glyceryl Stearate (COGNIS)
• ⁶¹Caprylic/Capric-Triglyceride (COGNIS)
• ⁶²Tocopherol und Hydrogenated Tallow Glycerides Citrate (COGNIS)

When washing the hair with this tinting shampoo they get a shiny, light blonde color. 46. Cream duration wave Well cream Plantacare ^® 810 UP ⁵² 5.0 thioglycolic 8.0 Turpinal® ^® SL 0.5 Ammonia (25%) 7.3 ammonium carbonate 3.0 Cetyl / stearyl alcohol 5.0 Guerbet alcohol 4.0 Hydrolyzate 1 2.0 champagne extract 0.5 Salcare ^® SC 96 3.0 Gluadin® ^® WQ 2.0 perfume oil qs water ad 100

• ⁵² C8-C10-alkylglucoside with degree of oligomerization 1.6 (about 60% active substance) (COGNIS)

fixing Plantacare® ^® 810 UP 5.0 hardened castor oil 2.0 potassium bromate 3.5 nitrilotriacetic 0.3 citric acid 0.2 Hydrolyzate 1 0.5 Derivative 1 1.5 champagne extract 0.5 Merquat ^® 550 ⁵³ 0.5 Hydagen® ^® HCMF ⁵⁴ 0.5 Gluadin® ^® WQ 0.5 perfume oil qs water ad 100

• ⁵³ Dimethyldiallylammonium chloride-acrylamide copolymer (8% active ingredient, INCI name: Polyquarternium 7) (MOBIL OIL)
• ⁵⁴ chitosan powder (INCI name: chitosan) (COGNIS)

47. Face Waters 47.1 47.2 47.3 Pluronic ^® L 64 ⁵⁵ 3.0 4.0 5.0 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.25 0.25 0.25 Hydrolyzate 2 0.5 0.3 0.8 champagne extract 0.5 0.25 1.0 caffeine 0.3 0.3 0.75 taurine 0.25 0.25 0.5 carnitintartrat 0.5 0.5 0.5 Vitamin E 0.5 0.5 1.0 dipropylene 10.0 10.0 10.0 Emulsifier TD9 / PEG40HCO ⁵⁶ 0.5 0.5 0.5 perfume 0.2 0.2 0.2 ZnGluconate 0.05 0.07 0.10 Hydagen CMF ^{® 57} 3.5 6.0 9.5 Water (NaOH to pH = 5) ad 100 ad 100 ad 100

• ⁵⁵ EO-PO-EO block polymer (EO = 40% by weight), OH = 39.1
• ⁵⁶ Trideceth 9 and PEG40-hydrogenated castor oil
• ⁵⁷ solution of chitosan (about 1 wt .-%) in a 0.4% aqueous glycolic acid solution

48. Skin Emulsions (O / W) 48.1 48.2 Emulgade® ^® SE ⁵⁹ 8.0 8.0 Cutina ^{® MD-60} A 1.5 1.5 Cetyl / stearyl 1.5 1.5 Myritol ^® 318 ⁶¹ 10.0 10.0 Derivative 7 2.5 1.0 2-ethylhexyl stearate 5.0 5.0 Dimethylpolysiloxane (350 at) 1.0 1.0 Controx ^® KS ⁶² 0.05 0.05 PHB propyl 0.2 0.2 PHB Methylester 0.2 0.2 champagne extract 0.5 0.25 1,2-propylene glycol 3.0 3.0 Hydagen® ^® CMF 3.0 8.0 ZnGluconate 0.04 0.10 Water (NaOH to pH = 5) ad 100 ad 100

• ⁵⁹ Mixture of: glyceryl stearate, ceteareth-20, ceteareth-12, cetearyl alcohol and cetyl palmitate (COGNIS)
• ⁶⁰ glyceryl stearates (COGNIS)
• ⁶¹ Caprylic / Capric Triglycerides (COGNIS)
• ⁶² Tocopherol and Hydrogenated Tallow Glycerides Citrate (COGNIS)

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited patent literature

• WO 92/13829 [0178]
• - DE 3929173 [0333]
• - DE 3929973 [0333, 0333, 0334]

Cited non-patent literature

• - DIN 60001 [0108]
• - ISO 6938 [0108]

Claims (40)

