DD151073A1 - METHOD FOR MODIFYING POLYMERS - Google Patents

Abstract

The invention particularly relates to the improvement of antistatic behavior and hygroscopicity or hydrophilicity. The aim of the invention is to obtain polymers permanently antistatic and with improved hydrophilic properties. These effects are achieved by applying polymerizable monomers containing quaternary ammonium groups to monovalent polymerizable comonomers.

Description

263/2753/111

200S57

Method of liodization of polishing

Field of application of grfinduri- ^:

The invention relates to the refinement of synthetic polymers, preferably of textile sheets of high-octane materials, especially to the improvement of the antistatic behavior and the hydrophilicity or hygroscopicity.

Char a kteristik; the known ^ n ^ technical solutions:

3s is known to use organic ammonium compounds as internal and external antistatic agents (RI3THILiYSR, S: Antistatics Terms, Construction and Use in Thermoplastics, Rubber, Asbestos, Kunststoffe 2o (1973) 2, pp. 76-76, 80, 88, 182, 134, 29ε, 300, 302, 304, 305, 308, 419-420, 425). Veiter is known to thermally fix Arnuoniumpolymere or copolymers on РоіушегоЬэг-flat. Sbenfalls begannt is vinylpyridine on foremen '"-ie Polyanid, polyester stralilenchei ^ i graft and subsequently through a ϊϊ-alkylation in Pyridiniurav he с indungen 3SU I ¹ \; andeln (ÜT-03 1 · 943 · 0δΊ, OH PS-39S. 4S4, OB-PS 872,217).

It is also known that vinyl monomers containing quinear groups of AEiT.Ion.iung ethyleneglycidene and Vinj'lbensylbr-iEiethylaEffinoniimichlorid grafting droplets (US Patent 3,026,292, US Patent No. 3,281,263). The radiation-chemical grafting of rewards, the reactive aruppen "s, B. Spoxyelgruppen, and their further Umsetzer ini Pfropfcopolynerisat su ^ 'лаіпо- or Ainmonirjaverbindunfen is also known (DI-OS 1.494-142, "GB-PS 916,529) -

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Also known is the radiation-chemical grafting of aminated acrylates with "non-methacrylates and vinylpyridines, some without, partly with low-acid treatment by weakly mineral acid solutions (DT-OS 1,420,333, US Pat. No. 3,281,263, US Pat. No. 3,088,791, US Pat. PS 3,412,172, OH-ES 380,372, OH-PS 398,494, QB-PS 872,217, QB-PS 901,042).

Furthermore, it is known that an antistatic or Eydrophilyeffelct can be achieved by grafting of monomers containing carboxylic or sulfonic acid groups and corresponding post-treatments such as introduction of alkali or Aznmoniumionen by ion exchange (Db-V ₁ ⁷ P 113,780, DI-OS 1,419 .117, DT-OS 1,420,639, US Pat. No. 999,056, US Pat. No. 3,099,331, US Pat. No. 3,488,258, SYS Patent 380,372, CH-PS 398,494, PE-PS No. 2,181,215, QB- PS 838.413). Furthermore, the use of mixtures of two or more monomers to grafting reactions is well known. In particular, nonionic monomers or unsaturated acids and nonionic ionomers are used. However, the use of itaconic acid with the weakly basic 4-vinylpyridine is also known (DT-OS 1,943,061).

These processes are mostly problematic in terms of their technology and economics, since they are mostly sweeping step processes.

When using antistatic agents that are not chemically bound to the substrate, the permanence of the antistatic effect is limited. On the other hand, polymerizable ammonia compounds have unfavorable diffusion behavior in polymers such as polyamide, polyester or polyacrylonitrile, which has insufficient degrees of grafting and, associated therewith, the formation of large amounts of water-soluble homopolymer for the olefin. From ITachteil is also that the achievable by grafting aainierter (meth) -Acrylate and Vinylpyridine achievable antichetrostatic effect due to their Sasisität is only very weak and for example for textiles an improvement in Wearingverhaltenö causes.

