DE10106216A1 - Green tea extract used for relaxation is decaffeinated and contains little tannin but has a high L-theanine content - Google Patents

Green tea extract used for relaxation is decaffeinated and contains little tannin but has a high L-theanine content

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Publication number
DE10106216A1
DE10106216A1 DE2001106216 DE10106216A DE10106216A1 DE 10106216 A1 DE10106216 A1 DE 10106216A1 DE 2001106216 DE2001106216 DE 2001106216 DE 10106216 A DE10106216 A DE 10106216A DE 10106216 A1 DE10106216 A1 DE 10106216A1
Authority
DE
Germany
Prior art keywords
green tea
decaffeinated
extract
tea extract
theanine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE2001106216
Other languages
German (de)
Inventor
Joachim Tretzel
Reinhold Zenger
Adolf Kler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DOEHLER EURO CITRUS NATURAL BE
PLANTEXTRAKT GmbH and Co KG
Original Assignee
DOEHLER EURO CITRUS NATURAL BE
PLANTEXTRAKT GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DOEHLER EURO CITRUS NATURAL BE, PLANTEXTRAKT GmbH and Co KG filed Critical DOEHLER EURO CITRUS NATURAL BE
Priority to DE2001106216 priority Critical patent/DE10106216A1/en
Publication of DE10106216A1 publication Critical patent/DE10106216A1/en
Ceased legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23FCOFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F3/00Tea; Tea substitutes; Preparations thereof
    • A23F3/16Tea extraction; Tea extracts; Treating tea extract; Making instant tea
    • A23F3/163Liquid or semi-liquid tea extract preparations, e.g. gels, liquid extracts in solid capsules
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23FCOFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F3/00Tea; Tea substitutes; Preparations thereof
    • A23F3/16Tea extraction; Tea extracts; Treating tea extract; Making instant tea
    • A23F3/20Removing unwanted substances
    • A23F3/205Using flocculating or adsorbing agents
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23FCOFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F3/00Tea; Tea substitutes; Preparations thereof
    • A23F3/36Reducing or removing alkaloid content; Preparations produced thereby; Extracts or infusions thereof
    • A23F3/366Reducing or removing alkaloid content; Preparations produced thereby; Extracts or infusions thereof by extraction of the leaves with selective solvents
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/02Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation containing fruit or vegetable juices
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/385Concentrates of non-alcoholic beverages
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/105Plant extracts, their artificial duplicates or their derivatives

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Dispersion Chemistry (AREA)
  • Botany (AREA)
  • Mycology (AREA)
  • Tea And Coffee (AREA)

Abstract

Green tea extract is decaffeinated and contains little tannin but has a high L-theanine content.

Description

Gegenstand der vorliegenden Erfindung ist ein coffeinarmer, gerbstoffarmer, theaninangereicherte Grünteeextrakt, Verfahren zu seiner Herstellung sowie seine Verwendung.The present invention relates to a low-caffeine, low-tannin, theanine-enriched green tea extract, process for its preparation and its use.

Normaler wässriger Grünteeextrakt enthält Koffein, Gerbstoffe und L-Theanin.Normal aqueous green tea extract contains caffeine, tannins and L-theanine.

Es ist bekannt, dass L-Theanin entspannende Wirkung besitzt.L-theanine is known to have a relaxing effect.

Die Erfindung hat sich die Aufgabe gestellt, einen Grünteeextrakt zur Verfügung zu stellen, welcher als entspannende Zutat auch zu Getränken oder Getränke­ konzentraten zugegeben werden kann.The object of the invention is to provide a green tea extract to provide which as a relaxing ingredient also to beverages or beverages concentrates can be added.

Diese Aufgabe wird gelöst durch einen Grünteeextrakt, der sowohl entkoffeiniert und gerbstoffarm, aber bezüglich L-Theanin angereichert ist.This task is solved by a green tea extract that is both decaffeinated and low in tannins, but enriched in L-theanine.

Ein derartiger Grünteeextrakt wird erfindungsgemäß hergestellt, indem Grün­ teeblätter, Grünteefannings oder Grünteepulver zunächst entkoffeiniert und dann mit Wasser extrahiert werden, woraufhin der Extrakt mit Polystyrol in Kontakt gebracht und anschließend aufkonzentriert wird.According to the invention, such a green tea extract is produced by green tea leaves, green tea tannins or green tea powder first decaffeinated and then extracted with water, whereupon the extract with polystyrene in Brought into contact and then concentrated.

Vorzugsweise wird der konzentrierte Extrakt anschließend zusammen mit einem Trägerstoff sprühgetrocknet, vakuumbandgetrocknet oder gefriergetrocknet.The concentrated extract is then preferably combined with a Spray dried, vacuum belt dried or freeze dried carrier.