Protein hydrolysates obtained from hair of mammals with a hair density of at least 400 hairs per cm ² . Protein hydrolyzate derivatives obtained by chemical reaction of mammalian hair protein hydrolyzates having a hair density of at least 400 hairs per cm ² . Cosmetic compositions containing at least one protein hydrolyzate and / or at least one protein hydrolyzate derivative obtained from hair of mammals having a hair density of at least 400 hairs per cm ² . Textile treatment agent, preferably fabric softener or wool detergent, containing at least one protein hydrolyzate and / or at least one protein hydrolyzate derivative, obtained from hair of mammals having a hair density of at least 400 hairs per cm ² . Composition according to one of claims 3 or 4, characterized in that it comprises at least one protein hydrolyzate and / or at least one protein hydrolyzate derivative obtained from hairs of mammals having a hair density of at least 500 hairs per cm ² , preferably with a hair density of at least 1000 hairs per cm ² , more preferably with a hair density of at least 2000 hairs per cm ² , even more preferably with a hair density of at least 2500 hairs per cm ² and in particular with a hair density of at least 5000 hairs per cm ² . Agent according to one of claims 3 to 5, characterized in that it comprises at least one protein hydrolyzate and / or at least one protein hydrolyzate derivative obtained from Hair of mammals with a hair thickness of maximum 100 microns, preferably of at most 85 microns, especially preferably of not more than 75 μm and in particular of maximum 65 μm, included. Agent according to one of claims 3 to 6, characterized in that it - based on the weight of the ready-to-use agent - 0.05 to 20 wt .-%, preferably 0.1 to 15 wt .-%, particularly preferably 0.25 to 10 wt .-% and in particular 0.5 to 5 wt .-% protein hydrolyzate (s) and / or protein hydrolyzate derivatives from hair of mammals having a hair density of at least 400 hairs per cm ² included. Agent according to one of claims 3 to 7, characterized in that it comprises at least one protein hydrolyzate and / or at least one protein hydrolyzate derivative obtained from Hairs of Chinchillidae species included. Agent according to one of claims 3 to 8, characterized in that it comprises at least one protein hydrolyzate and / or at least one protein hydrolyzate derivative obtained from Hairs of rabbits, especially Angora rabbits. Agent according to one of claims 3 to 9, characterized in that it comprises at least one protein hydrolyzate and / or at least one protein hydrolyzate derivative obtained from Hair of goats, in particular of mohair or angora goats. Agent according to one of claims 3 to 10, characterized in that they additionally - based on the weight of the ready-to-use agent - 0.5 to 50 Wt .-%, preferably 1 to 40 wt .-%, particularly preferably 2.5 to 30 wt .-% and in particular 5 to 25 wt .-% of at least one surfactant contain. Composition according to Claim 11, characterized in that it comprises amphoteric surfactant (s) from the groups of - N-alkylglycines, - N-alkylpropionic acids, - N-alkylaminobutyric acids, - N-alkyliminodipropionic acids, - N-hydroxyethyl-N-alkylamidopropylglycines , - N-alkyltaurines, - N-alkylsarcosines, - 2-alkylaminopropionic acids each having about 8 to 24 C atoms in the alkyl group, - alkylaminoacetic acids each having about 8 to 24 C atoms in the alkyl group, - N-cocoalkylaminopropionate, - cocoacylaminoethylaminopropionate - C ₁₂ -C ₁₈ -acylsarcosine, - N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, - N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyl- dimethylammonium glycinate, - 2-alkyl-3-carboxymethyl-3-hydroxyethylimidazolines having in each case 8 to 18 carbon atoms in the alkyl or acyl group - cocoacylaminoethylhydroxyethylcarboxymethylglycinate - the compounds known by the INCI name cocamidopropyl betaine, The term "disodium cocoamphodiacetate" includes known compounds, preferred agents comprising the amphoteric surfactant (s) in amounts of from 0.5% to 9% by weight, preferably from 0.75% to 8% by weight, and most preferably 1% to 7.5 wt .-%, each based on the total agent included. Agent according to one of Claims 11 or 12, characterized in that it contains 0.1 to 10% by weight of at least one betaine of the formula (BI)

in which R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms, and / or 0.1 to 10% by weight of at least one betaine of the formula (B-II)

