DE102007042749A1 - Method for determination of specific nitrogen oxide emission as exhaust characteristic number of combustion engine, involves determining nitrogen oxide mass flow as operating characteristic - Google Patents

Abstract

The method involves determining nitrogen oxide mass flow as an operating characteristic and engine power output as another operating characteristic. The nitrogen oxide mass flow and engine power output are derived from a measured variable deviating from the operating characteristic. The exhaust characteristic number is computed as a quotient from corrected nitrogen oxide mass flow and engine power output. The carbon dioxide concentration in the dry exhaust gas is determined and carbon monoxide concentration in the dry exhaust gas is regulated. An independent claim is included for a device for determination of an exhaust characteristic number.

Description

The The invention relates to a method and a device for determination the specific nitrogen oxide (NOx) emission as the exhaust gas index of a Combustion engine.

in the In the wake of the ongoing climate debate have been in many areas of passenger and freight traffic for individual Transportation regulations and provisions on climate protection introduced the limit values for the Define exhaust emission. These limits are mostly relative Limits, because it has little sense, for example, the absolute emissions of a Plane with that of a car. That's why you use specific indicators, for example, sets the emission of pollutants in relation to the number of transported People.

There Such a key figure in the field of freight transport would not be very meaningful For example, the Marpol Convention in Annex VI in the shipping sector before, the exhaust emission of a ship in relation to the engine power to put, so gram pollutant per kilowatt of power and operating hours. Currently, the emission of sulfur oxides (Box) and nitrogen oxides (NOx) regulated. This rule is for all ships from a power of 130 kW already binding and valid worldwide, with compliance with the limit in each port to be checked by the local authority sanctions may also be imposed in the event of non-compliance.

Also in the automotive sector a similar specific Key figure conceivable, where currently discussed absolute limits which are difficult especially for powerful engines to be fulfilled.

In Every case is reliable and mobile measurement systems necessary to quickly and easily check the site Internal combustion engines to ensure compliance with the limits. Often, however, it is difficult or impossible to provide the necessary operating characteristics for Determination of the exhaust gas ratio to measure directly. For example, it is usually not possible the currently delivered power or the current fuel consumption to determine, without complicated attachments or conversions on the machine to do it yourself.

task The invention therefore relates to a method and a device, for simple real-time determination of a specific exhaust emission ratio of a Combustion engine under real conditions, to create.

These Task is inventively characterized solved, that the nitrogen oxide mass flow as the first operating characteristic and the Engine power output is determined as the second operating characteristic, the nitrogen oxide mass flow and the engine output from at least one of each of Operating characteristic deviating Measured derived is and the exhaust gas ratio as a quotient of the nitrogen oxide mass flow and the engine power output is calculated.

Thereby that the operating characteristics of easier derived measured quantities a process and measuring system can be used which without complicated and complex structures gets along. Such a method is therefore different at each location Engines used and enabled the reliable one Control of the exhaust gas ratio in real time.

Is appropriate it, when determining the two operating characteristics for different load conditions of the engine is repeated and the relation formed over the sums of the operating characteristic becomes.

Especially is appropriate it, if the belonging to a specific load level operating characteristics before the summation with the purpose of the engine adapted weighting factors For example, the weighting factors are multiplied can be stored in a table. In particular, it is possible the individual load levels vary in the index too consider. A ship's diesel is running mainly under full load, so the weighting factor will be higher here can be as idle, whereas an automobile mainly under part load or below and therefore the pollutant emissions in this Load range stronger can be weighted.

The specific exhaust gas ratio is preferred as a corrected nitrogen oxide mass flow defined per kilowatt of engine power and per hour of operation and hereinafter simply referred to as nitrogen oxide index.

In A first embodiment of the invention is the engine performance determined from the current torque and the engine speed, where the torque, for example, by a strain gauge the wave is determined.

A second embodiment of the determination of the nitrogen oxide index according to the invention provides for calculating the engine power from the fuel mass flow and the specific fuel (heavy oil) consumption of the engine. Where the specific fuel consumption is a value given by the manufacturer, which contains in tabular form, at which power the engine which fuel Ver has custom. By determining the current fuel consumption, the power can simply be read from the table or interpolated based on the table values.

from time to time However, it may be difficult or impossible to use a fuel mass flow sensor on Therefore, it may be useful to measure the fuel mass flow from the exhaust gas mass flow and the stoichiometric air requirement to calculate. By simple consideration of the reaction equation can be calculated back from the exhaust gas amount to the fuel mass flow.

there results in the stoichiometric Air demand from the chemical composition of the fuel, in particular the mass fraction of carbon, hydrogen and sulfur.