The same is true when working with the hydrochlorides or hydrosulfates of these compounds.

During i.'acchproscsaea, these did not undergo hydrolysis in practical use, in which the nonionic amino compounds are also formed. IVlylcylpyridinium compounds form with anionsalctivene env enences from Ya ash agents, eg, alkyl sulphates and -he- sulphonates. Very poorly soluble neutral salicylates with inadequate aiitielectrostatic activity are produced by the grafting of carbon building. Lilonoraeren containing Sulfonsäurogruppen and post recoverable antistatic effect is running in practical use by v / hile the washing and Spülprozecses lonenaustauschvorgänge, due to the content of alkaline earth UIID Schwernetallionen of the tap water, not permanent "The in 3? £? Op Ε - copolymerizing alkaline earth and heavy metal salts cause a near complete loss of the antistatic properties. These interfering ion exchange processes depend on the type of cations introduced during the aftertreatment.

The simpler part of the known process for the doping of itaconic acid and 4-vinylpyridine with respect to the production of antistatic properties is that they are not permanent in the vaporizing process. The initially existing improved electrical conductivity goes through the also taking place in this Systen Anlagervmg of Srdalkali and. Schv / ermetallionen to the acid group !! v / ähresd dec ', rapid and Spülprozssses lost. They are free to react with this reaction and the tertiary amino groups are effective in maintaining an anti-electrostatic effect.

Object of the invention:

The aim of the invention is to modify polymers so that permanently antistatic and with improved hygroscopicity bsw. Hydrophilio-treated products are obtained.

n 'of' .Ѵенеѵі о dor Srf

Technis che i - ^ ^ ZQV...

Auigabs of the invention is not suitable to use more suitable starting materials.

200557

del 'invention:

The object is achieved according to the invention by applying polyan-isocyanurate-compatible monomers containing quaternary ammonium groups to a polymer together with monovalent polyfunctional monomers.

It is advantageous, as a quaternary Anmraniumgruppen containing polymerizable monomers Dimethyldiallylammoniumhalogenide I der.Struktur

£ COE ₂ = CHCH ₂ ;, H * (OH ₃ J ₂ J ^Xe (I)

with χ = Cl, Br or IT-Trialkylaminoiaiumalkylacrylate II of the structure

£ CH ₂ = C (H ₁ ) 00 -R ₂ -U ⁹ H ₃ H ₄ H ₅ IX ^е (II)

with H ₁ = H, CH ₃

H ₂ = (OH g) _n ; a »1,2,3 ... E ₃₁ E ₄₁ R ₅ = alkyl

χ = Cl ₁ Br ₁ OH ₃ SO ₄

or H-trialkylammoniumalkylacrylanides III of Strulrtur Γ CII ₂ = C (R ₁ ) Cl ((R ₂ ) -E ₃ -I ⁹ Е ₄ Н ₅ еЛ χ ^β (III)

with E ₁ = H, CH ₃

H ₂ = H, alkyl E ₃ = (OH ₂ J _n ; η = 1,2,3 ... E ₄ , E ₅ , Hg> alkyl

χ = Cl, Br, CH ₃ SO ₄

to use.

Furthermore, it is advantageous alo monovalent poljaeriBatioaBfähige comonomers unsaturated carboxylic acids IV of the structure

CII ₂ = C (E) COOH (IV)

Eit H = H, CIIj, CIIgOOOH

or their derivatives, such as amides, ox trisils, or unsaturated sulfonic acids V, VI of the structures

CH ₂ = 0 (H ₁ ) -H 2 -SO ₃ H (V)

"" with R ₁ = H, OH ₃

R ₂ = (CH ₂ J _n ; η = 0,1,2,3 ...

^с б ^н 4 OE ₂ = 0 (H ₁ ) CR ₂ -E ₃ -SO ₃ H (¥ 1)

with E ₁ = H, OH ₃

S ₂ = HII, О

H ₃ = (0Η ₂ ) _η ·, η = 1,2,3 ...