in which R is a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms. Composition according to Claim 13, characterized in that the radical R in the formulas (BI) and (B-II) is selected from - H ₃ C- (CH ₂ ) ₇ - - H ₃ C- (CH ₂ ) ₉ - H ₃ C- (CH ₂ ) ₁₁ - - H ₃ C- (CH ₂ ) ₁₃ - - H ₃ C- (CH ₂ ) ₁₅ - - H ₃ C- (CH ₂ ) ₇ -CH = CH- (CH ₂ ) ₇ - or mixtures of these. Agent according to one of claims 3 to 13, characterized in that there are no alkyl and alkenyl sulfates contains. Agent according to one of claims 3 to 14, characterized in that there are no alkyl and alkenyl ether sulfates contains. Agent according to one of claims 3 to 16, characterized in that it is sulphate-free. Agent according to one of Claims 3 to 17, characterized in that it contains no compounds of the formula (I) H- (O-CH ₂ CH ₂ ) _n -OH (I), in which n stands for integers between 1 and 100,000. Agent according to one of Claims 3 to 18, characterized in that it contains no compounds of the formula (II) H- (O-CH (CH ₃ ) CH ₂ ) _n -OH (II), in which n stands for integers between 1 and 100,000. Agent according to one of Claims 3 to 19, characterized in that it contains no compounds of the formula (III) R- (O-CH ₂ CH ₂ ) _n -OH (III), wherein R is any alkyl or alkenyl group and n is an integer between 1 and 10,000. Agent according to one of Claims 3 to 20, characterized in that it contains no compounds of the formula (IV) R- (O-CH ₂ CH ₂ ) _n -OSO ₃ H (IV), wherein R is any alkyl or alkenyl group and n is an integer between 1 and 10,000. Agent according to one of Claims 3 to 21, characterized in that there are no compounds which contain the grouping of the formula (V) - (O-CH ₂ CH ₂ ) _n - (V), in which n stands for integers between 2 and 100,000. Agent according to one of claims 8 to 22, characterized in that it is a hair cleanser which is additionally in a cosmetically acceptable Carrier at least one grooming enhancer from the group i. L-carnitine and / or its salts; ii. Panthenol and / or panthothenic acid; iii. the 2-furanones and / or their derivatives, in particular pantolactone; iv. Taurine and / or its salts; v. niacinamide; vi. ubiquinone vii. Ectoin; viii. allantoin; ix. Extracts of Echinacea contains. Hair treatment composition according to claim 23, characterized characterized in that it - based on its weight - 0.001 to 10% by weight, preferably 0.005 to 7.5% by weight, more preferably 0.01 to 5 wt .-% and in particular 0.05 to 2.5 wt .-% L-carnitine or L-carnitine derivatives, preferred L-carnitine derivatives are selected from acetyl-L-carnitine, L-carnitine fumarate, L-carnitine citrate, lauroyl-L-carnitine and especially L-carnitine tartrate. Hair treatment composition according to one of the claims 23 or 24, characterized in that - related on its weight - 0.01 to 5 wt .-%, preferably 0.05 to 2.5 wt .-%, particularly preferably 0.1 to 1.5 wt .-% and in particular 0.25 to 1% by weight of panthenol ((±) -2,4-dihydroxy-N- (3-hydroxypropyl) -3,3-dimethyl-butyramide) contains. Hair treatment composition according to any one of claims 23 to 25, characterized in that it - based on its weight - 0.01 to 15 wt .-%, preferably 0.025 to 12.5 wt .-%, particularly preferably 0.05 to 10 wt. %, more preferably 0.1 to 7.5% by weight and in particular 0.5 to 5% by weight of at least one 2-furanone derivative of the formula (Fur-I) and / or of the formula (Fur-II)