Of the Exhaust gas mass flow can also be difficult to measure, which is why over the Inlet mass air flow and an excess air factor on the exhaust gas mass flow be recalculated can. Considered the air excess factor, that not all air (oxygen) is necessary for combustion and therefore not in the fuel bill may enter.

The excess air factor is determined from the composition of the exhaust gas, in particular the volume concentration of the carbon oxides CO and CO ₂ and the hydrocarbons HC. Here, too, the measurement effort can be reduced by calculating the carbon dioxide content from the oxygen volume concentration.

Of the Inlet mass airflow is relatively easy with a vane anemometer or a similar one gauge measurable. If there is no access to the air intake of the engine, can However, it can also be calculated.

To is the speed, the cubic capacity and the number of cylinders of the engine, the charge air pressure and the charge air temperature after the intercooler and the ambient temperature as well as air pressure and relative humidity determined and calculated from the inlet air mass flow.

to Determination of the power thus provides several options depending on what kind of sensors available stand and which points are accessible on the engine. In the worst case Case is enough already a simple oxygen and hydrocarbon measurement in the Exhaust gas, including a small opening in the exhaust system is enough a thin one Introduce probe. All other data can then calculated from these measurements and known engine data.

Similarly be proceeded in the determination of the nitrogen oxide mass flow. Again, the direct measurement of mass flow is sometimes difficult, especially for ships, a mass flow measurement in the exhaust stack problematic feasible is. In addition, there is the problem that known measuring methods for Mass flow measurement can only determine a total mass flow and do not differ directly according to individual gas components.

Therefore it is necessary over a gas sensor to determine the volume concentration of nitrogen oxides and calculate the mass flow from it. Determine commercially available NOx sensors the concentration in dry exhaust gas, which is why the measurement result for Further use with a dry-moist correction factor becomes.

This dry-humidification correction factor is determined by the volume concentration of CO and CO ₂ as well as by the ambient conditions such as absolute air pressure, relative humidity and temperature.

The thus formed NOx concentration in wet exhaust gas is combined with the wet exhaust mass flow to a NOx mass flow, wherein the exhaust gas mass flow already in the performance determination measured or determined and therefore already present as value or can be determined by the same method.

Of the Now existing value of the NOx mass flow must again with a Moisture correction factor to be offset by a correct value to obtain the exhaust gas ratio calculation. This moisture correction factor is determined by the air temperature and the air pressure of the intercooler as well the ambient conditions such as absolute air pressure, relative humidity and temperature.

Thereby This method is universally applicable and easy in the field feasible. Especially on a ship it is possible with a simple Sample near the engine perform the oxygen and hydrocarbon measurement in the exhaust, without that elaborate Exhaust gas mass flow sensors need to be arranged in the fireplace.

Furthermore allows the real-time determination of the exhaust gas ratio an optimization of the combustion process in the engine, as observed directly and under real operating conditions can be, how are changes affect the exhaust gas concentration at the input parameters.

The method is the example below the determination of the weighted nitrogen oxide index GAS _{NOx in} accordance with Marpol 73/78 Annex VI, hereafter Marpol, with reference to the drawings.

It demonstrate:

1 a schematic arrangement for determining the exhaust gas ratio,

2 a flow chart for determining the weighted nitrogen oxide index,

3 a flow chart of a first method for engine output power determination,

4 a flowchart of a first method for the corrected nitrogen oxide mass flow determination,

5 a flowchart of a second method for engine output power determination and

6 a flowchart of a second method for the corrected nitrogen oxide mass flow determination.

In 1 a device for determining the nitrogen oxide index is shown, as it can be used for example for measuring on board a ship.

Central part of the system is a measuring device 30 that has a hose with an exhaust probe 31 is connected and suitable for measuring the exhaust gas volume concentrations of CO, CO ₂ , NOx and HC. For this purpose, the measuring device has a pump, which sucks in exhaust gas via the probe tip and pumps it through a sensor path in the measuring device. The measuring device has a modular design, so that further sensors can simply be plugged into the measuring section should further measured values, such as SOx, be required for other or future applications. The exhaust gas measured values 38 are sent to a central measured value detection device 32 forwarded.