^С 6 ^Н 4

to use.

In the case of the use of quonsernary ammonium groups containing ionic acids with unsaturated acids, it is irrelevant to the permanence of the antielectrical properties whether during the washing and rinsing process Ъеізріеівѵ / еізе alkaline earth ions are adsorbed to the acid group. In all cases, the good antiolecrostatic properties of the products produced are accounted for by the cationic component of the iono-ionic solution. The electrical V / iderstäncle _у д specified in the Auafuhrunsubeispielsn '' suggest dai3 before the V / aschbehandlung a strong ".". 'Eclicselwirkung 2v; een ate sauron and basic Gruppsn the HSR ^ ectollten S; -stene there. The electrical properties of this concept correspond etv / a to those resulting from the formation of a Лпіопе ^ епеіа-Ллгпопіиіікошріехез during the Ѵ / гхсІіогозоссе.

By angGvrer.aete Verfaliren be ιε addition to electrostatic Έ ± £ & 3Β &, £ ΐεζ> ^ іэісі ^ сіі "! ^ Important for ЗеісіеійгтззъехЪІИеп of synthetic ü'aoern in relation to a comfortable wearing properties hydrophilicity and Kygroskopisität improved. For CharakteriGierung hygroscopicity v; the uchtatsats: u ² ^

1) measured according to i'GL 16-650 272 Ъеі 65 % relative humidity and £ 2 ° ΰ

2) V.ac üer ^r ^ eli0.1t the Llaterialc according Linntcllung of Üorptionsoleicligcnvichtes boi G5% relative humidity and 22 ⁰ G in £

200SS7

below the invention to mohreron Ausiührungobeispielou explained in more detail v;

Example 1:

A gowirlre of polyanidaeide is made with a solution of the ingredients

25 parts I nit χ «Cl (Ia) 5 parts IV nit R = H (IVa)

70 parts '"' aoaer

contacted in a Poulard and squeezed off. The so-called LпргЦ ^ - niorte Laterial is with electron beams еіпез 31 оI: tron accelerator uit a dose rate of 1.5 x Ю i "d s" at an Eloktrononenergie 1 UoV in air bea-cracks. The irradiation amount is 3 ϊ 10 rd. Thereafter, unreacted Ъip. Parts not permanently fixed on the surface of the samarne sur- face removed from the tonsillar vein with a vasaer of 40 to 50 ° a.

! Laugh a 2гоокепрі * оаоЗ ". The modified b! aterial can immediately further-ϋ viex-the.

By Uodifiaierung daa LIaterial received Ilassesunelisie of 8.3% and a ^ euohussatia of _5} 6 ~ Л. 2'άτ the electrical .Tiders'jand give the following LIeSwerte:

1) I-eosin ~ after Zrodifisierun ^ at & 5 ^c , 'j relative humid and 22 ⁰ C

2) I-Iessun ^ after 40 LIaschinemväschen at 65% relative Luftfeuch-ue and 22 ⁰ C.

Example 2:

Implementation of the procedure in accordance with clause І. A cotton yarn of polyester silk is used for the soldering process. The acidification rate is 6.3 ^c / o, and the humid content is 5.3 / i-pur. The electric Ѵ / іаегзіаші results in the following lead values;

8,7 x 10 ¹⁰ XL i J * «11 s 10 ¹¹

* 8,7 x 10 ¹⁰ XL i J * «1,1 s 10 ¹

Example 3:

Perforation of the method according to Seicpiel 1. For the purpose of llodifying a knitted fabric made of acrylic fibers is used. The Best rahlungsdosis is 1 s 10 rd. Han gets a letdown of 4,8 % and a Peuclitesata of 4,8 %. Pure electrical resistance results in the following values; J = 8, б s 10 ¹⁰ H; y * = 1,2 χ 1O ¹¹ JQ.

Example 4 ;.