Durch die Entfernung des Koffeins wird die entspannende Wirkung des Grüntee­ extrakts deutlich verstärkt.By removing the caffeine, the relaxing effects of green tea become extract significantly strengthened.

Die Entkoffeinierung erfolgt vorzugsweise mit den üblichen Methoden, wie zum Beispiel mittels überkritischer Kohlensäure oder Ethylacetat. Decaffeination is preferably carried out using the usual methods, such as Example using supercritical carbonic acid or ethyl acetate.  

Die erfindungsgemäße Behandlung des wässrigen Extrakts mit Polystyrol führt überraschenderweise zu einer teilweisen Entfernung der Gerbstoffe, nicht jedoch des L-Theanins. Bei dem erfindungsgemäßen Verfahren verbleiben eine geringe Menge Tee-Polyphenole im Extrakt, welche einerseits den Geschmack der Ge­ tränke verbessern, jedoch andererseits nicht mehr in der Lage sind, sonstige Bestandteile der Getränke und Getränkekonzentrate auszufällen. Durch den Zusatz des erfindungsgemäßen Grünteeextrakts zu Getränken oder Getränke­ konzentraten vermindert sich die Neigung zur Sedimentation.The treatment according to the invention of the aqueous extract with polystyrene leads Surprisingly, partial removal of the tannins, but not of L-theanine. In the process according to the invention, a small number remain Amount of tea polyphenols in the extract, which on the one hand affects the taste of the Ge improve potions, but on the other hand are no longer able to do other things Precipitate components of drinks and beverage concentrates. By the Addition of the green tea extract according to the invention to beverages or beverages the tendency towards sedimentation is reduced.

Zur Herstellung des erfindungsgemäßen Grünteeextrakts werden vorzugsweise Grünteequalitäten eingesetzt, die an sich schon einen höheren L-Theaningehalt besitzen. Der L-Theaningehalt von Grüntee bewegt sich laut Literaturangaben im Bereich von 0,2 bis 2.7%.For the production of the green tea extract according to the invention, preference is given to Green tea qualities used, which in themselves have a higher L-Theaningehalt have. According to the literature, the L-theaning content of green tea is in the Range from 0.2 to 2.7%.

Die Entkoffeinierung mit überkritischem CO2 erfolgt vorzugsweise im Tempera­ turbereich zwischen 30 und 70°C.Decaffeination with supercritical CO 2 is preferably carried out in the temperature range between 30 and 70 ° C.

Die wässrige Extraktion des entkoffeinierten Grüntees mit Wasser kann im Tem­ peraturbereich zwischen 10 und 90°C erfolgen. Der ablaufende Dünnextrakt wird gesammelt und über eine Absorberkolone mit Polystyrolharz geführt. Die ablaufende Menge wird gesammelt und aufkonzentriert.The aqueous extraction of the decaffeinated green tea with water can be temp temperature range between 10 and 90 ° C. The expiring thin extract is collected and passed over an absorber column with polystyrene resin. The running amount is collected and concentrated.

Zusammenfassend besteht das bevorzugte Verfahren somit aus folgenden Schritten:
In summary, the preferred method consists of the following steps:

  • 1. Als Rohstoff werden möglichst Grüntee-Qualitäten mit höherem Theaninge­ halt gewählt. Der Theaningehalt von Grüntee bewegt sich laut Angaben im Bereich von 0,2 bis 2,7%; vgl. Mukai, T., et. al. Tea Res. J., 76, 45, 1992 und Jkegaya, K., et. al., Bulletin of the National Research Institute of Vege­ tables, Ornamental Plants and Tea, 47, 1988. 1. Green tea grades with higher theaninge are used as raw materials just chosen. The theaning content of green tea is, according to information, in the Range from 0.2 to 2.7%; see. Mukai, T., et. al. Tea Res. J., 76, 45, 1992 and Jkegaya, K., et. al., Bulletin of the National Research Institute of Vege tables, Ornamental Plants and Tea, 47, 1988.  
  • 2. Selektierte Grüntee-Qualitäten werden in geeigneten Verfahren mittels CO2 oder Ethylacetat entkoffeiniert. Es können verschiedene Qualitäten, wie z. B. Blatt, Fannings als auch Pulver eingesetzt werden.2. Selected green tea qualities are decaffeinated using suitable processes using CO 2 or ethyl acetate. Different qualities, e.g. B. sheet, fannings and powder can be used.
  • 3. Durch anschließende Extraktion des entkoffeinierten Grüntees mit Wasser von 10-90°C wird ein Flüssig-Tee-Extrakt erhalten.3. Then extract the decaffeinated green tea with water from A liquid tea extract is obtained at 10-90 ° C.
  • 4. Der so gewonnene flüssige Grüntee-Extrakt wird durch ein Adsorberbett aus Polystyrol geleitet. Der durchlaufende, d. h. nicht adsorbierte Extraktanteil wird dabei gesammelt und aufkonzentriert.4. The liquid green tea extract obtained in this way is extracted through an adsorber bed Polystyrene headed. The continuous, i.e. H. extract portion not adsorbed collected and concentrated.
  • 5. Der oben beschriebene Grüntee-Extrakt kann anschließend durch geeignete Verfahren, wie Sprühtrocknung, Vakuumbandtrocknung, Gefriertrocknung, etc. mit oder ohne den Zusatz von Trägerstoff getrocknet werden.5. The green tea extract described above can then by suitable Processes such as spray drying, vacuum belt drying, freeze drying, etc. be dried with or without the addition of a carrier.