in which the radicals R ¹ to R ¹⁰ independently of one another represent: - hydrogen, -OH, a methyl, methoxy, aminomethyl or hydroxymethyl radical, --C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, --C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxy hydrocarbon radical, --C ₂ -C ₄ - saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbyl radical, - a group -OR ¹¹ , with R ¹¹ as a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxy-hydrocarbon radical, - a group -NR ¹² R ¹³ , where R ¹² and R ¹³ each independently of one another represent hydrogen, a methyl, e C ₂ -C ₄ saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, C ₂ -C ₄ saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxy hydrocarbon radical, - one Group -COOR ¹⁴ , where R ¹⁴ is hydrogen, a methyl, a C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ -saturated one or two times unsaturated, branched or linear mono-, di- or trihydroxy-hydrocarbon radical, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbyl radical, - a group -CONR ¹⁵ R ¹⁶ , where R ¹⁵ and R ^{16 are} each hydrogen, methyl, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ - saturated mono- or diunsaturated, branched or linear mono-, di- or trihydroxyhydrocarbyl radical, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbyl radical, - a group -COR ¹⁶ , wherein R ¹⁶ represents a methyl, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxy-hydrocarbon radical, a -C ₂ -C ₄ -saturated or mono- or diunsaturated, branched or linear mono-, di- or triaminocarbyl radical, - a group -OCOR ¹⁷ , where R ¹⁷ is a methyl -, -C ₂ -C ₃₀ - saturated or mono- or polyunsaturated, branched or linear hydrocarbon radical, a -C ₂ -C ₃₀ -saturated or mono- or polyunsaturated , branched or linear mono-, di-, tri- or polyhydroxy hydrocarbon radical, a -C ₂ -C ₃₀ -saturated or mono- or polyunsaturated, branched or linear mono-, di-, tri- or polyamino hydrocarbon radical, with the proviso that for the case when R ⁷ and R ^{8 are} -OH and at the same time R ⁹ or R ^{10 is} hydrogen, the remaining group R ⁹ or R ¹⁰ does not represent a dihydroxyethyl radical. Hair treatment composition according to one of the claims 23 to 26, characterized in that - related by weight - 0.01 to 15% by weight, preferably 0.025 to 12.5 wt .-%, particularly preferably 0.05 to 10 wt .-%, more preferably 0.1 to 7.5 wt .-% and in particular 0.5 to 5 wt .-% taurine (2-aminoethanesulfonic acid). Hair treatment composition according to one of Claims 23 to 27, characterized in that it contains, based on its weight, from 0.1 to 5% by weight, preferably from 0.2 to 4% by weight, more preferably from 0.25 to 3.5 Wt .-%, more preferably 0.5 to 3 wt .-% and in particular 0.5 to 2.5 wt .-% vitamins and / or pro-vitamins and / or vitamin precursors contains, preferably the groups A, B, C, E, F and H are assigned, with preferred means -2,4-dihydroxy-N- (3-hydroxypropyl) -3,3-dimethyl-butyramide, provitamin B ₅ ) and / or pantothenic acid (vitamin B ₃ , vitamin B ₅ ) and / or niacin, niacinamide or nicotinamide (vitamin B ₃ ) and / or L-ascorbic acid (vitamin C) and / or thiamine (vitamin B ₁ ) and / or riboflavin (vitamin B ₂ , vitamin G) and / or biotin (vitamin B ₇ , vitamin H) and / or folic acid (vitamin B ₉ , vitamin B _c or vitamin M) and / or vitamin B ₆ and / or vitamin B ₁₂ . Hair treatment composition according to any one of claims 23 to 28, characterized in that it - be based on its weight - 0.0001 to 1 wt .-%, preferably 0.001 to 0.5 wt .-% and particularly preferably 0.005 to 0.1 wt .-% of at least one ubiquinone and / or at least one ubiquinol and / or at least containing a derivative of these substances, preferred agents containing a ubiquinone of the formula (Ubi)

in which n stands for the values = 6, 7, 8, 9 or 10, particularly preferably 10 (coenzyme Q10). Hair treatment composition according to one of the claims 23 to 29, characterized in that - related on its weight - 0.001 to 10 wt .-%, preferably 0.01 to 5 wt .-%, particularly preferably 0.05 to 2.5 wt .-% and in particular 0.1 to 1% by weight of (S) -2-methyl-1,4,5,6-tetrahydro-4-pyrimidinecarboxylic acid (ectoine) and the physiologically acceptable salts of this compound and / or (S, S) -5-hydroxy-2-methyl-1,4,5,6-tetrahydro-4-pyrimidinecarboxylic acid (Hydroxyectoine) and the physiologically acceptable salts of these Compound contains. Hair treatment composition according to one of the claims 23 to 30, characterized in that - related on its weight - 0.001 to 10 wt .-%, preferably 0.01 to 5 wt .-%, particularly preferably 0.05 to 2.5 wt .-% and in particular 0.1 to 1% by weight of 5-ureidohydantoin (allantoin). Hair treatment composition according to one of the claims 23 to 31, characterized in that - related on its weight - 0.001 to 10 wt .-%, in particular 0.01 to 2% by weight of active ingredient, obtainable from plants of the genus Echinacea, preferably from pressed juices and extracts, which are obtained from Echinacea purpurea contains. Hair treatment composition according to any one of claims 23 to 32, characterized in that it - based on its weight - from 0.001 to 2.5 wt .-%, preferably 0.0025 to 1 wt .-%, particularly preferably 0.005 to 0.5 wt. % and in particular 0.01 to 0.1 wt .-% purine (s) and / or purine derivative (s), wherein preferred agents purine and / or purine derivative (s) of the formula (Pur-I)