Furthermore, the device has measuring devices for ambient 35 and engine parameters 36 on, by radio or via cable to the central data acquisition device 32 be transmitted.

The measured data in the central measured value acquisition device 32 are from at least one computer 33 which has a suitable program for performing the key figure calculation. The program is still supported by table data 37 the engine and fuel manufacturer available. As a result of the calculation can directly a corresponding certificate 34 to be issued. It is also possible with the calculator 33 To monitor the measurement data permanently, so that at any time a current value of the exhaust gas ratio can be calculated and displayed. It is also conceivable that the display is located directly on the ship's command bridge, so that the captain can monitor the exhaust emission of the engine at any time. As a result, malfunctions in the engine can be detected at an early stage and greater damage can be avoided.

In 2 is a flowchart of the method for determining the weighted nitrogen oxide index GAS _NOx 1 describing the nitrogen oxide mass output in the exhaust gas per kilowatt of power and hour of operation. Thus, the method includes determining the power 2 and the nitrogen oxide mass flow 3 , The performance 2 and the nitrogen oxide mass flow 3 is determined at different load levels of the engine and the values with a weighting factor 4 weighted. The nitrogen oxide code is calculated according to the step in the step 5 given formula:

About the weighting factors 4 takes into account that, depending on the application, a motor is mainly operated in a specific load range. For ships, this also depends on the type of drive. For example, the diesel engine of a diesel-electric drive will always drive at full speed so that the voltage generated has the correct frequency. Therefore, in a diesel-electric drive the pollutant emissions at low speed is negligible, since the engine is usually not operated in this area. On direct-driven ships, however, the speed is throttled when driving slowly. Why the pollutant emissions contribute to the total output here.

The in step 5 The calculation described above can also be applied to other specific key figures and would also be suitable for calculating, for example, the CO ₂ emissions per kilometer used in motor vehicles. Again, a weighting of different performance levels could be useful.

power 2 and nitrogen oxide mass flow 3 can be determined by different methods. A first method for determining performance is in 3 shown.

To determine the performance 2 Here is a torque measurement 6 provided on the shaft of the engine. For this purpose, for example, a strain gauge is attached to the shaft and converted the measured voltage into a torque. Along with the speed 7 the engine can be the power 2 can be calculated simply according to the formula P _i = T · 2π · n.

If, however, a measurement of torque 6 is not possible, for example, since there is no access to the shaft and no strain gauges can be attached is in 4 described a method for determining power, which does not require the measurement of torque and only makes simple demands on the measurement technology.

In a first step is out of the speed 7 , the number of cylinders 8th , the cubic capacity 9 , the charge air pressure 10 and the charge air temperature 11 after the intercooler, as well as the ambient conditions 12 such as absolute air pressure, relative humidity and temperature, the intake air mass flow 13 calculated.

In a second step, which is temporally independent of the first step but has to be carried out under the same conditions, the dry carbon dioxide volume becomes the concentration of the carbon dioxide 14 and carbon oxides 15 as well as hydrocarbons 16 measured. For this purpose, for example, a probe is introduced into the exhaust passage of the engine, through which the exhaust gas is sucked into a measuring device and is passed there via various sensors. Alternatively, the CO ₂ volumetric concentration can also be calculated from the oxygen concentration. From the three values can be an excess of air factor 17 calculate how much of the intake air was not needed for combustion.

From the intake air mass flow 13 and the excess air factor 17 becomes an exhaust mass flow 18 calculated.

In parallel, in a further step, the stoichiometric air requirement 19 from the specific composition of the fuel 20 calculated, wherein the composition is a value specified by the fuel manufacturer. The calculation can therefore be carried out in advance and the result can be temporarily stored. The interesting components are the carbon, sulfur and hydrogen content in the fuel.

By considering the reaction equation and the molar mass balance can be based on the exhaust gas mass flow 18 and the stoichiometric air requirement 19 the fuel mass flow 21 determine.

From the fuel mass flow 21 is in a final step with the present in tabular form engine manufacturer information on the specific fuel consumption 22 the performance 2 of the motor is calculated or interpolated.