Sine solution from the Beatand parts

25 parts Ϊ with χ = 32? (Ib)

5 Ropes IYo, 70 Ropes'. Vaciser

is sur contacting a knitted fabric from Poljaraidaeide einge- зеЬ? Л, you ^ ^ civxiihrimz ^it Terfaiirens as in Example 1. 1'iS.n receives eino ІІаавезипаЬг.е of 6.7 ^С Л and S'euchtesatz vbn 5J2 ^c / o, For the electrical resistance the following results:

ρ "= 8.5 x 10 ¹⁰ H; ρ * = 1.0 s 10 ¹¹ £ L Ά Yes

Example 5:

Sine solution of the ingredients 15 ropes Ia

5 files Acrylamide GO parts '.,' Asser

2O05S7

is used for contacting a fabric made of polyamide silk. Implementation of the method according to Example 1. Ыап receives a Hassezunahnie of 5.9 % and a renewal rate of 5.4 ^C A · Pur the electrical resistance results in the following Meßv / erte:

/ <4.0 χ 10 ^s Л; j £ = 3.3 я W ¹⁰ XL

Example S:

A solution of components

10 ropes Ia 1 rope acrylamide

SO parts Yfesser

is used for contacting a fabric made of polyamide silk. Implementation of the method according to Example 1 * One obtains a biasoeaunahme of 1.4 % _t whereby the moisture content is indeed only slightly increased, but the wettability of the fabric is much improved. Pure electrical resistance results in the following key values:

у "« - 4.0 XW ⁸ U; J ¹ = 8.6 s 10

Example 7:

A solution of the components 10 ropes Ia

1 rope acrylonitrile 75 ropes V / asser

15 2 _e ile ethanol

It is used for dressing of Polyajaid silk. Procedure of the procedure according to example 1. Ilan receives an IJasBezunahne of 1.1 S. The wettability of the fabric is much improved, Kir the electrical Vriderstand the following Ueßwerte result:

y \ 4.0 χ 10 ^В Л; j * = 9.2 ze W ¹⁰ SX.

Example 8:

Sine solution of the ingredients 10 ropes Ia

2 ropes 2 - hydrox; ^R ethyl acrylate

becomes the Korvfcal: tiorunr; a ger. ^r ir2: os of polyamide silk used «performing luxis of the procedure according to example 1. lian receives еіpэ ire increase топ 4.3 JS and a wetness of 4.9; i. Kir don electrical resistance results in the following Heßwerte:

/ * 4.0 χ W ⁸ &; f ^Z ~ 3.8 χ 7O ^1O _ß_ Example 9:

An Ib'smig from the ingredients

25 ropes la 5 ropes V with R ₁ = Я, R ₂ = P ^ CgH ₄ (Vd)

70 ropes T / assel ·

It is used to contact a fabric with polyamide silk. Carrying out the method according to example 1. Кап receives a Uassezunalime of 7,8 Й and a Peuclrfcesatz of 5s 6 % » Kir the elelctrischen V / iderstand result the following measured values:

f ¹ = 8.4 χ 10 ¹⁰ U; f * = 9.9 s 10 ¹⁰ U.

Example 10:

Sine solution on the components

25 Ropes Ia 5 Rope = VI Bit R ₁ = Hf R ₂ = HH; H ₃ = OH ₂ (TIA)

70 hurry iTasser

It is used to contact a tissue made of polyesters. Carrying out the method according to example 1. A value of 3.4 % is then added to this and a rate of acidity of 2.3% of the electrical resistance gives the following values:

ρ "= 8.2 χ 1O ¹⁰ JX; γ ¹ = 1.0 χ Yes Yes

Example 11:

A solution to the components 55 Ropes Ia

5 ropes VI cit H ₁ = Hj R ₂ = 0; H ₃ = (Kl ₂ ) ^ (VId) 70 ropes', ',' tibcoi ·

v / ird to the Kontiitionffig a GsrirlceD made of polyamide D ei of a £ O set. Carrying out the procedure according to example 1. & Ian obtains an increase of 5> 7% and a moisture content of 5 _t 3% · S ¹ Ur the electrical resistance results in the following key values:

J * «9,0 χ 10 ¹⁰ Jl; $ «1,2 χ 10 ¹¹ Я

Example 12:

A solution of the ingredients

15 ropes II with ГЦ = Hj R ₂ »(CH ₂ ) ₂ ; H ₃ = CH ₃ IR ₄₁ H ₅ * =

= CH ₃ SO ₄ (IIa)

5 parts I7a SO parts V / asser

is used for contacting a knitted fabric made of polyanidaeide. The procedure according to Example 1, however, the irradiation dose is 1 χ 10 rd · LIan receives a pale increase of 6.7 5j and a 3 e luminance of 5.4 % · Hir, the electrical resistance results in the following Keßwertes y ^ «7, S ζ 1O ¹⁰ Xl; £ »9,7 ζ Ю ¹⁰ Ju,

Example 13:

To carry out the procedure according to Example 12. For modification, a fabric of polyester silk is used. LIan receives an increase of 5.5 / 5 and a weight ratio of 2.1 fj. The following values are given for the elixctricum of Jiderland:

f "« 8,3 x 10 ¹⁰ A if 'β 9,8 ζ 10 ¹⁰ Λ

Example 14;

By passing the procedure according to Example 12 for oil-dialysis, a slurry of acrylic fibers is dissolved. A slurry gauge of 5 * 3 and a weight of 2 * a is obtained.

200557

PLiR the electrical ./iderstand 'results in the following Ließv / erte: o * = 8.0 χ 1O ¹⁰ XJ. ; _J * = 9.7 X 10 ¹⁰ O.

Example 15:

A solution of the ingredients

15 parts II with R ₁ = CH ₃ ; R ₂ = (OHg) ₂ ; R ₃ R ₄ R = O ₃ H _5. ' χ = Br (lib)

5 parts IV with R = OH- (IVb) j

80 ropes "

is used to contact a fabric of polyamide soides. Performance of the method according to Example A mass increase of 6.3 % and a moisture content of 5.3 % × 5Ur electrical resistance τ / ground are obtained following Eeßwerte:

o * - 8,1 χ 10 ¹⁰ Xi. f = 9.8 ;; 10 ¹⁰ y.

Example 16:

Sine solution ^{of all} components 15 Seil Ha 5 parts IV nit H = OHgCiOOH (IVc)

20 I'eile V / ansar

It is used for the oilation of a polyanide silk vineyard. Carrying out the method according to example Lxm, an increase of 4, S ^c , a, and a moisture content of 5, ^1, 5, 3, ^{1, 1,} 2, 4, 4, 5, 4, 4, 5, 8, 8, 8, 8, 8, 8, 10, respectively, results in the following values:

J = 8,1 x IO й if = 1,0гЮ ¹ U Зо.іиді. эі 17: Зіпе LbGUi ^ s ^аг - ^с ^ ^{е ±} ' components

5 parts of i-ieth-1-acrylamide; 65 Healt, 'anoer 15 Soilo ethanol

SiU ¹ contacting a knitted fabric made of Acrylfacern used. Carry out the process according to Example 12. Llan receives a cup addition of 3.5, 3 and a good wettability. For the electrical resistance the following values are given:

/ = 6.9 X 10 ⁸ ß. ; J * »8,7 я 10 ¹⁰ Δ. Example 18:

Sine solution of the components 15 ropes Ha 5 parts V with R ₁ = Hj R ₂ = (0H ₂ ) _n for η = 0 (Va)

80 parts ϊ / asser

is used for contacting a knitted fabric made of polyamide silk. Execution of the Verfalirens according to Example 12. Kan receives a cash draw of 4.3 / J and a Peuchteoata of 4.8 Jo. JJ ¹ For the electrical resistance, the following values are obtained:

»^ = 8,7 к 10 ¹⁰ Xl i | * = 1,3i 10 ¹¹ Ω- Beisolel 19:

Sine solution of the ingredients

10 parts Ha

10 parts V with R ₁ = E, ¹ R ₂ = CHg (Vb) 80 parts' .Vasoer

to contact me; a Gev / irkea made of polyamide silk used. Carrying out the process according to Example 1. Kan receives an ilasaesu & ohme of 2.7 ^C A and a good wettability. Pure electrical resistance results in the following Eeßwerte:

y ^ = 8.6 χ 1O ^{1o .a} ; {J = 1.12 10 ¹¹ Ji Example 20

оЗіпе solution from the ingredients 15 parts Ua

5 parts V ait Ii ₁ = OH ₃ ; H ₂ = OH ₂ (Vc) 80 parts "./asser

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It is used for contacting an Oestrickea and Polyenterooide. Performance of the method according to Example LIan receives a Ilassezunahme of 2.3 % and a good wettability. ] The following values are given for the electrical resistance:

£ = 8.8 χ 10 ¹⁰ JX; J = 1.1 χ 1O ¹¹ Q. Example 21:

A solution from the Beatand parts

5 parts Ils

1 part Td 90 parts water

is used for contacting a knitted fabric made of polyamide silk, carrying out the process according to Example 12. A hassan increase of 3.9 % and an excess moisture of 1.7 ίί are obtained. The following measured values result for the electrical resistance:

у * = 8.9 к 1O ¹⁰ XJ. ; j * = 9, δ χ 10 ¹⁰ ß.

Example 22:

A solution of the ingredients

10 parts Ha 3 parts VIa

SO parts' .Vascer

is used for contacting a knitted fabric made of polyamide silk. Carrying out the procedure according to example 12. Kan receives a 4.3 % growth rate and a wetness rate of 4.9 fä. For electric resistance, the following values result:

£ ~ 8J χ 10 ¹⁰ Λ. ; J ^ = 9.5 χ Ю ¹⁰ β.

Sine solution of the ingredients 10 ropes Ha

3 should VI bit H ₁ = Ii; R ₂ = ITIIj R ₃ = (CH ₂ ) _2. (VIb) 90 parts ',! Aaaer

zvx contacting a fabric made of polyamide silk is used. Carrying out the process according to Example 12. Kan receives a cash increase of 4.1 % and a moisture content of 4.8 ', i. The electrical properties are as follows:

o "= 8.7 χ 10 ¹⁰ U; O = 9.7 x 10 ¹⁰ O #A Yes

Example 24:

A solution of the components 10 parts Ha 3 parts VI with R ₁ = H; R ₂ = HH; E ₃ = P- ^ ₆ H ₄ (VIo)

9.0 parts ", (a

is used for contacting a fabric made of polyamide silk. Implementation of the method according to Example 12. This gives a llassezunahme of 1.8 % and a good wettability, par the electrical resistance results in the following measurements:

»* = 9,2 ж 1O ¹⁰ JQ. ; f ¹ = 1.3 x 10 ¹¹ Sb

Example 25:

One syrup from the ingredients 10 parts Ila 3 parts VI nit E ₁ = CE ₃ ! H ₂ = O; E ₃ = PO ₆ H ₄ (7Ie)

90 parts 7, 'asser

It is used for contacting textile fabrics made of polyamide silk. Carrying out the procedure according to Example 12. This gives a Hassezunähme of 2.1 ^ and a good wettability. For the electrical resistance the following measurements were made. ^T erte:

f " = 9.0 χ 1O ¹⁰ JQ.; j> * = 1.1 X 10 ¹¹ Sl

ζ ииэ э /

 Example 26:

Bine solution of the components

10 Suppose III with R ₁₁ Rg = H; R ₃ = OH ₂ ; H ₄₁ R ₅ = EC

χ = CH ₃ SO ₄ (HIa)