in which the radicals R ¹ , R ² and R ^{3 are} independently selected from -H, -OH, NH ₂ , -SH and the radicals R ⁴ , R ⁵ and R ^{6 are} independently selected from -H, -CH ₃ and -CH ₂ -CH ₃ , where the following compounds are preferred: - purine (R ¹ = R ² = R ³ = R ⁴ = R ⁵ = R ⁶ = H) - adenine (R ¹ = NH ₂ , R ² = R ³ = R ⁴ = R ⁵ = R ⁶ = H) - guanine (R ¹ = OH, R ² = NH ₂ , R ³ = R ⁴ = R ⁵ = R ⁶ = H) - uric acid (R ¹ = R ² = R ³ = OH, R ⁴ = R ⁵ = R ⁶ = H) - hypoxanthine (R ¹ = OH, R ² = R ³ = R ⁴ = R ⁵ = R ⁶ = H) - 6 purine thiol (R ¹ = SH , R ² = R ³ = R ⁴ = R ⁵ = R ⁶ = H) - 6-thioguanine (R ¹ = SH, R ² = NH ₂ , R ³ = R ⁴ = R ⁵ = R ⁶ = H) - xanthine (R ¹ = R ² = OH, R ³ = R ⁴ = R ⁵ = R ⁶ = H) - caffeine (R ¹ = R ² = OH, R ³ = H, R ⁴ = R ⁵ = R ⁶ = CH ₃ ) - Theobromine (R ¹ = R ² = OH, R ³ = R ⁴ = H, R ⁵ = R ⁶ = CH ₃ ) Theophylline (R ¹ = R ² = OH, R ³ = H, R ⁴ = CH ₃ , R ⁵ = CH ₃ , R ⁶ = H). Hair treatment composition according to one of the claims 23 to 33, characterized in that - related on its weight - 0.001 to 2.5 wt .-%, preferably 0.0025 to 1 wt .-%, particularly preferably 0.005 to 0.5 wt .-% and in particular 0.01 to 0.1 wt .-% flavonoids, in particular flavonols, particularly preferred 3,3 ', 4', 5,7-pentahydroxyflavone (quercetin) and / or 3,3 ', 4', 5,7-pentahydroxyflavone-3-O-rutinoside (rutin), contains. Hair treatment composition according to one of claims 23 to 34, characterized in that it additionally contains 0.001 to 5 wt .-%, preferably 0.01 to 4 wt .-%, particularly preferably 0.02 to 2.5 wt .-% and in particular 0 , 1 to 1.5% by weight of bisabolol and / or oxides of bisabolol, preferably (-) - alpha-bisabolol

contains. Hair treatment composition according to one of the claims 23 to 35, characterized in that - related by weight - 0.01 to 15% by weight, preferably 0.025 to 12.5 wt .-%, particularly preferably 0.05 to 10 wt .-%, more preferably 0.1 to 7.5 wt .-% and in particular 0.5 to 5 wt .-% N-methyl-guanidino-acetic acid Contains (creatine). Hair treatment composition according to one of the claims 23 to 36, characterized in that it additionally - related by weight - from 0.001% to 5% by weight of anti-dandruff active substances, in particular, piroctone oleamine (1-hydroxy-4-methyl-6- (2,4,4-tri-methylpentyl) -pyridine-2 (1H) -one, Compound with 2-aminoethanol, 1: 1) and / or zinc pyrithione and / or Selenium sulfide and / or climbazole and / or salicylic acid or Contains fumaric acid. Process for the treatment of skin and hair, thereby characterized in that an agent according to one of the claims 3 or 5 to 37 applied to the skin and / or hair, distributed and after a contact time of a few seconds up to 45 minutes rinsed out with water again. Process for the treatment of textiles, by characterized in that a means according to claim 4 diluted or undiluted applied to the textiles, distributed and after a contact time of a few seconds up to 45 minutes rinsed out with water again. Use of hair treatment agent after one of claims 23 to 37 for the improvement of at least one the properties - Tensile strength of keratinic Fibers, in particular human hair; - stabilization the moisture balance of keratinic fibers, in particular human hair; - combability of keratinic Fibers, in particular human hair; - delay the aging process of keratinic fibers, especially human hair; - restructuring of keratinic fibers, especially human hair, during and after the Perming process; - Reduction of the elasticity decrease of keratinic fibers, especially human hair in case of damage by atmospheric influences.