Das erfindungsgemäße Verfahren und das dabei entstehende Produkt werden durch die nachfolgenden Beispiele näher erläutert:The method according to the invention and the resulting product are explained in more detail by the following examples:

BeispieleExamples Beispiel 1example 1

300 kg Grünteefannings werden bei 30 bis 70°C mit überkritischem CO2 entkof­ feiniert. Der so behandelte Tee wird dann mit 3.000 l Wasser bei Temperaturen zwischen 10 und 90°C extrahiert. Der ablaufende Dünnextrakt wird gesammelt und über eine Absorberkolone mit Polystyrolharz geführt. Die ablaufende Menge von ca. 3.000 l wird gesammelt und konzentriert. Der entstandene Grünteeex­ trakt ist entkoffeiniert und gerbstoffarm, aber bezüglich L-Theanin stark ange­ reichert. 300 kg of green tea tannings are decaffeinated with supercritical CO 2 at 30 to 70 ° C. The tea treated in this way is then extracted with 3,000 l of water at temperatures between 10 and 90 ° C. The running thin extract is collected and passed over an absorber column with polystyrene resin. The running amount of approx. 3,000 l is collected and concentrated. The resulting green tea extract is decaffeinated and low in tannins, but is highly enriched in terms of L-theanine.

Beispiel 2Example 2

7,5 Teile des gemäß Beispiel 1 hergestellten Grünteeextraktes werden mit 13,5 Teilen Traubensaftkonzentrat (weiß, 65° Brix) und 6,2 Teilen Zitronensaftkon­ zentrat (klar, 50° Brix, 38,5% Säure) versetzt. Zusätzlich wird 0,1 Teil natürli­ ches Grünteearoma aus Tee (FTNF) zugesetzt. Dieses Gemisch wird in eine 6%ige Zuckerlösung eingebracht. Die Dosage des Grünteeextraktes wird so gewählt, dass das Fertiggetränk ca. 150 mg/l Theanin enthält und der Saftgehalt 10% beträgt. Vorzugsweise wird als Abfüllwasser enthärtetes Wasser verwen­ det.7.5 parts of the green tea extract prepared according to Example 1 are 13.5 Parts of grape juice concentrate (white, 65 ° Brix) and 6.2 parts of lemon juice con concentrate (clear, 50 ° Brix, 38.5% acid) added. In addition, 0.1 part is natural Green tea aroma from tea (FTNF) added. This mixture is in a 6% sugar solution introduced. The dosage of the green tea extract is like this chosen that the finished drink contains approx. 150 mg / l theanine and the juice content Is 10%. Softened water is preferably used as bottling water det.

Das so erhaltene Getränk hat eine typische Farbe und schmeckt angenehm nach Grüntee. Der dem Grüntee entsprechende adstringierende Nachgeschmack ist ebenfalls angenehm und nicht überproportional bitter. Das so erhaltene Getränk ist aufgrund seines fehlenden Koffeingehaltes und erhöhten L-Theaningehaltes nicht mehr anregend, sondern entspannend.The drink obtained in this way has a typical color and tastes pleasant Green tea. The astringent aftertaste corresponding to green tea is also pleasant and not disproportionately bitter. The drink so obtained is due to its lack of caffeine content and increased L-theaning content no longer stimulating, but relaxing.

Claims (6)