5 parts IVa 85 parts "Juanen

v.'ird used for contacting a Gev / ebec of polyamide silk. Carrying out the procedure according to Example 12 "Ian receives an increase of 6.1 % and a phosphorus rate of 5.7 %. Mr electrical resistance results in the following values:

J ^ = 8.1 χ 10 ¹⁰ Λ; $ д = 9.4 χ 10 ¹⁰ Λ

Example 27:

Sine solution from the bedding parts

10th part III ait R ₁ = OH ,; R ₂ = H; R ₃ = (OHg) ₂ ;

R ₄ , E ₅ , R ₆ = C ₂ H ₅ ; T. = Br (IHiO

5 parts Äcr-ylsaid 85 ropes Vauaer

is used for the purposes of a dressing of polyanide silk. "Diarrhea of the process according to Example 12. Ivlan obtains a kassunahcie of 5.9 % and a Youngtate of 5, G %. For the electrical resistance the following values result:

J _A ¹ = 6.3 - 10 ⁸ Jl,; ^ = 3.9 X 10 ¹⁰ Л

Belaplel 2S:

Sine Löeun £ from the ingredients

10 -loilo IHa 5 ropes 2-I-b'droxi'äthylaorylat

85 ieile Ѵасьм?

νίχϊα to Kontoitierung eino Geoobeo from Polyamidoeide einjoeetf.t. The method according to Example 12. Ъст receives one! .ІаоиСЕіиіаіше of 6.8 fj and a peuclitoo of 6, 'i ^c , i.

The electrical resistances are as follows: J ** 4.0 χ 10 ⁸ Xl;} * = 8.6 χ 10 ¹⁰ JO.

Example 29:

A solution of the components

10 parts HIa 5 parts Vd

85! Ile / asser

is used to contact a Qevirlces of polyamide silk. Implementation of the method according to Example 12. This gives a Hassezunähme of 5.7 % and a moisture content of 5i6 / i. E ¹ Ur the electrical resistance, the following IieSv; erte:

/ = 8.5 к 10 ¹⁰ Xl ; $ l = 9, S χ 10 ¹⁰ ^ L

Claims (4)

1st method sur. Modification of Polymers, Preferably Testils, Forming High-Polymers V / Ceramics, Whose Substances are Applied to Polymers and Irradiated with High-Energy Rays, characterized in that Polynierization-Acceptable Monomers Containing Quaternary Jtoammonium Groups are Co-Applied Together with Monovalent Polymerizable Monomers earth. 2. The method according to Punlct 1, characterized in that as a quaternary ammonium ^ PPQ ^ containing polymerisationsfäliige monomers Dimethyldiallylaminoniumhaloseaide of the structure [(CH ₂ β OHOHg) ₂ ϊϊ ^Φ (CH ₃ ) Л χ ^θ with s в 01, Br or ii-Irialkylammonirmiallcy! Acrylates of Strulitur I CI-I ₂ = 0 (R ₁ ) CO-H ₂ -II ^ ₃ R ₄ H ₅ J х ^Ѳ 0 R ₁ = H, CH ₃ R ₂ - (OHp) _n J η = 1,2,3 ... H ₃ -, R ₄ , n ₅ = alkyl X в Cl ₁ Br ₁ CH ₃ SO ₄ or F-Sriallcylansioniuiaallcylacrylaniide the structure with E ₁ = H, OH ₃ R ₂ = H, alkyl E ₃ = CCSH ₂ J ₁₁ ; л »1,2,3. R ₄ . R ₅ , Ii ₅ = alkyl messy / earth · 2005S7 3 'method according to item 1, characterized in that as monovalent polymorisationsfa'higo monomers unsaturated carboxylic acids of the structure GH _{K 2} C (R) COOH with R = H, CH ₂ , CH ₂ COOH or their derivatives or unsaturated sulfonic acids of the structures used / grounded. 4. The method according to item 1 and 2, characterized in that are used as derivatives of the unsaturated carboxylic acids Anide, xTitrile or ester.