4 shows a first method for the determination of the nitrogen oxide mass flow GNOX, which is required in addition to the power to calculate the nitrogen oxide index. An essential part of the method is the determination of the nitrogen oxide volume concentration 23 in dry exhaust. For this purpose, a sensor in the exhaust stream is necessary, which is advantageously arranged in the same meter, which among other things also for the measurement of carbon dioxide 14 is provided. In the simplest case, it is sufficient to install a corresponding sensor module in the airway of the meter, so that the installation cost is very low.

The NOx concentration must be further processed with a dry-humidification correction factor 24 from the ambient conditions already determined in the performance determination 12 and the carbon monoxide concentrations 14 . 15 is calculated on the volume concentration in wet exhaust gas 25 be converted.

In a parallel step, the fuel mass flow becomes 26 measured, for which purpose, for example, an impeller is installed in the fuel supply line. From the fuel mass flow 26 and the excess air factor already calculated in the performance determination 17 and the stoichiometric air requirement 19 becomes the wet exhaust gas mass flow 27 calculated.

From the wet exhaust mass flow 27 and the NOx concentration 25 In a next step, the wet NOx mass flow 28 calculated in the exhaust gas.

However, since the nitrogen oxide index must not be subject to environmental influences such as air humidity, in a further step, an NOx moisture correction factor must be determined from the ambient conditions already determined in the performance determination 12 and the charge air pressure 10 and the charge air temperature 11 after the intercooler, are calculated.

From the moist NOx mass flow 28 and the NOx moisture correction factor 29 is in a final step the NOx mass flow 3 calculated, which is needed to determine the nitrogen oxide index.

In 6 is another method for determining the NOx mass flow 3 shown that only in the determination of the fuel masses current from the procedure in 5 different.

As a fuel mass flow 21 Here is the calculated value from the performance determination according to 4 accepted. As a result, it is possible to dispense with a measurement of the fuel mass flow and to simplify the process considerably, since in most cases there is no possibility of subsequently or temporarily attaching a mass flow sensor to a motor.

Claims (26)