1. Grünteeextrakt, dadurch gekennzeichnet, dass er entkoffeiniert und gerb­ stoffarm, aber bezüglich L-Theanin angereichert ist.1. Green tea extract, characterized in that it is decaffeinated and low in tannin, but is enriched in terms of L-theanine. 2. Verfahren zur Herstellung eines entkoffeinierten, gerbstoffarmen, aber bezüg­ lich L-Theanin angereicherten Grünteeextraktes dadurch gekennzeichnet, dass Grünteeblätter, Grünteefannings oder Grünteepulver zunächst entkoffei­ niert und dann mit Wasser extrahiert werden, woraufhin der Extrakt mit Po­ lystyrol in Kontakt gebracht und anschließend aufkonzentriert wird.2. Process for the production of a decaffeinated, low tannin, but cover characterized L-theanine-enriched green tea extract, that green tea leaves, green tea tannings or green tea powder first decaffeinate niert and then extracted with water, whereupon the extract with Po lystyrene brought into contact and then concentrated. 3. Verfahren gemäß Anspruch 2, dadurch gekennzeichnet, dass der konzent­ rierte Extrakt anschließend ggf. zusammen mit einem Trägerstoff sprühge­ trocknet, vakuumbandgetrocknet oder gefriergetrocknet wird.3. The method according to claim 2, characterized in that the concentration Spray the extracted extract together with a carrier if necessary dries, vacuum belt-dried or freeze-dried. 4. Verfahren gemäß Ansprüche 2 oder 3, dadurch gekennzeichnet, dass mittels überkritischer Kohlensäure oder Ethylacetat entkoffeiniert wird.4. The method according to claims 2 or 3, characterized in that by means decaffeinated supercritical carbonic acid or ethyl acetate. 5. Verwendung eines entkoffeinierten, gerbstoffarmen aber bezüglich L-Theanin angereicherten Grünteeextraktes als Zutat zu Getränken oder Getränkekon­ zentraten.5. Use of a decaffeinated, low tannin but with regard to L-theanine Enriched green tea extract as an ingredient in drinks or beverages trates. 6. Verwendung gemäß Anspruch 5 als entspannend Mittel.6. Use according to claim 5 as a relaxing agent.
DE2001106216 2001-02-10 2001-02-10 Green tea extract used for relaxation is decaffeinated and contains little tannin but has a high L-theanine content Ceased DE10106216A1 (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006027063A1 (en) * 2004-09-04 2006-03-16 Unilever Plc Process for making tea
WO2006037503A1 (en) * 2004-10-01 2006-04-13 Unilever Plc Process for making tea extracts
WO2006037511A1 (en) * 2004-10-01 2006-04-13 Unilever Plc Process for making tea extracts
WO2008037417A1 (en) * 2006-09-26 2008-04-03 Plantextrakt Gmbh & Co. Kg Green tea extract, especially for use as a functional food item, food supplement or corresponding ingredient, the use thereof and method for producing said green tea extract
WO2008037418A1 (en) * 2006-09-26 2008-04-03 Plantextrakt Gmbh & Co. Kg Green tea medicinal extract, especially for use in the prophylaxis and treatment of diseases of the central nervous system or metabolic diseases, its use for producing a drug and method for producing the same
KR20230000018A (en) * 2021-06-23 2023-01-02 전남대학교산학협력단 Method for preparing green tea extract comprising high concentrated theanin and gaba

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3414767C2 (en) * 1984-04-18 1989-06-15 Hopfenextraktion Hvg Barth, Raiser & Co, 8069 Wolnzach, De
DE3313339C2 (en) * 1983-04-13 1991-03-21 Kord Beteiligungsgesellschaft Mbh & Co Kg, 2000 Hamburg, De
DE69322761T2 (en) * 1993-02-24 1999-05-20 Sara Lee/De N.V., Utrecht Recovery of activated carbon loaded with caffeine using organic solvents

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3313339C2 (en) * 1983-04-13 1991-03-21 Kord Beteiligungsgesellschaft Mbh & Co Kg, 2000 Hamburg, De
DE3414767C2 (en) * 1984-04-18 1989-06-15 Hopfenextraktion Hvg Barth, Raiser & Co, 8069 Wolnzach, De
DE69322761T2 (en) * 1993-02-24 1999-05-20 Sara Lee/De N.V., Utrecht Recovery of activated carbon loaded with caffeine using organic solvents

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Pat. Abstr. of Jp., 06100442 A *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006027063A1 (en) * 2004-09-04 2006-03-16 Unilever Plc Process for making tea
AU2005282039B2 (en) * 2004-09-04 2009-04-02 Unilever Plc Process for making tea
WO2006037503A1 (en) * 2004-10-01 2006-04-13 Unilever Plc Process for making tea extracts
WO2006037511A1 (en) * 2004-10-01 2006-04-13 Unilever Plc Process for making tea extracts
WO2008037417A1 (en) * 2006-09-26 2008-04-03 Plantextrakt Gmbh & Co. Kg Green tea extract, especially for use as a functional food item, food supplement or corresponding ingredient, the use thereof and method for producing said green tea extract
WO2008037418A1 (en) * 2006-09-26 2008-04-03 Plantextrakt Gmbh & Co. Kg Green tea medicinal extract, especially for use in the prophylaxis and treatment of diseases of the central nervous system or metabolic diseases, its use for producing a drug and method for producing the same
KR20230000018A (en) * 2021-06-23 2023-01-02 전남대학교산학협력단 Method for preparing green tea extract comprising high concentrated theanin and gaba
KR102575611B1 (en) * 2021-06-23 2023-09-07 전남대학교산학협력단 Method for preparing green tea extract comprising high concentrated theanin and gaba

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