Method for determining the specific nitrogen oxide (NOx) emission as the exhaust gas index of an internal combustion engine, characterized in that the nitrogen oxide mass flow ( 3 ) as the first operating parameter and the engine output ( 2 ) are determined as a second operating characteristic that the nitrogen oxide mass flow ( 3 ) and the engine power output ( 2 ) are derived from in each case at least one measured variable deviating from the operating parameter, and the exhaust gas index is calculated as the quotient of the corrected nitrogen oxide mass flow ( 3 ) and the engine power output ( 2 ) is calculated. A method according to claim 1, characterized in that the determination of the first and second operating characteristic for different load conditions of the engine is repeated and the exhaust gas ratio ( 1 ) is formed as a quotient of the sums of the operating parameters. A method according to claim 2, characterized in that the operating characteristics of the different load conditions when summing each with a weighting factor ( 4 ) and the weighting factors ( 4 ) are adapted to the purpose of the internal combustion engine. Method according to claim 3, characterized in that the weighting factors ( 4 ) are stored in a table. Method according to one of claims 1 to 4, characterized in that the method step for determining the engine output power ( 2 ) includes the following additional steps: determining the actual torque ( 6 ) of the motor • Determination of the current speed ( 7 ) of the motor Method according to one of claims 1 to 4, characterized in that the method step determining the engine power output ( 2 ) comprises the following additional process steps: determination of the fuel mass flow ( 21 ) • Determination of specific heavy oil consumption ( 22 ) Method according to one of claims 1 to 4, characterized in that the method step determining the NOx mass flow ( 3 ) in the exhaust gas comprises the following additional process steps: • Determination of the moist NOx mass flow in the exhaust gas ( 28 ) • determination of a moisture correction factor ( 29 ) Method according to claim 7, characterized in that the step of determining the moisture correction factor ( 29 ) comprises the following additional process steps: • Determination of the charge air pressure after the intercooler ( 10 ) • Determination of the charge air temperature after the intercooler ( 11 ) • Determination of environmental conditions ( 12 ), absolute air pressure (p _B ), temperature (T _a ) and relative humidity (R _a ) A method according to claim 8, characterized in that the method step determining the moist NOx mass flow ( 28 ) in the exhaust gas comprises the following additional process steps: • determination of the moist exhaust gas mass flow ( 27 ) • Determination of NOx concentration ( 25 ) in the moist exhaust gas A method according to claim 9, characterized in that the method step determining the NOx concentration ( 25 ) in the moist exhaust gas comprises the following additional process steps: • Determination of the NOx concentration in the dry exhaust gas ( 23 ) • Determination of the dry-moist correction factor ( 24 ) A method according to claim 10, characterized in that the method step determining the dry-moist correction factor ( 24 ) comprises the following additional process steps: • Determination of CO ₂ concentration in dry exhaust gas ( 14 ) • Determination of CO concentration in dry exhaust gas ( 15 ) • Determination of environmental conditions ( 12 ), absolute air pressure (p _B ), temperature (T _a ) and relative humidity (R _a ) A method according to claim 9, characterized in that the method step determining the moist exhaust gas mass flow ( 27 ) comprises the following additional process steps: • determination of the fuel mass flow ( 26 ) • determination of excess air factor ( 17 ) • Determination of the stoichiometric air requirement ( 19 ) A method according to claim 6 or 12, characterized in that the method step determining the mass flow of fuel ( 26 ) comprises the following additional process steps: • Determination of the stoichiometric air requirement ( 19 ) • determination of the dry air mass flow into the combustion engine ( 18 ) Method according to claim 12 or 13, characterized in that the step of determining the stoichiometric air requirement ( 19 ) comprises the following additional process step: determination of the fuel composition ( 20 ), in particular the mass fractions of hydrogen, carbon and sulfur (ALF, BET and GAM) A method according to claim 13, characterized in that the method step determining the dry air mass flow ( 18 ) comprises in the internal combustion engine the following additional process steps: • Determination of the intake air mass flow ( 13 ) • determination of excess air factor ( 17 ) A method according to claim 15, characterized in that the method step determining the intake air mass flow ( 13 ) comprises the following additional process steps: • determination of engine speed ( 7 ) • Determining the number of cylinders ( 8th ) of the engine • Determination of the displacement ( 9 ) • Determination of the charge air pressure after the intercooler ( 10 ) • Determination of the charge air temperature after the intercooler ( 11 ) • Determination of environmental conditions ( 12 ), in particular absolute air pressure (p _B ), temperature (T _a ) and relative humidity (R _a ) A method according to claim 12 or 15, characterized in that the method step determining the excess air factor ( 17 ) comprises the following additional process steps: • Determination of CO ₂ volume concentration ( 14 ) in dry exhaust gas • Determination of CO volume concentration ( 15 ) in dry exhaust gas • Determination of hydrocarbon concentration ( 16 ) in the dry exhaust gas A method according to claim 17, characterized in that the method step determining the CO ₂ volume concentration ( 14 ) comprises the following additional process step: • Determining the oxygen concentration O ₂ in the exhaust gas Device for determining an exhaust gas ratio, characterized in that the device comprises means ( 30 . 31 . 35 . 36 ) for detecting a first and second operating characteristic, a measured value acquisition unit ( 32 ) and a computing unit ( 33 ), which is suitable from the operating characteristics of the exhaust gas ratio ( 1 ) to calculate. Device according to claim 19, characterized in that that the device has a sensor for determining the oxygen Volume concentration in the exhaust gas of the engine has. Device according to one of claims 19 or 20, characterized in that the device comprises a sensor for the determination of the NOx volume concentration ( 23 ) in the exhaust of the engine. Device according to one of claims 19 to 21, characterized in that the device comprises a sensor for determining the hydrocarbon concentration ( 16 ) in the exhaust of the engine. Device according to one of claims 19 to 22, characterized in that the device comprises a sensor for determining the speed ( 7 ) of the engine. Device according to one of claims 19 to 23, characterized in that the device sensors for determining the charge air temperature ( 11 ) and the charge air pressure ( 10 ) in the intercooler. Device according to one of claims 19 to 24, characterized in that the device comprises sensors for determining the ambient temperature (T _a ), the absolute air pressure (p _B ) and the relative humidity (R _a ). Device according to one of claims 19 to 25, characterized in that the sensors for transmitting the measurement data has a radio link to the Meßwerterfassungseiheit ( 32 ) exhibit.